Abstract: Molybdenum-free lubricating compositions are provided, having an antioxidation additive composition based on a combination of (1) alkylated diphenylamine (APDA), (2) polyamine dispersant, and (3) monoglyceride, ethoxylated amide, or mixtures thereof. Further synergy is achieved when component (3) is borated, allowing a reduction in phosphorus levels to below 0.08% or even a phosphorus-free composition.
Type:
Grant
Filed:
April 26, 2007
Date of Patent:
March 8, 2011
Assignee:
R.T. Vanderbilt Company, Inc.
Inventors:
Gaston A. Aguilar, Brian Stunkel, Steven G. Donnelly
Abstract: A lubricating oil composition is disclosed which comprises (a) a major amount of an oil of lubricating viscosity, (b) one or more phosphorus-containing anti-wear additives other than a zinc dithiophosphate, (c) one or more ashless dispersants, (d) one or more metal-containing detergents, and (e) one or more antioxidants, wherein the lubricating oil composition contains no more than about 0.03 weight percent of phosphorus, based on the total weight of the natural gas engine lubricating oil composition, and further wherein the lubricating oil composition is substantially free of any zinc compounds.
Abstract: The present disclosure relates to a lubricant composition comprising a first phosphorus compound, a second phosphorus compound, and a third phosphorus compound, wherein the first phosphorus compound is present in the lubricant composition in an amount to provide between about 120 and 350 ppm phosphorus. The lubricant composition may provide robust anti-wear and reduced pitting.
Abstract: A lubricant suitable for lubricating a two-stroke cycle engine which is fueled with a liquid fuel having a volatility less than that of gasoline comprises an oleaginous synthetic ester, a normally liquid solvent having a kinematic viscosity of less than about 5 or 2 mm2/s at 100° C. and a nitrogen-containing dispersant bearing a hydrocarbyl group of at least 26 carbon atoms and having a nitrogen content of at least 4 percent by weight. The nitrogen content of the lubricant is at least about 0.3 percent by weight.
Abstract: The present invention provides a lubricating oil composition for internal combustion engine exhibiting excellent fuel-saving performance for a long period of time. The lubricating oil composition for internal combustion engine is characterized by containing a base oil having a kinematic viscosity as measured at 100° C. of 2 to 10 mm2/s, an aromatic content (% CA) of 3 or less, and a sulfur content of 300 ppm by mass or less, and the following additives: (1) an alkaline earth metal salicylate-based detergent in an amount of 0.3 to 1.5 mass % as reduced to sulfated ash; (2) a zinc dihydrocarbyldithiophosphate in an amount of 0.03 to 0.10 mass % as reduced to phosphorus; (3) a succinimide-based ashless dispersant having a molecular weight of 500 to 4,000, and an alkenyl group or an alkyl group in an amount of 0.05 to 0.20 mass % as reduced to nitrogen; (4) a phenol-based ashless antioxidant in an amount of 0.05 to 3.0 mass %; (5) an amine-based ashless antioxidant in an amount of 0.05 to 3.
Abstract: A lubricating oil composition comprising a base oil of lubricating viscosity having a kinematic viscosity of 22 to 300 mm2/s at 40° C. and dissolved or dispersed therein the following additives in the following amounts based on a total amount of the lubricating oil composition: (1) an overbased sulfurized alkylphenol calcium salt detergent in an amount of 0.1 to 1.6 wt. % in terms of calcium content, (2) an overbased calcium alkylbenzenesulfonate detergent in an amount of 0.6 to 2.1 wt. % in terms of calcium content, (3) a nitrogen-containing ashless dispersant in an amount of 0.005 to 0.1 wt. % in terms of nitrogen content, and (4) a zinc dihydrocarbyldithiophosphate in an amount of 0.01 to 0.1 wt.
Abstract: Provided herein are lubricating oil compositions comprising a major amount of a base oil, at least one oil-soluble molybdenum compound and a zinc dialkyldithiophosphate compound, wherein the molybdenum content derived from the molybdenum compound is at least 10 ppm based on the total weight of the lubricating oil composition and the phosphorus content derived from the zinc dialkyldithiophosphate compound is about 200 to 500 ppm based on the total weight of the lubricating oil composition. The lubricating oil composition can further comprise at least one additive. Methods of making and using the lubricating oil compositions are also described.
Abstract: A lubricant additive gel formed by the gellation of two or more lubricant additives for the slow release of the additive components into a fluid. The lubricant additive gel slowly releases into its component lubricant additives when contacted with the fluid such as an oil thereby serving as a lubricant fluid such as an oil thereby.
Type:
Application
Filed:
August 23, 2010
Publication date:
December 16, 2010
Inventors:
James D. Burrington, Bruce H. Grasser, Herman F. George, John R. Martin, John K. Pudelski, James P. Roski, Barbara L. Soukup, Melinda E. Bartlett
Abstract: A lubricating oil composition of TBN 8-9 having up to 0.3 wt. % sulfur, up to 0.08 wt. % phosphorus, and a sulfated ash content up to 0.80 wt. %, comprising an overbased magnesium-containing lubricating oil detergent, and 2.5 to 4 wt. % of a nitrogen-containing ashless dispersant.
Abstract: Formulations using tartaric compounds of the present invention in a low sulfur, low ash and low phosphorous lubricant lower wear, and friction and improves fuel economy.
Type:
Application
Filed:
November 27, 2007
Publication date:
November 11, 2010
Applicant:
THE LUBRIZOL CORPORATION
Inventors:
Jody A. Kocsis, Jonathan S. Vilardo, Jason R. Brown, Daniel E. Barrer, Richard J. Vickerman, Patrick E. Mosier
Abstract: A synergistic demulsifier composition for the improvement of demulsification properties and method of making said composition is disclosed along with a lubricant composition containing same. The demulsifier composition consists of effective amounts of one or more demulsifier additives and one or more dispersants. The demulsifier additives consist of a first copolymer of propylene oxide and ethylene oxide and a second copolymer of propylene oxide and ethylene oxide. The dispersant can be an untreated polyalkene succinimide type dispersant, preferably an untreated polyisobutylene succinimide type dispersant.
Abstract: A lubricating oil composition of the present invention which contains an ether ashless friction modifier is applicable to a sliding surface having a low friction sliding member, is capable of imparting excellent low friction characteristics thereto and, in particular, is capable of giving a fuel saving effect when applied to an internal combustion engine.
Abstract: A lubricant additive gel formed by the gellation of two or more lubricant additives for the slow release of the additive components into a fluid. The lubricant additive gel slowly releases into its component lubricant additives when contacted with the fluid such as an oil thereby serving as a lubricant fluid such as an oil thereby.
Type:
Grant
Filed:
May 28, 2008
Date of Patent:
September 21, 2010
Assignee:
The Lubrizol Corporation
Inventors:
James D. Burrington, Bruce H. Grasser, Herman F. George, John R. Martin, John K. Pudelski, James P. Roski, Barbara L. Soukup, Melinda E. Bartlett
Abstract: A lubricant composition suitable for lubricating a direct fuel injection two-stroke engine comprises at least one condensation product of a fatty acid with an amine or ammonia and of at least one Mannich dispersant, each in an amount of 0.5 to 8 percent by weight, along with an oil of lubricating viscosity.
Type:
Grant
Filed:
April 17, 2003
Date of Patent:
September 14, 2010
Assignee:
The Lubrizol Corporation
Inventors:
Laimute R. Svarcas, William K. S. Cleveland, John L. Petric
Abstract: Formulations using tartaric compounds of the present invention in a low sulfur, low ash and low phosphorous lubricant lower wear, and friction and improves fuel economy.
Type:
Application
Filed:
May 17, 2010
Publication date:
September 9, 2010
Applicant:
Th Lubrizol Corporation
Inventors:
Jody Kocsis, Jonathan S. Vilardo, Jason R. Brown, Daniel E. Barrer, Richard J. Vickerman, Patrick E. Mosier
Abstract: Disclosed are lubricating oil compositions excellent in friction reducing effect and long drain properties and particularly suitable for internal combustion engines, which comprise a lubricating base oil, a specific phosphorus compound in an amount of 0.005 to 0.5 percent by mass in terms of phosphorus based on the total mass of the composition, and at least one additive selected from the group consisting of (C) metallic detergents, (D) ashless dispersants, and (E) anti-oxidants, and further contains (F) a sulfur-containing organic molybdenum complex and (G) an ashless friction modifier and which satisfy prescribed requirements and have a sulfated ash content not exceeding a specified level.
Abstract: Formulations using tartaric compounds of the present invention in a low sulfur, low ash and low phosphorous lubricant lower wear, and friction and improves fuel economy.
Type:
Application
Filed:
May 17, 2010
Publication date:
September 2, 2010
Applicant:
Th Lubrizol Corporation
Inventors:
Jody Kocsis, Jonathan S. Vilardo, Jason R. Brown, Daniel E. Barrer, Richard J. Vickerman, Patrick E. Mosier
Abstract: A lubricating oil composition includes: a lubricating base oil; and an imide compound, an amide compound and an aliphatic amine compound mixed with the lubricating base oil. A content of the imide compound is 300 to 1000 ppm by mass of the total amount of the composition in terms of nitrogen. A content of the amide compound is 380 to 1300 ppm by mass of the total amount of the composition in terms of nitrogen. A content of the aliphatic amine compound is 35 to 360 ppm by mass of the total amount of the composition in terms of nitrogen.
Abstract: A method for preventing or inhibiting exhaust valve seat recession in a natural gas fueled engine, the method comprising lubricating the engine with a natural gas engine lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity; and (b) an alkali metal-containing detergent, wherein the natural gas engine lubricating oil composition is substantially free of each of any alkaline earth metal-containing detergents and lithium-containing detergents is disclosed.
Abstract: A lubricating composition comprising an oil of lubricating viscosity, 1 to 80 parts per million by weight of titanium in the form of an oil-soluble titanium-containing material, and a salicylate detergent provides beneficial effects on properties such as deposit control, oxidation, and filterability in engine oils.
Abstract: Polyalkenyl succinimides which can be obtained with a process which comprises: a. reacting a reactive medium-high molecular weight polyalkene with maleic anhydride at a temperature higher than 180° C.; b. carrying out the reaction thermally for a time sufficient for having a conversion of the terminal vinylidene groups higher than 10%; c. completing the thermal reaction in the presence of a reaction accelerator consisting of a Lewis acid; d. reacting the reaction product of step (c) with an amine which has at least one primary aminic group capable of forming an imide group.
Type:
Application
Filed:
July 8, 2008
Publication date:
August 5, 2010
Applicant:
ENI S.P.A
Inventors:
Riccardo Rausa, Orazio Pianta, Alberto Roselli, Mauro Anzani
Abstract: The present invention relates to a method of lubricating an aluminium-composite surface by supplying to the aluminium composite surface (typically an internal combustion engine aluminium surface) a lubricating composition comprising an oil of lubricating viscosity and an ashless antiwear agent.
Abstract: Formulations using tartaric compounds of the present invention in a low sulfur, low ash and low phosphorous lubricant lower wear, and friction and improves fuel economy.
Type:
Application
Filed:
March 16, 2010
Publication date:
July 8, 2010
Applicant:
The Lubrizol Corporation
Inventors:
Jody Kocsis, Jonathan S. Vilardo, Jason R. Brown, Daniel E. Barrer, Richard J. Vickerman, Patrick E. Mosier
Abstract: Para-alkylated substituted diphenylamines are made by catalytically alkylating diphenylamine with a branched-chain alkene, such as propene, oligomer mixture in which the oligomer present in the greatest percentage has 15-24 carbon atoms. The alkylated diphenylamines are useful crankcase lubricant additives such as for reducing piston deposits and engine sludge.
Type:
Application
Filed:
June 6, 2008
Publication date:
July 8, 2010
Inventors:
Stephen Arrowsmith, Christopher J. Booth, Aubrey L. Burrows, Paul Wilson, Neal J. Milne, Lin Wangkan, Jacob Emert, Laurent Chambard
Abstract: The present invention for a two-stroke marine engine, which can be used with both high-sulphur content fuel oils and low-sulphur content fuel oils. It relates to a cylinder lubricant having a BN determined according to the standard ASTM D-2896 greater than or equal to 40 milligrams of potash per gram of lubricant, comprising a lubricant base stock for marine engines and at least one overbased detergent based on alkali metals or alkaline-earth metals, characterized in that it also contains a quantity of 0.01% to 10% preferably 0.1% to 2% by weight relative to the total weight of the lubricant, of one or more (A) compounds chosen from the primary, secondary or tertiary monoalcohols the alkyl or alkylene chain of which is saturated or unsaturated, linear or branched and comprises at least 12 carbon atoms.
Type:
Application
Filed:
October 5, 2007
Publication date:
July 1, 2010
Applicant:
TOTAL RAFFINAGE MARKETING
Inventors:
Valérie Doyen, Denis Lancon, Jean-Marie Bourmaud, Florence Bredon
Abstract: An oil-soluble lubricating oil additive composition prepared by a process which comprises reacting a succinimide, succinamide or mixtures thereof with a first post-treating agent, thereby producing an initial post-treated product which is reacted with a second post-treating agent.
Abstract: An oil-soluble lubricating oil additive composition prepared by the process which comprises (A) reacting a copolymer of an (i) an unsaturated acidic reagent; and (ii) a mono-olefin, with at least one linking hydrocarbyl di-primary amine, thereby producing a hybrid succinic anhydride copolymer having from about 10% to about 90% unreacted anhydride groups; and subsequently (B) reacting the hybrid succinic anhydride copolymer with a second amine compound, thereby producing the succinimide.
Abstract: A lubricant additive composition having environmentally compatible characteristics as defined by European Council Directive 67/548/EEC is disclosed. Such a composition may include components selected from non-persistent materials, non-bioaccumulative materials, or non-toxic materials.
Abstract: This invention relates to detergents, lubricating oil additives and compositions, and methods of preparing detergents, lubricating oil additives and compositions. More specifically, this invention relates to novel phenolic dimers.
Type:
Grant
Filed:
November 24, 2004
Date of Patent:
June 8, 2010
Assignee:
Afton Chemical Corporation
Inventors:
Abbas Kadkhodayan, Ju-Fu Shiau, Joe S. Bradley, Cathy C. Devlin, Charles A. Passut
Abstract: The present disclosure relates to a compound of the formula I or a tribologically acceptable salt, solvate, hydrate, or proadditive thereof, wherein R1, R2 and R4 are as defined herein. Such novel pyrrolidine, or succinimide, derivatives may be useful as friction modifiers in lubricant compositions. This disclosure also relates to a method of using such friction modifier compounds in lubricating fluid formulations to lubricate machine parts, including gear, axle, engine, and transmission parts, and to lubricant compositions containing such friction modifier compounds.
Abstract: A lubricant composition of a synthetic oil of lubricating viscosity, 3 to 6 percent by weight of a nitrogen-containing dispersant, 1 to 2.5 weight percent of an overbased magnesium detergent, 1 to 5 weight percent of an antioxidant; and 0.25 to 1.5 weight percent of a friction modifier is useful for lubricating a hydrogen-fueled engine. The composition will typically contain less than 0.01 weight percent Ca, less than 0.01 weight percent Zn, less than 0.06 weight percent P, and will have a sulfated ash level of less than 1.2%.
Abstract: The invention provides a lubricating composition containing an oil of lubricating viscosity, an amine-containing friction modifier, and an ashless antiwear agent. The lubricating composition is suitable for lubricating an internal combustion engine.
Abstract: An oil-soluble lubricating oil additive composition comprising (a) at least 3.5 wt-% of at least one friction modifier selected from the group consisting of fatty acids, fatty acid amides, fatty acid esters, and alkane diols which have a melting point of greater than 30° C.; (b) at least 10 wt-% actives dispersant; and (c) a sufficient amount of surfactant to make said additive composition haze-, sediment-, and skin-free, provided that said additive composition contains at least 150 mm surfactant per kg of said lubricating oil additive composition.
Abstract: Formulations using tartaric compounds of the present invention in a low sulfur, low ash and low phosphorous lubricant lower wear, and friction and improves fuel economy.
Type:
Application
Filed:
December 3, 2009
Publication date:
April 1, 2010
Applicant:
The Lubrizol Corporation
Inventors:
Jody Kocsis, Jonathan S. Vilardo, Jason R. Brown, Daniel E. Barrer, Richard J. Vickerman
Abstract: A lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity, (b) an ashless dispersant, (c) at least one metal-containing detergent, (d) an antioxidant, and (e) an anti-wear agent, wherein the lubricating oil composition is free of any zinc dialkyl dithiophosphate compound and is substantially free of any phosphorus content is disclosed.
Abstract: There is disclosed a fuel composition comprising (a) a major amount of a middle distillate fuel comprising from about 0.5% to about 30% by weight fatty acid methyl esters, relative to the total amount of the fuel composition; and (b) a minor amount of an additive composition comprising an antioxidant system comprising at least one cyclic amine antioxidant and at least one phenolic antioxidant, and at least one ashless dispersant, wherein said fuel composition demonstrates reduced sediment formation as compared to a fuel composition devoid of the additive composition, and methods of use thereof.
Abstract: The present invention relates to a lubricating composition containing a dicarboxylic acid ester or a dicarboxylic acid amide as an antiwear agent. The invention further provides a lubricating composition suitable for the mechanical device such as an internal combustion engine.
Type:
Application
Filed:
October 22, 2007
Publication date:
February 25, 2010
Inventors:
Jason R. Brown, Patrick E. Mosier, Paul E. Adams
Abstract: A lubricant in the form of a water or oil insoluble solvent in oil emulsion is described where a base (soluble or dispersible in said oil-insoluble solvent or water) is present in the dispersed phase. These lubricants are beneficial in various applications such as internal combustion engines where the oil needs enough basicity to neutralize any inorganic acids generated by sulfur present in the fuel.
Type:
Grant
Filed:
June 27, 2002
Date of Patent:
January 26, 2010
Assignee:
The Lubrizol Corporation
Inventors:
Stephen J. Cook, Alexandra Mayhew, Helena M. Cressey
Abstract: Copolymers made with allyl-terminated polyolefins and unsaturated acidic reactants, dispersants using same, and methods of making same are provided. Under one aspect, a copolymer of an unsaturated acidic reactant and high molecular weight polyolefin, wherein the polyolefin comprises an allyl-terminated polymeric product, is provided. The allyl-terminated polymeric product is formed, e.g., by forming a quasi-living tert-halide terminated polyolefin under suitable quasi-living conditions, and contacting the tert-halide terminated polyolefin with an allylsilane compound and a Lewis acid. In some embodiments, the allylsilane compound includes allyltrimethylsilane.
Abstract: A composition of the reaction product of (a) an polyisobutylene substituted succinimide dispersant; (b) an amine component comprising at least one aromatic amine containing at least one N—H group capable of condensing with said carboxylic acid functionality; and (c) an aldehyde; which may optionally be reacted with (d) a maleinated copolymer, is a useful dispersant viscosity modifier.
Abstract: Organo-Cobalt complexes having long chain saturated and unsaturated alkyl functionality as multifunctional additives in crankcase oils and the method of preparation thereof.
Type:
Grant
Filed:
January 27, 2005
Date of Patent:
January 19, 2010
Assignee:
The Lubrizol Corporation
Inventors:
Jonathan S. Vilardo, Jason R. Brown, William D. Abraham, Patrick E. Mosier, Paul E. Adams, Douglas T. Jayne, Richard M. Lange
Abstract: A molybdated succinimide complex is disclosed which is prepared by a process comprising (a) reacting an alkyl or alkenyl succinimide of a polyamine of formula I wherein R is an about C12 to about C30 alkyl or alkenyl group; a and b are independently 2 or 3, and x is 0 to 10, with an ethylenically unsaturated carboxylic acid or anhydride thereof; and (b) reacting the product of step (a) with an acidic molybdenum compound. Also disclosed is a lubricating oil composition containing at least (a) a major amount of a base oil of lubricating viscosity and (b) a minor amount of the molybdated succinimide complex.
Abstract: A slideway lubricating oil composition, additive concentrate, method of lubricating sliding parts. The lubricating oil includes a base oil; a metal-free friction modifier; and a metal-free, sulfur-free, phosphorus containing anti-wear/extreme pressure agent. The lubricating oil provides a lower coefficient of friction for non-metal sliding surfaces than for metal sliding surfaces.
Type:
Application
Filed:
June 23, 2008
Publication date:
December 24, 2009
Applicant:
AFTON CHEMICAL CORPORATION
Inventors:
Mark T. Devlin, Helen T. Ryan, Katie A. Hudson
Abstract: The present invention relates to an automatic transmission lubricating oil composition, and particularly to an automatic transmission lubricating oil composition comprising an oil of lubricating viscosity, an ashless dispersant, an anti-oxidant, a phosphorus-based anti-wear agent and a friction-modifier, wherein more than 310 ppm of phosphorus is contained, thereby being useful for lubricating or operating an automatic transmission comprising a transmission clutch using a slip lock-up torque converter and a paper based clutch material and a planetary gear system, especially six-speed automatic transmission.
Type:
Application
Filed:
November 18, 2008
Publication date:
December 10, 2009
Applicants:
HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATION, INFINEUM KOREA LTD
Inventors:
Sang Yeob Cha, Skip Watts, Hirokazu Saito
Abstract: The invention provides a lubricating composition containing (a) 0.001 wt % to 15 wt % of a polymer with radial or star architecture; (b) an overbased detergent; (c) a dispersant; and (d) an oil of lubricating viscosity. The invention further provides a method for lubricating a mechanical device with the lubricating composition.
Type:
Application
Filed:
April 19, 2007
Publication date:
December 3, 2009
Applicant:
The Lubrizol Corporation
Inventors:
Barton J. Schober, Mark C. Davies, Michael R. Sutton, Marina Baum, Daniel C. Visger, David Price, Brent R. Dohnar, Mark F. Wilkes
Abstract: A gas turbine lubricating composition comprises a first lubricating composition and a delivery system for delivering at least one additive to said first lubricating composition in a controlled, time-release manner, thereby converting said first lubricating composition to a second lubricating composition, different from said first lubricating composition. In one embodiment, the delivery system comprises a controlled release gel. A method of lubricating a gas turbine using such lubricating composition is also disclosed.
Abstract: A composition of a major amount of an oil of lubricating viscosity; a secondary or tertiary amine being represented by the formula R1R2NR3 wherein R1 and R2 are alkyl groups of at least 6 carbon atoms and R3 is hydrogen, a hydrocarbyl group, a hydroxyl-containing alkyl group, or an amine-containing alkyl group; and a dispersant, provides high static coefficients of friction and a durable positive slope during oxidative and mechanical stressing, particularly as a friction component of an automatic transmission.
Type:
Grant
Filed:
April 12, 2006
Date of Patent:
November 17, 2009
Assignee:
The Lubrizol Corporation
Inventors:
Craig D. Tipton, Mark R. Baker, Shreyasi Lahiri, William D. Abraham, Richard J. Vickerman, Suzanne M. Patterson
Abstract: This invention describes novel trunk piston engine lubricating oil compositions for use in trunk piston engines operating on low sulfur marine residual fuels, as well as methods for lubricating trunk piston engines, methods of using the trunk piston lubricating oil compositions, and methods of making thereof.
Abstract: A modified lubricating oil detergent that is the reaction product of an oil soluble detergent comprising an alkali- or alkaline earth metal hydrocarbyl phenate, carboxylate or sulfonate and an ?, ?-unsaturated carbonyl compound; and lubricating oil compositions containing a combination of such a modified detergent and a nitrogen-containing dispersant.
Abstract: The invention provides a lubricating composition containing (a) 0.1 to 15 wt % of a polymer with (i) a weight average molecular weight of 100,000 to 500,000; and (ii) a shear stability index of 10 to 60; (b) a phosphorus-containing acid, salt, or ester; (c) a dispersant; and (d) an oil of lubricating viscosity. The invention further provides a method for lubricating a mechanical device with the lubricating composition.
Type:
Application
Filed:
April 12, 2007
Publication date:
August 20, 2009
Applicant:
The Lubrizol Corporation
Inventors:
Craig D. Tipton, Marina Baum, Barton J. Schober