Abstract: Of the many embodiments presented herein, one is a subterranean treatment fluid comprising: an aqueous fluid; and a water-soluble degradable synthetic vinyl polymer having a labile link in its backbone. Also provided in one instance is a water-soluble degradable synthetic vinyl polymer with labile group in its backbone made by a redox polymerization, the redox polymerization reaction comprising these reactants: a macroinitiator that comprises a labile link, an oxidizing metal ion, and a vinyl monomer.

Abstract: Process for producing fiber-reinforced composite materials, by a) molding a textile structure and then spray-applying a binder, or saturating the textile structure with a binder, or b) first spray-applying a binder to a textile structure, or saturating a textile structure with a binder, and then subjecting the material to forming and drying.

Abstract: The precipitation of polymeric kinetic hydrate inhibitors (KHIs) in stored produced water is prevented or inhibited by incorporating a water immiscible solvent therein having a polarity index greater than about 3. The polymeric KHIs whose precipitation is inhibited or prevented include, but are not limited to, hyperbranched molecules, polyvinylcaprolactam, polyvinylpyrrolidone, and the like. Suitable water immiscible solvents include, but are not necessarily limited to, xylene, toluene, kerosene, mineral spirits, trimethylbenzene, cumene, heavy aromatic naphtha, ethylbenzene, polyethylbenzene, naphthalene, and mixtures thereof.

Abstract: The disclosures herein relate to a polymer such as nylon 66, having low yellowness and excellent whiteness retention for applications in melt extrusion and injection molding where an increase in molecular weight is not desirable. The polymer is prepared with a phosphorus compound content, e.g., a sodium hypophosphite (SHP) content, in an amount of 150 to 300 ppm by weight. The presence of an “end cap” additive such as one selected from acetic acid, propionic acid, benzoic acid, or succinic acid, added at the start of polymerization, effectively mitigates undesired molecular weight gain.

Abstract: Disclosed are a novel ionic organic compound and a method for producing the ionic organic compound by a simple process. Also disclosed are a hydrogelling agent composed of an ionic organic compound obtained by the method, an alcohol gelling agent, a gel which uses the gelling agent, while using water or methanol as a medium, and a carbon nanotube dispersant composed of the compound. Specifically disclosed is an ionic organic compound represented by general formula (1). The compound is obtained by a condensation reaction of (A) an aromatic diamide compound or cyclohexane diamide compound having a 4-(chloromethyl)benzamide group at both ends, and (B) a compound selected from N,N,N?,N?-tetramethylalkylenediamines which may have a substituent wherein there are 1-6 carbon atoms between nitrogen atoms. The thus-obtained ionic organic compound serves as a gelling agent which is capable of gelling a neutral aqueous solution or an alcohol.

Abstract: The present invention discloses statistical antibiofouling nonionic-zwitterionic copolymers. The antibiofouling nonionic-zwitterionic copolymers are with the LCST (Lower Critical Solution Temperature) and/or UCST (Upper Critical Solution Temperature), and with increasing content of the nonionic monomers, the LCST and/or UCST of copolymers varies.

Abstract: Disclosed is the use of water-soluble graft copolymers prepared by free-radically initiated graft polymerization of 40 to 90% by weight of component (A), selected from the group consisting of monosaccharides, oligosaccaharides, polysaccharides and derivatives thereof, with 5 to 40% by weight of monomers (B), selected from the group consisting of ethylenically unsaturated C3-C10 monocarboxylic acids or the alkali or ammonium salts thereof, and 10 to 50% by weight of monomers (C), selected from the group consisting of ethylenically unsaturated N-containing monomers and/or ethylenically unsaturated monomers containing sulfo-groups, in cleaning compositions which, as well as the graft polymer, comprise at least one surfactant component, for hydrophilization and/or improvement of shine retention of hard surfaces which have been brought into contact with these cleaning compositions.

Abstract: The invention relates to a fatty acid modified polyesteramide resin obtained from components comprising: i) at least one ?, ?- unsaturated diacid; ii) optionally at least one other diacid and/or anhydride; iii) at least one alkanol-amine; and iv) at least one fatty acid and/or fatty acid derivative; wherein the molar ratio of component iii): [component i)+component ii)] is in the range of from 1.2:1.0 to 3.0:1.0; and wherein component iv) is incorporated in the polyesteramide resin in the range of from 18 to 60 wt % based on the total weight of components i) to iv).

Abstract: The invention relates to a novel process for making compositions comprising a polyamid, water and a salt, having reduced crystallinity, wherein the process comprising the steps of: a. mixing the polyamide, water and a salt b. heating the mixture to a temperature above 100° C. in a range between 120° C. below the Brill temperature and 50° C. above the Brill temperature of the polyamide at a pressure above the vapour pressure of the mixture at said temperature c. optionally cooling down the mixture.

Abstract: The invention provides stain-proofing agents capable of farming coating films excellent in rain streak stain resistance and durability thereof, coating compositions comprising the stain-proofing agents, and articles coated therewith. A stain-proofing agent comprising a polymer which contains at least one repeating unit having at least two hydroxyl groups, wherein the content (by mass) of the repeating unit is more than 10%. A stain-proofing agent comprising a polymer which contains at least two repeating units having hydroxymethyl groups, wherein the content (by mass) of the repeating unit is more than 30%. A coating composition comprising such a stain-proofing agent and a coating resin such as a fluororesin.

Abstract: The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof Formula 1 wherein R is H or C1-30-optionally substituted hydrocarbyl; or R may be R?C?O (an acyl group where R? is hydrogen, alkyl, aryl or an optionally substituted alkyl or aryl); U is oxygen, —NH or —NR??; R?? is a C1-30-optionally substituted hydrocarbyl Y is C2-4-alkyleneoxy; T is the residue of substituted acetic acid or propionic acid; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof, or mixtures thereof; x is from 2 to 90; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group R—U—(Y)x-T-.

Abstract: A process for preparing a curable polyester based emulsion is provided in embodiments, containing one or more unsaturated polyesters and one or more photoinitiators obtained by a phase inversion process, in which the particle size and particle size distribution is controlled by process parameters, such as solvent, solvent ratio, neutralization ratio of the resin and temperature.

Abstract: Engineered crosslinked thermoplastic particles are useful for interlaminar toughening of pre-pregs and composite materials.

Abstract: Disclosed is a coloring composition containing (A) a pigment dispersion composed of a pigment having an average particle diameter of 0.1-0.5 ?m, a polymer dispersant containing a hydrophobic group and an ionic group as indispensable components and an aqueous medium, and (B) a crosslinking agent. The coloring composition is characterized in that a crosslinking reaction is caused between the polymer dispersant and the crosslinking agent at the time of coloring, thereby fixing the pigment onto fibers.

Abstract: The invention relates to an aqueous polymer dispersion which can be obtained from a mixture of monomers comprising, in parts by weight: a) 100 of at least one ethylenically unsaturated monomer not comprising an ionic group, b) 0.5 to 15 of at least one ethylenically unsaturated monomer carrying at least one carboxyl and/or carboxylic anhydride functional group, c) at least one ethylenically unsaturated monomer carrying at least one second functionality selected from: phosphate, phosphonate or phosphinate, in an amount such that the ratio c/(b+c) varies from 0.05 to 0.

Abstract: An aqueous dispersion of polyamide rubber elastic body, which contains an aqueous medium and a polyamide rubber elastic body emulsified and dispersed in the aqueous medium in the presence of a surfactant. The surfactant is used in an amount of 1 to 20 parts by weight based on 100 parts by weight of the polyamide rubber elastic body, and is for example at least one member selected from the group consisting of a polyoxyalkylene alkyl ether sulfate, a dialkyl sulfosuccinate, a fatty acid salt and an ethylene oxide/propylene oxide copolymer. This aqueous dispersion can produce a molded article having the characteristics of the polyamide rubber elastic body, particularly a molded article which hardly suffers from bleeding of the surfactant and is excellent in transparency.

Abstract: A method of making a thickened hardener composition useful in a two part resin system. The thickened hardener composition includes a carrier, a peroxide catalyst, and a thickening and volumetrically increasing agent, wherein the thickening and volumetrically increasing agent is microspheres. A method of making a thermoset resin from a two-part polyester resin system is also provided.

Abstract: The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof; wherein R is C1-50-optionally substituted hydrocarbyl; Y is C2-4-alkyleneoxy; T is C2-4 alkylene; A is the residue of a dibasic acid or anhydride thereof; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof; x is from 2 to 60; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group RO—(Y)x-T-NH-A-. The invention further discloses the composition as a dispersant for an organic media.

Abstract: A sizing agent for fibers is provided, which contains a polyester resin, and is capable of improving the emulsification stability and the sizing property while maintaining adhesive property with a matrix resin. The sizing agent for fibers is an aqueous solution or an aqueous emulsion, which contains a polyester resin (A) that satisfies all the following conditions (i)-(iv) and an aqueous medium: (i) that the polyester resin (A) is made from a dicarboxylic acid or its anhydride (a) and diols (b); (ii) that at least one of the diols (b) is diol (b1) that has an average 4.5-60 contiguous oxyethylene groups; (iii) that the weight percentage of the average 4.5-60 contiguous oxyethylene groups in the polyester resin (A) is 25-50 wt %; and (iv) that a mixture of 10 parts by weight of the polyester resin (A) and 90 parts by weight of water forms an uniform transparent solution or an uniform emulsion at 25° C.

Abstract: The invention relates to a composition containing a particulate solid, an organic or aqueous medium, and a copolymer containing less than 25 mol % of residues of monomers comprising a dicarboxylic acid, or anhydride thereof. The invention further relates to novel copolymers, and the use of the copolymers as a dispersant.

Abstract: A method of stabilizing an aqueous solution of polyaminoamide-epichlorohydrin resin comprising sequentially adding to the solution about 0.1 to about 10 weight percent of one or more strong acids and about 0.1 to about 10 weight percent of one or more weak acids to prepare a stabilized solution having a pH of about 3-4.

Abstract: A binder composition for mineral fiber mats or the like, where the binder composition includes a carboxylated emulsion resin and a polyfunctional aziridine crosslinking agent. The binder composition is formaldehyde free, exhibits good crosslinking density, and enables the economical production of strong, flexible fiberglass mats which may be used as thermal and acoustic insulation.

Abstract: The present invention provides coating compositions that include reactive diluents and have high performance, low VOC levels, and low irritation levels. Certain embodiments of the present invention include water and water-dispersible polymers and other embodiments do not include water.

Abstract: Disclosed is a hollow fiber that includes a hollow positioned at the center of the hollow fiber, macropores positioned at adjacent to the hollow, and mesopores and picopores positioned at adjacent to macropores, and the picopores are three dimensionally connected to each other to form a three dimensional network structure. The hollow fiber includes a polymer derived from polyimide, and the polyimide includes a repeating unit obtained from aromatic diamine including at least one ortho-positioned functional group with respect to an amine group and dianhydride.

Abstract: Disclosed herein are a polyamic acid dope solution composition, a method for preparing a hollow fiber using the composition and a hollow fiber prepared by the method. More specifically, disclosed are a method for preparing a hollow fiber, comprising preparing a polyamic acid dope solution composition comprising polyhydroxyamic acid, polythiolamic acid or polyaminoamic acid, spinning the composition to prepare a hollow fiber, and imidizing and thermally rearranging the hollow fiber, and the hollow fiber prepared by the method. In accordance with the method, a hollow fiber made of a high free volume polymer membrane can be prepared by spinning the dope solution composition to prepare a hollow fiber and thermally rearranging the hollow fiber via thermal treatment. The hollow fiber thus prepared exhibits excellent gas permeability and selectivity, thus being suitable for use as a gas separation membrane.

Abstract: A two-component, water based micro encapsulation composition and method for the cleanup of hydrocarbon spills or contaminates on various surfaces and media. The two-part formulation includes a first solution including water in a predetermined ratio of a water soluble alkaline silicate solution having at least one alkali metal and a predetermined ratio of at least one water soluble surfactant; and a second solution including water, a predetermined ratio of water soluble acid, a predetermined ratio of water dispersible polymer, a predetermined ratio of water soluble hydrotrope, and a predetermined ratio of at least one water soluble flocculating agent. A method of using the two-part formulation includes preparing the two-part formulation, allowing the first solution to contact the hydrocarbon or chemical contaminate; allowing the second solution to contact the first solution and contaminate to form a homogeneous mixture; and removing the homogeneous mixture.

Abstract: A hydrophilic composition is provided the hydrophilic composition containing a hydrophilic polymer (A) containing a crosslinking group; and a W/O/W type emulsion (B).

Abstract: A solution with a salt-sensitive polymer binder for use in fibrous webs, where the binder contains a copolymer comprising repeat units derived from butyl acrylate, methyl methacrylate and amino functionalized alkyl acrylate or methacrylate or amino functionalized alkyl acrylamide or methacrylamide optionally including monomers such as vinyl acetate and/or vinyl acetate/ethylene. The binder solution is prepared by emulsion-polymerizing a copolymer and then neutralizing the copolymer with acid to make it water soluble. The binders are particularly suitable for strengthening nonwoven fibrous webs in disposable articles such as wet-wipes, personal care products, diapers, and the like and retain their salt-sensitivity with or without divalent metal scavengers.

Abstract: The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof. Formula 1 wherein R is H or C1-30-optionally substituted hydrocarbyl; or R may be R?C—O (an acyl group where R? is hydrogen, alkyl, aryl or an optionally substituted alkyl or aryl); U is oxygen, —NH or —NR??; R?? is a C1-30-optionally substituted hydrocarbyl Y is C2-4-alkyleneoxy; T is the residue of substituted acetic acid or propionic acid; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof, or mixtures thereof; x is from 2 to 90; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group R—U—(Y)x-T-.

Abstract: It is the purpose of the present invention to provide a carbodiimide compound exhibiting superior water resistance and having good storage stability when it is applied to a waterborne coating composition, and a waterborne curable resin composition comprising thereof, and the carbodiimide compound of the present invention is represented by the following general formula (1): wherein X represents a bifunctional organic group containing at least one carbodiimide group, Y represents a structure in which a hydroxyl group is eliminated from a polyalkylene glycol monoalkyl ether, R0 represents hydrogen or an alkyl group having 2 or less carbon atoms, R1 represents an alkylene group having 4 or less carbon atoms, n represents 0 or 1 and m represents an integer of 11 or more, and wherein the repeating number of oxyalkylene group in the polyalkylene glycol monoalkyl ether is 6 to 40.

Abstract: A fluoropolymer composition comprising monomers copolymerized in the following percentages by weight: (a) from about 20% to about 95% of a fluoroalkyl monomer, or mixture of monomers, of formula (I) Rf1-L-X—C(O)—C(R)?CH2 ??(I) wherein Rf1 is a monovalent, partially or fully fluorinated, linear or branched, alkyl radical having from about 2 to about 100 carbon atoms; optionally interrupted by 1 to about 50 oxygen atoms; wherein the ratio of carbon atoms to oxygen atoms is at least about 2:1 and no oxygen atoms are bonded to each other; L is a linear or branched divalent linking group having 1 to about 20 carbon atoms; optionally interrupted by 1 to about 4 hetero-radicals selected from the group consisting or —O—, —NR1—, —S—, —SO—, —SO2—, —N(R1)C(O)—; wherein R1 is H or C1 to C6 alkyl; X is —O—, —NR1—, or —S—; R is hydrogen, Cl, F or CH3; (b) from about 5% to about 80% of at least one of: (i) an alkyl(meth)acrylate monomer having a linear, branched or cyclic alkyl group of from about 6 to about 1

Abstract: Hydroxypolyamides, hydroxypolyamide products, and post-hydroxypolyamides are disclosed as gel forming agents. Hydroxypolyamides and post-hydroxypolyamides are prepared from known methods. Hydroxypolyamide products are produced from a modified polymerization procedure which utilizes strong base for deprotonation of ammonium salts from the esterification of stoichiometrically equivalent polyacid:polyamine salts. The hydroxypolyamide products are capable of gel formation at lower concentrations than hydroxypolyamides and post-hydroxypolyamides from the known methods of preparation, and are therefore superior gel forming agents.

Abstract: The invention relates to supramolecular ionomers. i.e. polymers having quadruple hydrogen bonding units (4H-units) and ionic groups or ionogenic groups within their structure. The supramolecular ionomers can be dispersed or solubilized in water at high solids contents while maintaining low viscosities, facilitating easy use and processing of the resulting aqueous formulations. The aqueous supramolecular ionomer compositions have excellent film-forming properties. Moreover, the polymer materials have good mechanical properties after drying, as they are not tacky, show high elasticity and low or no creep.

Abstract: A method of forming dispersed water-soluble quantum dots and tuning water-soluble quantum dot aggregate size by providing a plurality of water-soluble quantum dots in a dispersion, the plurality of water-soluble quantum dots are modified with an amphiphilic polymer, and by adding an amount of the amphiphilic polymer to the dispersion such that the ratio of the amphiphilic polymer units to quantum dots is maintained higher to obtain dispersions of smaller quantum dot aggregates and kept lower to obtain dispersions of larger quantum dot aggregates.

Abstract: An aqueous dispersion of hybrid particles consisting of inorganic or organic pigment particles and organic nano-particles attached to the surface of the pigment particles, the nano-particles having a particle size between 2 and 200 nanometers. Preferably the nano-particles have a glass transition temperature of at least 120° C. and comprise co-polymers of vinyl monomers and a mixture comprising maleic anhydride and derivates of maleic anhydride. In a process for preparing such an aqueous dispersion a copolymer of vinyl monomers and maleic anhydride is treated in water with a compound having the general formula R—NH2 of which R is H, alkyl with 1 to 18 C-atoms or aryl, and in the presence of one or more inorganic pigment particles, at least 35% of the maleic anhydride groups being transformed in imides groups.

Abstract: An improved process for the hydrolysis of nylon polymer is herein disclosed using ionic liquids and optionally one equivalent of sulfuric acid per amide residue of the polymer. The process provides for a simplified means for separation of the hydrolyzed polyamide constituent monomers.

Abstract: The present invention is directed to novel organometallic complexes as catalysts for the reaction of compounds with isocyanate and hydroxyl functional groups to form urethane and/or polyurethane and the process employing such catalysts. More particularly, the present invention is directed to novel complexes of zinc(II) with substituted amidines. These novel catalysts are useful for the production of urethanes and polyurethanes which are important in many industrial applications.

Abstract: This aqueous composition for coating supports to provide same with anti-blocking properties, comprises: 50 to 99 parts of a binding polymer; 1 to 50 parts of expansible microspheres, The binding polymer is a copolymer having at least one crosslinkable function.

Abstract: The present invention is directed to a process for the preparation of an aqueous dispersion of coacervates having a core-shell structure, the core (a) being an inorganic particle being anionic or cationic and the shell (b) being a copolymer wherein said copolymer comprises at least two parts, A and B, part A being cationic if particle (a) is anionic, and anionic if particle (a) is cationic, and part B being neutral in pH conditions of said dispersion. More particularly, the invention is directed to treating compositions comprising that aqueous dispersion of coacervates delivering antifouling, water sheeting, antisoiling, anti-adhesion, adhesion, anti-deposition, and/or anti-UV properties onto all kinds of surfaces.

Abstract: A water based inkjet ink set with excellent image stability, durability and quality, comprising at least one cyan ink, at least one magenta ink, at least one yellow ink, at least one black ink, and at least one colorless protective ink, wherein: (a) the cyan, magenta, yellow, and black inks each comprise a pigment colorant; (b) the cyan, magenta, yellow, black, and colorless protective inks each comprise a polymeric binder additive; and (c) the surface tensions of the inks have the following relationships: (i) the dynamic surface tension at 10 milliseconds surface age for all inks of the ink set is greater than or equal to 35 mN/m, (ii) the static surface tensions of the yellow ink and of the colorless protective ink are at least 2.0 mN/m lower than the static surface tensions of the cyan, magenta and black inks of the ink set and (iii) the static surface tension of the colorless protective ink is at least 1.0 mN/m lower than the static surface tension of the yellow ink.

Abstract: The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof: Formula (1) wherein R and R? are independently H or Cl-30-optionally substituted hydrocarbyl; or R is H or Cl-30-optionally substituted hydrocarbyl and R? is R? C=O (an acyl group where R? is hydrogen, alkyl or an optionally substituted alkyl or aryl or an optionally substituted aryl); Y is C2-4-alkyleneoxy; T is C2-4 alkylene; A is the residue of a dibasic acid or anhydride thereof; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof, or mixtures thereof; x is from 2 to 90; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group RR?N-T-O-(Y)X-T-NH-A-.

Abstract: An ink composition comprising (a) water, (b) pigment particles dispersed with a dispersant or self dispersing without the need for a dispersant, (c) at least one humectant, and (d) at least one polyurethane additive which is distinct from the dispersant, having an average molecular weight of at least about 10,000 and a sufficient number of acid groups to provide an acid number greater than about 60, the polyurethane being present at a level of at least 10 percent by weight relative to the pigment particles and comprising a polyether segment having a molecular weight greater than 250 and less than 2900, wherein the acid groups on the polyurethane are at least partially neutralized only with a monovalent inorganic base.

Abstract: A polymer composite composed of a polymerized mixture of functionalized carbon nanotubes and monomer which chemically reacts with the functionalized nanotubes. The carbon nanotubes are functionalized by reacting with oxidizing or other chemical media through chemical reactions or physical adsorption. The reacted surface carbons of the nanotubes are further functionalized with chemical moieties that react with the surface carbons and selected monomers. The functionalized nanotubes are first dispersed in an appropriate medium such as water, alcohol or a liquefied monomer and then the mixture is polymerized. The polymerization results in polymer chains of increasing weight bound to the surface carbons of the nanotubes. The composite may consists of some polymer chains imbedded in the composite without attachment to the nanotubes.

Abstract: The invention is directed to aqueous compositions of sagging control agents comprising at least one urea groups containing sagging control agent and water, wherein the sagging control agents are obtained by reacting in an aqueous phase A) at least one hydrophilic polyisocyanate with B) at least one amino-functional compound selected from a group consisting of an amine with at least one primary amino group and at least one hydroxyl group, having the at least one primary amino group on a primary carbon atom, an amino ether with at least one primary amino group, having the at least one primary amino group on a primary carbon atom and mixtures thereof. The invention is also directed to coating compositions containing the aqueous compositions of sagging control agents.

Abstract: The invention is directed to hydrophilic sagging control agents comprising at least one urea group and to aqueous coating compositions containing those hydrophilic sagging control agents. The sagging control agents are obtained by reacting A) at least one hydrophilic polyisocyanate with B) at least one amino-functional compound selected from a group consisting of an amine with at least one primary amino group and at least one hydroxyl group, having the at least one primary amino group on a primary carbon atom, an amino ether with at least one primary amino group, having the at least one primary amino group on a primary carbon atom and mixtures thereof.

Abstract: The present invention provides a composition containing a particulate solid, an organic medium and/or water and a compound of Formula (1) and salts thereof; wherein R is C1-50-optionally substituted hydrocarbyl; Y is C2-4-alkyleneoxy; T is C2-4alkylene; A is the residue of a dibasic acid or anhydride thereof; Z is the residue of a polyamine and/or polyimine; W is the residue of an oxide, urea or dibasic acid or anhydride thereof; x is from 2 to 60; and v represents the maximum available number of amino and/or imino groups in Z which does not carry the group RO—(Y)x-T-NH-A-. The invention further discloses the composition as a dispersant for an organic media.

Abstract: A method of stabilizing an aqueous solution of polyaminoamide-epichlorohydrin resin comprising adjusting the pH of the solution to less than about 3 with strong acid and then adding to the solution a weak acid in a mole ratio of total protons available from the weak acid to total protons available from the strong acid of about 0.05 to about 2.

Abstract: A process for treating a composition containing a polyamine-epihalohydrin resin that has a low level of CPD-producing species and good gelation stability is disclosed. A polyamine-epihalohydrin resin is prepared with a ratio of epihalohydrin:amine of less than about 1.1:1.0; The resin is then subjected to a base treatment followed by an acid treatment resulting in a resin that has good gelation storage stability and produces low levels of CPD.

Abstract: The present invention is directed to a curable, water-based coating composition utilized in waterborne coating systems such as a waterborne primer system. The coating composition is the reaction product of a water-dispersible cross-linking agent and a water-based copolymer prepared by free-radical polymerization. The copolymer is the reaction product of a first block and a second block. The first block is the reaction product of a plurality of ethylenically unsaturated monomers. One of the ethylenically unsaturated monomers includes a functional group suitable for reaction with the cross-linking agent. The functional group in the first block is preferably a carbonate, carbamate, or hydroxyl functional group. Other monomers in the plurality include acrylic acid and methyl methacrylate. The first block is also the reaction product of a vinylaromatic hydrocarbon monomer such as diphenylethylene. The second block is the reaction product of a non-functional, ethylenically unsaturated monomer.

Abstract: The present invention contemplates a process for forming polyaminoamide polymers formed by the reaction of a dibasic acid/ester with excess amounts of an amine; the intermediate polymer resulting therefrom; a process for synthesizing effective, high solids resins resulting from the reaction of intermediate polymers with an epihalohydrin; and the resultant high, solids resin. These resins may be used as wet strength resins in the papermaking industry.