N-containing Reactant Patents (Class 524/838)
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Patent number: 5100991Abstract: The specification describes and claims certain organosilicon compounds and the preparation thereof. The organosilicon compounds comprise (A) a silane according to the general formula R.sup.1.sub.a A.sub.b Si(R"NXR').sub.c or (B) a polysiloxane comprising one or more siloxane units according to the general formula (i) ##EQU1## any remaining units of the polysiloxane being at least predominantly according to the general formula (ii) ##EQU2## A represents a hydroxyl or a hydrolyzable group, R.sup.1 represents a monovalent hydrocarbon group having up to 8 carbon atoms, R.sup.2 represents a hydroxyl group, a group R.sup.1, a group OR.sup.1 or a group COR.sup.1, R.sup.4 represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkenyl group or an aryl group, R' represents a group R.sup.4 or a group X, R" represents a divalent hydrocarbon group which may have nitrogen, oxygen or sulphur present in the carbon chain, X represents a group CO(CHR).sub.Type: GrantFiled: December 10, 1990Date of Patent: March 31, 1992Assignee: Dow Corning LimitedInventors: Stephen E. Cray, James McVie, Paul A. Yianni
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Patent number: 5073593Abstract: According to this invention, a microemulsion of an organopolysiloxane containing cyclohexylamino groups is prepared as follows: component (A), an organopolysiloxane containing cyclohexylamino groups and component (B), a nonionic surfactant and component (C), ethylene glycol or propylene glycol are blended. Formic acid or acetic acid, component (D) and water, component (E), are then added. The mixture is then stirred to form an emulsion precursor liquid, which is then dispersed in a prescribed amount of water. The microemulsion of the organopolysiloxane containing cyclohexylamino groups prepared using the method of this invention has an excellent shelf stability.Type: GrantFiled: June 13, 1990Date of Patent: December 17, 1991Assignee: Dow Corning Toray Silicone Company, LTD.Inventors: Masaru Ozaki, Isao Ona
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Patent number: 5041494Abstract: The present invention is directed to aqueous solutions or dispersions of cationically modified polyurethanes, characterized in that the dissolved or dispersed polyurethanes(i) contain about 2 to 200 milliequivalents of incorporated ammonium groups per 100 g of solids content,(ii) contain 0 to about 25% by weight of ethylene oxide units within terminal or lateral polyether chains and(iii) contain at least 1.3% by weight, calculated as SiO.sub.3 (molecular weight=76), of built-in structural units corresponding to the formula ##STR1## wherein R', R" and R"' may be the same or different and represent hydrogen or alkyl groups containing 1 to 4 carbon atoms,the total quantity of hydrophilic structural units (i) and (ii) being sufficient to ensure the solubility or dispersibility of the polyurethanes in water and the solutions or dispersions having a pH value of 3 to 6.Type: GrantFiled: October 28, 1988Date of Patent: August 20, 1991Assignee: Bayer AktiengesellschaftInventors: Joachim Franke, Hanns P. Muller
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Patent number: 5039738Abstract: Process for preparing a modified aminoorganosiloxane emulsion having improved non-yellowing properties comprising reacting (a) a dialkyl pyrocarbonate, (b) a dialkyl oxalate, or (c) a mixture thereof with an aminoorganosiloxane in an aqueous emulsion in which (a), (b) or (c) ranges from about 0.1% to 15% based on the weight of aminoorganosiloxane in the emulsion.Type: GrantFiled: December 14, 1990Date of Patent: August 13, 1991Assignee: Union Carbide Chemicals and Plastics Technology CorporationInventor: Anna M. Czech
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Patent number: 5017297Abstract: Microemulsions are provided in which the oil phase comprises a reaction product of an organosilicon compound having amino groups and an organosilicon compound having epoxy groups, wherein the reaction product has at least one amino group and two silicon-bond --OR groups. A method for making the microemulsions which comprises reacting the two organosilicon compounds sufficiently to allow the reaction of some of the amine groups with the epoxy groups, but avoiding the excessive crosslinking of the components and their application in the treatment of fibrous materials is also described.Type: GrantFiled: August 17, 1989Date of Patent: May 21, 1991Assignee: Dow Corning LimitedInventors: Konstantinos Spyropoulos, Paul A. Yianni
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Patent number: 5008328Abstract: This invention provides an aqueous organosilicon resin coating composition comprising:(I) an aqueous organosilicon resin which is a condensation product and which contains a quaternary ammonium base, the condensation product being prepared from (i) an organosilicon compound represented by the formulaR.sup.1.sub.a Si(OR.sup.2).sub.4-a (A)wherein R.sup.1 is hydrocarbon group having 1 to 12 carbon atoms, R.sup.2 is hydrocarbon group having 1 to 8 carbon atoms and a is 0, 1 or 2, and/or a low condensate thereof and (ii) an organosilicon compound represented by the formula ##STR1## wherein R.sup.3 is hydrogen atom or methyl group, R.sup.4 is bivalent hydrocarbon group having 1 to 8 carbon atoms and R.sup.2 is as defined above, and/or a low condensate thereof and,(II) an aqueous medium.Type: GrantFiled: February 21, 1989Date of Patent: April 16, 1991Assignee: Kansai Paint Co., Ltd.Inventors: Noboru Nakai, Osamu Isozaki
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Patent number: 4935464Abstract: A microemulsion with an average particle size not exceeding 0.15 micrometers or organopolysiloxane composed of trifunctional siloxane units with the formula RSiO.sub.3/2 and difunctional siloxane units with the formula R.sup.1.sub.2 SiO is characterized by transparency, by excellent mechanical, dilution, and blending stabilities and by an excellent stability against pH variations. The microemulsion is prepared by process comprising the slow addition, to an aqueous emulsion-polymerization catalyst solution, of a crude emulsion prepared from an organotrialkoxysilane having the formula RSi(OR.sup.1).sub.3, a cyclic organopolysiloxane having the formula (R.sup.1.sub.2 SiO).sub.n, a surfactant, and water. A microemulsion which consists of 30 to 95 mol % trifunctional siloxane units and 70 to 5 mol % difunctional siloxane units is useful as a fiber-treatment agent that can impart slip resistance to fibrous material without stiffening the hand, while at the same time not causing oil spots.Type: GrantFiled: April 28, 1988Date of Patent: June 19, 1990Assignee: Toray Silicone Company LimitedInventors: Isao Ona, Masaru Ozaki
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Patent number: 4921895Abstract: A preparation for finishing textile fibers or products comprising textile fibers is disclosed. The preparation is liquid and contains 0.5 to 80% by weight of a mixture of modified organopolysiloxane A and B in a ratio of A:B by weight of 10:1 to 1:1, with the proviso that organpolysiloxane A is a linear siloxane containing polyether groups and having at least 40 dialkylsiloxy units, to which are linked at least 2 polyether groups, each of which has a molecular weight of 600 to 4,000 and which comprises 40 to 100 mole percent of oxyethylene units, the remainder being oxypropylene units, the ratio of the number of dialkylsiloxy units to the number of polyether groups being greater than or equal to 8.Type: GrantFiled: January 17, 1989Date of Patent: May 1, 1990Assignee: Th. Goldschmidt AGInventors: Dietmar Schaefer, Friedhelm Nickel
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Patent number: 4847120Abstract: A prepolymer composition for forming a scratch-resistant coating, comprising an acidic, aqueous solution of a polysiloxane prepolymer having non-coreactive side groups and co-reactive side groups other than hydrolysable groups, the composition being curable by evaporation of solvent and a decrease in acidity causing the co-reactive groups to react together to cross-link the polymer. Suitable co-reactive side groups are amino, epoxy and thiol. Suitable non-coreactive side groups are alkyl and gamma methacryloxy propyl. Acidity is suitably achieved by using a volatilisable organic acid such as acetic acid, so that it evaporates with the solvents to decrease the acidity.Type: GrantFiled: November 7, 1988Date of Patent: July 11, 1989Assignee: Cogent LimitedInventor: John A. G. Gent
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Patent number: 4816303Abstract: Corrosion of ferrous metal and aluminum surfaces, in particular, is inhibited by a layer of an organic-metallic complex of a polyamine with a (i) metal oxide, or (ii) metallate ion, or (iii) water-soluble metallate salt, in aqueous systems having a pH greater than about 7. The polyamine contains at least four (4) amine groups, two of which are secondary amine groups. The effect of the N atoms stretched over the length of the polyamine produces a "caging effect"0 which immobilizes the oxide, or metallate ions, thus forming the protective layer. The organic-metallic complex deposited on the metal's surface forms the "amine-metallic" layer which may be either an "amine-metal oxide complex" which is a coordination complex, or, an "amine-metallate complex". The amine-metallate complex may be either an ionic complex of "amine.Type: GrantFiled: June 15, 1987Date of Patent: March 28, 1989Assignee: The B. F. Goodrich CompanyInventors: William J. Kroenke, Anthony M. Mazany, John V. Standish
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Patent number: 4767646Abstract: Aqueous overfinish compositions, yarns treated therewith, and methods of producing wet abrasion resistant cordage from the yarn are all disclosed. One of the compositions includes an oxidized polyethylene emulsified with a non-nitrogen, nonionic emulsifier and neutralized with an alkali hydroxide, and a compound selected from the group consisting of a siloxane of the comonomers dimethyl and 3-[(2-aminoethyl)aminopropyl], and an amide melamine wax. An alternate finish composition comprises an oxidized polyethylene, neutralized with ammonium hydroxide and emulsified with a non-nitrogen, nonionic emulsifier. Yarn treated with this alternate finish has enhanced wet abrasion resistance. Yarns of this invention are ideally suited for heavy ropes and other industrial cordage applications where wet and dry abrasion resistance and strength are desirable.Type: GrantFiled: October 24, 1985Date of Patent: August 30, 1988Assignee: Allied CorporationInventors: Colleen W. Cordova, Robert M. Marshall
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Patent number: 4720520Abstract: A method for impregnating organic fibers which comprises applying a composition containing (1) an organopolysiloxane having silicon-bonded condensable groups and containing diorganosiloxane units in which the two SiC-bonded organic radicals are monovalent hydrocarbon radicals and also contains two monovalent SiC-bonded radicals having a basic nitrogen group; (2) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule; and (3) a catalyst which promotes the condensation of the silicon-bonded condensable groups, in which the SiC-bonded radicals having a basic nitrogen group are present in the organopolysiloxane (1) as monoorganosiloxane units and as diorganosiloxane units.Type: GrantFiled: April 9, 1987Date of Patent: January 19, 1988Assignee: Wacker-Chemie GmbHInventors: Karl Huhn, Ingomar Kovar
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Patent number: 4720513Abstract: The present invention relates to an instantaneous adhesive composition which is satisfactorily made thixotropic or gelled and has a rapid setting time and an excellent adhesive strength, said composition being obtained by adding to an .alpha.-cyanoacrylate a silica gel treated with a silyl isocyanate.Type: GrantFiled: May 4, 1987Date of Patent: January 19, 1988Assignee: Matsumoto Seiyaku Kogyo Kabushiki KaishaInventors: Makoto Kameyama, Masakazu Wakabayashi, Iwakichi Sugiyama
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Patent number: 4643839Abstract: The reaction product of phosphorous acid, formaldehyde, and monomeric or polymeric alkoxysilanes having one or more aminoalkylene groups are useful as gelation inhibitors for aqueous glycol solutions.Type: GrantFiled: April 16, 1984Date of Patent: February 17, 1987Assignee: The Dow Chemical CompanyInventors: Richard A. Pierce, David A. Wilson
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Patent number: 4618642Abstract: An aqueous silicone elastomeric emulsion is a storage stable, paste-type material useful as a caulking material. The caulking material is obtained by mixing an anionic emulsion containing dispersed particles of hydroxyl endblocked polydiorganosiloxane, dialkyltindicarboxylate, silane of the formula RSi(OR').sub.3 where R is a monovalent hydrocarbon radical of from 1 to 4 carbon atoms inclusive and R' is a lower alkyl radical of from 1 to 4 carbon atoms inclusive or a radical of the formula --N.dbd.CR.sub.2, and inert, non-siliceous filler.Type: GrantFiled: May 2, 1985Date of Patent: October 21, 1986Assignee: Dow Corning CorporationInventor: Christine J. Schoenherr
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Patent number: 4608412Abstract: A silicone caulking material obtained by mixing an anionically stabilized, hydroxyl endblocked polydiorganosiloxane in an aqueous emulsion, dialkyltindicarboxylate, alkylorthosilicate, and inert, non-siliceous filler is capable of yielding an elastomer upon removal of the water immediately upon mixing of the ingredients. When the caulking material also contains 2-amino-2-methyl-1-propanol, the emulsion also has a useful shelf life in that the emulsion shows no gelation upon aging. The physical properties of the elastomer produced by removing the water from the emulsion do not change appreciably during the useful life of the caulking material.Type: GrantFiled: May 24, 1985Date of Patent: August 26, 1986Assignee: Dow Corning CorporationInventor: Alan L. Freiberg
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Patent number: 4600436Abstract: Aminofunctional emulsions and aminofunctional silicone polishes are provided which exhibit improved adhesion and resistance to removal by detergent washing when applied to solid surfaces.Type: GrantFiled: May 22, 1984Date of Patent: July 15, 1986Assignee: General Electric CompanyInventors: Frank J. Traver, Raymond J. Thimineur, Anthony A. Zotto
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Patent number: 4559271Abstract: Ultraviolet radiation resistant silicone resin coating compositions are provided having improved thermoformability. Improved thermoformability and shortened required aging are achieved by the addition of a Lewis acid compound to the coating compositions is disclosed. Thermoformability is also improved by using the UV screen containing silicone resin coating composition in conjunction with extensible acrylate primers.Type: GrantFiled: July 27, 1984Date of Patent: December 17, 1985Assignee: General Electric CompanyInventors: James E. Doin, Howard A. Vaughn, Jr.
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Patent number: 4559385Abstract: Aqueous emulsions for impregnating organic fibers, comprising, in addition to water and dispersants, (1) a diorganopolysiloxane having a Si-bonded hydroxyl group in each terminal unit and whose organic radicals are free of basic nitrogen atoms; (2) an organopolysiloxane containing diorganosiloxane units in which the two organic radicals are monovalent hydrocarbon radicals and also contains at least two monovalent SiC-bonded organic radicals per molecule having a basic nitrogen atom in which the organopolysiloxane is present in the emulsion in an amount of from 5 to 50 weight percent based on the weight of the diorganopolysiloxane (1); (3) an organosilicon compound selected from an organosilane containing at least two SiOC-bonded monovalent organic radicals consisting of carbon, hydrogen and possibly oxygen and/or partial hydrolyzates thereof, in which the organosilicon compound is present in the emulsion in an amount of from 2 to 6 weight percent based on the total weight of the diorganopolysiloxane (1) and oType: GrantFiled: September 10, 1984Date of Patent: December 17, 1985Assignee: Wacker-Chemie GmbHInventors: Karl Huhn, Kurt Ullrich
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Patent number: 4558093Abstract: A laser shield consists essentially of a series of spherical glass bubbles densely packed within a range of 1.95.times.10.sup.3 bubbles per cubic centimeter to 1.25.times.10.sup.8 bubbles per cubic centimeter encapsulated in a matrix of silicone to provide a flexible and lightweight foam-like material to terminate CO.sub.2 laser radiation without producing a substantial carbon plume. The glass bubbles may be filled with a gas. In another embodiment, a laser shield consists essentially of water encapsulated in a matrix of silicone to provide a flexible and lightweight material to terminate CO.sub.2 laser radiation without producing a substantial carbon plume. In another embodiment, water bubbles and glass bubbles are both encapsulated within a matrix of silicone to provide a laser shield. A surgical drape, a surgical sponge and an endotracheal tube are formed of a flexible and lightweight material of a series of densely packed bubbles encapsulated in a matrix of silicone to terminate laser radiation.Type: GrantFiled: April 30, 1984Date of Patent: December 10, 1985Inventors: John R. Hatzenbuhler, Thomas A. Lindl
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Patent number: 4535109Abstract: Described is a method of producing silicone aqueous emulsion compositions which cure at room temperature by the removal of water to form elastomeric coatings or films with superior surface gloss, good adhesion to substrates, and rustproofness. The method prepares an emulsion of polydiorganosiloxane having at least two hydroxyl groups per molecule, colloidal silica or alkali metal silicate, curing catalyst, emulsifier, and water, the emulsion having a pH of from 9 to 12. After a period of ripening for a period of time, so that an elastomeric material will be formed when water is removed at room temperature, an amino-functional silane or its partial hydrolyzate is added to give the emulsion its improved properties.Type: GrantFiled: September 24, 1984Date of Patent: August 13, 1985Assignee: Toray Silicone Company, Ltd.Inventors: Hidetoshi Kondo, Taro Koshii
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Patent number: 4496687Abstract: The invention provides a novel organopolysiloxane-containing aqueous emulsion composition which, upon removal of water by drying at room temperature, can give a cured rubbery elastomer having excellent mechanical properties and exhibiting strong adhesion to the substrate on which it has been cured. The inventive composition is prepared by blending (A) an aqueous emulsion of an organopolysiloxane having silicon-bonded hydroxy groups and emulsified in water by use of an anionic surface active agent, (B) a mixture of a reaction product of a carboxylic acid anhydride with an amino-functional organosilane and a colloidal silica in the form of an aqueous suspension and (C) a curing catalyst in limited proportions.Type: GrantFiled: January 27, 1984Date of Patent: January 29, 1985Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Fumio Okada, Toshio Oba, Morizo Nakazato
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Patent number: 4495322Abstract: What are disclosed are coating formulations of improved storage stability comprising a silicone resin prepared by the condensation of partially hydrolyzed organo-silicon compounds in the presence of an acid, said coating formulations containing an amide of an alkanoic acid having up to 22 carbon atoms or an amide of benzoic acid, optionally substituted, or a carbamic acid ester having an alkyl group containing up to 18 carbon atoms or having a phenyl or naphthyl group, optionally substituted, in the ester part, or containing ureas or lactams, or mixtures thereof.Type: GrantFiled: March 5, 1984Date of Patent: January 22, 1985Assignee: Rohm GmbHInventor: Ralf Liebler
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Patent number: 4477499Abstract: Ultraviolet radiation resistant silicone resin coating compositions are provided having improved thermoformability. Improved thermoformability and shortened required aging are achieved by the addition of a Lewis acid compound to the coating compositions is disclosed. Thermoformability is also improved by using the UV screen containing silicone resin coating composition in conjunction with extensible acrylate primers.Type: GrantFiled: September 7, 1982Date of Patent: October 16, 1984Assignee: General Electric CompanyInventors: James E. Doin, Howard A. Vaughn, Jr.
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Patent number: 4467068Abstract: A composition for concealing grazes or scratches on glass surfaces comprising an emulsion of composition (A) and composition (B), said composition (A) comprising the emulsion-polymerization product of:(1) 0.1-60 weight percent of (A) of the reaction product of:(a) 0.1-50 weight percent of (a) and (b) of the product obtained by reacting:(i) 1 mole of a compound of the formula Q.sup.1 NHR.sup.1 SiR.sub.a.sup.2 (OR).sub.3-a with(ii) 0.5-3.0 moles of a compound of the formula Q.sup.2 R.sup.4 SiR.sub.a.sup.2 (OR).sup.6).sub.3-b ;(b) 50-99.9 weight percent of (a) and (b) of a polydiorganosiloxane having at least one silanol group and a viscosity at 25.degree. C. of 5-10,000 cSt;(2) 1-50 weight percent of (A) of a compound of the formula (R.sup.7 R.sup.8 SiO).sub.n ;(3) 0.Type: GrantFiled: May 18, 1983Date of Patent: August 21, 1984Assignee: Toshiba Silicone Co., Ltd.Inventors: Kazo Maruyama, Akitsugu Kurita
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Patent number: 4436856Abstract: Organic fibers are impregnated with an aqueous emulsion comprising (1) an organopolysiloxane containing diorganosiloxane units in which both organic radicals are monovalent hydrocarbon radicals, and further contains at least two monovalent SiC-bonded organic radicals with a basic nitrogen atom per molecule in which the SiC-bonded organic radicals with a basic nitrogen are present in monoorganosiloxane units, (2) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule, (3) a catalyst for the condensation of Si-bonded condensable groups (4) emulsifiers, and (5) a diorganopolysiloxane containing an Si-bonded hydroxyl group in each of its terminal units and whose radicals are free of the basic nitrogen atom. If it is desired to impart hydrophobic properties to the impregnated organic fibers, then it is essential that (6) a trimethylsiloxy end-blocked diorganopolysiloxane be added to the aqueous emulsion.Type: GrantFiled: February 8, 1982Date of Patent: March 13, 1984Assignee: Wacker-Chemie GmbHInventors: Karl Huhn, Heinrich Marwitz
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Patent number: 4412035Abstract: The present invention relates to a silicone cationic emulsion composition of a polydioganosiloxane containing amino, epoxy, and hydroxyl groups as functional groups, and which may be used as a releasing agent, stripping agent, paint component, and anti-foaming agent.Type: GrantFiled: May 24, 1982Date of Patent: October 25, 1983Assignee: Toshiba Silicones Ltd.Inventor: Akitsugu Kurita
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Patent number: 4377676Abstract: This invention discloses silicone-alkyd resins and a method for their preparation which overcomes prior art problems in the manufacture of such resins. The method consists of reacting all of the components of the silicone-alkyd resin together essentially simultaneously.Type: GrantFiled: September 23, 1981Date of Patent: March 22, 1983Assignee: Dow Corning CorporationInventors: Laura A. Gauthier, Gary E. LeGrow
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Patent number: 4373060Abstract: A silicone hardcoat composition for plastic substrates is provided in the form of an aqueous cohydrolyzate of chemically combined siloxy units, organosiloxy units and siloxy units having from 1-3 chemically combined UV stabilizing organic groups attached to silicon by carbon-silicon bonds. Thermoplastic substrates treated with such silicone hardcoat compositions are also provided.Type: GrantFiled: May 30, 1980Date of Patent: February 8, 1983Assignee: General Electric CompanyInventor: Ta-Yen Ching
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Patent number: 4324712Abstract: Silicone resin coating compositions, having a basic pH in the range of from 7.1 to 7.8 are provided. These coating compositions are prepared by hydrolyzing an alkyltrialkoxysilane or aryltrialkoxysilane in an aqueous colloidal silica dispersion and adding to the resultant hydrolysis product a linear functionally terminated oligomeric siloxane. When applied to a solid substrate, these silicone resin compositions provide an abrasion resistant coating having improved resistance to cracking.Type: GrantFiled: January 18, 1980Date of Patent: April 13, 1982Assignee: General Electric CompanyInventor: Howard A. Vaughn, Jr.