Abstract: Novel nickel and/or cobalt plated sponge based catalysts are disclosed. The catalyst have an activity and/or selectivity comparable to conventional nickel and/or cobalt sponge catalysts, e.g., Raney® nickel or Raney® cobalt catalysts, but require a reduced content of nickel and/or cobalt. Catalysts in accordance with the invention comprise nickel and/or cobalt coated on at least a portion of the surface of a sponge support. Preferably, the sponge support comprises at least one metal other than or different from the metal(s) contained in the coating. The method of preparing the plated catalysts, and the method of using the catalysts in the preparation of organic compounds are also disclosed.

Abstract: N2O is removed in nitric acid manufacture by using catalysts comprising three-dimensional structures coated with catalytically active materials.

Abstract: The present invention relates to novel singlet oxygen catalysts useful for the production of specialty chemicals. The catalysts include a core material selected from amine coated polymeric beads, amine coated glass beads and multi-generational dendrimers to which condensed carbon molecules are bonded. These catalysts may in turn give rise to other solid phase heterogeneous catalysts useful for stereoselective or regioselective reactions, by way of non-limiting example.

Abstract: Bulk and supported catalysts are prepared from an aqueous slurry containing a catalytically active material and a binder. The slurry is either coated onto a support and dried to form a porous, high surface area phase containing the catalytically active material, or reduced to a paste-like consistency, molded and dried to form a bulk catalyst. The processes and catalysts may be employed in various catalytic chemical processes to achieve high effectiveness factor of the catalytically active material while achieving a lower pressure drop.

Abstract: A catalyst for preferentially reducing carbon monoxide in a hydrogen stream. The catalyst is formed from a chemical composition including a hexaaluminate, a metal hydroxide and a precious metal. The composition may be disposed on a support or may be extruded or cast into or onto a support. Incorporation of hexaaluminates allows inclusion of metal hydroxides that flux the active precious metal surface at higher temperatures than can aluminum oxide-based catalytic compositions, thereby enhancing resistance of the catalyst and monolithic support and increasing the durability and thermal range of the PROX catalyst. An additional advantage is that lesser amounts of precious metal oxides need be deposited onto the hexaaluminate, while retaining activity similar to aluminum oxide compositions.

Abstract: A diesel oxidation catalyst comprising a honeycomb substrate washcoated with a mixture of clay, a refractory oxide and a zeolite is disclosed. The washcoated substrate is subsequently deposited with a precious metal catalyst and a sulfur oxidation suppressant.

Abstract: A metal oxide which has a large pore volume, and is very useful as a catalyst support. An alkaline material is added to an aqueous solution in which a compound of a metal element for composing an oxide is dissolved, a resultant mixture is co-precipitated, an obtained precipitate is washed, a washed precipitate is stirred in water along with a surfactant, and is calcined. By adding the surfactant after washing, the pH is not changed so that the adding effect of the surfactant is achieved to its upper most limit, thereby obtaining a metal oxide which has a large pore volume and a large mean diameter of secondary particles, and exhibits excellent gas diffusion properties.

Abstract: The invention relates to a passivated hydrogenation catalyst that is embedded in a primary amine, a derivative thereof, and/or a nitrile, the process to make such catalysts, as well as the use of such catalysts in a hydrogenation process in which an amine or a derivative thereof is produced.

Abstract: An electrode catalyst for a fuel cell is provided which excels in catalytic activity and catalytic durability. The electrode catalyst for the fuel cell has noble metal-containing particle deposited on an electroconductive carrier and the noble metal-containing particle possesses a core-shell structure comprising a core part formed of a noble metal alloy and a shell part formed of a noble metal layer different in composition from the core par and formed on the periphery of the core part. This core-shell structure enables the catalytic activity and the catalytic durability of the electrode catalyst to be enhanced simultaneously.

Abstract: A process for the preparation of mesostructured organofunctional silica and silica-alumina compositions using a hydrolyzable organosilane compound is described. The process uses a water soluble silicate to form the compositions, which have hexagonal, wormhole or foam mesostructures. The compositions are useful for catalytic and sorption applications.

Abstract: The present invention provides a bimodal porous carbon capsule with a hollow core and a mesoporous shell structure, which can be employed as an electrocatalyst support for a fuel cell; electrocatalysts for the fuel cell using the bimodal porous carbon capsule, and a method of preparing the same. The electrocatalyst according to the present invention has higher catalysis activity as compared with the Pt—Ru or Pt catalyst supported by the conventional carbon black, so that the performance of the fuel cell is enhanced, and it can be easily prepared in an aqueous solution state. According to the present invention, the porous carbon support employed as the support for the catalyst has excellent conductivity and a high surface area, so that the loaded catalyst can be prepared with a smaller amount than that of the conventional carbon black.

Abstract: Nanoporous metal foams are prepared by ignition of high nitrogen transition metal complexes. The ammonium salts of iron(III) tris[bi(tetrazolato)-amine], cobalt(III) tris(bi(tetrazolato)amine), and high nitrogen compounds of copper and silver were prepared as loose powders, pressed into pellets and wafers, and ignited under an inert atmosphere to form nanoporous metal foam monoliths having very high surface area and very low density.

Abstract: An improved catalyst system that includes a metal support structure and an anti-corrosive layer on the metal support structure, and has improved resistance to corrosion and other degradation under corrosive environments. Typically, a catalyst supporting layer is applied over the anti-corrosive layer.

Abstract: This invention aims at providing a catalyst body exhibiting a lower degradation of a catalyst due to thermal durability and capable of keeping higher catalyst performance for a long time. A catalyst component such as Pt is directly supported by Zr, W, etc, replacing elements inside a support such as Al of cordierite to provide a catalyst body without forming a coating layer. A combination of the catalyst component and the element inside the support is selected so that support strength is greater than 5 eV by simulation using a density functional method. Coarsening of catalyst particles can be suppressed and a high-performance catalyst body excellent in thermal durability can be obtained.

Abstract: The invention provides alumina agglomerates of the type obtained by dehydrating an aluminum hydroxide or oxyhydroxide, agglomerating the alumina obtained, hydrothermally treating the agglomerates and calcining. The invention also provides a catalyst support, an adsorbent material and a catalyst constituted by said agglomerates. The invention also provides methods for preparing said agglomerates.

Abstract: The present invention relates to a catalytic device for the implementation of a reaction in a gaseous medium at high temperature, such as, for example, the synthesis of HCN or the oxidation of ammonia, comprising: at least one textured material (1) which is effective as catalyst for the said reaction, a support (2) comprising at least one ceramic part (3), the structure of which makes possible the passage of the gases, the said part (3) of the said support (2) having a corrugated face (6), so that the increase in surface area (?) produced by the corrugations with respect to a flat surface is at least equal to that (?) calculated for sawtooth corrugations and of between approximately 1.1 and approximately 3, the said textured material (1) being positioned so that it is held against the corrugated face (6) of the said part (3) of the said support (2) and follows the form thereof.

Abstract: Provided herein are monocomponent and hybrid catalyst compositions for use in steam-cracking of hydrocarbon feeds to selectively produce light olefins. The catalyst compositions being characterized by a first catalytic component comprising oxides of aluminum, silicon, chromium, and optionally, oxides of monovalent alkaline metals, and further comprising a binder, preferably bentonite clay. Preferably, the catalyst compositions will comprise a catalytic component in accordance with the following formula: (a) SiO2·(b) A12O3·(c) Cr2O3(d) alk2O, with alk being a monovalent alkaline metal, preferably selected from sodium, potassium and lithium. The second catalytic component is selected from a crystalline zeolite or a silica molecular sieve. Also provided in the present invention are methods of making the catalyst compositions.

Abstract: The invention relates to alumina agglomerates of the type obtained by dehydrating an aluminium oxyhydroxide or hydroxide, agglomerating the alumina thus obtained, hydrothermally treating the agglomerates and calcinating same. Said agglomerates are characterised in that: the V37 ? thereof is greater than or equal to 75 ml/100 g, preferably greater than or equal to 80 ml/100 g and, better still, greater than or equal to 85 ml/100 g; the V0.1 ?m thereof is less than or equal to 31 ml/100 g; and the V0.2 ?m thereof is less than or equal to 20 ml/100 g, preferably less than or equal to 15 ml/100 g and, better still, less than or equal to 10 ml/100 g. The invention also relates to a catalyst carrier, an intrinsic catalyst or an absorbent, in particular for use in the petroleum and petrochemical industry, comprising such alumina agglomerates. Moreover, the invention relates to methods for preparing said agglomerates.

Abstract: A catalyst system for removing one or more components from a fluid stream includes a binder layer and a plurality of catalyst structures affixed to, and protruding from, the binder layer such that the catalyst structure surface is directly exposed to the fluid stream. Methods for preparing a catalyst system, and for selectively removing components from a fluid stream via a catalyst system are also disclosed.

Abstract: The present invention comprises a novel process for the preparation of carbon based structured materials with controlled topology, morphology and functionality. The nanostructured materials are prepared by controlled carbonization, or pyrolysis, of precursors comprising phase separated copolymers. The precursor materials are selected to phase separate and self organize in bulk, in solution, in the presence of phase selective solvents, at surfaces, interfaces or during fabrication, into articles, fibers or films exhibiting well-defined, self-organized morphology or precursors of well-defined, self-organized, bi- or tri-phasic morphology. Compositional control over the (co)polymers provides control over the structure of the phase separated precursor whose organization therein dictates the nanostructure of the material obtained after carbonization or pyrolysis, wherein each dimension of the formed structure can be predetermined.

Abstract: The present invention includes a catalyst structure and method of making the catalyst structure for Fischer-Tropsch synthesis that both rely upon the catalyst structure having a first porous structure with a first pore surface area and a first pore size of at least about 0.1 ?m, preferably from about 10 ?m to about 300 ?m. A porous interfacial layer with a second pore surface area and a second pore size less than the first pore size is placed upon the first pore surface area. Finally, a Fischer-Tropsch catalyst selected from the group consisting of cobalt, ruthenium, iron and combinations thereof is placed upon the second pore surface area. Further improvement is achieved by using a microchannel reactor wherein the reaction chamber walls define a microchannel with the catalyst structure is placed therein through which pass reactants. The walls may separate the reaction chamber from at least one cooling chamber. The present invention also includes a method of Fischer-Tropsch synthesis.

Abstract: The invention relates to a mechanically stable, porous shaped activated carbon article having a first three-dimensional framework structure based on carbonized resin, a second three-dimensional inorganic framework structure comprising ceramic material and/or baked refractory material, and binding agent, as well as activated carbon particles, in which the first and second framework structures penetrate each other at least partially and the activated carbon particles are fixed to the framework structures. The invention also relates to a process for the production of such a shaped activated carbon article and to the use thereof.

Abstract: A supported catalyst comprising a mixed metal oxide is useful for the vapor phase oxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated carboxylic acid and for the vapor phase ammoxidation of an alkane or a mixture of an alkane and an alkene to an unsaturated nitrile.

Abstract: According to the present invention, a water absorbent material and materials to be sucked included in a water permeable bag type member form a water absorber. Thus, the water absorber is small both in weight and volume upon its transportation, and accordingly, the water absorber can be rapidly conveyed in large quantities without depending on a human power. The water absorber absorbs water upon its use to adequately satisfy a function of a form traceability for weight, volume and outline.

Abstract: Electrocatalyst powders and methods for producing electrocatalyst powders, such as carbon composite electrocatalyst powders. The powders have a well-controlled microstructure and morphology. The method includes forming the particles from an aerosol of precursors by heating the aerosol to a relatively low temperature, such as not greater than about 400° C.

Abstract: Provided is a catalyst formulation which exhibits extended catalyst life. The formulation comprises a mixture of a ceramic foam material uniformly interspersed between the solid catalyst particles, with the volume percent of ceramic material in the mixture preferably ranging from 20 to 60 volume %. The catalyst formulation is particularly applicable to solid catalyst particles comprised of a phosphoric acid impregnated substrate, and is particularly useful for processes such as catalytic hydrocarbon condensation processes.

Abstract: Monolithic metallic catalyst substrates offering improved heat conductivity are provided from metal powder extrusion batches of copper, tin, zinc, aluminum, iron, silver, nickel, and mixtures and alloys thereof by extrusion through a honeycomb extrusion die followed by drying and firing in a two stage firing process to oxidize organic extrusion batch components, remove residual oxides from the porous wall structure, and consolidate the metal powders to strong, integral honeycomb support structures.

Abstract: A catalyst useful for catalytic vapor-phase oxidation of isobutylene, t-butanol or propylene to produce respectively corresponding unsaturated aldehyde and unsaturated carboxylic acid is provided. The catalyst consists of ring-formed shaped bodies composed of (i) a catalyst composition containing at least molybdenum and bismuth as the active ingredients and (ii) inorganic fibers. The catalyst excels in mechanical strength, can give the object products at high yield and shows little activity degradation with time.

Abstract: A method and system for the in situ synthesis of a combinatorial library including impregnating a first component with a second component. The method and system advantageously may be employed in the synthesis of materials for screening for usefulness as a catalyst.

Abstract: For carrying out a heterogeneously catalyzed reaction, such as the generation of hydrogen from hydrocarbons or alcohol, a reaction mixture comprising a hydrocarbon and water is supplied to a catalyst, which is produced by pressing at least one catalyst powder into a layer. Instead of a metallic housing, stacked layers are sealed by an edge seal, introduced into the layer or applied on the layer.

Abstract: An object of the present invention is to provide a manufacturing method by which alumina-silica based fibers excellent in mechanical strength can be readily and securely obtained, and the present invention obtains precursor fibers as a material by using an alumina-silica based fiber spinning stock solution for use in an inorganic salt method. Next, the precursor fibers are heated under an environment which makes it difficult to carry out an oxidizing reaction on the carbon component contained in the precursor fibers. Thus, the precursor fibers are sintered to obtain alumina-silica based fibers.

Abstract: A catalyst suited for catalytic vapor-phase oxidation of isobutylene, t-butanol or propylene to produce respectively corresponding unsaturated aldehyde and unsaturated carboxylic acid is provided. Said catalyst consists of ring-formed shaped bodies composed of (i) a catalyst composition containing at least molybdenum and bismuth as the active ingredients and (ii) inorganic fibers. The catalyst excels in mechanical strength, can give the object products at high yield and shows little activity degradation with time.

Abstract: A channelized sorbent material comprises porous sorbent particles characterized by an average pore diameter. Each sorbent particle has at least one interior channel of an average transverse dimension (i.e. transverse diameter) that is at least ten times larger than the average pore diameter of the porous sorbent particle. The interior channel may constitute a single cylindrical through-bore in the sorbent particle, or alternatively, an array of intersecting or non-intersecting channels. The porous sorbent particles preferably comprise bead activated carbon particles. Such channelized sorbent material is particular useful as sorbent media in an adsorption-desorption apparatus for storage and dispensing of a sorbable fluid.

Abstract: The present invention includes a catalyst having a layered structure with, (1) a porous support, (2) a buffer layer, (3) an interfacial layer, and optionally (4) a catalyst layer. The invention also provides a process in which a reactant is converted to a product by passing through a reaction chamber containing the catalyst.

Abstract: A silica-based photocatalyst fiber having visible-light activity, which fiber comprises a composite oxide phase comprising an oxide phase (first phase) mainly made of a silica component and a titania phase (second phase), wherein the second phase contains a metal element other than titanium and the existent ratio of the second phase slopingly increases towards the surface of the fiber, and a process for the production thereof.

Abstract: Metal catalysts comprising hollow forms or spheres are made of metal alloy and optionally activated. The metal catalysts can be used for the hydrogenation, dehydrogenation, isomerization reductive alkylation, reductive amination, and/or hydration reaction of organic compounds.

Abstract: Provided is a catalyst structure used for purifying an exhaust gas; to be disposed in an exhaust gas flow passage; preferable for obtaining a highly efficient and compact exhaust gas purifying apparatus; and produced by alternately stacking platelike catalysts 1, and gas dispersing members composed of netlike products 7 having many holes passing from the front surface to the back surface thereof, or linear, belt-shaped, or rodlike materials of a metal, ceramic, or glass to disturb the flow of an exhaust gas in a flow passage of the gas thereby to promote contact of the gas to be treated with the catalyst.

Abstract: A honeycomb body made from a ceramic material with improved radial pressure resistance that is of cylindrical shape and features a first and a second end face and a cylindrical shell and that is traversed from one end face to the other by axially parallel channels formed by channel walls and distributed across the cross section of the honeycomb body in a regular grid pattern, in which design an outer marginal zone of the honeycomb body, the thickness of which amounts to several channel diameters, encloses a central area. The increase in radial pressure resistance of the honeycomb body is achieved by reinforcing the ceramic material of the cylindrical shell and of the channel walls in the outer marginal zone of the honeycomb body by depositing on or in it one or several inorganic substances for the purpose of increasing its mechanical stability.

Abstract: One aspect of the invention relates to a catalyst composite containing an extruded catalyst support containing an extruded activated carbonaceous material having specifically a defined pore structure. For example, the extruded activated carbonaceous material may have pores wherein at least about 40% of total Hg porosity occurs in pores having a diameter of about 200 Å and larger. Alternatively the extruded activated carbonaceous material may have a first set of pores having a pore diameter of at least about 40 Å and at most about 100 Å with a porosity of at least about 0.15 cc/g, and a second set of pores having a pore diameter of at least about 5,000 Å and at most about 20,000 Å with a porosity of at least about 0.3 cc/g.

Abstract: An improved heterogeneous catalyst for catalyzing the reaction of gaseous reactants, comprising a high performance catalyst particle with a diameter to height ratio in the range between about 0.5:1 to 1.0:1.0, the high performance catalyst particle has a Relative Particle Size Parameter (RPSP) and a Geometric Surface Area (GSA), wherein the high performance catalyst particle has a higher GSA for a particular RPSP than a prior art catalyst particle. In another embodiment the improved heterogeneous catalyst with a diameter to height ratio in the range between about 0.5:1 to 1.0:1.0 has a Relative Particle Size Parameter (RPSP), a Geometric Surface Area (GSA), and an associated Relative Pressure Drop (RPD), wherein the high performance catalyst particle has a higher GSA for a particular RPSP or alternately a lower RPD for a particular GSA than a prior art catalyst particle.

Abstract: A silicon carbide-based porous material containing silicon carbide particles (1) as an aggregate and metallic silicon (2), wherein the average particle diameter of the silicon carbide-based porous material is at least 0.25 time the average particle diameter of the silicon carbide particles (1), or the contact angle between the silicon carbide particles (1) and the metallic silicon (2) is acute, or a large number of secondary texture particles each formed by contact of at least four silicon carbide particles (1) with one metallic silicon (2) are bonded to each other to form a porous structure. This silicon carbide-based porous material can be sintered, in its production, at a relatively low firing temperature and, therefore, can be provided at a low production cost, at a high yield and at a low product cost.

Abstract: A supported catalyst is provided comprising catalyst metal nanoparticles having an average particle size of 3.0 nm or less, or more typically 2.0 nm or less, and typically having a standard deviation of particle size of 0.5 nm or less, which are supported on support particles at a loading of 30% or more. Typical catalyst metals are selected from platinum, palladium, ruthenium, rhodium, iridium, osmium, molybdenum, tungsten, iron, nickel and tin. Typical support particles are carbon. A method of making a supported catalyst is provided comprising the steps of: a) providing a solution of metal chlorides of one or more catalyst metals in solvent system containing at least one polyalcohol, typically ethylene glycol containing less than 2% water; b) forming a colloidal suspension of unprotected catalyst metal nanoparticles by raising the pH of the solution, typically to a pH of 10 or higher, and heating said solution, typically to 125 ° C.

Abstract: A process for producing an acrylic polymer capable of providing a polymer controlled in molecular weight and free of colorization, and a heterogeneous polymerization catalyst used in the process for producing an acrylic polymer are provided. The heterogeneous polymerization catalyst contains (A) a radical generating substance, (B) a metallic halide containing a metallic element selected from the group consisting of the Group 4 to Group 12 elements and a halogen element selected from the group consisting of chlorine, bromine and iodine, and (C) a carrier carrying a ligand capable of forming a coordination bond with the metallic halide (B). The process for producing an acrylic polymer contains a step of polymerizing a monomer containing at least an acrylate and/or a methacrylate in the presence of the heterogeneous polymerization catalyst.

Abstract: Electrocatalyst powders and methods for producing electrocatalyst powders, such as carbon composite electrocatalyst powders. The powders have a well-controlled microstructure and morphology. The method includes forming the particles from an aerosol of precursors by heating the aerosol to a relatively low temperature, such as not greater than about 400° C.

Abstract: The present invention can realize a catalyst body which can efficiently achieve a catalytic reaction with a minimum required amount of catalyst and can exhibit high catalytic performance at low cost.

Abstract: The invention involves a process for production of macrostructures of a microporous material. The process is characterized by the fact that seeds formed in or introduced by ion exchange or adsorption to a porous organic ion exchanger with the desired size, shape and porosity are made to grow and form a continuous structure by further deposition of inorganic material from a synthesis solution under hydrothermal conditions. The organic ion exchanger can be eliminated by chemical destruction or dissolution and, in so doing, leaves behind an inorganic microporous structure with the size and shape of the employed organic ion exchanger.

Abstract: The invention provides a supported metal membrane which contains a metal membrane on a support surface of a porous membrane support. The supported metal membrane is obtainable by applying the metal membrane to the support surface of the membrane support, wherein the pores in the membrane support are sealed, at least in the region of the support surface, prior to applying the metal membrane and are opened by removing the auxiliary substance only after applying the metal membrane.

Abstract: Metal catalysts comprising hollow forms or spheres are made of metal alloy and optionally activated. The metal catalysts can be used for the hydrogenation, dehydrogenation, isomerization reductive alkylation, reductive amination, and/or hydration reaction of organic compounds.

Abstract: A titania-coated honeycomb catalyst matrix is provided for the ultraviolet-photocatalytic oxidation of organic pollutants in a flowing fluid. A honeycomb-shaped skeletal structure (12) has a thin, lightweight substrate (18) of metal or ceramic, typically an aluminum alloy, and a surface coating (20) of photocatalyst, such as titania. The photocatalyst (20) is bonded to the substrate (18) via a thin oxide layer (18′) on the substrate. The oxide layer (18′) may be grown on the substrate. The photocatalyst coating (20) is made by mixing (30) titania powder in a TiO2 sol-gel to form a titania slurry. The substrate with oxide layer is coated (30) with the titania slurry and then heat treated (31). The photocatalyst coating (20) is typically applied to substrate sheets (40, 60, 62) preformed for assembly into a honeycomb-shaped skeletal structure (12) having an array of parallel cells (46, 46′).

Abstract: A fixed bed Raney copper catalyst, which is doped with iron, noble metals or other metals, is employed as the fixed bed catalyst in the fixed bed dehydrogenation of alcohols.