Abstract: Alkoxy-modified silsesquioxane compounds are described. The alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber of volatile organic compounds (VOC), especially alcohol, during compounding and further processing. Further described are methods for making alkoxy-modified silsesquioxanes, methods for making vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, and pneumatic tires comprising a component that contains alkoxy-modified silsesquioxanes.

Abstract: Provided by using a catalyst containing an yttrium compound is conjugated diene polymer with very low solution viscosity, improved workability, high degree of branching, and high content of cis-1,4 structures. Also provided is a rubber composition utilizing the polymer and allowing excellent dispersion of reinforcing agent. According to a method of manufacturing a conjugated diene polymer characterized by polymerizing a conjugated diene at 50 to 120° C. in the presence of a catalyst obtained from (A) an yttrium compound, (B) an ionic compound consisting of a non-coordinating anion and a cation, and (C) an organoaluminum compound, the conjugated diene polymer has the following characteristics that: (1) a ratio (Tcp/ML1+4) between a 5 wt % toluene solution viscosity (Tcp) measured at 25° C. and a Mooney viscosity (ML1+4) at 100° C. is 0.1 to 1.2; and (2) a content of cis-1,4 structures is 80% or higher, and a content of 1,2 structures is lower than 5%.

Abstract: The invention relates to a polymer composition comprising a matrix polymer, silica particles dispersed therein, and a coupling agent and a screening agent for the silica particles, and is characterized in that the screening agent is an alkylamine compound. The polymer composition is particularly suitable for the manufacture of rubber tires with improved rolling resistance.

Abstract: A multi-layered membrane comprising a first layer that is substantially white in color; and a second layer including ground thermoset rubber.

Abstract: A plastic packaging component is provided that is formed of a resin containing an electromagnetic spectrally detectable additive mixed with the resin. The resin formed into a plastic packaging component of an aerosol package lid, an aerosol spray button, an aerosol spray tube, a trigger sprayer, an integrated lid-sprayer, a grease cartridge, a grease cap, plastic fiber toweling, a packaging strap, a pail lid, a jar cap, or a brush. A process for detecting a displaced packaging component in an organic production stream is provided that includes adding to a resin an electromagnetically detectable additive intermixed with the resin and forming the additive loaded resin into the plastic packaging component. The production stream is then scanned for the detectable signal of the additive. Upon detecting the additive, an alarm signal is provided that the production stream contains the displaced packaging component.

Abstract: The invention disclosed herein relates to an improved process for making elastomeric polyisoprene articles. In particular, the process of the invention is a system which produces synthetic polyisoprene articles exhibiting tensile strength properties similar to that of solvent-based processes using natural rubber latex. The process comprises an accelerator composition at the pre-cure stage comprising a dithiocarbamate, a thiazole and a guanidine compound. In a preferred embodiment, the accelerator composition comprises zinc diethyldithiocarbamate (ZDEC), zinc 2-mercaptobenzothiazole (ZMBT) and diphenyl guanidine (DPG), in conjunction with a stabilizer, such as sodium caseinate. The invention also includes an elastomeric polyisoprene product made by the process, such as a surgeon's glove.

Abstract: New compositions for use as protective coatings and/or adhesives are provided. The compositions comprise a hydrocarbon resin (e.g., terpene rosin) and a rubber (e.g., EPDM) dispersed or dissolved in a solvent system. The solvent system is preferably a single-solvent system, and the compositions are preferably free of surfactants, dyes, and chromophores. The compositions can be cured or dried to form layers or films that are chemically and thermally resistant, but that can be readily dissolved and removed at the appropriate stage in the fabrication process.

Abstract: Using a target loading value and target intrinsic properties desired for a rubber formulation, two or more fillers are combined to create a blend having the desired intrinsic properties—i. e. a blend can be created emulating the desired intrinsic properties of a single filler system. In another exemplary aspect, knowing the individual loadings of fillers along with the target values desired for the loading of the blend and its intrinsic properties, individual intrinsic properties for at least one unknown filler that will be used to create the blend can be calculated. The unknown filler can then be identified by comparing the calculated intrinsic properties with the intrinsic properties of known fillers. The method allows e.g.) a manufacturer to blend a variety of suitable fillers while maintaining a more limited inventory of fillers than would otherwise be required for multiple rubber formulations.

Abstract: The use of a functionalized organosilicon compound as a coupling agent between an inorganic filler and an elastomer in an elastomer composition including an isoprene elastomer and a reinforcing inorganic filler is disclosed. The compound is selected among functionalized organosilicon compounds including at least one double bond C?C or C?N, and not including any C?C—C?O bonds or N?N bonds, and reacting with the isoprene units according to an electrocyclic reaction, in particular according to a standard cycloaddition reaction [2+1], [2+2], [3+2] or a Diels-Alder reaction [4+2] or an ene-synthesis reaction other than an ene-synthesis reaction between an isoprene unit and a C?C—C?O or N?N function. Also described, are elastomer composition(s) obtained and items manufactured using such compositions.

Abstract: This invention relates to novel sulfur-containing silane coupling agents, and organic polymers containing carbon-carbon double bonds. These novel silanes can be carried on organic and inorganic fillers. The invention also relates to articles of manufacture, particularly tires, made from the elastomer compositions described herein.

Abstract: Blends of carbon black or other fillers is described. The blends of carbon black or other fillers are preferably pre-blended prior to introducing the blend into a product such as an elastomeric or polymeric product.

Abstract: The invention relates to a rubber mixture, in particular for vehicle air-inflated tires, seat belts, belts and hoses. The rubber mixture is characterized by the following composition: at least one polar or non-polar rubber and at least one bright and/or dark filler and at least one softener, wherein the softener is free of polycyclic aromatics according to Directive 76/769/EEC, and wherein the carbon source for the softener comes from non-fossil sources, and other additives.

Abstract: A rubber mixture which exhibits reliable processability contains (A) a rubber or mixture of rubbers, (B) a filler, (C) at least one organosilane, (D) a thiuram accelerator, and (E) a nitrogen-containing co-activator. A weight ratio of thiuram accelerator (D) to nitrogen-containing co-activator (E) is equal to or greater than 1.

Abstract: A rubber composition based on at least one diene elastomer, containing less than 2 phr of zinc, phr meaning parts per hundred parts of rubber (elastomer), and based on at least one reinforcing filler and one sulphur-based crosslinking system, comprising a zinc carboxylate of formula: (RCOO)2Zn, in which R represents a hydrocarbon group chosen from cyclic or non-cyclic, linear or branched alkyl groups having 1 to 16 carbon atoms, aryl groups, aralkyl groups or alkaryl groups having 1 to 16 carbon atoms. Also disclosed is a process for preparing such a rubber composition which is suitable for manufacturing tires or semi-finished products made of rubber intended for these tires.

Abstract: A rubber mixture with improved abrasion with improved abrasion performance, in particular for pneumatic tires, has the following composition: from 30 to 100 phr of at least one diene rubber; from 0.1 to 10 phr of at least one vulcanization accelerator selected from the group consisting of: thiazole accelerators, mercapto accelerators, sulfenamide accelerators, guanidine accelerators, thiuram accelerators, dithiocarbamate accelerators, amine accelerators, thioureas, and/or other accelerators; and a vulcanization system of sulfur comprising elemental sulfur, sulfur donor and silane between 0.25 and 0.08 moles per 100 parts by weight of the rubber elastometer, whereby the free sulfur contributes in the range of 0 to 70%, the sulfur donor contributes in the range of 5 to 30%, and the silane contributes in the range of 20 to 95%.

Abstract: The invention is a method of producing an essentially electrically neutral polymer dispersion, comprising a polymerizing one or more monomers in the presence of a nonionic surfactant, wherein the polymerization preferably occurs in the absence of ionic surfactants. The invention also includes methods of producing positively or negatively charged polymer dispersions comprising producing the essentially nonionic polymer dispersion and further adding a cationically-charged or anionically-charged surfactant or electrolyte. The invention further includes dispersions produced by the methods of the invention and polymer films and powders produced from these dispersions.

Abstract: A method for preparing a functionalized polymer, the method comprising the step of reacting a reactive polymer with a functionalizing agent defined by formula I or formula II: or combinations thereof, where R1, R2, and R3 are each independently a divalent organic group, R4 and R5 are each independently a monovalent organic group, a is an integer from 0 to 1, x is an integer from 0 to 2, y is an integer from 1 to 3, x+y=3, and ? is a protected amino group.

Abstract: Described are diol-derived organofunctional silanes in which the silanes contain cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and methods for the preparation of the silanes. Also described are rubber compositions containing the diol-derived organofunctional silanes, methods for the preparation of the rubber compositions and articles of manufacture containing the rubber compositions, in particular, automotive tires and components thereof.

Abstract: A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.

Abstract: The rubber composition of the present invention is prepared by mixing 10 to 200 parts by mass of silica and 1 to 30 parts by mass of a silane compound having sulfur atom, which has a specific structure such that an organooxysilyl group is present at both ends of the molecule and sulfide or a polysulfide is present at the central portion of the molecule, with 100 parts by mass of a polymer. The rubber composition of the present invention has a small viscosity in the unvulcanized condition and provides excellent dispersion of silica. When this composition is used as a material for a tire tread, a tire exhibiting excellent abrasion resistance, a small rolling resistance and excellent braking property and steering stability on wet roads, can be obtained.

Abstract: The present invention relates to a rubber granulate conversion process comprising steps consisting in: a) pyrolysing the rubber granulates at a temperature between 400 and 500° C. in the presence of water, to obtain a carbonized substance and a gaseous phase; and b) recovering the carbonized substance obtained during the previous step. The invention also relates to the products resulting from the conversion process and to the use of said products.

Abstract: A tire composition with a Shore A hardness, according to DIN 53 505 and ASTM D2240, of not less than 40 and not greater than 95 and a glass-transition temperature Tg (E?max), according to DIN 53 513 with a specified temperature sweep of ?80° C. to +80° C. and a specified compression of 10+0.2% at 10 Hz, not less than ?80° C. and not greater than 0° C., with improved abrasion performance, in particular for pneumatic tires, has the following composition: at least one vulcanizable diene rubber selected from natural rubbers, synthetic polyisoprene rubbers, polyisobutylene rubbers, polybutadiene rubbers (BR), and random styrene-butadiene rubbers; from 35 to 300 phr of at least one active filler selected from carbon blacks, silicas, silicon based fillers, and metal oxides, of which at least 10 phr must be carbon blacks, silicas, or some combination thereof; from 0 to 250 phr of other or further additives; from 0.

Abstract: The present invention provides: a rubber composition for a tire having favorable productivity, excellent heat aging resistance and abrasion resistance, and excellent fuel economy; and a pneumatic tire using the rubber composition. The rubber composition contains neither soluble sulfur nor insoluble sulfur, and contains diene rubber, 1-15 parts by mass of compound 1 represented by formula (1) and 0.1-5 parts by mass of compound 2 represented by formula (2), per 100 parts by mass of the diene rubber, and the amount ratio of compound 1 to compound 2 (compound 1/compound 2) is 1-8. wherein R1-R4 are the same or different, and represent C1-20 alkyl, C6-20 aryl, or C7-20 aralkyl, and n represents an integer of 1-12; wherein R5-R7 are the same or different, and represent C5-12 alkyl, x and y are the same or different, and represent an integer of 2-4, and m represents an integer of 0-10.

Abstract: Moisture curable one-component organosilicon compositions exhibiting excellent resilience and adhesiveness contain an ?-alkoxysilyl-terminated base polymer, aminoalkylalkoxysilane adhesion promoter, and polyolefin bearing succinic anhydride groups.

Abstract: Tire tread comprising a rubber composition, the said composition comprising at least one diene elastomer, one reinforcing filler and one plasticizing system, characterized in that the said plasticizing system comprises, in combination: a plasticizing hydrocarbon resin, the glass transition temperature of which is greater than 0° C.; and a carboxylic acid diester corresponding to the formula (I): R—OOC—(CH2)n—COO—R ?in which n is included within a range from 1 to 15 and the R radicals, which are identical or different, represent a hydrocarbon radical. The invention also relates to the use of such a tread in the manufacture or the retreading of tires exhibiting a substantially improved compromise in properties with regard to the wear resistance and the wet grip.

Abstract: A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[-CaH2a—S[C(?O)]bR]n wherein G is selected from the group consisting of: saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen, and saturated monocyclic silicone [RSiO—]n[R2SiO—]p group of valence n; wherein each R independently is a hydrogen or monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 0 or 1; p is an integer of from 0 to 3; and, n is an integer of from 3 to 6, with the provisos that when b is 0, R is a hydrogen atom, and when G is a non-halogenated, saturated monocyclic aliphatic group of 6 carbon atoms, n cannot be 3.

Abstract: Adhesive, comprising silanized, structurally modified, pyrogenically prepared silicas containing on their surface fixed vinyl groups or vinylsilyl groups, with hydrophobic groups, such as trimethylsilyl and/or dimethylsilyl and/or monomethylsilyl, additionally being fixed on the surface.

Abstract: A vulcanizable composition of matter comprising a rubber component, a filler, a curative for the rubber, where the rubber component includes a multi-modal polymer including at least two distinct peak molecular weights within a range defined by a lower limit of 80 kg/mole and an upper limit of 500 kg/mole.

Abstract: A process of producing an artificial latex, comprising the steps: (a) cement formation, wherein a rubber is dissolved in a suitable hydrocarbon solvent; (b) emulsification of the cement formed in step (a), together with an aqueous soap solution, thus forming an oil-in-water emulsion; (c) hydrocarbon solvent removal, resulting in a latex of the rubber having particles of a median particle size in the range of from about 0.5 to 2.0 ?m, and optionally (d) latex concentration, forming an artificial latex with a higher solids content, characterized in that in step (b) a premix is formed first, which is subsequently homogenized into an oil-in-water emulsion, and wherein the premix is formed by mixing the cement with the aqueous soap solution at a volume ratio of 1:1.

Abstract: Co-agglomerated dispersions and methods for their preparation are described herein. The co-agglomerated dispersions are prepared by co-agglomerating an anionic polymer dispersion and inert particles. The polymers for use in the co-agglomerated dispersions are derived from one or more monomers including at least one conjugated diene monomer. The inert particles have a particle size of less than 2 ?m. Also described herein is an aqueous dispersion including co-agglomerated particles formed from at least one polymer and at least one inert material. Further described herein are foamed polymers, latex-based adhesives, waterproofing membranes, sound absorbing coatings, and methods for their preparation and use.

Abstract: Provided is a composition comprising at least one polymer having a degree of unsaturation of no more than about 50 mol %; a filler selected from the group consisting of carbon black, silica, and mixtures thereof; and a polymeric additive comprising a functional end group reactive with said filler, wherein said polymeric additive has a degree of unsaturation of no more than about 50 mol % and a number average molecular weight between about 1,000 and about 25,000. The composition may optionally contain one or more polymers having a degree of unsaturation of more than 50 mol %. The composition may be particularly useful as a component for a tire.

Abstract: A method for preparing a functionalized polymer, the method comprising providing a reactive polymer, where the reactive polymer includes a carbon anion, an oxygen anion, a sulfur anion, or a nitrogen anion, reacting the reactive polymer with carbon disulfide to form a polymer including a dithio carboxyl group, and reacting the polymer including the dithio carboxyl group with a blocking agent.

Abstract: A crosslinkable rubber composition comprising 0.2 to 10 parts by weight of an aromatic secondary amine-based anti-aging agent and 0.5 to 20 parts by weight of a polyamine-based crosslinking agent with respect to 100 parts by weight of a nitrile rubber including an ?,?-ethylenically unsaturated nitrile unit and an ?,?-ethylenically unsaturated dicarboxylic acid monoester unit, and with iodine value of 120 or less. The present invention can provide a crosslinkable rubber composition, providable of a cross-linked rubber excellent in a variety of properties such as mechanical strength and small in compression set, and a cross-linked rubber obtained by cross-linking the rubber composition.

Abstract: A process for simply and inexpensively producing a conjugated diene polymer with a narrow molecular weight distribution and a high cis-bond content at a low cost is provided. The process comprises a polymerization step, wherein a conjugated diene polymer having a cis-1,4-bond content of 98.5 mass % or more and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) measured by gel permeation chromatography of 2.5 or less is obtained by carrying out a polymerization reaction in conjugated diene compounds using a catalyst composition containing a rare earth element-containing compound or a reaction product of the rare earth element-containing compound with a Lewis base, an aluminoxane and/or organoaluminum compound, and an iodine-containing compound.

Abstract: Waterborne, polymer based coating compositions for interior and exterior use on elastomeric substrates (such as tires) with one or more polymer latex resins (having one or more carboxylic acid groups) in an amount sufficient to provide polymer solids in an amount of from 5 to 50% by weight of the coating; optionally one or more coalescing agents in an amount effective to coalesce and fuse polymer particles of the polymer latex resin into a relatively stretchable film when cured; one or more defoaming agents in an amount effective to enhance foam dissipation prior to film formation; one or more coupling agents having a first reactive group which is capable of bonding with the one or more carboxylic acid groups and a second reactive group which is capable of bonding with an elastomers substrate. Also, a method for applying such compositions to elastomeric substrates, such as tires.

Abstract: A rubber composition, comprising a rubber component, and a carbon black, the carbon black satisfying the dibutyl phthalate (DBP) absorption number [unit: mL/100 g] of the carbon black is from 90 to 180, the difference of the BET specific surface area (BET5) [unit: m2/g] of the carbon black from the external specific surface area (STSA) [unit: m2/g] thereof satisfies the following: 5<(BET5)?(STSA)<12, the ratio between the Stokes diameter (Dst) of the carbon black and the Stokes diameter distribution (?D?50 (half band width)) thereof satisfies the following: 0.70<the ratio of (?D?50)/(Dst)<1.10, and the ratio between the BET specific surface area (BET5) [unit: m2/g] of the carbon black and the iodine adsorption number (IA) [unit: mg/g] thereof satisfies the following: 1.05<the ratio of (BET5)/(IA)<1.35.

Abstract: Nanocomposite compositions containing a graft polymer and a filler such as nano-sized silica having flame resistant properties are described.

Abstract: The present invention is further directed to a method of producing a particulate composite of silica and elastomer comprising the steps of dispersing a diene based elastomer in a hydrophobic liquid to form an elastomer dispersion; mixing the elastomer dispersion with an aqueous solution of an alkali metal silicate to form a mixture; adding a precipitating agent to the mixture to precipitate a porous silica onto the dispersed elastomer to form a particulate composite of silica and elastomer comprising a porous silica shell at least partially surrounding a core of diene based elastomer; and optionally adding a separating agent to remove the hydrophobic liquid from the particulate composite.

Abstract: An alkali metal-reacted aromatic compound which has three or more carbon atoms which are directly bonded to alkali metal atoms and aromatic rings in one molecule is used as a polymerization initiator to polymerize a monomer mixture which is contains at least one conjugated diene compound to thereby produce a radial conjugated diene polymer. Further, active ends of the polymer having active ends which is obtained by this method is made to react with a modifier which can react with the active ends to thereby produce an end-modified radial conjugated diene polymer. According to the present invention, it is possible to provide a method of production of the radial conjugated diene polymer which gives a high degree of freedom of polymer design and easy control of the polymer structure.

Abstract: By a rubber composition for a side wall, including a rubber component containing a natural rubber component consisting of a natural rubber and a modified natural rubber, 20 to 60 parts by mass of silica, and 0.5 to 15 parts by mass of at least any one of a terpene-based resin and a rosin-based resin based on 100 parts by mass of the rubber component, and a pneumatic tire provided with a side wall rubber using the same, a rubber composition for a side wall in which both of maintenance of properties desired in a rubber composition for a side wall such as durability and improvement in processibility can be realized while a use amount of a raw material derived from a petroleum source is reduced, and a pneumatic tire in which running safety is improved by providing with a side wall rubber using the same, are provided.

Abstract: Provided are a process for efficiently producing a rubber wet master batch in which a dispersibility of carbon black in the rubber is improved, in which a reinforcing property and an abrasion resistance of the rubber can be enhanced by using carbon black having a high surface activity, in which a yield of the carbon black in the wet master batch obtained is not reduced and in which a handling property of the carbon black is good as compared with master batches prepared by using a granulated and dried substance of carbon black prepared by a conventional wet method and non-granulated carbon black, a carbon black-containing rubber wet master batch obtained by the above process and a rubber composition and a tire prepared by using the master batch.

Abstract: The invention relates to rubber mixtures containing silane and having possibly functionalized diene rubbers and microgels, to a method for the production thereof, and to the use thereof to produce wet slipping resistant and low-rolling resistance motor vehicle tire treads having high abrasion resistance.

Abstract: The present invention relates to a precipitated silica for elastomers and, more particularly, to a new highly dispersible and highly reinforcing precipitated silica for elastomers. The invention further provides the process for its production and rubber products made therefrom.

Abstract: The present teachings provide a composition that includes a functionalized polyfluoropolyether and functionalized polybutadiene in a weight ratio of functionalized polyfluoropolyether/functionalized polybutadiene of from about 20/80 to about 80/20 in a solvent. The composition can be used to form a surface layer having a water contact angle of greater than about 90° and a hexanedecane contact angle greater than about 45°.

Abstract: Provided is a rubber composition comprising an inorganic filler, a compound having at least one group A reacting with a rubber and two or more groups B adsorbing on the inorganic filler described above in the same molecule, a compound having the group A reacting with a rubber and an amino group in the same molecule or acrylate or methacrylate having a specific structure and further comprising, if necessary, a silane coupling agent. This makes it possible to provide a rubber composition which is excellent in the dispersibility of an inorganic filler, so that it does not elevate a viscosity of a non-vulcanized rubber and does not damage the processability and which does not bring about roughening on the surface of a rubber and is improved in a storage modulus.

Abstract: A modified conjugated diene polymer comprises a modifying group based on a low molecular weight compound having two or more tertiary amino groups and one or more alkoxysilyl groups in a molecule which bonds to a conjugated diene polymer obtained by polymerization of a conjugated diene compound or a conjugated diene polymer obtained by copolymerization of a conjugated diene compound and an aromatic vinyl compound. The process for producing the modified conjugated diene polymer comprises the steps of: polymerizing a conjugated diene compound or copolymerizing a conjugated diene compound and an aromatic vinyl compound in a hydrocarbon solvent using an alkali metal initiator and/or an alkaline earth metal initiator; and reacting active terminals of the resulting polymer with a low molecular weight compound having two or more tertiary amino groups and one or more alkoxysilyl groups in the molecule.

Abstract: The present invention relates to an essential colourless binder composition comprising a naphthenic oil having a total content of naphthenics of 35%-80% by weight, based on the total weight of the naphthenic oil, and a petroleum or synthetic hydrocarbon resin, wherein the ratio of the naphthenic oil and the petroleum or synthetic hydrocarbon resin is between 10:90 to 90:10. The essential colourless binder composition is suitable for use in coloured asphalt compositions and emulsions.

Abstract: A composition is provided for use with an unsaturated elastomer. The composition may include a sulfur-functional linear polyorganosiloxane. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group. Under certain conditions, the sulfur group may react with the unsaturated elastomer. The invention includes embodiments that may relate to methods of making and using the sulfur-functional linear polyorganosiloxane in elastomer compositions.

Abstract: The invention relates to a rubber composition that is free of zinc or that contains less than 0.5 phr of zinc, which can be used for the manufacture of tyres, based on at least: one diene elastomer; one sulphur-based crosslinking system; one inorganic filler as reinforcing filler; one blocked mercaptosilane of general formula I below: (R3O)R2R1—Si—Z—S—C(?O)-A in which: R1 and R2, which are identical or different, represent a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; R3 represents a monovalent hydrocarbon-based group chosen from linear or branched alkyls having from 1 to 4 carbon atoms; A represents hydrogen or a monovalent hydrocarbon-based group chosen from alkyls, which are linear or branched, cycloalkyls or aryls, having from 1 to 18 carbon atoms; Z represents a divalent bonding group comprising from 1 to 18 carbon atoms.

Abstract: The present invention relates to rubber compositions containing a filler and comprising (i) at least one rubber containing olefinic unsaturation and (ii) functionalized nano transition metal oxide and/or sulfide particles. The invention further relates to a method of manufacture of the rubber compositions and to the use of the compositions in tires, belts and/or hoses.