Abstract: The invention provides a heat transfer composition comprising a minimum of about 80% by weight of R-1243zf and a maximum of 20% by weight of R-32, based on the total weight of the composition.

Abstract: This invention provides a process for extruding a PLA resin using high levels of CO2. Excellent quality, low density foam is produced easily and reproducibly. The foams arc capable of being heat-annealed to induce significant crystallinity, even when an ordinarily amorphous PLA resin is used.

Abstract: The invention relates to a body, particularly a molded body made of polystyrene, particularly polystyrene particle foam or polystyrene hard foam, wherein the polystyrene, particularly the polystyrene particle foam or the polystyrene hard foam, comprises petroleum coke, particularly petroleum coke particles.

Abstract: The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Abstract: Polymeric foam and polymeric foam products that contain a foamable polymer material, at least one blowing agent, a polystyrene/polyethylene oxide copolymer, and optionally, an infrared attenuating agent, are provided. In exemplary embodiments, the blowing agent includes at least one hydrofluorocarbon blowing agent. The maleic anhydride-styrene copolymer grafted with polyethylene oxide provides a water vapor permeability of 1.1 perm inch or greater in the extruded foam product without detrimentally affecting physical or thermal properties of the product. Additionally, the copolymer of maleic anhydride-styrene grafted with polyethylene oxide has a positive affect on the processability of the blowing agent(s) in the composition by both widening the process window and enhancing the solubility of the blowing agent in the polymer melt. Thus, the polystyrene/polyethylene oxide copolymer present in the inventive composition acts as a cell enlarger, a plasticizer, and a processing aid.

Abstract: Polyolefin dispersions, froths, and foams and articles manufactured therefrom are disclosed. Also disclosed is a method for generating a thermoplastic foam from an aqueous dispersion. The aqueous dispersion may include a thermoplastic resin, water, and a stabilizing agent. The method may include adding at least one frothing surfactant to the aqueous dispersion to form a mixture, adding a flame retardant and/or a phase change material, frothing the mixture to create a froth, and removing at least a portion of the water to produce the foam.

Abstract: A heat transfer composition comprising trans-1,3,3,3-tetrafluoropropene (R-1234ze(E)), difluoromethane (R-32) and 1,1-difluoroethane (R-152a).

Abstract: To provide a method for easily producing an ethylene/tetrafluoroethylene copolymer porous material having excellent chemical resistance and filtration performance and has a high heat resistance, within a wide range of the porosity, and an ethylene/tetrafluoroethylene copolymer porous material obtained by such a process. A process for producing an ethylene/tetrafluoroethylene copolymer porous material which comprises a step of dissolving an ethylene/tetrafluoroethylene copolymer having repeating units based on ethylene and repeating units based on tetrafluoroethylene at a temperature of at most 300° C. in a solvent which can dissolve the ethylene/tetrafluoroethylene copolymer at a temperature of at most 300° C., to achieve a predetermined concentration to obtain a solution, a step of forming the solution to obtain a formed product, and a step of cooling the formed product to a temperature of at most the phase separation temperature of the solution to solidify the ethylene/tetrafluoroethylene copolymer.

Abstract: The present invention relates to compositions comprising poly-oxycarbosilane and methods for using the compositions in step and flash imprint lithography. The imprinting compositions comprise a poly-oxycarbosilane polymer, a silanol, a reaction initiator and optionally a pore generator.

Abstract: Energy-activated room temperature-pumpable polymer compositions, devices for activating and processing the same into solid cellular or non-cellular polymeric materials that can be used as adhesives, sealants, coatings or gasket materials, and methods of making and using the same. The compositions according to the invention include solid particles that include one or more polymers, which are emulsified, dispersed or suspended in a liquid carrier together with at least one processing aid, such as a reactive blowing agent, a low molecular weight surfactant, a high molecular weight surfactant, one or more compounds found in latex paint, starch, cellulosic derived products and combinations of two or more thereof. The processing aids provide various benefits including, for example, reduced density, improved process hygiene, improved foam stability, faster bonding times and/or lower processing temperatures.

Abstract: A method for forming a fire resistant material is disclosed. The method comprises providing a plurality of expandable beads of a polymeric material. The beads are coated with an exfoliable graphite. The exfoliable graphite is adhered to the beads with a resin having a solubility parameter of the polymeric material. The beads are thereafter caused or allowed expand and fuse.

Abstract: Expanded and extruded biodegradable polymer foams are obtained using biodegradable polymers and environmentally benign non-VOC methyl formate as a blowing agent. The blowing agent can be a blend further including at least one co-blowing agent, preferably an environmentally friendly species (e.g., non-VOC), which is either a physical co-blowing agent (e.g. an inorganic agent, a hydrocarbon, a halogenated hydrocarbon, a hydrocarbon with polar, functional group(s), water or any combination thereof), or a chemical co-blowing agent, or combinations thereof. The blowing agent blend can include any combination of methyl formate and one or more co-blowing agents. The polymer foam can include a biodegradable polymer or its blends with other biodegradable polymers or conventional (non-biodegradable) polymers. The methyl formate-based blowing agent blends produce stable foams for various applications, including containers, packaging systems, as well as for insulation and protective cushioning.

Abstract: A method for forming a fire resistant material is disclosed. The method comprises providing a plurality of expandable beads of a polymeric material. The beads are coated with an exfoliable graphite. The exfoliable graphite is adhered to the beads with a resin having a solubility parameter of the polymeric material. The beads are thereafter caused or allowed to expand and fuse.

Abstract: The invention is directed to polyethylene foam based on a blend comprising 95.5-99.5% by weight low density polyethylene and 0.5-4.5% by weight high density polyethylene and a nucleating agent. The invention is also directed to a process for physical foaming of a blend comprising 95.5-99.5% by weight low density polyethylene and 0.5-4.5% by weight high density polyethylene in the presence of a physical blowing agent and a nucleating agent.

Abstract: A method comprising contacting a first styrenic polymer composition comprising residual styrene monomer with a molecular sieve, and recovering a second styrenic polymer composition comprising a reduced amount of residual styrene monomer. A composition comprising a styrenic polymer having a residual styrene monomer amount of less than 100 ppm produced by contacting a styrenic polymer composition having a residual styrene monomer amount of equal to or greater than 100 ppm with a molecular sieve, and recovering the styrenic polymer having a residual styrene monomer amount of less than 100 ppm. A method comprising providing a styrenic polymer composition having a residual styrene monomer amount of equal to or greater than 100 ppm, contacting the styrenic polymer composition with a molecular sieve, adding a nucleating agent, a foaming agent, and a coloring agent to the styrenic polymer composition, and forming an expanded styrenic polymer composition having a residual styrene monomer amount of less than 100 ppm.

Abstract: A tire puncture sealant including a urethane emulsion, an acrylic emulsion or a polyolefin emulsion, and an antifreezing agent has a comparatively low viscosity and an excellent storage stability while showing sealing properties equivalent to those of a conventional tire puncture sealant. A tire puncture sealant including a synthetic resin emulsion and an antifreezing agent, and having a hydrogen ion exponent of 5.5 to 8.5 has a less pungent odor and hardly causes corrosion of steel cord. A tire puncture sealant including a chloroprene emulsion and an antifreezing agent and having a hydrogen ion exponent of less than 9.0 has a comparatively low viscosity and a less odor while showing sealing properties equivalent to those of a conventional tire puncture sealant.

Abstract: Blowing-agent mixtures containing HFC-365mfc, HFC-227ea and one or both of 1,1,1,3,3-pentafluoropropane and 1,1,1,2-tetrafluoroethane are disclosed; as well as non-combustible polyether polyol and/or polyester polyol premixes for producing foamed products, in particular polyurethane foams.

Abstract: Azeotropic or azeotrope-like compositions are disclosed. The azeotropic or azeotrope-like compositions are mixtures of E-1,1,1,4,4,4-hexafluoro-2-butene with methyl formate, n-pentane, 2-methylbutane trans-1,2-dichloroethylene, 1,1,1,3,3-pentafluoropropane, n-butane or isobutane. Also disclosed is a process of preparing a thermoplastic or thermoset foam by using such azeotropic or azeotrope-like compositions as blowing agents. Also disclosed is a process of producing refrigeration by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as solvents. Also disclosed is a process of producing an aerosol product by using such azeotropic or azeotrope-like compositions. Also disclosed is a process of using such azeotropic or azeotrope-like compositions as heat transfer media. Also disclosed is a process of extinguishing or suppressing a fire by using such azeotropic or azeotrope-like compositions.

Abstract: The invention is directed to polyurethane foams which are flotation resistant with sufficient strength and density to provide stability and inhibit erosion at pipeline trench sites, and other uses, wherein at least 50% of the foam is open cell and has a density of approximately 1.3 lbs/ft3 to 3.5 lbs/ft3.

Abstract: An open-cell carbon nanotube foam is made of a plurality of separated carbon nanotubes. The foam exhibits a Poisson's ratio substantially equal to zero, a compressibility of at least 85%, a recovery rate of at least 120 mm/min, a compressive strength of at least 12 MPa, a sag factor of at least 4, a fatigue resistance to no more than 15% permanent deformation when subjected to at least 1,000 compressive cycles at a strain of 85%, and/or a resilience of between 25% and 30%. The carbon nanotubes may be multiwalled carbon nanotubes that are aligned parallel to a thickness of a film comprising the foam.

Abstract: Provided are azeotropic or azeotrope-like mixtures of 2,3,3,3-tetrafluoropropene (1234yf) and 3,3,3-trifluoropropene (1243zf), as well as methods for producing and using the same.

Abstract: A foamed composition adapted to seal to a substrate is provided. The foamed composition includes a radiation curable rubber, a photoinitiator, a blowing agent, a styrene-ethylene/butylene block copolymer, a light mineral oil, rheology modifier, a tackifier, and one of a radiation curable monomer and radiation curable oligomer, and wherein the composition is foamed upon application to the substrate.

Abstract: The present invention relates to blowing agent compositions comprising the unsaturated halogenated hydroolefin 3,3,3-trifluoropropene (HFO 1243zf) and combinations including primarily 3,3,3-trifluoropropene (HFO 1243zf). The blowing agent compositions are useful in that they provide sufficient plasticization to permit the production of low density insulating thermoplastic foams with improved k-factor.

Abstract: The present invention relates to blowing agent compositions comprising at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HCFOs of the present invention include, but are not limited to, 1-chloro-3, 3,3-trifluoropropene (HCFO-1233zd), particularly the trans-isomer, 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), dichloro-fluorinated propenes, and mixtures thereof. The blowing agent compositions of the present invention are used with coblowing agents including carbon dioxide, atmospheric gases, hydrofluorocarbons (HFC), hydrofluoroolefins (HFO), alkanes, hydrofluoroethers (HFE), and mixtures thereof. Preferred HFCs used as coblowing agents in the present invention include, but are not limited to, 1,1,1,2-tetrafluoroethane (HFC-134a), 1,1-difluoroethane (HFC-152a), 1,1,1-trifluoroethane (HFC-143a), pentafluorethane (HFC-125), difluoromethane (HFC-32).

Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is predominately the trans isomer of the hydrochlorofluoroolefin (HCFO) HFCO-1233zd alone or in combination with a hydrofluoroolefin (HFO), hydrofluorocarbon (HFC), hydrochlorofluoroolefin (HCFO), a hydrocarbon. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

Abstract: The present invention relates to blowing agent compositions comprising (1) at least one hydrofluoroolefin (HFO) and (2) at least one hydrochlorofluoroolefin (HCFO) used in the preparation of foamable thermoplastic compositions. The HFOs of component (1) include, but are not limited too, 3,3,3-trifluoropropene (HFO-1243zf), 1,2,3,3,3-pentafluoropropene (HFO-1225ye), cis- and/or trans-1,3,3,3-tetrafluoropropene (HFO-1234ze), and 2,3,3,3-tetrafluoropropene (HFO 1234yf), and mixtures thereof. The HCFOs of component (2) include, but are not limited to, 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd), 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf) and mixtures thereof. The blowing agent compositions are useful in the production of low density insulating foams with improved k-factor.

Abstract: There is presented a new flame retardant composition comprising a brominated aromatic composition and a butyl substituted phenyl phosphate.

Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is the hydrofluoropropene HFO-1243zf in combination with a hydrochlorofluoroolefin (HCFO) selected from HCFO-1233zd, HCFO-1233xf and HCFO-1223. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

Abstract: Alkenyl aromatic polymer foam comprising a polymer matrix containing one or more polymer and defining a plurality of cells having an average cell size wherein: (a) the alkenyl aromatic polymer foam has: —(i) an average cell size that is in a range of 0.02 and 5 millimeters; —(ii) a density of 64 kilograms per cubic meter or less; —(iii) an open cell content less than 30 percent; and—(iv) a cell size variation of 30% or less; and wherein the foam further comprises one or more fluorinated alkene blowing agent at a concentration of 0.03 moles or more and 0.3 moles or less per 100 grams of polymer foam.

Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234yf in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

Abstract: The invention relates to methods for the production of polymer carrier materials for solid phase synthesis, particularly for peptide synthesis. (Meth)acrylamide derivatives based on carbon hydrates, which can also contain other protective groups, are polymerized by means of suspension polymerization in an aqueous phase, optionally with the addition of pore-forming additives, and subsequently the protective groups are fully or partially cleaved. It is thus possible to obtain polymer carriers whose morphology (particle size, porosity), degree of cross-linking and swelling capability in aqueous and organic media can be adjusted in a targeted manner and whose reactive groups offer multiple opportunities for the immobilization of anchor groups and protective groups. The hydroxyl groups of the polymer carrier can be activated according to usual methods of solid phase synthesis.

Abstract: A blowing agent for thermosetting foams is disclosed. The blowing agent is a hydrofluoroolefin (HCFO), preferably HFCO-1234ze in combination with a hydrochlorofluoroolefin (HCFO) preferably one selected from HCFO-1233zd, HCFO-1223, HCFO-1233xf and mixtures thereof. The blowing agent is effective as a blowing agent in the manufacture of thermosetting foams.

Abstract: A foamed sheet of a base resin containing 50 to 100% by weight of a polylactic acid resin and having an apparent density of 63 to 630 kg/m3, a thickness of 0.5 to 7 mm and endothermic and exothermic calorific values of ?Hendo:2 and ?Hexo:2, respectively, as measured by heat flux differential scanning calorimetry at a heating rate of 2° C./min. The endothermic calorific value ?Hendo:2 is at least 10 J/g and the difference (?Hendo:2??Hexo:2) between the endothermic calorific value ?Hendo:2 and the exothermic calorific value ?Hexo:2 is less than 40 J/g. A foam molding such as a receptacle is prepared by thermoforming the foamed sheet.

Abstract: A composition which comprises 1,1,1,3,3-pentafluorobutane (HFC-365mfc) and 1,1,1,3,3-pentafluoropropane (HFC-245fa) in a weight ratio HFC-365mfc/HFC-245fa of from 60:40 to 75:25.

Abstract: There is presented a new flame retardant composition comprising a brominated aromatic composition and a butyl substituted phenyl phosphate.

Abstract: Composition for preparing a biodegradable polyurethane-based foam and a biodegradable polyurethane foam, comprising mixtures based on poly(hydroxybutyrate) polymer, polyols of renewable source, isocyanates and additives, with the object of preparing biodegradable polyurethane foams. In the process, the poly(hydroxybutyrate) plus the polyol, the isocyanate and the additives are previously mixed in specific mixers; once the homogenization is reached, the mixture is poured in mold for growing. After curing, the resulting product presents foam characteristics, with its density, toughness and cell size varying according to the proportion of the reagents and allowing the manufacture of several products.

Abstract: Mixtures of tetrafluoropropenes with bromofluoropropenes provide compositions that have boiling points within an acceptable range, have good chemical stability, low GWP and are essentially non-flammable.

Abstract: A composition used for preparing foaming material comprising a polyhydroxyalkanoate, a polylactic acid and a foaming agent, which posses certain tensile strength, elongation in break and expansion ratio as well as full bio-degradability, thus can be used in packaging industry.

Abstract: The invention relates to a process for producing rigid polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein at least one graft polyol b1) which can be prepared by in-situ polymerization of olefinically unsaturated monomers in a polyether alcohol b1i), where the polyether alcohol b1i) has a functionality of from 2 to 4 and a hydroxyl number in the range from 100 to 250 mg KOH/g, its polyether chain comprises propylene oxide and up to 20% by weight, based on the polyether alcohol b1i), of ethylene oxide, and acrylonitrile and styrene in a weight ratio of acrylonitrile:styrene of from >1:1 to 4:1 are used as olefinically unsaturated monomers, is used as compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b), and the reaction is carried out in the presence of at least one compound b1ii) which has at least one olefinic double bond an

Abstract: Heat transfer compositions are usable in their own right or are suitable as a replacement for existing refrigeration usages. The compositions possess a reduced Greenhouse Warming Potential, yet have a capacity and energy efficiency (which may be conveniently expressed as the “Coefficient of Performance”) ideally within 20% of the values of those attained using R-134a, and preferably within 10% or less (e.g. about 5%) of these values.

Abstract: Foamable, isocyanate-functional organopolysiloxanes with more uniform molecular weights are produced by reaction of an aminoalkyl or hydroxyalkyl functional organopolysiloxane with a stoichiometric excess of a di- or polysiocyanate in the presence of a compatibilizer which provides a homogenous reaction mixture.

Abstract: Composition in the foam form containing a continuous oily phase and at least one structuring agent for the oily phase chosen from polymeric structuring agents. Method of use. Kit.

Abstract: The invention pertains to a process for producing a cross-linked polyolefin foam in a continuous process using standard processing equipment without using a moisture cross-linking step after processing. In this method, a vinyl functional silane compound is melt grafted onto a low density polyethylene in the presence of a free radical generator. The resulting silane grafted polyethylene resin is mixed and melted with a blowing agent in a continuous process in the presence of water to form a vinyl functional silane foam.

Abstract: A method for improving the processability of foam premixes containing HFC and/or pentane-based blowing agents in polyols is provided, which method comprises adding trans-1,2-dichloroethylene to said premix in an amount effective to enhance said processability.

Abstract: Disclosed are compositions comprising at least one iodocarbon compound and preferably at least one stabilization agent comprising a diene-based compound. These compositions are generally useful as refrigerants for heating and cooling, as blowing agents, as aerosol propellants, as solvent composition, and as fire extinguishing and suppressing agents.

Abstract: A polyurethane foam for vehicles is obtained by reaction, foaming, and curing of a polyurethane-foam raw material comprising polyol, polyisocyanate, a blowing agent, and a catalyst, and is used for vehicle parts. The foam raw material comprises expanded graphite and an inorganic compound hydrate. The polyol preferably comprises polymeric polyol in which a polyether polyol is graft-polymerized with a vinyl monomer, polyether polyol having a mass average molecular weight of from 400 to 1,000 in which a polyhydric alcohol is addition-polymerized with an alkylene oxide, and polyether polyol having a mass average molecular weight of from 2,000 to 4,000 in which a polyhydric alcohol is addition-polymerized with an alkylene oxide.

Abstract: A low-k organic dielectric material having stable nano-sized porous is provided as well as a method of fabricating the same. The porous low-k organic dielectric material is made from a composition of matter having a vitrification temperature (Tv-comp) which includes a b-staged thermosetting resin having a vitrification temperate (Tv-resin), a pore generating material, and a reactive additive. The reactive additive lowers Tv-comp below Tv-resin.

Abstract: A blowing agent blend for making thermoplastic polymer foams comprises methyl formate. The blowing agent blend can further comprise at least one co-blowing agent. The co-blowing agent is either a physical co-blowing agent (e.g. an inorganic agent, a hydrocarbon, a halogenated hydrocarbon, a hydrocarbon with polar, functional group(s), water or any combination thereof), or a chemical co-blowing agent, or combinations thereof. The thermoplastic polymer foam can be an alkenyl aromatic polymer foam, e.g. a polystyrene foam. The blowing agent blend can comprise any combination of methyl formate and one or more co-blowing agents. The methyl formate-based blowing agent blends produce stable foams for various applications, including containers, packaging systems, as well as insulation boards and building materials. A process for the preparation of such foams is also provided.

Abstract: A blowing agent blend for making thermoplastic polymer foams comprises methyl formate. The blowing agent blend can further comprise at least one co-blowing agent. The co-blowing agent is either a physical co-blowing agent (e.g. an inorganic agent, a hydrocarbon, a halogenated hydrocarbon, a hydrocarbon with polar, functional group(s), water or any combination thereof), or a chemical co-blowing agent, or combinations thereof. The thermoplastic polymer foam can be an alkenyl aromatic polymer foam, e.g. a polystyrene foam. The blowing agent blend can comprise 100 mol % methyl formate, or it can comprise any combination of methyl formate and one or more co-blowing agents. The methyl formate-based blowing agent blends produce stable foams. A process for the preparation of such foams is also provided.

Abstract: A thermoprocessable polymeric composition formed by ethylene/chlorotrifluoroethylene copolymers containing from 0.5 to 20% by moles of ethylene, optionally in combination with the chlorotrifluoroethylene homopolymer, wherein the composition contains in total from 90 to 99.5% by moles of chlorotrifluoroethylene and from 0.5-10% by moles of ethylene; said polymeric composition having a second melting temperature (TmII) higher than 185° C., preferably higher than 200° C.