N=c=x Reactant Having At Least Two C-nh-c(=x)- Groups, E.g., Prepolymers, Etc. Patents (Class 521/159)
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Patent number: 8980966Abstract: The invention relates to hydrophilic aliphatic polyurethane foams obtained by reacting special prepolymers having a low monomer concentration and hydrophilic polyisocyanates in the presence of water. The absorptive properties make said polyurethane foams particularly suitable for producing wound dressings, cosmetic articles, or incontinence products.Type: GrantFiled: August 26, 2010Date of Patent: March 17, 2015Assignee: Bayer MaterialScience AGInventors: Sebastian Dörr, Meike Niesten
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Patent number: 8975306Abstract: A viscoelastic foam system is provided having an amine-based polyoxypropylene extended polyol to impart strength, recoverability and endurance to the foam, and an appropriately selected non-amine-based polyol to provide flexibility to the foam. The combination of amine-based propylene oxide extended polyol and non-amine-based polyol provides a viscoelastic semi-rigid foam with excellent impact and recovery properties, recovering to substantially 100% of its initial volume and shape following an impact, yet with sufficient rigidity and stiffness so that it is effective at absorbing multiple impacts. A method of making the above viscoelastic foam is also provided.Type: GrantFiled: October 19, 2004Date of Patent: March 10, 2015Assignee: Intellectual Property Holdings, LLCInventor: Charles M. Milliren
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Patent number: 8946315Abstract: The invention relates to hydrophilic, aliphatic polyurethane foams, which are accessible by reacting hydrophilic polyisocyanates in the presence of water. Due to the absorption properties thereof, the polyurethane foams are in particular suited for producing wound dressings, cosmetic articles or incontinence products.Type: GrantFiled: January 7, 2011Date of Patent: February 3, 2015Assignee: Bayer Intellectual Property GmbHInventors: Meike Niesten, Sebastian Dörr
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Publication number: 20150020573Abstract: This invention relates to impact absorbing foams. These foams comprise a polymeric foam and ceramic particulates dispersing the foam. These foams have numerous uses, including, for example, as interior pads for football helmets, and the like, for reducing head injuries.Type: ApplicationFiled: October 9, 2014Publication date: January 22, 2015Inventors: Karl-Heinz Schofalvi, Ji Seung Kim, Christopher James Durning
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Patent number: 8927613Abstract: The present invention relates to cellular polyisocyanate polyaddition products whose density to DIN EN ISO 845 is from 200 to 800 kg/m3, and also to prepolymer composed of at least one diisocyanate (a) and of at least one polyether alcohol (b), where the at least one polyether alcohol (b) comprises the following components: (b1) aliphatic polyether alcohols whose number-average molar mass is from 300 to 1000 g/mol, (b2) aliphatic polyether alcohols whose number-average molar mass is from 2000 to 10 000 g/mol, and (b3) aliphatic polyether alcohols whose number-average molar mass is from 10 000 to 100 000 g/mol, to a process for its production, to a cellular polyisocyanate polyaddition product thus produced, and to its use as damping elements in vehicle construction.Type: GrantFiled: July 14, 2009Date of Patent: January 6, 2015Assignee: BASF SEInventors: Frank Prissok, Joern Duwenhorst, Michael Harms, Sven Lasai
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Patent number: 8927614Abstract: The invention relates to a process for producing polyurethanes by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, wherein the compounds b) having at least two hydrogen atoms which are reactive toward isocyanate groups comprise at least one polyether alcohol b1) which has been prepared by reaction of an aromatic amine b1a) with propylene oxide using an amine b1b) which is different from b1a) as catalyst.Type: GrantFiled: April 22, 2011Date of Patent: January 6, 2015Assignee: BASF SEInventors: Marc Fricke, Markus Schütte, Sirus Zarbakhsh, Johann Klassen
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Patent number: 8921434Abstract: A polylactic acid composition is produced with an MI value of 0.05 or more and 5 or less, the MI value being measured at 190° C. under a load of 21.6 kg in accordance with JIS K7210 (ISO 1133). A polylactic acid is crosslinked with a polyisocyanate to generate a cross-linked polylactic acid, including a large cross-linked polylactic acid molecule which inhibits foaming. The cross-linked polylactic acid is mechanically grinded-by applying a shear force to decrease a molecular weight of the large cross-linked polylactic acid molecule. The amount of the polyisocyanate combined is 0.4 to 5% by weight based on the polylactic acid. The grinding is conducted in supercritical condition of an inert gas. A foam molded article is made from the polylactic acid composition.Type: GrantFiled: March 29, 2011Date of Patent: December 30, 2014Inventors: Kosuke Uchiyama, Kazunori Tsuda, Tenya Suzuki
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Publication number: 20140378031Abstract: The purpose of the present invention is to provide: a polishing pad which has improved dressing properties, while maintaining the hardness; or a polishing pad which does not easily make a scratch on the surface of an object to be polished, while having improved dressing properties. A polishing pad of the present invention is characterized by having a polishing layer that is formed of a polyurethane resin foam or an unfoamed polyurethane resin, and is also characterized in that the polyurethane resin foam or the unfoamed polyurethane resin contains, as starting material components, (A) an isocyanate component, (B) a polyol component and (C) an aromatic compound that has one hydroxyl group and/or an aromatic compound that has one amino group.Type: ApplicationFiled: August 24, 2012Publication date: December 25, 2014Applicant: TOYO TIRE & RUBBER CO., LTD.Inventors: Akinori Sato, Masato Doura
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Patent number: 8906975Abstract: A conventional flexible polyurethane foam, made using methylene diphenyl diisocyanate (MDI), having a bulk foam density in the range of 2.5 pounds per cubic foot or lower and having a foam hardness or IFD in the range of 10 to 90 lb/50 in2. The present invention is also directed to the method for the making thereof.Type: GrantFiled: February 5, 2010Date of Patent: December 9, 2014Assignee: Hickory Springs Manufacturing CompanyInventors: Dimitrios V. Dounis, Dwayne Lewis Beard, Camden Eugene McLaughlin, Kimberly R. Fair
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Patent number: 8883869Abstract: This invention relates to impact absorbing foams. These foams comprise a polymeric foam and ceramic particulates dispersing the foam. These foams have numerous uses, including, for example, as interior pads for football helmets, and the like, for reducing head injuries.Type: GrantFiled: August 8, 2012Date of Patent: November 11, 2014Assignee: Provee Technologies, LLCInventors: Karl-Heinz Schofalvi, Ji Seung Kim, Christopher James Durning
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Publication number: 20140329923Abstract: A method of making a polyurethane foam from a mixture of isocyanate modified polyol and foam-forming ingredients, wherein the isocyanate modified polyol is made by reacting at least one polyol with at least one multifunctional isocyanate, wherein the isocyanate modified polyol is a non-foamed polyol polymer having available OH groups, wherein the foam forming ingredients comprise at least a multifunctional isocyanate and a foaming agent, preferably water, and characterised in that (i) the at least one polyol from which the isocyanate modified polyol is made comprises at least one lipid-based polyol which has undergone reaction with the isocyanate in the presence of a PU gelation catalyst, and/or (ii) the isocyanate modified polyol is mixed with a lipid-based polyol prior to, or at the same time as, foaming.Type: ApplicationFiled: July 19, 2014Publication date: November 6, 2014Applicant: GREEN URETHANES LIMITEDInventors: Jeffrey Philip ROWLANDS, Frans PAAP
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Publication number: 20140330235Abstract: Super-soft foam materials, optionally for use as medical dressings, are provided. The pads are made of a foam prepared from NCO-terminated prepolymers in combination with an aqueous phase including fatty alcohols and alkyl polysaccharides. The foam may optionally contain at least one medicinal agent.Type: ApplicationFiled: July 21, 2014Publication date: November 6, 2014Inventor: Hansen P. Swaniker
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Patent number: 8865785Abstract: A polishing pad capable of maintaining a high level of dimensional stability upon moisture absorption or water absorption and providing high polishing rate includes a polishing layer of a polyurethane foam having fine cells, wherein the polyurethane foam includes a cured product of a reaction of (1) an isocyanate-terminated prepolymer (A) that includes an isocyanate monomer, a high molecular weight polyol (a), and a low molecular weight polyol, (2) an isocyanate-terminated prepolymer (B) that includes a polymerized diisocyanate and a polyethylene glycol with a number average molecular weight of 200 to 1,000, and (3) a chain extender.Type: GrantFiled: March 13, 2008Date of Patent: October 21, 2014Assignee: Toyo Tire & Rubber Co., Ltd.Inventor: Yoshiyuki Nakai
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Patent number: 8841403Abstract: A catalyst system which is suitable for catalyzing the production of polyurethane systems is provided. The catalyst system contains a metal salt of a carboxylic acid to whose carbonyl carbon a hydrogen atom or a hydrocarbon radical is bound, with the proviso that the carboxylic acid does not have exclusively a single ethyl or n-propyl branch in the 2 position.Type: GrantFiled: July 14, 2010Date of Patent: September 23, 2014Assignee: Evonik Degussa GmbHInventors: Sarah Schmitz, Roland Hubel
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Publication number: 20140256838Abstract: A wettable, high strength, ether foam, particularly suited for ink holders, that includes a prepolymer that is formed before adding it to other components in the foam formulation.Type: ApplicationFiled: March 6, 2013Publication date: September 11, 2014Inventors: Joseph W. Lovette, Saranya Maungnoi
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Patent number: 8822556Abstract: The present invention relates to a one-component, moisture-curing foam consisting of 10 to 60% by volume of at least one gas and of a one-component, moisture-curing composition Z comprising at least one polymer P having isocycanate groups and/or alkoxysilane groups and 5 to 50% by weight of carbon black, based on the total weight of the one-component, moisture-curing foam. Such foams are suitable as adhesives or sealants, for the production of coatings or for the film-filling of hollow structures, in particular in vehicle construction.Type: GrantFiled: November 18, 2008Date of Patent: September 2, 2014Assignee: Sika Technology AGInventors: Sabine Erdelt, Roberto Cutri, Urs Jaeger
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Patent number: 8815968Abstract: A method of making a polyurethane foam from a mixture of isocyanate modified polyol and foam-forming ingredients, wherein the isocyanate modified polyol is made by reacting at least one polyol with at least one multifunctional isocyanate, wherein the isocyanate modified polyol is a non-foamed polyol polymer having available OH groups, wherein the foam forming ingredients comprise at least a multifunctional isocyanate and a foaming agent, preferably water, and characterized in that (i) the at least one polyol from which the isocyanate modified polyol is made comprises at least one lipid-based polyol which has undergone reaction with the isocyanate in the presence of a PU gelation catalyst, and/or (ii) the isocyanate modified polyol is mixed with a lipid-based polyol prior to, or at the same time as, foaming.Type: GrantFiled: March 3, 2010Date of Patent: August 26, 2014Assignee: Green Urethanes LimitedInventors: Jeffrey Philip Rowlands, Frans Paap
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Patent number: 8809410Abstract: Flexible polyurethane foam having a density of 25-70 kg/m3 and a compression load deflection of 5-15 kPa. Process for making a flexible polyurethane foam and the use as plant growth medium and in green roofs and green walls.Type: GrantFiled: September 14, 2010Date of Patent: August 19, 2014Assignee: Huntsman International LLCInventors: Johan Antoine Stefaan Macken, Herman Eugene Germain Moureau, Steven Ramsdonck, Annelies Vandevelde
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Patent number: 8785511Abstract: Low density silicone-containing polyurethane foams with excellent surface characteristics are prepared by reacting a foamable composition containing a siloxane of the formula and an isocyanate, in the presence of at least one blowing agent.Type: GrantFiled: December 5, 2011Date of Patent: July 22, 2014Assignee: Wacker Chemie AGInventors: Jens Cremer, Steffen Jungermann
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Patent number: 8779020Abstract: A polishing pad generates very few scratches on a surface of a polishing object, and is excellent in planarization property. The polishing pad has a high polishing rate and is excellent in planarization property. The polishing pad grooves become very little clogged with abrasive grains or polishing swarf during polishing and, even when continuously used for a long period of time, the polishing rate is scarcely reduced.Type: GrantFiled: September 7, 2012Date of Patent: July 15, 2014Assignee: Toyo Tire & Rubber Co., Ltd.Inventors: Atsushi Kazuno, Kazuyuki Ogawa, Masahiko Nakamori, Takatoshi Yamada, Tetsuo Shimomura
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Patent number: 8741976Abstract: A process for producing porous aerogels or xerogels includes a reaction of at least one polyfunctional isocyanate with an amine component. The amine component includes at least one polyfunctional substituted aromatic amine. The reaction is in the presence of a solvent and a catalyst. Aerogels and xerogels that can be obtained in this way can be used as insulation material and in vacuum insulation panels.Type: GrantFiled: November 4, 2011Date of Patent: June 3, 2014Assignee: BASF SEInventors: Marc Fricke, Mark Elbing
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Patent number: 8741977Abstract: An odor-absorbing foam composition comprising a cyclodextrin crosslinked with a polyurethane prepolymer. In one embodiment, the foam includes a ratio of the cyclodextrin to the polyurethane prepolymer selected to result in formation of the foam. The odor-absorbing foam may be used in a personal care product or wound care. A process for preparing a foam, including providing a cyclodextrin; providing a polyurethane prepolymer; combining the cyclodextrin with the polyurethane prepolymer; and allowing the polyurethane prepolymer to react with water and crosslink the cyclodextrin to form the foam. A process for preparing an odor-absorbing foam article such as a personal care product, including preparing the foam and applying it or the components thereof to a suitable substrate.Type: GrantFiled: March 11, 2008Date of Patent: June 3, 2014Assignee: Avery Dennison CorporationInventors: Anne Marie Paule Wibaux, Bert Paesen
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Patent number: 8722753Abstract: A method of making a hydroxyl terminated precursor for polyurethane is disclosed. The method comprises heating a vegetable oil-polyol mixture of modified vegetable oil containing about two or more hydroxyl groups per molecule and a polyether polyol having about two or more hydroxyl groups per molecule at a temperature of at least about 25 degrees Celsius and at a pressure of about 1 atmosphere. The mixture has a hydroxyl equivalent ratio of about 1:1 vegetable oil to polyol. The method further comprises mixing for at least about 10 minutes an isocyanate containing about two or more isocyanato groups per molecule at least about 25 degrees Celsius to the vegetable oil-polyol mixture at a molar equivalent ratio of at least 2:1 vegetable oil-polyol mixture to isocyanate to react the isocyanate with the mixture to form the hydroxyl terminated precursor.Type: GrantFiled: August 21, 2007Date of Patent: May 13, 2014Assignee: Lear CorporationInventors: Thomas N. Jones, Edmund J. Madaj
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Publication number: 20140107243Abstract: The invention relates to a specific composition comprising A) isocyanate-functional prepolymers obtainable by reaction of A1) aliphatic diisocyanates with A2) di- to hexa-functional polyalkylene oxides having an ethylene oxide content of 50 to 100 mol %, based on the total amount of the oxyalkylene groups present, B) an aqueous polyurethane suspension, an aqueous polyacrylate suspension or aqueous silica sols, especially for production of hydrophilic, aliphatic polyurethane foams. The invention further provides a process for producing a hydrophilic, aliphatic polyurethane foam, based on the inventive composition, a polyurethane foam obtainable by the process and a wound dressing comprising the polyurethane foam.Type: ApplicationFiled: April 30, 2012Publication date: April 17, 2014Applicant: Bayer Intellectual Property GmbHInventors: Meike Niesten, Sebastian Dörr, Sascha Plug, Jan Schönberger
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Publication number: 20140094530Abstract: Polyurethane foams having a NFPA 101 Class B rating (ASTM E-84) which pass the FM 4450 calorimeter Test are produced by reacting: (a) an organic polyisocyanate, (b) at least one polyether polyol or polyester polyol with a nominal hydroxyl functionality of at least 2.0, (c) a blowing agent composition and (d) at least one halogen-free flame retardant. The blowing agent composition includes: (1) no more than 10% by weight, based on total weight of the foam-forming composition, of one or more hydrocarbons having an LEL less than 2% by volume in air, and/or (2) a hydrocarbon having an LEL greater than 2% by volume in air, and (3) up to 1% by weight, based on total weight of foam-forming composition, of water.Type: ApplicationFiled: October 2, 2012Publication date: April 3, 2014Applicant: Bayer MaterialScience LLCInventors: George G. Combs, Susan C. Pigott
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Patent number: 8673991Abstract: The two-part curable polyurethane foam resin composition uses little or no petroleum-derived raw materials but a plant-derived raw material so that the biomass ratio can be improved, the load on the environment can be reduced, and excellent physical characteristics can be exhibited. The two-part curable polyurethane foam resin composition includes a main agent that contains an isocyanate-terminated urethane prepolymer (A) and a curing agent that contains an isocyanate-reactive compound (B), water (C), and a catalyst (D), in which a polyol component used in (A) and (B) uses a castor oil polyol (b1) having 1.5 to 2.3 functional groups on average and a polyol (b2) prepared by addition polymerization of lactone to polytetramethylene glycol and/or polytetramethylene glycol (b3), the ratio (b1)/(b2) and/or (b3)=15/85 to 60/40 on a mass basis, and a content of the castor oil polyol (b1) is 10 to 45% by mass.Type: GrantFiled: March 22, 2011Date of Patent: March 18, 2014Assignee: DIC CorporationInventors: Tomoaki Shinchi, Hiroshi Suzaki
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Publication number: 20140066535Abstract: The present invention relates to a method for producing flexible polyurethane foams, wherein an isocyanate component (component B) is used which comprises polyether carbonate polyol, and to the isocyanate component itself. The invention also provides an NCO-terminated, urethane group-comprising prepolymer obtainable by reaction of one or more polyisocyanates (B1) with one or more polyether carbonate polyols.Type: ApplicationFiled: March 23, 2012Publication date: March 6, 2014Applicant: Bayer Intellectual Property GmbHInventors: Gundolf Jacobs, Sven Meyer-Ahrens, Bert Klesczewski, Angelika Schulz
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Publication number: 20140045962Abstract: This invention relates to impact absorbing foams. These foams comprise a polymeric foam and ceramic particulates dispersing the foam. These foams have numerous uses, including, for example, as interior pads for football helmets, and the like, for reducing head injuries.Type: ApplicationFiled: August 8, 2012Publication date: February 13, 2014Inventors: Karl-Heinz Schofalvi, Ji Seung Kim, Christopher James Durning
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Patent number: 8642670Abstract: The present invention relates to an open-cell polyurethane foam comprising polyester and polyether structures and having a density of 70 to 300 g/L, 1 to 20 cells/cm, a rebound intensity greater than 30%, an elongation at break of greater than 200%, a tear propagation resistance of greater than 1.2 N/mm and a tensile strength of greater than 200 kPa. The present invention further relates to a process for producing inventive open-cell polyurethane sponges and to the use thereof as a pipe cleaning sponge.Type: GrantFiled: March 13, 2009Date of Patent: February 4, 2014Assignee: BASF SEInventors: Nils Mohmeyer, Ralf Fritz, Annika Habicht, Daniela Tepe, Frank Prissok, Michael Harms, Bernd Bruchmann, Daniel Schoenfelder, Daniel Freidank, Andreas Emge, Andrea Eisenhardt
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Publication number: 20140010981Abstract: The present invention relates to a composition for producing a rigid polyurethane foam comprising at least one polyol having a molecular weight of not less than 1700 g/mol and at least one blowing agent as component A, and at least one polyisocyanate as component B, wherein the at least one polyisocyanate B comprises from 11 to 39.5 wt % of a polyisocyanate prepolymer, based on a polyether polyol having an OH number of at least 100 mg KOH/g, to a rigid polyurethane foam obtainable by reacting this composition, to a process for producing such a rigid polyurethane foam, to the use of such a rigid polyurethane foam for insulation, especially for pipe insulation and also to a process for producing an insulated pipe.Type: ApplicationFiled: June 21, 2013Publication date: January 9, 2014Applicant: BASF SEInventors: Christof GRIESER-SCHMITZ, Gianpaolo Tomasi, Ludwig Windeler, Alex Popov, Carsten Ellersiek, Annika Halwe-Bommelmann
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Patent number: 8618337Abstract: The invention relates to a process for preparing polyether alcohols by reacting a) aromatic amines with b) alkylene oxides in the presence of c) a catalyst, wherein the alkylene oxide b) comprises at least 90% by weight, based on the weight of the component b), of propylene oxide and an amine is used as catalyst c).Type: GrantFiled: April 22, 2011Date of Patent: December 31, 2013Assignee: BASF SEInventors: Sirus Zarbakhsh, Markus Schuette, Marc Fricke
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Patent number: 8598247Abstract: A process is disclosed for preparing a elastomer by contacting under reaction conditions: a) an isocyanate component comprising an isocyanate-terminated prepolymer having an isocyanate (NCO) content of 10 to 30 weight percent where the prepolymer is the reaction product of a stoichiometric excess of one or more di- or poly-isocyanate compounds, collectively referred to hereinafter as isocyanate component, with a first polyol component; b) a second polyol component; and c) an effective amount of a blowing agent to provide a polyurethane elastomer with a density of from 200 to 1200 kg/m3; wherein a) and b) are used at an isocyanate index of from 85 to 115, and at least one of the first polyol composition and the second polyol composition contains at least one hydroxymethyl-containing polyester polyol.Type: GrantFiled: April 16, 2009Date of Patent: December 3, 2013Assignee: Dow Global Technologies LLCInventor: Giuseppe Vairo
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Patent number: 8598297Abstract: Prepolymers are prepared by a reaction of a polyisocyanate and a hydroxylmethyl containing polyester polyol derived from a fatty acid. The prepolymers can be prepared having isocyanate, hydroxyl, or a variety of other reactive functional groups. The prepolymers are useful in making polyurethanes and other polymers, or a crosslinking agents.Type: GrantFiled: October 24, 2005Date of Patent: December 3, 2013Assignee: Dow Global Technologies LLCInventors: Erdem Bedri, Debkumar Bhattacharjee, John N. Argyropoulos
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Patent number: 8592497Abstract: The invention relates to a process for the preparation of polyurethanes by reacting polyisocyanates a) with compounds having at least two hydrogen atoms reactive with isocyanate groups b), wherein a polyisocyanate a) used is at least one polyisocyanate ai) having an average functionality of greater than 2, a content of diisocyanates of not more than 2% by weight and a content of uretonimines of not more than 4% by weight, based in each case on the weight of the polyisocyanate ai).Type: GrantFiled: April 3, 2007Date of Patent: November 26, 2013Assignee: BASF AktiengesellschaftInventors: Hans-Juergen Reese, Imbridt Murrar, Ralf Fritz, Andres Cabrera, Birgit Magg
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Patent number: 8551201Abstract: Polyurethane composition based on a certain polyether and polyester prepolymer reaction mixture, wherein the composition is utilized in manufacturing chemical mechanical polishing/planarizing (CMP) pads. The CMP pads have low rebound and can dissipate irregular energy as well as stabilize polishing to yield improved uniformity and less dishing of the substrate.Type: GrantFiled: August 7, 2009Date of Patent: October 8, 2013Assignee: Praxair S.T. Technology, Inc.Inventors: Yong Zhang, David Huang, Lu Sun
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Publication number: 20130243986Abstract: A method of making a molded rigid polyurethane foam comprising injecting into a closed mold cavity a reaction mixture at a packing factor of 1.03 to 1.9, wherein the mold cavity is under a pressure of from 300 to 950 mbar, wherein the reaction mixture comprises an organic polyisocyanate, a polyol composition, a catalyst, optionally auxiliary substances and/or additives, and a chemical blowing agent component in an amount of from 1 to 5 weight percent based on the total weight of the components excluding polyisocyanate, the chemical blowing agent component comprising at least one chemical blowing agent, wherein the chemical blowing agent component is the sole blowing agent.Type: ApplicationFiled: November 30, 2011Publication date: September 19, 2013Applicant: DOW GLOBAL TECHNOLOGIES LLCInventors: Cecilia Girotti, Francesca Pignagnoli, Vanni Parenti
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Patent number: 8530535Abstract: A polishing pad generates very few scratches on a surface of a polishing object, and is excellent in planarization property. The polishing pad has a high polishing rate and is excellent in planarization property. The polishing pad grooves become very little clogged with abrasive grains or polishing swarf during polishing and, even when continuously used for a long period of time, the polishing rate is scarcely reduced.Type: GrantFiled: May 13, 2011Date of Patent: September 10, 2013Assignee: Toyo Tire & Rubber Co., Ltd.Inventors: Atsushi Kazuno, Kazuyuki Ogawa, Masahiko Nakamori, Takatoshi Yamada, Tetsuo Shimomura
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Publication number: 20130203880Abstract: This invention relates to polyurethane foams which exhibit decreased aldehyde emission, to a process of preparing these polyurethane foams, and to a method of decreasing aldehyde emissions in foams. The polyurethane foams herein additionally comprise a small quantity of a polyhydrazodicarbonamide dispersion polyol to the isocyanate-reactive component, or a trimerized hexamethylene diisocyanate to the polyisocyanate component.Type: ApplicationFiled: February 2, 2012Publication date: August 8, 2013Applicant: Bayer MaterialScience LLCInventors: Emmanuel George, Mark A. Koshute, Brian L. Neal, Carl Thompson, Adona Marcum
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Publication number: 20130203877Abstract: An object of the present invention is to inexpensively provide a method and device of producing a high viscosity polylactic acid composition, which composition is appropriate for foam molding having a high expansion ratio and is stable, and a foam molded article having a high expansion ratio formed of said high viscosity polylactic acid composition. A method of producing a polylactic acid foam molded article of the present invention which can achieve the above-described object is characterized by comprising a step of mechanically grinding a polylactic acid composition by applying a shear force, using a device equipped with an injection molding machine (B) or an extrusion molding machine (G), an orifice portion (S) and a foaming mold (P), in a foaming gas atmosphere in the orifice portion (S).Type: ApplicationFiled: March 29, 2011Publication date: August 8, 2013Inventors: Kosuke Uchiyama, Kazunori Tsuda, Tenya Suzuki
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Patent number: 8501828Abstract: The present invention provides processes for producing re-bonded polyurethane foam constructs that are useful in applications such as carpet underlayments. According to the invention, a tertiary amine is employed as a catalyst either alone, or preferably in combination with other catalysts in a binder which comprises an organic isocyanate and a polyol. Inclusion of a tertiary amine as a catalyst dramatically increases production throughput.Type: GrantFiled: August 11, 2005Date of Patent: August 6, 2013Assignee: Huntsman Petrochemical LLCInventors: Roger Hennington, Donald H. Ridgway, Robert A. Grigsby, Jr., Robert G. Sawitski, Jr., Jennifer K. Pratt
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Patent number: 8497316Abstract: It concerns a crosslinkable and foaming polyester-polyurethane resin moulding composition, comprising: an A component, comprising: A1) at least one poly-functional isocyanate compound, and A2) at least one free radical polymerization initiator a B component, comprising by weight: B1) 100 parts of at least one polyol resin comprising: —B11) 50 to 80 parts of at least one ethylenically unsaturated polyester polyol—B 12) 20 to 50 parts of at least one ethylenically unsaturated monomer, with, B11), being the reaction product of: a) an acid component comprising: a1) at least one ethylenically unsaturated diacid, and a2) at least one saturated diacid with a1/a2 molar ratio so varying to have an unsaturation content in B11) from 0.25/1 to 5/1, and, b) a diol component in excess with respect to component a) B2) from 0.01 to 1.Type: GrantFiled: September 29, 2008Date of Patent: July 30, 2013Assignee: CCP Composites UK LtdInventors: Paul Darby, Phil Dean
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Publication number: 20130184367Abstract: The invention relates to foamed lightfast polyurethane mouldings and to the use thereof.Type: ApplicationFiled: September 2, 2011Publication date: July 18, 2013Applicant: Bayer Intellectual Property GmbHInventors: Birgit Meyer Zu Berstenhorst, Reinhard Halpaap, Norbert Eisen, Uwe Pfeuffer
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Patent number: 8476328Abstract: A method for manufacturing a polishing pad that has high level of optical detection accuracy and is prevented from causing slurry leak from between the polishing region and the light-transmitting region includes preparing a cell-dispersed urethane composition by a mechanical foaming method; placing a light-transmitting region at a predetermined position on a face material or a belt conveyor, continuously discharging the cell-dispersed urethane composition onto part of the face material or the belt conveyor where the light-transmitting region is not placed; placing another face material or belt conveyor on the discharged cell-dispersed urethane composition; curing the cell-dispersed urethane composition to form a polishing region including a polyurethane foam, so that a polishing sheet is prepared; applying a coating composition containing an aliphatic and/or alicyclic polyisocyanate to one side of the polishing sheet and curing the coating composition to form water-impermeable film; and cutting the polishingType: GrantFiled: February 26, 2009Date of Patent: July 2, 2013Assignee: Toyo Tire & Rubber Co., LtdInventors: Junji Hirose, Takeshi Fukuda
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Publication number: 20130165544Abstract: The present invention pertains to the field of polyurethane, especially relates to an isocyanate-terminated prepolymer, the method for preparing the same and the use thereof. The present invention adjusts the reaction components and the ratios thereof to obtain an isocyanate-terminated prepolymer suitable for preparing flexible polyurethane foam under a relative low mold temperature. The method for preparing flexible polyurethane foam by using the isocyanate-terminated prepolymer provided in this present invention can reduce the mold temperature, production time and energy consumption, as well as to obtain a polyurethane flexible foam processing good physical and mechanical properties.Type: ApplicationFiled: February 15, 2013Publication date: June 27, 2013Applicant: Bayer Intellectual Property GmbHInventor: Bayer Intellectual Property GmhH
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Publication number: 20130158145Abstract: The present invention relates to the use of solvent-free low-monomer polyisocyanates based on araliphatic diisocyanates for the production of light- and weather-resistant polyurethane bodies having a high light refraction and low dispersion.Type: ApplicationFiled: July 15, 2011Publication date: June 20, 2013Applicant: BAYER INTELLECTUAL PROPERTY GMBHInventors: Hans-Josef Laas, Dorota Greszta-Franz, Reinhard Halpaap, Dieter Mager, Hans-Ulrich Meier-Westhues
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Patent number: 8466207Abstract: Disclosed is a method for making a polyurethane closed-cell foam material exhibiting a bulk density below 4 lbs/ft3 and high strength. The present embodiment uses the reaction product of a modified MDI and a sucrose/glycerine based polyether polyol resin wherein a small measured quantity of the polyol resin is “pre-reacted” with a larger quantity of the isocyanate in a defined ratio such that when the necessary remaining quantity of the polyol resin is added to the “pre-reacted” resin together with a tertiary amine catalyst and water as a blowing agent, the polymerization proceeds slowly enough to provide a stable foam body.Type: GrantFiled: February 27, 2007Date of Patent: June 18, 2013Assignee: Sandia CorporationInventors: Leroy L. Whinnery, Jr., Steven H. Goods, Dawn M. Skala, Craig C. Henderson, Patrick N. Keifer
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Patent number: 8465669Abstract: To obtain a non-particle-aggregation-type organic polymer monolith separation medium, there is provided a monolith separation medium comprising a skeletal phase and pores being continuous in the form of three-dimensional network, which skeletal phase on its surface has a functional group permitting introduction of a new functional group. The skeletal phase has a non-particle-aggregation-type co-continuous structure having an average diameter of submicron to micrometer size, and is constituted of an addition polymer from an epoxy compound of bi- or higher functionality and an amine compound of bi- or higher functionality. Further, the skeletal phase is enriched in organic matter and does not contain any carbon atoms derived from aromatic series.Type: GrantFiled: August 3, 2011Date of Patent: June 18, 2013Assignee: Shimadzu CorporationInventor: Ken Hosoya
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Patent number: 8455101Abstract: The present invention relates to a process for producing a polyurethane lamination resin, by mixing a) an isocyanate prepolymer based on diphenylmethane diisocyanate having a difunctionally started polyether, b) polyphenylene polymethylene polyisocyanate, c) trifunctionally started polyetherpolyol with an average molar mass of from 350 to 600 g/mol, d) a thermoactivatable capped catalyst, e) if appropriate, chain extender and/or crosslinking agent, f) if appropriate, water-absorbent substances, and g) if appropriate, other additives to give the polyurethane lamination resin. The present invention further relates to a polyurethane lamination resin, obtainable via a process of this type, and to the use of this type of polyurethane lamination resin for producing laminates, and also to skis or snowboards, comprising this type of laminate.Type: GrantFiled: October 22, 2008Date of Patent: June 4, 2013Assignee: BASF SEInventors: Hans-Juergen Reese, Bert Neuhaus, Silvio Holl, Guenter Taenny
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Publication number: 20130109774Abstract: The invention relates to a method for producing hydrophilic, aliphatic polyurethane foams having low bulk density. The invention further relates to hydrophilic, aliphatic polyurethane foams that can be obtained according to the method, and to the use thereof as a wound dressing, incontinence product, or as a cosmetic article.Type: ApplicationFiled: June 20, 2011Publication date: May 2, 2013Applicant: BAYER INTELLECTUAL PROPERTY GMBHInventors: Sebastian Dörr, Meike Niesten
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Publication number: 20130085193Abstract: A composition and method for producing a tertiary amine is disclosed. The tertiary amine is contacted with an inert gas. The inert gas is nitrogen or more preferably argon. The amine composition is useful in producing polyurethane foam with lower levels of chemical emissions particularly lower emissions of toxic chemicals.Type: ApplicationFiled: October 2, 2012Publication date: April 4, 2013Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Juan Jesus Burdeniuc, Jennifer Elizabeth Antoline Al-Rashid, Andrew Wilson Wang, Diana Sue Dunn, You-Moon Jeon, Jane Garrett Kniss, Stephan Hermann Wendel