With Organic Chalcogen Or Halogen Compound Patents (Class 508/295)
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Patent number: 9284506Abstract: A water-in-oil emulsion of light fuel oil, and a process for the stabilization of a water-in-oil emulsion of a light fuel oil are described.Type: GrantFiled: March 16, 2011Date of Patent: March 15, 2016Assignee: ECO ENERGY HOLDING ASInventors: Arne Meland, Luigi Brambilla
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Publication number: 20150148275Abstract: The present invention relates to a lubricating composition containing an oil of lubricating viscosity and a star polymer that has at least two inner blocks, at least one of which is in turn bonded to one or more outer blocks. The invention further relates to methods of lubricating a mechanical device with the lubricating composition.Type: ApplicationFiled: December 16, 2014Publication date: May 28, 2015Inventors: Haihu Qin, Marina Baum, John R. Johnson
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Publication number: 20150038383Abstract: A method for preventing or inhibiting exhaust valve seat recession in a natural gas fueled internal combustion engine is disclosed. The method involves lubricating the engine with a lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity, and (b) a minor amount of a natural gas engine oil additive package, wherein the lubricating oil composition is substantially free of each of any zinc compounds and alkaline earth metal salts of a condensation product of an alkylene polyamine, an aldehyde and a substituted phenol.Type: ApplicationFiled: October 17, 2014Publication date: February 5, 2015Inventors: Melanie F. Tobias, Jon F. Von Staden
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Patent number: 7585821Abstract: A modified lubricating oil detergent that is the reaction product of an oil soluble detergent comprising an alkali- or alkaline earth metal hydrocarbyl phenate, carboxylate or sulfonate and an ?, ?-unsaturated carbonyl compound; and lubricating oil compositions containing a combination of such a modified detergent and a nitrogen-containing dispersant.Type: GrantFiled: August 6, 2002Date of Patent: September 8, 2009Assignee: Infineum International LimitedInventors: Jacob Emert, Antonio Gutierrez
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Patent number: 6855675Abstract: A lubricating oil composition that has excellent antiwear properties and is especially useful for internal combustion engine comprises a lubricating base oil and contains the following components: sulfoxymolybdenum dithiocarbamate, zinc dialkyldithiophosphate and a mixture of 100 to 50% by weight of calcium alkylsalicylate and 0 to 50% by weight of magnesium alkylsalicylate, the amount of molybdenum derived from the sulfoxymolybdenum dithiocarbamate being from 200 to 1000 ppm (weight basis) of the total weight of the composition, the amount of phosphorus derived from the zinc dialkyldithiophosphate being from 0.04 to 15% by weight of the total weight of the composition, and the total amount of the calcium alkylsalicylate and the magnesium alkylsalicylate being from 1 to 10% by weight of the total weight of the composition.Type: GrantFiled: May 24, 1995Date of Patent: February 15, 2005Assignee: TonenGeneral Sekiyu K.K.Inventors: Michiya Yamada, Satoshi Asano, Hirotaka Tomizawa
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Patent number: 6852679Abstract: A lubricating oil composition having less than 0.2 wt. % sulfur, less than 50 ppm chlorine, less than 50 ppm phosphorus, a NOACK volatility of 15 wt. % or less comprising an organo-molybdenum compound, an overbased calcium or magnesium salicylate, a dispersant and a supplemental antioxidant.Type: GrantFiled: February 20, 2002Date of Patent: February 8, 2005Assignee: Infineum International Ltd.Inventors: Rolfe J. Hartley, Malcolm Waddoups, Ricardo A. Bloch, Roger W. Glyde, Robert Robson
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Patent number: 6716801Abstract: A stable, clear water-in-oil emulsion consisting of from about 5 to about 40 wt % aqueous phase and from about 95 to about 60 wt % non-aqueous phase, said aqueous phase being dispersed in said non-aqueous phase in the form of droplets having an average droplet size no greater than about 0.1 &mgr;m, said emulsion comprising at least 60 wt % of an oil selected from fuel oils, lubricating oils and mixtures thereof, from about 5 to about 30 wt % of an emulsifier composition, and the balance to 100 wt % water, wherein said emulsifier composition consists essentially of i) a mixture of C6-C15 alcohol ethoxylates, each comprising from 2 to 12 EO groups, ii) from 0 to about 25 wt % of an emulsifier selected from polyisobutylsuccinimide, a sorbitan ester and mixtures thereof, and iii) from 0 to about 90 wt % of an amine ethoxylate. The microemulsion is useful as a fuel and/or lubricant/coolant.Type: GrantFiled: December 23, 2002Date of Patent: April 6, 2004Inventor: David William Martin
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Publication number: 20040029747Abstract: A modified lubricating oil detergent that is the reaction product of an oil soluble detergent comprising an alkali- or alkaline earth metal hydrocarbyl phenate, carboxylate or sulfonate and an &agr;, &bgr;-unsaturated carbonyl compound; and lubricating oil compositions containing a combination of such a modified detergent and a nitrogen-containing dispersant.Type: ApplicationFiled: August 6, 2002Publication date: February 12, 2004Inventors: Jacob Emert, Antonio Gutierrez
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Patent number: 6677281Abstract: A lubricant having improved rust protection and demulsibility has a specific balance of an ashless dispersant and a rust inhibitor additive combination comprising a metallic and ashless rust inhibitor.Type: GrantFiled: March 22, 2002Date of Patent: January 13, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Willie Allan Givens, Jr., Angela Stefana Galiano-Roth
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Publication number: 20030224948Abstract: An additive formulation comprising one or more ec-treated dispersants, borated dispersants, and a dispersed aromatic dicarboxylic acid corrosion inhibitor; a dispersant inhibitor package comprising one or more ec-treated dispersants, borated dispersants, and a dispersed aromatic dicarboxylic acid corrosion inhibitor; a lubricating oil comprising said dispersant inhibitor package; and a method for lubricating engines.Type: ApplicationFiled: February 14, 2003Publication date: December 4, 2003Inventors: Willem Van Dam, Michael T. Menasco, James J. Harrison, Mark R. Logan
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Publication number: 20030191031Abstract: A combination of an ashless dispersant comprising the reaction product of a succinic anhydride and a polyamine and an ashless rust inhibitor comprising a mixture of a succinic anhydride and a oxime substituted aromatic compound in a lubricant base stock along with a poly alkylene alcohol demulsifier provides a circulating oil composition having good demulsibility, deposit control and rust inhibition.Type: ApplicationFiled: January 28, 2003Publication date: October 9, 2003Inventors: Kevin Buzdygon, Angela Stefana Galiano-Roth
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Publication number: 20030176297Abstract: A lubricating oil composition having less than 0.2 wt. % sulfur, less than 50 ppm chlorine, less than 50 ppm phosphorus, a NOACK volatility of 15 wt. % or less comprising an organo-molybdenum compound, an overbased calcium or magnesium salicylate, a dispersant and a supplemental antioxidant.Type: ApplicationFiled: February 20, 2002Publication date: September 18, 2003Inventors: Rolfe J. Hartley, Malcolm Waddoups, Ricardo A. Bloch, Roger W. Glyde, Robert Robson
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Publication number: 20030134755Abstract: A stable, clear water-in-oil emulsion consisting of from about 5 to about 40 wt % aqueous phase and from about 95 to about 60 wt % non-aqueous phase, said aqueous phase being dispersed in said non-aqueous phase in the form of droplets having an average droplet size no greater than about 0.1 &mgr;m, said emulsion comprising at least 60 wt % of an oil selected from fuel oils, lubricating oils and mixtures thereof, from about 5 to about 30 wt % of an emulsifier composition, and the balance to 100 wt % water, wherein said emulsifier composition consists essentially of i) a mixture of C6-C15 alcohol ethoxylates, each comprising from 2 to 12 EO groups, ii) from 0 to about 25 wt % of an emulsifier selected from polyisobutylsuccinimide, a sorbitan ester and mixtures thereof, and iii) from 0 to about 90 wt % of an amine ethoxylate. The microemulsion is useful as a fuel and/or lubricant/coolant.Type: ApplicationFiled: December 23, 2002Publication date: July 17, 2003Inventor: David William Martin
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Publication number: 20030125218Abstract: A biodegradable lubricating oil composition especially useful as a gear oil employs a synthetic alcohol ester basestock formed from mono- and dipentaerythritol with certain mono- and dicarboxylic acids or dicarboxylic acid anhydrides and an effective amount of a polyoxyalkylene alcohol demulsifying agent, a combination of alkylated organic acid and ashless succinimide rust inhibitors and an ashless dithiocarbamate antiwear and extreme pressure agent.Type: ApplicationFiled: October 8, 2002Publication date: July 3, 2003Inventors: Angeline Baird Cardis, Susan Ardito
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Patent number: 6562765Abstract: An engine oil having a base oil and a friction reducing amount of an oil soluble sulfurized or unsulfurized oxymolybdenum complex prepared from reacting, in the presence of a polar promoter, an acidic molybdenum compound and a basic nitrogen compound and a low concentration of a sulfurized oxymolybdenum dialkyldithiocarbamate; employed together to provide at least 450 parts per million of molybdenum and less than 175 parts per million of molybdenum from the dialkyldithiocarbamate, both on the basis of the engine oil.Type: GrantFiled: July 11, 2002Date of Patent: May 13, 2003Assignee: Chevron Oronite Company LLCInventor: Alexander B. Boffa
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Publication number: 20030073590Abstract: Lubricating oil compositions for residual fuel oil-fuelled diesel engines for marine and stationary applications comprising, or made by admixing:Type: ApplicationFiled: September 10, 2002Publication date: April 17, 2003Inventors: Laurent Chambard, Keith Strickland
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Patent number: 6528459Abstract: The invention concerns a lubricant for a two-stroke slow speed crosshead marine engine, powered with a fuel with sulfur content not less than 1%, consisting of a mixture of distillates used as lubricating bases containing x wt. % of dispersing additive of the succinimide type, y wt. % of an overbased detergent additive of the sulfonate type, and z wt. % of an overbased detergent additive of the phenate type. The invention is characterized in that x, y and z are selected in the intervals 0.5≦x≦2.5, 2.5≦y≦10 and 11≦z≦24.5 such that 15≦x+y+z≦36 and 1.5≦y/x≦13, the BN of the lubricant, determined according to the ASTM D-2896 standard, is not less than 70 mg KOH/g, and the speed at which sulfuric acid is neutralized by the lubricant, defined by the maximum speed of pressure increase of a closed chamber, with its walls covered with a film of said lubricant from 80 to 100 &mgr;m thick, maintained at 100° C.Type: GrantFiled: September 18, 2000Date of Patent: March 4, 2003Assignee: Elf Antar FranceInventor: Jean-Philippe Roman
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Publication number: 20030027726Abstract: A lubricant having improved rust protection and demulsibility has a specific balance of an ashless dispersant and a rust inhibitor additive combination comprising a metallic and ashless rust inhibitor.Type: ApplicationFiled: March 22, 2002Publication date: February 6, 2003Inventors: Willie Allan Givens, Angela Stefana Galiano-Roth
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Publication number: 20020098991Abstract: A gas-fuelled engine lubricating oil composition having a TBN in the range of 2 to 20 and comprising:Type: ApplicationFiled: October 4, 2001Publication date: July 25, 2002Inventors: Adrian Dunn, Laurent Chambard, Terence Garner
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Patent number: 6268316Abstract: In diesel engines, soot is produced by combustion and enters into the engine oil, preventing the engine lubricant from fully exercising its lubricity. The present invention provides a lubricating composition comprising a lubricating basestock, an organic molybdenum compound (A) and succinimide (B) having 0.01 or less of an IR spectrum absorbance peak intensity ratio &agr;/&bgr;, wherein &agr; represents an absorbance peak intensity at 1,550±10 cm−1 and &bgr; represents an absorbance peak intensity at 1,700±10 cm−1. Preferably, the organic molybdenum compound is the compound represented by the following formula (1) or formula (2): (wherein R1 to R8 each independently represent a hydrocarbon, and X1 to X8 each independently represent a sulfur atom or an oxygen atom), or a reaction product of an amine and a molybdenum compound having at least one pentavalent or hexavalent molybdenum atom.Type: GrantFiled: March 24, 2000Date of Patent: July 31, 2001Assignee: Asahi Denka Kogyo K.K.Inventors: Noriyoshi Tanaka, Aritoshi Fukushima, Kazuhisa Morita, Yoko Saito, Atsuo Miyashita
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Patent number: 6127321Abstract: Hydrocarbyl substituted C.sub.4 to C.sub.10 monounsaturated dicarboxylic acid, anhydrides or esters, e.g. polyisobutenyl succinic anhydride, preferably made by reacting polymer of C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a molecular weight of about 1500 to 5,000, preferably with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 1.05 to 1.25 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting materials are useful per se as oil additives, or may be further reacted with amines, alcohols, amino alcohols, boric acid, etc. to form dispersants.Type: GrantFiled: September 5, 1991Date of Patent: October 3, 2000Assignee: Exxon Chemical Patents IncInventors: Jacob Emert, Robert D. Lundberg, Malcolm Waddoups
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Patent number: 6066601Abstract: A coating additive composition containing the combination of a) at least one non-crosslinked product made by the reaction of an amine and a carboxylic acid, the product containing at least two hydrocarbyl groups each having about 12 to about 100 carbon atoms; and (ii) at least one fluoropolymer. The additive composition is useful as a nonflatting slip-enhancing agent in both in solvent-based and powder coatings. The cured coatings exhibit lower coefficient of friction and substantial gloss retention.Type: GrantFiled: October 6, 1998Date of Patent: May 23, 2000Assignee: The Lubrizol CorporationInventor: Thomas F. Steckel
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Patent number: 6043199Abstract: Turbine oils of improved corrosion resistance comprise a synthetic ester base stock and additives comprising a combination of a dibasic carboxylic acid and a second component selected from alkyl or alkenyl succinic acid/anhydride ester or hemi-linear or branched ester and hydroxylated derivatives of such esters or hemi esters, and linear or branched alkyl or alkenyl substituted succinimide or amino substituted succinimide.Type: GrantFiled: November 13, 1998Date of Patent: March 28, 2000Assignee: Exxon Research and Engineering Co.Inventor: Patrick Edward Godici
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Patent number: 5958848Abstract: Multigrade crankcase lubricants having low concentrations of chlorine and sulphated ash use multifunctional viscosity modifiers in place of conventional chlorine-containing dispersants. The lubricant contains at least 1.5 weight percent of a chlorine-containing dispersant that is a reaction product of a polyisobutenyl succinic anhydride and an organic amine, a multifunctional viscosity modifier and a detergent system that comprises a metal sulfonateand one or more metal salts of a phenolic organic acid selected from the group consisting of alkyl phenols, sulfurized alkyl phenols, and alkyl salicylic acids in an amount that provides at least 0.0025 gram equivalents of phenolic hydroxide. At least one of the metal salts is overbased and the detergent system includes not more than 0.008 gram equivalent % carbonate. The gram equivalent ratio of the total amount of phenolic hydroxide to the metal sulfonate is at least 1.Type: GrantFiled: March 25, 1998Date of Patent: September 28, 1999Assignee: Exxon Chemical Patents, Inc.Inventor: Robert Robson
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Patent number: 5866519Abstract: This invention provides a composition and method for producing partial synthetic automatic transmission fluids having improved shear-stability and low temperature properties without the need to incorporate polymeric viscosity modifiers.Type: GrantFiled: July 7, 1997Date of Patent: February 2, 1999Assignee: Exxon Chemical Patents Inc.Inventors: Raymond Frederick Watts, Ricardo Alfredo Bloch
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Patent number: 5789355Abstract: This invention relates to low volatility 5W20, 5W30, 10W40, 10W50, 15W40 or 15W50 multigrade oils for crankcase lubrication of gasoline and diesel engines, the oils comprising:a) basestock having an average basestock neutral number of not less than 105 for a 5W multigrade, not less than 145 for a 10W multigrade and not less than 200 for a 15W multigrade,b) a detergent inhibitor package including an ashless dispersant comprising an oil soluble polymeric hydrocarbon backbone having functional groups in which the hydrocarbon backbone is derived from an ethylene alpha-olefin (EAO) copolymer or alpha-olefin homo- or copolymer having an M.sub.n of from 500 to 7000, and preferably having >30% of terminal vinylidene unsaturation, andc) a viscosity modifier.These multigrade crankcase oils provide better volatility with reduced use or even without the need for expensive light neutral basestocks or non-conventional lubricant basestocks, while at the same time providing adequate control of sludge and varnish.Type: GrantFiled: December 20, 1996Date of Patent: August 4, 1998Assignee: Exxon Chemical LimitedInventors: David Robert Adams, Paul Brice
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Patent number: 5756429Abstract: A lubricating oil composition for a high-speed gear particularly having a peripheral speed of 10 m/sec or more is herein disclosed which is obtained by blending a base oil having a % C.sub.A of 5 or less and preferably further having a nitrogen content of 50 ppm or less and a sulfur content of 50 ppm or less with a sulfur additive, a phosphorus additive and a nitrogen additive so that an element ratio 100N/(S+P) in the composition may be in the range of 4 to 10 by weight, and the lubricating oil composition has a sufficient hypoid gear performance, can inhibit the formation of a sludge, and permits the prolongation of the life of an oil seal for use in a high-speed and/or a high-temperature rotating portion.Type: GrantFiled: March 28, 1996Date of Patent: May 26, 1998Assignee: Idemitsu Kosan Co., Ltd.Inventor: Toshihiko Ichihashi
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Patent number: 5744430Abstract: There is provided a composition having therein a base oil with a specified kinematic viscosity and with a specified total amount of aromatics, comprising, in specified amounts based on the total weight of the composition:(b) an alkaline earth metal salicylate detergent;(c) a zinc dialkyldithiophosphate;(d) a succinimide ashless dispersant containing a polybutenyl group having a specified number-average molecular weight;(e) a phenol ashless antioxidant;(f) a molybdenum dithiocarbamate friction modifier; and(g) a viscosity index improver in such an amount that the kinematic viscosity of said composition ranges from 5.6 to 12.5 mm.sup.2 /s at 100.degree. C. The present invention provides an engine oil which has excellent fuel consumption and maintains the fuel consumption for a long period of time.Type: GrantFiled: April 25, 1996Date of Patent: April 28, 1998Assignee: Nippon Oil Co., Ltd.Inventors: Kiyoshi Inoue, Yasuhisa Yamada, Akira Yaguchi, Masakuni Hirata
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Patent number: 5646099Abstract: This invention provides a composition and method for producing partial synthetic automatic transmission fluids having improved shear-stability and low temperature properties without the need to incorporate polymeric viscosity modifiers.Type: GrantFiled: July 17, 1995Date of Patent: July 8, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Raymond Frederick Watts, Ricardo Alfredo Bloch
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Patent number: 5641732Abstract: This invention provides compositions and methods for producing partial synthetic automatic transmission fluids capable of improved viscometric properties and capable of achieving -40.degree. C. Brookfield viscosities not greater than 15,000 centipoise.Type: GrantFiled: July 17, 1995Date of Patent: June 24, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Ricardo Altredo Bloch, Christopher William Cornish, Raymond Frederick Watts
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Patent number: 5641733Abstract: This invention provides compositions and methods for producing partial synthetic automatic transmission fluids capable of improved viscometric properties and capable of achieving -40.degree. C. Brookfield viscosities not greater than 15,000 centipoise.Type: GrantFiled: September 1, 1995Date of Patent: June 24, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Ricardo Alfredo Bloch, Christopher William Cornish, Raymond Frederick Watts
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Patent number: 5614480Abstract: A lubricating oil composition is described which comprises a major amount of an oil of lubricating viscosity and(A) at least about 1% by weight of at least one carboxylic derivative composition produced by reacting(A-1) at least one substituted succinic acylating agent containing at least about 50 carbon atoms in the substituent with(A-2) from about 0.5 equivalent up to about 2 moles, per equivalent of acylating agent (A-1), of at least one amine compound characterized by the presence within its structure of at least one HN<group; and(B) at least one alkali metal overbased salt of a hydrocarbyl-substituted carboxylic acid or a mixture of a hydrocarbyl carboxylic acid and a hydrocarbyl-substituted sulfonic acid having a metal ratio of greater than 2 in an amount sufficient to provide at least about 0.Type: GrantFiled: July 25, 1994Date of Patent: March 25, 1997Assignee: The Lubrizol CorporationInventors: Mary F. Salomon, Kirk E. Davis, Jack L. Karn, John Cahoon