Abstract: A rubber asphalt and a preparation method thereof are disclosed. The rubber asphalt comprises matrix asphalt and rubber powder modifier in a ratio of 4:1-4, wherein the rubber powder modifier comprises waste tire rubber powder and hexanediol in a ratio of 94-96:6-4. The method comprises the following steps: mixing the hexanediol with the waste tire rubber powder according to the ratio and stirring and wetting to obtain the rubber powder modifier; placing the matrix asphalt into a reaction kettle and heating to 90-170° C.; adding the rubber powder modifier into the reaction kettle according to the ratio; and raising the temperature to 190-210° C. under the stirring state to obtain the rubber asphalt. The rubber asphalt has an extensibility of 13-19 cm at 5° C., a penetration of 68-75 at 25° C. and a softening point of 53-90° C. The asphalt-aggregate ratio of a mixed material on the subsequent work section can be reduced to 6-8 from 8-10.
Abstract: Pavement compositions containing increased amounts of reclaimed asphalt pavement (RAP) are described. Addition of polyphosphoric acid (PPA) to pavement compositions containing RAP allows increased RAP content in road pavements while maintaining acceptable properties in the final pavement composition. Methods for producing road pavements containing RAP and PPA are also provided.
Abstract: The present invention relates to a method for preparing an industrial asphalt comprising sparging an oxygen containing gas through an asphalt flux in the presence of 0.25 weight percent to about 12 weight percent of a highly saturated rubbery polymer at a temperature within the range of about 400° F. to about 550° F. for a period of time which is sufficient to increase the softening point of the asphalt flux to a value which is within the range of 185° F. to 250° F. and a penetration value of at least 15 dmm to produce the industrial asphalt. The highly saturated rubbery polymer can be a styrene-ethylene/butylene-styrene block copolymer rubber or a highly saturated styrene-ethylene/propylene-styrene block copolymer rubber.
Type:
Grant
Filed:
May 23, 2012
Date of Patent:
December 2, 2014
Assignee:
Building Materials Investment Corporation
Inventors:
Keith Edward Stephens, Nicholas R. Soto, Denis Muki Tibah
Abstract: Disclosed herein are an asphalt concrete mixture, an asphalt binder composition, and methods of preparing the related compositions. The asphalt binder compositions include a polyphosphoric acid, a macromolecular polymer having a saturated backbone with macromolecular modifications, sulfur, and non-surfactant additives based on wax chemistry. The compositions are capable of being performance graded and being used in warm mix asphalt applications.
Type:
Grant
Filed:
March 28, 2014
Date of Patent:
November 25, 2014
Assignee:
Saudi Arabian Oil Company
Inventors:
Milind M. Vaidya, Anwar H. Khawajah, Rashid M. Othman, Laurand Lewandowski
Abstract: A Performance Grade sulfur-extended asphalt binder emulsion is made by combining a viscosifier, an emulsifier, a Performance Grade sulfur-extended asphalt binder, optionally a saponification agent, and a base aqueous solution. During creation of the asphalt emulsion, none of the components or combinations of them exceeds 275° F. The Performance Grade sulfur-extended asphalt binder composition is made by combining free or element sulfur, a linear alkane material, optionally a saturated-backbone polymer modifier, optionally a non-aqueous acid, and a base asphalt. The disclosed Performance Graded sulfur-extended asphalt binder and Performance Graded asphalt sulfur-extended asphalt binder emulsion allow operators using these products directly or in combination with aggregates and other materials to mix and blend the compositions, and apply the compositions in the field, at temperatures less than 300° F.
Type:
Grant
Filed:
October 26, 2012
Date of Patent:
November 11, 2014
Assignee:
Saudi Arabian Oil Company
Inventors:
Milind M. Vaidya, Anwar H. Khawajah, Jean-Pierre R. Ballaguet, Laurand Lewandowski
Abstract: The present invention is related to dispersion compositions and asphalt compositions including the dispersion compositions. The dispersion compositions include a microgels dispersed in a continuous oil phase. The dispersed microgels include at least one water swollen/swellable polymer, water soluble polymer, or combination thereof. The asphalt compositions include bitumen, aggregate, and a dispersion composition having a microgels dispersed in oil. The dispersed microgels include at least one water swollen/swellable polymer, water soluble polymer, or combination thereof.
Abstract: The invention relates to a bituminous composition containing at least one bitumen and at least one polyolefin capable of forming a supramolecular assembly comprising one or more associative group(s). The invention also relates to the use of such bituminous composition for the preparation of asphalt mixtures useful for the coating of rolling surfaces, for the preparation of water-proofing coatings, and for the preparation of adhesive formulations.
Type:
Grant
Filed:
August 18, 2010
Date of Patent:
October 7, 2014
Assignee:
Ceca S.A.
Inventors:
Juan Antonio Gonzalez Leon, Gilles Barreto
Abstract: The invention relates to asphalt emulsions comprising an asphalt component selected from the group consisting of a solvent extracted asphalt, an oxidized asphalt, and combinations thereof. The invention also relates to products made therefrom, including fibrous mats comprising a fiber component, such as glass fibers, and a binder component comprising an asphalt emulsion. The invention further relates to wet-laid processes for manufacturing fibrous mats and that employ the use of an amphoteric surfactant, which is applied to a wet fiber web prepared from a dispersion of fiber components, such as glass fibers.
Type:
Grant
Filed:
December 5, 2012
Date of Patent:
September 23, 2014
Assignee:
Building Materials Investment Corporation
Inventors:
Younger Ahluwalia, James A. Svec, Margie Beerer
Abstract: Straight run bitumen is widely used in the production of built-structure waterproofing systems, more particularly waterproofing membranes. In order to be able to obtain supplies of straight run bitumen wherever it is obtainable at favorable prices, it would have to be transported over relatively long distances. Since straight run bitumen is viscid at ambient temperature, it would have to be transported hot, which is not possible with conventional straight run bitumen. According to the invention, the straight run bitumen is admixed with a small proportion of at least one hydrocarbonaceous polymer. This solidifies straight run bitumen at ambient temperatures, making it transportable cold in the solid state.
Abstract: A modified toner based additive is a mixture of a toner powder and a second material selected from a group including a gelling clay, a reactive agent, an elastomer, a functional filler, a handling and agglomerating agent, a compatibilizer and mixtures thereof.
Abstract: One embodiment provides a process for preparing an asphalt-coated crumb rubber composition that meets the specification set forth in ASTM D80-02 or deviations thereof which may be established by the specifying agency from time to time. The process generally comprises obtaining asphalt of different penetration grades, combining the asphalt of each grade with preselected chemicals to form separate premixed components, blending the premixed components together under predetermined conditions to form, upon curing, an asphalt-coated crumb rubber composition that meets certain physical requirements for asphalt-rubber binder (ARB), such as those set forth in ASTM D8-02. Advantageously, the resulting asphalt-coated crumb rubber composition not only meets the physical requirements of ARB used in road paving but also has improved dispersion of the rubber, such as dispersion of the rubber in an oil-in-water emulsion of an asphalt.
Abstract: An asphalt binder includes asphalt and an asphalt binder modifier, which includes bio-oil. The asphalt binder can include a carboxyl additive. The asphalt can optionally include polymer-modified asphalt. An asphalt material includes mineral aggregate, an asphalt material binder including asphalt, and an asphalt binder modifier including bio-oil. A method for making the asphalt binder is disclosed. The asphalt material includes asphalt pavement and roofing shingles. The asphalt binder can be emulsified with water and a surfactant for use as a weatherproofing sealant or as an adhesive.
Type:
Application
Filed:
March 17, 2014
Publication date:
July 17, 2014
Applicant:
Iowa State University Research Foundation, Inc.
Inventors:
Ronald Christopher WILLIAMS, Robert C. BROWN, Sheng TANG
Abstract: Disclosed herein are an asphalt concrete mixture, an asphalt binder composition, and methods of preparing the related compositions. The asphalt binder compositions include a polyphosphoric acid, a macromolecular polymer having a saturated backbone with macromolecular modifications, and sulfur. The compositions are capable of being performance graded.
Type:
Grant
Filed:
November 3, 2010
Date of Patent:
July 8, 2014
Assignee:
Saudi Arabian Oil Company
Inventors:
Milind M. Vaidya, Anwar H. Khawajah, Rashid M. Othman, Laurand Lewandowski
Abstract: A saturated elastomeric mixture is disclosed having a cured or vulcanized elastomer crumb rubber and atmospheric distillations bottoms residue is disclosed.
Abstract: Disclosed herein are an asphalt concrete mixture, an asphalt binder composition, and methods of preparing the related compositions. The asphalt binder compositions include a polyphosphoric acid, a macromolecular polymer having a saturated backbone with macromolecular modifications, sulfur, and non-surfactant additives based on wax chemistry. The compositions are capable of being performance graded and being used in warm mix asphalt applications.
Type:
Grant
Filed:
November 3, 2010
Date of Patent:
May 13, 2014
Assignees:
Saudi Arabian Oil Company, PRI Asphalt Technologies, Inc.
Inventors:
Milind M. Vaidya, Anwar H. Khawajah, Rashid M. Othman, Laurand Lewandowski
Abstract: A method for rejuvenating a bitumen containing compositions includes adding to the bitumen containing compositions a distillation residue of cashew nut shell liquid (CNSL). The distillation residue may be obtained by distillation of cashew nut shell liquid up to a temperature of between 250 and 350° C. The bitumen containing composition may be selected from: bitumen, asphalt, roof covering, insulating material, shore covering material, and anti-drum plates.
Type:
Grant
Filed:
January 21, 2010
Date of Patent:
April 22, 2014
Assignee:
Van Weezenbeek Specialties B.V.
Inventors:
Jeroen Berend Venema, Antonius Caspar Johannes Eijkenboom, Koen Dimitri van Weezenbeek, Sebastiaan Joannes van Weezenbeek
Abstract: A flame retardant composition is produced by mixing a flammable organic material with an inorganic phosphorus-inorganic phosphoric oxyacid compound or its salts. The inorganic phosphorus-inorganic phosphoric oxyacid compounds are produced by reacting an inorganic phosphorus compound having a valence of 3-4 with an inorganic phosphorus oxyacid with a valence of 5. Carbonization auxiliaries, metal-containing compound having a carbonization acceleration effect, a comb-like polymer and a filler may be added with the flame retardant composition.
Abstract: Cross-linked rubber obtained from a rubber composition, which comprises 100 parts by weight of EPDM, 5-120 parts by weight carbon black, 70-150 parts by weight of fine bituminous powder, and 0.2-8 parts by weight of an organic peroxide, has distinguished heat resistance and sealability, and can suppress blister generation due to pressure changes when used in contact with carbon dioxide, and is specifically distinguished foaming-resistance characteristics due to abrupt pressure reduction of carbon dioxide, which are the necessary characteristics of seal material for carbon dioxide refrigerant, and also distinguished compression set characteristics, which determine the product life at elevated temperatures, and thus is suitable for use as carbon dioxide seal materials, such as O rings, packings, gaskets, oil seals, valves, etc.
Abstract: A roofing membrane that includes a blend of thermoplastic polyurethane and petroleum liquid so as to improve the UV stability of the blend without adversely affecting the flexibility of the dried and/or cured blend.
Abstract: The present application relates generally to bio-adhesive components isolated from bio-oil prepared from animal waste, methods of preparation of the bio-adhesive components and uses thereof. Such uses include, but are not limited to, asphalt bio-binders, bio-adhesion promoters, asphalt bio-rejuvenators, asphalt bio-extenders, bio-asphalt as well as uses in roofing, soil stabilization, crack and joint sealing and flooring adhesives.
Type:
Application
Filed:
September 20, 2013
Publication date:
March 27, 2014
Applicant:
North Carolina Agricultural and Technical State University
Abstract: Disclosed is a modified asphalt composition including a styrenic block copolymer and a vegetable wax as modifier. With lower viscosity at high temperatures as compared to the asphalt composition modified only with the styrenic block copolymer, it can be manufactured and used at lower temperatures. Also, with higher ductility at low temperatures, it can minimize fatigue crack even in cold weathers.
Type:
Grant
Filed:
December 20, 2011
Date of Patent:
March 25, 2014
Assignee:
Korea Kumho Petrochemical Co., Ltd.
Inventors:
Jae Yun Kim, Min Sung Kwon, Eun Kyung No, Sun Woo Cheen
Abstract: Straight run bitumen is widely used in the production of built-structure waterproofing systems, more particularly waterproofing membranes. In order to be able to obtain supplies of straight run bitumen wherever it is obtainable at favorable prices, it would have to be transported over relatively long distances. Since straight run bitumen is viscid at ambient temperature, it would have to be transported hot, which is not possible with conventional straight run bitumen. According to the invention, the straight run bitumen is admixed with a small proportion of at least one hydrocarbonaceous polymer. This solidifies straight run bitumen at ambient temperatures, making it transportable cold in the solid state.
Abstract: A non-blown roofing grade bitumen composition comprising bitumen feedstock, polyolefin having a molecular weight of from about 800 to about 50,000 g/mol, and optionally one or more additives, wherein the softening point of the composition is above 70° C. as determined according to method ASTM D36 and the penetration of the composition is at least about 12 dmm at 25° C. as determined according to method ASTM D5. A method of making the same.
Type:
Application
Filed:
September 5, 2013
Publication date:
March 13, 2014
Applicant:
Honeywell International Inc.
Inventors:
Steven L. Rotz, Scott Hacker, Yonghong Ruan
Abstract: This invention encompasses rubber modified asphalt cement compositions, as well as systems, apparatuses, methods for preparing, as well as methods for using rubber-modified asphalt cement compositions.
Abstract: A process of preparing a polymer modified asphalt (PMA) comprising mixing a predetermined amount of a polymer-asphalt master batch with a predetermined amount of an asphalt-cross linking agent blend. The polymer-asphalt master batch comprises at least one polymer and a first asphalt. The asphalt-cross linking agent blend comprises a second asphalt and at least one cross linking agent. A predetermined amount of the polymer-asphalt master batch is blended with a predetermined amount of the asphalt-cross linking agent blend to form a PMA blend. Mixing of the PMA blend is performed without substantial delay following blending of the polymer-asphalt master batch with the asphalt-cross linking agent blend.
Abstract: The present invention has for its object a prefabricated sealing membrane formed by a support, coated on at least one surface, and preferably impregnated throughout, with a modified bitumen base composition, characterized in that the thermoplastic bituminous composition for coating and/or impregnation is a bituminous binder modified by a thermoplastic polyurethane having the following weight proportion: 40 to 90% bitumen, 10 to 50% thermoplastic polyurethane, 0 to 10% aromatic oil, 0 to 50% filler, 0 to 0.5% catalyst.
Type:
Grant
Filed:
April 23, 2008
Date of Patent:
February 25, 2014
Assignee:
Soprema
Inventors:
Pierre Etienne Bindschedler, Remi Perrin, Corinne Schall, Arnaud Nouri
Abstract: An asphalt paving material comprises an asphalt binder present in an amount of from about 3 to about 8 weight percent of the asphalt paving material. The asphalt binder comprises base asphalt and oxidized polyolefin that is present in an amount of from about 0.25 to about 10 weight percent of the base asphalt. Aggregate is present in an amount of about 92 to about 97 weight percent of the asphalt paving material. The oxidized polyolefin effectively adheres the asphalt binder to the aggregate so as to resist stripping of the asphalt binder from the aggregate caused by moisture.
Type:
Grant
Filed:
January 13, 2012
Date of Patent:
February 25, 2014
Assignee:
Honeywell International Inc.
Inventors:
Steven Rotz, Scott Hacker, Yonghong Ruan
Abstract: A method of producing treated liquid hydrocarbons. The method begins by pressurizing a latex in a pressure vessel. This is followed by flowing the latex from the pressure vessel into a pipeline containing liquid hydrocarbons to produce treated liquid hydrocarbons. In this embodiment the latex comprises a drag reducing polymer.
Abstract: A viscous composition for making a layer and/or a coating for a road track or a building, and containing a viscous fraction. The viscous fraction mainly contains vegetable pitch, in particular tall oil pitch, and a phenolic modified rosin.
Abstract: A method begins by obtaining a slipstream of a liquid. The slipstream of liquid is then mixed upstream of an injection pump with a latex comprising a drag reducing polymer to produce a drag reducing mixture. The drag reducing mixture is then injected into a liquid hydrocarbon to produce a treated liquid hydrocarbon.
Abstract: Cut back asphalt compositions and product wherein the cutting solvent comprises a tall oil based solvent and optionally other renewable solvents.
Type:
Grant
Filed:
January 8, 2009
Date of Patent:
December 17, 2013
Assignee:
PVS Meridian Chemicals, Inc.
Inventors:
Terry Naidoo, William E. Sonnier, Rick Billings
Abstract: Additives may be used to improve certain physical properties of bitumen. The additives are prepared using a formulation comprising: a first component selected from the group consisting of (alkoxylated)-(di or tri)-alkyl phenol-aldehyde (amine) resins; ?-Olefin-maleic anhydride co-polymers and grafted polymers including half ester/amide and full ester/amide derivatives; and combinations thereof; and a second component which is a synergist and selected from the group consisting of polyamines, amidoamines, imidazolines, and combinations thereof.
Abstract: The invention relates to a method of making a theremorevsible bituminous composition. The method includes transferring an additive to a bitumen to form a mixture, and stirring the mixture until its appearance is homogenous. The additive can be an organogelator with general formula R?—(COOH)z, where R? is a linear or branched, saturated or unsaturated chain having 4 to 68 carbon atoms and z is an integer varying from 2 to 4. The bituminous composition is hard at the temperature of use without increasing its viscosity when hot.
Type:
Application
Filed:
July 19, 2013
Publication date:
November 14, 2013
Inventors:
Laurence Lapalu, Régis Vincent, Laurent Bouteiller, Benjamin Isare
Abstract: A method of forming an asphalt mixture includes mixing a polyol with a bio-source material to form a bio-asphalt. The method can further include mixing the bio-asphalt with a bitumen source different from the bio-asphalt to form an asphalt mixture. The bio-source material can include an oil, such as a vegetable oil, an animal fat, or any combination thereof. The bitumen source can include a petroleum-based asphalt. The method can further include adding a modifier, such as a fatty acid, a polycarboxylic acid, a polyacrylic acid, a polyacrylate comprising a copolymer, or any combination thereof. Moreover, a roofing grade asphalt mixture includes a bio-asphalt. The bio-asphalt includes an alkyd, wherein the alkyd is a reaction product of a polyol and a bio-source material. The roofing grade asphalt mixture further includes a bitumen source material and particles.
Type:
Application
Filed:
March 15, 2013
Publication date:
November 7, 2013
Inventors:
Keith C. Hong, Gregory F. Jacobs, Rajesh Ranjan
Abstract: A sealant composition comprising a binder and a filler material. The binder comprising a residual pitch product and an elastomeric material and, optionally, asphalt, a microcrystalline wax, and/or oil. The filler material is present in an amount of between about 11 vol. % and about 67 vol. % of the sealant composition. In one embodiment, the filler material is present in an amount of between about 25 wt. % and about 70 wt. % of the sealant composition.
Abstract: A phosphorescent asphalt mixture comprising a binder, aggregate and a phosphorescent compound is disclosed. The phosphorescent compound has formula MAl2O4, wherein M is chosen from Sr, Ba and Ca, and wherein the phosphorescent compound has been doped with at least one rare earth element.
Abstract: A bituminous composition comprising a bitumen emulsion in an amount from about 2% to about 10% by total weight of the bituminous composition, and aggregate in an amount from about 90% to about 99% by total weight of the bituminous composition, wherein the bituminous composition is at a temperature range of about 50° C. to about 140° C. The bitumen emulsion comprises hard bitumen in an amount from about 50% to about 75% by total weight of the bitumen emulsion, the hard bitumen being characterized by a penetration number of about 100 dmm or less at 25° C. as determined according to the AASHTO Method T49, and an emulsifier in an amount from about 0.05% to about 2% by total weight of the bitumen emulsion, the emulsifier having a Hildebrand solubility parameter of at least of about 19 (MPa)½. Also disclosed are the methods of producing and using such bituminous compositions.
Type:
Application
Filed:
April 19, 2013
Publication date:
September 5, 2013
Inventors:
Everett CREWS, Iain JACK, Tom GIRARDEAU
Abstract: The present invention provides a polycarbonate resin composition comprising a polycarbonate (A), a styrene copolymer resin (B), carbon nano-tubes (C) and a carbon black (D).
Type:
Grant
Filed:
December 15, 2010
Date of Patent:
August 20, 2013
Assignee:
Cheil Industries Inc.
Inventors:
Young Min Shin, Sang Wan Kim, Young Kyu Chang, Young Sil Lee
Abstract: The disclosure relates to a bituminous composition comprising at least one bitumen and at least one organogelling molecule taken alone or as a mixture, said organogelling molecule being represented by the following general formula (I): where: A represents an acyclic, cyclic or polycyclic, saturated or unsaturated, linear or branched hydrocarbon-based group having 3 to 92 carbon atoms, resulting from the polymerization of the side chains of at least one unsaturated fatty acid, X represents an NH group or an oxygen atom O, R1 represents a group chosen from: a linear or branched hydrocarbon-based group having 2 to 40 carbon atoms, optionally comprising one or more heteroatoms and optionally comprising one or more unsaturations, or a substituted or unsubstituted aromatic group, R2 represents a group chosen from: a hydrogen atom, a linear or branched hydrocarbon-based group having 1 to 40 carbon atoms, comprising one or more heteroatoms and optionally comprising one or more unsaturations, or a substituted or unsub
Type:
Grant
Filed:
November 25, 2008
Date of Patent:
August 13, 2013
Assignees:
Total Raffinage Marketing, Universite Pierre et Marie Curie
Inventors:
Pierre Chaverot, Sylvia Dreessen, Laurent Bouteiller, Emmanuelle Bugnet
Abstract: A black matrix or coating includes carbon black including a first carbon black having an I2 number from 30 mg/g to 200 mg/g and a DBP from 20 cc/100 g to 45 cc/100 g.
Type:
Grant
Filed:
April 23, 2008
Date of Patent:
August 6, 2013
Assignee:
Cabot Corporation
Inventors:
James A. Belmont, Geoffrey D. Moeser, Andriy Korchev, Agathagelos Kyrlidis, Jeremy K. Huffman
Abstract: The present invention relates to bitumen additive mixtures, their use and application for the fabrication of asphalt mixtures used in pavement and waterproofing, and more specifically for construction, repair and maintenance of sidewalks, roads, highways, parking lots or airport runaways and service roads and any other rolling surfaces.
Type:
Grant
Filed:
July 6, 2010
Date of Patent:
July 30, 2013
Assignee:
CECA S.A.
Inventors:
Juan Antonio Gonzalez Leon, Gilles Barreto, Vincent Luca, Eric Jorda
Abstract: Bitumen may be prepared by mixing at least two bitumen feed streams to prepare a bitumen product stream; analyzing the feed streams and the product stream to determine a stability index for each using a Bitumen Asphaltene Stability Index Test; and when the index value for the bitumen product stream is less than about 90% of the weighted average index value for the feed streams, modifying the product stream to achieve a stability index value that is at least 90% of the weighted average index value for the feed streams.
Abstract: A method of producing sulfur modified organosilane compounds that can be used in asphalt binders which method involves: combining together an organosilane or mixtures of organosilanes, a sulfide, a halogen acceptor and solvent to form a reaction mixture; and allowing the organosilane to react with the sulfide in the presence of a halogen acceptor to produce a sulfur modified organosilane compound. The sulfur modified organosilane compound can be introduced into a polymer modified or unmodified asphalt binder in which the sulfur modified organosilane compound reacts with components in the asphalt mixture to form a modified asphalt. The organosilanes used to produce the sulfur modified organosilanes can be from a source of waste products (such as Direct Product Residue) in which case the waste products can be reused in asphalt binders.
Abstract: A method of forming an asphalt mixture can include mixing a bio-asphalt and a bitumen source material different from the bio-asphalt. The bio-asphalt can be formed by mixing a bio-source material with a liquid catalyst. Particles can be added to the asphalt mixture. In an embodiment, the bitumen source material can have a softening point of at least approximately 93° C. and a penetration distance no greater than approximately 25 dmm. In another embodiment, the roofing-grade asphalt mixture can have a softening point of at least approximately 104° C., a penetration distance no greater than approximately 12 dmm, a viscosity of at least approximately 3000 cps at a temperature of 204° C., or any combination thereof. The asphalt mixture can be applied to a base material to form a roofing product. The asphalt mixture can be applied as a pavement product.
Abstract: We disclose a method of making an asphalt composition containing large quantities of ground tire rubber. Over 20% GTR by weight can be used in the asphalt composition without the GTR settling out. The method comprises a series of heating and blending and using a GTR stabilizer.
Abstract: A system for reducing pressure drop associated with the turbulent flow of asphaltenic crude oil through a conduit. The crude oil has a high asphaltene content and/or a low API gravity. Such reduction in pressure drop is achieved by treating the asphaltenic crude oil with a high molecular weight drag reducing polymer that can have a solubility parameter within about 20 percent of the solubility parameter of the heavy crude oil. The drag reducing polymer can also comprise the residues of monomers having at least one heteroatom.
Type:
Grant
Filed:
August 11, 2011
Date of Patent:
May 28, 2013
Assignee:
Phillips 66 Company
Inventors:
Stuart N. Milligan, Ray L. Johnston, Timothy L. Burden, Wayne R. Dreher, Kenneth W. Smith, William F. Harris
Abstract: A method of preparing a drag reducing polymer wherein the drag reducing polymer is able to be injected into a pipeline, such that the friction loss associated with the turbulent flow through the pipeline is reduced by suppressing the growth of turbulent eddies. The drag reducing polymer is injected into a pipeline of liquid hydrocarbon hydrocarbon having an asphaltene content of at least 3 weight percent and an API gravity of less than about 26° to thereby produce a treated liquid hydrocarbon wherein the viscosity of the treated liquid hydrocarbon is not less than the viscosity of the liquid hydrocarbon prior to treatment with the drag reducing polymer. The drag reducing polymer has a solubility parameter within 4 MPa1/2 of the solubility parameter of the liquid hydrocarbon. The drag reducing polymer is also added to the liquid hydrocarbon in the range from about 0.1 to about 500 ppmw.
Type:
Grant
Filed:
August 11, 2011
Date of Patent:
May 28, 2013
Assignee:
Phillips 66 Company
Inventors:
Stuart N. Milligan, Ray L. Johnston, Timothy L. Burden, Wayne R. Dreher, Kenneth W. Smith, William F. Harris