At Least One Polymer Is Derived From An Ethylenically Unsaturated Aromatic Reactant Or Wherein The Polymer-forming System Contains The Same Type Of Reactant Patents (Class 521/139)
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Publication number: 20120308898Abstract: A porous film includes aromatic polyamide as a constituent component that has high heat resistance, high air permeability and high affinity to electrolytes. It is a porous aromatic polyamide film including aromatic polyamide and a hydrophilic polymer, wherein the hydrophilic polymer accounts for 12 to 50 parts by mass per 100 parts by mass of the aromatic polyamide, the thickness being 2 to 30 micrometers, the Gurley air permeability being 0.5 to 300 seconds/100 ml, and the thermal shrinkage rate being ?0.5 to 1.0% at 200° C.Type: ApplicationFiled: December 3, 2010Publication date: December 6, 2012Applicant: TORAY INDUSTRIES, INC.Inventors: Atsushi Sawamoto, Kenta Nishibara, Akimitsu Tsukuda
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Patent number: 8323787Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, an additive blend of polyethylene oxide and a copolymer of polystyrene and maleic anhydride, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the polyethylene oxide is ethoxylated polyethylene oxide. Additionally, in at least one embodiment, the blowing agent includes at least one hydrofluorocarbon blowing agent. The blend of ethoxylated polyethylene oxide and copolymer of polystyrene and maleic anhydride provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product and increases the average cell size of the foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the additive acts as a cell enlarger, a water vapor permeability enhancer, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.Type: GrantFiled: January 29, 2010Date of Patent: December 4, 2012Assignee: Owens Corning Intellectual Capital, LLCInventors: Yadollah Delaviz, Raymond M. Breindel, John F. Budinscak, Jr.
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Patent number: 8324287Abstract: Prepare a polymeric foam from a foamable polymer composition containing a thermoplastic polymer composition and a blowing agent wherein 75 percent or more by weight of all non-halogenated polymers in the foamable polymer composition is a styrene-acrylonitrile copolymer composition having a polymerized acrylonitrile content distribution with a positive skew in a copolymerized AN content distribution and a positive percent difference between the mean and the median copolymerized AN content distribution.Type: GrantFiled: March 30, 2009Date of Patent: December 4, 2012Assignee: Dow Global Technologies LLCInventors: Lawrence S. Hood, Stephane Costeux, William A. Heeschen
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Patent number: 8318863Abstract: Foaming polypropylene resin compositions are excellent in balance between melt tension and flowability, can give injection-molded foams having superior mechanical strength such as impact resistance, and are suited for the production of automobile parts or the like. Processes of the invention produce injection-molded foams from the compositions. A foaming polypropylene resin composition according to the present invention includes a polypropylene resin (A) and an ethylene/?-olefin having 3-10 carbon atoms copolymer (B) in a specific ratio; the ethylene/?-olefin having 3-10-carbon atoms copolymer (B) includes a higher molecular weight component (B-H) having MFR190 of 1 to 10 g/10 min and a lower molecular weight component (B-L) having MFR190 of 20 to 50 g/10 min; and the weight ratio between (B-H) and (B-L), (B-H):(B-L), is in the range of 6:4 to 2:8.Type: GrantFiled: September 19, 2008Date of Patent: November 27, 2012Assignee: Prime Polymer Co., Ltd.Inventors: Tatsuji Kawamura, Yukio Ishii, Ikunori Sakai
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Patent number: 8314161Abstract: Provided are methods for producing a high strength, but easily deformed, polystyrene foam board that can endure repeatedly deformations from its original configuration into more complex curved shapes without damaging the board integrity or substantially reducing its structural strength. Also provided are rigid polystyrene foam boards produced by this method that exhibit improved bending and impact resistance while substantially retaining or improving other properties, for example, the thermal dimensional stability and fire resistance, exhibited by corresponding conventional XPS foam boards. The foamable compositions may incorporate one or more of a variety of polymer processing aids for the purpose of altering the performance of the final foam products, thereby allowing the properties of the final foam product to be customized to some degree.Type: GrantFiled: August 22, 2005Date of Patent: November 20, 2012Assignee: Owens Corning Intellectual Capital, LLCInventors: Mark E. Polasky, Raymond M. Breindel, Roland R. Loh, Yadollah Delaviz, Bharat Patel
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Publication number: 20120283345Abstract: The invention is directed to extruded foam based on thermoplastic polymers. The foam contains at least one styrene copolymer which contains copolymerized maleic anhydride units or copolymerized maleimide units, and optionally styrene-acrylonitrile copolymers (SAN), and thermoplastic polymers and at least one halogen-containing polymer as flame retardant, and at least one flame retardant synergist selected from antimony trioxide and dicumyl. The invention also relates to a process for producing the foam with introducing carbon dioxide as blowing agent, and acetone as coblowing agent; into the polymer melt in order to form a foamable melt, and extruding the foamable melt into a region of relatively low pressure with foaming to give the extruded foam. The invention also relates to the use of said foam as insulation material and as structural foam.Type: ApplicationFiled: May 4, 2012Publication date: November 8, 2012Applicant: BASF SEInventors: Holger Ruckdäschel, Ingo Bellin, Christian Däschlein, Klaus Hahn, Peter Merkel, Juan-Manuel Igea-Ruiz, Herbert Schall, Maria-Kristin Sommer, Tobias Höld, Christoph Hahn, Elmar Boy
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Patent number: 8293807Abstract: The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein at least one graft polyol b1) which can be prepared by in-situ polymerization of olefinically unsaturated monomers in a polyether alcohol b1i), where the polyether alcohol b1i) has a functionality of from 2 to 4 and a hydroxyl number in the range from 100 to 250 mg KOH/g, its polyether chain comprises propylene oxide and up to 20% by weight, based on the polyether alcohol b1i), of ethylene oxide, and acrylonitrile and styrene in a weight ratio of acrylonitrile:styrene of from >1:1 to 4:1 are used as olefinically unsaturated monomers, is used as compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b), and the reaction is carried out in the presence of at least one compound b1ii) which has at least one olefinic double bond anType: GrantFiled: September 6, 2007Date of Patent: October 23, 2012Assignee: BASF AktiengesellschaftInventors: Andreas Emge, Daniel Freidank, Holger Seifert
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Publication number: 20120252914Abstract: Flame-retardant polymer foams which comprise, as flame retardant, at least one halogenated polymer, for example brominated polystyrene or styrene-butadiene block copolymer having bromine content in the range from 40 to 80% by weight, or tetrabromobisphenol A compounds (TBBPA), processes for producing these, and also flame-retardant expandable styrene polymers.Type: ApplicationFiled: December 13, 2010Publication date: October 4, 2012Applicant: BASF SEInventors: Klaus Hahn, Olaf Kriha, Ingo Bellin, Frank Braun, Patrick Spies, Jan Kurt Walter Sandler, Geert Janssens, Jürgen Fischer, Christoph Fleckenstein, Hartmut Denecke, Sabine Fuchs, Peter Merkel, Manfred Pawlowski, Holger Ruckdäschel, Klemens Massonne
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Patent number: 8268904Abstract: Prepare an extruded polymeric foam using a thermoplastic polymer composition of styrene-acrylonitrile copolymer having a copolymerized acrylonitrile comonomer content of 20 weight-percent or less, a mean acrylonitrile comonomer content that exceeds its median acrylonitrile comonomer content and an average copolymerized acrylonitrile comonomer distribution having a breadth at half-height that is greater than 2.5 weight-percent as measured at half peak height of a copolymerized acrylonitrile comonomer distribution curve for the styrene-acrylonitrile copolymer.Type: GrantFiled: September 8, 2010Date of Patent: September 18, 2012Assignee: Dow Global Technologies LLCInventors: Lawrence S. Hood, Brian H. Deshano
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Publication number: 20120220678Abstract: The present invention relates to compositions comprising (i) as component (I), at least one molding composition comprising components A and B, where A) is a graft copolymer as component A, and B) is a thermoplastic copolymer as component B; and (ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II) in which R1 is C1-C10-alkyl or C3-C8-cycloalkyl, m is 0, 1, 2, or 3, n is 2, 3, or 4, and R is hydrogen or C1-C30-alkyl; or the group —(COOR)n forms an anhydride of the formula where it is essential to the invention that component (I) comprises from 11 to 19.9% by weight of component A and from 80.Type: ApplicationFiled: November 2, 2010Publication date: August 30, 2012Inventors: Christof Mehler, Rolf Minkwitz, Christian Schade, Piyada Charoensirisomboon, Norbert Niessner, Kyung Ho Shon
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Publication number: 20120214889Abstract: The present invention relates to processes for preparing copolymers A) with a reduced soil particle content, comprising 49.2 to 93.2% by weight of structural units which derive from one or more vinylaromatic monomers (component A1)), 6 to 50% by weight of structural units which derive from one or more vinyl cyanides (component A2)), 0.Type: ApplicationFiled: October 25, 2010Publication date: August 23, 2012Applicant: BASF SEInventors: Martin Weber, Peter Ittemann, Axel Gottschalk, Bernd Niedermaier, Birgit Reinhard, Dirk Meckelnburg
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Publication number: 20120208909Abstract: The invention relates to a mixture comprising: a) 1 to 40% by weight of a styrene-butadiene-styrene block copolymer having 1.) 60 to 95% by weight of styrene monomer and 2.) 5 to 50% by weight of diene monomer; b) 60 to 99% by weight of styrene polymer; c) 0 to 50% by weight of a filler; and d) 0.1 to 20% by weight of a foaming additive, the sum of the components a) to d) being 100% by weight.Type: ApplicationFiled: October 5, 2010Publication date: August 16, 2012Applicant: BASF SEInventors: Norbert Niessner, Rogelio Chavez
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Publication number: 20120208913Abstract: Foamable polystyrene compositions with enhanced blowing agent solubility and methods of making such polystyrene compositions by incorporating a polar additive in styrenic polymer or copolymers.Type: ApplicationFiled: January 11, 2012Publication date: August 16, 2012Applicant: FINA TECHNOLOGY, INC.Inventors: Wei Wang, Jose M. Sosa, David W. Knoeppel
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Patent number: 8242183Abstract: Certain brominated polymers compounds are effective FR additives for combustible organic polymers. These FR additives include: i) a copolymer having styrene and 2,3-dibromopropylmaleimide repeating units; ii) a brominated polyester having aliphatically bound bromine; iii) an allyl ether of a ring-brominated novolac resin; iv) a 3-bromo-2-hydroxypropyl ether of a novolac resin; v) a 2,3-dibromopropyl ether of a cresol novolac resin; and vi) a brominated ROMP polymer or copolymer.Type: GrantFiled: January 30, 2009Date of Patent: August 14, 2012Assignee: Dow Global Technologies LLCInventors: Bruce A. King, Anteneh Z. Worku, William G. Stobby
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Patent number: 8217092Abstract: A multicomponent polyurethane/vinyl ester hybrid foam system for forming a gradient foam with soft and rigid foam regions, with a polyol component (A), a polyisocyanate component (B), and a component (C), which contains a catalyst for the polymerization of the vinyl monomer, with the polyol component (A) containing, as vinyl monomer, a mixture of vinyl esters of at least one polymerizable hydroxyvinyl ester and at least one branched, at least trifunctional, polymerizable vinyl ester, and the polyisocyanate component (B) containing a thermally activatable free radical-forming agent as catalyst for the polymerization of the vinyl monomers, with the proviso that the proportion by weight of the vinyl ester mixture is greater than the proportion by weight of the at least one polyol as well as the proportion by weight of the at least one polyisocyanate.Type: GrantFiled: November 28, 2007Date of Patent: July 10, 2012Assignee: Hilti AktiengesellschaftInventor: Arne Reinheimer
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Patent number: 8217093Abstract: A two-component polyurethane/vinyl ester hybrid foam system is formed of a polyol component (A), which contains at least one polyol, a catalyst for the reaction of the polyol with the polyisocyanate, at least one polymerizable vinyl monomer and water or a blowing agent on the basis of a compressed or liquefied gas as foam-forming agent, and a polyisocyanate component (B), which contains at least one polyisocyanate and a catalyst for the polymerization of the vinyl monomer, and is designed for use as a flame retardant material and material for filling openings, cable and pipe bushings in walls, floors and/or of buildings for the purpose of fire protection.Type: GrantFiled: November 28, 2007Date of Patent: July 10, 2012Assignee: Hilti AktiengesellschaftInventor: Arne Reinheimer
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Publication number: 20120172214Abstract: A sheet material that includes an elastic component or material (e.g., film, nonwoven web laminated to the elastic component, etc.) is provided. The elastic component is formed from a styrenic block copolymer composition containing from about 10 wt. % to about 90 wt. % of styrene-butadiene-styrene block copolymer; and from about 10 wt % to about 90 wt. % of styrene-isoprene/butadiene-styrene block copolymer. The styrenic block copolymer composition has good viscosity stability during extrusion and thus may be readily formed into an elastic sheet material. The elastic sheet material may be subsequently crosslinked to achieve the desired elastic and mechanical properties.Type: ApplicationFiled: December 30, 2010Publication date: July 5, 2012Inventor: Oomman P. Thomas
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Patent number: 8211953Abstract: The present invention relates to a polyolefin resin foam which includes a polyolefin resin composition includes: (A) a rubber and/or a thermoplastic elastomer; (B) a polyolefin resin; and (C) at least one aliphatic compound selected from an aliphatic acid, an aliphatic acid amide and an aliphatic acid metallic soap, the compound having a polar functional group and having a melting point of 50 to 150° C., in which a content of the aliphatic compound is 1 to 5 parts by weight based on 100 parts by weight of the total amount of the rubber and/or thermoplastic elastomer and the polyolefin resin. The polyolefin resin foam of the invention is excellent in flexibility and cushioning properties, and has good processability, especially excellent cutting processability.Type: GrantFiled: September 27, 2007Date of Patent: July 3, 2012Assignee: Nitto Denko CorporationInventors: Makoto Saitou, Yasuyuki Tokunaga, Takio Itou, Hiroki Fujii
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Patent number: 8211952Abstract: A foamed composition adapted to seal to a substrate is provided. The foamed composition includes a radiation curable rubber, a photoinitiator, a blowing agent, a styrene-ethylene/butylene block copolymer, a light mineral oil, rheology modifier, a tackifier, and one of a radiation curable monomer and radiation curable oligomer, and wherein the composition is foamed upon application to the substrate.Type: GrantFiled: August 10, 2007Date of Patent: July 3, 2012Assignee: ADCO Products, Inc.Inventors: Eli Kendra, Dennis Booth, Paul Snowwhite
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Publication number: 20120164513Abstract: The present discloser provides a battery separator, including: a porous hyper-branched polymer which undergoes a closed-pore mechanism at a field effect condition, wherein the field effect condition includes at least one of a temperature being above 150° C., a voltage being 20V, or a current being 6 A; and a porous structure material. The invention also provides a method for manufacturing the battery separator and a secondary battery having the battery separator.Type: ApplicationFiled: September 18, 2011Publication date: June 28, 2012Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Yu Min Peng, Jing-Pin Pan, Tsung-Hsiung Wang, Chang-Rung Yang
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Publication number: 20120161061Abstract: Closed-cell extruded foam extruded foam with density in the range from 20 to 150 g/l and with a cell number in the range from 1 to 30 cells per mm is obtainable via (a) heating of a polymer component P, formed from P1) from 80 to 100% by weight (based on P) of one or more styrene-acrylonitrile copolymers (SAN), comprising a1) from 18 to 40% by weight (based on SAN) of copolymerized acrylonitrile, a2) from 60 to 82% by weight (based on SAN) of copolymerized styrene, and a3) from 0 to 22% by weight (based on SAN) of at least one copolymerized monomer from the group consisting of alkyl(meth)acrylates, (meth)acrylic acid, maleic anhydride and maleimides, P2) from 0 to 20% by weight (based on P) of one or more thermoplastic polymers from the group consisting of styrene copolymers, polyolefins, polyacrylates, polycarbonates (PC), polyesters, polyamides, polyether sulfones (PES), polyether ketones (PEK), and polyether sulfides, to form a polymer melt, (b) introduction of from 1 to 12% by weight (based on P) ofType: ApplicationFiled: September 6, 2010Publication date: June 28, 2012Applicant: BASF SEInventors: Klaus Hahn, Holger Ruckdäschel, Ingo Bellin, Peter Merkel, Markus Hartenstein
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Patent number: 8202945Abstract: Butadiene copolymers are brominated using certain quaternary ammonium tribromides as the brominating agent. The bromination process proceeds easily under mild conditions, and produces a brominated product that has excellent thermal stability.Type: GrantFiled: August 14, 2007Date of Patent: June 19, 2012Assignee: Dow Global Technologies LLCInventors: Bruce A. King, David B. Gorman, John W. Hull, Jr., Daniel J. Murray, Terry L. Gehrman
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Publication number: 20120148522Abstract: An article comprising a polyelectrolyte complex comprising an interpenetrating network of at least one predominantly positively charged polyelectrolyte polymer and at least one predominantly negatively charged polyelectrolyte polymer, the polyelectrolyte complex further comprising a plurality of closed-shell pores, the plurality of pores having at least one average transverse dimension between about 100 nanometer and about 1000 micrometers.Type: ApplicationFiled: August 19, 2010Publication date: June 14, 2012Applicant: FLORIDA STATE UNIVERSITY RESEARCH FOUNDATION, INC.Inventor: Joseph B. Schlenoff
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Publication number: 20120126455Abstract: Methods of processing high service temperature crosslinked thermoplastic gels are provided. The methods include combining (a) an oil-swelled physically crosslinked thermoplastic elastomer gel comprising at least one functional group configured to chemically crosslink in the presence of a crosslinker and (b) a crosslinker; maintaining the combination of the physically crosslinked thermoplastic elastomer gel and the crosslinker at a temperature at which they remain substantially unreacted; subsequently heating the combination to a temperature at which the oil-swelled physically crosslinked thermoplastic elastomer gel reacts with the crosslinker.Type: ApplicationFiled: November 24, 2010Publication date: May 24, 2012Applicant: Tyco Electronics CorporationInventors: Mark W. Ellsworth, Michael A. Oar
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Publication number: 20120129965Abstract: The present invention relates to the use of a mixture of film-forming polymers and hollow organic particles for coating materials, especially in paints, and to coating materials comprising such blends.Type: ApplicationFiled: July 21, 2010Publication date: May 24, 2012Applicant: BASF SEInventors: Arno Tuchbreiter, Oliver Wagner, Chris Titmarsh
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Publication number: 20120121876Abstract: Use of a material for the absorption of impact energy wherein the composition of the material is a mixture of, at least component (A) which is an organic thermoplastic elastomer having a hardness below 80 shore A measured at 23° C. and component (B) which is a non cross-linked and substantially non reactive silicone polymer or a cross-linked silicone polymer, with the exclusion of borated silicone polymers exhibiting dilatant properties.Type: ApplicationFiled: December 23, 2009Publication date: May 17, 2012Inventor: Daniel Milesi
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Patent number: 8158722Abstract: Composition comprising at least one copolymer A composed of at least one alkylated styrene, of acrylonitrile, and, if appropriate, of at least one further monomer, at least one block copolymer B which has at least one block forming a hard phase and composed of at least one vinylaromatic monomer and has at least one block forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene, and at least one further copolymer C, and, if appropriate, one polymer D, where the copolymer C is at least one triblock copolymer composed of a first block composed of at least one vinylaromatic monomer, of a second block composed of at least one diene, and of a third block composed of at least one methyl methacrylate monomer, or comprising at least 50% by weight of methyl methacrylate, and the polymer D is at least one styrene polymer selected from glass-clear and impact-resistant polystyrene.Type: GrantFiled: March 4, 2009Date of Patent: April 17, 2012Assignee: Styrolution GmbHInventors: Konrad Knoll, Koch Jürgen, Piyada Charoensirisomboon
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Patent number: 8148437Abstract: The present invention relates to a process for producing integral polyurethane foams, in which a) organic polyisocyanates are mixed with b) relatively high molecular weight compounds having at least two reactive hydrogen atoms, c) blowing agents, d) dialkyl cyclohexanedicarboxylates and, if appropriate, e) chain extenders and/or crosslinkers, f) catalysts and g) other auxiliaries and/or additives to form a reaction mixture, the reaction mixture is introduced into a mold and allowed to react to form an integral polyurethane foam. The present invention further relates to integral polyurethane foams comprising dialkyl cyclohexanedicarboxylates, the use of such foams in the interior of road vehicles or as shoe soles and the use of dialkyl cyclohexanedicarboxylates as internal mold release agents in the production of integral polyurethane foams.Type: GrantFiled: November 25, 2008Date of Patent: April 3, 2012Assignee: BASF SEInventors: Marco Ortalda, Tony Spitilli
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Publication number: 20120059077Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is ?1 or ?2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.Type: ApplicationFiled: November 15, 2011Publication date: March 8, 2012Applicant: FINA TECHNOLOGY, INC.Inventors: John Gaustad, Juan J. Aguirre, Jeo Shuler
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Publication number: 20120053256Abstract: Disclosed herein are a biomass composite composition and a foaming method thereof. The biomass composite composition includes (a) polyester alloy containing biodegradable polyester and petrochemical plastic, (b) reinforcing agent, (c) foaming agent, (d) compatibilizer, (e) lubricant, and (f) impact modifier. The biomass composite composition of the present invention is biodegradable and of heat resistance and melt strength suitable for manufacture of foam products.Type: ApplicationFiled: October 19, 2010Publication date: March 1, 2012Inventors: Jong-Wu CHEN, Hsiang-Jen Hsiao, Chia-Hung Li, Chin-Fu Chen
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Publication number: 20120034518Abstract: A microporous membrane comprising polyolefin copolymer, the membrane having a shutdown temperature?130.5° C. and a shutdown activation energy E2?3.5×103 J/mol.Type: ApplicationFiled: March 5, 2010Publication date: February 9, 2012Applicant: TORAY TONEN SPECIALTY SEPARATOR GODO KAISHAInventors: Takeshi Ishihara, Satoshi Miyaoka, Koichi Kono, Donna J. Crowther, Patrick Brant
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Publication number: 20120021225Abstract: A laminated composition includes a first polymer layer having a first surface and a second surface; a second polymer layer having a first surface and a second surface; and an adhesive layer joining the second surface of the first polymer layer to a first surface of the second polymer layer; where the adhesive layer includes a heat-shrinkable resin including heat-generating particles.Type: ApplicationFiled: May 14, 2010Publication date: January 26, 2012Inventors: Maki Maekawa, Takahisa Kusuura
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Publication number: 20120021220Abstract: A method of reducing an odor of composite resin particles comprising the step of: fluidizing the composite resin particles, which contain a polyolefin-based resin and a polystyrene-based resin and which are used for producing an expanded molded article, in a container with a gas that is blown thereinto from its bottom and that has a temperature of (T?40)° C. to (T?10)° C. (T is a softening temperature of the composite resin particles), to reduce the odor generated from a raw material of the composite resin particles and generated according to a method of the composite resin particles, wherein the composite resin particles whose odor is reduced are impregnated with a blowing agent; and the resultant is pre-expanded and then subject to an in-mold forming to make the expanded molded article have an odor strength of 3 or less in average value in odor test in which odor of an isovaleric acid diluted 100000 times is defined as 3, which means a reference odor, within 0 to 5 levels of the odor strength.Type: ApplicationFiled: March 24, 2010Publication date: January 26, 2012Applicant: SEKISUI PLASTICS CO., LTD.Inventors: Shinji Ishida, Hideyasu Matsumura
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Publication number: 20120003478Abstract: A method of reducing a volatile organic compound of composite resin particles comprising the step of: blowing a gas from a bottom part of a container in order to fluidize composite resin particles containing a polyolefin-based resin and a polystyrene-based resin in the container until an amount of volatile organic compounds contained in the whole composite resin particles becomes 50 ppm or less, wherein the gas has a temperature of (T?40) to (T?10)° C. when a softening temperature of the composite resin particles is defined as T° C.Type: ApplicationFiled: March 24, 2010Publication date: January 5, 2012Applicant: SEKISUI PLASTICS CO., LTD.Inventors: Hideyasu Matsumura, Shinji Ishida
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Publication number: 20120004337Abstract: A method for producing styrene-modified linear low-density polyethylene-based resin particles, which includes the steps of: dispersing 100 parts by weight of non-crosslinked linear low-density polyethylene-based resin particles which are polymerized using a metallocene compound as a catalyst and contain an inorganic nucleating agent, 50 to 800 parts by weight of a styrene-based monomer and 0.1 to 0.9 parts by weight of a polymerization initiator relative to 100 parts by weight of the styrene-based monomer into an aqueous suspension containing a dispersant; impregnating the polyethylene-based resin particles with the styrene-based monomer under heating the resulting dispersion at such a temperature that the styrene-based monomer does not substantially polymerize; and performing polymerization of the styrene-based monomer at a temperature of (T+10) to (T+35)° C. where T° C. is a crystallization peak temperature of the polyethylene-based resin particles.Type: ApplicationFiled: September 12, 2011Publication date: January 5, 2012Applicant: SEKISUI PLASTICS CO., LTD.Inventors: Hideyasu MATSUMURA, Tatsuya MATSUGASHITA
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Publication number: 20110316198Abstract: The invention relates to elastic expanded polymer foams and also a process for producing expanded polymer foams by sintering a mixture comprising foam particles P1 and P2 composed of different thermoplastic polymers or polymer blends, wherein the foam particles P1 are obtained by prefoaming expandable, thermoplastic polymer particles comprising A) from 45 to 97.9 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin having a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin having a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a styrene-butadiene or styrene-isoprene block copolymer, C2) from 0.0 to 10 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, E) from 0 to 5 percent by weight of a nucleating agent, where the sum of A) to E) is 100% by weight.Type: ApplicationFiled: March 1, 2010Publication date: December 29, 2011Applicant: BASF SEInventors: Carsten Schips, Jens Assmann, Georg Grässel, Geert Janssens, Maximillan Hofmann, Holger Ruckdäschel, Jürgen Lambert, Christof Zylla
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Publication number: 20110318594Abstract: Aqueous coating composition having a PVC from 78 to 85% and free of non-fugitive coalescing solvent, comprising, based on the total volume solids of the dry coating unless otherwise stated, a) opacifying pigment particles comprising from 3 to 10% titanium dioxide and from 0 to 20% of hollow polymeric particles; b) non-opacifying extender particles comprising calcium magnesium carbonate and/or calcium carbonate and/or nepheline syenite and/or kaolin; c) polymer binder particles of calculated Fox Tg of from 5 to 25° C. having an acid value of from 15 to 65 mg KOH/g of polymer; d) dispersant having weight average molecular weight of at least 3500 Daltons, and wherein the dispersant demand of a mixture of the opacifying pigment particles, other than the hollow polymeric particles, of a) and the extender particles of b) is greater than 0.35 wt %, calculated on the weight of the titanium dioxide and extender particles; e) fugitive coalescing solvent.Type: ApplicationFiled: April 21, 2011Publication date: December 29, 2011Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventors: Stephen Arthur WHEELER, Anthony David WOODS, Simon Nicholas EMMETT, Gary JEFFERSON, Javier PEREZ-AMOROS
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Patent number: 8084510Abstract: Expandable polystyrenic resin particles having superior resistance to cracking of a molded foam product, having superior retention of blowing agent and maintaining expandability over a long period of time, a production process thereof, and a molded foam product are provided.Type: GrantFiled: October 25, 2007Date of Patent: December 27, 2011Assignee: Sekisui Plastics Co., Ltd.Inventors: Ikuo Morioka, Yasutaka Tsutsui, Hideyasu Matsumura
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Patent number: 8076383Abstract: The present invention relates to a method for producing a porous resin particle having a functional group X, the method including: dissolving a radical polymerizable aromatic monovinyl monomer and a radical polymerizable aromatic divinyl monomer together with a polymerization initiator in an organic solvent to prepare a monomer solution, dispersing the monomer solution in water in the presence of a dispersion stabilizer to obtain a suspension polymerization reaction mixture, and performing a suspension copolymerization while adding, when 0 to 80% of the entire polymerization time of the suspension copolymerization is passed, a mercapto compound represented by the formula (I): HS—R—X??(I) in which R represents an alkylene group having a carbon number of 2 to 12, and the functional group X represents a functional group selected from a hydroxy group and a primary amino group, to the suspension polymerization reaction mixture; and the porous resin particle obtained by the method.Type: GrantFiled: November 5, 2008Date of Patent: December 13, 2011Assignee: Nitto Denko CorporationInventors: Tatsuya Konishi, Kenjiro Mori
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Publication number: 20110275731Abstract: The present invention provides a crosslinked foam having an excellent balance of various physical properties in terms of lightness, flexibility, permanent compression set, tear strength, impact resilience, and molding stability; a shoe midsole; and a crosslinkable and foamable composition that provides the crosslinked foam and shoe midsole. A crosslinkable and foamable composition comprising (A) an ethylene-based copolymer; (B) a copolymer comprising a vinyl aromatic monomer unit and an unsaturated bond-containing a conjugated diene monomer unit; (C) an organic peroxide; and (D) a foaming agent; a mass ratio of the component (A) to the component (B), (NB), being from 97/3 to 50/50; and the component (B) comprising 5 mass % or more and 80 mass % or less of the vinyl aromatic monomer unit, and 5 mass % or more and 55 mass % or less of the conjugated diene monomer unit.Type: ApplicationFiled: December 21, 2009Publication date: November 10, 2011Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Daisuke Shimizu, Yoshifumi Araki, Katsumi Suzuki, Yasuhiro Kusanose, Mika Horiuchi
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Publication number: 20110268972Abstract: Expandable, thermoplastic polymer bead material composed of a multiphase polymer mixture which comprises blowing agent and has at least one continuous phase of a thermoplastic polymer, where at least two different disperse phases P1 and P2 are present, disperse in the continuous phase, and also to processes for its production, and to use for the production of elastic molded foams.Type: ApplicationFiled: December 15, 2009Publication date: November 3, 2011Applicant: BASF SEInventors: Carsten Schips, Klaus Hahn, Maximilian Hofmann, Holger Ruckdäschel, Jens Assmann, Geert Janssens, Georg Gräßel, Jurgen Lambert, Christof Zylla
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Publication number: 20110262686Abstract: The present invention is an article of a film or sheet or a laminate of the film or sheet with nonwoven facing layer(s). The film or sheet is a blended compound of selectively hydrogenated thermoplastic block copolymer, a tackifying resin, and polyolefin and/or polystyrene, that has superior tensile strength and a good balance of good elasticity, low stiffness and good adhesion.Type: ApplicationFiled: April 22, 2010Publication date: October 27, 2011Inventors: Kathryn Wright, Chandra Brown
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Publication number: 20110244180Abstract: A heat insulator that generates no smoke when incinerated, has a low calorific value, and achieves a desired dimension and heat insulation performance is provided. A heat insulator 1 is formed by heat-mixing, in an extruder 11, a paper pellet 7 that is a mixture of a fine paper powder having a particle diameter of 30 to 200 ?m and starch, a container recycle pellet 8 that is a mixture of polypropylene, polyethylene, and polystyrene, foamable polypropylene 9, and water 10 to obtain a plate-like foamed product 2, and orthogonally overlaying a plurality of plate-like foamed products 2. A weight distribution is set so that the paper pellet 7 is 50 to 65% by weight, the container recycle pellet 8 is 13 to 25% by weight, the foamable polypropylene 9 is 10 to 30% by weight, and the water 10 is 10 to 20% by weight to these resins and other materials.Type: ApplicationFiled: April 4, 2011Publication date: October 6, 2011Applicant: Kankyokeieisogokenkyusho Co., Inc.Inventor: Takamichi Matsushita
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Patent number: 8017664Abstract: The invention relates to a process for the batch or semi-batch preparation of a polymer polyol, which process involves (1) preparing a seed by polymerizing in a base polyol at least one ethylenically unsaturated monomer in the presence of a polymerization initiator and macromer, and in the presence of from 0.5 to 50% wt of polymer polyol heel, based on amount of polymer present in the heel compared with total amount of polymer formed, (2) adding additional ethylenically unsaturated monomer to the seed obtained in step (1) and optionally additional polyol, and (3) polymerizing the mixture obtained in step (2).Type: GrantFiled: May 14, 2003Date of Patent: September 13, 2011Assignee: Shell Oil CompanyInventors: Bob Heinis, Willem Karzijn, Martien Krijger, Martinus Johannes Maria Lelieveld
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Publication number: 20110218346Abstract: Provided are a kind of high selectivity polymeric adsorbents with amide functional groups based on the hydrogen bonding interaction, which is prepared by adequately swelling a DVB-co-MA copolymer of 6% crosslinking degree as the initial resin with dimethyl formamide, performing an amination reaction by adding a diamine, soaking the dried resultant yellow resin with an acylating agent that is a dianhydride, and performing an acylation reaction to obtain the polymeric adsorbent with amide functional groups of the invention. The polymeric adsorbent of the invention can be used to effectively isolate and purify the active ingredients, i.e., flavones and lactones, from the extract of ginkgo leaf.Type: ApplicationFiled: February 12, 2009Publication date: September 8, 2011Applicant: NANKAI UNIVERSITYInventors: Zhi Yuan, Chunhong Wang, Rongfu Shi, Jing Zhang, Ping Ren, Yingchao Chen
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Publication number: 20110217538Abstract: A thermoplastic elastomer composition for injection molding is provided that includes component (A), component (B), component (C) and component (D) below, relative to 100 parts by weight of component (A), component (B) having a content of 5 to 150 parts by weight, component (C) having a content of 5 to 300 parts by weight, and component (D) having a content of 5 to 150 parts by weight. (A): A hydrogenated product of a block copolymer composed of a block (a) composed of an aromatic vinyl compound-based monomer unit, and a block (b) composed of a conjugated diene compound-based monomer unit, having a 1,2-bond content of not less than 60%, (B): a propylene-based resin, (C): a mineral oil softener, and (D): an ethylene-propylene copolymer rubber having a Mooney viscosity (ML1+4, 100° C.) of 20 to 200, an ethylene-based monomer unit having a content of 40 to 80 wt % (relative to 100 wt % of the copolymer rubber).Type: ApplicationFiled: March 2, 2011Publication date: September 8, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yu MIURA, Yuya YAMAMOTO
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Patent number: 8008398Abstract: Foamable compositions which are usable for the manufacture of foamed, flexible, heat resistant, thermoplastic elastomeric articles, and which comprises at least: (a) 100 pbw of one or more selectively hydrogenated block copolymers, (b) 5 to 50 pbw per 100 pbw of component (a) of one or more different selectively hydrogenated block copolymers, (c) 42 to 80 pbw per 100 pbw of component (a) of a linear crystalline polymer comprising propylene as the major component, (d) from 100 to 250 pbw per 100 pbw of component (a) of a softener compatible with blocks B and B?, and (e) from 0.01 to 3 wt. %, relative to the weight of the primary components (a) to (e) of a solid chemical nucleating agent of the endothermic group in combination with a blowing agent.Type: GrantFiled: September 3, 2004Date of Patent: August 30, 2011Assignee: Kraton Polymers U.S. LLCInventors: Xavier Muyldermans, Emmanuelle Coignoul
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Publication number: 20110204536Abstract: A styrenic monomer-diolefin copolymer comprises polystyrenic monomer micro-blocks and polydiolefin micro-blocks, in which the content of styrenic monomer units is 10-80 wt %, the ratio of diolefin units of 1,2-structure is less than 30% in the total diolefin units, and the number-average molecular weight (Mn) of the copolymer is 25,000-500,000. The preparation methods and uses in foam products thereof are also disclosed.Type: ApplicationFiled: July 15, 2009Publication date: August 25, 2011Inventors: Hongwen Liang, Aimin Zhang, Lixin Zhou, Jinkui Xia, Zhibin Zhang, Weiping Zhou
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Publication number: 20110196054Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, an infrared attenuating agent, and a polystyrene/polyethylene oxide copolymer are provided. In exemplary embodiments, the blowing agent contains an HFC. The maleic anhydride-styrene copolymer grafted with polyethylene oxide increases the cell size of the polymer foam and offsets or even negates the decreased cell size caused by an HFC blowing agent and/or infrared attenuating agents. In addition, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid. A method of forming an extruded foam product is also provided.Type: ApplicationFiled: January 29, 2010Publication date: August 11, 2011Inventors: Yadollah Delaviz, Raymond M. Breindel, Klein Rodrigues, Bharat Patel
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Publication number: 20110190405Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, a polystyrene/polyethylene oxide copolymer, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the blowing agent includes at least one hydrofluorocarbon blowing agent. The maleic anhydride-styrene copolymer grafted with polyethylene oxide provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid.Type: ApplicationFiled: January 29, 2010Publication date: August 4, 2011Inventors: Yadollah Delaviz, Raymond M. Breindel, Mitchell Z. Weekley, John F. Budinscak