Agent Contains An Ethylenic Group Patents (Class 525/193)
  • Patent number: 7488779
    Abstract: A golf ball which is formed from a vulcanized rubber compound composed of 100 parts by weight of a rubber base material, 10 to 60 parts by weight of an unsaturated carboxylic acid and/or a metal salt thereof, 0.1 to 5 parts by weight of an organosulfur compound, 5 to 80 parts by weight of an inorganic filler, and 0.1 to 3 parts by weight of an organic peroxide, the rubber base material being composed of a first polybutadiene accounting for 50 to 95 wt % and a second polybutadiene accounting for 5 to 50 wt %, both polybutadiene being synthesized by using a rare earth element-based catalyst, the first polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) no lower than 50 and the second polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) no higher than 45. The golf ball is characterized by good rebound resilience and good workability with which it is produced.
    Type: Grant
    Filed: April 19, 2007
    Date of Patent: February 10, 2009
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Nobuyuki Kataoka, Atsushi Nanba, Hiroto Sasaki
  • Patent number: 7485683
    Abstract: A compatibilizer including a first portion compatible with a fluoropolymer and a second portion compatible with a polyolefin. Compatibilized compositions comprising a polyolefin, a fluoropolymer, and a compatibilizer are also disclosed. Methods for forming both the compatibilizer and the blends contained in the compatibilizer are described. The compatibilized compositions of the present invention exhibit desired mechanical properties such as tensile strength and elongation. The flame retarded compatibilized blends exhibit desirable dielectric properties, are flame resistant and exhibit low smoke emission.
    Type: Grant
    Filed: June 26, 2006
    Date of Patent: February 3, 2009
    Assignee: Teknor Apex Company
    Inventors: Raman Patel, Biing-Lin Lee, John C. Andries, Maryellen Cox
  • Publication number: 20080300367
    Abstract: Disclosed is the preparation of compositions which are mixtures of certain types of epoxidized rigid copolymers of ?-olefins and diene-derived co-monomers in combination with elastomeric diene-based polymers or copolymers. These two types of rigid and elastomeric polymeric materials are placed in a common liquid reaction medium and contacted therein with an oxidizing agent. The oxidizing agent, which can be a peroxide or peracid, epoxidizes in-situ at least a portion of the residual double bonds of the rigid copolymer and preferably also introduces hydroxyl groups, e.g., diol moieties, (or derivatives thereof such as ester groups) onto the unsaturated moieties of the elastomeric diene-based polymers or copolymers. This combination of materials which has been oxidized in-situ can then be co-precipitated to form a polymeric mixture which can be melt-molded into polyolefin materials of improved structural, thermal and mechanical properties with desirable impact resistance.
    Type: Application
    Filed: June 1, 2007
    Publication date: December 4, 2008
    Inventors: Abhimanyu Onkar Patil, Stephen Zushma
  • Patent number: 7432037
    Abstract: The invention provides a curable resin composition having an addition polymerization-based block copolymer (I) and an ethylenic unsaturated compound (II). Also provided is a flexographic plate material using the curable resin composition as its constituent. The flexographic plate material containing the curable resin composition of the present invention, can be cured to form strong and extendable areas and can be used to make flexographic plates that can form a sharp image plate surface even for a fine image. The flexographic plate material of the present invention is particularly useful in printing on cardboards, recycled paper or other paper articles with rough surfaces.
    Type: Grant
    Filed: October 20, 2003
    Date of Patent: October 7, 2008
    Assignee: Kuraray Co., Ltd.
    Inventors: Kenji Suzuki, Kenji Shachi, Mizuho Maeda
  • Patent number: 7427649
    Abstract: The invention relates to a polyethylene composition with multi-modal molecular mass distribution, which is particularly suitable for blow molding of small containers with a volume in the range of from 200 to 5000 cm3 (=ml). The composition has a density in the range of from 0.955 to 0.960 g/cm3 at 23° C. and an MFR190/5 in the range from 0.8 to 1.6 dg/min. It composition from 45 to 55% by weight of a low-molecular-mass ethylene homopolymer A, from 20 to 35% by weight of a high-molecular-mass copolymer B made from ethylene and from another 1-olefin having from 4 to 8 carbon atoms, and from 20 to 30% by weight of an ultrahigh-molecular-mass ethylene copolymer C.
    Type: Grant
    Filed: December 6, 2003
    Date of Patent: September 23, 2008
    Assignee: Basell Polyolefine GmbH
    Inventors: Joachim Berthold, Ludwig Böhm, Peter Krümpel, Rainer Mantel
  • Patent number: 7423088
    Abstract: A composition containing (1) a crystalline polypropylene resin and (2) one or more ?-nucleating agents of the formula (I), wherein R1, R2 and R3, independently of one another, are C1-C20alkyl, C2-Calkyl substituted by C1-C10alkylamino, di(C1-C10alkyl)amino, C1-C10alkyloxy or hydroxy; C3-C20alkenyl, C5-C12cycloalkyl, C5-C12Cycloalkyl substituted by 1, 2 or 3 C1-C10alkyl; cyclohexylmethyl; cyclohexylmethyl substituted by 1, 2 or 3 C1-C10alkyl; C5-C9cycloalkenyl, C5-C9cycloalkenyl substituted by 1, 2 or 3 C1-C10alkyl; phenyl substituted by 1, 2 or 3 radicals selected from the group consisting of C1-C10-oalkyl, C1-C10alkyloxy, hydroxy, halogen, trihalogenmethyl, trihalogenmethoxy, benzoyl, phenylamino, acylamino and phenylazo; C7-C9phenylalkyl, C7-C9phenylalkyl which is substituted on the phenyl by 1, 2 or 3 radicals selected from the group consisting of C1-C10alkyl, C1-C10alkoxy and hydroxy; naphthyl, naphthyl substituted by C1C10alkyl, adamantyl, or a 5 to 6 membered heterocyclic group; characterized in that th
    Type: Grant
    Filed: May 22, 2003
    Date of Patent: September 9, 2008
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Dietmar Mäder, Kurt Hoffmann, Hans-Werner Schmidt
  • Patent number: 7411024
    Abstract: Interpolymer resin particles comprised of 20% to 60% by weight of uncross-linked polyolefin e.g. polyethylene, polypropylene, and from 40% to 80% by weight based on the weight of the particles of a vinyl aromatic monomer, e.g. styrene, that is polymerized in a suspension process to form an interpenetrating network of polyolefin with polymerized vinyl aromatic monomer particles and having a gel content of 0 to 1.5% by weight based on the weight of the particles for improved processability in end-use applications and improved ESCR properties. The interpolymer resin particles have a VICAT softening temperature from about 90° C. to about 115° C., and a melt index from 0.2 to 35.0 g/10 minutes (Condition G). The particles can be mixed with a blowing agent to form extruded foam articles, such as foam board, and can be used in extrusion, injection molding, rotomolding, and thermoforming processes to form a layer, e.g.
    Type: Grant
    Filed: December 8, 2004
    Date of Patent: August 12, 2008
    Assignee: NOVA Chemicals Inc.
    Inventor: Steven M. Krupinski
  • Patent number: 7396879
    Abstract: Residual monomer in a polymer matrix may be reduced by a method including admixing a polymer matrix comprising an amount of residual monomer and a conjugated diene. This method can be carried out under reaction conditions such that the amount of residual monomer is reduced. The monomer comprises at least one electron withdrawing substituent and the conjugated diene comprises at least one electron donating substituent. This method is particularly useful for reducing the amount of residual styrene monomer in polystyrene homopolymer and copolymer compositions.
    Type: Grant
    Filed: February 22, 2005
    Date of Patent: July 8, 2008
    Assignee: Fina Technology, Inc.
    Inventor: Jay Reimers
  • Patent number: 7396882
    Abstract: Styrene-free unsaturated polyester resin compositions are provided which have low volatile organic compounds and hazardous air pollutants emissions when these resin compositions are used in open molding applications. A process for the manufacture of these resin compositions is provided.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: July 8, 2008
    Assignee: AOC, LLC
    Inventors: John C. Hewitt, John E. McAlvin, Paul Taylor Hutson, Amber E. Craig, Marjorie Krantz, Derek K. Rivers
  • Patent number: 7390851
    Abstract: This invention relates to toughened cyanoacrylate compositions which exhibit improved peel strengths and fixture speeds. The toughened cyanoacrylate compositions include a toughening agent comprising poly(vinychloride-co-vinyl acetate) and poly(methylmethacrytlate).
    Type: Grant
    Filed: April 14, 2006
    Date of Patent: June 24, 2008
    Assignee: Loctite (R&D) Limited
    Inventor: Hanns Roland Misiak
  • Patent number: 7384999
    Abstract: The invention relates to a powdery pigment preparation containing a pigment which is dispersed in an acrylate resin and which is characterized in that the acrylate resin has an average molecular mass Mw ranging from 40000 to 80000 g/mol and is a copolymer comprised of 50 to 65 mol % ethyl methacrylate, of 30 to 45 mol % butyl methacrylate, and of 0.5 to 5 mol % methacrylic acid. The powdery pigment preparation can be used for dyeing films, particularly those made of polymethyl methacrylate. The films do not have any specks nor holes.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: June 10, 2008
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Robert Balent, Dietmar Beck, Heinfred Ohleier
  • Patent number: 7375160
    Abstract: A rubber-reinforced vinyl resin which is obtained by polymerizing a vinyl monomer in the presence of a rubber-like copolymer comprising at least two members selected from (I) an ethylene-?-olefin based rubber having a Mooney viscosity of 15 or higher, (II) an ethylene-octene based rubber having a Mooney viscosity less than 15, and (III) an ethylene-octene based rubber having a Mooney viscosity of 15 or higher; a process for producing the resin; and a composition containing the rubber-reinforced vinyl resin. They are excellent in moldability and gives a molded articles which are excellent in appearance in terms of gloss, flow marks, weld appearance, color unevenness at welded portions, colorability and the like, and excellent in impact resistance, for example, impact resistance at low temperatures as well as in weatherability.
    Type: Grant
    Filed: September 29, 2003
    Date of Patent: May 20, 2008
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Shinji Isoda, Hironari Muraki, Tadashi Nagahara, Hiromi Tomono
  • Publication number: 20080114128
    Abstract: The invention relates to a method for the preparation of copolymers in the form of a star comprising at least two types of polymer arms having a different chemical nature. The method comprises a radical polymerization phase for a composition comprising at least one cross-linking monomer, a free radical source, and at least two first generation (co)polymers having a different chemical nature and optionally a different molecular mass. The invention also relates to star copolymers which can be prepared by said method, and the uses thereof.
    Type: Application
    Filed: May 13, 2005
    Publication date: May 15, 2008
    Inventors: Mathias Destarac, Claire Pitois, Daniel Taton, Katerina Karagianni
  • Patent number: 7326752
    Abstract: Styrene-free unsaturated polyester resin compositions are provided which contain low amounts of hazardous air pollutants, good mechanical and physical properties and good weathering characteristics. A process for the manufacture of these resin compositions is also provided.
    Type: Grant
    Filed: February 27, 2004
    Date of Patent: February 5, 2008
    Assignee: AOC, LLC
    Inventors: John E. McAlvin, Daniel A. Oakley, Paul Taylor Hutson, David J. Zwissler, Thomas J. Folda
  • Publication number: 20070282069
    Abstract: The invention provides a golf ball material composed of (i) a non-ionomeric thermoplastic resin, (ii) an ionomeric resin and/or an acid-containing polymer which is the base polymer of an ionomeric resin, and (iii) a norbornene dicarboxylic anhydride and/or a derivative thereof. Methods for preparing such a material, and a golf ball which includes as a component therein a part made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent rebound resilience, durability and flexibility.
    Type: Application
    Filed: May 31, 2006
    Publication date: December 6, 2007
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 7300978
    Abstract: This invention relates to a process for stabilising and at the same time phase compatibilising plastics or plastic compositions by incorporating polymeric compounds obtainable by reacting a compound selected from the group consisting of the sterically hindered phenols, sterically hindered amines, lactones, sulfides, phosphites, benzotriazoles, benzophenones and 2-(2-hydroxyphenyl)-1,3,5-triazines, which compounds contain at least one reactive group, with a compatibilisator.
    Type: Grant
    Filed: February 23, 2004
    Date of Patent: November 27, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Rudolf Pfaendner, Heinz Herbst, Kurt Hoffmann, Samuel Evans, Alfred Steinmann
  • Patent number: 7291675
    Abstract: A rubber composition for a one-piece golf ball or for a solid core of a solid golf ball having a multilayer construction in which the core is enclosed directly, or with an intermediate layer, by a cover includes (a) 100 parts by weight of a base rubber, (b) 10 to 60 parts by weight of a co-crosslinking agent, (c) 5 to 80 parts by weight of an inorganic filler, (d) 0.1 to 5 parts by weight of an organic peroxide, (e) 0.05 to 5 parts by weight of an organosulfur compound, (f) 0.05 to 5 parts by weight of sulfur, and (g) 1 to 10 parts by weight of a binary copolymer consisting of a polyolefin component and a polyamide component. Golf ball rubber compositions and golf balls made using such compositions have a good resilience and excellent durability.
    Type: Grant
    Filed: March 1, 2005
    Date of Patent: November 6, 2007
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Atsushi Nanba, Jun Shindo
  • Patent number: 7291677
    Abstract: A thermoplastic elastomer that is adherent to polar materials may be made from a dynamically vulcanized blend of propylene resin, ethylene/alpha-olefin/non-conjugated diene elastomers, and a bonding agent via a curing system containing a free radical initiator, at least one co-agent including multifunctional acrylates containing at least two acrylate groups, multifunctional maleimides containing at least two imide groups, or mixtures of both, where the elastomer gel content in the modified blend is at least about 97 percent. Reaction mixtures, articles made therefrom, and methods of dynamically vulcanizing are also disclosed.
    Type: Grant
    Filed: June 29, 2004
    Date of Patent: November 6, 2007
    Assignee: Solvay Engineered Polymers, Inc.
    Inventors: Kevin Cai, Anthony Nguyen, Charles G. Reid
  • Patent number: 7288597
    Abstract: What is described is a reactive extrusion process of making a polymeric hydrogel of a polymeric anhydride or acid, e.g. maleic anhydride or maleic acid polymer, or copolymer thereof, crosslinked with a crosslinking agent containing at least 2 crosslinkable groups, particularly, —OH or —NH2, or both. The reaction product is a crosslinked polymeric ester or amide/imide, or both, suitably having a mole ratio of —OH, or —NH2, to —COOH, of 1:10 to 10:1, preferably 2:10 to 7:1. The hydrogel is particularly swellable in water, e.g. >100% in 1 hour in aqueous media; and forms a thin, tacky layer on a substrate, which property is useful in bioadhesive products.
    Type: Grant
    Filed: October 10, 2006
    Date of Patent: October 30, 2007
    Assignee: ISP Investments Inc.
    Inventors: Krystyna Plochocka, Timothy G. Bee
  • Patent number: 7262249
    Abstract: A thermoplastic resin composition comprising: a graft copolymer obtained by polymerizing 10 to 70 parts by weight of a monomer containing 60 to 100% by weight of at least one vinyl monomer selected from the group consisting of a (meth)acrylate ester compound, an aromatic vinyl compound and a vinyl cyanide compound and 0 to 40% by weight of a monomer which is copolymerizable therewith, in the presence of 30 to 90 parts by weight of hollow rubber particles which are rubber obtained by polymerizing a polymerization component comprising a butadiene without using a crosslinking agent and have a porosity of 3 to 90% in the form of a latex, wherein the total amount of the monomer and the rubber particles is 100 parts by weight; and a thermoplastic resin.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: August 28, 2007
    Assignee: Kaneka Corporation
    Inventors: Akira Takaki, Toshio Mizuta, Akio Sato
  • Patent number: 7259210
    Abstract: A bone cement formulation stored as a solid component pack having 0.3 to 20 solid component pack weight percent of an elastomer and a polymer bead core having a polyacrylate terminated surface. The second component pack is a liquid component pack including an acrylate monomer. An alternate solid component pack includes 3 to 25 solid component pack weight percent of a polyacrylate and a rubber toughened polymethyl methacrylate. A cement mixing and delivering system according to the present invention includes a tube having an exit nozzle and an aperture. An end plate is adapted to seal against the interior of the tube aperture and the end plate has a plurality of needles protruding therefrom into the tube. A rotatable and slidable divider is received within the tube intermediate between the end plate and the exit nozzle. The divider includes at least two plates.
    Type: Grant
    Filed: January 28, 2002
    Date of Patent: August 21, 2007
    Assignee: The UAB Research Foundation
    Inventors: Aaron D. Puckett, Jr., Jack Lemons, Lujia Bu, Jimmy W. Mays
  • Patent number: 7256236
    Abstract: Disclosed are methods for advantageously producing maleated polypropylenes having a relatively high percentage of bound maleic anhydride, based on the total amount of maleic anhydride moieties present in the grafting reaction product, and the maleated polypropylenes produced therefrom. The methods produce maleated polypropylenes wherein at least about 60% of the maleic anhydride moieties in the grafting reaction product are bound to the polypropylene.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: August 14, 2007
    Assignee: Honeywell International Inc.
    Inventor: Scott M. Hacker
  • Patent number: 7238120
    Abstract: A rubber compound for solid golf balls which includes (A) a base rubber, (B) a filler, (C) an organic peroxide, and (D) a co-crosslinking agent coated with a coating rubber in which the ratio of the co-crosslinking agent to the coating rubber is from 100/1 to 100/20 by weight. A solid golf ball with good flight performance and uniform quality which is formed from the rubber compound. The rubber compound contains a co-crosslinking agent (a metal salt of unsaturated carboxylic acid) finely dispersed therein and also permits processing with good workability.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: July 3, 2007
    Assignee: Fujifilm Corporation
    Inventors: Nobuyuki Kataoka, Atsushi Nanba, Hiroshi Higuchi, Kazuhiko Nakamura, Masataka Imoto
  • Patent number: 7230053
    Abstract: A golf ball, typically its core, is manufactured by molding and vulcanizing a rubber composition comprising a base rubber, an unsaturated carboxylic acid or a metal salt thereof, an inorganic filler, an organic peroxide, and an organosulfur compound. The base rubber contains a polybutadiene having a Mw of 60–150×104 and a Mw/Mn of up to 2.0 and containing at least 98% of cis-1,4 bonds and up to 1.5% of trans-1,4 bonds. The composition is easy to mold and work, and the golf ball has good rebound and improved flight performance.
    Type: Grant
    Filed: October 7, 2004
    Date of Patent: June 12, 2007
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Nobuyuki Kataoka, Atsushi Nanba, Yasuo Wakatsuki, Shojiro Kaita
  • Patent number: 7226975
    Abstract: Golf ball compositions including novel processing aids, e.g., metal salts of unsaturated fatty acids, high styrene resins, transpolyisoprene, and transpolybutadiene, for inclusion in rubber-based compositions that reduce safety risks, mixer down time, increase dispersion of the ingredients during processing, and increase component COR over that of a component formed with a conventional processing aid.
    Type: Grant
    Filed: May 12, 2004
    Date of Patent: June 5, 2007
    Assignee: Acushnet Company
    Inventors: Peter R. Voorheis, Samuel A. Pasqua, Jr.
  • Patent number: 7226367
    Abstract: A golf ball comprises a solid core consisting of a center core and an outer core, wherein at least one of cores is made of a rubber composition comprising 100 parts by weight of a base rubber including. 60 to 100% by weight of a polybutadiene containing at least 60% by weight of cis-1,4-bond, having a Mooney viscosity (ML1+4 (100° C.)) of at least 52, and synthesized using a rare-earth catalyst, 10 to 60 parts by weight of an unsaturated carboxylic acid and/or a metal salt thereof, 5 to 80 parts by weight of an-inorganic filler, and an organic peroxide, and wherein the center core has a JIS-C hardness of 40 to 60 on its center and a JIS-C hardness of 55 to 75 on its surface and the difference therebetween is at least 10, the outer core is harder than the surface hardness of the center core, the cross-sectional hardness of 1 mm outside from the border between the center core and the outer core is from 65 to 85 on a JIS-C hardness, the surface of the outer core has a JIS-C hardness of 75 to 95.
    Type: Grant
    Filed: April 12, 2006
    Date of Patent: June 5, 2007
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Nobuyuki Kataoka, Atsushi Nanba, Hiroyuki Nagasawa
  • Patent number: 7223819
    Abstract: A golf ball which is formed from a vulcanized rubber compound composed of 100 parts by weight of a rubber base material, 10 to 60 parts by weight of an unsaturated carboxylic acid and/or a metal salt thereof, 0.1 to 5 parts by weight of an organosulfur compound, 5 to 80 parts by weight of an inorganic filler, and 0.1 to 3 parts by weight of an organic peroxide, the rubber base material being composed of a first polybutadiene accounting for 50 to 95 wt % and a second polybutadiene accounting for 5 to 50 wt %, both polybutadiene being synthesized by using a rare earth element-based catalyst, the first polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) no lower than 50 and the second polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) no higher than 45. The golf ball is characterized by good rebound resilience and good workability with which it is produced.
    Type: Grant
    Filed: August 31, 2004
    Date of Patent: May 29, 2007
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Nobuyuki Kataoka, Atsushi Nanba, Hiroto Sasaki
  • Patent number: 7201969
    Abstract: A surface protecting adhesive film for a semiconductor wafer in which an adhesive layer is formed on one surface of a base film, wherein the adhesive layer comprises 100 weight parts of a polymer (A) having a functional group capable of reacting with a cross-linking agent and a temperature in a range of from ?50° C. to 5° C. at which tan ? of a dynamic viscoelasticity is maximized, from 10 weight parts to 100 weight parts of a polymer (B) having a functional group capable of reacting with a cross-linking agent and a temperature in a range of from more than 5° C. to 50° C. at which tan ? of a dynamic viscoelasticity is maximized, and from 0.
    Type: Grant
    Filed: March 26, 2003
    Date of Patent: April 10, 2007
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masafumi Miyakawa, Makoto Kataoka, Jun Nakashima, Yoshihisa Saimoto, Shinichi Hayakawa, Yasuhisa Fujii
  • Patent number: 7202310
    Abstract: An alkenyl- or crosslinkable silyl-terminated vinyl polymer is provided. Such a functional group is introduced into its terminus at a high ratio, not via sulfur atoms. Those polymers can be prepared by polymerizing a vinyl monomer for obtaining a halogen-terminated vinyl polymer, and then substituting an oxy anion or carbanion having such a functional group for the terminal halogen of said polymer.
    Type: Grant
    Filed: January 26, 2004
    Date of Patent: April 10, 2007
    Assignee: Kaneka Corporation
    Inventors: Kenichi Kitano, Yoshiki Nakagawa, Masato Kusakabe
  • Patent number: 7199190
    Abstract: A golf ball-which is formed from a crosslinked rubber compound composed of, as essential components, (A) a rubber base material composed of (a) a polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) of 50 to 120, which is synthesized by using a group VIII element catalyst and/or a rare earth element-based catalyst, and (b) a solid isoprene rubber containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) of 70 to 90, with the ratio of (a) to (b) being from 70/30 to 98/2 by weight; (B) an unsaturated carboxylic acid and/or a metal salt thereof; and (C) an organic peroxide. The golf ball is characterized by good rebound resilience and good workability with which it is produced.
    Type: Grant
    Filed: August 31, 2004
    Date of Patent: April 3, 2007
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Nobuyuki Kataoka, Atsushi Nanba, Hiroto Sasaki
  • Patent number: 7193005
    Abstract: Aqueous polymer dispersions comprising a) 50–70% by weight of polymer particles composed of at least two different (co)polymers having glass transition temperatures each above 50° C. and synthesized from at least 80% by weight of at least one principal monomer, 0.1–10% by weight of at least one auxiliary monomer, and 0–3% by weight of at least one crosslinker molecule, the difference in the glass transition temperatures (Tg) of the different polymers being at least 10° C., and b) 30–50% by weight of at least one polyfunctional (meth)acrylate, the dispersion a) being subjected to physical and/or chemical deodorization.
    Type: Grant
    Filed: May 21, 2003
    Date of Patent: March 20, 2007
    Assignee: BASF Aktiengesellschaft
    Inventors: Joerg Leuninger, Wolfgang Paulus, Anke Mueller
  • Patent number: 7189786
    Abstract: A golf ball which is formed from a crosslinked rubber compound composed of, as essential components, (A) a rubber base material composed of (a) a polybutadiene containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) of 50 to 120, which is synthesized by using a group VIII catalyst element and/or a rare earth element-based catalyst, and (b) a solid isoprene rubber containing no less than 60 wt % of cis-1,4 bonds and having a Mooney viscosity (ML1+4 (100° C.)) of 70 to 90, with the ratio of (a) to (b) being from 96/4 to 99/1 by weight; (B) an unsaturated carboxylic acid and/or a metal salt thereof; and (C) an organic peroxide. The golf ball is characterized by good rebound resilience and good workability with which it is produced.
    Type: Grant
    Filed: August 31, 2004
    Date of Patent: March 13, 2007
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Atsushi Nanba, Nobuyuki Kataoka, Hiroto Sasaki
  • Patent number: 7189785
    Abstract: This invention has an object of enhancing the cold resistance of a heavy duty power transmission V-belt without impairing its durability at high temperatures, ensuring its sufficient power transmission capability and concurrently enhancing its permanent set resistance. To attain the object, the invention employs, for a rubber element of the belt, a rubber composition in which 20 to 40 parts by weight of a metal salt monomer of an organic acid and 5 to 35 parts by weight of short fibers are mixed into 100 parts by weight of a rubber component composed of EPDM and HNBR in their ratio of 55/45 to 75/25, the rubber hardness measured with a durometer Type D is 40 to 60, the value of t5 given by a Gehman torsion test is ?50° C. to ?35° C., and the amount of acetone extract from the rubber component is 9% or less.
    Type: Grant
    Filed: April 23, 2003
    Date of Patent: March 13, 2007
    Assignee: Bando Chemical Industries, Ltd.
    Inventor: Shigeki Okuno
  • Patent number: 7156944
    Abstract: To obtain an adhesive having both a high initial adhesive capacity and high heat resistance, a fusible adhesive which can be cross-linked by radiation and a low tendency to creep is provided. The adhesive contains 0 to 40 weight percent of at least one elastomer which cannot be cross-linked by radiation, 15 to 40 weight percent of at least one compound containing at least two olefinic double bonds, and 20 to 85 weight percent of at least one tackifier. The adhesive is especially suitable for use on high speed labeling machines.
    Type: Grant
    Filed: January 24, 2005
    Date of Patent: January 2, 2007
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thomas Moeller, Marcus Heemann, Andreas Ferencz
  • Patent number: 7153908
    Abstract: A process involves adding a peroxide masterbatch to a molten blend of a fluorocarbon elastomer and a thermoplastic material. The peroxide masterbatch contains greater than or equal to 5% weight percent organic peroxide, further contains a fluorocarbon elastomer, and typically also contains a crosslinker containing at least two sites of olefinic unsaturation. The fluorocarbon elastomer in the molten blend and in the peroxide masterbatch may be the same or different. After the peroxide masterbatch is added to the molten blend, the combination is mixed at a temperature and for a time sufficient to effect cure of the fluorocarbon elastomers. By using a masterbatch, a faster and more uniform dispersion of peroxide curative is possible due to pre-dispersion of peroxide in the elastomer phase, which leads to shaped articles having improved mechanical properties.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: December 26, 2006
    Assignee: Freudenberg-NOK General Partnership
    Inventor: Edward Hosung Park
  • Patent number: 7148290
    Abstract: A rubber composition for a golf ball having excellent rebound characteristics and excellent durability, and showing good workability, which contains a base rubber, a co-crosslinking agent, an organic peroxide and an inorganic filler, wherein the base rubber includes a polybutadiene containing a cis-1,4 bond of not less than 80%, having a Mooney viscosity of not less than 30 to less than 50 ML1+4(100° C.) and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to the number average molecular weight (Mn) of 3.0 to 6.0, synthesized using a lanthanide-containing catalyst.
    Type: Grant
    Filed: May 4, 2005
    Date of Patent: December 12, 2006
    Assignee: SRI Sports Limited
    Inventors: Koichi Fujisawa, Yoshikazu Yabuki
  • Patent number: 7148279
    Abstract: A golf ball a core and a cover, wherein at least one of the core or the cover includes a blend of a highly neutralized ionomer formed from a reaction between an ionomer having acid groups, a suitable cation source, and a salt of an organic acid, the cation source being present in an amount sufficient to neutralized the acid by 80% or greater; and a crosslinked or vulcanized diene rubber.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: December 12, 2006
    Assignee: Acushnet Company
    Inventors: Peter R. Voorheis, Michael J. Sullivan, Derek A. Ladd, Murali Rajagopalan
  • Patent number: 7148262
    Abstract: The present invention relates to an apparatus and method for reusing waste material generated during the manufacturing of golf ball cores. More specifically, the present invention relates to a method and apparatus for drying the waste material in order lower its moisture content. In addition, the present invention relates to golf balls and golf ball components that utilize waste material, and in particular swarf.
    Type: Grant
    Filed: February 4, 2004
    Date of Patent: December 12, 2006
    Assignee: Acushnet Company
    Inventors: Richard S. Danner, Richard K. Brown, Samuel A. Pasqua, Jr.
  • Patent number: 7122602
    Abstract: What is described is a reactive extrusion process of making a polymeric hydrogel of a polymeric anhydride or acid, e.g. maleic anhydride or maleic acid polymer, or copolymer thereof, crosslinked with a crosslinking agent containing at least 2 crosslinkable groups, particularly, —OH or —NH2, or both. The reaction product is a crosslinked polymeric ester or amide/imide, or both, suitably having a mole ratio of —OH, or —NH2, to —COOH, of 1:10 to 10:1, preferably 2:10 to 7:1. The hydrogel is particularly swellable in water, e.g. >100% in 1 hour in aqueous media; and forms a thin, tacky layer on a substrate, which property is useful in bioadhesive products.
    Type: Grant
    Filed: March 16, 2004
    Date of Patent: October 17, 2006
    Assignee: ISP Investments Inc.
    Inventors: Krystyna Plochocka, Timothy G. Bee
  • Patent number: 7119147
    Abstract: A rubber composition which prevents the rise in rubber hardness over time and can maintain good performance on snow and ice over a long period, which includes (A) a diene rubber containing, as a main component, at least one member selected from the group consisting of natural rubber and butadiene rubber, and (B) 5 to 60 parts by weight of vegetable oil which has an iodine value of at least 80 and contains at least 70% by weight of unsaturated fatty acid having at least 18 carbon atoms, based on 100 parts by weight of the diene rubber (A), the rubber composition having a tan ? peak temperature Tg of at most ?50° C. and a rubber hardness of at most 64 at 0° C. The present invention also relates to a pneumatic tire using the rubber composition as the tread.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: October 10, 2006
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Naohiko Kikuchi
  • Patent number: 7112632
    Abstract: A process for the preparation of low branch content polybutadiene comprising: (a) a first butadiene polymerisation stage; (b) treatment of the polymer solution obtained upon completion of stage (a) with a coupling agent selected from: (i) polyunsaturated natural oils; (ii) butadiene and/or isoprene oligomers; (iii) butadiene and/or isoprene co-polymers with vinylarene monomers; the unsaturations present in compounds (i)–(iii) being at least partially substituted with groups selected from epoxides, anhydrides and esters; (c) recovery of the low branch content polybutadiene obtained upon completion of stage (b).
    Type: Grant
    Filed: October 17, 2005
    Date of Patent: September 26, 2006
    Assignee: Polimeri Europa S.p.A.
    Inventors: Gian Tommaso Viola, Fabio Bacchelli, Silvia Valenti
  • Patent number: 7094836
    Abstract: A compatibilizer including a first portion compatible with a fluoropolymer and a second portion compatible with a polyolefin. Compatibilized compositions comprising a polyolefin, a fluoropolymer, and a compatibilizer are also disclosed. Methods for forming both the compatibilizer and the blends contained in the compatibilizer are described. The compatibilized compositions of the present invention exhibit desired mechanical properties such as tensile strength and elongation. The flame retarded compatibilized blends exhibit desirable dielectric properties, are flame resistant and exhibit low smoke emission.
    Type: Grant
    Filed: March 4, 2004
    Date of Patent: August 22, 2006
    Assignee: Teknor Apex Company
    Inventors: Raman Patel, Biing-Lin Lee, John C. Andries, Maryellen Cox
  • Patent number: 7094837
    Abstract: Thermoplastic elastomers having the property of optical translucence are provided by incorporating syndiotactic polypropylene homopolymer into olefinic elastomers. The rubber component of the composition is at least partially cured.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: August 22, 2006
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria D. Ellul, Donald R. Hazelton
  • Patent number: 7074859
    Abstract: A golf ball is characterized by comprising a molded and vulcanized product of a rubber composition as a constituent component, the rubber composition comprising 100 pbw of a base rubber including 60–100 wt % of a polybutadiene containing at least 60 wt % of cis-1,4-bond, having a Mooney viscosity (ML1+4 (100° C.)) of at least 40, and synthesized using a rare-earth catalyst, 10–60 pbw of an unsaturated carboxylic acid and/or a metal salt thereof, 0.1–5 pbw of an organosulfur compound, 5–80 pbw of an inorganic filler, and at least two organic peroxides including an organic peroxide having the shortest half-life at 155° C. designated (a) and another organic peroxide having the longest half-life at 155° C. designated (b), a ratio of half-lives (bt/at) being from 7 to 20 wherein at is the half-life of (a) and bt is the half-life of (b), a total content of the organic peroxides being 0.1–0.8 pbw per 100 pbw of the base rubber.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: July 11, 2006
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroshi Higuchi, Nobuyuki Kataoka, Atsushi Nanba, Hiroyuki Nagasawa
  • Patent number: 7067582
    Abstract: The invention is directed to golf ball core compositions comprising at least one natural or synthetic rubber and at least one high Vicat softening temperature thermoplastic material, methods of preparing the compositions, and golf ball cores and golf balls including the compositions. The compositions of the invention are made by mixing at least one natural or synthetic rubber and at least one thermoplastic or thermoplastic elastomer at a first temperature; cooling the mixture to a second temperature which is below an activation temperature of a free-radical initiator; adding the free-radical initiator to the first mixture to form a second mixture; and heating the second mixture to a third temperature that to facilitate crosslinking. The golf ball cores are incorporated into multilayer balls including dual cover balls with thin outer layers.
    Type: Grant
    Filed: November 25, 2003
    Date of Patent: June 27, 2006
    Assignee: Acushnet Company
    Inventors: Murali Rajagopalan, Derek A. Ladd
  • Patent number: 7019087
    Abstract: A method for the production of moldable masses is provided. The method includes compounding a polyolefin having a density of less than about 0.918 g/cm3 serial cross-linking agents. The moldable masses can be used the production of low-emission floor coverings with excellent material properties.
    Type: Grant
    Filed: August 12, 2002
    Date of Patent: March 28, 2006
    Assignee: DLW Aktiengesellschaft
    Inventors: Hanns-Jörg Mauk, Bernd Fischer, Renate Stefani
  • Patent number: 7019077
    Abstract: The present invention provides a resin composition for a primer comprising (a) 100 parts by weight of a chlorinated polyolefin having a chlorine content of 5–50 wt. % and a weight-average molecular weight of 30000–120000, and (b) 15–80 parts by weight of a hydroxyl-containing petroleum resin.
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: March 28, 2006
    Assignees: Toyo Kasei Kogyo Company Limited, Arakawa Chemical Industries, Ltd.
    Inventors: Satoshi Yoshikawa, Takafumi Masuda, Shoji Maekawa, Takumi Okazaki, Tsukasa Ishimoto
  • Patent number: 7005478
    Abstract: The present invention is directed to methods of making natural or synthetic latex articles without the use of accelerators, thiurams or carbamates. The method includes making an elastomeric material by mixing a base polymer containing carboxylate groups with a carboxylic acid or derivative thereof, a divalent or trivalent metal, an amine or amino compound, and a neutralizing agent. The elastomeric material is formed into a latex article. The present invention is also directed to a latex article made according to this method. The latex article does not contain any accelerators, thiurams or carbamates.
    Type: Grant
    Filed: November 4, 2003
    Date of Patent: February 28, 2006
    Assignee: Best Manufacturing Company
    Inventors: William Andrus Williams, Joyce Lee Cleveland
  • Patent number: 6982301
    Abstract: A golf ball comprising a solid core and a cover disposed about the core, wherein the core is formed from a polybutadiene blend comprising a) a first polybutadiene having a first Mooney viscosity between about 50 and about 150, and b) a second polybutadiene having a second Mooney viscosity between about 30 and about 100, wherein the first Mooney viscosity is greater than the second Mooney viscosity, and wherein the blend has a greater weight percentage of the first polybutadiene than that of the second polybutadiene.
    Type: Grant
    Filed: August 12, 2003
    Date of Patent: January 3, 2006
    Assignee: Acushnet Company
    Inventors: Peter R. Voorheis, Samuel A. Pasqua, Jr., Michael J. Sullivan, David A. Bulpett, Derek A. Ladd
  • Patent number: 6964999
    Abstract: A vinyl polymer having at least one terminal group of the general formula (1) per molecule; —OC(O)C(R)?CH2??(1) wherein R represents hydrogen or an organic group containing 1 to 20 carbon atoms; a curable composition containing said polymer; an aqueous emulsion containing either said polymer or said curable composition; a pressure sensitive adhesive composition and a pressure sensitive adhesive each comprising said curable composition or aqueous emulsion.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: November 15, 2005
    Assignee: Kaneka Corporation
    Inventors: Yoshiki Nakagawa, Masayuki Fujita, Kenichi Kitano