Nitrogen Patents (Class 522/116)
  • Patent number: 5728505
    Abstract: Aqueous processable, photopolymerized coating compositions are disclosed, which after curing, have superior flexibility for use as permanent coatings for the protection of printed circuitry.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: March 17, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Thomas Eugene Dueber, Frank Leonard Schadt, III
  • Patent number: 5652281
    Abstract: Disclosed are graft copolymers of polyolefins and a method of preparing the graft copolymers. The method includes irradiating a mass of olefin polymer particles and thereafter treating the mass of particles with a vinyl monomer in liquid form. A nonoxidizing environment is maintained throughout the process while free radicals produced in the olefin polymer by the irradiation are present, thereby preventing degradation of the polymer. In a final step, residual free radicals are deactivated, and any unreacted monomer is removed.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: July 29, 1997
    Assignee: Montell North America Inc.
    Inventors: Paolo Galli, Anthony J. DeNicola, Jr., Jeanine A. Smith
  • Patent number: 5627011
    Abstract: The invention relates to the use of oxime sulfonates of formula 1 ##STR1## wherein R is naphthyl, ##STR2## Ar is an unsubstituted aryl group or an aryl group which carries one or more than one substituent selected from the group consisting of nitro, chloro, bromo, hydroxyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 perfluoroalkyl, C.sub.1 -C.sub.4 alkoxy and acid degradable substituents;R.sub.0 is either a R.sub.1 --X group or R.sub.2 ;X is an oxygen or a sulfur atom;R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl or unsubstituted phenyl or phenyl which is substituted by a member selected from the group consisting of chloro, bromo, C.sub.1 -C.sub.4 alkyl and C.sub.1 -C.sub.4 alkoxy, andR.sub.2 is hydrogen, C.sub.1 -C.sub.
    Type: Grant
    Filed: May 12, 1995
    Date of Patent: May 6, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Norbert Munzel, Reinhard Schulz, Heinz Holzwarth, Stephan Ilg
  • Patent number: 5612391
    Abstract: Contact lenses formed from compounds of formula I: ##STR1## are disclosed. The compounds are photoinitiators which can be functionalized by means of ethylenic groups or can be bonded to H-active substances, in order, for example, to modify surfaces by means of photopolymerizable substances. The compounds are especially useful in the manufacture of contact lenses.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 18, 1997
    Assignee: Ciba Geigy Corporation
    Inventors: Peter Chabrecek, Dieter Lohmann
  • Patent number: 5576146
    Abstract: A photosensitive polymer-containing system containing: (a) an energy sensitive polymer having a linear hydrocarbyl backbone and pendant peptide groups with free-radically polymerizable functionality attached thereto; (b) a vinyl-halomethyl-s-triazine capable of free-radical generation upon excitation with electromagnetic radiation having a wavelength of from about 330 to 500 nm; (c) an organic acid having a pKa of from about 1.8 to 5.5; (d) a leuco dye; and (e) a binder. A colorant may optionally be added. The photosensitive systems exhibit an increased shelf-life and excellent photosensitivity.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: November 19, 1996
    Assignee: Imation Corp.
    Inventor: M. Zaki Ali
  • Patent number: 5536759
    Abstract: This invention is a hot melt pressure sensitive adhesive formed by copolymerizing acrylic, or a combination of acrylic and vinyl, monomers, at least one of which is a photoinitiator, with the functional monomer, 1-(1-isocyanato-1-methyl ethyl)-3-(1-methyl ethenyl)benzene (m-TMI), to give a saturated polymer with pendant vinyl groups that are crosslinked by UV radiation.
    Type: Grant
    Filed: October 13, 1994
    Date of Patent: July 16, 1996
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Roopram Ramharack, Rama Chandran
  • Patent number: 5530036
    Abstract: An epoxy group-containing thermosetting resin composition comprising (A) a copolymer obtained From (a) at least one member selected from an unsaturated carboxylic acid and an unsaturated carboxylic acid anhydride, (b) an epoxy group-containing unsaturated compound, (c) a monoolefin unsaturated compound, and optionally (d) a conjugated diolefin unsaturated compound, and (B) an organic solvent for dissolving the above copolymer. There is also provided another epoxy-group containing thermosetting resin composition which contains the above component (A), (C) a polymerizable compound having at least one ethylenically unsaturated double bond, and (D) a photopolymerization initiator. These epoxy-group containing thermosetting resin compositions are excellent in storage stability.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: June 25, 1996
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Kimiyasu Sano, Masayuki Endo, Atsufumi Shimada, Yasuaki Yokoyama, Nobuo Bessho
  • Patent number: 5451453
    Abstract: Supports having azlactone-functional surfaces, adduct supports prepared from such azlactone-functional supports, and methods of preparing both are disclosed. Azlactone functionality is introduced to surfaces of a pre-existing support in a manner which retains useful physical and chemical characteristics of the pre-existing support. One method involves exposing surfaces with high energy radiation to generate free radical reaction sites on the surfaces and causing azlactone-functional moieties to react with the free radical reaction sites. Another method involves coating surfaces with azlactone monomers, crosslinking monomers, and optionally co-monomers and polymerizing the monomers to form a polymerized coating of azlactone-functionality on the surfaces. Another method involves dispersion polymerization of azlactone-functional moieties to produce azlactone-functional particles within pores and interstices of a pre-existing support.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: September 19, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: David R. Gagnon, Patrick L. Coleman, Gary J. Drtina, Oh-Seung Kwon, Christopher S. Lyons, Dean S. Milbrath, Jerald K. Rasmussen, Julie B. Stahl
  • Patent number: 5420171
    Abstract: A UV curable organic solvent soluble, aqueous nonalkaline soluble and peelable temporary solder mask composition to be applied to a surface to be protected, having a reactive diluent monomer capable of polymerization upon exposure to ultraviolet light and a photoinitiator serving as a free radical source to initiate polymerization.
    Type: Grant
    Filed: December 31, 1991
    Date of Patent: May 30, 1995
    Assignee: Tech Spray, Inc.
    Inventor: Greg R. Unruh
  • Patent number: 5413863
    Abstract: Holographic films are disclosed that contain a binder having the following formula:(M).sub.w (VAc).sub.x (VOH).sub.y (VOS).sub.zwherein M is a fluoromonomer; VAc is vinyl acetate; VOH is vinyl alcohol; and VOS is vinyl trimethylsilyl ether; and wherein w, x, y, and z are percentages by weight; w is 5 to 30, x is 40 to 80, y is 0 to 20, and z is 2 to 30; said copolymers containing 3 to 23% by weight fluorine. These imaged films are particularly suited for lamination to glass in head-up display applications.
    Type: Grant
    Filed: November 4, 1993
    Date of Patent: May 9, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Andrew M. Weber, Aleksander Beresniewicz
  • Patent number: 5411994
    Abstract: Disclosed are graft copolymers of polyolefins and a method of preparing said graft copolymers. The method comprises irradiating a mass of olefin polymer particles and thereafter treating the mass of particles with a vinyl monomer in liquid form. A nonoxidizing environment is maintained throughout the process while free radicals produced in the olefin polymer by the irradiation are present, thereby preventing degradation of the polymer. In a final step, residual free radicals are deactivated, and any unreacted monomer is removed.
    Type: Grant
    Filed: November 6, 1992
    Date of Patent: May 2, 1995
    Assignee: Himont Incorporated
    Inventors: Paolo Galli, Anthony J. DeNicola, Jr., Jeanine A. Smith
  • Patent number: 5389699
    Abstract: UV-crosslinkable materials based on (meth)acrylate copolymers and containing from 0.01 to 10% by weight, based on the copolymer, of copolymerized monomers of the formula I ##STR1## where x is alkyl of 1 to 3 carbon atoms or is phenyl which is unsubstituted or substituted by n Y groups, Y is --H, --CF.sub.3, --O-- alkyl and/or alkyl-COO--, where alkyl in each case is of 1 to 4 carbon atoms, halogen, --CH, --COOH or a non-ortho --OH group, n is from 0 to 4 and Z is a group of the formula ##STR2## where R is H or C.sub.1 -C.sub.4 -alkyl and A is an alkylene, oxaalkylene or polyoxaalkylene radical of 2 to 12 carbon atoms are used as hotmelt adhesives, for coating sheet-like mineral substrates and as surface coatings.
    Type: Grant
    Filed: July 8, 1993
    Date of Patent: February 14, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Rehmer, Andreas Boettcher, Michael Portugall
  • Patent number: 5385956
    Abstract: The method concerns preparing a polymer composition containing an electrically conductive polymer which is formed, in the presence of a catalyst, from polymerizable monomer units that are converted from non-polymerizable precursor monomers with the aid of a sufficiently energy-intense light source. In this method according to the invention is that the precursor monomers have a structure according to formula (I). The method according to the invention makes it possible to very easily and rapidly, and thus economically, prepare a polymer composition containing an electrically conductive polymer. Furthermore, the method according to the invention permits a polymer composition to be produced that contains an electrically conductive polymer in specifically pre-selected areas.
    Type: Grant
    Filed: July 15, 1993
    Date of Patent: January 31, 1995
    Assignee: DSM N.V.
    Inventors: Ronald M. A. M. Schellekens, Hans K. Van Dijk
  • Patent number: 5380772
    Abstract: A modelling liquid used for building up dental porcelain, comprising:(A) a photopolymerizable compound having at least one ethylenically unsaturated double bond,(B) a photopolymerization initiator,(C) a reducing agent, and(D) a polymerization inhibitor.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: January 10, 1995
    Assignee: G-C Toshi Kogyo Corporation
    Inventors: Akira Hasegawa, Tsugumichi Kawasaki
  • Patent number: 5361616
    Abstract: A coating composition having photopolymerizability and heat curability, which comprises, as main components,(A) a vinyl copolymer having polymerizable double bonds and crosslinkable hydroxyl groups,(B) a condensation polymerizable compound of the following formula (i) or a condensation polymer thereof, and(C) a photopolymerization initiator: ##STR1## wherein each of the plurality of R which may be the same or different, is --H, --CH.sub.2 OH, --CH.sub.2 OCH.sub.3, --CH.sub.2 OC.sub.4 H.sub.
    Type: Grant
    Filed: June 9, 1992
    Date of Patent: November 8, 1994
    Assignee: Dai Nippon Toryo Co., Ltd.
    Inventors: Toshiya Takahashi, Norio Uriya, Yoshihisa Nagashima
  • Patent number: 5356950
    Abstract: A grafted polymer of an isomonoolefin and an alkylstyrene, such as a maleic anhydride-grafted copolymer of isobutylene and para-methylstyrene, is provided. Processes for preparing the grafted polymer are also provided.
    Type: Grant
    Filed: April 26, 1993
    Date of Patent: October 18, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Donald A. White, Hsien C. Wang
  • Patent number: 5344701
    Abstract: Supports having azlactone-functional surfaces, adduct supports prepared from such azlactone-functional supports, and methods of preparing both are disclosed. Azlactone functionality is introduced to surfaces of a pre-existing support in a manner which retains useful physical and chemical characteristics of the pre-existing support. One method involves exposing surfaces with high energy radiation to generate free radical reaction sites on the surfaces and causing azlactone-functional moieties to react with the free radical reaction sites. Another method involves coating surfaces with azlactone monomers, crosslinking monomers, and optionally co-monomers and polymerizing the monomers to form a polymerized coating of azlactone-functionality on the surfaces. Another method involves dispersion polymerization of azlactone-functional moieties to produce azlactone-functional particles within pores and interstices of a pre-existing support.
    Type: Grant
    Filed: June 9, 1992
    Date of Patent: September 6, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: David R. Gagnon, Patrick L. Coleman, Gary J. Ortina, Christopher S. Lyons, Dean S. Milbrath, Jerald K. Rasmussen, Julie B. Stahl
  • Patent number: 5314962
    Abstract: An acrylate is polymerized by the photo-decomposition of ##STR1## to make a polymeric intermediate containing dithiocarbamate groups at both its ends, and a hard polymer-forming monomer is polymerized by the photo-decomposition of this dithiocarbamate group-containing polymeric intermediate to form blocks of a polymer of said hard polymer-forming monomer on both sides of said polymeric intermediate, thereby forming an ABA type block copolymer.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: May 24, 1994
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Takayuki Otsu, Shunichi Himori, Takashi Kiriyama
  • Patent number: 5264533
    Abstract: UV-crosslinkable materials based on (meth)acrylate copolymers and containing special modified unsaturated benzophenone derivatives as copolymerized units are used as hotmelt adhesives, for coating sheet-like mineral substrates and as surface coatings.
    Type: Grant
    Filed: August 1, 1991
    Date of Patent: November 23, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerd Rehmer, Andreas Boettcher, Michael Portugall
  • Patent number: 5250389
    Abstract: Disclosed is a photosensitive elastomer composition comprising (1) a thermoplastic block copolymer comprising at least one monovinyl substituted aromatic hydrocarbon polymer block and at least one conjugated diene polymer block, wherein a monovinyl substituted aromatic hydrocarbon content (A) is 10 to 35% by weight, and the vinyl content (V) of a conjugated diene is 20 to 50%, and the (A) and the (V) satisfy the formula: 40.ltoreq.(A)+(V).ltoreq.70; (2) an ethylenically unsaturated compound component; and (3) a photopolymerization initiator.
    Type: Grant
    Filed: May 12, 1992
    Date of Patent: October 5, 1993
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Shohei Nakamura, Kousi Anai
  • Patent number: 5230987
    Abstract: Disclosed is a water developable photosensitive resin composition suitable for a printing plate, which has excellent dimensional stability and excellent chemical and physical properties. The photosensitive resin composition comprises;(A) an acrylic resin of which glass transition temperature (T.sub.g), as defined by ##EQU1## [wherein T.sub.g1, T.sub.g2, . . . represents a glass transition temperature of a homopolymer prepared from each monomer, T.sub.g0 represents a glass transition temperature of a copolymer and W.sub.1, W.sub.2, . . . shows a weight fraction of each monomer.] and acid value (AV) satisfy the following relations;60.degree. C..ltoreq.T.sub.g .ltoreq.125.degree. C.80 mg KOH/g.ltoreq.AV.ltoreq.130 mg KOH/g, andT.sub.g -10.ltoreq.AV.ltoreq.T.sub.g +40(B) a basic nitrogen atom-containing compound(C) an ethylenically unsaturated monomer, and(D) a photopolymerization initiator.
    Type: Grant
    Filed: May 29, 1990
    Date of Patent: July 27, 1993
    Assignees: Nippon Paint Co. Ltd., Mitsubishi Rayon Co., Ltd.
    Inventors: Toshitaka Kawanami, Yasushi Umeda, Norihisa Osaka
  • Patent number: 5227279
    Abstract: Disclosed is a polymer having a group represented by the following formula (I) or (II) in a side chain on a main chain consisting of carbon-carbon bonds: ##STR1## [wherein X is an oxygen atom, a sulfur atom or N--R.sup.1, R.sup.1 is a hydrogen atom, an alkyl group containing 1 to 3 carbon atoms or CH.sub.2 CO.sub.2 H], said group being decarboxylated by photo-reaction of its own or by photo-reaction with a photo-sensitizer which absorbs light to generate a free radical.
    Type: Grant
    Filed: March 24, 1992
    Date of Patent: July 13, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventor: Masami Kawabata
  • Patent number: 5221589
    Abstract: Disclosed is a photosensitive resin composition which, can be hot melt molding and and is water-developable. The composition does not need the preliminary exposure process and when cured has suitable hardness and printing properties. The photosensitive resin composition comprises;(A) a water soluble or water dispersible polyvinyl alcohol prepared by saponifying a copolymer obtained by copolymerizing 90 to 99.9 mol % of a vinyl ester and 0.1 to 10 mol % of an ionic group-containing monomer; said polyvinyl alcohol having a saponification degree of the vinyl ester unit of 60 to 75 mol % and a hot melt flow starting temperature of 95.degree. to 170.degree. C.,(B) a polymerizable compound prepared by reacting in the presence of an acid catalyst, (i) N-methylol (meth)acrylamide or N-alkoxymethyl (meth)acrylamide and (ii) a compound selected from the group consisting of monoalcohols, polyhydric alcohols, amides, haloalkylamides, aromatic compounds, ureas and mixtures thereof, and(C) a photopolymerization initiator.
    Type: Grant
    Filed: April 3, 1991
    Date of Patent: June 22, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Osamu Nanba, Chitoshi Kawaguchi, Seiji Arimatsu, Kazunori Kanda
  • Patent number: 5202361
    Abstract: Radiation-curable, tackifier-free compositions are provided which contain: (i) a blend of certain acrylate esters and monoethylenically-unsaturated copolymerizable monomers; (ii) certain .alpha.-olefin polymers; and (iii) a photoinitiator and optionally, a crosslinker. Pressure-sensitive adhesives having good adhesion to both low and high energy surfaces as well as possessing excellent low and high temperature performance properties are prepared by exposing the radiation-curable compositions to light having a wavelength in the range of from about 280 to 400 nm.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: April 13, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Patrick G. Zimmerman, Gaddam N. Babu, Lang N. Nguyen, Ingrid E. Blair, George F. Vesley
  • Patent number: 5196478
    Abstract: This invention relates to radio-derivatized polymers and a method of producing them by contacting non-polymerizable conjugands with radiolysable polymers in the presence of irradiation. The resulting radio-derivatized polymers can be further linked with ligands of organic or inorganic nature to immobilize such ligands.
    Type: Grant
    Filed: April 9, 1990
    Date of Patent: March 23, 1993
    Assignee: Epipharm Allergie-Service Gesellschaft m.b.H.
    Inventors: Janos M. Varga, Peter Fritsch
  • Patent number: 5194454
    Abstract: According to the invention the material, in particular a textile, includes in its polymeric structure grafts forming complexes with at least one metal ion possessing recognized antiseptic activity. These grafts are formed by polymerization of unsaturated monomers with a complexing function, including the phosphate of ethylene glycol methacrylate or a polymerizable derivative of quinoline such as acryl 8-hydroxy quinoline. The process of preparation comprises a first step of grafting, for example by electronic irradiation of the material and impregnation with a bath of monomer, and a second step of impregnation of the grafted material with one or serveral baths containing the metal ion(s), such as copper, zinc, tin, mercury.
    Type: Grant
    Filed: January 29, 1991
    Date of Patent: March 16, 1993
    Assignee: Centre Technique Industriel dit: Institut Textile De France
    Inventors: Roger Chatelin, Louis Gavet, Michel Bourgeois, Christine Darroux
  • Patent number: 5185188
    Abstract: A method for surface treating a resin composition molded article and a method for coating a resin composition molded article are disclosed, which comprise irradiating a molded article with ultraviolet light having an irradiation wavelength in the region of 300 nm or less and, if desired, coating the thus UV-irradiated surface with a coating, the molded article being obtained from a resin composition comprising (I) 100 parts by weight of a resin composition comprising (A) from 5 to 99.5% by weight of a polypropylene resin selected from the group consisting of polypropylene, modified polypropylene, and a modified polypropylene/polypropylene composition and (B) from 0.
    Type: Grant
    Filed: November 21, 1990
    Date of Patent: February 9, 1993
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Hiroomi Abe, Hideo Shinonaga, Kiyoshi Mitsui, Satoru Sogabe
  • Patent number: 5164424
    Abstract: A polymer is disclosed which has a betaine structure on at least one side chain. The polymer according to this invention is suitable for use as a material for producing a pervaporation membrane. A process is described for producing the polymer according to this invention whereby betaine groups are introduced into a starting polymer. The betaine groups are introduced into the starting polymer by irradiation of the starting polymer with ionizing radiation and then treatment of the irradiated starting polymer with monomers that are capable of a graft reaction. Monomers that either already contain a betaine function or are capable of forming such a function are used. The betaine can be formed, e.g., by alkylating quaternation of a nitrogen atom present in the monomer if an acid group is introduced simultaneously with the alkylating agent.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: November 17, 1992
    Assignee: Deutsche Carbone AG
    Inventors: Hartmut E. A. Brueschke, Guenter F. Tuesel, Guido Ellinghorst, Axel Niemoeller
  • Patent number: 5143947
    Abstract: Radiation curable compositions useful as coatings for wood, metal, glass, fabric, paper, fiber and plastics are made from copolymers of 4-hydroxystyrene and an alkadiene or an allyl ester of an ethylenically unsaturated acid blended wit ethylenically unsaturated compounds.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: September 1, 1992
    Assignee: Hoechst Celanese Corporation
    Inventor: Balaram Gupta
  • Patent number: 5096790
    Abstract: A new class of sensitizers for photopolymerizable compositions is disclosed derived from cyclic ketones and tricyclic aminoaldehydes. A preferred compound is cyclopentanone, 2.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: March 17, 1992
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Bruce M. Monroe
  • Patent number: 5079047
    Abstract: The current invention provides a photopolymerized pressure-sensitive adhesive which adheres well to all common surfaces and has an outstanding ability to bond to plasticized vinyl substrates and to remain firmly bonded thereto even after the in contact therewith for extended periods of time comprising the photopolymerization reaction product of a mixture containing about: 60-95 parts of alkyl acrylate; 5-40 parts monoethylenically unsaturated polar copolymerizable monomer; 10-30 parts ethylene vinylacetate copolymer containing about 40% to 70% vinylacetate; and 0.1-1 part photoinitiator.
    Type: Grant
    Filed: May 12, 1989
    Date of Patent: January 7, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Yvan A. Bogaert, Martine H. A. Deketele
  • Patent number: 5075347
    Abstract: An improved process for forming hydroperoxide derivatives of rubbery polymers. The hydroperoxide derivatives being particularly well suited for use as intermediates in forming graft rubbery polymers. The process involves dissolving a rubbery polymer in a monomer mixture and adding to the rubbery polymer/monomer mixture a photosensitizing agent. The rubbery polymer-monomer mixture is then oxygenated and exposed to light under conditions wherein triplet oxygen is converted to singlet oxygen. The improvement comprises adding to the rubbery polymer/monomer mixture a solvent capable of solubilizing the photosensitizing agent in the rubbery polymer/monomer mixutre. The solubilizer increases the yield of hydroperoxide derivatives of rubbery polymers formed by a factor of 3.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: December 24, 1991
    Assignee: The Dow Chemical Company
    Inventors: Alan E. Platt, Jerry L. Hahnfeld, David A. Habermann
  • Patent number: 5057390
    Abstract: A photosensitive composition characterized by comprising:(a) a vinyl alcohol polymer containing the following structural unit A and having a saponification degree of a vinyl ester unit of not less than 70 mol %: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 each represents H or a hydrocarbon group having 1 to 4 carbon atoms;(b) a radically polymerizable ethylenic unsaturated compound; and,(c) a photopolymerization initiator,having flexiblity and impact resistance which can maintain sufficient softness but are not broken particularly even at low temperature and low humidity so that resin plates showing high printing quality can be obtained from the photosensitive composition.
    Type: Grant
    Filed: November 20, 1986
    Date of Patent: October 15, 1991
    Assignee: Kuraray Company, Ltd.
    Inventors: Toshiaki Sato, Junnosuke Yamuchi, Takuji Okaya
  • Patent number: 5026742
    Abstract: Radiation-crosslinkable contact adhesive mixtures are prepared from polymers having a glass transition temperature of less than 0.degree. C. and a K value of from 20 to 80, derivatives of dihydroxypropyl (meth)acrylates as reactive diluents and small amounts of polymerizable tertiary amino compounds by a process in which the mixture is heated at from 80.degree. to 120.degree. C. for not more than 2 hours and solvents are then separated off under atmospheric or reduced pressure.
    Type: Grant
    Filed: August 15, 1989
    Date of Patent: June 25, 1991
    Assignee: BASF Aktiengesellschaft
    Inventor: Gerd Rehmer
  • Patent number: 5002975
    Abstract: Liquid, photocurable coating compositions containing nitrile copolymers. Such compositions comprises from about 10 percent to about 60 percent by weight of a high nitrile copolymer, containing at least about 70 percent by weight of a nitrile polymer; from about 30 percent to 90 percent by weight of a photopolymerizable solvent for the high nitrile copolymer, wherein the photopolymerizable solvent is selected from the group consisting of N-vinyl pyrrolidone, cyanoethylacrylate, styrene, N,N-dimethylacylamide, N,N-methylenebisacrylamide, gamma-butyrolactone and combinations thereof, and from about 0.1 percent to about 10 percent by weight of a photoinitiator soluble in the photopolymerizable solvent for curing the high nitrile copolymer with the incorporation of at least 50 percent by weight of the solvent therein upon exposure to ultraviolet radiation, having a wavelength of from about 2000 .ANG. to 14,000 .ANG.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: March 26, 1991
    Assignee: The Standard Oil Company
    Inventors: Rosemary Bartoszek-Loza, Richard J. Butler
  • Patent number: 4996134
    Abstract: A conjugated diene copolymer comprising (A) 10 to 60 mole % of a conjugated diene compound unit, (B) 5 to 50 mole % of an .alpha.,.beta.-ethylenically unsaturated carboxylic acid unit, (C) 0.1 to 20 mole % of a polyfunctional alkenyl compound unit, (D) 0 to 10 mole % of a diene compound unit having cyclic carbon-carbon double bonds and (E) 0 to 80 mole % of a monoolefinically unsaturated compound unit, the sum of the amounts of units (A), (B), (C), (D) and (E) being 100 mole %, said copolymer having an intrinsic viscosity [.eta.] of 0.01 to 3.0 dl/g as measured at 30.degree. C. in dimethylformamide. The copolymer is soluble in aqueous alkali solutions, excels in processability and photosetting property, and has excellent rubber elasticity and transparency even after photosetting.
    Type: Grant
    Filed: March 26, 1985
    Date of Patent: February 26, 1991
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hiroji Enyo, Shin-ichiro Iwanaga, Yasuhiko Takemura
  • Patent number: 4987053
    Abstract: Compounds of the general formula I ##STR1## are described in which Q denotes ##STR2## R denotes alkyl, hydroxyalkyl or aryl, R.sup.1 and R.sup.2 denote H, alkyl or alkoxyalkyl,R.sup.3 denotes H, methyl or ethyl,D.sup.1 and D.sup.2 denote saturated hydrocarbon groups,E denotes alkylene, cycloalkylene, arylene, saturated or unsaturated heteroyls or a group of the formula II ##STR3## a and b denote integers from 1 to 4. c denotes an integer from 1 to 3,m denotes 2, 3 or 4, depending on the valency of Q, andn denotes an integer from 1 to m, where all radicals of the same definition may be identical to or different from one another.The compounds are suitable as polymerizable compounds for photopolymerizable mixtures and are distinguished by ready polymerizability in combination with photoinitiators and long shelf lives in the layer.
    Type: Grant
    Filed: November 14, 1988
    Date of Patent: January 22, 1991
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Joachim Gersdorf, Klaus Rose
  • Patent number: 4980269
    Abstract: A photosensitive elastomeric composition comprising (1) at least one elastomer, (2) an addition-polymerizable compound having at least one CH.sub.2 .dbd.C< group and (3) a polymerization initiator activatable by actinic light, wherein the elastomer (1) is an elastomer selected from (a) an elastomeric polymer composed of a polyene monomer containing at least two non-conjugated double bonds and a conjugated diene-type monomer or both a conjugated diene-type monomer and a copolymerizable vinyl monomer and (b) an elastomeric linear A-B type (wherein A represents a polymer block of a monovinyl aromatic compound and B represents a polymer block of a conjugated diene-type monomer) block copolymer in which a terminal group having a polymerizable ethylenic double bond is present in at least one end of the molecular chain.
    Type: Grant
    Filed: May 11, 1988
    Date of Patent: December 25, 1990
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Fusayoshi Sakurai, Hiroto Kidokoro, Mitsuhiro Tamura
  • Patent number: 4959178
    Abstract: An actinic radiation curable polymer thick film composition comprising by weight:(a) about 10 to about 20 parts of an unsaturated monomer capable of being polymerized by actinic radiation;(b) about 2.5 to about 8 parts of at least one thermoplastic polymer having a glass transition value of above about 100.degree. F. and not capable of being substantially cross-linked with monomer (a) and said polymer (b) is dissolved in monomer (a);(c) about 68 to about 85 parts of conductive metal particles; and(d) about 0.1 to about 5 parts of at least one actinic radiation polymerization initiator.
    Type: Grant
    Filed: January 27, 1987
    Date of Patent: September 25, 1990
    Assignee: Advanced Products Inc.
    Inventors: Richard L. Frentzel, Noel C. Peralta
  • Patent number: 4957852
    Abstract: In hot embossing plates which are crosslinkable by photopolymerization and comprise(a) a heat-stable, dimensionally stable base and(b) a relief-forming layer which is crosslinkable by photopolymerization and soluble or dispersible in water and contains(b.sub.1) one or more partially or virtually completely hydrolyzed polyvinyl alkanecarboxylates as binders,(b.sub.2) one or more alkenecarbonylamino-N-methylene ethers of polyhydric alcohols as photopolymerizable monomers and(b.sub.3) photopolymerization initiators,the relief-forming layer (b) contains, as further binders (b.sub.1),(b.sub.11) alkenecarboxylates and/or alkenecarbonylamino-N-methylene ethers of partially or virtually completely hydrolyzed polyvinyl alkanecarboxylates and/or(b.sub.12) alkenecarboxylates and/or alkenecarbonylamino-N-methylene ethers of partially or virtually completely hydrolyzed graft copolymers of vinyl alkanecarboxylates and alkylene oxides,and is more than 0.8 mm thick.
    Type: Grant
    Filed: June 10, 1988
    Date of Patent: September 18, 1990
    Assignee: BASF Aktiengesellschaft
    Inventor: Bernd Bronstert
  • Patent number: 4952481
    Abstract: There is hereby provided a photosensitive resin composition suitable for a relief printing plate having an excellent resistance to a water based ink, whereby water or a water like solvent can be employed as a developing solution, which comprises;(i) a polymer (A) having a molecular weight of 5,000 to 500,000 which contains an amino group and a polymerizable double bond moiety,(ii) a monomer (B) having an .alpha.,.beta.-ethylenically unsaturated bond and a free acid group which can quaternize the nitrogen atom of the polymer (A),(iii) a photopolymerizable unsaturated compound (C), and(iv) a photopolymerization initiator (D).
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: August 28, 1990
    Assignee: Napp Systems (USA), Inc.
    Inventors: Mamoru Seio, Hidefumi Kusuda, Masami Kawabata
  • Patent number: 4950549
    Abstract: Polypropylene articles are provided. The polypropylene articles comprise non-crystalline mesomorphous polypropylene having olefinic unsaturation-containing monomers graft-polymerized thereon by ionizing radiation in a dosage sufficient to degrade crystalline polypropylene. The irradiated polypropylene articles retain useful tensile properties after storage periods of as long as at least about four months.
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: August 21, 1990
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard J. Rolando, Dennis L. Krueger, Daniel E. Meyer, Thomas I. Insley
  • Patent number: 4942112
    Abstract: Solid photopolymerizable compositions and photosensitive elements are provided that are useful in preparing optical elements, and especially holograms. The composition contains a polymeric binder, a liquid ethylenically unsaturated monomer, and a photoinitiator system. Typical compositions have a refractive index modulation of at least 0.005 when measured per the specified test.
    Type: Grant
    Filed: January 15, 1988
    Date of Patent: July 17, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Bruce M. Monroe, William K. Smothers
  • Patent number: 4942001
    Abstract: A stereolithographic method which employs an ultraviolet-curable liquid composition adapted to cure rapidly to a lightly cross-linked solvent-swellable three-dimensional complexly-shaped polymeric thin-walled element constituted by heat-softenable solid polymer upon exposure to ultraviolet dosage in the range of about 0.1 to about 10 Joules per square centimeter and which possesses reduced distortion comprises, from 20 to 80 weight percent, of a resinous polyacrylate or polymethacrylate dissolved in a combination of 10 to 45 weight percent of a liquid polyacrylate or polymethacrylate, which is preferably trifunctional, and 10 to 45 weight percent of liquid N-vinyl monomer, preferably N-vinyl pyrrolidone. Thus, the weight ratio of polyacrylate: polymethacrylate: N-vinyl monomer is about 1:2:2 to about 8:1:1. One of the foregoing polyacrylates or polymethacrylates is a polyacrylate and the other is a polymethacrylate so that good cure speed is accompanied by good distortion resistance.
    Type: Grant
    Filed: October 31, 1989
    Date of Patent: July 17, 1990
    Assignee: Inc. DeSoto
    Inventors: Edward J. Murphy, Robert E. Ansel, John J. Krajewski
  • Patent number: 4933260
    Abstract: A water-based photopolymerizable resin composition is disclosed which is suitable for the preparation of a relief printing plate by the photolithographic techniques. The inventive composition, which basically comprises a water-soluble polymer, e.g., poly(vinyl alcohol), a photopolymerizable monomer and a photopolymerization initiator, is characterized in that at least a part of the photopolymerizable monomer is N-tetrahydrofurfuryloxymethyl acrylamide or N-tetrahydrofurfuryloxymethyl methacrylamide. By virtue of this unique ingredient in the composition, the printing plate prepared from the inventive composition is imparted with improved fidelity of pattern reproduction and durability in printing as a consequence of increased hardness and pliability to be freed from the drawback of crack formation in printing even on a cylinder of small diameter under a cold and low-humidity condition.
    Type: Grant
    Filed: August 31, 1989
    Date of Patent: June 12, 1990
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Naoya Katsumata, Syunzi Nakazato, Katsuyuki Ohta, Toshimi Aoyama
  • Patent number: 4927738
    Abstract: A conjugated diene copolymer comprising (A) 40 to 90 mole % of a conjugated diene component, (B) 0.5 to 10 mole % of an alpha,beta-ethylenically unsaturated carboxylic acid component, (C) 0.1 to 5 mole % of a polyfunctional alkenyl compound component and (D) 5 to 58 mole % of a monoolefinically unsaturated compound component wherein the intrinsic viscosity [.eta.] of the copolymer as measured at 30.degree. C. in dimethylformamide is 0.01 to 3.0 dl/g, the width (.DELTA.Tg) of the endothermic transition temperature section determined by a differential scanning calorimetry is 45.degree. to 120.degree. C. and the limit temperature (T.sub.1) on the lower temperature side of the endothermic transition temperature section is -40.degree. C. or less.
    Type: Grant
    Filed: November 24, 1987
    Date of Patent: May 22, 1990
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Shin-ichiro Iwanaga, Tatsuaki Matsunaga, Ituo Nishiwaki, Hiroji Enyo
  • Patent number: 4897433
    Abstract: A process for producing a medical material having high anti-thrombogenicity that is suitable for use in catheters and other medical devices in contact with blood flowing in circulatory organs and other tissues is disclosed. According to this process, an acrylamide or methacrylamide derivative having a tertiary amino group, or an unsaturated monomer having a hydrophihlic group and the ability to promote copolymerization, or a mixture thereof is graft polymerized onto a polyurethane elastomeric or polyolefinic high-molecular weight substrate with an ionizing radiation.
    Type: Grant
    Filed: December 3, 1987
    Date of Patent: January 30, 1990
    Assignees: Japan Atomic Energy Research Inst., Sumitomo Bakelite Co., Ltd.
    Inventors: Takanobu Sugo, Jiro Okamoto, Seiryo Tasaki, Tadayuki Onishi
  • Patent number: 4865743
    Abstract: For producing solution/diffusion membranes, homogeneous dense films prepared by melt extrusion or casting from synthetic polymers, having a melting temperature above 140.degree. C., a glass transition temperature above 0.degree. C. and long time stability against boiling ethanol are irradiated with accelerated electrons and submitted to a subsequent radical graft copolymerization. After graft polymerzation, the functional groups are converted into the dissociated salts.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: September 12, 1989
    Assignee: GFT Gesellschaft fur Trenntechnik mbh
    Inventors: Guido Ellinghorst, Bernd Goetz, Axel Niemoeller, Horst Scholz, Hartmut E. A. Brueschke, Guenter Tusel
  • Patent number: 4851454
    Abstract: Photolytically crosslinkable thermally stable compositions comprising at least one crosslinkable polymer and a crosslinkable quantity of a multifunctional 3,4-disubstituted maleimide. The compositions may be employed to prepare adhesives and photo printing mats.
    Type: Grant
    Filed: October 26, 1987
    Date of Patent: July 25, 1989
    Assignee: The Dow Chemical Company
    Inventors: Jerry E. White, Lu Ho Tung, Mary K. Dehnke
  • Patent number: 4849307
    Abstract: The invention relates to a novel photosensitive recording material which can be developed in aqueous solvents after its imagewise irradiation with actinic light and which consists essentially of a dimensionally stable base (A) and of a photosensitive recording layer (B). The said photosensitive recording layer (B) contains from about 48 to about 85% by weight, based on the photosensitive recording layer (B) of one or more elastomeric graft copolymers (B1) which are selected from the group consisting of polyalkylene oxide - vinyl ester - graft copolymers whose vinyl ester structural units have been hydrolyzed to a degree of not less 50 mol.-% from about 0.01 to about 10% by weight, based on the photosensitive recording layer (B), of one or more photoinitiators (B2), and from about 5 to about 30% by weight, based on the photosensitive recording layer (B), of one or more photopolymerizable monomers (B3).
    Type: Grant
    Filed: December 8, 1987
    Date of Patent: July 18, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Gerhard Hoffmann, Horst Koch, Guenther Schulz