Process Of Treating Scrap Or Waste Product Containing At Least One Polymer Derived From Ethylenic Unsaturated Monomers Only Patents (Class 521/40.5)
  • Patent number: 8455558
    Abstract: A composite material produced from carpet waste and a binding agent, in intimate association, which material includes 25% and 99% carpet waste and between 1 and 25% binding agent. A method for manufacturing the composite material is also disclosed.
    Type: Grant
    Filed: January 4, 2011
    Date of Patent: June 4, 2013
    Assignee: Material Innovations LLC
    Inventors: Douglas Mancosh, James P. Przybylinski, David E. Murdock
  • Patent number: 8450382
    Abstract: Techniques for creating recycled plastic materials from waste plastic materials are described. A recycled plastic material contains at least a primary polymer, a secondary polymer, and residual additives. Predetermined properties of the recycled plastic material can be controlled by selecting the types of waste plastic materials used in the recycling feed, determining the types and amounts of recycled plastic material recovered from a separation process and blending the recycled plastic material with other materials.
    Type: Grant
    Filed: February 7, 2011
    Date of Patent: May 28, 2013
    Assignee: MBA Polymers, Inc.
    Inventors: Brian L. Riise, Laurence E. Allen, III, Ron C. Rau, Michael B. Biddle
  • Patent number: 8445552
    Abstract: Embodiments of the present invention are directed to solid surface sheets and methods of making solid surface sheets, wherein the method comprises dissolving post-consumer recycled polystyrene in a first liquid resin precursor to form a blend, solidifying the blend via curing, grinding the solidified blend into recycled particles, adding the recycled particles and filler into a second liquid resin precursor to produce a solid surface precursor, and molding and curing the solid surface precursor to produce the solid surface sheet.
    Type: Grant
    Filed: December 1, 2010
    Date of Patent: May 21, 2013
    Assignee: The Diller Corporation
    Inventors: Kevin O'Brien, Dave Swenson
  • Patent number: 8404754
    Abstract: A process for recycling a coloured thermoplastic material comprising an absorbed disperse dye comprises contacting the optionally comminuted coloured thermoplastic material with a caustic wash and recovering an at least partly colour-modified thermoplastic composition from the caustic wash.
    Type: Grant
    Filed: December 5, 2005
    Date of Patent: March 26, 2013
    Assignee: Colormatrix Europe Limited
    Inventors: Mark Frost, Fuquan Zeng, Victoria Sayer
  • Patent number: 8394866
    Abstract: A method for preparing contaminated plastics ground into flakes, such as RPET or such polymers, having at least decontamination and SSP treatment steps, with at least one reactor, with heating to the process temperature taking place essentially outside the reactor. Also, a device for carrying out the method, and having at least one decontamination reactor and at least one SSP reactor, a device for heating plastic flakes to the process temperature being arranged upstream of the decontamination reactor. Also an SSP reactor having at least two individual reactors, and preferably between 3 and 7 individual reactors.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: March 12, 2013
    Assignee: Krones AG
    Inventors: Thomas Friedlaender, Thomas Rieckmann, Frank Marx
  • Patent number: 8383764
    Abstract: The invention relates to block polymers, for example, arborescent copolymer compounds, and to methods of making and purifying such compounds. In one embodiment, the invention relates to arborescent polymer compounds that contain one or more styrene polymeric blocks in combination with one or more isobutylene polymeric blocks. In another embodiment, the invention relates to methods for purifying arborescent polymer compounds that contain at least one styrene polymeric block in combination with at least one isobutylene polymeric block.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: February 26, 2013
    Assignee: The University of Akron
    Inventor: Judit E. Puskas
  • Patent number: 8349285
    Abstract: The invention relates a pyrolytic carbon black produced from pyrolyzed rubber, the pyrolytic carbon black having an ash content ranging between 9-15%, a toluene discoloration at 425 mu of between 80-90% transmission, an iodine adsorption between 30 and 45 mg/g; and, an n-dibutyl phthalate absorption number of or to 65 cc/100 gm.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: January 8, 2013
    Assignee: Raymond Chabot Inc.
    Inventors: Andrew D. E. MacIntosh, Vincent W. Y. Wong
  • Patent number: 8334325
    Abstract: The present invention relates to a method for preferentially breaking cross-links in a vulcanised rubber, thereby de-vulcanising the rubber, by the use of a supercritical fluid, such as carbon dioxide. The supercritical fluid maintained at an appropriate solubility parameter, swells the vulcanised rubber to a state of equilibrium swell. The cross links (3) become fully extended and under strain to hold the internal pressures caused by the solvent swelling affect of the supercritical gas. When equilibrium swell has been achieved, the pressure within the processing vessel is rapidly dropped to a level of not less than 60% of the level at which saturation took place, causing a degassing and expansion of the supercritical fluid that has been absorbed within the vulcanised rubber. The resulting three dimensional separation of the rubber molecules will put a further rapid strain on the cross links, causing them to break (7), thereby giving the affect of de-vulcanization.
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: December 18, 2012
    Assignee: Rubber-Regen LLP
    Inventors: Michiel Jan Dees, Philip James Hough
  • Patent number: 8334326
    Abstract: The invention relates to a method for adjusting the pH value and/or for neutralizing acid and/or basic compounds, in particular degradation or decomposition products, as part of the reprocessing and recycling of in particular thermoplastic materials, in the course of which the polymer particles are permanently moved and heated in a reactor, wherein at least one filler is added for neutralization purposes, specifically in a quantity which corresponds at least to the anticipated acid or alkali load.
    Type: Grant
    Filed: March 30, 2010
    Date of Patent: December 18, 2012
    Assignee: Erema Engineering Recycling Maschinen und Anlagen Gesellschaft m.b.H.
    Inventors: Klaus Feichtinger, Manfred Hackl, Gerhard Wendelin
  • Patent number: 8318895
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: August 2, 2012
    Date of Patent: November 27, 2012
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 8314206
    Abstract: In one embodiment, a block copolymer-containing composition includes PS-b-PXVP and a lithium salt, where “X” is 2 or 4. All lithium salt is present in the composition at no greater than 1 ppm by weight. In one embodiment, a homogenous block copolymer-including comprising has PS-b-PXVP present in the composition at no less than 99.99998% by weight, where “X” is 2 or 4. Methods of forming such compositions are disclosed.
    Type: Grant
    Filed: December 2, 2008
    Date of Patent: November 20, 2012
    Assignee: Micron Technology, Inc.
    Inventors: Dan Millward, Scott Sills
  • Patent number: 8309682
    Abstract: A process is described for recycling superabsorbent polymer fines into a process that includes treating the superabsorbent polymer fines with caustic and a polymerization step for making the superabsorbent polymer gel. The process requires treating the superabsorbent polymer fines with a caustic, followed by mixture with polymerizable monomer solution, and polymerizing the mixture of the superabsorbent polymer fines and monomer to form the aqueous fluid absorbent polymer. In the process, the fines are incorporated into the new polymer gel and become indistinguishable there from. The gel may then be comminuted into a particulate dried and then separated into a portion having a desired minimum particle size in a fines portion having less than the desired size. The particulate may then be coated with a surface crosslinking agent and surface additives and heated for surface conversion.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: November 13, 2012
    Assignee: Evonik Stockhausen, LLC
    Inventors: Gonglu Tian, Scott J. Smith, Janet Pate-Linton
  • Patent number: 8309618
    Abstract: The disclosure relates to methods and materials useful for depolymerizing a polymer. In one embodiment, for example, the disclosure provides a method for depolymerizing a polymer containing electrophilic linkages, wherein the method comprises contacting the polymer with a nucleophilic reagent in the presence of a guanidine-containing compound. The methods and materials of the disclosure find utility, for example, in the field of waste reclamation and recycling.
    Type: Grant
    Filed: July 1, 2009
    Date of Patent: November 13, 2012
    Assignees: International Business Machines Corporation, Stanford University
    Inventors: James Lupton Hedrick, Russell Clayton Pratt, Robert M. Waymouth
  • Patent number: 8304458
    Abstract: A method of reclaiming a cured elastomer material in the form of crumb or chips, comprising mixing the elastomer material with a devulcanization-aiding chemical composition and performing devulcanization by applying a shear-stress deformation while performing a mechanical disintegration into fine-ground crumbs under a controllable temperature not exceeding about 90 degrees C.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: November 6, 2012
    Assignee: Innovert Investments A.L. Ltd
    Inventor: Lev Beirakh
  • Patent number: 8304459
    Abstract: The present invention relates to a method for preferentially breaking cross-links in a vulcanized rubber, thereby de-vulcanizing the rubber, by the use of a supercritical fluid, such as carbon dioxide. The supercritical fluid maintained at an appropriate solubility parameter, swells the vulcanized rubber to a state of equilibrium swell. The cross links become fully extended and under strain to hold the internal pressures caused by the solvent swelling affect of the supercritical gas. When equilibrium swell has been achieved, the pressure within the processing vessel is rapidly dropped to a predetermined level causing a degassing and expansion of the supercritical fluid that has been absorbed within the vulcanized rubber. The resulting three dimensional separation of the rubber molecules will put a further rapid strain on the cross links, causing them to break, thereby giving the affect of de-vulcanization.
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: November 6, 2012
    Assignee: Rubber-Regen LLP
    Inventors: Philip J. Hough, Anthony N. Hough
  • Patent number: 8304462
    Abstract: The present invention provides methods of making composite materials comprising combining particles of crosslinked rubber with one or more aqueous polymer dispersion of a suspension polymer to form a mixture in aqueous dispersion, and, optionally, subjecting the aqueous dispersion mixture to solid state shear pulverization to form materials that can be processed as thermoplastics at crosslinked rubber concentrations of from 10 to as high as 95 wt. %, based on the total solids of the material. The method may further comprise kneading and/or compression molding the pulverized product to form useful articles, such as roofing membranes and shoe soles.
    Type: Grant
    Filed: December 28, 2009
    Date of Patent: November 6, 2012
    Assignee: Rohm and Haas Company
    Inventors: Willie Lau, Rachel Z. Pytel, Joseph M. Rokowski
  • Patent number: 8304464
    Abstract: The invention relates to a method for mixing a polyester with caustic material including providing a polyester, preferably PET, mixing the polyester with the caustic material; and heating the mixture in temperature stages defined as a function of a reaction sequence of the reaction between the PET and the caustic material.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: November 6, 2012
    Assignee: Cleanaway PET International GmbH
    Inventor: Ulrich Schmidt
  • Patent number: 8304460
    Abstract: The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 ?m or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 ?m in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials.
    Type: Grant
    Filed: June 17, 2009
    Date of Patent: November 6, 2012
    Assignee: Rohm and Haas Company
    Inventors: Willie Lau, Donald C. Schall, Harry R. Heulings, IV, Kimberly B. Kosto, Joseph M. Rokowski
  • Patent number: 8299135
    Abstract: Embodiments of the invention provide a process for processing post-consumer polymer. The polymer is contacted with a control medium having a carrier gas and a reactive vapor. Such a process is useful for processing post-consumer polymers with lower energy and reactants than with liquid reactants, and also promotes decontamination of the recycled polymer during the reaction.
    Type: Grant
    Filed: July 2, 2010
    Date of Patent: October 30, 2012
    Assignee: Bepex International, LLC
    Inventor: Girish Bhatt
  • Patent number: 8278365
    Abstract: A composite material is produced from carpet waste and a binding agent, in intimate association, and may also include wood fiber or chips and/or other additives. A method of manufacturing a composite material includes shredding carpet waste, coating the carpet waste with a binding agent, and subjecting the shredded, coated carpet waste to elevated heat and pressure. As an additional step, the composite material may be actively cooled to prevent deformation of the material.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: October 2, 2012
    Assignee: Material Innovations LLC
    Inventors: David E. Murdock, Douglas Mancosh, James P. Przybylinski
  • Patent number: 8273800
    Abstract: A surfacing composition made of recycled paint, which requires no priming, has a non-reflective “flat” appearance, and is partially composed of dried paint. The composition provides a useful application for used or excess household paint, which would otherwise require special methods of disposal and potentially create future toxic cleanup problems. The composition is made of granular dried paint and a water-based sealer, which can be spread on a surface to repair imperfections. The surface can then be finished, and no priming is required. Due to the composition's flat appearance, the patch does not display any characteristic sheen where the repair has been made. The composition provides a simple means of recycling paint, and provides a simple and inexpensive means of repairing imperfections in walls and other surfaces while saving the step of priming the patch before painting or repainting.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: September 25, 2012
    Inventor: Larry Allen Holloway
  • Publication number: 20120214884
    Abstract: The present invention provides a method of making a flexible foaming member from recycled material. The present invention relates to a production method to recycling wastes containing rubber, plastic and metal materials and pulverize them into scraps under normal temperatures, then roughly separate the various materials contained in the waste scraps into different layers based on the difference of specific gravity, and further take out the scraps of rubber and plastic materials with lower specific gravity from the waste scraps, then conduct multiple heating and pulverizations under different temperatures to produce composite-material scraps, and then using some composite-material scraps to mix flexible materials and foaming agents, then pressing the mixture into a plate-like foaming material, and conduct vulcanization and foam forming for the plates of foam material to become a elastic foam.
    Type: Application
    Filed: April 30, 2012
    Publication date: August 23, 2012
    Inventor: Semi KAO
  • Patent number: 8202918
    Abstract: Methods and systems for processing waste materials and for manufacturing composite materials are disclosed herein. According to some embodiments, the heterogeneous waste includes a plastic component and a non-plastic component, and the non-plastic component includes a plurality of pieces of waste. The heterogeneous waste is heated to melt at least a portion of said plastic component and reducing a volume of said heterogeneous waste, and then mixed (e.g. by rotating a mixing chamber or by stirring) until at least some said pieces are each encapsulated by the melted plastic component. Upon cooling, the mixture optionally sets into a composite material. The presently disclosed invention does not require pre-sorting of the heterogeneous waste and is operative to process “as is” waste. Optionally, the waste is pre-sorted.
    Type: Grant
    Filed: October 28, 2010
    Date of Patent: June 19, 2012
    Inventors: Amit Azulay, Yuval Tamir
  • Patent number: 8188155
    Abstract: The present invention relates to a method for preferentially breaking cross-links in a vulcanized rubber, thereby de-vulcanizing the rubber, by the use of a supercritical fluid, such as carbon dioxide The supercritical fluid causes swelling of the said vulcanized rubber material, wherein the time of swelling is not more than 50% of the time required for full volume equilibrium swelling of the rubber in said supercritical fluid and the swelling is followed by a rapid reduction of the supercritical fluid pressure The cross links (3) become fully extended and under strain to hold the internal pressures caused by the solvent swelling affect of the supercritical gas When equilibrium swell has been achieved, the pressure within the processing vessel is rapidly dropped to a predetermined level causing a degassing and expansion of the supercritical fluid that has been absorbed within the vulcanized rubber The resulting three dimensional separation of the rubber molecules will put a further rapid strain on the cross l
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: May 29, 2012
    Assignee: Rubber-Regen LLP
    Inventors: Michiel Jan Dees, Philip James Hough
  • Patent number: 8188154
    Abstract: A decomposition reaction apparatus for the decomposition treatment of a thermosetting resin, which comprises a reaction apparatus comprising an introduction section for introducing a resin composition containing the thermosetting resin and a solvent containing a monomer component of the thermosetting resin or a component similar to the monomer component, a decomposition reaction section for heating and pressuring the resin composition and the above solvent so as for the solvent to have a supercritical state or a subcritical state, to thereby prepare a treated and recovered product containing a recycled resin formed by the reduction of the molecular weight of the above thermosetting resin, and a discharge section for discharging the treated and recovered product.
    Type: Grant
    Filed: October 7, 2005
    Date of Patent: May 29, 2012
    Assignee: Sumitomo Bakelite Company, Ltd.
    Inventors: Junya Goto, Sumiya Miyake, Masaki Ishikawa, Kazunori Shimoyachi
  • Patent number: 8183337
    Abstract: Methods for the purification of ethylene vinyl alcohol copolymers are provided.
    Type: Grant
    Filed: April 29, 2009
    Date of Patent: May 22, 2012
    Assignee: Abbott Cardiovascular Systems Inc.
    Inventor: Stephen D. Pacetti
  • Patent number: 8168688
    Abstract: A process for making a solid component out of recycled paint sludge is provided. The process can include providing a paint sludge and providing a second material. Thereafter, the paint sludge and the second material are mixed to produce a paint sludge-second material mixture. The paint sludge-second material mixture is processed in order to produce a polymer containing precursor. The processing can include granulating or densifying the paint sludge-second material mixture. After the precursor has been produced, it can be placed within a molding machine and a solid component is molded. The molding machine can be an injection molding machine, an extrusion molding machine or a blow molding machine.
    Type: Grant
    Filed: March 6, 2009
    Date of Patent: May 1, 2012
    Inventors: Dan Chrzanowski, Brandon Chrzanowski
  • Patent number: 8153699
    Abstract: A surfacing composition made of recycled paint, which requires no priming, has a non-reflective “flat” appearance, and is partially composed of dried paint. The composition provides a useful application for used or excess household paint, which would otherwise require special methods of disposal and potentially create future toxic cleanup problems. The composition is made of granular dried paint and a water-based sealer, which can be spread on a surface to repair imperfections. The surface can then be finished, and no priming is required. Due to the composition's flat appearance, the patch does not display any characteristic sheen where the repair has been made. The composition provides a simple means of recycling paint, and provides a simple and inexpensive means of repairing imperfections in walls and other surfaces while saving the step of priming the patch before painting or repainting.
    Type: Grant
    Filed: April 13, 2009
    Date of Patent: April 10, 2012
    Inventor: Larry Allen Holloway
  • Publication number: 20120071573
    Abstract: The invention relates to a method for adjusting the pH value and/or for neutralizing acid and/or basic compounds, in particular degradation or decomposition products, as part of the reprocessing and recycling of in particular thermoplastic materials, in the course of which the polymer particles are permanently moved and heated in a reactor, wherein at least one filler is added for neutralization purposes, specifically in a quantity which corresponds at least to the anticipated acid or alkali load.
    Type: Application
    Filed: March 30, 2010
    Publication date: March 22, 2012
    Applicant: EREMA Engineering Recycling Maschinen und Anlagen Gesellschaft m.b.H.
    Inventors: Klaus Feichtinger, Manfred Hackl, Gerhard Wendelin
  • Patent number: 8138232
    Abstract: The invention relates to a method for recycling plastic materials which contain at least two polymers, copolymers or blends thereof based on polystyrene. The plastic material is thereby mixed with a solvent for the polymers, copolymers or blends. Subsequently a precipitation is effected by addition of a corresponding precipitant so that then the gelatinous precipitation product can be separated from the further components of the plastic material. The method is used for recycling of any plastic materials, in particular of plastic materials from electronic scrap processing and from shredder light fractions.
    Type: Grant
    Filed: June 8, 2006
    Date of Patent: March 20, 2012
    Assignee: Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung E.V.
    Inventors: Andreas Maeurer, Martin Schlummer, Otto Beck
  • Patent number: 8138233
    Abstract: In one embodiment, the invention relates to a two step process in which a 1,4-butane diol component reacts with a polyethylene terephthalate component under conditions that depolymerize the polyethylene terephthalate component into a molten mixture and the molten mixture is placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. In another embodiment, the invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butane diol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: March 20, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Kristen Cohoon-Brister, Sandeep Dhawan, Robert Russell Gallucci, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Publication number: 20120045653
    Abstract: A resin composition, contains: a thermoplastic polyurethane (A); a thermoplastic polyurethane (B); and an ethylene-vinyl alcohol copolymer (C), wherein an isocyanate group content (mole) in raw materials of the thermoplastic polyurethane (A) is greater than a hydroxyl group content (mole) therein, an isocyanate group content (mole) in raw materials of the thermoplastic polyurethane (B) is nearly equal to a hydroxyl group content (mole) therein, and the thermoplastic polyurethane (B) and the ethylene-vinyl alcohol copolymer (C) have a mass ratio (B/C) of from 70/30 to 99/1 and a content of the thermoplastic polyurethane (A), based on 100 parts by mass of a total of the thermoplastic polyurethane (B) and the ethylene-vinyl alcohol copolymer (C), is from 1 to 30 parts by mass. Thus, a resin composition is provided that contains thermoplastic polyurethanes and an ethylene-vinyl alcohol copolymer and is good in melt shapability.
    Type: Application
    Filed: March 29, 2010
    Publication date: February 23, 2012
    Applicant: KURARAY CO., LTD.
    Inventors: Kouta Isoyama, Tatsuya Oshita, Hidekazu Saitou, Hiroyuki Ono
  • Patent number: 8106104
    Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a plastic content predetermined to be desirable for reprocessing into at least one of such useful articles.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: January 31, 2012
    Assignee: Advanced Environmental Recycling Technologies, Inc.
    Inventors: Joe G. Brooks, Christopher Lynn Becker
  • Patent number: 8106103
    Abstract: A method for reformulating reclaimed, contaminated mixed waste plastics into useful articles wherein a plurality of batches of the mixed waste plastics are preprocessed to produce substantially homogeneous mixtures of a desired particle size range that are characterized according to their respective apparent densities, and are thereafter blended to produce a mixed plastic feed material having a color predetermined to be desirable for reprocessing into at least one of such useful articles.
    Type: Grant
    Filed: July 21, 2008
    Date of Patent: January 31, 2012
    Assignee: Advanced Environmental Recycling Technologies, Inc.
    Inventors: Joe G. Brooks, Christopher Lynn Becker
  • Publication number: 20120007284
    Abstract: A composite formulation consisting of agglomerated industrial/residential sewer sludge and recycled high density polyethylene (HDPE) and/or polypropylene (PP) materials. The recycled plastic materials act as a binder for the pozzolan industrial/residential sewer sludge. The composite formulation can be produced in a batching process wherein the sieved dried sewer sludge and the recycled plastic in appropriate small cut pieces is fed into a large plastic extruder, heated and extruded into specific structures. The formulation can also be compounded using a compression mold wherein sieved dry sewer sludge are added to heated chopped recycled plastics and heat mixed to produce pellets or directed into a compression mold to create a structural member of predetermined shape.
    Type: Application
    Filed: July 12, 2010
    Publication date: January 12, 2012
    Inventors: Darrel S. Nelson, James M. Oliver
  • Patent number: 8088834
    Abstract: The invention relates to a process for making modified polybutylene terephththalate random copolymers from a polyethylene terephthalate component. The invention relates to a three step process in which a diol component selected from the group consisting of ethylene glycol, propylene glycol, and combinations thereof reacts with a polyethylene terephthalate component under conditions sufficient to depolymerize the polyethylene terephthalate component into a first molten mixture; and where the first molten mixture is combined with 1,4-butanediol under conditions that create a second molten mixture that is subsequently placed under subatmospheric conditions that produce the modified polybutylene terephthalate random copolymers. The invention also relates to compositions made from the process.
    Type: Grant
    Filed: September 2, 2010
    Date of Patent: January 3, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Parminder Agarwal, Kristen Cohoon, Sandeep Kumar Dhawan, Robert Russell Galucci, Ganesh Kannan, Sr., Kenneth Frederick Miller, Deepak Ramaraju, Gomatam Raghavan Ravi, Dhaval Shah
  • Patent number: 8044107
    Abstract: A method of producing an embedded recycled container sheet includes: (a) providing a plurality of empty recycled plastic containers; (b) flattening the plurality of empty recycled plastic containers to reduce their width by at least 80%; (c) providing a base substrate of plastic; (d) placing the plurality of flattened, empty recycled plastic containers on the base substrate; and, (e) applying a molten top layer of plastic on the plurality of flattened, empty recycled plastic containers and on the base substrate, and cooling the molten top layer, so as to embed the plurality of empty recycled plastic containers between the top layer and the base substrate. A method of producing product from the resulting sheet involves creating the product using a processing step selected from the group consisting of molding, casting, cutting, machining, and combinations of these.
    Type: Grant
    Filed: June 22, 2009
    Date of Patent: October 25, 2011
    Assignee: Bgreen Innovations Inc
    Inventor: Kenneth P. Glynn
  • Patent number: 8030364
    Abstract: The present invention relates to a preparing method of polyols, polyurethane and polyurethane foams using the same. Polyester, polyamide and polyurethane are depolymerized with the polymeric fatty acid mono(polyhydroxyl alcohol)ide composition and additionally reacted with the polybasic acid, polyol and amine to prepare acid value of 05-˜1 mgKOH/g, hydroxyl value of 10˜500 mgKOH/g, and amine value of 1˜50 mgKOH/g in polyol. This is to transform the double bond of the unsaturated fatty acid from the component of the oils and fats into a conjugated double bond to induce the Diels-Alder reaction, and with the improvement of the reactivity to form a stable combination in the chemical structure to prevent the separate leaching appearance of fat and fatty oil from the final product. In particular, by recycling waste edible oil and waste synthetic resin that can be employed as industrially useful material, the invention provides environment advantages.
    Type: Grant
    Filed: October 10, 2005
    Date of Patent: October 4, 2011
    Inventors: Do Gyun Kim, Hyosung Kim
  • Patent number: 8013028
    Abstract: An embedded recycled container sheet binder includes a front cover and a back cover, the front cover and the back cover being connected to one another for opening and closing, at least one of the front cover and the back cover being, at least in part, a plurality of flattened recycled containers embedded in a plastic base, and each of the plurality of flattened recycled containers being visibly recognizable. The plurality of flattened recycled containers is preferably embedded between a base substrate of plastic and a top layer of plastic. The base substrate is a recycled plastic base substrate selected from the group consisting of clear plastic, opaque plastic, colored plastic and combinations thereof. In some preferred embodiments, the embedded recycled container sheet binder the top layer is a recycled plastic selected from the group consisting of clear plastic, opaque plastic and combinations thereof.
    Type: Grant
    Filed: August 31, 2009
    Date of Patent: September 6, 2011
    Assignee: B Green Innovations, Inc.
    Inventor: Kenneth P. Glynn
  • Patent number: 8013027
    Abstract: A basket is made from embedded recycled container sheet. The basket includes: a side wall and a bottom, the side wall and the bottom being connected to one another in the shape of a basket with an open top, the side wall being, at least in part, a plurality of flattened recycled containers embedded therein, and each of the plurality of flattened recycled containers being visibly recognizable. In some embodiments, the basket also includes a hanging mechanism attached to at least one of the side wall and the bottom. The side wall has a footprint that may be circular, conical, oval, square, rectangular, polygonal or irregular.
    Type: Grant
    Filed: August 31, 2009
    Date of Patent: September 6, 2011
    Assignee: B Green Innovations, Inc.
    Inventor: Kenneth P. Glynn
  • Publication number: 20110207838
    Abstract: Disclosed is a thermoplastic resin composition including a) 50 to 92 weight percent of a recycled thermoplastic, wherein said recycled thermoplastic includes at least 60 weight percent of a recycled polyamide selected from the group consisting of polyamide 66, polyamide 6, and copolymers having repeat units of polyamide 66 and polyamide 6; and 8 to 30 weight percent of polymer toughener, wherein said polymer toughener comprises at least one acid polymer toughener(s) wherein said polymer toughener has an averaged calculated acid number of about 10 to about 90 mg KOH/g before blending into said thermoplastic composition.
    Type: Application
    Filed: February 21, 2011
    Publication date: August 25, 2011
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventor: Avelino F. Lima
  • Patent number: 7999012
    Abstract: Disclosed is a system to mechanically destroy printer toner cartridges and reclaim their constituent materials under a water shielded environment while providing a safer and more environmentally friendly recycling system. The present invention is an economical system that provides greater protection from possible fire or explosion and releases less irritating or possibly harmful airborne contamination than the currently available systems.
    Type: Grant
    Filed: October 20, 2008
    Date of Patent: August 16, 2011
    Inventors: Lacee Lamphere, Brian Ibarra, Donald Laffler, James Hardin
  • Patent number: 7985778
    Abstract: Synthetic resin containing ester bond is subjected to hydrolysis treatment to reclaim raw material component before polymerization. Method for decomposing and reclaiming synthetic resin having ester bond in composition structure thereof, by conducting hydrolysis treatment and then separation collection treatment. In the hydrolysis treatment, article containing synthetic resin to be decomposed and reclaimed is exposed to water vapor atmosphere filled under saturation water vapor pressure at treatment temperature at or below melting point of the synthetic resin. The synthetic resin in article to be treated is hydrolyzed by water vapor generated at the treatment temperature, to generate decomposition product before polymerizing to the synthetic resin containing an ester bond. The separation collection treatment is treatment in which the decomposition product generated by the hydrolysis treatment is separated into liquid component and solid component to be collected individually.
    Type: Grant
    Filed: March 6, 2007
    Date of Patent: July 26, 2011
    Inventor: Koichi Nakamura
  • Patent number: 7981940
    Abstract: Provided is a method of treating a sealing compound, in order to recover from the inside of a pneumatic tire the sealing compound that was used for repairing a puncture, the sealing compound including an aqueous solution having at least rubber latex dispersed therein, the method comprising: solid-liquid separating, by injecting a treating agent into the inside of a pneumatic tire into which the sealing compound was injected, the treating agent comprising at least one of a salt that is a reaction compound of an acid and a base and/or a water-soluble organic solvent, mixing the treating agent with the sealing compound inside the pneumatic tire, and aggregating and solidifying the rubber latex in the sealing compound.
    Type: Grant
    Filed: May 26, 2005
    Date of Patent: July 19, 2011
    Assignee: Bridgestone Corporation
    Inventors: Shinichi Iwasaki, Rieko Iwasaki, legal representative, Ryuji Izumoto, Daisuke Sugio
  • Patent number: 7981941
    Abstract: A method for reprocessing used PET bottles having the step of shredding the bottles to form plastic flakes, sorting the plastic flakes according to at least one criterion into at least two partial quantities, and performing an individual processing treatment including a decontamination treatment. The device permits performing the method whereby it is possible to separate the plastic flakes produced from the threaded part of a PET bottle, these flakes being more difficult to purify, from the lighter plastic flakes from the wall of the bottle, which have a thin wall and are easier to purify, and treating them further in separate reprocessing steps.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: July 19, 2011
    Assignee: Krones AG
    Inventors: Thomas Friedlaender, Maren Hofferbert, Timm Kirchhoff
  • Patent number: 7973092
    Abstract: A method for reprocessing used PET bottles having the steps of shredding the bottles to form plastic flakes, sorting the plastic flakes according to at least one criterion into at least two partial quantities, and performing an individual processing treatment including a decontamination treatment. The device permits performing the method whereby it is possible to separate the plastic flakes produced from the threaded part of a PET bottle, these flakes being more difficult to purify, from the lighter plastic flakes from the wall of the bottle, which have a thin wall and are easier to purify, and treating them further in separate reprocessing steps.
    Type: Grant
    Filed: October 9, 2004
    Date of Patent: July 5, 2011
    Assignee: Krones AG
    Inventors: Thomas Friedlaender, Maren Hofferbert, Timm Kirchhoff
  • Patent number: 7959890
    Abstract: The invention relates to recycled rubber produced by a process comprising the steps of: a) shredding cleaned rubber tires into shreds less than 2? long; b) pyrolyzing the shreds in a reaction chamber of a thermal processor in a first anaerobic environment to produce a char; c) drawing off volatile organics from the reaction chamber; c) removing the char from the reaction chamber; d) cooling the char in a second anaerobic environment; e) removing metal and textile components from the char to obtain pyrolytic carbon black; f) milling and sizing the pyrolytic carbon black so obtained into particles of 325 mesh size or smaller; and, g) utilizing the pyrolytic carbon black from the previous step in a polymerization process that produces said recycled rubber. It also relates to the high quality pyrolytic carbon black recovered from this process.
    Type: Grant
    Filed: February 1, 2010
    Date of Patent: June 14, 2011
    Assignee: RIPP Resource Recovery Corporation
    Inventors: Andrew D. E. MacIntosh, Vincent W. Y. Wong
  • Patent number: 7947749
    Abstract: A system to recycle plastics, which enables a supply of recycled plastics having a stable quality required for the recycled products. A system to recycle a used plastic material as a resin material including (a) means to sort used plastic materials for the purpose of recycling said used plastic materials, (b) means to crush and melt said used plastic material after it has been sorted, (c) reviving means to regain a desired property, and (d) means to measure a physical property of a reclaimed plastic after it has been revived and to indicate said measured physical property for quality assurance.
    Type: Grant
    Filed: November 5, 2008
    Date of Patent: May 24, 2011
    Assignee: Sony Corporation
    Inventors: Daisuke Hasegawa, Yasuhito Inagaki, Haruo Watanabe, Masahiro Sawaguchi
  • Patent number: 7935737
    Abstract: Compositions of matter including articles derived from (a) from 5 to 99.99 wt % of a modified polybutylene terephthalate random copolymer that (1) is derived from polyethylene terephthalate and (2) contains a at least one residue derived from polyethylene terephthalate selected from the group consisting of antimony, germanium, diethylene glycol groups, isophthalic acid groups, cis isomer of cyclohexane dimethanol, trans isomer of cyclohexane dimethanol, sodium benzoate, alkali salts, napthalane dicarboxylic acids, 1,3-propane diols, cobalt, cobalt-containing compounds, and combinations thereof, and (b) from 0.01 to 95 wt. % of a member selected from the group consisting of (1) fillers, (2) a carboxy reactive component, (3) polyethyelene terephthalate, (4) a component including a polycarbonate and an impact modifier. The articles may be derived from various conversion processes, e.g., injection molding processes, extrusion processes, thermoforming processes, melt-blown process.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: May 3, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Vikram Gopal, Ganesh Kannan, Kenneth Frederick Miller, Dhaval Shah
  • Patent number: 7935736
    Abstract: The invention relates to a method for recycling polyesters or polyester mixtures from polyester-containing waste, in which the polyester or the polyester mixture is dissolved in a solvent and subsequently free-flowing particles are precipitated herefrom with a precipitant. The precipitant is thereby chosen such that subsequent separation of precipitant and solvent is made possible in a simple manner.
    Type: Grant
    Filed: April 13, 2005
    Date of Patent: May 3, 2011
    Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.
    Inventors: Andreas Mäurer, Udo Knauf, Gerd Wolz, Michael Frankl, Otto Beck