Heterocyclic Reactant Contains 1,2-epoxy Group Patents (Class 525/208)
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Patent number: 6313224Abstract: Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer.Type: GrantFiled: November 9, 1999Date of Patent: November 6, 2001Assignee: PPG Industrial Ohio, Inc.Inventors: Debra L. Singer, Kurt G. Olson, Kurt A. Humbert, Karen A. Barkac, Mark E. Wozniak
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Patent number: 6313221Abstract: A thermosetting powder coating composition prepared by a wet process, which contains a mixture comprising (a) an epoxy-containing acrylic resin, (b) a polycarboxylic acid compound curing agent, (c) fine crosslinked resin particles and/or (d) a resin that exists in the liquid form at room temperature.Type: GrantFiled: May 26, 2000Date of Patent: November 6, 2001Assignee: Nippon Paint Co., Ltd.Inventors: Masami Yabuta, Yutaka Harada, Atsushi Yamada, Yasuhiko Nakae, Kazuhiko Nishimura, Haruhiko Sato
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Patent number: 6294610Abstract: Coating powders having a resin system of comprising an epoxy resin and a carboxylic acid functional polymer contain a cure catalyst of formulae (I), (II) or mixtures of (I) and (II): where Z is selected from P, As, and N, the R1s are the same or different and are independently selected from alkyl groups, alkenyl groups, and aryl groups; R2s are the same or different and are selected from alkyl groups, phenyl groups, substituted phenyl groups, Br, Cl, I, and F; and the R3s are the same or different and are independently selected from the group consisting of H, alkyl groups, alkenyl groups, acyl groups, cycloalkyl groups, cycloalkenyl groups, aldehyde group, carboxyl group, cyano group and nitro group.Type: GrantFiled: November 29, 1999Date of Patent: September 25, 2001Assignee: Rohm and Haas CompanyInventors: Andrew T. Daly, Richard P. Haley, Michael M. Cook, Jeffrey A. Ulman
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Patent number: 6288156Abstract: A thermoplastic polymer composition comprising (a) 50-90 wt. % of a polymer blend comprising (i) 10-40 wt. % polypropylene (ii) 15-50 wt. % uncrosslinked ethylene propylene copolymer rubber having an ethylene content of 60-80 wt %, (iii) 20-60 wt. % of an ionomeric copolymer of ethylene and an &agr;,&bgr;-unsaturated C3-C8 carboxylic acid, and (iv) 0.1-5 wt. % of a copolymer of ethylene and glycidyl acrylate or glycidyl methacrylate, (b) 10-40 wt. % inorganic filler and (c) 0-15 wt. % of an uncrosslinked ethylene propylene copolymer rubber having an ethylene content of 60-80 wt. % grafted with 0.01-5 wt. % of an &agr;,&bgr;-unsaturated carboxylic acid or an anhydride thereof.Type: GrantFiled: April 29, 1999Date of Patent: September 11, 2001Assignee: E. I. du Pont de Nemours and CompanyInventor: Karlheinz Hausmann
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Patent number: 6274239Abstract: A polymeric composition for coating electric cables for power transmission at medium/high voltage, having an improved resistance against the formation of the so-called water trees, comprises a polymeric polyolefin base including, in parts by weight to the total weight thereof, from 0.5 to 15 parts of ester groups and from 0.01 to 5 parts of epoxy groups. Electric cables according to the invention comprise at least one electrically conducting core (2) and an insulation coating (5) comprising the aforementioned polymeric composition.Type: GrantFiled: January 5, 1999Date of Patent: August 14, 2001Assignee: Pirelli Cavi S.p.A.Inventors: Franco Peruzzotti, Valeria Garcia
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Patent number: 6268437Abstract: The invention provides a golf ball cover stock based on a heated mixture of (a) an ionomer resin, (b) polyethylene, and (c) an epoxy group-modified polyolefin or (d) a low molecular weight polyethylene wax. Component (c) or (d) improves the dispersion of polyethylene in the ionomer resin so that a larger amount of polyethylene may be blended in micro-dispersion form. A golf ball having a cover made of the cover stock is durable and wear resistant and offers a good feel when hit.Type: GrantFiled: August 2, 1999Date of Patent: July 31, 2001Assignee: Bridgestone Sports Co., Ltd.Inventors: Rinya Takesue, Yasushi Ichikawa, Shunichi Kashiwagi
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Patent number: 6265489Abstract: A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) polycarboxylic acid functional polymer, and (b) epoxide functional crosslinking agent having at least two epoxide groups, e.g., triglycidyl isocyanurate (TGIC), is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.0. The thermosetting compositions of the present invention have utility as powder coatings compositions.Type: GrantFiled: August 16, 1999Date of Patent: July 24, 2001Assignee: PPG Industries Ohio, Inc.Inventors: Karen A. Barkac, Simion Coca, James R. Franks, Kurt A. Humbert, Paul H. Lamers, Roxalana L. Martin, James B. O'Dwyer, Kurt G. Olson, Daniela White
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Publication number: 20010007892Abstract: A rubber composition obtained byType: ApplicationFiled: February 5, 2001Publication date: July 12, 2001Applicant: Sumitomo Rubber Industries, Ltd.Inventors: Yasuhisa Minagawa, Hiroki Sarashi, Minoru Ueda
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Patent number: 6258874Abstract: This invention relates to a binder composition suitable for coating compositions, which binder composition contains one or more carboxy-functional polymers, one or more compounds having an epoxide function in the molecule, one or more polyols having at least two hydroxyl functions in the molecule, which polyols differ from a component A) optionally containing hydroxyl functions, components which crosslink with hydroxyl groups to form ethers and/or a triazine-based crosslinking agent, optionally one or more polyisocyanates, which may optionally be capped, optionally an anhydride component and optionally one or more catalysts for catalysing the reaction of carboxyl and epoxide groups.Type: GrantFiled: June 14, 1999Date of Patent: July 10, 2001Assignee: Herberts GmbH & Co. KGInventors: Volker Duecoffre, Walter Schubert
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Patent number: 6221940Abstract: A thermoplastic resin composition containing a polyetherimide resin, a glycidyl ester impact modifier and a organometallic compound exhibits improved impact strength and ductility.Type: GrantFiled: December 23, 1997Date of Patent: April 24, 2001Assignee: General Electric CompanyInventors: Robert Puyenbroek, James Fishburn
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Patent number: 6217982Abstract: A calenderable thermoplastic polymer alloy composition made by blending ethylene/alkyl (meth)acrylate with a blend of polypropylene, ethylene copolymer ionomer resin, ethylene/glycidyl acrylate or methacrylate copolymer, and uncrosslinked ethylene propylene rubber.Type: GrantFiled: October 8, 1998Date of Patent: April 17, 2001Assignee: E. I. du Pont de Nemours and CompanyInventor: Robert Louis Dawson
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Patent number: 6210294Abstract: A golf ball comprising a center, a cover, and optionally, at least one intermediate layer disposed between the center and the cover, wherein at least one of the center, the cover, and the at least one intermediate layer is formed with a polyurethane composition comprising a reaction product of a prepolymer of at least one polyol and at least one polyisocyanate, and a curing agent of at least one diol. A polyurethane composition, suitable for forming golf equipment, said composition comprising a reaction product of a prepolymer of at least one polyol and at least one polyisocyanate, and a curing agent of at least one diol.Type: GrantFiled: May 14, 1999Date of Patent: April 3, 2001Assignee: Acushnet CompanyInventor: Shenshen Wu
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Patent number: 6211291Abstract: Nonhalogen-Containing Thermoplastic Polyolefin blends are provided which are either heat resistant and are particularly useful in wire and cable coatings, extruded profiles, sheet form or injection molded part or have an elastomeric behavior and are particularly useful in injection molded part. These blends comprise preferably (1) ethylene n-butyl acrylate glycidyl methacrylate (EnBAGMA) terpolymer, (2) an ethylene propylene rubber (EPDM) grafted with maleic anhydride, (3) a polypropylene homopolymer for heat resistance or a very low density polyethylene for elastomeric behavior or a linear low density polyethylene (LLDPE) or a low density polyethylene or a high density polyethylene or an ethylene-polypropylene copolymer.Type: GrantFiled: June 28, 2000Date of Patent: April 3, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Loic Pierre Rolland, Melanie Beatrice Boisson
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Patent number: 6207768Abstract: The combination of powder coatings usable in a coating method comprising mixing two or more powder coatings of which each color is different, wherein each of the powder coatings fuses with each other and is heat-cured, to thereby give a coating film having a homogeneous hue. A powder coating composition comprising two or more powder coatings of which each color is different, wherein each of the powder coatings fuses with each other and is heat-cured, to thereby give a coating film having a homogeneous hue. A coating method comprising the steps of (a) applying to a substrate two or more powder coatings, of which each color is different; (b) heating to fuse with each other each of the two or more powder coatings applied in step (a); and (c) curing the resulting fused product in step (b), to give a coating film having a homogeneous hue.Type: GrantFiled: November 25, 1997Date of Patent: March 27, 2001Assignee: Kao CorporationInventors: Yukiya Sato, Hisakazu Tajima, Katsutoshi Aoki, Takehiko Tohjo, Yasunori Inagaki, Masayuki Maruta, Shingo Tanaka
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Patent number: 6200639Abstract: Coating composition suitable for multi-layer lacquerings, with a binder composition which comprises: A) 25 to 75 wt. % of carboxyl-functional (meth)acrylic copolymers and/or carboxyl-functional polyesters, the carboxyl functionality of which corresponds to an acid number of 15 to 300 mg KOH/g, B) 25 to 75 wt. % of epoxide-functionalized crosslinker resins, at least one of which is a (meth)acrylic copolymer which has been prepared co-using tert-butyl (meth)acrylate, C) 0 to 50 wt. % of polyols which have at least two hydroxyl functions in the molecule, D) 0 to 40 wt. % of components which crosslink with hydroxyl groups to form ethers, and/or of a crosslinking agent based on triazine, E) 0 to 40 wt. % of polyisocyanates, F) 0 to 50 wt. % of at least one organic polyanhydride with at least two cyclic carboxylic acid anhydride groups per molecule, G) 0 to 20 wt. % of reactive thinners with an epoxide function, H) 0 to 10 wt. % of one or more catalysts for the reaction of carboxyl and epoxide groups.Type: GrantFiled: June 14, 1999Date of Patent: March 13, 2001Assignee: Herberts GmbH., KGInventors: Volker Duecoffre, Walter Schubert, Friedrich Herrmann, Carmen Flosbach, Claudia Leckebusch
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Patent number: 6191225Abstract: A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) polycarboxylic acid functional polymer, and (b) epoxy functional polymer, is described. The polycarboxylic acid functional polymer and epoxy functional polymer are each prepared by atom transfer radical polymerization and have well defined polymer chain architecture and polydispersity index of less than 2.5. The thermosetting compositions of the present invention have utility as powder coatings compositions.Type: GrantFiled: August 16, 1999Date of Patent: February 20, 2001Assignee: PPG Industries Ohio, Inc.Inventors: Karen A. Barkac, Simion Coca, James R. Franks, Kurt A. Humbert, Paul H. Lamers, Roxalana L. Martin, James B. O'Dwyer, Kurt G. Olson, Daniela White
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Patent number: 6180726Abstract: The present invention relates to a high temperature resistant coating composition and a method of using thereof. More particularly, the invention relates to a coating composition comprising a resin containing functional hydroxyl groups (A), a polyfunctional epoxy resin (B), and an anhydride compound.(C).Type: GrantFiled: March 10, 1998Date of Patent: January 30, 2001Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Wayne G. Eklund, Paula Bushendorf
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Patent number: 6166143Abstract: A thermoplastic elastomer composition containing a component (A) (thermoplastic polyolefin resin), component (B) (epoxy-group-containing ethylene acrylic ester copolymer rubber), and component (C) (acid-modified polyolefin resin) comprising a continuous phase of the component (A) in which the component (B) is dispersed as a dispersed phase and is cross-linked by a peroxide; a thermoplastic elastomer composition comprising a continuous phase of a thermoplastic polyolefin resin (A) and a dispersed phase of an epoxy-group-containing ethylene-acrylic ester copolymer rubber component (B) and acrylonitrile butadiene rubber component (C), which is dynamically cross-linked; and a hose having an inner tube, at least one reinforcing layer, and an outer cover, wherein the inner tube and the outer cover contain a thermoplastic elastomer composition comprised of a thermoplastic resin in which is blended an at least partially cross-linked elastomer component, the reinforcing layer is a brass-plated wire, and the reinforcinType: GrantFiled: July 2, 1998Date of Patent: December 26, 2000Assignee: The Yokohama Rubber Co., Ltd.Inventors: Jiro Watanabe, Yuichi Hara, Daisuke Irii, Takashi Satoh, Gou Kawaguchi, Shigeru Yamauchi, Susumu Hatanaka, Noriaki Kuroda
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Patent number: 6153680Abstract: Thermoplastic polymer alloy compositions and a process for preparing the compositions are provided comprising a blend of polypropylene, uncrosslinked ethylene copolymer, ionomeric copolymer of ethylene and .alpha.,.beta.-unsaturated C.sub.3 -C.sub.8 carboxylic acid, crosslinking agent, and silicone elastomer. The compositions may further comprise particulate filler, color concentrate and/or coloring pigment. The compositions are particularly useful for forming interior skin sheets for applications where low gloss and high scuff resistance are desired without the need for painting. A one step process for preparing moldable sheets from the thermoplastic polymer alloy compositions by in-line compounding and reactive extrusion is also provided which eliminates separate compounding and pelletizing processing steps as precursors to the sheet extrusion process.Type: GrantFiled: June 30, 1999Date of Patent: November 28, 2000Assignee: Delphi Technologies, Inc.Inventors: Suresh Deepchand Shah, Srimannarayana Kakarala, Jeanne E. Schneider
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Patent number: 6113998Abstract: A metal/synthetic resin laminate comprising a metal substrate layer, an epoxy resin-based adhesive layer (a "1st adhesive layer"), an adhesive layer (a "2nd adhesive layer") comprising an epoxidized styrenic thermoplastic elastomer D prepared through epoxidation of a double bond derived from a conjugated diene compound of a block copolymer C comprising a polymer block A composed mainly of a styrenic compound and a polymer block B composed mainly of a conjugated diene compound or a partial hydrogenation product thereof, and a synthetic resin layer; and a synthetic resin-clad metallic pipe wherein the above metal substrate layer is tubular.Type: GrantFiled: June 4, 1998Date of Patent: September 5, 2000Assignee: Daicel Chemical Industries Ltd.Inventors: Katsumi Aizawa, Yoshihiro Ohtsuka
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Patent number: 6103387Abstract: A thermosetting composition comprises (A) a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the blocked carboxyl groups, and (C) a dispersing component of at least one inorganic oxide sol selected from the group consisting of aluminium oxide sol, silica sol, zirconium oxide sol and antimony oxide sol, and optionally (D) a thermal latent acid catalyst which is activated during curing the composition by heating. A method of coating and a coated article comprise applying the composition. The obtained paint film has excellent weathering resistance, stain resistance, stain-removing property, chemical resistance, moisture resistance and excellent appearance.Type: GrantFiled: June 10, 1997Date of Patent: August 15, 2000Assignee: NOF CorporationInventors: Toshio Yamamoto, Masahiro Sano, Hiroki Mizutani, Keiji Komoto, Masahiro Ishidoya
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Patent number: 6084009Abstract: A thermosetting powder paint composition comprising:(A) a (meth)acrylic copolymer having glycidyl groups;(B) a polybasic carboxylic acid and/or polybasic carboxylic anhydride; and(C) particles having a core/shell structure each comprising a core having Tg of 20.degree. C. or below, the core being covered at least partially with a shell having Tg of 40.degree. C. or above, and said shell having no glycidyl group.The paint composition is excellent in weather resistance as well as in impact resistance and chipping resistance.Type: GrantFiled: April 23, 1997Date of Patent: July 4, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Mitsuyuki Mizoguchi, Yoshiro Fuseya, Yoshihiro Fujita, Yukiatsu Ishino, Masashi Seki, Takahisa Miyawaki
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Patent number: 6045902Abstract: A tearable film having excellent tear properties contains a dispersed phase and a continuous phase, with said film formed from a composition containing a styrenic polymer, an olefinic polymer, and a compatibilizer wherein the compatibilizer is selected from the group consisting of hydrogenated or modified copolymer of styrene and conjugated diene, olefinic copolymer having a cyclic olefin unit, and chlorinated polyolefin. The film composition is subjected, without stretching, to T-die molding or inflation molding to provide a tearable film. In the continuous phase of the film, said dispersed phase having an average aspect ratio of 3 or more and/or a thickness of 1 .mu.m or less is dispersed in layers. The ratio of the continuous phase to the dispersed phase is 35-98:2-65 (% by weight). In the film, the tearing maximum torque is 60 g.multidot.cm/.mu.m or less and the tearing maximum tensile force is 10 g/.mu.m or less, and the film can be torn straightly at least in one direction.Type: GrantFiled: July 1, 1994Date of Patent: April 4, 2000Assignee: Daicel Chemical Industries Ltd.Inventors: Shinichiro Imanishi, Kenji Ueda, Katsuhiko Sumida
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Patent number: 6037416Abstract: A thermosetting coating composition comprising an acrylic copolymer (A) containing vinyl monomer units each having an .alpha.,.beta.-dicarboxylic acid anhydride group and vinyl monomer units each having an .alpha.,.beta.-dicarboxylic monoester group in a total amount of 5-40 wt % and containing the vinyl monomer units with .alpha.,.beta.-dicarboxylic acid anhydride groups at 0.3-5 wt %, and an acrylic copolymer (B) with epoxy groups.Type: GrantFiled: February 10, 1998Date of Patent: March 14, 2000Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Akio Iwamoto, Takeshi Kato, Shinobu Fujie, Kazuhiko Hotta, Kunio Iwase, Hiroshi Takeuchi
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Patent number: 6030571Abstract: A method of molding which comprises preparing a molding material by compounding a filler and a curable composition, the filler being in an amount of 0 to 800 weight parts based on 100 weight parts of the curable composition and optionally aging the molding material at room temperature or by heating, followed by casting the molding material into a mold and curing the molding material under atmospheric pressure or higher, and articles molded by such method.Type: GrantFiled: May 22, 1997Date of Patent: February 29, 2000Assignee: NOF CorporationInventors: Yoshinori Nakane, Hiroki Mizutani, Hayato Ishibashi, Masahiro Ishidoya
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Patent number: 6013733Abstract: Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer.Type: GrantFiled: March 11, 1998Date of Patent: January 11, 2000Assignee: PPG Industries Ohio, Inc.Inventors: Debra L. Singer, Kurt G. Olson, Kurt A. Humbert, Karen A. Barkac, Mark E. Wozniak
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Patent number: 5994467Abstract: A polycarbonate blend composition with a good balance of high impact resistance, moldability, and controllable gloss with reduced tendencies of pearlescence or delamination in molded articles is prepared by admixing with polycarbonate a substantially linear ethylene polymer or linear ethylene polymer, an olefinic epoxide-containing copolymer, and a polyester.Type: GrantFiled: November 26, 1997Date of Patent: November 30, 1999Assignee: The Dow Chemical CompanyInventors: Hani Farah, Frank M. Hofmeister, Samuel A. Ogoe, Nancy J. Schrock, Leo R. Novak
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Patent number: 5993951Abstract: Disclosed is a transparent plastic sheet obtained by co-polymerizing 100 parts by weight of methyl methacrylate with 0.1 to 2.0 parts by weight of methacrylic acid and 0.1 to 1.5 parts by weight of glycidyl methacrylate, and having a thickness of not greater than 4 inches, wherein the angular deviation satisfies specified conditions according to the thickness of the sheet and wherein the degree of swelling is not greater than 2.50. This transparent plastic sheet shows neither coloring nor sink marks on the surface, has excellent craze resistance and low long-term water absorption percentage, and is hence suitable for use as an aircraft windshield.Type: GrantFiled: March 2, 1998Date of Patent: November 30, 1999Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Minoru Shimizu, Yoshifumi Kubota, Jun Nakauchi
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Patent number: 5969046Abstract: A method for reacting a methylene-containing component such as an acrylic polymer prepared from acetoacetoxyalkyl (meth)acrylate and an alkene-containing component such as a polyfumarate, polymaleate, a polyester containing both fumarate and maleate groups or a polyacrylate comprises the reaction of a tertiary amine such as triethylene diamine and an epoxide such as a glycidyl-functional (meth)acrylic polymer in the presence of the methylene-containing component and alkene-containing component. The tertiary amine can be incorporated into the alkene-containing component such as the reaction of an unsaturated polyester with a compound having both tertiary amine and primary or secondary amine groups. The tertiary amine can be incorporated into the methylene-containing component such as an acrylic polymer derived from a tertiary amino-functional monmer and acetoacetoxyalkyl (meth)acrylate.Type: GrantFiled: April 9, 1991Date of Patent: October 19, 1999Assignee: Rohm and Haas CompanyInventors: F. J. Schindler, M. J. Hurwitz, M. H. Wolfersberger, R. L. Fulton, Jr., W. E. Feely
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Patent number: 5962588Abstract: The present invention provides a curable resin composition incorporating an oligomer containing blocked hydroxyl group, an epoxy-group containing compound, hydrolytic silyl-group containing compound, and a dissociation catalyst and/or curing catalyst, each possessing a specific molecular weight; a paint which uses this resin composition as a binder; and a coat-finishing method which coat-finishes any desired material using the aforementioned resin composition and paint. According to the present invention, it is possible to reduce viscosity, and consequently increase the coat non-volatile content and hence improve acid resistance, abrasion resistance, and the like. In addition, according to the present invention, it is possible to obtain a curable resin composition, paint using this curable resin composition, and coat-finishing method for this paint in which the aforementioned resin and paint have an extremely high utility and possess a high solid content wherein air bubbles and drip-runs are not generated.Type: GrantFiled: November 12, 1997Date of Patent: October 5, 1999Assignees: Dainippon Ink and Chemicals, Inc., Mazda Motor CorporationInventors: Goro Iwamura, Shigeki Matsui, Ichiro Azuma, Yoshiaki Marutani, Hiroyuki Uemura, Tadamitsu Nakahama, Shinji Sasaki, Kazuhi Koga, Takashi Tomita, Mika Ohsawa
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Patent number: 5962591Abstract: There is a need for halogen-free polymeric compositions which offer increased heat and ultraviolet light resistance for utilization in automotive interiors. For instance, it is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance.Type: GrantFiled: August 26, 1997Date of Patent: October 5, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Hung Dang Ngoc, Bernard Louis Marie Nigen
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Patent number: 5959029Abstract: The invention relates to a chemical composition containing a) a copolymer based on styrene and/or at least one alkyl (meth)acrylate, the quantity of styrene and/or alkyl (meth)acrylate being .gtoreq.50% by weight, based on the total monomers, and at least one further comonomer, and b) a water-soluble polymeric protective colloid, wherein about 2 to 30 parts per weight of the water-soluble polymeric protective colloid are allotted to 100 parts by weight of the copolymer, and c) optional further additives as required. The copolymer contains appoximately 0.1 to 50% by weight units of an epoxide-group-containing ethylenically unsaturated comonomer. Such units show reactive epoxide groups. The invention relates further to an aqueous polymer dispersion of said chemical composition, the production of same and a special method for obtaining the chemical composition from the polymer dispersion and special applications of the aqueous polymer dispersion and the chemical composition.Type: GrantFiled: August 18, 1997Date of Patent: September 28, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: Robert Koelliker, Harald Bachler
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Patent number: 5948866Abstract: A powder paint composition and application method therefor are provided which can form a paint coating which has superior mar resistance and for which the external appearance, such as its smoothness and sharpness, is excellent.This paint powder composition comprises a multi-functional vinyl-type copolymer (A) which has a glass transition temperature of 40.degree. C. and which contains functional groups which are reactable with carboxylic acid; a polycarboxylic acid (B); and a multi-functional vinyl-type copolymer (C) which has a glass transition temperature of 0.degree. C. and which contains functional groups which are reactable with carboxylic acid.Type: GrantFiled: August 19, 1997Date of Patent: September 7, 1999Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Hirofumi Takeda, Ikuo Nakaya, Michiya Sugiyama, Akio Shoji
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Patent number: 5932658Abstract: The present invention provides a curable resin composition having good curability and storage stability, which provides a cured film having excellent weather resistance, acid resistance and mar resistance. The curable resin composition comprises:(a) 20 to 80% by weight of a polycarboxylic acid having an acid value of 25 to 300 mg KOH/g based on solid and a number average molecular weight of 500 to 20000; and(b) 20 to 80% by weight of a polyepoxide having an epoxy equivalent of 100 to 800 and a number average molecular weight of 500 to 20000, prepared by copolymerizing: (1) 10 to 60% by weight of a long-chain epoxy monomer; and (2) 40 to 90% by weight of an ethylenically unsaturated monomer having no epoxy group. The present invention also provides a process for forming a cured film using the resin composition.Type: GrantFiled: June 24, 1996Date of Patent: August 3, 1999Assignee: Nippon Paint Co., Ltd.Inventors: Yasuo Tanaka, Takeshi Takagi, Shigeyuki Sasaki, Makoto Shimizu, Yoshitaka Okude
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Patent number: 5902644Abstract: A method of forming a topcoat from a base coat and clear coat comprises applying to the surface of an undercoat or intercoat a base coat containing (A) a compound having at least two epoxy groups per molecule, (B) a compound having at least two carboxyl groups per molecule, wherein at least one of compounds (A) and (B) possesses hydroxyl groups, (C) a melamine resin with from 0.3-3.5 imino groups, from 2-5.5 alkyl ether groups per triazine nucleus and having a polymerization degree of from 1.6-3.5, and (D) pigment(s); then applying a clear coat prepared from (A) a compound having at least two epoxy groups per molecule and (B) a compound having at least two carboxyl groups per molecule, and curing by heating.Type: GrantFiled: May 27, 1997Date of Patent: May 11, 1999Assignee: Kansai Paint Company, LimitedInventors: Yasumasa Okumura, Hiroshi Igarashi, Hiroshi Kitagawa, Hironori Tonomura
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Patent number: 5898052Abstract: The present invention provides a base coat composition for forming a topcoat comprising (A) a compound having at least two epoxy groups in one molecule, (B) a compound having at least two carboxyl groups in one molecule, (C) a melamine resin of a polymerization degree of 1.6 to 3.5 having 0.3 to 3.5 imino groups per triazine nucleus, 0.3 to 3.5 methylol groups per triazine nucleus and 2 to 5.5 alkyl ether groups per triazine nucleus and (D) a coloring pigment and/or a metallic pigment, at least one of the components (A) and (B) having a hydroxyl group. The present invention also provides a coating method using said base coat composition and a clear coat composition mainly comprising said components (A) and (B).Type: GrantFiled: October 3, 1996Date of Patent: April 27, 1999Assignee: Kansai Paint Company, Ltd.Inventors: Yasumasa Okumura, Hiroshi Igarashi, Hiroshi Kitagawa, Hironori Tonomura
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Patent number: 5889115Abstract: The invention provides a curable coating composition comprising:(a) a vinyl polymer having, in one molecule, (i) a group formed by half esterification of an acid anhydride group and (ii) a primary hydroxyl group,(b) a vinyl polymer having an epoxy group and a primary hydroxyl group in one molecule, and(c) a vinyl polymer having an ethoxysilyl group and a secondary hydroxyl group in one molecule, and a method of forming a top coat using said composition.Type: GrantFiled: February 1, 1996Date of Patent: March 30, 1999Assignee: Kansai Paint Company LtdInventors: Motoshi Yabuta, Masaaki Saika, Yasushi Nakao, Hiroshi Igarashi, Satoshi Ikushima
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Patent number: 5872192Abstract: Thermosetting powder coatings based on epoxide-containing acrylate copolymer resins are disclosed comprising:(A) an acrylate copolymer that contains glycidyl ether residues;(B) an aliphatic and/or cycloaliphatic polybasic acid and/or a polyol-modified anhydride of a polybasic acid and/or an amorphous or semi-crystalline carboxy-functional copolyester resin and/or a carboxy-functional acrylic resin;(C) and, optionally, fillers and/or pigments and/or additives wherein the acrylate copolymer (A) has a molecular weight (Mw) of 1,000 to 30,000 and a glass transition temperature of 20 to 120.degree. C. and is obtainable by, in a first step, preparing a hydroxyl-functional acrylate copolymer (D), which copolymer is then transformed into the acrylate copolymer (A), by reaction with epihaloalkanes. The aforementioned compositions can be processed further to give thermosetting powder coatings which can be applied to substrates such as metal to form protective coatings or films.Type: GrantFiled: August 11, 1997Date of Patent: February 16, 1999Assignee: EMS--Inventa AGInventors: Andreas Kaplan, Rene Gisler, Albert Reich
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Patent number: 5840806Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).Type: GrantFiled: January 7, 1997Date of Patent: November 24, 1998Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka
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Patent number: 5811484Abstract: A process is disclosed for preparing water-dilutable, acrylate copolymer-based lacquer binders. A polycarboxylic component is reacted with an epoxide group-containing polyhydroxylic component, and the carboxylic groups are then at least partially neutralized. As epoxide group-containing monomers for the polyhydroxylic components, glycidyl(meth)acrylate and/or glycidylallylether are used in proportions from 0.1 to 3% by weight. Associated with cross-linking components and if required with other lacquer binders, these lacquer binders are suitable for producing water-dilutable baking enamels with a low auxiliary organic solvent content.Type: GrantFiled: June 24, 1996Date of Patent: September 22, 1998Assignee: Vianova Resins AktiengesellschaftInventors: Werner Wilfinger, Ingo Kriessmann, Kurt Gossak
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Patent number: 5798413Abstract: Polar thermoplastic polyolefin blends are provided which are flexible and are particularly useful in replacing polyvinyl chloride sheeting used as liners, folders, etc. The blends comprise in general, a non-polar thermoplastic polyolefin, a functionalized polar ethylene copolymer, and a functionalized olefin polymer as a compatibilizer, all of which are chlorine-free.Type: GrantFiled: August 29, 1996Date of Patent: August 25, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Heinz H. Spelthann, Karlheinz Hausmann
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Patent number: 5786435Abstract: The present invention relates to a low solvent content-type resin composition, a low solvent content-type coating composition containing such a resin composition as a binder, and a method for coating such a coating composition. The resin composition comprises an oligomer containing an alicyclic epoxy group in a molecule and having a number average molecular weight (Mn) of 300 to 2000, a weight average molecular weight (Mw) of 300 to 4000 and an Mw/Mn ratio of 1 to 2.5. The coating composition comprises such a resin composition and a cationic polymerization catalyst, wherein the content of an organic solvent content is 0 to 40 wt. %. Since the present composition contains a low molecular weight oligomer, the viscosity of the composition is low even though the solid content is high. Accordingly, the content of the organic solvent can be much reduced.Type: GrantFiled: September 10, 1997Date of Patent: July 28, 1998Assignee: Mazda Motor CorporationInventors: Yoshiaki Marutani, Tadamitsu Nakahama, Shinji Sasaki, Hiroyuki Uemura, Kazuhi Koga, Takashi Tomita, Mika Ohsawa
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Patent number: 5762820Abstract: The invention relates to binders for self-crosslinkable varnishes and paints comprising one or a number of hydroxylated and/or carboxylated fluorinated copolymers and one or a number of epoxidized and/or alkoxylated acrylic copolymers.Type: GrantFiled: June 21, 1996Date of Patent: June 9, 1998Assignee: Elf Atochem S. A.Inventors: Patrick Kappler, Jean-Luc Perillon, Catherine Savary
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Patent number: 5760140Abstract: The invention relates to a composition based on ethylene copolymers for manufacturing floor coverings and comprising: a) a copolymer having at least one epoxide functional group, b) a copolymer of ethylene and of at least one unsaturated monomer having functional groups which are reactive with the epoxide functional group of a), c) fillers, and optionally d) ethylene-vinyl acetate or ethylene-alkyl (meth)acrylate copolymers. The floor coverings obtained have an abrasion according to DIN 53516 of less than 300 mm.sup.3, a resistance to scratching which is greater than 150 g, and an oxygen index which is greater than 30.Type: GrantFiled: May 15, 1995Date of Patent: June 2, 1998Assignee: Elf Atochem S.A.Inventor: Jean-Michel Pierrot
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Patent number: 5756584Abstract: A pressure sensitive adhesive that includes:(a) the polymerization product of:(i) 25-98 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(ii) 2-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(iii) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(b) at least one tackifier that is miscible in the polymerization product at room temperature.Type: GrantFiled: January 3, 1997Date of Patent: May 26, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Greggory S. Bennett, Christopher A. Haak, Craig A. Gustafson
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Patent number: 5753767Abstract: A thermoplastic polymer composition capable of being extruded comprises a reaction product of an ionomer and a polymer which contains a moiety which is reactive with the acid or neutralized acid group of the ionomer. The composition is sufficiently non-sticking that it can be extruded and calendered without substantial adherance to any hot metal parts. Since this thermoplastic polymer composition does not stick to hot metal parts, the composition is more than suitable as resilient flooring and welding rods.Type: GrantFiled: December 13, 1996Date of Patent: May 19, 1998Assignee: Armstrong World Industries, Inc.Inventor: Harry D. Ward
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Patent number: 5733823Abstract: There are provided a prepreg for a printed circuit board which comprises a glass cloth impregnated with a flame retardative resin composition comprising a (A) resin composed of a (a) styrenic polymer having syndiotactic configuration, a (b) polymer having compatibility with or affinity for the component (a) and further containing polar group, and a (c) thermoplastic resin other than the components (a) and (b) and/or a rubbery elastomer; a (B) halogenated polystyrene in which the amount of halogen atoms contained in halogen compounds generated under specific conditions is at most 1000 ppm by weight; a (C) flame retardant aid; an (D) organic filler or inorganic filler; and the above glass cloth, and also a substrate for printed circuit which comprises the prepreg or a laminate comprising a plurality of the prepregs laminated on each other, at least one side of the prepreg or laminate being laminated with a metallic layer.Type: GrantFiled: September 6, 1996Date of Patent: March 31, 1998Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Taizou Sugioka, Shinobu Yamao
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Patent number: 5719234Abstract: An object of the present invention is to provide a heat-curable high solid coating composition capable of forming a coating film which is excellent in both acid resistance and scratch resistance, and a method for forming a topcoat using said composition.The present invention provides a heat-curable high solid coating composition comprising:(A) a carboxyl-containing compound,(B) a vinyl polymer having an epoxy group, a hydroxyl group and a hydrolyzable alkoxysilyl group in one molecule,(C) a reactive organopolysiloxane, and(D) a crosslinked particulate polymer. The present invention also provides a method for forming a topcoat using said composition.Type: GrantFiled: November 12, 1996Date of Patent: February 17, 1998Assignee: Kansai Paint Company, LimitedInventors: Motoshi Yabuta, Masaaki Saika, Satoru Ito, Hiroyuki Okada, Yasumasa Okumura, Hiroshi Igarashi, Satoshi Ikushima
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Patent number: 5717033Abstract: A particulate polymer A having a mean particle size of less than 1000 nm consists ofa1: up to 99.8% by weight of at least one vinylaromatic monomer a1,a2: up to 99.8% by weight of at least one alkyl methacrylate a2 where the alkyl radical is of 1 to 8 carbon atoms,a3: up to 50% by weight of at least one polar, copolymerizable, ethylenically unsaturated monomer a3,a4: from 0.1 to 10% by weight of at least one polyfunctional, crosslinking monomer a4 anda5: from 0.1 to 15, preferably from 0.5 to 10, % by weight of at least one monomer a5 containing one or more acidic, basic or epoxy groups,the sum of the components a1, a2 and a3 being from 75 to 99.8% by weight, based on A, and the sum of a1, a2, a3, a4 and a5 being 100% by weight, based on A.Type: GrantFiled: September 18, 1996Date of Patent: February 10, 1998Assignee: BASF AktiengesellschaftInventors: Wolfgang Fischer, Norbert Guntherberg, Graham Edmund McKee
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Patent number: 5710211Abstract: According to the present invention, there are provided a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (A) having an epoxy group with a compound (B) having a thiol or thioester group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction; and a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (C) having a thiol or thioester group with a compound (D) having an epoxy group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction. According to the present invention, it is possible to efficiently introduce into PVA various functional groups having excellent reactivity, crosslinkability, ionic interactivity, water-solubility, interfacial physical properties, low-temperature flexibility, etc., under relatively mild reaction conditions.Type: GrantFiled: July 19, 1996Date of Patent: January 20, 1998Assignee: Kuraray Co., Ltd.Inventors: Toshiaki Sato, Naoki Fujiwara, Atsushi Jikihara