Benzene Ring Bonded Directly To The Nitrogen Patents (Class 508/563)
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Publication number: 20110195886Abstract: The use of an additive including a mixture of oligomers that is produced from the reaction of aromatic amines chosen from: (i) the reaction with one another of diphenylamine (DPA) compounds of formula (I) below: wherein the groups R1 and R2 stand for, independently of one another, a hydrogen or a linear or branched alkyl group having from 1 to 30 carbon atoms, advantageously from 4 to 12 carbon atoms, (ii) the reaction with one another of phenyl-?-naphthylamine (PAN) compounds of formula (II) below: wherein the group R3 stands for a hydrogen or a linear or branched alkyl group having from 1 to 30 carbon atoms, advantageously from 4 to 12 carbon atoms, and (iii) the reaction of a (DPA) compound of formula (I) above with a (PAN) compound of formula (II) above as an agent for the stabilization of a lubricating composition for a conveyor chain subjected to a temperature of at least 120° C.Type: ApplicationFiled: October 7, 2009Publication date: August 11, 2011Applicant: NYCO S.A.Inventors: Gerard Goujon, Florence Severac, Marc BoreL-Garin
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Patent number: 7964542Abstract: Liquid compositions containing a specific hindered phenol or a hindered phenol in combination with an aromatic phosphite are provided which are used as a thermal interface between a heatsink and a chip during a test procedure for electronic components which compositions enhance the thermal conductivity between the heatsink and the chip, are easily removed from the heatsink and the chip after the test procedure without any deleterious residue and which allow the use of high temperatures for extended periods during the test procedure without any significant degradation of the composition. A method for using the compositions in electronic component test procedures such as burn-in procedures is also provided.Type: GrantFiled: January 12, 2006Date of Patent: June 21, 2011Assignee: International Business Machines CorporationInventors: Krishna G. Sachdev, Harbans Singh Sachdev, legal representative, Mark S. Chace, Normand Cote, David L. Gardell, Jeffrey D. Gelorme, Sushumna Iruvanti, G. John Lawson, Tuknekah M. Noble
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Publication number: 20110124538Abstract: Process technology is described for producing a reaction-derived product mixture containing a high yield of octylated phenyl-alpha-naphthylamine by catalytic alkylation of phenyl-alpha-naphthylamine with diisobutylene. New reaction-derived product mixtures are produced. Also provided are novel reaction-derived octylated phenyl-alpha-naphthylamine reaction product mixtures from which catalyst residues and excess olefin components have been removed. These reaction product mixtures are effective as antioxidants for various oxygen-sensitive substrate materials such as oils and lubricants. Also described are new octylated phenyl-alpha-naphthylamine product mixtures and their use in forming clear, stable, liquid antioxidant compositions for addition to a wide variety of substrates.Type: ApplicationFiled: July 21, 2009Publication date: May 26, 2011Applicant: ALBEMARLE CORPORATIONInventors: Steven G. Karseboom, Hassan Y. Elnagar, Vincent J. Gatto, William E. Moehle
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Publication number: 20110111997Abstract: A turbo-charged, sump-lubricated internal combustion engine which is susceptible to contamination of lubricant with liquid fuel, is lubricated with a lubricant which contains an amount of an aminic antioxidant, optionally in the absence of a phenolic antioxidant, thereby reducing the deterioration of said lubricant and formation of turbo sludge.Type: ApplicationFiled: May 7, 2009Publication date: May 12, 2011Applicant: THE LUBRIZOL CORPORTATIONInventors: Stephen J. Cook, Jolanta Z. Adamczewska
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Patent number: 7928045Abstract: A lubricant composition is disclosed that comprises lubricating oil and a mixture of at least two antioxidants, the first antioxidant being a substituted diphenylamine and/or a heterocyclic amine and the second antioxidant being a substituted phenol. Also disclosed is a method of increasing the oxidation stability of a lubricating oil comprising adding thereto at least two antioxidants, the first antioxidant being a substituted diphenylamine and/or a heterocyclic amine and the second antioxidant being a substituted phenol.Type: GrantFiled: February 21, 2007Date of Patent: April 19, 2011Assignee: Chemtura CorporationInventors: Jun Dong, Gerard Mulqueen, Michael J. Goode, Alan Holt, William D. Phillips
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Patent number: 7928265Abstract: Method of preparation of antioxidant composition on the basis of diphenylamine by catalytic alkylation of diphenylamine by an threefold excess of diisobutylene with regard to diphenylamine in the presence of an alkylation catalyst t in an amount of 5 to 30% by weight, as referred to diphenylamine, at a temperature of 140 to 160° C. Water contained in the catalyst, is removed and subsequently diphenylamine is left to complete the reaction with diisobutylene and after the reaction is finished, the reaction mixture is separated from the catalyst, unreacted diisobutylene is removed from it and the reaction product is obtained.Type: GrantFiled: May 5, 2006Date of Patent: April 19, 2011Assignee: Duslo A.S.Inventors: Viera Andruskova, Jan Uhlar, Peter Lehocky, Jaroslav Horak
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Publication number: 20110059879Abstract: A lubricating grease composition is disclosed. In one embodiment, the lubricating grease comprises at least one Group I oil, at least one Group II oil, a hydrophilic copolymer, and a soap thickener. The thickener is dispersed into at least one Group I oil during a cooking phase and the at least one Group II oil is introduced during a finishing phase. A method for making a lubricating grease is also disclosed. The method comprises obtaining at least one Group I oil, obtaining at least one Group II oil, obtaining a hydrophilic copolymer, obtaining a soap thickener, and mixing the at least one Group I oil, the least one Group II oil, the polymer and the soap thickener to form a grease wherein the thickener is dispersed into the at least one Group I oil during a cooking phase and at least one Group II oil is introduced during a finishing phase.Type: ApplicationFiled: December 4, 2009Publication date: March 10, 2011Inventors: Carol A. Barnes, Kamilah N. Smith, Alan G. Blahey, Douglas C. MacLaren
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Patent number: 7902131Abstract: Molybdenum-free lubricating compositions are provided, having an antioxidation additive composition based on a combination of (1) alkylated diphenylamine (APDA), (2) polyamine dispersant, and (3) monoglyceride, ethoxylated amide, or mixtures thereof. Further synergy is achieved when component (3) is borated, allowing a reduction in phosphorus levels to below 0.08% or even a phosphorus-free composition.Type: GrantFiled: April 26, 2007Date of Patent: March 8, 2011Assignee: R.T. Vanderbilt Company, Inc.Inventors: Gaston A. Aguilar, Brian Stunkel, Steven G. Donnelly
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Publication number: 20110030269Abstract: A lubricant composition is suitable for use in diesel engines and is resistant to degradation by oxidative by-products of biodiesel fuel. The composition includes (A) a base oil, (B) at least one diphenylamine antioxidant, and (C) at least one antioxidant. The antioxidant (C) is selected from the group consisting of a sulfur containing phenolic antioxidant, a phenyl-alpha-naphthylamine antioxidant, and combinations thereof. The lubricant composition is formed using a method. In the method, the (A) base oil has an initial oxidation value measured according to ASTM D 6186. In addition in the method, the lubricant composition includes up to about 6 wt % of the biodiesel fuel and has a final oxidation value measured according to ASTM D 6186 that is equal to or greater than the initial oxidation value of the (A) base oil.Type: ApplicationFiled: August 5, 2010Publication date: February 10, 2011Inventors: David Eliezer Chasan, Paul Fasano, Margaret Frances Egiziaco, Vineet Bajpai
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Patent number: 7847125Abstract: A compound having the formula: R1 and R2 together with the carbon atoms to which they are bonded are joined together to form a C3-C30 ring. The C3-C30 ring may be substituted with one or more substituents or unsubstituted. The C3-C30 ring may contain one or more heteroatoms. The C3-C30 ring may be saturated, partially unsaturated, or fully unsaturated.Type: GrantFiled: November 16, 2007Date of Patent: December 7, 2010Assignee: Chemtura CorporationInventors: Qinggao Ma, Cyril Migdal
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Patent number: 7847030Abstract: Provided is a process for making a diphenylamine-functionalized poly-?-olefin. The process has the following step: reacting an amount of a poly-?-olefin having a terminal double bond with a diphenylamine in the presence of a catalyst. The poly-?-olefin has a terminal double bond having a number average molecular weight of 120 to 600. The ratio of poly-?-olefin to diphenylamine is 1.0:1.0 to 10.0:1.0. Provided is also a diphenylamine-functionalized poly-?-olefin product.Type: GrantFiled: February 29, 2008Date of Patent: December 7, 2010Assignee: ExxonMobil Research and Engineering CompanyInventor: Abhimanyu O. Patil
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Patent number: 7838475Abstract: A composition is disclosed which comprises an aryl perfluoropolyether, optionally a halogenated oil, and further optionally a thickening agent. The composition can be used as a lubricant itself or as an additive to an oil or grease lubricant and can withstand temperatures higher than 300° C. without decomposition. The halogenated oil can be a perfluoropolyether, a fluorosilicone, a polytrifluorochloroethylene, or combinations of two or more thereof. The thickening agent can be finely divided silica, boron nitride, clay, soap, poly(tetrafluoroethylene), clay, talc, silica, titanium dioxide, polydimethylsiloxane, polyurea, polyurethane, or combinations of two or more thereof.Type: GrantFiled: September 1, 2005Date of Patent: November 23, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: Jon Lee Howell, Alice Elizabeth Van Der Ende, Erik William Perez, Krista Lynn Laugesen
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Patent number: 7838703Abstract: A diaromatic amine compound having the general formula: wherein R1 and R2 together with the carbon atoms to which they are bonded are joined together to form a C3-C30 ring, and R3 is an allyl, benzyl, or methallyl group. R4, R5, and R6 are independently hydrogen, C1-C30 alkyl group, C2-C30 alkenyl group, C3-C12 cycloalkyl group, C5-C25 aryl group, C6-C25 arylalkyl group, or C1-C30 alkoxy group.Type: GrantFiled: November 16, 2007Date of Patent: November 23, 2010Assignee: Chemtura CorporationInventors: Qinggao Ma, Cyril Migdal
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Patent number: 7838473Abstract: A lubricating oil composition of TBN 8-9 having up to 0.3 wt. % sulfur, up to 0.08 wt. % phosphorus, and a sulfated ash content up to 0.80 wt. %, comprising an overbased magnesium-containing lubricating oil detergent, and 2.5 to 4 wt. % of a nitrogen-containing ashless dispersant.Type: GrantFiled: September 14, 2005Date of Patent: November 23, 2010Assignee: Infineum International LimitedInventors: Robert W. Shaw, Michele Anne Thornhill
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Patent number: 7829511Abstract: A stabilized lubricant composition is disclosed that comprises lubricating oil and a mixture of (a) at least one organophosphite compound and (b) at least one aromatic secondary amine or one substituted phenol or mixtures thereof. The compositions have been found to be highly resistant to oxidation under demanding service conditions and to be useful as turbine lubricants.Type: GrantFiled: May 12, 2005Date of Patent: November 9, 2010Assignee: Chemtura CorporationInventors: Jun Dong, Cyril A. Migdal
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Patent number: 7825077Abstract: This invention provides a composition of lubricating oil for two stroke gasoline engine and a process for the preparation thereof. In addition to alkyl benzenes, the composition also contains an antioxidant, an antifoaming agent, a pour point dispersant, a corrosion inhibitor and a detergent-dispersant additive, an extreme pressure additive, a lubrication additives, comprising of the following steps (I) removing of insoluble matter from the base stock, (II) tailoring by vacuum distillation, (III) blending of different alkylates, (IV) removing the oxidized matters by adsorption, (V) addition of performance additives and homogenizing the mixture. The product of this invention has utility as lubricating oil for two stroke gasoline engine in both water-cooled and air-cooled two-cycle gasoline engines producing reduced smoke.Type: GrantFiled: March 13, 2006Date of Patent: November 2, 2010Assignee: Council of Scientific and Industrial ResearchInventors: Arun Kumar Singh, Naval Kishore Pandey, Ashok Kumar Gupta
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Publication number: 20100269774Abstract: The present invention provides a lubricating composition for use in diesel engines compatible with biofuel, the lubricating composition comprising a base oil belonging to Group III and/or Group II of the API base oil categories, from 0.5 to 5% by mass of a phenolic anti-oxidant and from 0.5 to 5% by mass of an amine-based anti-oxidant, the total content of the anti-oxidants being at least 2% by mass.Type: ApplicationFiled: July 21, 2008Publication date: October 28, 2010Inventors: Noriaki Shinoda, Eiji Nagatomi
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Patent number: 7820602Abstract: This invention relates to lubricating oil additives, and to lubricating oil compositions, their method of preparation, and use. More specifically, this invention relates to several novel lubricating oil additives and compositions which contain a tungsten compound and an antioxidant, namely aminic antioxidants such as a secondary diarylamine or an alkylated phenothiazine. The use of the tungsten compound with the secondary diarylamine and/or the alkylated phenothiazine provides improved oxidation and deposit control to lubricating oil compositions. The lubricating oil compositions of this invention are particularly useful as crankcase and transmission lubricants, gear oils and other high performance lubricant applications.Type: GrantFiled: July 12, 2006Date of Patent: October 26, 2010Assignee: King Industries, Inc.Inventors: Ramanathan Ravichandran, Farouk Abi-Karam, Alena Yermolenka, Michel Hourani, Ingo Roehrs
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Patent number: 7816308Abstract: Disclosed herein is a composition comprising: A) a lubricant; and B) a mixture of antioxidants, wherein said mixture is prepared by the partial condensation of an alkylated diphenylamine with an aldehyde or ketone in the presence of an acidic catalyst to yield at least one acridan of the general formula: wherein: R1, R2, R3, and R4 are independently selected from the group consisting of hydrogen, C3 to C32 alkyl, and C3 to C32 alkenyl, provided that at least one of R1, R2, R3, and R4 is not hydrogen, and R5 and R6 are independently selected from the group consisting of C1 to C20 hydrocarbyl and hydrogen; wherein, at the termination of said condensation, residual alkylated diphenylamine is not separated from the acridan product.Type: GrantFiled: April 14, 2004Date of Patent: October 19, 2010Assignee: Crompton CorporationInventors: Karl J. Duyck, Theodore E. Nalesnik, John R. Baranski, Cyril A. Migdal, Rebecca F. Seibert
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Patent number: 7795192Abstract: A lubricant composition suitable for lubricating a direct fuel injection two-stroke engine comprises at least one condensation product of a fatty acid with an amine or ammonia and of at least one Mannich dispersant, each in an amount of 0.5 to 8 percent by weight, along with an oil of lubricating viscosity.Type: GrantFiled: April 17, 2003Date of Patent: September 14, 2010Assignee: The Lubrizol CorporationInventors: Laimute R. Svarcas, William K. S. Cleveland, John L. Petric
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Patent number: 7790660Abstract: A polyalkylene glycol based lubricant composition that contains specified rust inhibitors and antioxidants has lowered operating temperature and is particularly suitable for use in worm drive gearboxes. The rust inhibitors consist of an N-acylo arcosine and an imidizole while the antioxidant consists of an alkylated diphenyl amine and a hindered phenol.Type: GrantFiled: January 28, 2005Date of Patent: September 7, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: James Thomas Carey, David K. Prendergast, Kevin J. Buzdygon
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Publication number: 20100205980Abstract: A PAG lubricant basefluid for use with a fluoroalkene refrigerant, the basefluid containing a PAG having the formula: RX(RaO)x(RbO)yRc, where R is selected from alkyl groups having from 1-10 carbon atoms, acyl groups having from 1-10 carbon atoms, aliphatic hydrocarbon groups having from 2-6 valencies, and substituents containing a heterocyclic ring in which the heteroatom(s) are oxygen; X is O or S; Ra is a C2 alkylene group; Rb is a C3 alkylene group; Rc is the same as R or is an H; x and y are each independently 0 or an integer?100; and the sum of x+y is an integer in the range of from about 5-100. Refrigeration and lubricant compositions containing the PAG lubricant basefluid and a method of operating a motor-integrated compressor of a refrigeration or air conditioning system with substantially no electrical leakage current are also provided.Type: ApplicationFiled: December 14, 2009Publication date: August 19, 2010Applicant: SHRIEVE CHEMICAL PRODUCTS, INC.Inventors: Elizabeth Dixon, Phil Beckler
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Publication number: 20100173809Abstract: A finished lubricant having a kinematic viscosity at 40° C. between about 90 and 1700 cSt that passes the 4 hour TORT B rust test, comprising: a) greater than 65 weight percent API Group III base oil, API Group IV base oil, polyinternal olefin base oil, or mixtures thereof; and b) between about 0.10 wt % and about 5 wt % solubility improver. The solubility improver has an aniline point less than 50° C., or even lower. The finished lubricant can additionally comprise a mixture of amine phosphates.Type: ApplicationFiled: December 30, 2009Publication date: July 8, 2010Inventor: Mark E. Okazaki
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Publication number: 20100173811Abstract: Para-alkylated substituted diphenylamines are made by catalytically alkylating diphenylamine with a branched-chain alkene, such as propene, oligomer mixture in which the oligomer present in the greatest percentage has 15-24 carbon atoms. The alkylated diphenylamines are useful crankcase lubricant additives such as for reducing piston deposits and engine sludge.Type: ApplicationFiled: June 6, 2008Publication date: July 8, 2010Inventors: Stephen Arrowsmith, Christopher J. Booth, Aubrey L. Burrows, Paul Wilson, Neal J. Milne, Lin Wangkan, Jacob Emert, Laurent Chambard
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Publication number: 20100130396Abstract: The invention relates to antioxidant compositions for lubricants and organic polymers comprising a first antioxidant comprising a reaction product of p-cresol, dicyclopentadiene and isobutylene; and a second antioxidant comprising a diarylamine. The first antioxidant preferably has the structure: wherein n is 0-50, and R1 and R2 are independently hydrogen, a straight or branched C1-C30 alkyl or alkylene group optionally substituted with one or more substituents, C3-C12 cycloalkyl, C5-C12 aryl, or C6-C12 alkylaryl. The second antioxidant preferably has the formula: (R3)a—Ar1—NH—Ar2—(R4)b wherein Ar1 and Ar2 are independently aromatic hydrocarbon groups and R3 and R4 are independently hydrogen or hydrocarbyl groups having from 6 to about 100 carbon atoms and a and b are independently 0 to 3 but (a+b) is not greater than 4.Type: ApplicationFiled: November 24, 2008Publication date: May 27, 2010Applicant: CHEMTURA CORPORATIONInventor: Jun Dong
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Patent number: 7704931Abstract: A lubricant composition is disclosed that comprises lubricating oil and a mixture of at least two antioxidants, the first antioxidant being a secondary diarylamine and the second antioxidant being a substituted para-phenylenediamine. Also disclosed is a method of increasing the oxidation stability of a lubricating oil comprising adding thereto at least two antioxidants, the first antioxidant being a secondary diarylamine and the second antioxidant being a substituted para-phenylenediamine.Type: GrantFiled: June 3, 2005Date of Patent: April 27, 2010Assignee: Chemtura CorporationInventors: Jun Dong, Cyril A. Migdal
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Publication number: 20100093568Abstract: The present invention provides a refrigerating machine oil, a compressor oil composition, a hydraulic oil composition, a metalworking oil composition, a heat treating oil composition, a lubricating oil composition for machine tools and a lubricating oil composition which comprise a lubricating oil base oil having % CA of not more than 2, % CP/% CN of not less than 6 and an iodine value of not more than 2.5.Type: ApplicationFiled: July 3, 2007Publication date: April 15, 2010Inventors: Kazuo Tagawa, Yuji Shimomura, Ken Sawada, Katsuya Takigawa, Toshio Yoshida, Shinichi Mitsimoto, Eiji Akiyama, Junichi Shibata, Satoshi Suda, Hideo Yokota, Masahiro Hata, Hiroyuki Hoshino, Hajime Nakao, Shozaburo Konishi
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Publication number: 20100081591Abstract: A lubricating oil composition comprising (a) a major amount of an oil of lubricating viscosity, (b) an ashless dispersant, (c) at least one metal-containing detergent, (d) an antioxidant, and (e) an anti-wear agent, wherein the lubricating oil composition is free of any zinc dialkyl dithiophosphate compound and is substantially free of any phosphorus content is disclosed.Type: ApplicationFiled: September 30, 2008Publication date: April 1, 2010Applicant: Chevron Oronite Company LLCInventors: Elaine S. Yamaguchi, Kam-Sik Ng
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Patent number: 7683017Abstract: Disclosed is a lubricating oil composition containing an oil of lubricating viscosity and a particularly effective mixture of a nitro-substituted diphenylamine and a diarylamine which together provide superior oxidation inhibition.Type: GrantFiled: June 20, 2007Date of Patent: March 23, 2010Assignee: Chevron Oronite Company LLCInventors: Richard E. Cherpeck, Carrie Y. Chan
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Publication number: 20100016196Abstract: A substituted phosphite suitable for lubricating base stocks and thermoplastic polymers represented by the structure: wherein R1 is selected from the group consisting of C1-C22 alkyl and C4-C22 cycloalkyl; R2 and R3 are selected to form a C5-C18 aryl; and R4 and R5 are selected from the group consisting of H, C1-C22 alkyl, C2-C22 alkenyl, C4-C22 cycloalkyl, and C5-C8 aryl. The substituted phosphite may be combined with at least one primary antioxidant as well as other additives.Type: ApplicationFiled: June 27, 2008Publication date: January 21, 2010Inventors: Michael E. Gelbin, Jun Dong
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Publication number: 20100009875Abstract: A lubricating oil composition comprising: (A) a base stock; and (B) a liquid additive package. The liquid additive package comprises: (i) an alkylated diphenylamine; (ii) at least 5 weight % of a phenyl naphthylamine, based on the weight of the additive package; and (iii) a sulfur-containing phenol.Type: ApplicationFiled: June 2, 2009Publication date: January 14, 2010Applicant: Chemtura CorporationInventor: Jun DONG
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Publication number: 20090325831Abstract: An additive concentrate comprising a viscosity index modifying copolymer comprising the reaction product of an acylated ethylene-olefin copolymer and a polyamine, and lubricating compositions containing the same are provided. Methods of improving boundary film resistance of a lubricating composition and modifying the viscosity of a lubricating composition are also provided.Type: ApplicationFiled: June 30, 2008Publication date: December 31, 2009Inventors: Naresh C. Mathur, Akhilesh Duggal, Mark T. Devlin
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Patent number: 7625850Abstract: A high-temperature lubricating oil composition is provided, which is resistant to hardening and sludge formation, and displays minimal evaporation loss and superior thermal stability, even under practical high-temperature open system conditions such as those found in a tenter. A lubricating oil composition that provides excellent lubrication without damaging members used within working machinery is also provided. The lubricating oil composition comprises a polyolester based synthetic oil and a C12 to C72 fatty acid and/or a diphenylamine derivative containing an arylalkyl group with a number average molecular weight of 400 to 800.Type: GrantFiled: March 24, 2005Date of Patent: December 1, 2009Assignees: Mitsubishi Heavy Industries, Ltd., Sato Special Oil Co., Ltd.Inventors: Norihisa Horaguchi, Shiki Matsuo, Hideo Kometani, Naomoto Ishikawa, Tatsushi Seko, Yusuke Kinoshita, Masaru Seto, Kimihito Hitotsumatsu
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Patent number: 7569526Abstract: Disclosed herein is a method for reducing the oxidative and biological degradation of a metalworking fluid comprising adding thereto at least one antioxidant and at least one biocide.Type: GrantFiled: March 12, 2004Date of Patent: August 4, 2009Assignee: Crompton CorporationInventors: Michael T. Costello, Igor Riff
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Patent number: 7566687Abstract: Improved desulfurization compositions are provided for removing substantial fractions of sulfur, sulfur complexes, and sulfur compounds from liquid hydrocarbons such as crude oil and fuels. The preferred compositions comprise respective quantities of an alkylphenol ethoxylate, an amine, and an alkali metal nitrite. The compositions may be contacted with liquid hydrocarbons to achieve high levels of desulfurization.Type: GrantFiled: October 12, 2005Date of Patent: July 28, 2009Assignee: Jacam Chemical, LLCInventors: Gene H. Zaid, Beth Ann Wolf, Gary W. Zorn
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Publication number: 20090186785Abstract: The lubricating oil composition of the invention includes a base oil composed of mineral oil and/or synthetic oil, an amine antioxidant (A-1) in an amount of 800 ppm or more as reduced to the total amount of nitrogen, and a compound containing phosphorus and/or sulfur (A-2). The invention provides a compressor oil which realizes thermal/oxidation stability, resistance to sludge formation, lubricity, long service life, and water separation at high levels.Type: ApplicationFiled: December 7, 2006Publication date: July 23, 2009Applicant: IDEMITSU KOSAN CO., LTD.Inventor: Hideto Kamimura
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Publication number: 20090170738Abstract: The present invention provides a lubricating composition, particularly a grease composition and a lubricating oil composition, containing an aralkylated diphenylamine and a phenol compound having a molecular weight of not less than 340 which are compounded into a base oil. The lubricating composition is hardly decomposed or volatilized even at high temperatures and has a long oxidation life so that the lubricating characteristics thereof can be maintained for a long period of time.Type: ApplicationFiled: September 28, 2006Publication date: July 2, 2009Applicant: Idemitsu Kosan co., Ltd.Inventors: Yukitoshi Fujinami, Hideto kamimura
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Publication number: 20090156441Abstract: The invention is a C5-C12 cycloalkyl substituted phenylenediamine that provides deposit-control lubricant additives for organic materials including lubricating oil, gasoline, and diesel fuels. The invention improves the oxidative stability of the lubricants and fuels by adding cycloalkyl substituted phenylenediamines having one or more additional N-substituents.Type: ApplicationFiled: December 12, 2007Publication date: June 18, 2009Inventors: Robert G. Rowland, Theodore E. Nalesnik, Joseph P. Hartley, Neal J. Milne, Paul Wilson
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Publication number: 20090131293Abstract: A diaromatic amine compound having the general formula: wherein R1 and R2 together with the carbon atoms to which they are bonded are joined together to form a C3-C30 ring, and R3 is an allyl, benzyl, or methallyl group. R4, R5, and R6 are independently hydrogen, C1-C30 alkyl group, C2-C30 alkenyl group, C3-C12 cycloalkyl group, C5-C25 aryl group, C6-C25 arylalkyl group, or C1-C30 alkoxy group.Type: ApplicationFiled: November 16, 2007Publication date: May 21, 2009Inventors: Qinggao Ma, Cyril Migdal
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Patent number: 7534747Abstract: A soot reducing media that reduces the soot content in lubricating oil in an engine. Further a process employing a gel to decrease the amount of soot in the lubricating oil of an engine and/or decrease the emissions from an engine.Type: GrantFiled: June 25, 2003Date of Patent: May 19, 2009Assignee: The Lubrizol CorporationInventors: James D. Burrington, Herman F. George, John R. Martin, Ralph E. Kornbrekke
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Patent number: 7531083Abstract: Cycloalkane base oil, methods of making cycloalkane base oil, and dielectric liquid comprising cycloalkane base oil, the cycloalkane base oil comprising a quantity of isoparaffins and from 50 wt. % to 70 wt. % cycloalkanes having the formula CnH2n wherein n is from 15 to 30, said quantity of isoparaffins being less than 50 wt. % of said cycloalkane base oil.Type: GrantFiled: June 15, 2005Date of Patent: May 12, 2009Assignee: Shell Oil CompanyInventors: Steven Allen Holmes, John Robert Powers, Michael Phillip Smith, Abraham Robert Dekraker
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Publication number: 20090042755Abstract: A finished lubricant having a kinematic viscosity at 40° C. between about 90 and 1700 cSt that passes the TORT B rust test, comprising a highly paraffinic base oil and a solubility improver having an aniline point less than 50° C. A finished lubricant that passes the TORT B rust test, comprising a Fischer-Tropsch wax, oligomerized olefins, or mixture thereof; and a solubility improver. A process for making a lubricant, comprising blending together: a) a mixture of amine phosphates, b) an alkenyl succinic compound, and c) a highly paraffinic lubricating base oil.Type: ApplicationFiled: October 23, 2008Publication date: February 12, 2009Inventor: Mark E. Okazaki
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Publication number: 20090042754Abstract: A method of improving the rust inhibition of a lubricating oil by incorporating a solubility improver having an aniline point less than 10° C. A method of improving the rust inhibition of a lubricating oil by incorporating a solubility improver to enable the lubricating oil to meet the requirements of the MIL-PRF-17331J specification. A method of improving the rust inhibition of a lubricating oil by incorporating a solubility improver, a mixture of mono and diacid amine phosphate salts, and a alkenyl succinic compound into the lubricating oil.Type: ApplicationFiled: October 23, 2008Publication date: February 12, 2009Inventor: Mark E. Okazaki
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Publication number: 20090042753Abstract: The resistance to oxidation and nitration of a gas engine oil is improved by the use of a combination of a hindered phenolic antioxidant and an (alkylated) phenyl-?-naphthylamine antioxidant. The additional use of an organo molybdenum compound further enhances the resistance to oxidation and nitration.Type: ApplicationFiled: August 5, 2008Publication date: February 12, 2009Inventors: Marc-Andre Poirier, Kathleen Hoard Tellier, Stanley James Cartwright
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Publication number: 20090011961Abstract: Compositions are disclosed that comprise a lubricant, at least a first antioxidant and an optional second antioxidant, the first antioxidant being a styrenated phenolic antioxidant and the optional second antioxidant a secondary diarylamine for synergistic antioxidant action. Also disclosed is a method of increasing the oxidation stability of lubricating oils comprising: adding thereto at least a first antioxidant and, optionally, a second antioxidant, the first antioxidant being a styrenated phenolic antioxidant and the optional second antioxidant a secondary diarylamine.Type: ApplicationFiled: July 6, 2007Publication date: January 8, 2009Inventors: Jun Dong, Cyril A. Migdal, Gerard Mulqueen
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Publication number: 20080287329Abstract: The invention relates to a grade SAE 30 or 40 lubricant oil for marine four-stroke engines, comprising: (a) 50 to 95% by weight of an oil of mineral or synthetic origin, (b) at least one nanoparticulate detergent of a quantity sufficient for the neutralisation of the acid compounds formed by oxidation of the sulphurous compounds in the fuel supplying the engine, (c) 1 to 20% by weight of at least one polyisobutylene which is soluble in the base oil, with a number average molecular weight of 500 to 8000 inclusive and a kinematic viscosity (at 100° C.) of 50 to 50,000 mm2/s inclusive, preferably 200 to 6,000 mm2/s, (d) 0.05 to 5.0% of at least one aminated anti-oxidant agent active at a temperature of or above 180° C. and the use of said oil for lubrication of a four-stroke marine engine.Type: ApplicationFiled: December 16, 2005Publication date: November 20, 2008Applicant: TOTAL FRANCEInventors: Denis Lancon, Chantal Herault
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Publication number: 20080274925Abstract: The invention relates to a composition comprising a mixture of alkylated N-?-naphthyl-N-phenylamine (PANA) and alkylated diphenylamine (DPA), the product obtainable by alkylating PANA or a mixture of PANA and DPA with alkenes and the process for alkylating PANA or a mixture of PANA and DPA with alkenes. The compositions according to the present invention have an outstanding anti-oxidative action, which can be demonstrated by established test methods.Type: ApplicationFiled: March 23, 2005Publication date: November 6, 2008Inventors: Beat Michael Aebli, Samuel Evans, Marc Ribeaud, David Eliezer Chasan
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Patent number: 7413682Abstract: Antioxidants for industrial, automotive, and aviation lubricants and methods of making the same are provided. A process using alkylated diphenylamines; alkylated phenyl-?-naphthyl amines; and a metal catalyst to form oxidates is provided. The metal catalyst is a combination of a cation and an organic anion, for example, a metal acetylacetone. The reaction takes place in the presence of oxygen to form an antioxidant comprising oligomers of the alkylated diphenylamine and the alkylated phenyl-?-naphthyl amine, and a metal component of the catalyst.Type: GrantFiled: August 15, 2006Date of Patent: August 19, 2008Assignee: Anderol, Inc.Inventor: Eugene P. DiBella
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Publication number: 20080161216Abstract: The present invention relates to a process for preparing nonylated diphenylamines which improves nonene usage by recycling and reusing stripped nonene from an earlier process. The process comprising consecutive recycle of recovered nonene is conducted at a sequential two step temperature reaction, namely a more severe temperature followed by a lower temperature. The product prepared by this process is a useful antioxidant for lubricating oil compositions.Type: ApplicationFiled: December 20, 2007Publication date: July 3, 2008Inventor: Francois Simard
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Patent number: RE40595Abstract: There is disclosed a lubricating oil composition which contains from about 100 to 450 parts per million of molybdenum from a molybdenum compound which is substantially free of active sulfur and about 750 to 5,000 parts per million of a secondary diarylamine. This combination of ingredients provides improved oxidation control and friction modifier performance to the lubricating oil. The composition is particularly suited for use as a crankcase lubricant.Type: GrantFiled: May 20, 2005Date of Patent: December 2, 2008Assignee: Afton Chemical Intangibles LLCInventors: Vincent James Gatto, Mark Thomas Devlin