Abstract: Coating agent for producing an electric insulating coating on an electro steel sheet with good punching quality, weldability, annealing stability and high insulation resistance. Said agent comprises a metal organic and an organic film-forming agent and, optionally, chemically inert inorganic pigments and/or filler and other common additives such as antifoaming agents, leveling agents, catalyzers and the like.

Abstract: An adhesive composition based on resorcinol novolac or resorcinol-phenolic novolac contains 35-75% by weight of novolac, less than 25% by weight of water, and 10-40% by weight of an aliphatic divalent, trivalent alcohol. The adhesive composition may also contain up to 20% by weight of filter, based on the amount of novolac, water and alcohol. In a method for preparing the adhesive composition based on resorcinol novolac or resorcinol-phenolic novolac, the novolac is produced by conventional condensation, whereupon an aliphatic divalent, trivalent or tetravalent alcohol is added and water in the novolac is distilled off, resulting in an adhesive composition as defined above. Alternatively, the amount of water can be reduced in the condensation of the novolac to be replaced with an aliphatic divalent, trivalent or tetravalent alcohol.

Abstract: An aqueous phenolic resin dispersion that includes an aqueous continuous phase and, dispersed within the aqueous phase, the reaction product of a phenolic resin precursor and a modifying agent wherein the modifying agent includes at least one ionic group and at least one functional moiety that enables the modifying agent to undergo condensation with the phenolic resin precursor. The resulting dispersed phenolic resin reaction product includes at least one phenolic ring to which is bound the ionic group from the modifying agent. The pendant ionic group is a sulfate, sulfonate, sulfinate, sulfenate or oxysulfonate and the reaction-enabling moiety preferably is a hydroxy or hydroxyalkyl.

Abstract: Disclosed is a stabilized phenolic resin melamine dispersion comprising a liquid alkaline resole resin composition and solid melamine crystal dispersed throughout the resin composition. The liquid alkaline resole resin composition comprises the reaction product of combining formaldehyde and phenol at a formaldehyde to phenol mole ratio of about 0.5:1 to about 3.5:1 in the presence of a basic catalyst. The melamine crystal to phenol mole ratio ranges from about 0.01:1 to about 1:1. Moreover, the composition has a free formaldehyde content of at most about 0.5 weight percent. A method for making this dispersion is also disclosed.

Abstract: An adhesive composition based on resorcinol novolac or resorcinol-phenolic novolac consisting essentially of 35-75% by weight of novolac, less than 25% by weight of water, and 10-40% by weight of an aliphatic divalent, trivalent or tetravalent alcohol. The adhesive composition may also contain up to 20% by weight of filler, based on the amount of novolac, water and alcohol. In a method for preparing the adhesive composition based on resorcinol novolac or resorcinol-phenolic novolac, the novolac is produced by conventional condensation, whereupon an aliphatic divalent, trivalent or tetravalent alcohol is added and water in the novolac is distilled off, resulting in an adhesive composition as defined above. Alternatively, the amount of water can be reduced in the condensation of the novolac to be replaced with an aliphatic divalent, trivalant or tetravalent alcohol.

Abstract: A phenol resin molding compound which comprises phenol resin, a curing agent for the phenol resin, hydrogenated NBR, chopped strands of glass fibers and powdery glass fibers having a length of about 10 to about 200 .mu.m has a considerably improved elongation and an elevated safely factor from cracking without any substantial lowering of the modulus of tensile elasticity.

Abstract: The present invention relates to a glass fiber binding composition comprising an effective binding amount of an aqueous soluble furan resin, 15 to 99 percent by weight water, and an effective amount of a catalyst for curing the furan resin. The invention further pertains to a process of binding glass fibers at junctions of the fibers comprising the steps of providing newly formed glass fibers, applying an effect binding amount of an aqueous soluble furan resin to the junctions of the glass fibers, and curing the resin at the junctions of the glass fibers. Finally, the invention also discloses a glass fiber composition comprising a plurality of glass fibers having a plurality of junctions where two or more fibers meet, and an effective binding amount of an aqueous soluble furan resin comprising 15 to 99% water applied to the junctions of the glass fibers.

Abstract: This invention relates to a process for reclaiming ester-cured phenolic resin bonded sand. The process comprises contacting attrition reclaimed sand with a compound which converts potassium compounds to a form having a melting point of least 550.degree. C., and then thermally treating the sand at a temperature below that which the resulting potassium compound fuses.

Abstract: A molding compound which comprises phenol resin or polyphenylenesulfide resin, chopped strands of glass fibers and powdery glass fibers having a length of about 10 to about 200 .mu.m is used suitably for molding a resin stator having an insert molded or post-inserted metallic outer race.

Abstract: A self-hardening mold material composition comprising 100 parts by weight of molding sand, 0.1 to 6 parts by weight of a component (a), 0.1 to 4 parts by weight of a component (b), 0.05 to 2.0 parts by weight of a component (c) as SiO.sub.2, and 0.01 to 0.

Abstract: This invention relates to foundry mixes which comprise a dry foundry aggregate and a polyurethane-forming foundry binder. The binder components include a polyether polyol component and an organic polyisocyanate component which is cured with a liquid tertiary amine catalyst. The foundry mixes are used to prepare foundry shapes made from foundry mixes by a no-bake process. The resulting foundry shapes are used to cast metal parts from ferrous and non ferrous metals.

Abstract: A dispersion for producing an adhesive, waterproof and hydrolysis-resistant bonding layer for bonding metal, ceramics, glass and for polymer-plastic bonds, including a phenol resin-methacrylate dispersion containing phenol with free methylol groups, one or more mono- or multifunctional methacrylate compounds, dispersed acrylate, water and acetone.

Abstract: A wood adhesive composition including an effective amount of a phenol-formaldehyde resin; and a modifying agent which agent renders the composition capable of bonding to a hard wood.

Abstract: The present invention provides a monolithic refractory with self-flowability. A monolithic refractory of the first invention of the present invention contains refractory aggregates, liquid novolak type phenol resin and an organic separation preventative. A monolithic refractory of the second invention of the present invention contains refractory aggregates and a novolak type phenol resin solution with a number-average molecular weight of not more than 600. The first invention of the present invention gives good hot flowability and prevention of sedimentation of the aggregates to the monolithic refractory. The second invention gives good hot flowability, stabilization in adhesion and prevention of warpage of the hardened body obtained. With the present invention a monolithic refractory can be suitably selected and used according to its intended use and purpose.

Abstract: A latent catalyzed phenolic resin composition is provided containing a thermosetting phenolic resole resin and a latent catalyst consisting essentially of a primary or secondary amine salt of a strong acid.

Abstract: A composition and method of treating paint spray booth water to detackify organic solvent based paint particles. The composition comprises a melamine polymer obtained from the reaction of melamine, aldehyde and an amine selected from the group consisting of dicyandiamide and glycine. These melamine polymers may be used in combination with a polyacrylamide, which combination exhibits surprising and unexpected effects when used to detackify organic solvent paint particles.

Abstract: The invention relates to a composition consisting of a melamine solid suspended or dispersed in a resole resin. The method of the invention favors the intermolecular condensation polymerization reaction between phenol and melamine, rather than homopolymerization between phenol molecules or between melamine molecules. This invention reduces formaldehyde emissions by favoring a reaction whose by-product is water rather than formaldehyde. The compositions are useful for bonding glass fiber mats used for thermal and acoustical insulation.

Abstract: A composition comprising a 1,2-dialkylidenecyclobutane such as 1,2-dimethylenecyclobutane, a polyacrylate monomer and an optional polyimide such as a bismaleimide can be thermally cured to a tough copolymer having a high glass transition temperature.

Abstract: A latent catalyzed phenolic resin composition is provided containing a thermosetting phenolic resole resin and a latent catalyst consisting essentially of a primary or secondary amine salt of a strong acid.

Abstract: A composition comprising a 1,2-dialkylidenecyclobutane such as 1,2-dimethylenecyclobutane, a diallyl compound and a polyimide such as a bismaleimide can be thermally cured to a tough copolymer having a high glass transition temperature.

Abstract: Polymer powders which are redispersible in water and are obtainable by atomizing aqueous polymer dispersions to which from 3 to 50% by weight, based on the polymer, of a water-soluble alkali metal salt or alkaline earth metal salt of a phenolsulfonic acid/formaldehyde condensate has been added are used as additives in hydraulic binders.

Abstract: Certain polyether polyols are used in polyurethane-forming binders to improve the shakeout of molds and cores, made by cold-box and no-bake processes. Such molds and cores are used to make metal castings, particularly from low melting metals such as aluminum.

Abstract: A novel adhesive composition capable of bonding strongly polyester fibers and rubbers with reduced adhesive deterioration even at high temperatures is provided which comprises, as a predominant component, a co-condensation resin obtained by co-condensing at least one member selected from compounds (I) represented by the following general formula, ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen atoms, alkyl groups or alkoxy groups, the sum of carbon atoms of R.sub.1 and R.sub.2 being 0 to 4, at least one member selected from compounds (II) represented by the following general formula, ##STR2## wherein R.sub.3, R.sub.4 and R.sub.5 are hydrogen atoms or alkyl groups, the sum of carbon atoms of R.sub.3, R.sub.4 and R.sub.5 being 0 to 4, and aldehyde.

Abstract: An aniline-resorcin-formaldehyde copolycondensation product having a particular mol ratio of aniline to resorcin is used in an adhesive composition for well adhering fibrous material to rubber.

Abstract: A dark colored glass fiber insulation having improved moisture tolerance prepared using an aqueous phenolic resole resin composition containing a water soluble borate and cured under alkaline conditions.

Abstract: Modified benzylic ether resole resins and process for their preparation. The resins are prepared by treating a phenol with a molar excess of aldehyde in the presence of a divalent metal ion catalyst at a pH below 7 followed by further reaction at a pH above 8 in the presence of an alkaline catalyst. Alkaline solutions of the resins are used as foundry binders in an ester cure process.

Abstract: Toluene sulfonate salts of 2-alkyl imidazolines, e.g., 2-undecyl-4,4,5,5-tetramethyl imidazoline, are described. These compounds may be used as internal or external antistatic agents for fibers, e.g., acrylic fibers, and synthetic polymers, e.g., polystyrene.

Abstract: Phenolic molding compositions, particularly useful as sheet molding compounds comprise:(a) a resole phenolic resin,(b) a curing agent selected from the group consisting of alkaline earth metal oxides or hydroxides and silanes,(c) a filler,(d) a lactone such as butyrolactone, and(e) a fiber reinforcement.

Abstract: Cationic paint binders, particularly binders of the type used in cathodic electrodeposition coatings which crosslink through transesterification, transamidation, transurethanization, or through the reaction of chain end double bonds catalyzed with a condensation product of a dialkyltinoxide and a compound carrying at least one hydroxyl group are described. The hydroxyl compounds are the aliphatic alcohols, phenols, alkanolamines, or the reaction products of primary amines with monoepoxy compounds. The catalysts of the invention provide very good stability and good compatibility in aqueous cationic paint materials.

Abstract: A condensation product of phenol, formaldehyde and urea condensed in the presence of a basic catalyst, said condensation product being a liquid and having a free phenol content below 0.5%, a free formaldehyde content below 3%, expressed by weight based on the total weight of liquid, and a dilutability, measured at 20.degree. C., of at least equal to 1000%.

Abstract: A fast-curing, melamine-modified phenolic laminating resin is described comprising the co-condensation product of aldehyde, phenol and melamine in a water-soluble organic solvent. The modified laminating resin exhibits sufficiently high penetration and curing characteristics for use in a low pressure, continuous laminating process.

Abstract: There is provided a method for preparing cured moulded article of a predetermined density of from 1.66 to 9.0 which comprises selecting the resin and determining it % weight loss and % porosity under the curing conditions for the selected resin, then selecting a high density filler and a low density filler and resolving the equation: ##EQU1## wherein K is the desired density of the end product and has a value of from 1.66 to 9.0; HD is the density of the selected high density substantially water-insoluble material and has a value of above 3.2; ID is the density of the selected medium density substantially water-insoluble material and has a value of from 1.5 to 3.2; R is the density of the cured binding resin and has a value between 0.8 to 1.

Abstract: Novel metal-modified phenolic resins useful in the color developer part of a carbonless copy paper system are disclosed, as well as methods for preparing such resins. The metal-modified phenolic resins are reaction products of an aromatic carboxylic acid and a partial condensation reaction product (an oligomer) of a phenol and an aldehyde. The metal-containing compound is added either to the mixture of phenol and aldehyde in forming the oligomer or to the mixture of aromatic carboxylic acid and the oligomer. The color developer materials of the invention are coated on a paper substrate which forms a part of a pressure sensitive recording paper system. The color developer materials exhibit improved performance over prior art colored developer materials.

Abstract: A fast-curing, melamine-modified phenolic laminating resin is described comprising the co-condensation product of aldehyde, phenol and melamine in a water-soluble organic solvent. The modified laminating resin exhibits sufficiently high penetration and curing characteristics for use in a low pressure, continuous laminating process.

Abstract: A binder composition containing a phenolic resin, a polyisocyanate, a phosphorus based acid and optionally an acid halide and/or a base, and methods of making and using the same.

Abstract: Binders are described based on acid curing phenol resins and acid curing agents which, after mixing, have an extended processability time but nevertheless exhibit a rapid curing time at relatively low temperatures. They are obtained by using, as the resin, aqueous phenol resols and, as the curing agent, either copper, aluminum, or iron(III) salts of aromatic sulfonic acids or addition products of hydroxy-containing, water-compatible polyols with aromatic sulfonic acids or mixtures of these salts and the polyol addition products. The binders are used for impregnation of fabrics, for production of abrasives and for fiber reinforced plastics.

Abstract: What is disclosed are aqueous compositions which are useful for coating solid substrates such as glass, plastic and metal. The aqueous compositions comprise colloidal silica, a phenolic resin, water and at least one hydrolyzable silane. An example of such a composition is colloidal silica, phenolic resin, water and CH.sub.3 SiO.sub.3/2 obtained from CH.sub.3 Si(OCH.sub.3).sub.3.

Abstract: Water-dilutable resinous products are obtained by reacting(A) a resin having at least one phenolic hydroxyl group and a free position ortho and/or para to a phenolic hydroxyl group, and containing a residue formed by polymerization of a vinyl monomer in the resin or in a precursor thereof,(B) an aldehyde, and(C) sulphurous acid or an organic acid containing a primary or secondary amino group or a mercaptan group and a carboxylic, sulphonic or phosphonic acid group, or a water-soluble salt thereof.Aqueous compositions containing the resinous products and, if required, and aminoplast, a phenoplast or a blocked polyisocyanate, usually together with a minor amount of an organic solvent, are useful in the formation of surface coatings.

Abstract: In a process for hardening phenol-formaldehyde resol resins, comprising conducting the hardening of the resins with an acidic solution of water and/or an organic solvent having dissolved therein an aromatic sulphonic acid and/or concentrated sulphuric acid, the improvement comprising the hardening in the presence of aniline added to the phenolic resin beforehand in a quantity of between about 0.5 and 2% relative to the weight of the phenolic resin whereby the pot life is extended and the cure time is satisfactory, the resultant products being especially useful as prepegs.

Abstract: A binder containing a phenolic resin; a polyisocyanate; a curing component, and a phosphorus halide and use thereof.

Abstract: An aqueous dispersion comprising a poly(3,4-dihydro-3-substituted-1,3 benzoxazine) and a protonated reactive polyamine, wherein the polyamine is at least difunctional, its reactive groups being primary or secondary amine and is protonated with an inorganic or organic acid and wherein the poly(dihydrobenzoxazine) is the reaction product of about 1 equivalent of a primary amine, about 1 equivalent of a phenol and about two equivalents of formaldehyde. The dispersions can be dried and cured to provide useful surface coatings and primers. The curing step occurs without evolution of volatile matter.

Abstract: A phenol-formaldehyde resol to which urea has been added is mixed with a boric acid-hydroxyl-amide component to provide high temperature resistant binder compositions for use in the manufacture of thermally stable bonded mineral fibre insulation structures.

Abstract: This invention is concerned with foundry binder compositions for alkaline aggregates such as reclaimed sand, Olivia sand, alumina sand, etc., which cure at ambient temperatures. The binder composition is composed of phenolic resins, polyisocyanates and a hydrogen chloride emitting substance upon hydrolysis. Curing of this composition is by gaseous amines. The hydrogen chloride emitting substance on hydrolysis is selected from the following: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 can be selected from: Hydrogen, Chlorine, alkyl, vinyl or alkoxy, or(b) Thionyl chloride, sulfuryl chloride, acid chlorides of sulfur, such as methyl chlorosulfuric acid, ethyl chloroculfuric acid.

Abstract: An aqueous solution of a resin glue comprising formaldehyde, urea, melamine and phenol is obtained when phenol, formaldehyde and not more than 0.35 mole of an alkali metal bisulfite per mole of phenol are reacted to give a phenol-formaldehyde condensate, formaldehyde and urea in a molar ratio of not more than 2.5 are reacted to give a urea-formaldehyde condensate, and the reaction products are in turn reacted with melamine and formaldehyde.

Abstract: A method of manufacturing a lignosulfonate-phenol-formaldehyde resin includes heating a mixture of phenol, formaldehyde, lignosulfonate and alkali at a temperature of 60.degree. C. to 100.degree. C. and a pH of 8-13. The lignosulfonate comprises about 5 to about 80 percent of the total weight of phenol, formaldehyde and lignosulfonate and the lignosulfonate is mixed with said phenol and formaldehyde before substantial reaction between said phenol and said formaldehyde. Also disclosed are fibrous articles manufactured using this resin as a binder.

Abstract: A foundry composition adaptable to forming cores and molds comprising a foundry aggregate, a binder therefor, a catalyst and an amine, the binder being a substituted phenol.

Abstract: Particulate resoles are produced by mixing phenol, formaldehyde and amine in an aqueous medium containing a protective colloid. The resoles exhibit improved cure rate and sinter resistance when an alkaline compound is added to the reaction mixture after particulate formation.

Abstract: A composition containing a methylene donor, hydrophobic component containing an organic hydrophobic diluent and an isocyanate; and an aqueous component containing a water compatible aldehyde condensate and use thereof as an impregnant or bonding agent for cellulosic materials including paper, wood and cotton, and/or fibrous materials including synthetic fibers, such as rayon and nylon.

Abstract: A method of manufacturing a lignosulfonate-phenol-formaldehyde resin includes heating a mixture of phenol, formaldehyde, lignosulfonate and alkali at a temperature of 60.degree. C. to 100.degree. C. and a pH of 8-13. The lignosulfonate comprises about 5 to about 80 percent of the total weight of phenol, formaldehyde and lignosulfonate and the lignosulfonate is mixed with said phenol and formaldehyde before substantial reaction between said phenol and said formaldehyde. Also disclosed are fibrous articles manufactured using this resin as a binder.

Abstract: Modified benzylic ether resole resins and process for their preparation. The resins are prepared by treating a phenol with a molar excess of aldehyde in the presence of a divalent metal ion catalyst at a pH below 7 followed by further reaction at a pH above 8 in the presence of an alkaline catalyst. Alkaline solutions of the resins are used as foundry binders in an ester cure process.