Two Nitrogen Atoms In The Fused Or Bridged Ring System Patents (Class 524/92)
  • Patent number: 5476886
    Abstract: Mass-coloured synthetic polyamide containing, as pigment, at least one diketopyrrolopyrrole pigment of formula ##STR1## wherein A and B are each independently of the other a radical of formula ##STR2## wherein Q is a --CONH.sub.2 group,m is 1 or 2,R.sub.1 and R.sub.2 are each independently of the other hydrogen, Cl, Br, CH.sub.3 or C.sub.2 H.sub.5,R.sub.3 is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or phenyl,X is a direct bond, --O--, --S--, --SO.sub.2 --, --CH.dbd.CH--, --CH.sub.2 -- or --C(CH.sub.3).sub.2 --, andY is --O-- or --S--.Polyamides mass-coloured with the pigments useful in the practice of this invention have exceptional heat stability and excellent lightfastness.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: December 19, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Olof Wallquist, Bernd Lamatsch
  • Patent number: 5473001
    Abstract: Hindered amine light stabilizers are provided in which the hindered amine is contained in a unit of formula ##STR1## where X is ##STR2## and R.sup.1, R.sup.2, R.sup.3 and A are as defined as in the Summary of the Invention. Unique polymeric and non-polymeric compounds containing this unit are useful as additives for the stabilization of polymeric compositions which are normally subject to thermal, oxidative or actinic light degradation.
    Type: Grant
    Filed: April 17, 1995
    Date of Patent: December 5, 1995
    Assignee: Elf Atochem North America, Inc.
    Inventor: Terry N. Myers
  • Patent number: 5384351
    Abstract: Internal mould release compositions suitable for use in the production of moulded articles by the RIM process, comprise a blend of a metal salt of an organic acid and a polysiloxane polymer having isocyanate reactive organic groups and optionally a compatibilizing amount of an amidine or imidate compound.
    Type: Grant
    Filed: September 8, 1993
    Date of Patent: January 24, 1995
    Assignee: Imperial Chemical Industries PLC
    Inventor: Herbert R. Gillis
  • Patent number: 5378749
    Abstract: The invention relates to polyarylene sulfides (PAS), more particularly polyphenylene sulfides (PPS), showing reduced flash formation.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: January 3, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Burkhard Kohler, Bahman Sarabi
  • Patent number: 5376710
    Abstract: Compounds which comprise at least one group of the formula I or II ##STR1## and at least one polyalkylpiperidine group of the formula III ##STR2## in which R and R.sub.1 to R.sub.6 have the meaning indicated in claim 1, are effective stabilizers for organic materials against damage by light, oxygen and heat.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: December 27, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Mario Slongo, Jean-Luc Birbaum, Jean Rody, Andreas Valet
  • Patent number: 5350786
    Abstract: Stabilizers for organic polymers, consisting of one or more compounds of the classis of the sterically hindered amines (HALS) are directly added to the reaction mixture during the (co)polymerization of the .alpha.-olefins or of their mixtures with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized and show a thermo- and photo-oxidative resistance higher than that of the same polymeric compositions to which the same stabilizers are added by a traditional route.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: September 27, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Silvestro Costanzi, Damiano Gussoni, Luciano Pallini
  • Patent number: 5334642
    Abstract: Stabilized polyaryl ether ketone molding compositions containing as essential componentsA) from 50 to 99.99% by weight of a polyaryl ether ketone prepared by electrophilic polycondensation and composed to an extent of not less than 50 mol % of units of the formula I' ##STR1## where s and t are each 0, 1, 2 or 3, T and T' are each --O-- or --CO-- and Ar is meta-phenylene, paraphenylene or two aromatic rings linked to each other in the meta or para position by a chemical bond, or the ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.6 -C.sub.20 -aryl or halogen derivatives thereof,B) from 0.01 to 4% by weight of at least one organic compound which has a base constant pk.sub.b within the range from 2 to 12 and a boiling point of higher than 300.degree. C.,C) from 0 to 50% by weight of a further thermoplastic other than A), andD) from 0 to 45% by weight of fibrous or particulate fillers or mixtures thereof.
    Type: Grant
    Filed: December 30, 1992
    Date of Patent: August 2, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Koch, Gerhard Heinz
  • Patent number: 5308902
    Abstract: Biphosphites of formula I ##STR1## wherein m is 0, 1 or 2,n is 1 to 4 or 6,R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different, and A is the radical of an at least n-hydric alcohol or phenol, which radical is attached to the P atom or atoms through the alcoholic or phenolic O atom or atoms, obtainable by reacting a compound of formula II ##STR2## wherein m is 0, 1 or 2, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different and R.sub.2 ' is phenyl, C.sub.1 -C.sub.12 alkylphenyl or C.sub.1 -C.sub.4 alkyl, with a polyether polyol or polyether/ester polyol, the hydroxy functions of said polyether polyol or polyether/ester polyol being partially or completely esterified with the ##STR3## are suitable for use as stabilizers, especially processing stabilizers, for organic polymers, preferably PVC resins, high density polyethylene and propylene.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: May 3, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Holger Andreas, Alfred Renner, Horst Zinke
  • Patent number: 5298539
    Abstract: New additives in rubber compositions improve tire cord adhesion without need to use resorcinol. The new additives are derivatives of melamine, aceto guanamine, benzoguanamine, cyclohexylguanamine, and glycoluril, substituted with at least two vinyl-terminated radicals. Preferred compounds may also be substituted with at least one radical having a carbamylmethyl group.
    Type: Grant
    Filed: September 5, 1990
    Date of Patent: March 29, 1994
    Assignee: Cytec Industries, Inc.
    Inventors: Balwant Singh, John A. Sedlak
  • Patent number: 5264034
    Abstract: Pigment preparations consisting essentially of (a) at least one pigment based on perylene-3,4,9,10-tetracarboxylic dianhydride or on corresponding monoimides or diimides of tetracarboxylic acid monoanhydride, or a halogenation product thereof, (b) at least one pigment dispergent based on perylene-3,4,9,10-monoimide substituted on one or both imide nitrogen atoms by alkylene or arylene sulphonic or carboxylic acid groups or on corresponding diimides of tetracarboxylic acid monoanhydride, or a halogenation product thereof. The dispergents used appreciably enhance the key properties of perylene pigments, such as dispersibility, coloring power, stability to flocculation, transparency, rheological behavior and surface properties of the application medium. These new preparations are suitable for the pigmentation of high-quality lacquers and synthetic resins.
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: November 23, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Erwin Dietz, Manfred Urban
  • Patent number: 5213733
    Abstract: Synthetic textiles containing a photochromic pigment. The pigments are prepared by encapsulating a photochromic pigment in a thermoplastic polymer having a high melt flow index, mixed with a primary thermoplastic resin, and extruded at a temperature of less than 250.degree. C. through a spinnerette having a diameter of at least 0.3 ml.
    Type: Grant
    Filed: June 3, 1991
    Date of Patent: May 25, 1993
    Assignee: Industrial Technology Research Institute
    Inventors: Yean-Rong Hwu, Chi-Chung Bai, Li-Chang Tao, Der-Guey Luo, Andrew T. Hu
  • Patent number: 5208278
    Abstract: Stabilized polyaryl ether ketone molding compositions containing as essential componentsA) from 50 to 99.99% by weight of a polyaryl ether ketone prepared by electrophilic polycondensation and composed to an extent of not less than 50 mol % of units of the formula I' ##STR1## where s and t are each 0, 1, 2 or 3, T and T' are each --0-- or --CO-- and Ar is meta-phenylene, paraphenylene or two aromatic rings linked to each other in the meta or para position by a chemical bond, or the ring-substituted C.sub.1 -C.sub.8 -alkyl, C.sub.6 -C.sub.20 -aryl or halogen derivatives thereof,B) from 0.01 to 4% by weight of at least one organic compound which has a base constant pk.sub.b within the range from 2 to 12 and a boiling point of higher than 300.degree. C.,C) from 0 to 50% by weight of a further thermoplastic other than A), andD) from 0 to 45% by weight of fibrous or particulate fillers or mixtures thereof.
    Type: Grant
    Filed: March 29, 1991
    Date of Patent: May 4, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Koch, Gerhard Heinz
  • Patent number: 5134237
    Abstract: Compounds of the formula ##STR1## wherein Me denotes Zn, Cu, Co (II) or Ni;R.sub.1 denotes hydrogen, optionally substituted aryl or optionally substituted hetaryl;R.sub.2 denotes hydrogen, optionally substituted alkyl, cycloalkyl, aralkyl, aryl or hetaryl;R.sub.3 denotes a substituent;n denotes 0-4; andR.sub.4 denotes hydrogen or methyl;are suitable for pigmenting macromolecular substances and give very fast pigmentation.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: July 28, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventor: Meinhardt Rolf
  • Patent number: 5087658
    Abstract: A heat-resistant resin paste consisting essentially of a first organic liquid (A.sub.1), a second organic liquid (A.sub.2), a heat-resistant resin (B) which is soluble in an organic liquid mixture consisting essentially of the first organic liquid (A.sub.1) and the second organic liquid (A.sub.2), and fine particles of a heat-resistant resin (C) which are soluble in the first organic liquid (A.sub.1), but insoluble in the second organic liquid (A.sub.2). The first organic liquid (A.sub.1), the second organic liquid (A.sub.2), and the heat-resistant resin (B) are brought into a solution in which the fine particles of a heat-resistant resin (C) are dispersed. The heat-resistant resin paste may be suitably used for screen process printing to provide integrated circuit devices with insulator layers or surface protecting layers. The heat-resistant resin paste is suitable for forming insulator layers or surface protecting layers in integrated circuit devices by employing screen process printing.
    Type: Grant
    Filed: December 18, 1989
    Date of Patent: February 11, 1992
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Hiroshi Nishizawa, Kenji Suzuki, Yoshiyuki Mukoyama, Tohru Kikuchi, Hidetaka Sato
  • Patent number: 5068271
    Abstract: Disclosed are novel 2,4,6 substituted pyrimidines where the substituents may be the same or different groups. At least one substituent must be N-alkyl paraphenylenediamino, and the other substituents may be various radicals containing sulfur, oxygen or nitrogen or hydrogen or alkyl groups. The compounds are useful as antioxidants and antiozonants for unsaturated compounds and polymers.
    Type: Grant
    Filed: July 30, 1990
    Date of Patent: November 26, 1991
    Assignee: Uniroyal Chemical Company, Inc.
    Inventors: Edward L. Wheeler, Franklin H. Barrows, Robert J. Franko
  • Patent number: 5041310
    Abstract: A process for coating polymer particles with an additive includes preparing a liquid composition comprising one or more desired additives and a gelling agent in an oil. The composition is coated onto the polymer particle by any convenient procedure. On cooling the coated particle below the gelling point, the composition gels providing a polymer particle having a uniform coating of the additives which is suitable for direct introduction into a mold.
    Type: Grant
    Filed: June 21, 1990
    Date of Patent: August 20, 1991
    Assignee: Becton, Dickinson and Company
    Inventors: Joel L. Williams, Jane C. Graper
  • Patent number: 5037867
    Abstract: Substituted isoxazolidines of formula I ##STR1## where R.sub.1 and R.sub.2 are independently alkyl, cycloalkyl, alkenyl, aryl or phenylalkyl, R.sub.2 is additionally hydrogen, R.sub.3 is hydrogen or methyl, n is 1-4, E.sub.1 is an electron withdrawing group, and E.sub.2 is hydrogen, alkyl, phenyl or has the same meaning as E.sub.1, are effective in stablizing organic materials against oxidative, thermal and actinic degradation.
    Type: Grant
    Filed: April 12, 1990
    Date of Patent: August 6, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Stephen D. Pastor
  • Patent number: 5008312
    Abstract: Bislactams of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3 and R.sup.4 independently of one another are each C.sub.1 -C.sub.4 -alkyl, or R.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4 form a tetra- or pentamethylene radical, and R.sup.5 is hydrogen, carbonyl-C.sub.1 -C.sub.8 -alkyl, benzoyl, C.sub.1 -C.sub.8 -alkyl, C.sub.7 -C.sub.10 -phenylalkyl, the phenyl nucleus being unsubstituted or substituted by one or two C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkyoxy, fluorine, chlorine or bromine radicals, or is C.sub.1 -C.sub.3 -cyanoalkyl, C.sub.2 -C.sub.4 -hydroxyalkyl or C.sub.2 - or C.sub.3 -aminoalkyl, and the acid addition salts and hydrates of these compounds.The compounds (I) are stabilizers for organic materials.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: April 16, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Alexander Aumueller, Peter Neumann, Hubert Trauth
  • Patent number: 5001171
    Abstract: It now has been found that uncured modified rubber compositions comprising mixtures of elastomers and a reinforcing filler can be prepared having improved properties.
    Type: Grant
    Filed: October 21, 1988
    Date of Patent: March 19, 1991
    Assignee: Bridgestone/Firestone, Inc.
    Inventors: Georg G. Bohm, Daniel F. Graves
  • Patent number: 4966930
    Abstract: A process for coloring high molecular organic material, which comprises the use of isoindolines of formula I ##STR1## wherein A is a group of formula ##STR2## wherein R is a group selected from --CONHR.sub.1, --COOR.sub.2 and ##STR3## and R.sub.1 is hydrogen, C hd 1-C.sub.4 alkyl, phenyl or phenyl which is substituted by one or more identical or different members of the group consisting of halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, --COR.sub.3, --NHCOR.sub.4 or ##STR4## in which formulae R.sub.3 is C.sub.1 -C.sub.4 alkoxy, --NH.sub.2 or --NHR.sub.4,R.sub.4 is C.sub.1 -C.sub.4 alkyl andR.sub.5 is hydrogen, halogen or C.sub.1 -C.sub.4 alkyl, andR.sub.2 is C.sub.1 -C.sub.4 alkyl and Q is --NH or --S--;or A is a group of formula ##STR5## wherein V is NH or O, X.sub.1 and X.sub.3 are each independently of the other halogen, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylmercapto, or phenoxy or phenylmercapto, each unsubstituted or substituted by halogen, C hd 1-C.sub.4 alkyl or C.sub.1 -C.sub.
    Type: Grant
    Filed: July 1, 1988
    Date of Patent: October 30, 1990
    Assignee: Ciba-Geigy Corporation
    Inventor: Jost von der Crone
  • Patent number: 4965302
    Abstract: Disclosed herein is a thermoplastic polyester molded article comprising a thermoplastic polyester and at least one of the specified diimide compounds, the latter being blended in an amount effective for ultraviolet screening. The polyester molded article and a composition for producing it according to this invention is capable of screening ultraviolet rays not only in the short wavelength region but also in the long wavelength region and has uniform dispersion stability and thermal stability. The molded articles of the present invention are free of undesired coloration and deposition of extraneous matter.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: October 23, 1990
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Takuji Hirahara, Takashi Nakamura, Yoshiko Kumeno, Takayuki Ohta, Tetsuo Kasai
  • Patent number: 4962141
    Abstract: Aqueous emulsions containing an ethylene-vinyl chloride (EVCl) copolymer and tetramethylol glycoluril are described for use as binder compositions suitable for application onto nonbonded filter paper. The emulsions are prepared by incorporating 4 to 10 wt % tetramethylol glycoluril, based on the total weight of the emulsion copolymer, into an aqueous disperson of a copolymer consisting essentially of 65 to 90 wt % vinyl chloride 5 to 35 wt % ethylene and optionally, up to 10 wt % of a hydroxyalkyl- or carboxylic acid-containing functional comonomer. The polymerization is conducted in the presence of a stabilizing system consisting essentially of 3 to 15 wt % polyvinyl alcohol. Filter paper impregnated with these emulsions maintain tensile strength and flexibility upon being subjected to hot oil.
    Type: Grant
    Filed: March 20, 1989
    Date of Patent: October 9, 1990
    Assignee: Air Products and Chemicals, Inc.
    Inventors: John G. Iacoviello, George Davidowich, Bheema R. Vijayendran, John S. Sadowski
  • Patent number: 4931220
    Abstract: Described is photochromic particulate material comprising a photochromic substance within a matrix of a polymerizate of a polyfunctional acrylate monomer. The photochromic particulate material may be produced by adding an organic photochromic substance to a polymerizable composition including a polyfunctional acrylate monomer and polymerizing the resultant admixture, e.g., by emulsion polymerization. In the case of emulsion or suspension polymerization, finely divided particulate organic photochromic materials are separated from the polymerization medium in the form of spheroidal thermoset photochromic particles of fairly uniform size. If desired, the particles recovered from the polymerization medium may be further ground in conventional attrition mills to further reduce the size of the particulate product. In the case of bulk polymerization, the polymerizate may be formed as a continuously cast sheet, which is then pulverized to a particulate material of pigmentary size.
    Type: Grant
    Filed: November 24, 1987
    Date of Patent: June 5, 1990
    Assignee: PPG Industries, Inc.
    Inventors: Ronald L. Haynes, Charles H. Hoelscher, Jonathan G. Lasch
  • Patent number: 4910287
    Abstract: The present disclosure is concerned with catalyzing the reactivity of carboxyl group bearing polyesters such as terephthalic acid, isophthalic acid, neophentyl glycol based polyesters which are suitable for use in powder coating formulations with epoxide compounds. An enhanced uniformity of catalysis is obtained without a degradation of color by adding 1-methyl imidazole to a liquid melt of the polyester. In a preferred embodiment between 0.03 and 0.3 weight percent of the 1-methyl imidazole is added to a molten polyester which has an acid number between 10 and 100, a 200.degree. C. I.C.I. cone and plate viscosity between 20 and 70 Poise, and a DSC determined glass transition temperature of at least about 40.degree. C. when the polyester is at a sufficiently elevated temperature to have I.C.I. plate and cone viscosity of less than about 70 Poise.
    Type: Grant
    Filed: January 6, 1989
    Date of Patent: March 20, 1990
    Assignee: Ruco Polymer Corporation
    Inventors: John J. McLafferty, Sue L. Wang
  • Patent number: 4892899
    Abstract: Composition of matter containing(a) a compound of the formula I ##STR1## in which A is one of the groups of the formulae ##STR2## in which B is --O--, --S--, --SO.sub.2 --, --N.dbd.N--, --CH.sub.2 --, --CH.dbd.CH--, ##STR3## --CONH--, --NHCONH--, or --CONHNHCO--, Q is --O-- or --NH-- and Z is --O-- or --S-- and R and R' are independently of each other hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or phenoxy, and(b) a compound of the formula II ##STR4## in which A' is as defined above for A, D is hydrogen, amino or a group of the formula III ##STR5## E is --O-- or --S--, T.sub.1, T.sub.2 and T.sub.3 independently of one another are chlorine or a group --ET', T' is a group of the formulae ##STR6## X.sup..sym. is H.sup..sym. or a group of the formulae M.sup.n.sym. /n or N.sup..beta. (R.sub.1)(R.sub.2)(R.sub.3)(R.sub.4), Mhu n.sym. is an n-valent metal cation, n is 1, 2 or 3, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently of one another hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.
    Type: Grant
    Filed: December 8, 1987
    Date of Patent: January 9, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Edward E. Jaffe, Jost von der Crone, Bernhard Medinger
  • Patent number: 4888368
    Abstract: This invention relates to a method and composition for inhibiting discoloration of the emulsions due to contact with ferrous materials. The invention comprises adding from 0.1 to 1.6 wt. %, preferably, from 0.3 to 0.9 wt. % based on the oil phase of the emulsion of one or more members of the group consisting of phosphoric acid and disodium phosphate. The invention also optionally comprises an amount of pit corrosion inhibitor selected from the group consisting of zinc pyrithione and a zinc containing siloxane resin. The invention also includes the composition of a silicone polymer in water emulsion, wherein the emulsion contains form 0.1 to 1.6 wt%, preferably, from 0.3 to 0.9 wt. % based on the oil phase of the emulsion of one or more mebers of the group consisting of phosphoric acid and disodium phosphate and optionally comprises an amount of pit corrosion inhibitor.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: December 19, 1989
    Assignee: Dow Corning Corporation
    Inventors: Gretchen S. Kohl, James McGee
  • Patent number: 4855093
    Abstract: A process for producing a diaphragm for a speaker of carbonaceous materials which includes the steps of mixing carbon powder in a binder mainly containing chlorine-containing vinyl resin to be carbonized after calcining, applying high shearing force to a mixture composition obtained by uniformly mixing and dispersing the resultant mixture to sufficiently knead the mixture, then preliminarily molding the resultant mixture in a sheet shape, molding the preliminarily molded sheet into a diaphragm, insolubilizing, infusibilizing the diaphragm and calcining the diaphragm in an inert atmosphere, wherein the mixture composition contains at least 0.1 to 5 percentage by weight of 1.8-diazobicyclo (5, 4, 0) undecene-7 or that in which its salt is chlorine-containing vinyl chloride.
    Type: Grant
    Filed: February 19, 1988
    Date of Patent: August 8, 1989
    Assignee: Mitsubishi Pencil Co., Ltd.
    Inventor: Mitsuru Yoshida
  • Patent number: 4841016
    Abstract: An additive composition for enhancing curing and color clarity properties of polyester resins. The additive comprises from about 50 to 75 parts by weight of a mercaptan, and from about 50 to about 25 parts by weight of a quaternary ammonium salt. From about 0.5 to about 25 parts by weight of a polymerization initiator can be incorporated into the additive when the polyester resin is utilized as a gel coat. Resinous compositions formulated with the additive consist essentially of from about 50 to about 99.5 parts by weight of a polyester resin, from about 0.5 to about 35 parts by weight of the mercaptan, from about 0.1 to about 15 parts by weight of the quaternary ammonium salt, and a minor effective amount of an oxidizing agent for the polyester resin.
    Type: Grant
    Filed: March 16, 1988
    Date of Patent: June 20, 1989
    Inventor: Bill R. Edwards
  • Patent number: 4826903
    Abstract: Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate (a) containing a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound or (b) having reacted therewith or copolymerized therein a styryl residue derived from a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound, having the formula ##STR1## wherein R.sup.4 and R.sup.5 represent the acyl radical and the other radicals are as defined in the specification.Preferred compositions comprise a linear polyester containing a styryl residue as an integral part of the polymer chain. The styryl residues absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.
    Type: Grant
    Filed: February 22, 1988
    Date of Patent: May 2, 1989
    Assignee: Eastman Kodak Company
    Inventors: Max A. Weaver, Samuel D. Hilbert, Wayne P. Pruett, Clarence A. Coates, Jr.
  • Patent number: 4822845
    Abstract: It now has been found that uncured rubber composition comprising rubbers having an unsaturated carbon chain and at least one carbon black can be improved by including therein, a minor property-improving amount of at least one aromatic heterocyclic di-N-oxide compound of the partial formula ##STR1## wherein the depicted carbon atoms are part of an optionally substituted aromatic ring, and R.sup.1 and R.sup.2 are each independently hydrogen, hydrocarbyl, halohydrocarbyl, hydrocarbyloxy, hydrocarbyl sulfonyl, hydrocarbyl thio, hydrocarbylsulfoxidyl, halogen, amino,--CN--OH--CHO--CH(O hydrocarbyl)2--C(O)R.sup.3--C(O)OR.sup.3--C(N--OH)R.sup.3--C(O)NR.sup.3 R.sup.6--CH.dbd.N--NH--C(O)OR.sup.3--CH.sub.2 OC(O)CH.sub.3--R.sup.4 YR.sup.3--C(O)NHR.sup.4 OH--C(NH)NR.sup.7 R.sup.8,or--C(O)NHN(R.sup.3).sub.2wherein each R.sup.3 is independently hydrogen or a hydrocarbyl group, R.sup.4 is a divalent hydrocarbyl group, R.sup.6 is hydrogen, hydrocarbyl, --R.sup.4 OR.sup.3, or --R.sup.4 COOR.sup.3 ; R.sup.
    Type: Grant
    Filed: April 13, 1987
    Date of Patent: April 18, 1989
    Assignee: The Firestone Tire & Rubber & Company
    Inventors: Daniel F. Graves, Hans-Wilhelm Engels
  • Patent number: 4808643
    Abstract: EPDM and/or EPR rubber/silicone compositions having improved thermal properties, well adapted for the production of a wide variety of useful shaped articles, e.g., automotive seals, gaskets and belts, include a 2-mercapto-benzimidazole or salt thereof, preferably the zinc salt, an antioxidant comprising a secondary amine function, a diorganopolysiloxane oil, appropriate filler material and a peroxide crosslinking catalyst.
    Type: Grant
    Filed: March 30, 1988
    Date of Patent: February 28, 1989
    Assignees: Rhone-Poulenc Chimie, Compagnie de Raffinage et de Distribution Total France
    Inventors: Guy Lemoine, Robert Lucas, Meyer Soria
  • Patent number: 4762870
    Abstract: It now has been found that the properties of rubber compositions comprising rubbers having an unsaturated carbon chain can be improved by including therein, a minor property-improving amount of at least one hydroxy-benzimidazole oxide compound of the formula ##STR1## wherein R is hydrogen, or a halogen, hydroxyl, lower acyl, lower hydrocarbyl, lower hydrocarbyloxy, lower hydrocarbylthio, carboxyl, cyano, amino, amide or --C(O)-- lower hydrocarbyl group, and R' is hydrogen, or a lower hydrocarbyl, lower hydrocarbyl amide, carboxamide carboxy acid, carboxy ester, or aryl group. When vulcanizates are prepared from such rubber compositions containing one or more fillers, the vulcanizates exhibit reduced low strain hysteresis and a high electrical resistivity.
    Type: Grant
    Filed: April 13, 1987
    Date of Patent: August 9, 1988
    Assignee: The Firestone Tire & Rubber Company
    Inventors: Daniel F. Graves, Hans-Wilhelm Engels
  • Patent number: 4761446
    Abstract: It now has been found that the properties of filled rubber compositions comprising rubbers having an unsaturated carbon chain can be improved by including therein, a minor property-improving amount of at least one 1,3-dihydroxy-benzimidazolinone or derivative compound of the formula ##STR1## wherein R is hydrogen, or a halogen, hydroxyl, lower hydrocarbyl, lower hydrocarbyloxy, lower hydrocarbylthio, lower hydrocarbyl nitrile, carboxyl, cyano, nitro, amino, amide or --C(O)--R'" where R'" is an aryl or a lower hydrocarbyl group; each R' independently is H, lower alkyl, acyl, CONR"2 or CONHR" where R" is alkyl or aryl. When vulcanizates are prepared from such uncured rubber compositions, the vulcanizates exhibit reduced low strain hysteresis and a high electrical resistivity.
    Type: Grant
    Filed: April 13, 1987
    Date of Patent: August 2, 1988
    Assignee: The Firestone Tire & Rubber Company
    Inventors: Daniel F. Graves, Hans-Wilhelm Engels
  • Patent number: 4740537
    Abstract: Disclosed is a composition that is polymerizable by contacting it with an olefin metathesis catalyst comprising dicyclopentadiene, red phosphorus, and a brominated aromatic compound selected from the group consisting of decabromodiphenyl oxide, N,N'-ethylene-bis-(tetrabromophthalimide), brominated polystyrene, brominated polyphenylene oxide, tetradecabromodiphenoxy benzene, tetrabromoxylene, and octabromodiphenyl oxide.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: April 26, 1988
    Assignee: Hercules Incorporated
    Inventor: Paul A. Silver
  • Patent number: 4740542
    Abstract: A method of stabilizing a polymer film coating or molded article against the action of light, moisture, and oxygen is disclosed. The method comprises incorporating in said polymer a stabilizingly and synergistically effective amount of:(A) A 2,2,6,6-tetraalkylpiperidine compound, or the acid addition salts or complexes with metal compounds thereof; and(B) A tris-aryl-s-triazine compound represented by the formula: ##STR1## wherein X, Y and Z are each aromatic, carbocylic radicals of less than three 6-membered rings, and at least one of X, Y and Z is substituted by a hydroxy group ortho to the point of attachment to the triazine ring; and each of R.sup.1 through R.sup.9 is selected from the group consisting of hydrogen, hydroxy, alkyl, alkoxy, sulfonic, carboxy, halo, haloalkyl and acylamino.
    Type: Grant
    Filed: August 11, 1986
    Date of Patent: April 26, 1988
    Assignee: American Cyanamid Company
    Inventor: Peter V. Susi
  • Patent number: 4719300
    Abstract: The novel colorants of the formula (I) ##STR1## where the rings A, B and C independently of one another are unsubstituted or substituted by groups which impart insolubility, possess high color strength, very good fastness to migration and excellent lightfastness and weatherfastness and are therefore very useful for pigmenting plastics and surface coatings.
    Type: Grant
    Filed: July 7, 1986
    Date of Patent: January 12, 1988
    Assignee: BASF Aktiengesellschaft
    Inventor: Wolfgang Lotsch
  • Patent number: 4670486
    Abstract: High molecular weight organic material is effectively colored by the incorporation therein of a copper or nickel complex of the ligand compound of formula I ##STR1## wherein A is an isocyclic or heterocyclic aromatic moiety, R is H, halogen, lower alkyl or alkoxy, R.sub.1 is H, lower alkyl, phenyl or substituted phenyl, and B is H, lower alkyl, ureido or substituted ureido, guanidino, anilino, benzamido or a heterocyclic aromatic moiety.
    Type: Grant
    Filed: June 13, 1985
    Date of Patent: June 2, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Georg Cseh, Paul Lienhard
  • Patent number: 4659775
    Abstract: The invention relates to a process for the preparation of pyrrolo[3,4-c]pyrroles of formula (1) ##STR1## wherein each of R.sub.1 and R.sub.2 independently of the other is an alkyl or aralkyl group or an isocyclic or heterocyclic aromatic radical, which process comprises reacting an ester of formula (2) or (3) ##STR2## with a nitrile of the formula R.sub.2 CN, in which formulae each of R and R' independently of the other is an alkyl or aryl group, and R.sub.1 and R.sub.2 are as defined above, in the presence of a strong base in an organic solvent.The invention also relates to compounds of formula (8) ##STR3## wherein R.sub.3 in an alkyl or aralkyl group or an ortho-substituted isocyclic or heterocyclic aromatic radical and R.sub.4 is an alkyl or aralkyl group or an isocyclic or heterocyclic aromatic radical.The pyrrolopyrroles obtained are valuable pigments for coloring compounds of high molecular weight such as plastics and lacquers in yellow to red shades of excellent fastness properties.
    Type: Grant
    Filed: November 1, 1985
    Date of Patent: April 21, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Johannes Pfenninger, Abul Iqbal, Alain C. Rochat, Olof Wallquist
  • Patent number: 4631302
    Abstract: A biocidal wax composition for preventing corrosion and biological fouling nd surface degradation of submerged structures comprises from about 10 to about 40 percent of total biocidal wax composition of a biocidal polymeric gel consisting of a polymer from the group consisting of a polyethylene, polypropylene, a copolymer of polyethylene and vinyl acetate, and mixtures thereof and a solvent selected from the group consisting of mineral oil, a paraffin wax and mixtures thereof, and a biocide; and from about 60 to about 90 percent of total biocidal wax composition of a wax matrix composition consisting of petrolatum, at least two chlorinated waxes, and a microcrystalline wax. The biocidal wax is prepared by shock-cooling a hot solution of a polymer through its cloud point, admixing a biocide with the gel, and admixing the above wax matrix composition with the gel.
    Type: Grant
    Filed: July 1, 1985
    Date of Patent: December 23, 1986
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Robert F. Supcoe, Thomas Radakovich
  • Patent number: 4619956
    Abstract: A method of stabilizing a polymer film coating or molded article against the action of light, moisture, and oxygen is disclosed. The method comprises incorporating in said polymer a stabilizingly and synergistically effective amount of:(A) A 2,2,6,6-tetraalkylpiperidine compound, or the acid addition salts or complexes with metal compounds thereof; and(B) A tris-aryl-s-triazine compound represented by the formula: ##STR1## wherein X, Y and Z are each aromatic, carbocylic radicals of less than three 6-membered rings, and at least one of X, Y and Z is substituted by a hydroxy group ortho to the point of attachment to the triazine ring; and each of R.sup.1 through R.sup.9 is selected from the group consisting of hydrogen, hydroxy, alkyl, alkoxy, sulfonic, carboxy, halo, haloalkyl and acylamino.
    Type: Grant
    Filed: May 3, 1985
    Date of Patent: October 28, 1986
    Assignee: American Cyanamid Co.
    Inventor: Peter V. Susi
  • Patent number: 4613636
    Abstract: A peroxide-curable fluoroelastomer composition which can be readily removed from a mold cavity without tearing which comprises a fluoroelastomer whose interpolymerized units consist essentially of units of tetrafluoroethylene, units of perfluoroalkyl perfluorovinyl ether, units of a bromine-containing olefin and, optionally, units of ethylene, and from about 0.05-2 parts per 100 parts fluoroelastomer of an N,N,N',N'-tetrasubstituted 1,8-diaminonaphthalene having the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently alkyl groups of 1-6 carbon atoms, phenyl or benzyl, R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 can be joined to form a 5- or 6-membered heterocyclic ring in which a carbon atom can be replaced by an oxygen or a sulfur atom, R.sub.1 and R.sub.3 and/or R.sub.2 and R.sub.
    Type: Grant
    Filed: July 12, 1985
    Date of Patent: September 23, 1986
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Leo Ojakaar
  • Patent number: 4609699
    Abstract: This invention relates to polyarylene sulphides (PPS) produced in known manner from optionally substituted halogen benzenes and aromatic polyhalogen compounds, optionally in combination with other polymers, fillers and/or reinforcing fibres, which contain certain N-containing organic bases for reducing the elimination levels of acidic, corrosion-producing volatile constituents and for improving the flow properties thereof.
    Type: Grant
    Filed: October 22, 1984
    Date of Patent: September 2, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf-Volker Meyer, Klaus Reinking, Karsten-Josef Idel, Rolf Dhein
  • Patent number: 4570690
    Abstract: Filled rubber vulcanizates containing aromatic furazan oxides exhibit many improved properties such as increased filler-rubber interaction and decreased hysteresis. Useful furazan oxides have both carbons of the furazan ring as part of a fused aromatic ring. Typical examples are benzofurazan oxide and its methyl and methoxy analogs. Tires made from the inventive vulcanizates show lower running temperatures and improved rolling resistance. The desirable effects of the aromatic furazan oxides may be improved by mixing the rubber, filler and furazan oxide in a conventional mechanical compounding device at specific temperatures and time periods such as about 200.degree.-400.degree. F. for 2-20 minutes.
    Type: Grant
    Filed: September 21, 1984
    Date of Patent: February 18, 1986
    Assignee: The Firestone Tire & Rubber Company
    Inventor: Daniel F. Graves
  • Patent number: 4564680
    Abstract: Isoindolazines which, in one of their tautomeric structures, have the formula ##STR1## where the rings designated X and T can be substituted andA.sup.1 and A.sup.2 represent the divalent radical of a compound having two replaceable hydrogen atoms on a C or N atom, in particular the divalent radical of an active methylene compound, of an amine, of a hydrazine, of a hydrazide or of a hydrazone,salts and complexes of these compounds, processes for their preparation, and their use as pigments.
    Type: Grant
    Filed: August 3, 1983
    Date of Patent: January 14, 1986
    Assignee: Bayer Aktiengesellschaft
    Inventors: Meinhard Rolf, Rutger Neeff, Walter Muller, Volker Hederich
  • Patent number: 4557306
    Abstract: Carbon black products useful in rubber compositions, and rubber compositions (uncured or cured) containing said carbon black products are described. The carbon black products of the invention comprise carbon black having a surface area of at least 20 m.sup.2 /g. and up to about 10% by weight, based on the weight of the carbon black of at least one aromatic furazan oxide. Useful furazan oxides have both carbons of the furazan ring as part of a fused aromatic ring, and particular examples include benzofurazan oxide, and its methyl and methoxy analogs. Improvements in the processability of uncured rubber compositions containing the carbon black products of the invention have been observed.Filled rubber vulcanizates containing the carbon black products of the invention exhibit many improved properties such as increased filler-rubber interaction and decreased hysteresis.
    Type: Grant
    Filed: June 18, 1984
    Date of Patent: December 10, 1985
    Assignee: The Firestone Tire & Rubber Company
    Inventor: Daniel F. Graves
  • Patent number: 4435532
    Abstract: Use of zinc salts of mercaptobenzimidazoles corresponding to the following general formula: ##STR1## wherein R represents hydrogen or a C.sub.1 -C.sub.4 alkyl group; and/or a zinc salt of a di-C.sub.1 -C.sub.9 -alkyldithiophosphate for the preparation of nitrile rubber/PVC mixtures.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: March 6, 1984
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Thormer, Hans H. Bertram, Otto Benn, Helmut Hurnik
  • Patent number: 4417013
    Abstract: A solid pigment composition comprises an intimate mixture of a pigment and a copolymer of an alkyl or cycloalkyl methacrylate ester and a lesser amount of an aminoalkyl methacrylate ester. The compositions are compatible with a wide range of substrates such as paints, printing inks and bulk polymers.
    Type: Grant
    Filed: January 18, 1982
    Date of Patent: November 22, 1983
    Assignee: Sandoz Ltd.
    Inventor: Johann Schuster
  • Patent number: 4415685
    Abstract: A process for dyeing high-molecular organic material in the bulk characterized by the use of a 1,4-diketo-pyrrolo[3,4-c]-pyrrole of the formula ##STR1## wherein R.sub.1 and R.sub.2 are isocyclic or heterocyclic aromatic radicals, preferably unsubstituted or substituted phenyl or naphthyl radicals.The dyeings obtained, for example in plastics, fibres, lacquers and printings, are distinguished by very high coloring strength, high saturation, good dispersibility, good fastness to cross-lacquering, migration, heat, light and weather, and also by a high gloss and a good IR-remission behavior.
    Type: Grant
    Filed: March 16, 1982
    Date of Patent: November 15, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Abul Iqbal, Luigi Cassar
  • Patent number: 4415684
    Abstract: Novel compositions which are highly stable and resistant to degradation by ultraviolet (UV) light are prepared by dispersing polysubstituted 1,5-diazacycloalkanes in the material subject to degradation, particularly in polyolefins. The cyclic compounds of this invention have (a) a fixed three-carbon bridge between the N.sup.1 and N.sup.5 atoms of the diaza ring, the remaining portion of the ring having a variable length bridge of two or more carbon atoms, (b) an N-adjacent carbon atom of the diaza ring is polysubstituted, that is, has two substituents which may be cyclizable. Monocyclic 1,5-diazacycloalkanes are prepared by reducing the corresponding 2-keto-1,5-diazacycloalkane with metal hydride; bicyclic 1,5-diazacycloalkanes, particularly fused ring bicyclic compounds such as substituted 1,5-decahydrobenzodiazepines are prepared by reaction of a diaminocycloalkane with an unsaturated ketone or acid and reducing with metal hydride.
    Type: Grant
    Filed: March 5, 1982
    Date of Patent: November 15, 1983
    Assignee: The B. F. Goodrich Company
    Inventors: John T. Lai, Pyong N. Son
  • Patent number: RE31986
    Abstract: A process for the manufacture of pigments of the formula ##STR1## where ##STR2## is a radical of barbituric acid or of one of its derivatives and ##STR3## is a divalent radical of benzene, 1,2- or 2,3-naphthalene, pyridine or pyrazine, which radical may be unsubstituted or substituted by halogen, alkyl of 1 to 10 carbon atoms, phenyl, carbamoyl, alkylcarbonylamino (where alkyl is of 1 to 17 carbon atoms), benzoylamino, alkoxy of 1 to 4 carbon atoms or phenoxy, the number of substituents being 1 or 2, by condensing amino-imino compounds or bis-imino compounds of the formula ##STR4## where R' and R" may be identical or different and are hydrogen, alkyl of 1 to 4 carbon atoms, hydroxyalkyl of 2 or 3 carbon atoms, phenylalkyl of 7 or 8 carbon atoms or phenyl, with barbituric acid or its derivatives, in the molar ratio of 1:2, in water in the presence of aliphatic carboxylic acids, aromatic carboxylic acids, aliphatic sulfonic acids, aromatic sulfonic acids, mineral acids or mixtures of these, at a pH of from 1 to
    Type: Grant
    Filed: May 2, 1980
    Date of Patent: September 17, 1985
    Assignee: BASF Aktiengesellschaft
    Inventor: Wolfgang Lotsch