Abstract: The present invention is directed to a photocurable and antistatic resin composition for coating an optical fiber, comprising (A) a photopolymerizable urethane acrylate oligomer, (B) a reactive monomer having at least one (meth)acrylate or vinyl group, (C) a photoinitiator, and (D) an antistatic agent compatible with the oligomer and monomer components, and optionally (E) a pigment or dye. The coating of the inventive composition can increase the productivity of the optical fiber, and provide an optical fiber having a uniform coating layer.

Abstract: A two-part curable ink composition set includes an ink composition A which contains at least a photopolymerization initiator and a polymerizable compound and which does not contain a coloring material, and an ink composition B which contains at least a coloring material and a polymerizable compound and which does not contain a photopolymerization initiator, wherein either one or each of the ink composition A and the ink composition B contains a resin emulsion dispersed in the polymerizable compound.

Abstract: The present invention discloses an apparatus for indicating the passage of time, comprising a substrate and an indicating layer formed on the substrate. The indicating layer comprises a polymer matrix and a predetermined amount of redox compound under the reduced form. The redox compound is dispersed in the polymer matrix and has the following properties: the reduced form of the redox compound reacts with oxygen to form the oxidized form of the redox compound; the hue or color density of the reduced form of the redox compound is different from that of the oxidized form of the redox compound; and the hue or color density of the indicating layer varies as the time for the reduced form of the redox compound contacting with oxygen in environment increases to have the amount of the oxidized form of the redox compound increase so as to indicate the passage of time.

Abstract: An active ray curable ink-jet ink set comprising an active ray curable yellow ink, an active ray curable cyan ink, an active ray curable black ink, and further one or more active ray curable color inks other than yellow, cyan and black, wherein each of the active ray curable inks contains a photo-polymerization initiator, a photo-polymerizable compound, a pigment, and a dispersing agent which has an amine value and an acid value, provided that the acid value is higher than the amine value, and an average particle diameter of the pigment contained in the yellow ink is larger than that of the pigment in the cyan ink and than that of the pigment in the black ink by 0.025-0.090 ?m, and further the average particle diameter of the pigment contained in each of the inks of the active ray curable ink-jet ink set is 0.070-0.220 ?m.

Abstract: There is provided an inkjet ink comprising a photo-acid generating agent which is capable of generating an acid as it is irradiated with light, a color component, and an acid-polymerizable compound which can be polymerized in the presence of an acid, wherein at least 40% of the acid-polymerizable solvent is a vinyl ether compound represented by the following general formula (1): R13—R14—(R13)p ??(1) (Wherein R13(s) is a group selected from the group consisting of a vinyl ether group, a group having a vinyl ether skeleton, an alkoxy group, substituted hydroxyl group and hydroxyl group wherein at least one of R13(s) is vinyl ether group or a group having a vinyl ether skeleton, R14 is a group comprising a substituted or unsubstituted cyclic skeleton and having a valence of (p+1), and p is a positive integer including zero).

Abstract: According to the present invention, there is provided a curable composition, containing a compound (A) having at least one ethylenically unsaturated double bond, a photopolymerization initiator (B), a coloring agent (C), an alkali-soluble resin (D), and a compound (E) having in the molecule a partial structure of urethane, amide or urea.

Abstract: A rustproofing composition has superior properties satisfying rustproofing quality requirements and workability requirements for car underbodies, parts around tires, parts with pockets, plate-bonded parts or the like of car bodies, and containing volatile organic solvent of 20 mass % or less. In a rustproofing composition containing UV curable resin and photopolymerizing initiator and at least one of rustproofing oil and rustproofing wax, the content of nonvolatile component at 105° C. for 3 hours in the rustproofing oil and rustproofing wax is 80 mass % or more, the UV curable resin and photopolymerizing initiator are dissolved or dispersed in the rustproofing oil and rustproofing wax, and the UV curable resin is contained at 0.3 to 10 weight % to the total weight of the composition.

Abstract: The invention relates to UV curable, low gloss overprint varnish coating formulations and cured coatings prepared therefrom. The low gloss overprint varnish formulations contain a Michael addition resin, a polyamide powder and a reactive monomer.

Abstract: A composition comprising one or more radiation curable monomers and/or oligomers and one or heat stable composition comprising at least one radiation-curable alpha, beta-ethylenically unsaturated compound, at least one phenolic stabilizer, and at least one non-phenolic stabilizer selected from the group consisting of hydroperoxide decomposers and free radical traps. The compositions and methods are useful in applications such as radiation curable ink jet systems where viscosity is reduced by heating.

Abstract: To provide a radiation-curable ink composition that can form a high-quality image on not only liquid absorbing materials to be recorded but also non-liquid absorbing materials to be recorded, is superior in curing properties in air, and is superior in storage stability, color tone, light fastness and water resistance of ink, and also to provide an image recording method. The radiation-curable ink composition comprises a monomer having a polymerizable group selected from the group consisting of an acryloyl group, a methacryloyl group, an allyl group, and a vinyl group, an oil-soluble dye, and from 0.005 to 1% by weight of a storage stabilizer, wherein the oil-soluble dye is dissolved in the ink.

Abstract: A gas phase species (such as ozone, H2O2, or N2O) is photodissociated with ultraviolet light into a reactive species that is patternwise directed (e.g., through a mask) onto a surface of a material, such as an organosilicate. The reactive species reacts with the material to form a polar oxidation product such as —OH, thereby resulting in discrete hydrophilic regions separated from each other by hydrophobic regions. The degree of hydrophilicity of the discrete regions may be tailored by controlling the concentration of the reactive species, the ultraviolet light intensity, the temperature to which the material is heated, and exposure time. End products made with the methods are suitable for use in a biomolecular array.

Abstract: The invention is a radiation curable coating containing an antimicrobial agent, where upon irradiation with UV light, the radiation curable coating rapidly cures to a polymeric coating. The polymeric coating has durable antimicrobial properties, being especially effective at preventing the growth of Staphylococcus aureaus and Kleibsella pneumoniae on wood flooring and furniture. The major components in the radiation curable coating are a urethane acrylic oligomer, a radiation cure package, an antimicrobial agent, a cross-linking agent, and optionally, an additive package. The radiation curable urethane oligomer is a relatively short chain backbone urethane polymer that is end capped with a radiation curable moiety, where the moiety is an acrylic. The cross-linking agent is one or more monomers used to lower the viscosity and promote cross-linking, and include acrylate esters of mono-, di-, tri-, or tetrafunctional alcohols. The radiation cure package contains at least one photoinitiator.

Abstract: A novel thixotropic agent comprising urea crystals which comprises at least one compound containing at least one functional group having at least one bond which can be activated with actinic radiation; a novel process for preparing a thixotropic agent comprising urea crystals by reacting at least one primary and/or secondary amine and/or water with at least one polyisocyanate in a liquid organic medium consisting of or comprising at least one compound containing at least one functional group having at least one bond which can be activated with actinic radiation; and the use of the thixotropic agents to prepare coating materials, adhesives and sealing compounds curable thermally and with actinic radiation.

Abstract: In accordance with the present invention, there are provided thermosetting resin compositions with a reduced propensity to shrink in volume upon cure and methods of use therefor. The compositions of the present invention include compounds having aromatic, rigid-rod like spacer groups between the crosslinkable moieties. As such, these compounds impart a degree of liquid crystal-like character to the thermosetting resin composition which results in lower shrinkage upon cure. This effect follows from the well-known expansion that occurs when liquid crystal-like materials pass from a nematic liquid crystal-like state to an isotropic state. Further provided by the present invention are low shrinkage die attach pastes and methods of use therefor.

Abstract: Acrylic composition for use in variety of indoor or outdoor sealing applications, where it is required to seal, to fill or to repair cracks, joints, gaps etc. in concrete, masonry, stone, wood or other constructional materials. The composition comprises acrylic based reactionable oligomers and it can be foamed and then polymerized while producing foam with structure suitable for sealing.

Abstract: Certain essentially phenol antioxidant-free stabilizer systems that comprise either a binary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone system or a ternary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone/organic phosphite or phosphonite system are especially effective towards protecting polyolefins against the deleterious effects of gamma irradiation. Polyolefin articles such as medical packaging, hospital garments, draperies, woven and non-woven fiber products, surgery utensils, blow-molded I.V. bottles, hypodermic syringes, needle shields, laboratory ware such as trays, funnels, Petri dishes and filters, and hygiene related articles may be sterilized with gamma irradiation and are stabilized according to the present invention.

Abstract: Methods of forming crosslinked polymer particles in situ from polymer precursors such as monomers or oligomers, comprising exposing a composition comprising at least one polymer precursor, a solvent or solvent mixture, and an antisolvent or antisolvent mixture to photoradiation under conditions whereby particles are formed are provided. The polymer precursor may be photosensitive, or a separate polymerization initiator may be used. In a preferred embodiment, the polymer precursor is insoluble in the antisolvent or antisolvent mixture and the solvent or solvent mixture is soluble in the antisolvent or antisolvent mixture at the concentrations used. Crosslinked polymer particles and crosslinked polymer particles comprising a polymer and a bioactive material are also provided. The polymer may be erodable, and the polymer particles formed may be used in a variety of applications, including controlled release of bioactive materials such as drugs.

Abstract: Disclosed is a gas-generating, pressure-sensitive adhesive composition comprising a pressure-sensitive, ultraviolet irradiation-curable adhesive (A) containing a photoinitiator, wherein the adhesive (A) transmits therethrough an ultraviolet radiation, and a gas generator compound (B) which generates a gas upon irradiation thereof with an ultraviolet radiation, wherein the gas generator compound (B) is operably combined with the pressure-sensitive, ultraviolet irradiation-curable adhesive (A), so that, in operation, when the gas-generating, pressure-sensitive adhesive composition which is adhered to an adherend is irradiated with an ultraviolet radiation, the gas generator compound (B) generates a gas and the gas effuses at an interface between the gas-generating, pressure-sensitive adhesive composition and the adherend to thereby facilitate release of the adherend from the gas-generating, pressure-sensitive adhesive composition.

Abstract: A radiation curable, flexible, paintable composition produced from epoxy compounds and one or more polyol(s) has enhanced durability, thick and thin film adhesion, resistance to mold growth and dimensional changes while reducing solvent emissions. The composition can reduce, if not eliminate, runs and drips during the thermal bake cycles which are associated with using conventional compositions in automotive applications.

Abstract: An ultrafiltration membrane is modified to exhibit low protein fouling and yet maintains a greater fraction of the original membrane permeability and retention properties after modification. This is achieved by grafting monomer onto the surface of a highly photoactive membrane such as polyethersulfone, via the process of dipping the polymeric membrane into a solution containing one or more monomers and a chain transfer agent, removing the membrane from the solution, securing the membrane inside of a quartz vessel contained within another vessel of liquid filter, and irradiating the membrane with a UV light at a wavelength between the range of 280 nm and 300 nm. High density grafting and shorter grafted monomer chain length result in low protein fouling and retention of permeability.

Abstract: The invention relates to a process for the manufacture of a molding comprising the steps of a) preparing an aqueous solution comprising a water-soluble prepolymer having crosslinkable groups and a further polymer which is devoid of crosslinkable groups, b) introducing the solution obtained into a mold, c) triggering the crosslinking, and d) opening the mold such that the molding can be removed from the mold. According to the process of the invention moldings such as contact lenses may be manufactured with an improved quality and an improved overall yield.

Abstract: The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.).

Abstract: The invention relates to thermoplastic polyolefin compositions having enhanced surface durability and products thereof which include a thermoplastic polyolefin base component at least one radiation-crosslinkable component present in an amount sufficient to enhance the surface durability of the thermoplastic polyolefin component when radiation-cured and at least one photoinitiator present in an amount sufficient to initiate crosslinking of the radiation-crosslinkable component upon exposure of the thermoplastic polyolefin composition to radiation.

Abstract: A liquid colored radiation-curable composition that comprises:

Abstract: Certain essentially phenol antioxidant-free stabilizer systems that comprise either a binary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone system or a ternary hindered amine/hydroxylamine or nitrone or amine oxide or benzofuranone/organic phosphite or phosphonite system are especially effective towards protecting polyolefins against the deleterious effects of gamma irradiation. Polyolefin articles such as medical packaging, hospital garments, draperies, woven and non-woven fiber products, surgery utensils, blow-molded I.V. bottles, hypodermic syringes, needle shields, laboratory ware such as trays, funnels, Petri dishes and filters, and hygiene related articles may be sterilized with gamma irradiation and are stabilized according to the present invention.

Abstract: The present invention provides an aqueous solder resist composition comprising: (a) A water-soluble or water-dispersible, photopolymerizable resin containing at least one polymerizable unsaturated group and at least one carboxyl group, the carboxyl group being neutralized with an amine compound, (b) a photoinitiator, (c) an amino resin, and (d) a low reactivity epoxy compound free of an epoxy group represented by the formula  wherein Y is oxygen or nitrogen.

Abstract: The disclosed invention includes a composition for an optical fiber coating. The cured composition includes at least one monomer and at least one compound from the following group of compounds that consist of an ultra-violet light absorber, a hindered amine light stabilizer, and an optical brightener. The invention also includes an optical fiber coated with the inventive coating.

Abstract: A polyester polymer includes at least one hydroxyl terminated polyoxetane block containing repeat units derived from polymerizing at least one oxetane monomer having a pendant —CH2—O—(CH2)n—Rf group wherein said Rf group is partially or fully fluorinated. A preferred process for forming said polymer is by reacting a hydroxyl terminated polyoxetane with a polycarboxylic acid under appropriate conditions to form an ester linkage and then adding and reacting that product with polyester forming reactants. The polyester polymer containing at least one polyoxetane block therein when reacted with an amino resin curative can be used as a coating on a substrate wherein the coating has dry erase properties. The coated substrate can be used as prepared or applied to yet other substrates.

Abstract: Ink compositions having excellent imaging and a low tendency to foam are disclosed. The ink compositions may contain one or more fluorochemical surfactants. Methods of coating a substrate by printing the ink composition onto a substrate are also disclosed. Substrates coated with an ink composition are further disclosed.

Abstract: A photochromic cured product which has excellent photochromism such as high color density and high fading speed, excellent adhesion to a hard coat and high striping work efficiency. This cured product is obtained by polymerizing and curing a curable composition which comprises (A) a polyfunctional polymerizable monomer such as trimethylolpropane trimethacrylate, (B) a silyl monomer such as &ggr;-methacryloyloxypropyl trimethoxysilane, (C) another radically polymerizable monomer and (D) a photochromic compound. As for the contents of the polymerizable monomers, the content of the component (A) is 1 to 50 wt %, the content of the component (B) is 0.5 to 20 wt % and the balance consists of the component (C) based on the total of the components (A), (B) and (C). The photochromic compound (D) is contained in an amount of 0.0001 to 10 parts by weight based on 100 parts by weight of the total of the components (A), (B) and (C).

Abstract: A curable composition and method for making hollow shell molds, such as those employed to make hearing aids. The curable composition includes a (meth)acryl functionalized curable component, a cure system, a pigment composition, and a dispersion stabilizing additive. The pigment composition includes at least one pigment disbursed within the curable composition. The dispersion additive maintains the pigment in a disbursed form prior to cure. The dispersion additive includes an alkali metal cation and a reaction product.

Abstract: A conductive composition for a biological electrode is capable of reducing the impedance between the electrode and the skin. A conductive gel composition for a biological electrode which is capable of electrically and physically connecting a living body to an electrode element and is composed of at least the following components: (1) a radical-polymerizable unsaturated compound; (2) a moisturizer serving as a plasticizer and functioning to supplementing and promoting the physiological humidifying function of the horny layer; (3) a polymerization initiator; and (4) a crosslinking agent. This moisturizer serves also as a plasticizer and, furthermore, elevates the moisture content in the horny layer at the application of this composition. The above-mentioned composition may further contain a plasticizer selected from among polyhydric alcohols, amines and ethers.

Abstract: The invention relates to thermoplastic polyolefin compositions having enhanced surface durability and products thereof which include a thermoplastic polyolefin base component at least one radiation-crosslinkable component present in an amount sufficient to enhance the surface durability of the thermoplastic polyolefin component when radiation-cured and at least one photoinitiator present in an amount sufficient to initiate crosslinking of the radiation-crosslinkable component upon exposure of the thermoplastic polyolefin composition to radiation.

Abstract: A radiation curable, flexible, paintable composition produced from epoxy compounds and one or more polyol(s) has enhanced durability, thick and thin film adhesion, resistance to mold growth and dimensional changes while reducing solvent emissions. The composition can reduce, if not eliminate, runs and drips during the thermal bake cycles which are associated with using conventional compositions in automotive applications.

Abstract: A water-dispersible, radiation-curable polyurethane composed essentially of a) organic, aliphatic or alicyclic polyisocyanates, b) cycloaliphatic diols and/or cycloaliphatic diamines, c) compounds containing at least one isocyanate-reactive group and at least one free-radically polymerizable unsaturated group, d) compounds containing at least one isocyanate-reactive group and at least one dispersing-active group, e) if desired, compounds containing at least two isocyanate-reactive groups having a molecular weight <1000 g/mol, f) if desired, compounds other than a) to d) containing at least one isocyanate-reactive group.

Abstract: Disclosed herein is a game ball, such as a golf ball, having an indicia formed from a UV curable ink containing aluminum trihydroxide (ATH) filler. The ATH improves pad transfer of the ink. An ink composition suitable for pad printing, and a method for applying an indicia to a game ball also are disclosed. The UV curable ink has excellent pad transfer properties, and good durability.

Abstract: The present invention relates to a method for making a heat-resistant elastic article and a heat-resistant elastic article. The invention especially relates to a method of making elastic fibers and polymeric elastic fibers wherein the elastic fibers are capable of withstanding dyeing and heat-setting processes that typically are conducted at elevated temperatures (such as 110-230° C. and especially at greater than or equal to 130° C. for minutes). The inventive method comprises radiation crosslinking an article (or plurality of articles) under an inert or oxygen limited atmosphere (for example, in N2, argon, helium, carbon dioxide, xenon and/or a vacuum) wherein the article (or articles) comprises at least one amine stabilizer and preferably another optional stabilizer additive. More preferably, the radiation crosslinking is performed at a low temperature (−50 to 40° C.).

Abstract: There are provided a composition for coating which can form an ink receiving layer having excellent adhesion with hydrophobic substrates, water-resistance and printing stability, and an optical recording medium having an ink receiving layer formed from this composition. The composition contains a radiation-curable compound (A) composed of 50 to 90% by weight of a monofunctional (meth) acrylic monomer and 10 to 50% by weight of a multifunctional (meth) acrylic monomer, a water-absorbing organic filler (C) in an amount of 10 to 60% by weight relative to (A), and a water-absorbing inorganic filler (D) in an amount of 1 to 20% by weight relative to (A). This composition is applied on a protecting film (6) and cured to form an ink receiving layer (7), to obtain an optical disk (1).

Abstract: Selectively colorable compositions and a method for forming selectively colored polymeric bodies using such compositions are disclosed. In accordance with the invention, a selectively colorable polymerizable composition comprising a leucobase color former is irradiated with light of a particular wavelength and specific intensity for a specified duration. Exposure to actinic radiation cures the composition and activates the color former. Exposure to higher dosages of actinic radiation can bleach the composition. The irradiation dosage can be varied to selectively color the polymeric body whereby the resultant color of any particular area depends on the exposure dose received at that location. By varying the dose, a polymeric body can be prepared having distinctly colored elements at specific locations.

Abstract: The present invention relates to a process for process for preparing a coating by

Abstract: An ink for ink-jet recording contains a coloring agent, a polymerizable oligomer, water, and a photopolymerization initiator having a solubility in water of 3 percent by weight or more. Another ink for ink-jet recording contains a coloring agent, a polymerizable oligomer having at least two acryloyl groups and a solubility in water of 10 percent by weight or more, a photopolymerization initiator, and water. The specified polymerizable oligomer or photopolymerization initiator reduces bleeding of the ink on recording media.

Abstract: Compounds of the formula I in which R1 is C1-C4alkyl, R2 is hydrogen, C1-C4alkyl or C1-C4alkoxy and R3, R4, R5, R6 and R7 independently of one another are hydrogen, halogen, C1-C20alkyl, cyclopentyl, cyclohexyl, C2-C12alkenyl, C2-C18alkyl which is interrupted by one or more oxygen atoms, or are phenyl-substituted C1-C4alkyl, or are phenyl which is unsubstituted or is mono- or disubstituted by C1-C4alkyl and/or C1-C4alkoxy, with the provisos that at least one of the radicals R3, R4, R5, R6 and R7 is other than hydrogen and that, if R1 and R2 are methyl, R3 and R6 are not methyl, and mixtures of such compounds with &agr;-hydroxy ketones, benzophenones and &agr;-amino ketones, are suitable as photoinitiators.

Abstract: The present invention relates to a process for the production of three-dimensional articles by stereolithography using a radiation-curable composition comprising a mixture of at least one cationically polymerizable compound and/or at least one free radical polymerizable compound, at least one filler material and at least one photoinitiator for cationic and/or radical polymerization. An organic viscosity stabilizer material may be brought into contact with the composition to substantially delay or prevent undesirable viscosity increase and subsequently premature polymerization. A filler material is optionally added to the composition in an effective amount to at least delay or prevent a significant increase in viscosity and polymerization. The process is particularly suitable for stabilizing resins in stereolithography baths.

Abstract: Process for using microwave irradiation to prepare solutions of polymers functionalized with acid groups The invention relates to a process for preparing aqueous, hydrous and anhydrous solutions of polymers functionalized with acid groups, which comprises using microwave radiation to supply the heat required to prepare the solution. The solutions are suitable as a starting material for producing gas diffusion electrodes, fuel cells and polymer-electrolyte-stabilized platinum nanoparticles.

Abstract: A method of preparing a sterile article is disclosed. A polymer having a halogen-containing repeating unit is prepared that contains about 0.

Abstract: A positive-type radiation-sensitive resin composition is provided.

Abstract: An ultraviolet curable ink for stencil printing having a high yield value, hence excellent on-machine stability, is provided, which comprises an ultraviolet curable resin, a pigment, and an organic clay treated with a specific quaternary ammonium salt including a hectorite or bentonite based organic clay treated with dimethyl di(hydrogenated tallow) ammonium (DMDHT) salt.

Abstract: Described is a preferred UV curable coating composition comprising (exclusive of any solvent present): (a) about 5% to 90% by weight of an acrylated aliphatic urethane having a molecular weight of about 500 to 2000 and comprising an aliphatic urethane based on a polymer of allyl carbomonocycle diisocyanate with alkanepolyol polyacrylates, (b) about 5% to 30% by weight of a multifunctional acrylate having a molecular weight of about 170 to 1000 and containing at least two polymerizable unsaturated groups per molecule; and (c) a photopolymerization initiator and/or sensitizer. Also described are preferred processes of coating a plastic and coated articles involving the preferred coating compositions.

Abstract: The invention relates to coating compositions containing:

Abstract: There are provided a composition for coating which can form an ink receiving layer having excellent adhesion with hydrophobic substrates, water-resistance and printing stability, and an optical recording medium having an ink receiving layer formed from this composition. The composition contains a radiation-curable compound (A) composed of 50 to 90% by weight of a monofunctional (meth) acrylic monomer and 10 to 50% by weight of a multifunctional (meth) acrylic monomer, a water-absorbing organic filler (C) in an amount of 10 to 60% by weight relative to (A), and a water-absorbing inorganic filler (D) in an amount of 1 to 20% by weight relative to (A). This composition is applied on a protecting film (6) and cured to form an ink receiving layer (7), to obtain an optical disk (1).