Containing At Least Two Organic Materials, E.g., Binder Plus Other Organic Material, Etc. Patents (Class 523/157)
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Patent number: 11773240Abstract: Briefly described, and according to one embodiment, aspects of the present disclosure generally relate to natural rubber and functional silica compositions for tire manufacturing and methods for forming the same. In at least one embodiment, the disclosed composition is a renewable elastomeric polymeric composition for rubber compounding applications, such as low rolling resistance tire tread and winter tire tread applications. The disclosed composition may also reduce fuel consumption and, thus, carbon dioxide emissions in gas-powered vehicles, and increase driving range in electric vehicles, because the disclosed composition is more energy efficient than current tire material compositions. In various embodiments, the disclosed composition may be formed by blending water-soluble silsesquioxane oligomers into a natural rubber latex system, followed by in-situ formation of a continuous, molecular silica network within the resulting polymer.Type: GrantFiled: September 30, 2020Date of Patent: October 3, 2023Assignee: Silpara Technologies LLCInventor: Charles Thomas Rosenmayer
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Patent number: 10967677Abstract: There is provided a pneumatic tire having improved wet grip performance and fuel efficiency in a good balance. The pneumatic tire is provided with a tread composed of a rubber composition comprising not less than 0.5 part by mass of silica and not less than 5 parts by mass of a resin based on 100 parts by mass of a rubber component comprising 40 to 100% by mass of a styrene-butadiene rubber and 0 to 60% by mass of a butadiene rubber, wherein an adhesive force of the rubber composition measured by the specified adhesion test method is not less than 300 when an adhesive force of a reference rubber composition wherein the whole amount of resin has been replaced by oil is assumed to be 100, and a ratio of a loss tangent tan ?0° C. at 0° C. of the rubber composition to a loss tangent tan ?70° C. at 70° C. of the rubber composition (tan ?0° C./tan ?70° C. is from 3.0 to 10.Type: GrantFiled: March 27, 2017Date of Patent: April 6, 2021Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Suguru Izumo, Ryoji Kojima
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Patent number: 10836208Abstract: A rubber composition containing (A) at least one rubber selected from sulphur vulcanizable rubbery elastomers, (B) silica, (C) at least one non-ionic surfactant (C) that is selected from compounds according to general formula (I a) R1—CH(OH)—CH2—O-(AO)x—R2,??(I a) and from compounds according to general formula (I b) R1—CH(OH)—CH2—O-(AO)x-A1-O-(AO)y—CH2—CH(OH)—R1,??(I b) and from compounds according to general formula (I c) R1—CO—NH—CH2—CH2—O-(AO)x—CH2—CH2—NH—CO—R1,??(I c) wherein R1 are same or different and selected from C4-C30-alkyl, straight-chain or branched, and from C4-C30-alkylene, straight-chain or branched, with at least one C—C double bond, R2 are same or different and selected from C1-C30-alkyl, straight-chain or branched, and from C2-C30-alkylene, straight-chain or branched, with at least one C—C double bond, R2 is selected from C2-C10-alkylene, straight chain or branched, x, y same or different and selected from 10 to 50, and AO is selected from identical or different alkylene oxides, sType: GrantFiled: June 19, 2017Date of Patent: November 17, 2020Assignee: BASF SEInventors: Stephan Hueffer, Fritz Nimtz, Achim Fessenbecker, Alejandra Garcia Marcos
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Patent number: 10640579Abstract: The present invention provides a modified conjugated diene polymer in which a phenoxy group of a polar group-containing phenoxy compound is bonded to at least one selected from the group consisting of the end, main chain, and side chain of a conjugated diene polymer, which can further improve a rubber composition in the low-heat-generation property and abrasion resistance, and a rubber composition using the same.Type: GrantFiled: January 21, 2016Date of Patent: May 5, 2020Assignee: BRIDGESTONE CORPORATIONInventor: Tomohiro Urata
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Patent number: 10493800Abstract: A polymer blend consisting of (a) 60-96 percent by weight of a high molecular weight elastomeric polymer, (b) 4-35 percent by weight of a low molecular weight aromatic hydrocarbon polymer, and optionally (c) 0-13 percent by weight of an extender oil, wherein the amounts of the components (a), (b) and (c) are based on the total weight of the polymer blend.Type: GrantFiled: February 18, 2016Date of Patent: December 3, 2019Assignee: TRINSEO EUROPE GMBHInventors: Evemarie Hamann, Katja Osswald
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Patent number: 10336898Abstract: This invention relates to a process for stabilizing a phenolic resin containing a mixture of linear phenolic resins and calixarenes and a demulsifier composition comprising the stabilized phenolic resins prepared from the process. The process comprises contacting the phenolic resin with an alkylene carbonate, in the presence of a base catalyst, to at least partially alkoxylate the phenolic hydroxyl groups of the calixarenes. This process forms a stabilized phenolic resin with an increased solubility in a hydrocarbon solvent.Type: GrantFiled: January 19, 2017Date of Patent: July 2, 2019Assignee: SI GROUP, INC.Inventors: Todd Aube, Gennaro Barbiero, Ricky Biittig, James M. Baxter, Jr.
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Patent number: 10273351Abstract: Disclosed are sulfur-crosslinkable rubber mixtures that can be incorporated into treads of vehicle tires, and vehicle tires comprising the disclosed sulfur-crosslinkable rubber mixtures. The rubber mixtures comprise: at least one diene rubber, at least one silica, at least one hydrocarbon resin, and 1 to 40 phr of at least one liquid polybutadiene having terminal organosilicon modification and having a weight-average molecular weight Mw by GPC of 500 to 12 000 g/mol.Type: GrantFiled: December 8, 2017Date of Patent: April 30, 2019Assignee: Continental Reifen Deutschland GmbHInventors: Viktoria Pavon Sierra, Norbert Mueller, Catarina Sá, Thorsten Torbruegge, Christoph Vatterott, Anette Stark
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Patent number: 10138377Abstract: A lignin derivative that is extracted from biomass and is used for rubber reinforcement or for use in a molding material is provided. Such a lignin derivative has a number average molecular weight of 300 to 2,000, and contains a component that is soluble in a polar organic solvent, in an amount of 80% by mass or more. When such a lignin derivative is incorporated, a lignin resin composition, a rubber composition, or a molding material, all of which have excellent low hysteresis loss characteristics, elastic modulus, or tensile properties, can be obtained. Furthermore, when a component that is thermofusible is used as the soluble component, a lignin resin composition, a rubber composition, or a molding material, all of which have superior aforementioned characteristics, can be obtained.Type: GrantFiled: August 31, 2015Date of Patent: November 27, 2018Assignee: SUMITOMO BAKELITE CO., LTD.Inventors: Taketoshi Murai, Hiroshige Nakagawa, Mitsutaka Matsumoto
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Patent number: 9845385Abstract: The present invention provides a rubber composition that can enhance the fuel economy, wet-grip performance, abrasion resistance, and kneading processability in a balanced manner, and a pneumatic tire using this rubber composition. The present invention relates to a rubber composition that contains a rubber component and silica, wherein the rubber component contains, based on 100% by mass of the rubber component, 10 to 70% by mass of a high-cis polybutadiene having a cis content of 95% by mass or more and satisfying the following requirements (A) to (C): (A) a Mooney viscosity (ML) of 40 to 49; (B) a molecular weight distribution (weight-average molecular weight (Mw)/number-average molecular weight (Mn)) of 3.0 to 3.9; and (C) an index (n-value in Expression (1) below) of velocity dependence of Mooney viscosity of 2.3 to 3.Type: GrantFiled: April 27, 2012Date of Patent: December 19, 2017Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Takahiro Mabuchi, Tatsuhiro Tanaka, Kazuyuki Nishioka, Kenichi Uesaka
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Patent number: 9752008Abstract: It has been discovered that the use of a plasticizer, an ester of a cyclohexanepolycarboxylic acid, especially a 1,2-cyclohexanedicarboxylic acid ester, that is environmentally non-toxic, can replace environmentally unfriendly phthalate plasticizers, such as dioctyl phthalates used in vulcanizable rubber compositions, especially for tires, on a one to one weight basis (phr) without sacrificing beneficial rubber properties.Type: GrantFiled: February 25, 2013Date of Patent: September 5, 2017Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William J. Corsaut
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Patent number: 9580536Abstract: This invention relates to a process for stabilizing a phenolic resin containing a mixture of linear phenolic resins and calixarenes and a demulsifier composition comprising the stabilized phenolic resins prepared from the process. The process comprises contacting the phenolic resin with an alkylene carbonate, in the presence of a base catalyst, to at least partially alkoxylate the phenolic hydroxyl groups of the calixarenes. This process forms a stabilized phenolic resin with an increased solubility in a hydrocarbon solvent.Type: GrantFiled: October 21, 2015Date of Patent: February 28, 2017Assignee: SI GROUP, INC.Inventors: Todd Aube, Gennaro Barbiero, Ricky Biittig, James M. Baxter, Jr.
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Patent number: 9556331Abstract: The invention relates to rubber compositions containing at least one diene-based elastomer containing dual functionalized styrene/butadiene elastomers and filler reinforcement for the elastomer(s) comprised of pre-hydrophobated precipitated silica together with processing aid for the pre-treated precipitated silica comprised of zinc salt of fatty acids. The invention further relates to a pneumatic tire with tread comprised of such.Type: GrantFiled: December 9, 2015Date of Patent: January 31, 2017Assignee: The Goodyear Tire & Rubber CompanyInventors: Julia Martine Francoise Claudine Tahon, Wolfgang Karl Maegerle, Timo Benjamin Korfmann, Miriam Laackmann
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Patent number: 9534650Abstract: A friction material containing, as a binder, a lignin-phenol resin having a weight average molecular weight of 5,000 or less or a cardanol-modified lignin-phenol resin having a weight average molecular weight of 5,000 or less. The friction material is produced by a method including: reacting a lignin having a weight average molecular weight of 5,000 or less, a phenol, an aldehyde, and optionally a cardanol, in the presence of an acid catalyst.Type: GrantFiled: March 21, 2013Date of Patent: January 3, 2017Assignee: AKEBONO BRAKE INDUSTRY CO., LTD.Inventor: Motoki Kuroe
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Patent number: 9464146Abstract: Provided are a chloroprene rubber that is less adhesive to rolls and gives a vulcanized product superior in physical properties, a production method thereof, a chloroprene rubber composition and a vulcanized product thereof. A chloroprene rubber comprising a steroid skeleton-containing compound. The chloroprene rubber may contain a steroid skeleton-containing compound in an amount of 0.01 to 1 mass %. A vulcanized product is prepared by vulcanizing a composition containing the chloroprene rubber. The chloroprene rubber can be prepared, for example, by emulsion-polymerizing chloroprene alone or chloroprene and other monomers in combination in the presence of a rosin containing a steroid skeleton-containing compound.Type: GrantFiled: June 17, 2013Date of Patent: October 11, 2016Assignee: DENKA COMPANY LIMITEDInventors: Sachiyo Kishi, Hiroyuki Yashima, Hidehiro Matsuda
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Patent number: 9085694Abstract: Provided is a phenolic resin molding compound including (A) a novolac-type phenolic resin including an alkylbenzene-modified novolac-type phenolic resin, (B) a resol-type phenolic resin, (C) hexamethylenetetramine, (D) graphite, and (E) fiber-shaped filler, wherein in regard to the content of each component on the basis of the entirety of the molding compound, a total content of the components (A) to (C) is 30 to 40% by weight, a content of the component (D) is 30 to 50% by weight, and a content of the component (E) is 5 to 20% by weight.Type: GrantFiled: September 5, 2012Date of Patent: July 21, 2015Assignee: SUMITOMO BAKELITE CO., LTD.Inventor: Daisuke Inokawa
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Patent number: 8952088Abstract: A heavy vehicle tire tread constituted from a material based upon a rubber composition, the composition comprising, per 100 parts by weight of elastomer, between 35 and 60 phr of a solution polymerized styrene-butadiene rubber having a styrene content of between 10 wt. % and 35 wt. % and between 35 and 60 phr of a polybutadiene. The composition may further include between 45 and 110 phr of silica and between (1.94×10?3/n)(S) and (2.55×10?3/n)(S) moles of a sulfur-containing organosilicon compound as a silane coupling agent per 1 kg of the silica, wherein n is a number of silicon atoms in a molecule of the silane coupling agent and S is a CTAB surface area in m2/g of the silica. The rubber composition may be cured with a sulfur curing system comprising a sulfenamide accelerator and between 0.3 and 0.8 phr of free sulfur, wherein a ratio of the sulfenamide accelerator and the sulfur is between 2 and 7.Type: GrantFiled: April 29, 2009Date of Patent: February 10, 2015Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.Inventors: Jeremey J. Mehlem, Jesse J. Arnold
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Publication number: 20150031792Abstract: Disclosed is a method of preparing a rubber composition comprising the steps of (a) blending in at least one preparatory mixing step at least one natural or synthetic rubbery polymer, a silica filler, a silica coupling agent, and at least one vulcanization accelerator; and (b) subsequently blending therewith in a final mixing step a sulfur curative, wherein the average glass transition temperature of the polymer(s) is ?55° C. or less.Type: ApplicationFiled: July 25, 2012Publication date: January 29, 2015Inventor: Maryangel G. Dunlavy
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Patent number: 8846780Abstract: A friction element for a synchronizing device as well as an apparatus for producing a friction element for a synchronizing device are disclosed.Type: GrantFiled: June 18, 2012Date of Patent: September 30, 2014Assignee: Schaeffler Technologies AG & Co. KGInventors: Constanze Kuckuck, Stefan Steinmetz
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Publication number: 20140243448Abstract: A tire having an improved wet grip, in particular for a passenger vehicle, a van, or two-wheel vehicle, includes a tread of which includes a rubber composition. The rubber composition includes at least (phr meaning parts by weight per hundred parts of elastomer): as a first diene elastomer, from 55 to 95 phr of natural rubber or synthetic polyisoprene; as a second diene elastomer, from 5 to 45 phr of a polybutadiene or butadiene copolymer having a Tg greater than ?70° C.; as a reinforcing filler, from 60 to 90 phr of an inorganic filler; as a plasticizer, more than 5 phr of a thermoplastic hydrocarbon resin exhibiting a Tg greater than 20° C.; and optionally, from 0 to 20 phr of a plasticizing agent, which is a liquid at 23° C.Type: ApplicationFiled: September 26, 2012Publication date: August 28, 2014Applicants: MICHELIN RECHERCHE ET TECHNIQUE S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Pierre Lesage, Garance Lopitaux, Didier Vasseur
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Publication number: 20140227541Abstract: Provided is a friction material composition comprising: a binder; a fibrous base material; an abrasive material; an inorganic filler; and an organic filler, wherein the friction material composition further comprises: at least one selected from the group consisting of zinc, a cellulose fiber as the fibrous base materials and a flame retardant fiber as the fibrous base materials; an iron-based fiber as the fibrous base material in an specified amount; and an inorganic abrasive material having a Mohs hardness of 8 or higher and a particle size of 1 ?m or larger as the abrasive material in an amount of 1 wt % or less.Type: ApplicationFiled: April 17, 2014Publication date: August 14, 2014Inventors: Mitsuo UNNO, Manabu Ono, Takashi Kikudome
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Patent number: 8790772Abstract: A wound friction coating and a method for the production thereof.Type: GrantFiled: December 24, 2009Date of Patent: July 29, 2014Assignee: Schaeffler Technologies AG & Co. KGInventors: Tim-Florian Gerbing, Christian Spandern
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Patent number: 8536244Abstract: The friction lining mixture for a friction material for brake and clutch linings, the brake and clutch linings contains metal fibers and/or powder, functional fillers, lubricants and organic compounds for improving the performance capability of the friction pairing metallic and/or alloyed and/or bound tin in an amount of 0.5 to 50.0 percent by weight, preferably 2.0 to 10.0 percent by weight, the copper content in the friction lining mixture being 0.001 to 4.999 percent by weight, preferably 0.001 to 0.499 percent by weight.Type: GrantFiled: June 29, 2010Date of Patent: September 17, 2013Assignee: Honeywell Bremsbelag GmbHInventors: Norbert Schoo, Stephan Ernesti, Andreas Goldschmidt, Thomas Pfannebecker, Gerhard Burmester
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Publication number: 20130217802Abstract: A method for producing a rubber composition containing a rubber component (A) of at least one selected from natural rubbers and synthetic dienic rubbers, a filler containing an inorganic filler (B), and a silane coupling agent (C) of a compound having a mercapto group, wherein the rubber composition is kneaded in multiple stages, in the first stage of kneading, the rubber component (A), all or a part of the inorganic filler (B), and all or a part of the silane coupling agent (C) are kneaded, then in the first stage or in the subsequent kneading stage, at least one compound selected from an acidic compound (D) and a basic compound (E) is added, and the highest temperature of the rubber composition in the final stage of kneading is from 60 to 120° C.Type: ApplicationFiled: October 3, 2011Publication date: August 22, 2013Applicant: BRIDGESTONE CORPORATIONInventors: Seiichi Katou, Satoshi Horie
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Patent number: 8513331Abstract: A gelling agent, and a method of use for the same, for gelling a puncture repair material, the puncture repair material including a natural rubber latex, a resin emulsion, and an antifreezing agent, the gelling agent comprising a compound (?) of the following Formula (1). In the following Formula 1, R1 is an alkyl group having from 13 to 30 carbon atoms or an alkenyl group having from 13 to 30 carbon atoms.Type: GrantFiled: September 27, 2010Date of Patent: August 20, 2013Assignee: The Yokohama Rubber Co., Ltd.Inventors: Takahiro Okamatsu, Kazushi Kimura
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Patent number: 8431629Abstract: In a wet friction material, inorganic filler of small particle size is added to fill clearances or space between fibers with the inorganic filler. The inorganic filler is attached to the fibers with each other to reinforce strength of the wet friction material when an impregnated resin is hardened. Absolute specific gravity of the inorganic filler is set at a fixed value so as to make its compounding quantity small, thereby assuring a pore diameter of a friction material substrate without filling pores of the friction material substrate with the inorganic filler.Type: GrantFiled: August 7, 2008Date of Patent: April 30, 2013Assignee: Aisin Kako Kabushiki KaishaInventors: Yuko Higashijima, Ryouhei Hoshino, Takuya Muranaka
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Patent number: 8426508Abstract: The present invention has its object to provide a high performance studless tire, which has both good braking force and high handling stability on ice or snow, at higher productivity and at a lower price for customers. The studless tire comprises a tread made of a rubber composition containing 2.2 to 10 parts by mass of a fatty acid and/or a derivative of the fatty acid per 100 parts by mass of a rubber component, the tread having a JIS-A hardness of 50 or less.Type: GrantFiled: June 15, 2009Date of Patent: April 23, 2013Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Takayuki Hattori, Ryoji Kojima, Naohiko Kikuchi, Yasuhisa Minagawa
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Patent number: 8383698Abstract: It has been discovered that the use of a plasticizer, an ester of a cyclohexanepolycarboxylic acid, especially a 1,2-cyclohexanedicarboxylic acid ester, that is environmentally non-toxic, can replace environmentally unfriendly phthalate plasticizers, such as dioctyl phthalates used in vulcanizable rubber compositions, especially for tires, on a one to one weight basis (phr) without sacrificing beneficial rubber properties.Type: GrantFiled: September 10, 2009Date of Patent: February 26, 2013Assignee: Bridgestone CorporationInventors: Terrence E. Hogan, William J. Corsaut
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Patent number: 8372901Abstract: The invention relates to a tire tread having a composition based on at least one diene elastomer, one reinforcing filler and one vulcanization system, characterized in that the composition comprises a xanthan gum powder in a proportion of 10 to 40 pce. The invention also relates to a process for obtaining a rubber composition for a tread based on at least one diene elastomer, one reinforcing filler and one vulcanization system which comprises a first phase of thermomechanical kneading of the constituents of the composition, with the exception of the vulcanization system, characterized in that the composition comprises a xanthan gum powder in a proportion of 10 to 40 pce and in that the xanthan gum powder is incorporated during the first kneading phase.Type: GrantFiled: December 6, 2007Date of Patent: February 12, 2013Assignee: Michelin Recherche et Technique S.A.Inventors: Jean-Denis Hidrot, Salvatore Pagano
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Patent number: 8367767Abstract: A friction lining for a wet clutch, in particular for a converter lockup, the clutch containing the ingredients—cellulose fibers, aramid fibers, fillers and a bonding agent. To provide a cost-effective friction lining suitable for the application under the conditions of a converter lockup clutch, it is proposed to admix powdered nutshell of percentage weight between 1% and 40%.Type: GrantFiled: March 1, 2010Date of Patent: February 5, 2013Assignee: Schaeffler Technologies AG & Co., KGInventors: Firoz Jafri, Martin Fuss, Michael Wilfong
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Publication number: 20120302665Abstract: Modified rubber compositions containing an elastomer component and a modifier comprising a steroid and/or a peptide and methods of their production. Such modified rubber compositions can have improved properties and can be useful in making various articles of manufacture, such as, for example, in the manufacture of tires.Type: ApplicationFiled: December 1, 2010Publication date: November 29, 2012Inventors: Xiaorong Wang, Victor J. Foltz, Edward D. Kelley
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Publication number: 20120283355Abstract: A tire comprising a rubber composition based on at least an elastomer composite prepared by a method comprising: feeding a continuous flow of a first fluid comprising a first elastomer latex to a mixing zone of a coagulum reactor; feeding a continuous flow of a second fluid comprising a second elastomer latex to the mixing zone; feeding a continuous flow of a third fluid comprising a particulate filler slurry to the mixing zone; allowing the first elastomer latex and the second elastomer latex to coagulate with the particulate filler; and discharging a flow of elastomer composite from a discharge end of the coagulum reactor.Type: ApplicationFiled: September 16, 2010Publication date: November 8, 2012Applicants: Michelin Recherche et Technique S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Xuan Zhang, Ting Wang, Michael D. Morris
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Patent number: 8304471Abstract: A rubber composition, in particular intended for the manufacture of tires, based on at least a predominant elastomer, chosen from the group consisting of butyl rubbers, essentially unsaturated diene elastomers, essentially saturated diene elastomers and the mixtures of these elastomers, and a reinforcing filler, characterized in that the composition also comprises at least one inert filler chosen from silicon-based lamellar mineral fillers and a nonfunctionalized polyisobutylene oil, having a molecular weight of between 200 g/mol and 40 000 g/mol, present in a proportion of between 2 and 50 phe.Type: GrantFiled: December 16, 2008Date of Patent: November 6, 2012Assignees: Michelin Recherche et Technique S.A., Compagnie Generale des Etablissements MichelinInventors: Aurélie Joseph, Aline Riou
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Publication number: 20120277344Abstract: A tire comprising a rubber composition based on at least an elastomer composite formed by the method of flowing a coagulating mixture of a first elastomer latex comprising a first elastomer and a particulate filler slurry along a conduit; and introducing a second elastomer latex comprising a second elastomer into the flow of the coagulating mixtureType: ApplicationFiled: September 16, 2010Publication date: November 1, 2012Inventors: Ting Wang, Meng-Jiao Wang, Bernard Mariadass, Thirunavuc Karasu Govindan, Anthony das Thiruhelvanathan, Boon Kwang Lee, Xuan Zhang
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Patent number: 8278370Abstract: A friction lining made of a fibrous mixture with fillers and resin for a wet clutch. In order to design the friction lining able to withstand the higher torque to be transmitted, it is proposed to admix further filler with a Mohs hardness greater or equal to 9.0 and smaller or equal to 9.5 in addition to the ingredients of aramid fibers, cellulose fibers, phenol resin and amorphous silicon dioxide and first filler.Type: GrantFiled: March 1, 2010Date of Patent: October 2, 2012Assignee: Schaeffler Technologies AG & Co. KGInventors: Firoz Jafri, Martin Fuss, Michael Wilfong
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Publication number: 20120234441Abstract: A heavy vehicle tire tread constituted from a material based upon a rubber composition, the composition comprising, per 100 parts by weight of elastomer, between 35 and 60 phr of a solution polymerized styrene-butadiene rubber having a styrene content of between 10 wt. % and 35 wt. % and between 35 and 60 phr of a polybutadiene. The composition may further include between 45 and 110 phr of silica and between (1.94×10?3/n)(S) and (2.55×10?3/n)(S) moles of a sulfur-containing organosilicon compound as a silane coupling agent per 1 kg of the silica, wherein n is a number of silicon atoms in a molecule of the silane coupling agent and S is a CTAB surface area in m2/g of the silica. The rubber composition may be cured with a sulfur curing system comprising a sulfenamide accelerator and between 0.3 and 0.8 phr of free sulfur, wherein a ratio of the sulfenamide accelerator and the sulfur is between 2 and 7.Type: ApplicationFiled: April 29, 2009Publication date: September 20, 2012Inventors: Jeremey J. Mehlem, Jesse J. Arnold
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Publication number: 20120232186Abstract: A rubber composition for tire comprises: diene rubber component consisting of diene rubber (s); and multihollow particles amounting 0.3-20 mass parts relative to 100 mass parts of the diene rubber component; and microvoids being distributed in each of the multihollow particles throughout from a vicinity of center portion to a vicinity of surface of the particle; and porosity of the multihollow particles being in a range of 40% to 60%. A pneumatic tire has a tread that is formed of such rubber composition.Type: ApplicationFiled: February 2, 2012Publication date: September 13, 2012Applicant: TOYO TIRE & RUBBER CO., LTD.Inventor: Shinsaku Kamada
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Publication number: 20120220693Abstract: A pneumatic tire prepared by using a rubber composition prepared by compounding precipitated silica with a rubber component comprising 100 parts by mass of a rubber component (A) comprising at least one of a natural rubber and a synthetic diene base rubber and 5 to 60 parts by mass of an aromatic vinyl compound-diene compound copolymer (B) having a weight average molecular weight of 4,000 to 250,000 which comprises 0 to 80% by mass of the aromatic vinyl compound and in which a vinyl bond content in the parts of the diene compound is 0 to 80% by mass, wherein a cetyltrimethylammonium bromide-adsorbing specific surface area (CTAB) (m2/g) of the precipitated silica and the mode Aac (nm) in diameters of primary aggregates thereof determined by acoustic measurement of particle size distribution satisfy equation (I) shown below: Aac??0.76×(CTAB)+274??(I) and an ignition loss (mass reduction % when heated at 750° C.Type: ApplicationFiled: July 21, 2010Publication date: August 30, 2012Applicant: BRIDGESTONE CORPORATIONInventors: Shigeaki Matsuo, Yuta Hoshino
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Patent number: 8247487Abstract: This invention relates to a tire with a tread of a rubber composition containing carboxylated styrene/butadiene rubber.Type: GrantFiled: November 11, 2010Date of Patent: August 21, 2012Assignee: The Goodyear Tire & Rubber CompanyInventors: Robert Anthony Bethea, Paul Harry Sandstrom
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Publication number: 20120175033Abstract: A rubber composition based on at least a diene elastomer, a reinforcing filler and a crosslinking system, characterized in that it comprises at least 10 to 150 phr of a platy filler and from 0.01 to 0.3 phr of a metal salt. This composition has good processing and mechanical properties, and also improved oxygen impermeability properties over a wide temperature range, from ambient temperatures when the tire is stationary up to the temperatures of the tire when it is running. According to one preferred embodiment, the rubber composition described above can be used in the tire as a protective elastomer layer in at least one part of the tire.Type: ApplicationFiled: March 30, 2010Publication date: July 12, 2012Applicants: Michelin Recherche et Technique S.A., SOCIETE DE TECHNOLOGIE MICHELINInventors: David Lavialle, Jacques Besson
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Publication number: 20120172491Abstract: In order to provide a tire which is excellent in processability and which is excellent as well in a low fuel consumption, abrasion resistance and fracture resistance, assumed is such a constitution that used for a tire member is a rubber composition which contains a modified natural rubber having a polar group in the rubber molecule and precipitated silica, wherein a cetyltrimethylammonium bromide-adsorbing specific surface area (CTAB) (m2/g) of the precipitated silica and the mode Aac in diameters (nm) of primary aggregates thereof determined by acoustic measurement of particle size distribution satisfy an equation: Aac??0.76×(CTAB)+274.Type: ApplicationFiled: July 21, 2010Publication date: July 5, 2012Applicant: BRIDGESTONE CORPORATIONInventor: Toru Miyazaki
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Publication number: 20120152423Abstract: The invention relates to a tire having a rubber component which contains short fiber reinforcement with a compatabilizer for the fiber reinforcement. Desirably said short fiber reinforcement is an aramid pulp. Desirably said compatabilizer is an epoxy functionalized natural rubber.Type: ApplicationFiled: December 17, 2010Publication date: June 21, 2012Inventors: Junling Zhao, Martin Paul Cohen
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Publication number: 20120123017Abstract: This invention relates to a tire with a tread of a rubber composition containing carboxylated styrene/butadiene rubber.Type: ApplicationFiled: November 11, 2010Publication date: May 17, 2012Inventors: Robert Anthony Bethea, Paul Harry Sandstrom
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Publication number: 20120077902Abstract: The invention is directed to a pneumatic tire having a tread comprising a vulcanizable rubber composition comprising, expressed as parts by weight per 100 parts by weight of elastomer (phr), (A) 30 to 70 phr of a first styrene-butadiene rubber, wherein the first styrene-butadiene rubber is i) a solution-polymerized styrene-butadiene rubber with a bound styrene content of from 30 to 50 percent by weight, a vinyl 1,2 content of from 10 to 40 percent by weight based on the rubber weight, and a Tg of from about ?40° C. to about —20° C.; or ii) an emulsion-polymerized styrene-butadiene rubber with a bound styrene content of from 30 to 50 percent by weight, and a Tg of from about ?40° C. to about ?20° C.Type: ApplicationFiled: September 24, 2010Publication date: March 29, 2012Inventors: Pascal Patrick Steiner, Marc Weydert, Christian Jean-Marie Kaes
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Publication number: 20120067495Abstract: The invention relates to a cured rubber composition, its preparation and a tire with a component of such rubber composition.Type: ApplicationFiled: September 17, 2010Publication date: March 22, 2012Inventors: Bruce Raymond Hahn, Rebecca Lee Dando, Larry Ashley Gordon
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Publication number: 20110245371Abstract: The present invention is directed to a pneumatic tire comprising at least one component, the at least one component comprising a rubber composition, the rubber composition comprising: at least one diene based elastomer; an alkylalkoxysilane of formula I wherein R1 is exclusive of sulfur and is an alkyl group of 1 to 18 carbon atoms or an aryl group of 6 to 18 carbon atoms, and R2, R3 and R4 are independently alkyl of 1 to 8 carbon atoms; and a silicone T resin.Type: ApplicationFiled: February 23, 2011Publication date: October 6, 2011Inventors: Claude Schweitzer, Isabelle Lea Louise Marie Lambert, Uwe Ernst Frank, Claude Charles Jacoby
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Publication number: 20110207847Abstract: A tire using, for a tread, a rubber composition comprising (A) a rubber component comprising 15 to 70% by mass of a styrene-butadiene copolymer modified with an amine-based functional group and (B) silica having a specific surface area by cetyltrimethylammonium bromide (CTAB) adsorption of 60 to 130 m2/g and a specific surface area by nitrogen adsorption (N2SA) in accordance with the BET method of 70 to 140 m2/g in an amount of 20 to 150 parts by mass based on 100 parts by mass of the rubber component. The tire exhibits excellent abrasion resistance in combination with decreased rolling resistance (small heat buildup) and excellent steering stability which is typically expressed by excellent wet skid resistance.Type: ApplicationFiled: December 26, 2008Publication date: August 25, 2011Applicant: BRIDGESTONE CORPORATIONInventors: Naohiro Sasaka, Takumi Kimura
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Publication number: 20110160337Abstract: It is an object of the present invention to provide: a rubber composition for a tread, which improves processability, rolling resistance, wet skid performance, abrasion resistance, and handling stability in good balance; and a pneumatic tire having a tread produced from the rubber composition. The present invention relates to a rubber composition for a tread, including: a rubber component; an aromatic vinyl polymer; silica; and a mercapto group-containing silane coupling agent, wherein the aromatic vinyl polymer is a resin obtained by polymerization of ?-methylstyrene and/or styrene, and the amount of the aromatic vinyl polymer is 3 to 25 parts by mass, and the amount of the silica is 15 to 150 parts by mass, based on 100 parts by mass of the rubber component.Type: ApplicationFiled: December 23, 2010Publication date: June 30, 2011Inventor: Soh Ishino
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Publication number: 20110112215Abstract: The invention provides a rubber composition for studless tire achieving well-balanced abrasion resistance, performance on ice and snow, handling stability, and wet grip performance; and a studless tire including a tread produced from the composition. The composition contains: a rubber component; aromatic oil; silica; carbon black; and a mixture of a zinc salt of aliphatic carboxylic acid and a zinc salt of aromatic carboxylic acid, wherein the total of NR and BR in 100% by mass of the rubber component is 30% by mass or more, the amount of aromatic oil is 12-85 parts by mass, the amount of silica is 12-85 parts by mass, and the amount of mixture is 1 part by mass or more, per 100 parts by mass of the rubber component, and the proportion of silica is 45% by mass or more per 100% by mass of the total of the silica and carbon black.Type: ApplicationFiled: November 10, 2010Publication date: May 12, 2011Inventor: Ryoji KOJIMA
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Publication number: 20110077327Abstract: A gelling agent, and a method of use for the same, for gelling a puncture repair material, the puncture repair material including a natural rubber latex, a resin emulsion, and an antifreezing agent, the gelling agent comprising a compound (?) of the following Formula (1). In the following Formula 1, R1 is an alkyl group having from 13 to 30 carbon atoms or an alkenyl group having from 13 to 30 carbon atoms.Type: ApplicationFiled: September 27, 2010Publication date: March 31, 2011Inventors: Takahiro Okamatsu, Kazushi Kimura
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Publication number: 20110046264Abstract: Diol derived blocked mercaptofunctional silane compositions in which the silanes comprise cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and processes for their preparation are provided. Also provided are rubber compositions comprising the cyclic diol-derived blocked mercaptofunctional silanes, processes for their preparation and articles of manufacture comprising the rubber compositions, in particular, automotive tires and components thereof.Type: ApplicationFiled: November 1, 2010Publication date: February 24, 2011Applicant: Momentive Performance Materials Inc.Inventors: Richard W. Cruse, Leda N. Gonzalez, Rodica Himmeldirk, Larry Allen Divins, Melinda Jackson, Eric Raymond Pohl, Antonio Chaves