An Additional Olefinic Reactant Is Copolymerized With An Unsaturated Carboxylic Acid Anhydride So That The Anhydride Moiety Forms Part Of The Polymer Backbone (i.e., Addition Polymerization) Patents (Class 508/235)
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Patent number: 10584297Abstract: Ethylene-C3-C10 alpha olefin copolymers, dispersants and lubricating oils/fuel compositions incorporating dispersants, and related methods are generally described herein. The copolymer may comprise ethylene-derived units and C3-C10 alpha-olefin-derived units. The C3-C10 alpha-olefin-derived units may have a carbon number from three to ten. For example, the C3-C10 alpha-olefin-derived units may be propylene-derived units.Type: GrantFiled: December 13, 2016Date of Patent: March 10, 2020Assignee: AFTON Chemical CorporationInventors: Nathaniel Cain, John T. Loper, Lawrence Cunningham, Joseph W. Roos
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Patent number: 9416280Abstract: The invention relates to a composition containing a particulate solid, an organic or aqueous medium, and a copolymer containing less than 25 mol % of residues of monomers comprising a dicarboxylic acid, or anhydride thereof. The invention further relates to novel copolymers, and the use of the copolymers as a dispersant.Type: GrantFiled: April 4, 2008Date of Patent: August 16, 2016Assignee: Lubrizol LimitedInventor: Stuart N. Richards
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Publication number: 20140364349Abstract: A lubricant composition of an oil of lubricating viscosity; an esterified copolymer with a backbone comprising units derived from (i) an ?-olefin monomer of at least about 6 carbon atoms and (ii) an ethylenically unsaturated carboxylic acid in a mole ratio of 1:3 to 3:1; and a polymer comprising olefin monomer units of 3 to 5 carbon atoms, wherein at least 50 percent by weight of such units contain fewer than 6 carbon atoms and wherein less than 5 percent by weight of such units are ethylene monomer units; exhibits good power transfer efficiency and elastohydrodynamic film thickness.Type: ApplicationFiled: February 14, 2013Publication date: December 11, 2014Inventors: Daniel J. Knapton, William R. S. Barton, Brett Wessler, Mark R. Baker
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Patent number: 8728995Abstract: A polyalkenyl succinic anhydride is prepared with low amounts of resinous or chlorinated byproducts in a two-step process whereby a polyalkene is first reacted with an unsaturated organic acid in a thermal ene reaction, followed with exposure to a gaseous halogen in presence of an additional amount of the unsaturated organic acidic reagent. The foregoing process produces a polyisobutenyl succinic anhydride having a high ratio of succinic anhydride functional groups to polyisobutenyl backbone groups. Such a polyisobutenyl succinic anhydride is particular suitable for the production of oil-soluble hydrocarbyl succinimides that have good dispersant properties when added to lubricating oil compositions.Type: GrantFiled: January 19, 2011Date of Patent: May 20, 2014Assignee: Afton Chemical CorporationInventors: Chente Huang, John T. Loper
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Patent number: 8410031Abstract: A process is provided for preparing an imidized polymer in a mixing or kneading device, by a reaction in the presence of an acid of a mixture containing a polymer having anhydride groups or derivatives thereof and an aromatic polyamine compound. A solid multifunctional viscosity modifier is also provided which includes a polymer having between 0.1 and 10 functional groups per 1000 C-atoms. The functional groups include aromatic amine based imide groups with a ratio of imide groups to the functional groups being more than 0.85.Type: GrantFiled: November 4, 2005Date of Patent: April 2, 2013Assignee: Lanxess Elastomers B.V.Inventors: Patric Meessen, Johannes Hendrik Geesink
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Patent number: 8071519Abstract: A composition comprising a blend of first and second esters: the first ester comprising a reaction product of first reactants comprising trimer acid, first polyhydric alcohol and first monohydric alcohol; the first monohydric alcohol selected from the group of C8-18 monohydric alcohols; the second ester comprising a reaction product of second reactants comprising trimer acid, second polyhydric alcohol and second monohydric alcohol; the second monohydric alcohol selected from the group of C6-10 monohydric alcohols; the first and second monohydric alcohols being non-identical. This blend of esters, in combination with silica, is useful as a sealant composition, e.g., as a cable-protectant composition.Type: GrantFiled: April 25, 2002Date of Patent: December 6, 2011Assignee: Arizona Chemical Company, LLCInventors: Lloyd A. Nelson, Nancy D. Mosby
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Patent number: 7897696Abstract: A polyalkenyl succinic anhydride is prepared with low amounts of resinous or chlorinated byproducts in a two-step process whereby a polyalkene is first reacted with an unsaturated organic acid in a thermal ene reaction, followed with exposure to a gaseous halogen in presence of an additional amount of the unsaturated organic acidic reagent. The foregoing process produces a polyisobutenyl succinic anhydride having a high ratio of succinic anhydride functional groups to polyisobutenyl backbone groups. Such a polyisobutenyl succinic anhydride is particular suitable for the production of oil-soluble hydrocarbyl succinimides that have good dispersant properties when added to lubricating oil compositions.Type: GrantFiled: February 1, 2007Date of Patent: March 1, 2011Assignee: Afton Chemical CorporationInventors: Chente Huang, John T. Loper
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Patent number: 7884058Abstract: A stable colloidal suspension comprising: (a) a dispersed phase comprising a major amount of one or more dispersed hydrated polymeric compounds selected from the group consisting of polymolybdates, polytungstates, polyvanadates, polyniobates, polytantalates, polyuranates, and mixtures thereof, and, (b) an oil phase comprising one or more dispersing agents and a diluent oil. Processes for preparing the stable colloidal suspensions and their use in lubricating oil compositions are also provided.Type: GrantFiled: September 30, 2003Date of Patent: February 8, 2011Assignee: Chevron Oronite Company LLCInventors: Kenneth D. Nelson, James J. Harrison
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Publication number: 20080139423Abstract: A graft copolymer containing one or more ethylenically-unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing graftable monomers grafted to a polyolefin is disclosed. Novel monomers, methods of making such monomers, and graft copolymers comprising such monomers are based on reacting an acylating agent with an amine to form a reaction product. The reaction product may include more than one chemical compound formed from the combination of the acylating agent and the amine. The monomer is the graftable, ethylenically unsaturated, aliphatic or aromatic, nitrogen- and oxygen-containing compound(s) of the reaction product. The monomer may, but need not, be recovered from the product mixture. The preferred monomer is the reaction product of maleic anhydride and 4-aminodiphenylamine. Also described is a method of making a dispersant viscosity index improver. The monomer of the present invention may be grafted to a polyolefin in solutions or melts.Type: ApplicationFiled: February 11, 2008Publication date: June 12, 2008Inventors: Irwin L. Goldblatt, Shean-Jer Chen, Manish R. Patel, Stephen T. McKenna
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Patent number: 6544935Abstract: A nitrogen-containing ester derived from a carboxy-containing interpolymer having a reduced specific viscosity (RSV) of from about 0.Type: GrantFiled: January 9, 2002Date of Patent: April 8, 2003Assignee: The Lubrizol CorporationInventors: Daniel M. Vargo, Craig D. Tipton, Richard M. Lange
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Patent number: 6284716Abstract: Copolymers I carrying functional groups and comprising a) 20-60 mol % of at least one monoethylenically unsaturated C4-C6-dicarboxylic acid or an anhydride thereof, b) 10-70 mol % of at least one oligomer of propene or of a branched 1-olefin of 4 to 10 carbon atoms, having an average molecular weight Mw of from 300 to 5000, and c) 1-50 mol % of at least one monoethylenically unsaturated compound which is copolymerizable with the monomers a) and b), a process for their preparation, oil-soluble reaction products obtainable therefrom by reaction with an amine and the use of said reaction products as additives for lubricants and fuels.Type: GrantFiled: March 12, 1996Date of Patent: September 4, 2001Assignee: BASF AktiengesellschaftInventors: Wolfgang Günther, Knut Oppenländer, Walter Denzinger, Heinrich Hartmann, Helmut Mach, Harald Schwahn, Hans Peter Rath
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Patent number: 6127322Abstract: The reaction product of (i) an oligomer formed from one monomer or two or more different monomers, the or each monomer being an ethylenically unsaturated compound and said oligomer or each of said monomers being optionally partially or fully esterified, with (ii) a polyalkenyl derivative of an ethylenically unsaturated carboxylic reagent (iii), and (iv) a polyamine containing at least two --NH.sub.2 and/or --NH groups, wherein at least one of the ethylenically unsaturated compounds of the oligomer has a functional group which can react with an amine; and the use of the reaction product for its dispercency and low haze properties in lubricant compositions, fuel compositions and additive concentrates.Type: GrantFiled: November 12, 1996Date of Patent: October 3, 2000Assignee: Shell Oil CompanyInventors: Richard Mark Scott, Robert William Shaw
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Patent number: 6100224Abstract: A copolymer comprising units of an unsaturated dicarboxylic monomer and an ethylene .alpha.-olefin macromer is disclosed. The macromer is an unsaturated ethylene .alpha.-olefin polymer comprising units of from ethylene and at least one .alpha.-olefin represented by the formula CH.sub.2 .dbd.CHR.sup.a, wherein R.sup.a is a C.sub.1 to C.sub.18 linear alkyl group or a C.sub.3 to C.sub.18 branched alkyl group; the ethylene .alpha.-olefin polymer has a number average molecular weight of from about 500 to about 100,000; and at least about 30% of the unsaturation in the ethylene .alpha.-olefin polymer is terminal vinylidene. The copolymer has a carbon-carbon backbone and contains succinic groups and hydrocarbyl groups. The copolymer can be derivatized by reaction with nucleophilic reactants including monoamines, polyamines, monoalcohols, polyols, amino alcohols, reactant metal compounds and mixtures thereof. The derivatized copolymers can be post-treated (e.g., borated) with one or more post-treating agents (e.g.Type: GrantFiled: October 1, 1997Date of Patent: August 8, 2000Assignee: Exxon Chemical Patents IncInventors: Dennis G. Peiffer, Kenneth Lewtas, Robert D. Lundberg, Pamela J. Wright, Antonio G. Lazarus, Jacob Emert
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Patent number: 6025308Abstract: A method is disclosed for preparation of amine functionalized copolymers by reacting copolymers of alkyl methacrylate and maleic anhydride with N-phenyl-1,4-phenylenediamine in mineral oil and inert atmosphere at 40 to 75.degree. C. The copolymers are useful viscosity index improvers when incorporated into lubricating oils.Type: GrantFiled: September 10, 1998Date of Patent: February 15, 2000Assignee: R. T. Vanderbilt Company, Inc.Inventors: Hidehiko Matsuya, Thomas J. Karol
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Patent number: 5719108Abstract: Dispersant/VI improvers for lubricating oil compositions are disclosed which comprise the reaction product of (a) a copolymer of octadecene-1 and maleic anhydride, the copolymer having a number average molecular weight from greater than 6300 to less than 12000; and (b) a succinimide prepared from a polyamine and an acyclic hydrocarbyl-substituted succinic acylating agent of the formula: ##STR1## wherein X and X.sup.1 are the same or different; provided that at least one of X and X.sup.1 is such that the copolymer can function as a carboxylic acylating agent, and optionally (c) a primary or a secondary hydrocarbyl monoamine or a mixture thereof, preferably an amine of the formula: ##STR2## wherein R.sup.1 is either a saturated or an unsaturated aliphatic hydrocarbyl group, and R.sup.2 is either R.sup.1 or hydrogen, and the total number of carbon atoms in the groups R.sup.1 and R.sup.Type: GrantFiled: November 18, 1996Date of Patent: February 17, 1998Assignee: BP Chemicals (Additives) LimitedInventors: Robert Ian Wilby, Pauline Bowden Jackson
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Patent number: 5652202Abstract: Copolymers and functionalised copolymers comprising ethylene units, in combination with non ethylene copolymer derivatives, give improved engine piston cleanliness when used as lubricating oil additives.Type: GrantFiled: August 15, 1995Date of Patent: July 29, 1997Assignee: Exxon Chemical Patents Inc.Inventor: David Robert Adams
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Patent number: 5616153Abstract: A novel copolymer of an unsaturated acidic reactant and an atactic vinyl terminated propene polymer (VTPP) and its use in preparation of fuel and lubricant additives is taught. The VTPP has a major amount of polymer chains containing terminal vinyl unsaturation, a number average molecular weight of at least 500, and comprises at least 70 weight per cent propene and 0 to 30 weight per cent of at least one olefin selected from the group consisting of C.sub.2 and C.sub.4 to C.sub.10 olefins. The unsaturated acidic reactant comprises at least one unsaturated C.sub.4 to C.sub.10 carboxylic or dicarboxylic acid or anhydride. An oil soluble dispersant additive of the invention useful in oleaginous compositions is prepared by contacting the atactic VTPP copolymer with at least one nucleophilic reagent selected from the group consisting of amines, alcohols, metal reactants and mixtures thereof under conditions effective to form adducts of the nucleophilic reagent with the copolymer.Type: GrantFiled: October 3, 1995Date of Patent: April 1, 1997Assignee: Ethyl CorporationInventors: Carl A. Mike, Joseph J. Valcho, Daniel Yuan-Fu Yu