N=c=x Reactant Having At Least Two C-nh-c(=x)- Groups, E.g., Prepolymers, Etc. Patents (Class 521/159)
  • Patent number: 7795322
    Abstract: A prepolymer having an NCO content of less than 10%, based on the reaction of (a) diisocyanate with (b) polyether alcohol, the (b) polyether alcohol comprising (b1) and (b2) and/or (b3) with the following meanings for (b1), (b2) and (b3): (b1) polytetrahydrofuran having a molecular weight of from 1800 to 2100 g/mol and (b2) polyether alcohol having a molecular weight of from 500 to 7000 g/mol, based on ethylene oxide and/or propylene oxide, and/or (b3) polytetrahydrofuran having a molecular weight of from 800 to 1200 g/mol.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: September 14, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Elke Marten, Elke Weigelt, Anand G. Huprikar, Michael Strauβ
  • Patent number: 7790778
    Abstract: Isocyanate-terminated prepolymer having an NCO-value of 5-30% by weight and being the reaction product of an excessive amount of diphenylmethane diisocyanate comprising at least 80% by weight of 4,4?-diphenylmethane diisocyanate and a polyoxyethylene-polyoxypropylene polyol having an average molecular weight of 2000-10000, an average nominal hydroxy functionality of 2-6, an oxyethylene content of 21-45% by weight and a structure of the type -PO-PO/EO-EO wherein the PO block comprises 60-90% of the PO and the ratio of tipped EO:random is 3:1 to 1:3, and a process for preparing a flexible foam by reacting in a mould and at an index of 70-120, the above prepolymer or a composition comprising this prepolymer and b1) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, and a oxyethylene (EO) content of more than 50% by weight; and optionally b2) a polyoxyethylene-polyoxypropylene polyol, having an average nominal hydroxy functionality of 2-6, an EO content of between
    Type: Grant
    Filed: January 31, 2005
    Date of Patent: September 7, 2010
    Assignee: Huntsman International LLC
    Inventors: Koon Yeow Chan, Eric Huygens, Herman Eugene Germain Moureau, Anja Vanhalle, Jianming Yu
  • Publication number: 20100210748
    Abstract: The present invention relates to reactive polyurethane compositions having only small amounts of free, low molecular weight diisocyanates before and after crosslinking, and to the production thereof and the use thereof in reactive one- and two-component adhesives/sealants, bonding foams, encapsulating compounds and in flexible, rigid and integral foams.
    Type: Application
    Filed: January 15, 2010
    Publication date: August 19, 2010
    Applicant: Bayer MaterialScience AG
    Inventors: Marc Leimenstoll, Christos Karafilidis, Matthias Wintermantel, Peter Reichert, Lutz Brassat
  • Patent number: 7776934
    Abstract: Foamable one-part polyurethane compositions contain a high functionality quasi-prepolymer and a hydrated salt. The foamable compositions are capable of expanding to 1000% or more of their original volume to form a low density, stable foam. The compositions are particularly useful as foam-in-place thermal or sound insulation materials, especially in vehicle applications.
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: August 17, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Huzeir Lekovic, Ali El-Khatib
  • Patent number: 7772352
    Abstract: Absorbable polyurethanes, polyamides and polyester urethanes prepared from at least one compound selected from: or the diamines and diisocyanates thereof, wherein each X represents a member independently selected from —CH2COO— (glycolic acid moiety), —CH(CH3)COO— (lactic acid moiety), —CH2CH2OCH2COO— (dioxanone), —CH2CH2CH2CH2CH2COO— (caprolactone moiety), —(CH2)yCOO— where y is one of the numbers 2, 3, 4 or 6-24 inclusive, and —(CH2CH2O)z?CH2COO— where z? is an integer between 2 and 24, inclusive; each Y represents a member independently selected from —COCH2O— (glycolic ester moiety), —COCH(CH3)O— (lactic ester moiety), —COCH2OCH2CH2O— (dioxanone ester), —COCH2CH2CH2CH2CH2O— (caprolactone ester), —CO(CH2)mO— where m is an integer between 2, 3, 4 or 6-24 inclusive, —COCH2O(CH2CH2O)n— where n is an integer between 2 and 24, inclusive; R? is hydrogen, benzyl or an alkyl group, the alkyl group being either straight-chained or branched; p is an integer between 1 and 4, inclusive; and Rn represents one or more
    Type: Grant
    Filed: October 20, 2005
    Date of Patent: August 10, 2010
    Assignee: Bezwada Biomedical LLC
    Inventor: Rao S. Bezwada
  • Publication number: 20100190879
    Abstract: Compositions according to the invention comprise water, a polyurethane or poly(meth)acrylate having perfluoroalkyl groups and a special siloxane. The treatment of fiber materials, in particular of nonwovens made of polypropylene, leads to articles which have oil-, water- and alcohol-repellency properties and can be used in the medical sector.
    Type: Application
    Filed: September 11, 2008
    Publication date: July 29, 2010
    Applicant: Huntsman Textile Effects (Germany) GmbH
    Inventors: Simpert Ludemann, Rule Niederstadt, Jurgen Riedmann, Daniel Wilson
  • Publication number: 20100184878
    Abstract: The invention relates to polyurethane foams comprising oligomeric polyols. In embodiments of the invention, the polyurethane foams comprise the reaction product of: (a) a polyisocyanate; and (b) an active-hydrogen containing composition comprising an oligomeric polyol having a hydroxyl number of about 45 to about 65 mg KOH/g, a number average hydroxyl functionality (Fn) of less than about 2.7, and about 40% weight or greater oligomers. The polyurethane foams of the invention may be slabstock foams or molded foams. Also disclosed are low odor polyols and polyurethane compositions.
    Type: Application
    Filed: March 31, 2010
    Publication date: July 22, 2010
    Applicant: CARGILL, INCORPORATED
    Inventors: Timothy W. Abraham, Jack A. Carter, Dimitri Dounis, Jeff Malsam
  • Patent number: 7750058
    Abstract: The present invention is directed to a process for preparing water-blown rigid polyurethane foams having at least an 80% closed-cell content which involves reacting a) at least one polyol mixture which is composed of (i) at least one polymer polyol; (ii) at least one polyol having a hydroxyl value within the range of from about 200 to about 800; and (iii) optionally, at least one polyol having a hydroxyl value within the range of from about 25 to about 115; with b) at least one polymeric isocyanate and/or a prepolymer thereof; in the presence of c) optionally, at least one catalyst; d) water; and e) optionally, at least one additive or auxiliary agent. The present invention is also directed to the closed-cell water blown rigid polyurethane foams produced by the process of the present invention. The invention is further directed to a polyurethane-foam forming mixture which is used to produce the water-blown rigid polyurethane foams of the present invention.
    Type: Grant
    Filed: September 30, 2008
    Date of Patent: July 6, 2010
    Assignee: Bayer MaterialScience LLC
    Inventors: Karl W. Haider, Neil H. Nodelman, John P. Forsythe, Brian R. Suddaby
  • Publication number: 20100160473
    Abstract: A flexible polyurethane foam comprises the reaction product of an isocyanate component and an isocyanate-reactive component in the presence of a blowing agent. The isocyanate component comprises a polymeric diphenylmethane diisocyanate component and a monomeric diphenylmethane diisocyanate component. The monomeric diphenylmethane diisocyanate component comprises 2,4?-diphenylmethane diisocyanate and 4,4?-diphenylmethane diisocyanate. The isocyanate-reactive component comprises a polyether polyol having a molecular weight of from about 700 to about 20,000 and a plurality of terminal caps which are substantially free of ethylene oxide groups. The flexible polyurethane foam is substantially free of supplemental flame retardant additives and exhibits flame retardance under flammability tests according to California Technical Bulletin 117 regulations.
    Type: Application
    Filed: February 24, 2010
    Publication date: June 24, 2010
    Inventors: Raymond A. Neff, Theodore M. Smiecinski
  • Publication number: 20100130631
    Abstract: Polyester polyol compositions have a low viscosity and are suited for the production of rigid polyurethane foams. Compositions for rigid polyurethane foams contain the polyester polyol compositions. Rigid polyurethane foams are produced therefrom. A polyester polyol composition is obtained by: a step (I) in which a dibasic acid compound (A) is reacted with a trihydric or higher polyhydric alcohol (a compound (B)); and a step (II) in which the reaction mixture from the step (I) is reacted with a hydroxycarboxylic acid compound (C); at least one compound (C) being a compound (C?) selected from the group consisting of ricinoleic acid compounds and 12-hydroxystearic acid compounds; the polyester polyol composition having a hydroxyl value in the range of 250 to 550 mg KOH/g and an average functionality of 3 to 8.
    Type: Application
    Filed: April 21, 2008
    Publication date: May 27, 2010
    Inventors: Atsushi MIYATA, Tomoki TSUTSUI, Nobuhito KOGA, Masahiro SASAKI, Shinsuke MATSUMOTO, Kazuhiko OHKUBO
  • Publication number: 20100130632
    Abstract: Chemically blown polyurethane elastomeric closed cell foams which exhibit physical characteristics similar to those of neoprene foams are disclosed. The foams are prepared by blending a diisocyanate or polyisocyanate prepolymer, a polyol, such as a polyether polyol or polyester polyol, an amine catalyst, a chemical blowing agent, and optionally a C2-10 diol such as butanediol, and allowing the compounds to cure to form a polymeric material. The polymer is initially heated to a temperature at or above its softening temperature, but below the temperature at which the blowing agent becomes activated, to soften the polymer. The softened polymer is then heated to a temperature at which the blowing agent is activated. The resulting polymer foam includes closed cells, but has less rigidity than conventional closed cell foams. The foam can be used in various applications, for example, in diving suits and orthotic brace materials.
    Type: Application
    Filed: June 26, 2009
    Publication date: May 27, 2010
    Inventor: Eric Scott (Rick) Speas
  • Patent number: 7687548
    Abstract: Process for preparing a moulded elastomeric polyurethane material having an overall density of 200-1000 kg/m3, preferably of 200-500 kg/m3, and a compression load at 40% deflection of at least 25 kPa by reacting in a closed mould an isocyanate terminated prepolymer, having an NCO-value of 5-15% by weight and which is the reaction product of a polyisocyanate and a polyether polyol having an average nominal functionality of 2-6, an average equivalent weight of 500-5000 and an oxyethylene content of 50-90% by weight, and water. The elastomer obtained is claimed as well.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: March 30, 2010
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Johan Indesteege
  • Patent number: 7678936
    Abstract: A method of making an isocyanato terminated precursor for polyurethane is disclosed. The method comprises heating an isocyanate containing about two or more isocyanato groups per molecule at a temperature of up to 80 degrees Celsius and at a pressure of about 1 atmosphere. The method further comprises mixing a modified vegetable oil comprising about two or more hydroxyl groups per molecule with the isocyanate at a molar equivalent ratio of at least 2:1 isocyanate to vegetable oil for a predetermined time period to form the isocyanato terminated precursor.
    Type: Grant
    Filed: August 21, 2007
    Date of Patent: March 16, 2010
    Assignee: Lear Corporation
    Inventors: Thomas N. Jones, Edmund J. Madaj
  • Patent number: 7666919
    Abstract: A composition for making a polyurethane foam includes a non-fugitive tertiary amine urethane catalyst and an aromatic diacid ester diol or substituted carbamate thereof. Foams prepared from the reaction of a polyol and an organic isocyanate in the presence of these ingredients show excellent resistance to deterioration of physical properties upon humid ageing.
    Type: Grant
    Filed: March 14, 2006
    Date of Patent: February 23, 2010
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Juan Jesus Burdeniuc, Stephan Herman Wendel, Renee J. Keller
  • Publication number: 20100029798
    Abstract: A polyurethane elastic memory material that emits nano-negative ion far infrared rays and a method for preparing the same is disclosed. A nano-negative ion far infrared ray emitting additive that belongs to the Lianfuya Established Series is added to polyester and/or polyether polyol to create a polyurethane elastic memory foam material that emits negative ions at a rate of 3,000 negative ions/cm3 or more. The negative ions and far infrared rays provide for a positive effect in the treatment of many ailments.
    Type: Application
    Filed: July 28, 2009
    Publication date: February 4, 2010
    Inventor: Kwok Wah Yau
  • Publication number: 20100015893
    Abstract: An object of the invention is to provide a polishing pad having excellent planarization performance and wear resistance and to provide a method for manufacture thereof. The invention is directed to a polishing pad including a polishing layer including a polyurethane foam having fine cells, wherein the polyurethane foam is a cured product of a reaction of (1) an isocyanate-terminated prepolymer (A) that is capable of reacting with 4,4?-methylenebis(o-chloroaniline) to form a non-foamed polyurethane having a tan ? peak temperature of 100° C. or more, (2) an isocyanate-terminated prepolymer (B) that is capable of reacting with 4,4?-methylenebis(o-chloroaniline) to form a non-foamed polyurethane having a tan ? peak temperature of 40° C. or less, and (3) 4,4?-methylenebis(o-chloroaniline), and the isocyanate-terminated prepolymers (A) and (B) are mixed in an (A)/(B) ratio of 50/50 to 90/10 (by wt %).
    Type: Application
    Filed: August 22, 2007
    Publication date: January 21, 2010
    Applicant: Toyo Tire & Rubber Co., Ltd.
    Inventors: Atsushi Kazuno, Tetsuo Shimomura, Yoshiyuki Nakai, Kazuyuki Ogawa, Tsuyoshi Kimura
  • Publication number: 20090312451
    Abstract: The present invention relates to an ethylenically unsaturated prepolymer comprising at least one ending X which reacts by condensation chosen from hydroxyl and/or amine or free isocyanate groups and optionally an ending X? having ethylenic unsaturation, the prepolymer being the reaction product of the following components A and B: A) a first component A comprising the following mixture: i) at least one first ethylenically unsaturated resin carrying specific hydroxyl and/or amine reactive endings, and/or ii) optionally at least one second resin, other than the resin i), chosen from: ethylenically unsaturated hydroxylated resins, and/or hydroxylated and/or aminated saturated resins, and/or iii) optionally at least one third reactive saturated resin, iv) optionally at least one unsaturated monoalcohol up to 30% in equivalents of the OH+NH2 total, B) a second component B comprising at least one polyisocyanate with a functionality equal to 2 or greater than 2, A and B being in proportions which make it pos
    Type: Application
    Filed: July 4, 2007
    Publication date: December 17, 2009
    Inventors: Patrick Belliard, Jérôme Mazajczyk, Roland Delory, Guillaume Cledat, Francis Verdiere, Serge Herman
  • Publication number: 20090306238
    Abstract: Process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein the compounds having at least two hydrogen atoms which are reactive toward isocyanate groups comprise at least one polyether alcohol bi) which can be prepared by reacting aromatic amines with ethylene oxide and propylene oxide, with firstly propylene oxide and then ethylene oxide or a mixture of ethylene oxide and propylene oxide being added on in a first process step and the remaining amount of propylene oxide being added on in a second process step using a basic catalyst.
    Type: Application
    Filed: November 5, 2007
    Publication date: December 10, 2009
    Applicant: BASF SE
    Inventors: Stefan Dinsch, Juergen Winkler, Gerd Hoeppner, Holger Seifert
  • Publication number: 20090292035
    Abstract: A cellular foamed article is provided, including a polymeric foam material and a micro- or nano-sized reinforcement material embedded in the foam material. Also, methods of making a reinforced cellular foamed articles are provided, including preparing a dispersion comprising a reinforcement material and a polymer precursor; processing the reinforcement material so that it has a volume average length ranging from about average cross sectional diameter of from about 1 to about 500 nm and a volume average length of from about 10 nm to about 10 ?m; reacting the polymer precursor to form a foamable polymer; and foaming the foamable polymer.
    Type: Application
    Filed: May 26, 2009
    Publication date: November 26, 2009
    Inventor: Edmund Bernard Semmes
  • Publication number: 20090286897
    Abstract: Process for making a slabstock, visco-elastic, flexible, polyurethane foam which process comprises reacting a polyisocyanate and a polyol at an index of 60-95 and using a blowing agent, wherein 5-50 and preferably 10-40% by weight of the polyol used is castor oil. The foams and a polyol composition are claimed as well.
    Type: Application
    Filed: June 12, 2007
    Publication date: November 19, 2009
    Applicant: Huntsman International LLC
    Inventors: Kris Andries, Johan Antoine Stefaan
  • Publication number: 20090286896
    Abstract: A polyol includes the reaction product of an epoxidized oil and an organic acid. The epoxidized oil and the organic acid are reacted in the presence of a Lewis base catalyst including at least one of a phosphorous atom or a nitrogen atom. The polyol is formed by a method that includes the step of reacting the epoxidized oil with the organic acid in the presence of the Lewis base catalyst.
    Type: Application
    Filed: May 15, 2008
    Publication date: November 19, 2009
    Inventors: Yeonsuk Roh, Rajesh Kumar, Cheng-Le Zhao, David Kaczan, Theodore M. Smiecinski
  • Patent number: 7615580
    Abstract: A composition for making a polyurethane foam includes a non-fugitive tertiary amine urethane catalyst and an ester alcohol or substituted carbamate thereof. Foams prepared from the reaction of a polyol and an organic isocyanate in the presence of these ingredients show excellent resistance to deterioration of physical properties upon humid ageing.
    Type: Grant
    Filed: June 15, 2007
    Date of Patent: November 10, 2009
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Juan Jesus Burdeniuc, Stephan Herman Wendel, Renée Jo Keller
  • Patent number: 7612120
    Abstract: A method for producing polyisocyanurate insulation foams, the method comprising contacting an A-side stream of reactants that includes an isocyanate with a B-side stream of reactants that include a polyol and a blowing agent, where the blowing agent includes isopentane and n-pentane in a substantial absence of cyclopentane.
    Type: Grant
    Filed: August 13, 2003
    Date of Patent: November 3, 2009
    Inventor: John B. Letts
  • Publication number: 20090258959
    Abstract: Disclosed is a method of preparing MDI-based polyurethane polymer having a density in a range of between 25 and 80 kg/m3. The method includes the steps of a) mixing a first main raw material including methylene diphenyl diisocyanate polymer and carbonized methylene diphenyl diisocyanate, a second main raw material including 5 to 20 parts by weight of polyether polyol having a molecular weight of 3000 and 95 to 80 parts by weight of polyether polyol having a molecular weight of 5000, and an auxiliary material including a catalyst, a foam control agent, a crosslinking agent, a chain extender and water, and b) foaming the mixture of step a). In step a), the ratio by weight of the first main raw material to the second main raw material is in a range of 1:1.2 to 1:2.
    Type: Application
    Filed: August 4, 2008
    Publication date: October 15, 2009
    Inventors: Cheng-Chieh CHANG, Chin-Bing CHANG
  • Publication number: 20090253819
    Abstract: The invention relates to a process for the preparation of polyurethanes by reacting polyisocyanates a) with compounds having at least two hydrogen atoms reactive with isocyanate groups b), wherein a polyisocyanate a) used is at least one polyisocyanate ai) having an average functionality of greater than 2, a content of diisocyanates of not more than 2% by weight and a content of uretonimines of not more than 4% by weight, based in each case on the weight of the polyisocyanate ai).
    Type: Application
    Filed: April 3, 2007
    Publication date: October 8, 2009
    Applicant: BASF SE
    Inventors: Hans-Jürgen Reese, Imbridt Murrar, Ralf Fritz, Andres Cabrera, Birgit Magg
  • Publication number: 20090253816
    Abstract: Composition for preparing a biodegradable polyurethane-based foam and a biodegradable polyurethane foam, comprising mixtures based on poly(hydroxybutyrate) polymer, polyols of renewable source, isocyanates and additives, with the object of preparing biodegradable polyurethane foams. In the process, the poly(hydroxybutyrate) plus the polyol, the isocyanate and the additives are previously mixed in specific mixers; once the homogenization is reached, the mixture is poured in mold for growing. After curing, the resulting product presents foam characteristics, with its density, toughness and cell size varying according to the proportion of the reagents and allowing the manufacture of several products.
    Type: Application
    Filed: February 23, 2007
    Publication date: October 8, 2009
    Applicants: PHB INDUSTRIAL S.A., KEHL INDUSTRIA E COMERCIO LTDA
    Inventors: Jefter Fernandes Nascimento, Wagner Mauricio Pachekoski, Jose Ricardo De Lello Vicino
  • Publication number: 20090247658
    Abstract: A polyurethane and a polyurethane-urea are provided which are extremely useful in high-performance polyurethane elastomer applications such as elastic polyurethane fibers, synthetic/artificial leathers, and TPUs. Disclosed are: a process for producing a polyurethane from (a) a polyether polyol obtained by a dehydration condensation reaction of a polyol and containing a 1,3-propanediol unit, (b) a polyisocyanate compound, and (c) a chain extender, wherein the polyurethane is produced in the co-presence of an aprotic polar solvent; a polyurethane produced by the process for polyurethane production; and a film and a fiber each comprising the polyurethane.
    Type: Application
    Filed: July 11, 2007
    Publication date: October 1, 2009
    Applicant: Mitsubishi Chemcial
    Inventors: Mitsuharu Kobayashi, Youko Fukuuchi, Takanori Taniguchi
  • Publication number: 20090247659
    Abstract: The invention described herein relates to an essentially closed-cell two-component polyurethane foam containing an pesticide, which upon curing provides a barrier to insect infestation.
    Type: Application
    Filed: March 27, 2009
    Publication date: October 1, 2009
    Applicant: FOMO PRODUCTS, INC.
    Inventor: Anthony J. Taylor
  • Publication number: 20090169486
    Abstract: The present invention relates to biomedical foam articles for the wound sector which are formed by spraying a polymeric dispersion onto a wound. The polymeric dispersion being sprayed onto a wound surface forms a three-dimensional body which conforms to the spatial shape of the wound and which, as well as covering the wound surface, ensures a complete and accurately fitted packing of the wound in the depth dimension as well as the other dimensions. The biomedical foam articles of the present invention are particularly useful for treating chronic wounds.
    Type: Application
    Filed: April 5, 2007
    Publication date: July 2, 2009
    Applicant: Bayer Business Services GmbH
    Inventors: Melita Dietze, Burkhard Fugmann, Michael Mager, Thorsten Rische, Michael Heckes, Daniel Rudhardt, Rolf Gertzmann
  • Publication number: 20090170974
    Abstract: The invention is directed to a polymer foam precursor composition comprising 1 to 60%, preferably 5 to 30% by weight, of a biodiesel obtained by transesterification of vegetable oils. The polymer foam is advantageously a polyurethane foam and the biodiesel is a mixture of methyl and or ethyl fatty acid esters. The biodiesel is a latent hardener and/or extender and/or liquid filler The composition is advantageously used in pressurized vessel or aerosol type cans.
    Type: Application
    Filed: December 14, 2006
    Publication date: July 2, 2009
    Inventors: Aster De Schrijver, Joao Carlos Moura Bordado
  • Patent number: 7550517
    Abstract: Foamable mixtures of excellent quality and which are isocyanate free are prepared from silane-terminated prepolymers in which a proportion of the silane end groups are replaced by non-polar organic groups. As a result, the prepolymers have much greater hydrocarbon blowing agent compatibility.
    Type: Grant
    Filed: March 4, 2004
    Date of Patent: June 23, 2009
    Assignee: Wacker Chemie AG
    Inventors: Volker Stanjek, Richard Weidner
  • Patent number: 7538154
    Abstract: The invention provides aqueous preparations having soft-feel properties, foams obtainable by mechanically foaming these preparations, and soft-feel coatings based on the foams. The preparations comprise aqueous polyurethane-polyurea dispersions, hydroxy-functional, aqueous or water-dilutable binders, polyisocyanates which may have been hydrophilically modified, and foam stabilizers.
    Type: Grant
    Filed: October 6, 2005
    Date of Patent: May 26, 2009
    Assignee: Bayer MaterialScience AG
    Inventors: Torsten Pohl, Uwe Klippert, Thomas Münzmay, Frank Kobor
  • Publication number: 20090062414
    Abstract: A solid product formed by polymerizing a urethane prepolymer in the presence of a curative has a Bashore rebound that is less than about 38%. Preferably, the urethane prepolymer is an aliphatic isocyanate polyether prepolymer and the curative includes an aromatic diamine and a triol. To form a microcellular polyurethane material, the urethane prepolymer is frothed with inert gas, in the presence of a surfactant, then cured. The polyurethane can by employed to form highly damping CMP pads that have low rebound and can dissipate irregular energy and stabilize polishing to yield improved uniformity and less dishing.
    Type: Application
    Filed: August 28, 2007
    Publication date: March 5, 2009
    Inventors: David Picheng Huang, Ming Zhou, Timothy Dale Moser
  • Patent number: 7479530
    Abstract: A polymer comprising one or more macromonomer units selected from the group consisting of polysiloxane, perfluoroalkylpolyether (PFPE), fluorinated poly(meth)acrylate, polyalkyl (meth)acrylate, polyolefin and fluorinated polyolefin, and one or more charged units (such as an anionic, cationic or zwitter-ionic monomer), formed from a polymerization medium containing an aqueous solution of charged units and use of this polymer as an intraocular lens for the implantation into or onto the cornea. Another aspects relates to a process for coating the above polymer with an adhesive comprising covalently coupling co-reactive surface functional groups of a natural or synthetic polymer with functional groups present (or introduced) on the surface of the macromonomer containing polymer, followed by covalently coupling a multifunctionally activated compound having at least one functional group that is co-reactive to the reactive groups of the natural or synthetic polymer.
    Type: Grant
    Filed: May 21, 2003
    Date of Patent: January 20, 2009
    Assignee: Commonwealth Scientific and Industrial Research Organisation
    Inventors: Timothy Charles Hughes, Grace Yim Ngan Chan
  • Publication number: 20090018480
    Abstract: The present invention provides novel polyurethane-based wound dressing foams, obtained by foaming and curing silane-terminated polyurethanes.
    Type: Application
    Filed: July 9, 2008
    Publication date: January 15, 2009
    Applicants: Bayer MaterialScience AG, Bayer Innovation GmbH
    Inventors: Michael Mager, Michael Ludewig, Mathias Matner, Melita Dietze, Burkhard Fugmann
  • Publication number: 20080319096
    Abstract: The invention relates to polymer-modified polyisocyanates and to polyurethanes prepared therefrom, and to their use in the production of polyurethane molded bodies. The polyisocyanates are modified with thermoplastic vinyl polymers having a number average molecular weight of from 15 to 90 kg/mol.
    Type: Application
    Filed: July 30, 2008
    Publication date: December 25, 2008
    Inventors: Eduard Mayer, Erhard Michels, Helmut Meyer, Klaus Pleiss
  • Publication number: 20080300335
    Abstract: The invention relates to a process for producing viscoelastic flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, c) blowing agents, wherein the compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b) comprise b1) from 70 to 10 parts by weight of at least one polyether alcohol consisting of exclusively polyoxypropylene units or polyoxypropylene units and not more than 20% by weight, based on the total weight of the alkylene oxides used, of polyoxyethylene units in the polyether chain and having a nominal functionality of from 3 to 6 and a hydroxyl number in the range from 100 to 300 mg KOH/g, b2) from 10 to 70 parts by weight of at least one polyetherol consisting of exclusively polyoxypropylene units or polyoxypropylene units and not more than 20% by weight, based on the total amount of alkylene oxides used, of polyoxyethylene units in the polyether chain and having
    Type: Application
    Filed: November 30, 2006
    Publication date: December 4, 2008
    Applicant: BASF SE
    Inventors: Stephan Göttke, Heinz-Dieter Lutter, Berend Eling, Steven Edward Wujcik
  • Publication number: 20080269369
    Abstract: In one of its aspects, the present invention relates to foamed isocyanate-based polymer derived from a reaction mixture comprising an isocyanate, an active hydrogen-containing compound, a dendritic macromolecule and a blowing agent; wherein at least a 15% by weight of the dendritic macromolecule may be mixed with a polyether polyol having an OH number less than about 40 mg KOH/g to form a stable liquid at 23° C. The dendritic macromolecule confers advantageous load building characteristics to the foamed isocyanate-based polymer and may be used to partially or fully displace the use of conventional copolymer polyols used. A process for production of a foam isocyanate-based polymer and a process for conferring loading building properties to a foamed isocyanate-based polymer are also described.
    Type: Application
    Filed: June 30, 2008
    Publication date: October 30, 2008
    Applicant: WOODBRIDGE FOAM CORPORATION
    Inventors: Jeffrey D. van Heuman, Paul V. Farkas, Romeo Stanciu
  • Publication number: 20080242755
    Abstract: The polishing pad is suitable for planarizing at least one of semiconductor, optical and magnetic substrates. The polishing pad includes a cast polyurethane polymeric material formed with an isocyanate-terminated reaction product formed from a prepolymer reaction of a prepolymer polyol and a polyfunctional isocyanate. The isocyanate-terminated reaction product has 4.5 to 8.7 weight percent unreacted NCO; and the isocyanate-terminated reaction product is cured with a curative agent selected from the group comprising curative polyamines, curative polyols, curative alcoholamines and mixtures thereof. The polishing pad contains at least 0.1 volume percent filler or porosity.
    Type: Application
    Filed: June 4, 2008
    Publication date: October 2, 2008
    Inventor: Mary Jo Kulp
  • Patent number: 7414080
    Abstract: The polishing pad is suitable for planarizing at least one of semiconductor, optical and magnetic substrates. The polishing pad includes a cast polyurethane polymeric material formed with an isocyanate-terminated reaction product formed from a prepolymer reaction of a prepolymer polyol and a polyfunctional isocyanate. The isocyanate-terminated section product has 4.5 to 8.7 weight percent unreacted NCO; and the isocyanate-terminated reaction product is cured with a curative agent selected from the group comprising curative polyamines, curative polyols, curative alcoholamines and mixtures thereof. The polishing pad contains at least 0.1 volume percent filler or porosity.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: August 19, 2008
    Assignee: Materials CMP Holdings, Inc.
    Inventor: Mary Jo Kulp
  • Publication number: 20080164112
    Abstract: A cylindrical molding based on cellular polyurethane elastomers having a density according to DIN EN ISO 845 of from 300 to 900 kg/m3, a tensile strength according to DIN EN ISO 1798 of ?2.
    Type: Application
    Filed: February 21, 2006
    Publication date: July 10, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Elke Marten, Andreas Heidemann, Markus Schutte, Michael Strauss, Heinrich Bollmann, Ralf Hansen
  • Publication number: 20080161440
    Abstract: A prepolymer having an NCO content of less than 10%, based on the reaction of (a) diisocyanate with (b) polyether alcohol, the (b) polyether alcohol comprising (b1) and (b2) and/or (b3) with the following meanings for (b1), (b2) and (b3): (b1) polytetrahydrofuran having a molecular weight of from 1800 to 2100 g/mol and (b2) polyether alcohol having a molecular weight of from 500 to 7000 g/mol, based on ethylene oxide and/or propylene oxide, and/or (b3) polytetrahydrofuran having a molecular weight of from 800 to 1200 g/mol.
    Type: Application
    Filed: March 8, 2006
    Publication date: July 3, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Elke Marten, Elke Weigelt, Anand G. Huprikar, Michael Strauss
  • Patent number: 7393879
    Abstract: A method for producing a novel silicone foam by reaction of a polyisocyanate with a silicone oligomer having a plurality of functional end groups with active hydrogens, optionally in the presence of fire-retardants, under foam forming conditions which creates a new silicone foam for use in items such as residential upholstered furniture industry, seat cushions and bedding etc., and specifically for use in applications that require, high resilience and fire-retardant properties such as aircraft and surface transportation seat cushioning, military and shipboard mattresses etc.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: July 1, 2008
    Assignee: Chestnut Ridge Foam, Inc.
    Inventors: Jiri E. Kresta, David Munoz Rojas, Ramon Moliner, Chandrasiri Jayakody, Dan Myers
  • Patent number: 7378454
    Abstract: A polyurethane composition containing solid beads dispersed therein, is formed of a microcellular polyurethane foam, and the composition has a storage modulus of elasticity at 40° C. of 270 MPa or more as measured by means of a dynamic elasticity measuring device. Another polyurethane composition of this invention contains solid beads dispersed therein, that are capable of swelling with or are soluble in an aqueous medium. The former composition has excellent flattening capability, and the latter composition can provide a polished surface which combines good flatness and good uniformity and can also reduce scratches on the surface.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: May 27, 2008
    Assignee: Toyo Tire & Rubber Co., Ltd.
    Inventors: Takashi Masui, Masahiko Nakamori, Takatoshi Yamada, Koichi Ono, Kazuyuki Ogawa, Atsushi Kazuno, Hiroshi Seyanagi
  • Patent number: 7339020
    Abstract: High-functionality polyisocyanates are prepared by a process which comprises (i) preparation of an addition product (A) which contains one group which is reactive toward isocyanate and at least two isocyanate groups by reacting (a) a diisocyanate or polyisocyanate I with (b1) compounds having at least three groups which are reactive toward isocyanate or (b2) compounds containing two groups which are reactive toward isocyanate or mixtures of (b1) and (b2), where at least one of the components (a) or (b) has functional groups having differing reactivities toward the functional groups of the other component and the reaction ratio is selected so that the addition product (A) contains an average of one group which is reactive toward isocyanate, (ii) if desired, intermolecular addition reaction of the addition product (A) to form a polyaddition product (P) containing an average of one group which is reactive toward isocyanate and an average of more than two isocyanate groups, and (iii) reaction of the addition
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: March 4, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Bruchmann, Hans Renz, Rainer Königer, Ulrike Ehe, Ulrich Treuling, Rudolf Müller-Mall
  • Patent number: 7307136
    Abstract: A polyisocyanate-based elastomer having a ratio of the storage modulus (E?) at 20° C. and the storage modulus (E?) at 120° C. of between 0.75 and 1.5, a tan ? at 100° C. of less than 0.1 and a maximum value of the tan ? of more than 0.8, the tan ? being the ratio of the loss modulus (E?) and the storage modulus (E?).
    Type: Grant
    Filed: February 4, 2002
    Date of Patent: December 11, 2007
    Assignee: Huntsman International LLC
    Inventors: Gerhard Jozef Bleys, Alan James Hamilton, Jan Willem Leenslag
  • Patent number: 7238730
    Abstract: The subject invention provides a viscoelastic polyurethane foam being flame retardant and having a density of greater than two and a half pounds per cubic foot that comprises a reaction product of an isocyanate component, an isocyanate-reactive blend, and a chain extender. The isocyanate-reactive blend includes a first isocyanate-reactive component and a second isocyanate-reactive component. The first isocyanate-reactive component includes at least 60 parts by weight of ethylene oxide (EO) based on 100 parts by weight of the first isocyanate-reactive component and the second isocyanate-reactive component includes at most 30 parts by weight of EO based on 100 parts by weight of the second isocyanate-reactive component. The chain extender is reactive with the isocyanate component and has a backbone chain with from two to eight carbon atoms and is present in an amount of from 5 to 50 parts by weight based on 100 parts by weight of the foam.
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: July 3, 2007
    Assignee: BASF Corporation
    Inventors: Wassana Apichatachutapan, Raymond Neff, James Mullins, Theodore M. Smiecinski, Thomas B. Lee
  • Patent number: 7223801
    Abstract: A composition and method for protecting pipeline joints is disclosed. A mold covers the exposed pipeline joint. A reaction composition including a polyol, an isocyanate, and an ester, preferably 2,2,4-trimethyl-1,2-pentanediol diisobutyrate, is added to the mold and allowed to react to form a polymer.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: May 29, 2007
    Assignee: Baysystems North America LLC
    Inventor: Scott A Brown
  • Patent number: 7208531
    Abstract: The subject invention provides a viscoelastic polyurethane foam having a density of from one to twenty pounds per cubic foot. The foam is formed from a composition that is a reaction product of an isocyanate component (A), a first polyether polyol (B), a second polyether polyol (C), and a chain extender (D). The chain extender (D) has a backbone chain with from two to eight carbon atoms and has a weight-average molecular weight of less than 1,000 and is present in an amount of from 5 to 50 parts by weight based on 100 parts by weight of the composition. The viscoelastic polyurethane foam a first glass transition temperature greater than zero and a second glass transition temperature less than zero and having a tan delta peak ratio of the first glass transition temperature to the second glass transition temperature less than 2.2.
    Type: Grant
    Filed: August 11, 2004
    Date of Patent: April 24, 2007
    Assignee: BASF Corporation
    Inventors: Raymond A. Neff, Suzanne Dakin
  • Patent number: 7205374
    Abstract: A method of preparing an adhesive, the method comprising combining an isocyanate, a polyhydroxyl phenol-containing compound, a polyol, and a trimerization catalyst.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: April 17, 2007
    Assignee: BFS Diversified Products, LLC
    Inventors: John W. Fieldhouse, Joseph J. Kalwara, Edward G. Kane, John B. Letts