Two Or More Solid Polymers, Or Graft Or Graft-type, Or Block Or Block-type Solid Copolymer Patents (Class 524/68)
  • Publication number: 20120059094
    Abstract: The disclosure relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The disclosure also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The disclosure further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.
    Type: Application
    Filed: November 15, 2011
    Publication date: March 8, 2012
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS), TOTAL RAFFINAGE MARKETING
    Inventors: Pierre Chaverot, Charlotte Godivier, Ludwik Leibler, Ilias Iliopoulos, Amanda Kathryn Leach
  • Patent number: 8124677
    Abstract: A modified asphalt binder composition prepared by combining asphalt binder, phosphorus pentasulfide, and less than 2.5 parts by weight unsaturated polymer, per 100 parts by weight asphalt binder, to thereby produce a modified asphalt binder composition characterized by an elongation recovery at 25° C., as determined according to AASHTO T301, of greater than 75%, where the phosphorus pentasulfide includes a blend of P4S10 and P4S9.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: February 28, 2012
    Assignees: Firestone Polymers, LLC, Heritage Research Group
    Inventors: William L. Hergenrother, Peter W. Boerner, Daniel F. Graves, Christine Rademacher, Timothy P. Reece, Herbert L. Wissel
  • Patent number: 8114926
    Abstract: The invention relates to a method for the production of a bituminous binder and a bituminous binder which can be obtained according to said method. The method for the preparation of the bituminous binder comprises a mixing stage of 0.05 5 wt. % acid, 0.5 25 wt. % rubber crumbs and 70 99.5 wt. % bitumen. The invention also relates to bituminous concretes comprising said binder and a method for the production and use thereof.
    Type: Grant
    Filed: March 8, 2004
    Date of Patent: February 14, 2012
    Assignees: Eurovia, Innophos, Inc.
    Inventors: Dominique Dupuis, Didier Lesueur, Juan José Potti, Gilles Orange, John Godber
  • Patent number: 8099218
    Abstract: A method of operating a paving system includes establishing a plan for paving a work area which is based on a positional temperature model. The method further includes receiving temperature data for paving material and comparing the temperature data with data predicted by the positional temperature model. Operation of the paving system is adjusted where actual data differs from model predicted data. A paving system and control system are provided having an electronic control unit configured to compare electronic temperature data with a positional temperature model for paving material. The electronic control unit can control machines of the paving system based on comparing actual data with model predicted data, and can further update either or both of a plan for paving a work area and the positional temperature model itself based on differences between actual data and model predicted data.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: January 17, 2012
    Assignee: Caterpillar Inc.
    Inventors: Katherine C. Glee, Dean R. Potts, Paul T. Corcoran, Terry L. Rasmussen
  • Patent number: 8088845
    Abstract: The invention is directed to a paraffin wax contained in a thermoplastic polymer packaging material which is meltable along with the paraffin wax.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: January 3, 2012
    Assignee: Shell Oil Company
    Inventors: Stephane Le Clerc, Mohd Yazid Bin Jaafar, Antonius Adrianus Maria Roovers, Jason Boon Eong Teh
  • Patent number: 8076398
    Abstract: The present invention relates to a bituminous composition comprising at least one bitumen and at least one polycondensate capable of forming a supramolecular assembly comprising one or more associative group(s). The present invention also relates to the use of such bituminous composition for the preparation of asphalt mixtures useful for the coating of rolling surfaces, for the preparation of water-proofing coatings, and the for the preparation of adhesive formulations.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: December 13, 2011
    Assignee: Ceca S.A.
    Inventors: Juan Antonio Gonzalez Leon, Jean-Philippe Gillet, Gilles Barreto, Manuel Hidalgo, Vincent Luca
  • Publication number: 20110269877
    Abstract: Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications.
    Type: Application
    Filed: July 12, 2011
    Publication date: November 3, 2011
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Paul J. Buras, William D. Lee, James R. Butler
  • Publication number: 20110257308
    Abstract: The invention relates to a process for the preparation of mixtures containing bitumen and thermoplastic polymer at a high concentration, stable during storage, with particular characteristics of easy processability and movability which, once diluted, allow modified bitumens to be obtained with high performance characteristics. In particular, the process allows mixtures containing bitumen, thermoplastic polymer and wax, to be prepared, wherein the polymer is in a quantity varying from 5 to 30% by weight with respect to the weight of the mixture consisting of bitumen and polymer, and the wax is in a quantity varying from 4.7 to 16.
    Type: Application
    Filed: November 5, 2009
    Publication date: October 20, 2011
    Inventors: Paolo Italia, Luigi D'Elia
  • Publication number: 20110251308
    Abstract: Functionalized multi-arm polymers which comprise the reaction product of a coupling agent and a polymer synthesized by anionic polymerization. Furthermore, the invention relates to their preparation method and their different uses, especially as hot-melt adhesives.
    Type: Application
    Filed: December 10, 2009
    Publication date: October 13, 2011
    Applicant: DYNASOL ELASTOMEROS, S.A.
    Inventors: Sergio Corona Galvan, Rafael Polo Abad, Ma Dolores parellada Ferrer, Alejandro Claudio Esquivel de al Garza
  • Patent number: 8008377
    Abstract: A process for preparing a modified asphalt binder composition, the process comprising mixing asphalt, an unsaturated polymer, and an organothionating agent to form a modified asphalt composition.
    Type: Grant
    Filed: June 19, 2008
    Date of Patent: August 30, 2011
    Assignees: Firestone Polymers, LLC, Heritage Research Group
    Inventors: Christine Rademacher, Daniel Graves, Herb Wissel, Timothy Reece
  • Publication number: 20110196073
    Abstract: Methods of preparing a cross-linked, polymer-modified asphalt is provided. The method involves adding a crosslinking agent to asphalt prior to the addition of a crosslinkable polymer and an acid. Asphalt prepared by the disclosed methods exhibit improved properties such as properties measured by the Multiple Stress Creep Recovery (MSCR) test.
    Type: Application
    Filed: February 11, 2010
    Publication date: August 11, 2011
    Applicant: ICL Performance Products LP
    Inventors: Darrell C. Fee, René Maldonado, Enrique E. Romagosa
  • Publication number: 20110184090
    Abstract: A bitumen composition comprising crumb rubber, a polymer comprising glycidyl functional groups and wax is disclosed. The bitumen composition can be used to prepare asphalt mixtures.
    Type: Application
    Filed: August 24, 2009
    Publication date: July 28, 2011
    Inventors: Frits De Jonge, Sean Lok Ng, Sophie Nigen-Chaidron
  • Patent number: 7981517
    Abstract: This invention relates to bituminous compositions comprising an interpolymer and a bituminous material and methods of making and using same. The interpolymer may comprise ethylene, at least one alpha-olefin, and, optionally, at least one diene and the interpolymer is derived from polymer particles having a surface coating comprising a partitioning agent. Methods of making and using the bituminous compositions are also described.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: July 19, 2011
    Assignee: Dow Global Technologies Inc.
    Inventors: Brian W. Walther, Arnis U. Paeglis, Morgan M. Hughes, Carl F. Baker
  • Publication number: 20110160355
    Abstract: The present invention relates to a modified asphalt binder composition comprising: a. 70-85% by weight asphalt binder b. 0.1-5% by weight PPA c. 0.5-30% by weight supramolecular rubber.
    Type: Application
    Filed: November 5, 2010
    Publication date: June 30, 2011
    Inventor: Jean-Valery Martin
  • Patent number: 7968628
    Abstract: Bituminous asphalt binder materials which are modified by the addition of crumb rubber or ground tire rubber and a cross-linking agent are described. In addition, methods are provided for producing a modified asphalt binder containing crumb rubber or ground tire rubber and a cross-linking agent. The modified asphalt binders comprise neat asphalt, crumb rubber, one or more acids and a cross-linking agent. Optionally, the modified asphalt binder may include one or more polymer additives. The crumb rubber may be obtained from recycled truck and/or automobile tires. The addition of crumb rubber in asphalt binders can improve the consistency and properties of the asphalt binders at high and low temperatures. In particular, the modified asphalt binders of the present invention exhibit improved elastic behavior, resulting in improved performance of roads or other surfaces paved using the modified asphalt binder.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: June 28, 2011
    Assignee: Innophos, Inc.
    Inventor: Jean-Valery Martin
  • Publication number: 20110143066
    Abstract: A gas barrier layer constituted from a material based upon a rubber composition and a rubber article with a gas barrier layer constituted from a material based upon a rubber composition. The composition comprising, per 100 parts by weight of elastomer, a highly unsaturated diene elastomer, a butyl rubber, an aromatic hydrocarbon resin having a softening point of between 75° C. and 120° C. and an aliphatic hydrocarbon resin having a glass transition temperature greater than about 40° C. and a softening point of less than about 140° C.
    Type: Application
    Filed: May 14, 2009
    Publication date: June 16, 2011
    Inventor: Linda M. Roddy
  • Patent number: 7960454
    Abstract: The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one anhydride group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.
    Type: Grant
    Filed: December 16, 2005
    Date of Patent: June 14, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Walter Harvey Waddell, David Yen-Lung Chung, Robert Christopher Napier, Donald Sheley Tracey, Dirk Frans Rouckhout
  • Publication number: 20110136944
    Abstract: The invention relates to copolymers based on unsaturated mono or dicarboxylic acid derivatives, oxyalkyleneglycol-alkenyl ethers, vinyl polyalkyleneglycol or ester compounds, in addition to the use thereof as additives for aqueous suspensions based on mineral or bituminous binding agents. Said invention is characterized in that the inventive copolymers, having a long lateral chain, impart small amounts of excellent processing properties to aqueous binding suspension, and simultaneously cause the water content in the concrete to be greatly reduced.
    Type: Application
    Filed: February 11, 2011
    Publication date: June 9, 2011
    Inventors: Moraru BOGDAN, Hübsch Christian, Albrecht Gerhard, Scheul Stefanie, Jetzlsperger Eva
  • Patent number: 7951858
    Abstract: The invention concerns novel bituminous products, as well as novel aqueous emulsions of bituminous products, mixtures thereof with coated granules, useful for sealing application, building and maintaining road surfaces, sidewalks and runways, road surfaces, sidewalks, bicycle paths, parking lots and runways.
    Type: Grant
    Filed: June 6, 2007
    Date of Patent: May 31, 2011
    Assignee: CECA S,A,
    Inventors: Gilles Barreto, Lionel Grampre
  • Publication number: 20110105651
    Abstract: A modified asphalt binder composition prepared by combining asphalt binder, phosphorus pentasulfide, and less than 2.5 parts by weight unsaturated polymer, per 100 parts by weight asphalt binder, to thereby produce a modified asphalt binder composition characterized by an elongation recovery at 25° C., as determined according to AASHTO T301, of greater than 75%, where the phosphorus pentasulfide includes a blend of P4S10 and P4S9.
    Type: Application
    Filed: September 14, 2010
    Publication date: May 5, 2011
    Inventors: William L. Hergenrother, Peter W. Boerner, Daniel F. Graves, Christine Rademacher, Timothy P. Reece, Herbert L. Wissel
  • Publication number: 20110105652
    Abstract: A modified asphalt binder composition prepared by combining asphalt binder, phosphorus pentasulfide, and less than 2.5 parts by weight unsaturated polymer, per 100 parts by weight asphalt binder, to thereby produce a modified asphalt binder composition characterized by an elongation recovery at 25° C., as determined according to AASHTO T301, of greater than 75%.
    Type: Application
    Filed: September 14, 2010
    Publication date: May 5, 2011
    Inventors: William L. Hergenrother, Peter W. Boerner, Christine Rademacher, Daniel F. Graves, Timothy P. Reece, Herbert L. Wissel
  • Patent number: 7935749
    Abstract: Rubber particles in a water and polyhydric alcohol solution are added to an asphalt whereby the polyhydric alcohol substantially coats the rubber particles resulting in an easily mixed composition with the mixing temperature being reduced to a range of from about 250° F. to about 310° F. resulting in considerable energy savings. In a similar manner, a filler can be substantially coated by polyvinyl alcohol-water solution and the same blended with an asphalt and mixed at reduced temperatures. Another embodiment relates to the utilization of a polyhydric alcohol that is added to an asphalt and mixed therewith at reduced temperatures.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: May 3, 2011
    Inventor: David A. Carlson
  • Patent number: 7923487
    Abstract: A lightweight finish composition, method of production and a method of application are provided. The lightweight finish composition comprises a resin dispersion, alkali metal phosphate, alkylolammonium salt of a polyfunctional polymer, and lightweight aggregate such as silica spheres. The lightweight aggregate has a density and weight that is less than those of sand. The combination of alkali metal phosphate and alkylolammonium salt of a polyfunctional polymer stabilizes the lightweight finish composition by preventing the lightweight aggregate from absorbing water, after production of the lightweight finish composition.
    Type: Grant
    Filed: April 13, 2009
    Date of Patent: April 12, 2011
    Assignee: Construction Research & Technology GmbH
    Inventors: Markus Bohler, Michael Flynn
  • Publication number: 20110060078
    Abstract: The present invention relates to modified polyolefins having a propylene content of at least 50 ma-% and a maximum of 75 ma-%, being determined by means of 13C-NMR spectroscopy, and having a poly(ethylene) triad content of a maximum of 2.5 ma-%, being determined by means of 13C-NMR spectroscopy, relative to the total detected ethylene content, a melting heat of at least 9 and a maximum of 20 J/g, determined by means of differential calorimetry, and a solubility in xylol at ambient temperature of at least 96 ma-%, and a solubility in THF at ambient temperature of at least 67 ma-%, wherein one or multiple silanes are grafted onto the polymer. The invention further relates to a method for the production of the polyolefins, and to the use thereof, particularly in or as an adhesive.
    Type: Application
    Filed: July 2, 2009
    Publication date: March 10, 2011
    Applicant: Evonik Degussa GmbH
    Inventors: Hinnerk Gordon Becker, Hans Guenther Wey
  • Publication number: 20110034593
    Abstract: The present invention relates to a bituminous composition comprising at least one bitumen and at least one polycondensate capable of forming a supramolecular assembly comprising one or more associative group(s). The present invention also relates to the use of such bituminous composition for the preparation of asphalt mixtures useful for the coating of rolling surfaces, for the preparation of water-proofing coatings, and the for the preparation of adhesive formulations.
    Type: Application
    Filed: August 3, 2010
    Publication date: February 10, 2011
    Applicant: CECA S.A.
    Inventors: Juan Antonio Gonzalez Leon, Jean-Philippe Gillet, Gilles Barreto, Manuel Hidalgo, Vincent Luca
  • Publication number: 20110034594
    Abstract: The present invention provides a polymeric composition that includes a coupled block copolymer having a plurality of arms comprising at least two blocks of a monovinylaromatic hydrocarbon that are located on at least two of the plurality of arms, and at least one block of a conjugated diene located on at least one of the plurality of arms, and optionally one or more block copolymers comprising at least one block of monovinylaromatic hydrocarbon and at least one block of a conjugated diene, the block copolymer may be selected from linear copolymers, linear triblock copolymers, multiarm coupled block copolymers, and mixtures thereof. The molecular weight of the polymeric composition is in the range from about 100 kg/mol to about 400 kg/mol.
    Type: Application
    Filed: April 17, 2008
    Publication date: February 10, 2011
    Inventors: Erik Jan Scholten, Willem C. Vonk
  • Publication number: 20110009533
    Abstract: This invention relates to the modification of bitumen by polymeric materials used particularly for the preparation of asphalt mixtures with enhanced mechanical properties, wherein the polymeric materials are selected from additives capable of forming a supramolecular assembly. The modified bitumen may be used for the fabrication of asphalts mixtures with mineral aggregates used in construction or maintenance of sidewalks, roads, highways, parking lots or airport runaways and service roads and any other rolling surfaces.
    Type: Application
    Filed: February 20, 2009
    Publication date: January 13, 2011
    Inventors: Juan Antonio Gonzalez Leon, Gilles Barreto, Lionel Grampre
  • Publication number: 20110003916
    Abstract: The present invention relates to modified polyolefins with atactic structural elements, to processes for preparation thereof and to the use thereof, especially as an adhesive or as a constituent of adhesives.
    Type: Application
    Filed: July 6, 2010
    Publication date: January 6, 2011
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Hinnerk Gordon BECKER, Lutz Mindach, Holger Kautz, Miriam Ammer
  • Patent number: 7855250
    Abstract: A filling foam composition contains a polymer, 4,4?-oxybis(benzenesulfonylhydrazide), an amine compound (except urea compound) having a melting point of 40° C. or more, and an organic peroxide, and the amine compound is mixed in an amount of 5 parts by weight or more per 100 parts by weight of the 4,4?-oxybis(benzenesulfonylhydrazide).
    Type: Grant
    Filed: April 21, 2008
    Date of Patent: December 21, 2010
    Assignee: Nitto Denko Corporation
    Inventors: Takehiro Ui, Takashi Koizumi
  • Patent number: 7851523
    Abstract: An asphalt waterproof composition containing waste tire chips and bentonite which includes about 10-15 of asphalt, about 20-50 of oil, about 8-12 of filler, about 1-3.5 of elasticity increasing agent, about 25-40 of waste tire chips melting solution, about 0.5-1 of sulfur, about 0.05-1 of sulfur vulcanizing agent, about 0.1-0.4 of antiaging agent, about 10-20 of bentonite, about 1-5 of water soluble high polymer resin by weight, respectively, and the process for the preparation of its manufacture.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: December 14, 2010
    Assignee: Re-New System Co., Ltd.
    Inventors: Sang-Keun Lee, Jong-Yong Lee
  • Publication number: 20100297902
    Abstract: A roofing membrane that includes a blend of thermoplastic polyurethane and petroleum liquid so as to improve the UV stability of the blend without adversely affecting the flexibility of the dried and/or cured blend.
    Type: Application
    Filed: September 28, 2009
    Publication date: November 25, 2010
    Inventor: Jason Smith
  • Patent number: 7838575
    Abstract: High performance bituminous mixtures that are useful for the road paving and roofing industries comprise mineral aggregates coated with a thermoplastic polymer composition. Because of their high performance properties, the absence of any aggressive and toxic adhesion promoters and the possibility of using recovered or recycled thermoplastic polymers to form the coating or “membrane,” the bituminous mixtures described herein provide an excellent environmentally friendly solution for pavement construction and roofing industries.
    Type: Grant
    Filed: December 19, 2008
    Date of Patent: November 23, 2010
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Jiri Lang, Stephen L. Cluff
  • Patent number: 7834074
    Abstract: Plasticizing system usable for the plasticizing of a diene rubber composition. The plasticizing system is based on an MES or TDAE oil and a polylimonene resin. The rubber composition has an improved resistance to abrasion and to cuts, said composition being based on at least a diene elastomer, a reinforcing filler, a cross-linking system and a plasticizing system comprising between 5 and 35 phr of an MES or TDAE oil, and between 5 and 35 phr of a polylimonene resin (phr=parts by weight per hundred of elastomer). Advantageously, this plasticizing system furthermore comprises an unsaturated (C12-C22) fatty acid triester of glycerol, preferably a glycerol trioleate. A process is disclosed for preparing such a composition. The composition can be used for the manufacture of a finished article or a semi-finished product intended for a suspension system of a motor vehicle, in particular a tire or a tread of such a tire.
    Type: Grant
    Filed: February 10, 2005
    Date of Patent: November 16, 2010
    Assignee: Michelin Recherche et Technique S.A.
    Inventors: Thierry Brunelet, Martine Dinh, Jean-Michel Favrot, Philippe Labrunie, Garance Lopitaux, Jean-Gabriel Royet
  • Patent number: 7824485
    Abstract: Asphalt compositions and methods of forming such are described herein. The asphalt compositions and methods of forming such are generally adapted to enable open air processing while producing asphalt compositions that exhibit properties capable of meeting SUPERPAVE™ specifications.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: November 2, 2010
    Assignee: Fina Technology, Inc.
    Inventors: Paul J. Buras, William Lee, James R. Butler
  • Publication number: 20100273918
    Abstract: A mixture comprising a bitumen (A), and a polymer composition (B) comprising the following components, all percent amounts being by weight: I) from 1 to 30% of a butene-1 polymer having a Melt Flow Rate (MFR), measured according to ASTM D 1238, at 190° C./2.16 kg, from 0.1 to 1000 g/10 min.; and II) from 70 to 99% of a heterophasic polyolefm composition comprising the following polymer fractions: a) 4-45% of a propylene homopolymer or copolymer; b) 0-20% of a of a copolymer fraction containing ethylene, insoluble in xylene at room temperature; c) 40-95% of a copolymer of ethylene with propylene and/or a CH2?CHR ?-olefin, where R is a C2-C8 alkyl radical, containing ethylene in a quantity lower than 40% and being soluble in xylene at room temperature.
    Type: Application
    Filed: October 22, 2008
    Publication date: October 28, 2010
    Applicant: Basell Poliolefine Italia s.r.l.
    Inventor: Gian Luigi Rigosi
  • Patent number: 7820739
    Abstract: A method for forming a modified asphalt binder composition, the method comprising preparing a phosphorus pentasulfide-binder concentrate by introducing and mixing phosphorus pentasulfide and asphalt binder, where the phosphorus pentasulfide-binder concentrate includes greater than 0.5 parts by weight phosphorus pentasulfide per 100 parts by weight asphalt, preparing a polymer-binder concentrate by introducing and mixing polymer and asphalt binder, where the polymer-binder concentrate includes greater than 5 parts by weight polymer per 100 parts by weight asphalt, and introducing and mixing the phosphorus pentasulfide-binder concentrate with the polymer-binder concentrate to form a modified asphalt binder composition, where the phosphorus pentasulfide includes a blend of P4S10 and P4S9.
    Type: Grant
    Filed: November 30, 2009
    Date of Patent: October 26, 2010
    Inventors: William L. Hergenrother, Peter W. Boerner, Daniel F. Graves, Christine Rademacher, Timothy P. Reece, Herbert L. Wissel
  • Patent number: 7816429
    Abstract: A method for forming a modified asphalt binder composition, the method comprising preparing a phosphorus pentasulfide-binder concentrate by introducing and mixing phosphorus pentasulfide and asphalt binder, where the phosphorus pentasulfide-binder concentrate includes greater than 0.5 parts by weight phosphorus pentasulfide per 100 parts by weight asphalt, preparing a polymer-binder concentrate by introducing and mixing polymer and asphalt binder, where the polymer-binder concentrate includes greater than 5 parts by weight polymer per 100 parts by weight asphalt, and introducing and mixing the phosphorus pentasulfide-binder concentrate with the polymer-binder concentrate to form a modified asphalt binder composition.
    Type: Grant
    Filed: December 1, 2009
    Date of Patent: October 19, 2010
    Inventors: William L. Hergenrother, Peter W. Boerner, Christine Rademacher, Daniel F. Graves, Timothy P. Reece, Herbert L. Wissel
  • Patent number: 7811372
    Abstract: A rejuvenating agent having a viscosity of from 200 to 60000 cSt at 60° C. and comprising 10-90 weight % palm oil and 90-10 weight % bitumen, where the percentages are based upon the total weight of the composition, is disclosed. The rejuvenating agent is suitable for use in hot in-place and hot in-plant recycling processes.
    Type: Grant
    Filed: January 4, 2008
    Date of Patent: October 12, 2010
    Assignee: Shell Oil Company
    Inventors: Sophie Nigen-Chaidron, Laurent Porot
  • Publication number: 20100236178
    Abstract: A sealant composition for roofing shingles that includes a base asphalt, a linear and/or a radial copolymer, oil, and a wax is provided. The linear copolymer has an A-B di-block or an A-B-A tri-block structure. The radial copolymer may have an (A-B)n radial structure, where n is at least 4, or a tri-block (A-B-A) radial structure having from 4 to 8 arms. Blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene. The oil is a petroleum-based oil that both “softens” the asphalt and reduces the viscosity of the sealant composition. The wax may be a bis-stearamide wax. Additionally, the sealant composition may be reacted with elemental sulfur to crosslink the copolymer blend. The sealant composition seals at temperatures lower than conventional sealants and promotes the easy release of the shingle from a shingle bundle.
    Type: Application
    Filed: March 19, 2010
    Publication date: September 23, 2010
    Inventors: James E. Loftus, Donn R. Vermilion, Jason D. Guerra
  • Publication number: 20100227954
    Abstract: Asphalt compositions and products comprising petroleum asphalt, polyolefin, and a wax.
    Type: Application
    Filed: March 8, 2009
    Publication date: September 9, 2010
    Inventors: PREMNATHAN NAIDOO, Patrick Keating
  • Publication number: 20100222465
    Abstract: A method of selecting a crack resistant layer to be applied to an existing surface, the method comprising the steps of: selecting at least one bituminous binder to examine, where the bituminous binder comprises bitumen and one or more polymers, where the one or more polymers include a sufficient amount of conjugated diene such that at least 2.5% of the bituminous binder's weight comprises conjugated diene, preferably at least 3.0%, more preferably at least 3.5%, and most preferably 4.0%; forming at least one bituminous mixture comprising the bituminous binder and an aggregate; testing each bituminous mixture for mixture fracture energy properties; and selecting a bituminous binder for use in the crack resistant layer.
    Type: Application
    Filed: February 27, 2009
    Publication date: September 2, 2010
    Applicant: SEMMATERIALS, L.P.
    Inventors: James J. Barnat, Phillip Blankenship, Richard Steger, Todd Lynn, Jason Bausano, Jehna Dent, Tim McKinney
  • Publication number: 20100222466
    Abstract: A method of selecting a crack resistant layer to be applied to an existing surface, the method comprising the steps of: selecting at least one emulsified bituminous binder to examine, where the emulsified bituminous binder comprises bitumen, one or more emulsifier, and one or more polymers, where the one or more polymers, the one or more emulsifier, or both include a sufficient amount of conjugated diene such that at least 2.5% of the weight of the emulsified bituminous binder residuum comprises conjugated diene, preferably at least 3.0%, more preferably at least 3.5%, and most preferably 4.0%; forming at least one bituminous mixture comprising the emulsified bituminous binder and an aggregate; testing each bituminous mixture for fatigue properties; and selecting a bituminous binder for use in the crack resistant layer.
    Type: Application
    Filed: February 27, 2009
    Publication date: September 2, 2010
    Applicant: SEMMATERIALS, L.P.
    Inventors: James J. Barnat, Vince Vopat
  • Patent number: 7781503
    Abstract: A process for preparing a modified asphalt binder composition, the process comprising mixing asphalt, an unsaturated polymer, and phosphorus pentasulfide to form a modified asphalt composition.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: August 24, 2010
    Inventors: William L. Hergenrother, Peter W. Boerner, Christine Rademacher, Daniel F. Graves, Timothy P. Reece, Herbert L. Wissel
  • Publication number: 20100197835
    Abstract: The disclosure relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The disclosure also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The disclosure further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.
    Type: Application
    Filed: July 17, 2008
    Publication date: August 5, 2010
    Applicants: TOTAL REFFINAGE MARKETING, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS
    Inventors: Pierre Chaverot, Charlotte Godivier, Ludwik Leibler, Ilias Iliopoulos, Amanda Kathryn Leach
  • Publication number: 20100190894
    Abstract: The disclosure relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The disclosure also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The disclosure further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.
    Type: Application
    Filed: July 18, 2008
    Publication date: July 29, 2010
    Applicants: TOTAL RAFFINAGE MARKETING, CENTRE NATIONAL DE RECHERCHE SCIENTIFIQUE (CNRS)
    Inventors: Pierre Chaverot, Charlotte Godivier, Ludwik Leibler, Ilias Iliopoulos, Amanda Kathryn Leach
  • Publication number: 20100179255
    Abstract: A method of preparing asphalt, comprising a step of combining a bitumen composition with aggregate, is disclosed. The bitumen composition comprises greater than 75 wt % bitumen and between 0.005 and 0.5 wt % polyacrylamide.
    Type: Application
    Filed: April 24, 2008
    Publication date: July 15, 2010
    Inventors: Celine Grenier, Sophie Nigen-Chaidron
  • Patent number: 7745518
    Abstract: An asphalt binder is provided, comprising 85 to 97.5 parts by weight of a bitumen and 16 to 2.5 parts by weigh of a polymer composition, wherein the polymer composition comprises: (i) from 2 to 8, preferably from 3 to 6 parts by weight of a styrenic block copolymer having at least two blocks of monovinylaromatic hydrocarbon (A) and at least one block of a conjugated diene (B), wherein the block copolymer composition has a vinyl content of at least 25% by weight, preferably from 25 to 40% by weight, based on the total diene content; (ii) from 0 to 5, preferably from 1 to 3 parts by weight of a styrenic diblock copolymer having one block of monovinylaromatic hydrocarbon (A) and one block of a conjugated diene (B); and (iii) from 0.5 to 3, preferably from 1 to 2.5 parts by weight of an ethylene-vinyl acetate copolymer, wherein the weight ratio of (i)+(ii):(iii) is from 2:1 to 6:1, preferably from 3:1 to 4:1.
    Type: Grant
    Filed: October 16, 2006
    Date of Patent: June 29, 2010
    Assignee: Kraton Polymers U.S. LLC
    Inventor: Erik Jan Scholten
  • Patent number: 7732511
    Abstract: The invention relates to anhydrous bituminous products containing one or several specific additives which make it possible to substantially reduce a temperature for producing aggregate and bituminous product mixtures in such a way that it ranges from 20 to 40° C., wherein the temperature of the aggregate and the bituminous product mixture during spreading ranges from 10 to 40° C. and the temperature in the core of the aggregate and bituminous product mixtures during compacting can be raised to 50° C. without degrading the standardized properties of the bituminous product and the bituminous product and aggregate mixture and ensuring the process continuity from transport to compacting according to the state of the art. The inventive aggregate and bituminous product mixtures are particularly suitable for tightening, building and servicing road surfaces, pavements and airfield runways.
    Type: Grant
    Filed: April 4, 2006
    Date of Patent: June 8, 2010
    Assignee: Ceca S.A.
    Inventors: Gilles Barreto, Loic Fraboulet
  • Publication number: 20100105813
    Abstract: A modified-asphalt composition prepared by introducing a diene end-capped block copolymer with a molten asphalt composition.
    Type: Application
    Filed: April 18, 2008
    Publication date: April 29, 2010
    Inventors: Herb Wissel, Peter Boerner, Daniel Graves, Christine Rademacher, Timothy Reece
  • Patent number: RE42165
    Abstract: A modified asphalt composition is provided comprising at least one plastomer, at least one elastomer, at least one crosslinking agent and asphalt. More specifically, a modified asphalt composition is provided comprising an oxidized polyethylene, a styrene-butadiene-styrene block copolymer, sulfur, and asphalt. A hot mix asphalt composition is also provided comprising the modified asphalt composition and aggregate. Processes for producing the modified asphalt composition and the hot mix asphalt composition are also provided as well as articles produced from these inventive compositions.
    Type: Grant
    Filed: December 4, 2008
    Date of Patent: February 22, 2011
    Assignees: Westlake Longview Corp., PRI Asphalt Technologies, Inc.
    Inventors: Richard Kingsley Stuart, Jr., Jeffery Lynn Presley, Kenneth Francis Grzybowski