Si-h Or Si-c Reactant Contains An Atom Other Than C, H, O, Or Si Bonded To A Carbon Atom Patents (Class 525/102)
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Publication number: 20110284465Abstract: The current invention provides compositions, which are useful as stationary phases for a variety of chromatographic applications, such as high performance liquid chromatography (HPLC) and solid-phase extraction (SPE). The compositions provide both strong aromatic and hydrophobic interactions with components of a sample. Moreover, the invention provides compositions of new silanes, their immobilization on a solid substrate, such as silica, to form new stationary phases.Type: ApplicationFiled: May 19, 2011Publication date: November 24, 2011Applicant: Dionex CorporationInventors: Xiaodong Liu, Jinhua Chen, Christopher A. Pohl
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Publication number: 20110275756Abstract: A conjugated diene polymer obtained by reacting one end of a conjugated diene polymer having a monomer unit based on a conjugated diene and a monomer unit based on a compound represented by Formula (1) with a compound represented by Formula (2): wherein R11 to R14, R21 to R25, m and n are as defined in the specification.Type: ApplicationFiled: April 27, 2011Publication date: November 10, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Mana ITO, Katsunari INAGAKI
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Publication number: 20110275755Abstract: A conjugated diene polymer obtained by reacting one end of a conjugated diene polymer having a monomer unit based on a conjugated diene and a monomer unit based on a compound represented by Formula (1) with a compound represented by Formula (2) wherein the content of the monomer unit based on the compound represented by Formula (1) is 0.01 to 20% by weight relative to 100% by weight of the total amount of the monomer unit in the conjugated diene polymer: wherein R11, R12, R21-R25, A, m and n are as defined in the specification.Type: ApplicationFiled: April 27, 2011Publication date: November 10, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Mayumi OSHIMA, Mana ITO, Katsunari INAGAKI
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Publication number: 20110262672Abstract: There is provided a silicone-polyoxamide process additive for use in high clarity applications, articles made using the silicone-polyoxamide process additive, and methods for making these articles.Type: ApplicationFiled: November 20, 2009Publication date: October 27, 2011Inventors: Claude Lavallee, Audrey A. Sherman
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Patent number: 8039545Abstract: A functionalized polymer includes a polymer chain and a terminal group linked to the chain through a functionality that contains one or more urethane groups. The functionalized polymer can be provided by reacting a nucleophile with a polymer having terminal iso(thio)cyanate functionality which, in turn, can be provided by reacting a terminally active polymer with a polyiso(thio)cyanate. Even polymers that contain substantial amounts of styrene mer can be used in the described process.Type: GrantFiled: October 20, 2008Date of Patent: October 18, 2011Assignee: Bridgestone CorporationInventor: Yuan-Yong Yan
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Publication number: 20110244226Abstract: Blended release materials including a blend of a fluoro-functional silicone release polymer and a fluoropolymer are described. Exemplary fluoropolymers include fluoroolefin-based polymers and linear fluoropolymers including linear fluoroacryaltes. Articles including such release materials such as release liners, and adhesive articles, including silicone adhesive articles, are also described.Type: ApplicationFiled: December 14, 2009Publication date: October 6, 2011Inventors: Jayshree Seth, Zai-Ming Qiu, Marie A. Boulos, Michael A. Semonick, Ramesh C. Kumar
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Publication number: 20110243874Abstract: The present application relates to care agents, for example care polymers, and compositions such as consumer products comprising such care agents, as well as processes for making and using such care agents and such compositions. The performance of the care polymers that Applicants teach, can be further increased by following the emulsification teaching of the present specification and/or combining such care polymers with silicone materials.Type: ApplicationFiled: April 1, 2011Publication date: October 6, 2011Inventors: Rajan Keshav Panandiker, Luke Andrew Zannoni, Steven Daryl Smith, Robert Joseph McChain, Julie Ann Menkhaus
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Patent number: 8030430Abstract: A chemical composition comprises one or more urethane oligomers of at least two polymerized units selected from the group consisting of fluorine-containing urethane oligomers and long-chain hydrocarbon-containing urethane oligomers, wherein said oligomers comprise the reaction product of (a) one or more polyfunctional isocyanate compounds, (b) one or more polyols, (c) one or more monoalcohols selected from the group consisting of fluorocarbon monoalcohols, optionally substituted long-chain hydrocarbon monoalcohols, and mixtures thereof, (d) one or more silanes, and (e) one or more stabilizers comprising one or more reactive groups.Type: GrantFiled: October 1, 2004Date of Patent: October 4, 2011Assignee: 3M Innovative Properties CompanyInventors: Wayne W. Fan, Nathaniel P. Langford, Richard M. Fischer, Jr., Amy S. Barnes
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Patent number: 8022149Abstract: The present invention provides a solution to a problem that a composition including a reactive silicon group-containing polyether undergoes red coloration. More specifically, in a reactive silicon group-containing organic polymer which contains Co, the problem concerned is solved by limiting the Co content to 0.5 ppm or less. As the reactive silicon group-containing organic polymer, for example, a reactive silicon group-containing polyether (A) or a mixture of the reactive silicon group-containing polyether (A) and a vinyl polymer (B) may be cited. The reactive silicon group-containing polyether (A) is obtained, for example, by reacting a polyether or a derivative thereof which contains Co in a content of 0.5 ppm or less with a silane compound which has a group capable of reacting with the polyether or the derivative thereof and has a hydrolyzable group.Type: GrantFiled: April 23, 2004Date of Patent: September 20, 2011Assignee: Kaneka CorporationInventors: Kazuhiko Ueda, Jun Hattori, Shintaro Komitsu
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Publication number: 20110207886Abstract: Method for efficiently producing ?-hetero-substituted alkylhalohydrosilane, and use thereof. A method for producing (A) a halohydrosilane compound represented by the general formula (1): H—SiR2c(CR13-bYb)aX3-a-c (1) (wherein, R1 represents a hydrogen atom or a substituted or unsubstituted hydrocarbon group; R2 represents a substituted or unsubstituted hydrocarbon group; X represents a halogen atom; Y represents a hetero substituent; a is 1 or 2; b is any one of 1, 2 and 3; c is 1 or 0), by allowing (B) a halosilane compound represented by the general formula (2): SiR2c(CR13-bYb)aX4-a-c (2) (wherein, R1, R2, X, Y, a, b and c are as defined above) to react with (C) a hydrosilane compound. A method for producing a reactive silicon group-containing polymer using the halohydrosilane compound (A).Type: ApplicationFiled: January 9, 2011Publication date: August 25, 2011Applicant: Kaneka CorporationInventors: Katsuyu Wakabayashi, Hidenori Tanaka
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Publication number: 20110201727Abstract: The invention relates to silane modified additives obtained by condensation of one or a plurality of silanes of the general formula (RO)3-nR1nSi(R2X)(1), wherein R is an optionally substituted alkyle, aryle or alkoxyalkyl radical with 1 to 10 carbon atoms or hydrogen, R1 an optionally substituted hydrocarbon radical with 1 to 12 carbon atoms or hydrogen, R2 an optionally substituted alkylene radical with 1 to 20 carbon atoms, wherein methylene units that are not adjacent to one another can be substituted by groups —O—, and X is bound to R2 via a covalent bond and stands for an amino radical NHR3, an epoxy radical CR4(O)CR5R6, an urethane radical NR3—C(?O)OR3, an urea radical NR3—C(?O)NR3R4, a phosphorous acid radical P(?O)(OH)2, an anhydride radical C(?O)O(O?)CR3 or a carbon acid radical, wherein R3 is hydrogen or an optionally substituted alkyle, aryle or amino alkyle radical with 1 to 10 carbon atoms, R4, R5, R6 hydrogen or an optionally substituted alkyle or aryle radical with 1 to 10 carbon atoms, whereinType: ApplicationFiled: August 11, 2008Publication date: August 18, 2011Inventors: Abdulmajid Hashemzadeh, Marion Killat
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Patent number: 7989074Abstract: A polymeric material may be prepared by reacting a mixture comprising an amino functional polyorganosiloxane, polyisocyanate, and polyol. The polyol may comprise a hydroxy-functional poly(meth)acrylate. The polymeric material may be used as a coating for a substrate and may inhibit fouling on a surface exposed to aquatic conditions.Type: GrantFiled: June 6, 2007Date of Patent: August 2, 2011Assignee: NDSU Research FoundationInventors: Dean C. Webster, Robert J. Pieper, Abdullah Ekin
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Patent number: 7981966Abstract: There is obtained a rubber composition excellent in processability of unvulcanized compounded rubber, excellent in wear resistance and wet skid resistance of vulcanized rubber, low in rolling resistance, and suitable for tire applications, particularly for tire tread applications in which importance is given to low fuel consumption and safety. A rubber composition mainly comprising (I) 0.5 to 35% by weight of a conjugated diene-based (co)polymer rubber having an amino group and an alkoxysilyl group on a polymer chain and having a weight average molecular weight of 1,000 to 90,000, and (II) 99.5 to 65% by weight of a conjugated diene-based (co)polymer rubber having a weight average molecular weight of 100,000 to 2,000,000 (with the proviso that (I)+(II)=100% by weight).Type: GrantFiled: March 2, 2005Date of Patent: July 19, 2011Assignee: JSR CorporationInventors: Naokazu Kobayashi, Kouta Taniguchi, Toshihiro Tadaki
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Publication number: 20110172364Abstract: A core-first method is provided for making a core-shell nanoparticle that includes the following steps: adding to a solvent, a mono-vinyl monomer cross-linked with a cross-linking agent to form the core of the nanoparticle, the core having an average diameter of 5 nanometers to about 10,000 nanometers, and the core having polymer chains with living ends; adding a charge agent comprising a fixed formal charge group onto the living ends of the core to form the shell of the nanoparticle; controlling the charge of the nanoparticle based on the type of charge agent, the quantity of the charge agent, or both the type of charge agent and the quantity of the charge agent. A core-shell nanoparticle is also provided.Type: ApplicationFiled: December 28, 2010Publication date: July 14, 2011Inventors: Chen Yaohong, Masahiro Homma, Hideki Kitano
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Publication number: 20110172344Abstract: There is provided a modified conjugated diene-based polymer having a silyl group substituted with one or more alkoxy groups, and one or more nitrogen atoms on the chain ends of a conjugated diene-based polymer, the modified conjugated diene-based polymer being obtained by polymerizing a conjugated diene compound, or copolymerizing a conjugated diene compound with an aromatic vinyl compound, by using a polyfunctional anionic polymerization initiator prepared from a polyvinyl aromatic compound and an organolithium compound in a range of a molar ratio (the polyvinyl aromatic compound/the organolithium compound) of from 0.05 to 1.0, so as to obtain the conjugated diene-based polymer, and by reacting a living polymer end of the conjugated diene polymer with the compound having a silyl group substituted with two or more alkoxy groups, and one or more nitrogen atoms.Type: ApplicationFiled: October 13, 2009Publication date: July 14, 2011Applicant: ASAHI KASEI CHEMICALS CORPORATIONInventors: Junichi Yoshida, Shinichi Sekikawa, Ryoko Fukuoka
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Publication number: 20110165425Abstract: The present invention provides: an interlayer film for laminated glass having high adhesiveness to components for laminated glass such as a PET film and having high transparency; and a laminated glass comprising the interlayer film for laminated glass. An interlayer film 2 for laminated glass comprises a resin including an ethylene structural unit, a (meth)acrylate ester structural unit, and a structural unit having a glycidyl group. A laminated glass 1 comprises: a first and a second component 3, 4 for laminated glass; and an interlayer film 2 for laminated glass interposed between the first and the second component 3, 4 for laminated glass.Type: ApplicationFiled: February 3, 2010Publication date: July 7, 2011Inventors: Takahiro Futamura, Izumi Oomoto
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Publication number: 20110146877Abstract: The invention provides a method for producing a modified conjugated diene (co)polymer, the method including comprising: a modification reaction step including causing an organic silane compound to react with a conjugated diene (co)polymer having an active site at the active site, the organic silane compound having a characteristic group for forming a silanol group through hydrolysis and, in the vicinity of the characteristic group, (i) a functional group which binds the organic silane compound to the conjugated diene (co)polymer via addition to or substitution at the active site and which promotes reaction between the silanol group and a reinforcing filler after the addition or substitution reaction, or (ii) a functional group which promotes reaction between the silanol group and a reinforcing filler, and a hydrolyzation step performed after the modification reaction step; a modified conjugated diene (co)polymer having, at a molecular end of the conjugated diene (co)polymer, a silanol group, and a functionalType: ApplicationFiled: March 10, 2009Publication date: June 23, 2011Applicant: BRIDGESTONE CORPORATIONInventors: Ken Tanaka, Noriko Mori, Yuki Itoh, Yoichi Ozawa, Ryuji Nakagawa, Junko Matsushita, Shigeaki Matsuo, Kouji Masaki, Fumihiro Shiraishi, Fuminori Oota
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Publication number: 20110152458Abstract: A subject-matter of the present invention is a rubber composition intended for the manufacture of tyres or of tyre semi-finished products, based on at least one isoprene elastomer, an inorganic filler as reinforcing filler and a polyfunctional organosiloxane coupling agent capable of providing the bonding between the reinforcing inorganic filler and the isoprene elastomer, comprising per molecule, grafted to its silicon atoms, on the one hand at least one hydroxyl or hydrolysable functional group allowing it to be grafted to the reinforcing inorganic filler and, on the other hand, at least one group bearing at least one azodicarbonyl functional group —CO—N?N—CO— allowing it to be grafted to the isoprene elastomer.Type: ApplicationFiled: March 2, 2011Publication date: June 23, 2011Applicant: Michelin Recherche et Technique S.A.Inventors: Jose Carlos ARAUJO DA SILVA, Karine LONGCHAMBON, Sebastien STERIN
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Golf ball compositions having in-situ or reactive impact modified silicone-urea or silicone urethane
Patent number: 7951870Abstract: Modified silicone urea and modified silicone urethane polymers for use in golf equipment components to provide improved impact resistance upon contact with a golf club including reactive polymer alloys formed in situ from silicone-ureas and/or silicone-urethanes and impact resistant polymers and oligomers.Type: GrantFiled: November 15, 2006Date of Patent: May 31, 2011Assignee: Acushnet CompanyInventors: Murali Rajagopalan, Kevin M. Harris -
Patent number: 7943698Abstract: An ambient temperature curing coating composition comprising the crosslinked reaction product of: (a) an amino-functional compound, wherein the amino-functional compound is a bis-silylamine of general formula: (R2)b(R1Y)aSi-Q1-NH-Q2-(NH-Q3)n-Si(YR1)a(R2)b n?0 a=3?b b=0,1,2 each Y is independently a heteroatom, selected from O, N; if Y is N, then the valency of Y is 2; if Y is O, then the valency of Y is 1; each R1 is independently a monovalent radical (e.g., hydrogen, hydrocarbon including but not limited to alkyl (linear or branched), cycloalkyl, aryl, allyl, or aralkyl. Preferably, R1 is an alkyl of 1-10 carbon atoms. Each R1 may be the same or different; R2 is a monovalent radical, and can include heteroatoms (e.g., oxygen, nitrogen, sulfur) not directly bonded to the silicon atom, including but not limited to, alkyl (linear or branched), cycloalkyl, aryl, allyl, or aralkyl. Each R2 may be the same or different.Type: GrantFiled: December 11, 2008Date of Patent: May 17, 2011Assignee: The Sherwin-Williams CompanyInventors: Richard F. Tomko, Wai-Kwong Ho
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Publication number: 20110077325Abstract: A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing monomer with a coordination catalyst to form a reactive polymer; and (ii) reacting the reactive polymer with a carboxylic or thiocarboxylic ester containing a silylated amino group.Type: ApplicationFiled: September 30, 2009Publication date: March 31, 2011Applicant: Bridgestone CorporationInventor: Steven Luo
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Publication number: 20110052912Abstract: The invention relates to an adhesive composition that can be cross-linked by heating, said composition comprising between 20 and 85% of a polyurethane comprising 2 terminal groups of the hydrolysable alkoxysilane type of formula (I): wherein: R1 is a hydrocarbonated radical comprising between 5 and 15 carbon atoms; R2 is an alkylene radical comprising between 1 and 4 carbon atoms; R3 is an alkylene radical comprising between 1 and 3 carbon atoms; R4 and R5 are each an alkyl radical comprising between 1 and 4 carbon atoms; n is a whole number such that the average molar mass of the polyether block of formula —[OR2]n- is between 300 Da and 30 kDa; in is a whole number such that the average molar mass of the polymer of formula (I) is between 600 Da and 60 kDa; and p is a whole number equal to 0, 1 or 2. The composition also comprises between 15 and 80% of a compatible tackifying resin; and between 0.01 and 3% of a cross-linking catalyst.Type: ApplicationFiled: December 15, 2008Publication date: March 3, 2011Applicant: BODTIK SAInventors: Sylwia Poivet, David Goubard
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Publication number: 20110034602Abstract: The present invention relates to reactive compositions which at least one compound A having at least two reactive groups which are selected from the group comprising isocyanate, epoxide, alkoxysilane, and mixtures thereof and also at least one polymeric thixotropic agent B prepared by homopolymerizing a (meth)acrylate B1 or by copolymerizing a (meth)acrylate B1 with at least one further (meth)acrylate, the (meth)acrylate mixture possessing an average (meth)acrylate functionality ƒ of 2.5 to 4.5. The (meth)acrylate B1 here contains three or more (meth)acrylate groups. The invention additionally discloses the use of the compound B as a thixotropic agent.Type: ApplicationFiled: October 12, 2010Publication date: February 10, 2011Applicant: Sika Technology AGInventor: David Tobler
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Publication number: 20110009565Abstract: Disclosed herein are metal-terpyridine complexes and their use in hydrosilylation reactions.Type: ApplicationFiled: July 8, 2010Publication date: January 13, 2011Inventors: Johannes G.P. Delis, Paul J. Chirik, Aaron M. Tondreau
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Publication number: 20100311899Abstract: A functionalized polymer includes a polymer chain and a terminal functionality that includes at least one disilylamino group. The polymer can be the reaction product of a terminally active polymer chain and a compound that includes at least one disilylamino group and a group capable of reacting with terminally active polymers. Methods for making and using such polymers also are provided, as are compositions containing the polymer and one or more types of filler particles as well as vulcanizates provided from such compositions.Type: ApplicationFiled: December 26, 2008Publication date: December 9, 2010Applicant: BRIDGESTONE CORPORATIONInventors: Steven Luo, Dennis R. Brumbaugh, Michael W. Hayes, Yoichi Ozawa, Jason T. Poulton
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Publication number: 20100297368Abstract: The present invention relates to an acrylic pressure-sensitive adhesive composition, a polarizing plate and a liquid crystal display device, using the same. More specifically, the present invention relates to an acrylic pressure-sensitive adhesive composition having optimal stress releasing property which comprises an optically compensated acrylic copolymer (A) containing a cross-linkable functional group, an optically compensated acrylic copolymer (B) containing no cross-linkable functional group, and a multi-functional cross-linking agent (C). A polarizing plate and a liquid crystal display device comprising the pressure-sensitive adhesive composition meets with major properties such as adhesion endurance reliability, with effectively providing optical compensation effect and stress release effect, and has an effect of improving a light leakage phenomenon.Type: ApplicationFiled: October 22, 2007Publication date: November 25, 2010Applicant: LG CHEM LTD.Inventors: Seung Park, No Ma Kim, In Cheon Han, Kee Young Kim, Jeong Min Ha
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Publication number: 20100298465Abstract: A functionalized polymer defined by the formula ?-R1-?, where ? is a polymer chain, R1 is a bond or a divalent organic group, and ? is a sulfur-containing heterocycle.Type: ApplicationFiled: May 24, 2010Publication date: November 25, 2010Inventors: Terrence E. Hogan, Christine Rademacher, William Hergenrother, David F. Lawson
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Patent number: 7781525Abstract: A curable composition, which comprises: (A) an organic polymer having a reactive silicon-containing group, (B) a carboxylic acid and/or a metal salt of a carboxylic acid, (C) an amine compound having no reactive silicon group, (D) a silane compound substituted with an amino group and (E) a silane compound substituted with an epoxy group, wherein the ratio of the molar number (d) of all amino groups of the silane compound substituted with an amino group (D) contained in the composition to the molar number (e) of all epoxy groups of a silane compound substituted with an amino group (E) contained in the composition (i.e., the ratio of (d)/(e))) is 1 or more, and further the total amount of the component (D) and the component (E) with respect to 100 g of the component (A) is 30 mmol or more.Type: GrantFiled: December 20, 2005Date of Patent: August 24, 2010Assignee: Kaneka CorporationInventors: Ayako Yano, Toshihiko Okamoto
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Patent number: 7772320Abstract: A thermosetting coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material of (A1) from 0% to 50% by weight, based on the entirety of components (A1) and (A2), of a polymethacrylate copolymer containing more than 50% by weight, based on the entirety of comonomers in the copolymer (A1), of free-radically polymerizable, ethylenically unsaturated compounds (a1) containing at least one reactive group of the formula I —X—SiR?x(OR?)3-x??(I) and (A2) from 50% to 100% by weight, based on the entirety of components (A1) and (A2), of an adduct of polyisocyanate and alkoxysilane, (A2) containing at least one reactive group of the formula II: —NR—C(O)—N—(X—SiR?x(OR?)3-x)n(X?—SiR?y(OR?)3-y)m??(II) (B) a catalyst for the crosslinking of the —Si(OR?)3-x units, and (C) an aprotic solvent or a mixture of aprotic solvents.Type: GrantFiled: September 3, 2005Date of Patent: August 10, 2010Assignee: BASF CorporationInventors: Andreas Poppe, Guenter Klein, Andre Brosseit, Karin Wermelt, Martina Mollers
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Publication number: 20100163809Abstract: Branched polydiorganosiloxane polyamide, block copolymers and methods of making the copolymers are provided. The method of making the copolymers involves reacting one or more amine compounds including at least one polyamine with a precursor having at least one polydiorganosiloxane segment and at least two ester groups.Type: ApplicationFiled: March 4, 2010Publication date: July 1, 2010Inventors: Audrey A. Sherman, David B. Olson, Stephen A. Johnson, Craig E. Hamer, David S. Hays, Richard G. Hansen
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Publication number: 20100130686Abstract: It is intended to provide a conjugated diene polymer, a process for producing the conjugated diene polymer, a conjugated diene polymer composition and a process for producing the conjugated diene polymer composition. The conjugated diene polymer is a conjugated diene polymer having a conjugated diene-based monomer unit and a group represented by the formula (I), wherein assuming the whole area of the molecular weight distribution curve obtained by gel permeation chromatography as 100%, the peak area of the molecular weight peak at the lowest molecular weight is 50% or more. [In the formula, R1 and R2 each independently represent a hydrocarbon group, a hydrocarbon oxy group or a hydroxyl group, m represents an integer of 0 to 10, and A1 represents a polar functional group free of an active hydrogen atom.Type: ApplicationFiled: September 15, 2006Publication date: May 27, 2010Applicant: Sumitomo Chemical Company, LimitedInventor: Mayumi Oshima
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Publication number: 20100130664Abstract: The invention includes terminating compounds, polymers, rubber compositions and tires. The terminating compounds can provide terminating groups on the polymer. Polymers can be homopolymers, copolymers and terpolymers, and can include repeat units provided from conjugated diene monomers. Rubber compositions can be made from the polymers, and tires and various parts of tires can be made from those rubber compositions.Type: ApplicationFiled: November 24, 2008Publication date: May 27, 2010Applicant: The Goodyear Tire & Rubber CompanyInventors: Michael Joseph Rachita, Joseph John Kulig, Robert Alan Woloszynek
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Patent number: 7709574Abstract: The present invention is generally directed to methods of making ceramics with nanoscale/microscale structure involving self-assembly of precursor materials such as, but not limited to, inorganic-based block co-polymers, inorganic-/organic-based hybrid block co-polymers, and other similar materials, and to the structures made by such methods. Where such precursor materials are themselves novel, the present invention is also generally directed to those materials and their synthesis.Type: GrantFiled: July 18, 2006Date of Patent: May 4, 2010Assignee: General Electric CompanyInventors: Julin Wan, Patrick Roland Lucien Malenfant, Mohan Manoharan
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Publication number: 20100068534Abstract: Articles prepared with a pressure sensitive adhesive prepared by combining an acrylic polymer and a silane-functional polymer, such as glass and plastic laminates, show improved impact resistance.Type: ApplicationFiled: September 16, 2008Publication date: March 18, 2010Inventors: Charles W. Paul, Wu Suen
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Publication number: 20100060829Abstract: Organosilicon compounds are represented by the following formula: wherein R is a hydrolyzable group, R? is an alkyl having 1 to 4 carbon atoms, A is an alkylene having 1 to 6 carbon atoms, X is O or S, Y is —NH— or S, L1 and L2 are C or N, Z and M are —NH—, O or S, R1 to R11 are H, alkyl having 1 to 6 carbon atoms, alkoxy or fluoroalkyl, or amino, m is 1 to 3, and n is 0 to 3. R1 and R2 or R2 and R3 may bonded together. R5 and R6 or R9 and R10 may directly bond together. R4 and R7 or R8 and R11 may form a ring skeleton. Their production processes, pressure-sensitive adhesive compositions, self-adhesive polarizers and LCDs are also disclosed.Type: ApplicationFiled: September 3, 2009Publication date: March 11, 2010Applicant: Shin-Etsu Chemical Co., Ltd.Inventor: Kazuhiro Tsuchida
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Patent number: 7674858Abstract: The present invention provides a graft or a block polymer in which a fluorine rubber and a silicone rubber are chemically bonded. The present invention is a graft or a block polymer comprising at least one kind of a silicone rubber segment and at least one kind of a fluorine elastomer segment. Furthermore, it is preferable that a fluorine containing elastomer segment is an elastomer segment comprising vinylidene fluoride or an elastomer segment comprising tetrafluoroethylene and that a silicone rubber segment has a unit of dimethylsiloxane and/or methyl-3,3,3-trifluoropropylsiloxane.Type: GrantFiled: June 10, 2004Date of Patent: March 9, 2010Assignee: Daikin Industries, Ltd.Inventors: Tatsuya Morikawa, Mitsuru Kishine
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Patent number: 7671136Abstract: A functionalized polymer prepared by a process comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, the polymer having greater than about 85 percent in the 1,4-cis microstructure and less than about 3 percent in the 1,2- or 3,4-microstructure, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) or (II): where Z is a substituent that will react or interact with organic or inorganic fillers; with the proviso that each group attached to the imino carbon is attached via a carbon atom and R1, R2, R3, R4, R5, R13, R14 and Z are substituents that will not protonate a pseudo-living polymer.Type: GrantFiled: October 5, 2005Date of Patent: March 2, 2010Assignee: Bridgestone CorporationInventors: Yoichi Ozawa, H. Jerrold Miller, Koji Masaki
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Publication number: 20100048806Abstract: A process for producing a modified polymer rubber comprising the steps of: (1) polymerizing a conjugated diene monomer or a combination thereof with an aromatic vinyl monomer in a hydrocarbon solvent, in the presence of an alkali metal catalyst or a specified alkali metal compound, to form an alkali metal end-carrying active polymer, and (2) reacting the alkali metal end-carrying active polymer with a specified isocyanurate compound or a combination thereof with a specified coupling agent in a hydrocarbon solvent.Type: ApplicationFiled: October 29, 2009Publication date: February 25, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Katsunari INAGAKI, Seiichi MABE, Mayumi OSHIMA
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Publication number: 20090326151Abstract: Provided is a hair cosmetic that can exhibit hair styling capability, natural finishing capability, and hair style retentivity respectively at superior levels. The hair cosmetic contains a urethane-modified acrylic polymer having a structure in which a urethane polymer chain is bonded to an acrylic polymer chain through a linkage segment having a silicon-oxygen bond, in which the acrylic polymer chain is a residue of an acrylic polymer derived at least from an acrylic monomer (A) and a compound (B1) and/or a compound (B2), where the compound (B1) has a hydrolyzable silicon-containing group and an ethylenically unsaturated bond-containing group, and the compound (B2) has a hydrolyzable silicon-containing group and a mercapto group, and the urethane polymer chain is a residue of a urethane polymer (C) having a hydrolyzable silicon-containing group. The linkage segment in the urethane-modified acrylic polymer is preferably a silicone polymer chain.Type: ApplicationFiled: June 29, 2007Publication date: December 31, 2009Applicant: Konishi Co., Ltd.Inventors: Hideki Shimizu, Tomoko Watanabe, Tomoyuki Kawasoe, Taizo Fujiyama, Toshiki Origuchi, Shintaro Ogawa, Yoshitaka Nakayama
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Patent number: 7625981Abstract: A process for producing a modified polymer rubber comprising the steps of: (1) polymerizing a conjugated diene monomer or a combination thereof with an aromatic vinyl monomer in a hydrocarbon solvent, in the presence of an alkali metal catalyst or a specified alkali metal compound, to form an alkali metal end-carrying active polymer, and (2) reacting the alkali metal end-carrying active polymer with a specified isocyanurate compound or a combination thereof with a specified coupling agent in a hydrocarbon solvent.Type: GrantFiled: April 20, 2005Date of Patent: December 1, 2009Assignee: Sumitomo Chemical Company, LimitedInventors: Katsunari Inagaki, Seiichi Mabe, Mayumi Oshima
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Publication number: 20090275702Abstract: A moisture curable polymer and a curable composition having superior curability are provided. A polymer having a silicon group represented by the general formula: —SiFaR1bZc (wherein, R1 represents any one of a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, or an organosiloxy group represented by R23SiO— (R2 is each independently, a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms). Z is a hydroxyl group or a hydrolyzable group other than fluorine. a is any one of 1, 2, or 3; b is any one of 0, 1, or 2; c is any one of 0, 1, or 2; and a+b+c is 3. When b or c is 2, two R1 or two Z may be each the same or different) and a curable composition including this polymer, and a sealant and an adhesive in which the curable composition is used.Type: ApplicationFiled: August 23, 2007Publication date: November 5, 2009Applicant: KANEKA CORPORATIONInventors: Katsuyu Wakabayashi, Taisuke Sasaki
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Patent number: 7585570Abstract: To provide an adhesive comprising an acrylic resin (1), an acrylic resin (2), a silicone oligomer (3) and a crosslinking agent (4): wherein the acrylic resin (1) comprises a structural unit (a) derived from a monomer (A) and a structural unit (b) derived from a monomer (B) and has a weight-average molecular weight of 1,000,000 to 2,000,000, wherein the (A) is a (meth)acrylic ester represented by the formula (A) (wherein R1 represents hydrogen atom or methyl group, and R2 represents alkyl or aralkyl groups having 1 to 14 carbon atoms wherein hydrogen atom(s) of the R2 may be substituted with alkoxy group having 1 to 10 carbon atoms), and the (B) is at least any one of a (B-1) and a (B-2) wherein the (B-1) is a monomer comprising carboxyl group and one olefinic double bond, and the (B-2) is a monomer comprising at least one polar functional group selected from the group consisted of hydroxyl group, amide group, amino group, epoxy group, oxetanyl group, aldehyde group and isocyanate group and an olefType: GrantFiled: April 11, 2006Date of Patent: September 8, 2009Assignee: Sumitomo Chemical Company, LimitedInventors: Ryu Takeko, Atsushi Higo, Akira Kawamura
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Publication number: 20090221751Abstract: Rubber mixtures, including at least one rubber, a filler, an organosilicon compound of the formula I one rubber accelerator and one co-accelerator. The rubber mixtures are prepared by mixing at least one rubber, a filler, an organosilicon compound of the formula I, one rubber accelerator and one co-accelerator. The rubber mixtures can be used for production of mouldings. Also disclosed is a process for preparation of the organosilicon compound of the formula I via transesterification.Type: ApplicationFiled: January 9, 2007Publication date: September 3, 2009Applicant: EVONIK DEGUSSA GMBHInventors: Andre Hasse, Karsten Korth, Ingo Kiefer, Susann Witzsche, Philipp Albert, Oliver Klockmann
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Publication number: 20090196911Abstract: A silicone acrylate hybrid composition includes the reaction product of a silicon-containing pressure sensitive adhesive composition, an ethylenically unsaturated monomer, and an initiator. The silicon-containing pressure sensitive adhesive composition includes acrylate or methacrylate functionality. A method of making the hybrid composition includes polymerizing the ethylenically unsaturated monomer and the silicon-containing pressure sensitive adhesive composition in the presence of the initiator.Type: ApplicationFiled: June 6, 2007Publication date: August 6, 2009Inventors: Gary L. Loubert, Timothy Mitchell, Xavier Jean-Paul Thomas
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Patent number: 7560168Abstract: A gas barrier laminate film comprising a resin substrate on which a gas barrier vapor deposition layer, and a gas barrier covering layer are laminated, wherein the gas barrier covering layer is formed through the coating, and drying of a coating liquid comprising Si(OR1)4 or the hydrolyzates thereof, (R2Si(OR3)3)n or the hydrolyzates thereof (wherein R1 and R3 are individually CH3, C2H5 or C2H4OCH3, and R2 is an organic functional group) and a water-soluble polymer having a hydroxyl group.Type: GrantFiled: May 19, 2005Date of Patent: July 14, 2009Assignee: Toppan Printing Co., Ltd.Inventors: Tsukasa Tanaka, Noboru Sasaki
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Publication number: 20090176298Abstract: A main object of the invention is to provide a polymer compound for medicine which has an excellent capability of fixing a biologically active substance and has such chemical/physical stability that the compound is less dissolved or deteriorated in a washing step, in particular, which can be suitably applied to a plastic substrate surface. The invention provides a polymer compound for medical material which is a polymer comprising repeating units derived from an ethylenically unsaturated polymerizable monomer (a) having a functional group for fixing a biologically active substance, wherein the polymer has a reactive functional group on at least one terminal side thereof, and a biochip substrate wherein a layer containing the polymer compound is formed on a substrate surface, thereby attaining the object.Type: ApplicationFiled: May 18, 2006Publication date: July 9, 2009Applicant: SUMITOMO BAKELITE COMPANY, LTD.Inventors: Takayuki Matsumoto, Sumio Shibahara, Sohei Funaoka, Daisuke Masuda
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Patent number: 7553543Abstract: Optical articles, such as displays, optical lenses, windows, optical polarizers and transparent films are made as a composite structure comprising a substrate and an anti-reflective coating applied to the substrate. The anti-reflective coating comprises: A) a fluoroelastomer having cures sites selected from the group consisting of bromine atoms, chlorine atoms, iodine atoms, non-conjugated dienes, and mixtures of two or more thereof; and B) a non-fluorinated multiolefinic cross linking agent. The surface of the substrate may be treated by simultaneously bombarding the surface with an ionized inert gas, and etching the surface with an ionized reactive gas, so as to improve the adhesion of the coating to the substrate.Type: GrantFiled: December 16, 2005Date of Patent: June 30, 2009Assignee: E. I. du Pont de Nemours and CompanyInventor: Paul Gregory Bekiarian
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Publication number: 20090149601Abstract: A composition is provided for use with an unsaturated elastomer. The composition may include a sulfur-functional linear polyorganosiloxane. The sulfur-functional linear polyorganosiloxane may include a chemically protected sulfur group. Under certain conditions, the sulfur group may react with the unsaturated elastomer. The invention includes embodiments that may relate to methods of making and using the sulfur-functional linear polyorganosiloxane in elastomer compositions.Type: ApplicationFiled: February 12, 2009Publication date: June 11, 2009Applicant: CONTINENTAL AGInventors: Norberto SILVI, Robert James Perry, Ben Purushotam Patel, Paul Burchell Glaser, Brennan Alexander Smith
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Patent number: 7521509Abstract: The invention provides a fluoropolymer composition capable of improving the characteristics of the cured material obtained therefrom. A fluoropolymer composition comprising a methylene group-containing fluoropolymer (A) and a hydrosilylation catalyst (B), wherein the methylene group-containing fluoropolymer (A) has methylene group-containing repeating units in the main chain thereof and is capable of hydrosilylation in the presence of the hydrosilylation catalyst (B) and one terminus of the chain is a carbon-carbon double bond or an Si—H group and the other terminus of the chain is an Si—H group or a carbon-carbon double bond.Type: GrantFiled: December 4, 2003Date of Patent: April 21, 2009Assignee: Daikin Industries, Ltd.Inventors: Tatsuya Morikawa, Manabu Fujisawa, Mitsuru Kishine
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Publication number: 20090076221Abstract: A process for producing an adsorbent where a metal oxide is reacted with an alkoxy silane to produce an epoxy-functionalized metal oxide. This product is reacted with an amino-substituted propionic acid and a nitro-substituted fluorenone, and this product is grafted to the epoxy-functionalized metal oxide. This grafted product is the adsorbent, which may be contacted with a hydrocarbon mixture having at least one sulfur containing compound in order to remove this sulfur containing compound. Also disclosed is a process for adding polymerization groups to an adsorbent.Type: ApplicationFiled: June 6, 2008Publication date: March 19, 2009Inventors: Xiaolin Wei, Scott Michael Husson, Marcus V. Dutra e Mello, Daniel Chinn