Composition Devoid Of Magnetic Materials And Suitable For Preparation Of Magnetic Tape Recording Or Process Of Preparing Patents (Class 523/181)
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Patent number: 9422416Abstract: Provided is a resin composition that includes calcium carbonate contained in a polyester resin, a polyamide resin, or at thermosetting resin and that achieves good moldability. The resin composition includes calcium carbonate having a pH ranging from 6.0 to 8.5 and a 1N acetic acid-insoluble residue or 30% by mass or more and the calcium carbonate is contained in a polyester resin, a polyamide resin, or a thermosetting resin.Type: GrantFiled: November 8, 2011Date of Patent: August 23, 2016Assignee: SHIRAISHI CENTRAL LABORATORIES CO., LTD.Inventors: Kenichiro Eguchi, Motoshi Tamura
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Publication number: 20140087211Abstract: The magnetic recording medium coating composition includes carbon black; iron oxide; at least one organic solvent selected from the group consisting of methyl ethyl ketone, cyclohexanone, and isophorone; an organic tertiary amine selected from the group consisting of an aliphatic tertiary monoamine and an alicyclic tertiary amine; and an organic acid.Type: ApplicationFiled: September 26, 2013Publication date: March 27, 2014Applicant: FUJIFILM CORPORATIONInventor: Kazufumi OMURA
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Publication number: 20010021729Abstract: A composition useful for magnetic filled tires, particularly for tire sidewalls, which contains an orsganoxysilylsulfane coupling agent, is provided. The composition displays either improved fatigue resistance or either improved crack growth resistance or both. The sidewall composition is magnetizable to a magnetic field strength of preferably at least 0.1 Gauss, more preferably at least 0.5 Gauss, even more preferably at least 1 Gauss, even more preferably at least 10 Gauss, most preferably at least 25 Gauss, as measured at a distance of 8 mm for a 1 mm thick layer. The sidewall composition comprises 100 parts rubber, magnetic particulate, organosilane and curing agents. The compositions contain: curing agents in an amount effective to cure the rubber; such as sulfur preferably from 30 to 350 phr, more preferably from 40 to 300 phr, most preferably from 50 to 250 phr magnetic particulate; and preferably from 0.Type: ApplicationFiled: February 16, 2001Publication date: September 13, 2001Inventors: Frank P. Papp, Duane M. Oxley, James M. Giustino
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Patent number: 5494739Abstract: A biaxially oriented polyethylene-2,6-naphthalenedicarboxylate film, which can be used as a base film for a recording medium capable of high-density recording, characterized in that when h (unit: nm) stands for a height of a protrusion formed on the film surface, the numbers of protrusions in the range of 1.ltoreq.h<50, 50.ltoreq.h<100, and 100.ltoreq.h fall each within a specified range, that the film has a plane orientation coefficient (NS) and an average refractive index (n.sub.a) which satisfy the relationship NS.gtoreq.1.607n.sub.a -2.434, that the film has a surface roughness (Ra) of 2-10 nm and that the film has a heat shrinkage in the longitudinal direction of 0.08% or less when heat-treated under no load at 70.degree. C. for 1 hour.Type: GrantFiled: June 23, 1993Date of Patent: February 27, 1996Assignee: Teijin LimitedInventors: Takao Chuujou, Masahiro Hosoi, Ieyasu Kobayashi, Yasuhiro Saeki
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Patent number: 5382614Abstract: Difunctional perfluoropolyetheral compounds having polar or non-polar hydrogenated end groups, suitable for being used as inner lubricants in the chemical formulation of the active layer of magnetic recording media, characterized by a solubility in methylethylketone at 20.degree. C. ranging from 0.05% to 2% by weight.Type: GrantFiled: September 17, 1993Date of Patent: January 17, 1995Assignee: Ausimont S.p.A.Inventors: Mario A. Scarati, Gerardo Caporiccio
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Patent number: 5371166Abstract: The present invention discloses a novel polyurethane composition useful as a dispersing binder. The binder yields magnetic dispersions having high gloss values. Moreover, the polyurethane provides excellent hydrolytic stability. The polyurethane comprises a polyol, a diisocyanate a chain extender and an functional modifier formed of a reaction product of an aminodiol and Bronsted Acid.Type: GrantFiled: December 22, 1993Date of Patent: December 6, 1994Assignee: The B. F. Goodrich CompanyInventors: Julius Farkas, Dale R. Hall, Kyung J. Kim, Ravi R. Vedula
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Patent number: 5273826Abstract: A polyurethane resin is synthesized from a reaction mixture of at least one phosphorus compound, an epoxy compound, a polyisocyanate, a polyfunctional hydroxy compound, and optionally a chain extender. The polyurethane resin contains one phosphoric acid group or one residual group derived from phosphoric acid per 3,000 to about 200,000 number average molecular weight of the polyurethane resin. The weight average molecular weight of the polyurethane resin is from about 10,000 to about 250,000. A magnetic coating formulation is comprised of principally of magnetic particles and a binder. A magnetic recording media comprises a laminate as in the form of a magnetic layer composed principally of magnetic particles and a binder wherein at least a portion of the binder is the polyurethane resin. The substrate of the magnetic recording medium is a suitable polymer such as polyester, and the like.Type: GrantFiled: March 31, 1993Date of Patent: December 28, 1993Assignee: The B. F. Goodrich CompanyInventors: Masahiko Yasuda, Shigeo Hosokawa, Yorozu Yokomori, Shinichiro Jimbo, Edmond G. Kolycheck
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Patent number: 4840830Abstract: A polyester film suitable for use as the magnetic tape base for video recording, capable of high density recording and having stable slidability or running characteristics. The polyester film is made of a polyester which contains 0.05-1 wt % particles containing calcium and phosphorus and of which the number n of the second interference fringes (number/mm.sup.2) and the average centerline roughness (.mu.m) satisfy the following relationships:n<30 (1)0.005.ltoreq.R.sub.a .ltoreq.0.Type: GrantFiled: October 6, 1987Date of Patent: June 20, 1989Assignee: Diafoil Company, LimitedInventors: Seiji Sakamoto, Kiyoshi Yasumura
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Patent number: 4761327Abstract: A biaxially oriented film formed from a intimate mixture comprising (I) an aromatic polyester, (II) 0.005 to 1.0% by weight, based on the aromatic polyester, of fine particles of a silicone resin having (a) a composition represented by the following formula (A)R.sub.x SiO.sub.2-x/2 (A)wherein R represents a hydrocarbon group having 1 to 7 carbon atoms, and x is a number of from 1 to 1.2, (b) a volume shape factor (f), represented by the following formula (B), of more than 0.4 but not exceeding .pi./6f=V/D.sup.3 (B)wherein V is the average volume (.mu.m.sup.3) of the particles and D is the average maximum particle diameter (.mu.m) of the particle, and (c) an average particle diameter of 0.3 to 4 .mu.m. The film optionally contains (III) 0.005 to 1% by weight, based on the aromatic polyester, of inert fine particles having an average particle diameter of 0.01 to 1 .mu.m but being smaller than the average particle diameter of the silicone resin particles.Type: GrantFiled: January 14, 1987Date of Patent: August 2, 1988Assignee: Teijin LimitedInventors: Hisashi Hamano, Kinji Hasegawa, Yoshihiro Noumi, Hideo Katoh
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Patent number: 4715977Abstract: Phenoxy resins are acid-grafted by reaction of secondary hydroxyls with monoanhydrides of di- or polycarboxylic acids. The grafted resins have improved adhesion to smooth surfaces, can be readily emulsified, and are also useful in coatings for magnetic recording media.Type: GrantFiled: October 2, 1986Date of Patent: December 29, 1987Assignee: Union Carbide CorporationInventor: George A. Salensky
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Patent number: 4716209Abstract: An essentially isocyanate-free polyurethane polyurea polyethylenic oligomer is disclosed which is unusually strong and elastic. This oligomer is the reaction product of: (1) organic diisocyanate; (2) a stoichiometric deficiency of difunctional materials reactive therewith and consisting essentially of: (A) diol component selected from polycarbonate diol and polyoxyalkylene glycol, this diol component having a molecular weight of from 200 to 2000; (B) dihydric bisphenol-based alkylene oxide adduct containing from 2-10 alkylene groups per molecule; and (C) a diprimary diamine component selected from alkylene diamine and polyoxyalkylene diamine, this diamine component having a molecular weight of from about 70 to 800. Components (A) and (B) are present in a weight ratio of from 1:4 to 9:1 and component (C) is present to supply from 30 to 60 equivalent percent of the total equivalents of component (2).Type: GrantFiled: January 23, 1986Date of Patent: December 29, 1987Assignee: DeSoto, Inc.Inventors: Steven R. Schmid, Robert E. Ansel, Kevin P. Murray
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Patent number: 4711817Abstract: Phenoxy resins are acid-grafted by reaction of secondary hydroxyls with monoanhydrides of di- or polycarboxylic acids. The grafted resins have improved adhesion to smooth surfaces, can be readily emulsified, and are also useful in coatings for magnetic recording media.Type: GrantFiled: October 2, 1986Date of Patent: December 8, 1987Assignee: Union Carbide CorporationInventor: George A. Salensky
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Patent number: 4673705Abstract: Liquid coating compositions adapted to be cured by exposure to ionizing radiation are disclosed in which a liquid vehicle of coating viscosity having an ethylenically unsaturated portion comprising one or more polyethylenically unsaturated materials adapted to cure on radiation exposure, pigment dispersed in the vehicle, and an acrylate-functional radiation-curable dispersant having free carboxyl group for wetting the pigment and assisting in the stable dispersion of the pigment in the vehicle. This dispersant is an acrylate-functional carboxylic acid amide carrying free carboxyl groups, especially an adduct of a polyacrylate and a stoichiometric deficiency of a primary amine to provide a secondary amine having acrylate functionality, the secondary amine functionality being reacted with a polycarboxylic acid anhydride to form amide groups therewith.Type: GrantFiled: April 5, 1985Date of Patent: June 16, 1987Assignee: DeSoto, Inc.Inventors: Robert E. Ansel, Kevin P. Murray
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Patent number: 4647506Abstract: Flexible, self-cross-linking binders, useful for, e.g., paints and magnetic media composites, are prepared from hydroxyl-containing thermoplastic polymers reacted with condensates of diisocyanates and unsaturated esters. They can be cured with an electron beam.Type: GrantFiled: September 25, 1985Date of Patent: March 3, 1987Assignee: Union Carbide CorporationInventors: Ismael Colon, Robert Johnson
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Patent number: 4607068Abstract: Radiation curable coating compositions, and especially electron beam-curable coating compositions, are disclosed in which magnetizable particles are dispersed in a liquid vehicle comprising a polyethylenically unsaturated polyurethane oligomer which includes a polycarbonate diol, and from 5% to 50%, based on the total weight of unsaturated material, of a polyethylenically unsaturated isocyanurate, such as a triacrylate of tris(2-hydroxyethyl) isocyanurate.Type: GrantFiled: June 3, 1985Date of Patent: August 19, 1986Assignee: DeSoto, Inc.Inventor: Robert E. Ansel
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Patent number: 4595715Abstract: An oriented polyester film comprising ethylene terephthalate as the major repeating unit, which comprises particles of kaolinite and calcium carbonate uniformly dispersed therein, said kaolinite and said calcium carbonate having each an average particle size of 0.05 to 0.8 micron and being contained in such amounts as satisfying the following equations:70.ltoreq.D.times.A.ltoreq.1000 (I)1000.ltoreq.A+B.ltoreq.10000 (II)0.1.ltoreq.B/A.ltoreq.25 (III)wherein D is an average particle size (micron) of calcium carbonate, A is a content (ppm) of calcium carbonate and B is a content (ppm) of kaolinite, said oriented polyester film being excellent in flatness, slipperiness, abrasion resistance, etc. with a small number of coarse particles.Type: GrantFiled: September 7, 1984Date of Patent: June 17, 1986Assignees: Toyo Boseki Kabushiki Kaisha T/A Toyobo Co., Ltd., Nippon Magphane Kabushiki KaishaInventors: Katsuaki Kuze, Yujiro Matsuyama, Kozo Maeda, Takeshi Ota, Masahiro Kobayashi, Tsuyoshi Hongo, Osamu Makimura
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Patent number: 4539389Abstract: A biaxially oriented film of a film-forming aromatic polyester derived from an aromatic dicarboxylic acid as a main acid component and an aliphatic glycol as a main glycol component, said film having surface properties such that(1) it has a surface flatness, R.sub.CLA, of from 0.001 to 0.016 micron,(2) it has a coefficient of travelling friction, .mu.k, of from 0.01 to 0.20, and(3) the following relation is established between R.sub.CLA and .mu.k,0.10.ltoreq.10.times.R.sub.CLA +.mu.k.ltoreq.0.31.Preferably, said film has many minute protrusions on its surface which are attributed to fine particles of titanium dioxide or of both titanium dioxide and calcium carbonate, and has such further surface property that(4) a distribution curve showing the relation between the heights of said many protrusions on the film surface and the numbers of the protrusions having the respective heights does not cross a straight line represented by the following equation (1)log.sub.10 y=-8.0.times.+4.Type: GrantFiled: March 26, 1984Date of Patent: September 3, 1985Assignee: Teijin LimitedInventors: Tsutomu Kiriyama, Shigeru Horie, Tetsuo Ichihashi, Masahiro Oshida
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Patent number: 4503198Abstract: The electron radiation curable resin of this invention is an oligopolyester-urethane resin having urethane bonds at both terminals of a polyester moiety, or a polyester-polyurethane resin wherein polyester moieties are chain-extended through urethane bonds. The resin has a molecular weight of about 1,000 to 50,000, and has a double bond at each terminal of the molecule and contains in the molecure about 0.2 to 30 mol % of carboxylic acid component having a metal sulfonate group based on the total carboxylic acid component.This electron radiation curable resin is suitable as a binder for a magnetic paint for producing magnetic recording medium such as magnetic tape, and can provide a magnetic recording medium having excellent dispersibility, durability, and solvent resistance.Type: GrantFiled: April 18, 1983Date of Patent: March 5, 1985Assignee: Sony CorporationInventors: Seiichi Miyai, Kaoru Nakajima, Masashi Somezawa
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Patent number: 4496686Abstract: Liquid coating compositions adapted to be cured by exposure to penetrating radiation are disclosed in which a liquid vehicle of coating viscosity having an ethylenically unsaturated portion comprising one or more polyethylenically unsaturated materials adapted to cure on radiation exposure, pigment dispersed in the vehicle, and an ethylenically unsaturated radiation-curable dispersant containing a carboxyl group for wetting the pigment and assisting in the stable dipsersion of the pigment in the vehicle. This dispersant is a half amide or half ester of an ethylenically unsaturated polycarboxylic acid anhydride, such as maleic anhydride, with an organic compound having a molecular weight of from 100 to 4000 and which contains a single hydroxy group or a single amino group as the sole reactive group thereof.Type: GrantFiled: May 7, 1984Date of Patent: January 29, 1985Assignee: DeSoto, Inc.Inventor: Robert E. Ansel
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Patent number: 4476257Abstract: A magnetic coating composition used for producing magnetic recording media is disclosed. The composition is comprised of partially oxidized nitrocellulose and magnetic fine powder or magnetic metal fine powder. The composition may also include a synthetic resin binder. The partially oxidized nitrocellulose has a nitrogen content of 8.0 to 12.5% and contains 2.0 to 100 mmol of carboxyl group per 100 g of nitrocellulose. Use of the partically oxidized nitrocellulose gives increased ability to disperse the magnetic powder within the composition and does not adversely effect the adhesion between the composition and the support.Type: GrantFiled: February 24, 1983Date of Patent: October 9, 1984Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Teiichi Ishino, Ikuo Ueda, Rikiya Kai
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Patent number: 4384055Abstract: A hard vinyl chloride resin composition for information signal recording media, said composition consisting essentially of(A) 100 parts by weight of a copolymer having a specific viscosity of 0.16 to 0.31 and composed of 75 to 99% by weight of vinyl chloride, 1 to 10% by weight of ethylene and 0 to 15% by weight of another monomer copolymerizable with said monomers, and/or a polymer mixture having a specific viscosity of 0.16 to 0.31 and composed of at least two polymers selected so that the proportions of monomer components are the same as above, and(B) 15 to 30 parts by weight of carbon black having an oil absorption of 300 to 400 ml/100g and a surface area of at least 900 m.sup.2 /g.Type: GrantFiled: September 16, 1981Date of Patent: May 17, 1983Assignee: Nippon Zeon Co. Ltd.Inventors: Takao Okuda, Nobuhide Hada