Heterocyclic Reactant Contains 1,2-epoxy Group Patents (Class 525/208)
  • Patent number: 5691419
    Abstract: A coating agent comprises a binding agentcontaining at least one acrylate copolymer (A) with carboxyl groups and/or at least one acrylate copolymer (B) with epoxide groups, the acrylate copolymers (A) and (B) being obtained by solution polymerization using less than 5% by weight based on the total weight of monomers of one or more polysiloxane macromonomers a.sub.1 having a number-average molecular weight of 1000 to 40,000 and on average 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; and one or more epoxy resins.
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: November 25, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Stephan Engelke, Michael Brunnemann, Olaf Rotter, Andreas Holst
  • Patent number: 5686531
    Abstract: A coating agent comprises a binding agent containing at least one acrylate copolymer (A) with carboxyl groups and/or at least one acrylate copolymer (B) with epoxide groups, the acrylate copolymers (A) and (B) being obtained by solution polymerization using less than 5% by weight based on the total weight of monomers of one or more polysiloxane macromonomers a.sub.1 having a number-average molecular weight of 1000 to 40,000 and on average 0.5 to 2.5 ethylenically unsaturated double bonds per molecule; one or more addition and/or condensation resins with carboxyl groups; and one or more epoxy resins.
    Type: Grant
    Filed: May 24, 1995
    Date of Patent: November 11, 1997
    Assignee: BASF Lacke + Farben, AG
    Inventors: Stephan Engelke, Michael Brunnemann, Olaf Rotter, Andreas Holst
  • Patent number: 5681889
    Abstract: The present invention provides hydrophilic crosslinked polymer fine particles made of a copolymer composed of:2-50% by weight of (a) a monoethylenic monomer having a polyoxyalkylene or polyvinylpyrrolidone chain,20-97% by weight of (b) a (meth)acrylamide type monoethylenic monomer,1-30% by weight of (c) a crosslinkable unsaturated monomer selected from the group consisting of compounds having, in the molecule, at least two polymerizable double bonds, and compounds having, in the molecule, at least one functional group selected from hydrolyzable silyl groups and 1,2-epoxy groups and one polymerizable double bond, and0-50% by weight of (d) other monoethylenic monomer. Said polymer fine particles are superior in polymerization stability as well as in dispersion stability during storage, undergoes no adverse effect by dispersion stabilizer owing to no use of said stabilizer, and are suitably used for formation of a hydrophilic film.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: October 28, 1997
    Assignee: Kansai Paint Co., Ltd
    Inventors: Masahiro Kondo, Hiroshi Inoue
  • Patent number: 5661219
    Abstract: A curable composition comprising (A) a compound having in the molecule two or more specific blocked carboxyl groups: (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the blocked carboxyl groups, and (C) a catalytic component selected from the following: (a) a thermal latent acid catalyst which comprises a compound having a epoxy group, a specific compound having a sulfur atom and a specific Lewis acid; (b) a thermal latent acid catalyst which comprises a specific compound, having at least one of a nitrogen atom, an oxygen atom, a phosphorus atom or a sulfur atom, a specific compound having a halogen atom and a specific Lewis acid having at least one of an aluminum atom, a zinc atom or a tin atom; or a mixture which comprises (c) a metallic chelate compound and a specific organic silicon compound or a condensate thereof.
    Type: Grant
    Filed: August 29, 1994
    Date of Patent: August 26, 1997
    Assignee: Nof Corporation
    Inventors: Yoshinori Nakane, Hiroki Mizutani, Hayato Ishibashi, Masahiro Ishidoya
  • Patent number: 5660937
    Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: August 26, 1997
    Assignee: Nippon Oil And Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5650475
    Abstract: The present invention relates to a low solvent content type-coating composition which provides the resultant coating with improved surface appearance, acid resistance, alkali resistance, weathering resistance, scuff resistance and solvent resistance, while the content of an organic solvent of the coating composition can be much reduced to 0 to 30% at 25.degree. C. The low solvent content type-coating composition comprises a vinyl oligomer having a blocked carboxyl group and an additional group selected from an epoxy group, a silanol group, a hydrolyzable silyl group and an acid anhydride group. The vinyl oligomer has a number average molecular weight (Mn) of 600 to 2000, a weight average molecular weight (Mw) of 600 to 5000, and a ratio of a weight average molecular weight/a number average molecular weight (Mw/Mn) of 1.0 to 2.5. The blocked carboxyl group and an additional group may be present in the same or different vinyl oligomers.
    Type: Grant
    Filed: July 31, 1995
    Date of Patent: July 22, 1997
    Assignee: Mazda Motor Corporation
    Inventors: Yoshiaki Marutani, Tadamitsu Nakahama, Takashi Tomita, Hiroyuki Uemura, Kazuhi Koga, Mika Ohsawa, Goro Iwamura
  • Patent number: 5639828
    Abstract: A curable coating composition is described comprising two components that are reactive with one another upon curing to form urethane linkages. The urethane-forming components are an active hydrogen groups-containing component and a polyisocyanate, or a carbamate groups-containing component and a carbamate group-reactive component. The composition further comprises a third component that includes one or more epoxide groups. Coatings prepared with this coating composition can be cured and coated with additional coating(s), providing good intercoat adhesion to the subsequent coating.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: June 17, 1997
    Assignee: BASF Corporation
    Inventors: Rodney L. Briggs, John W. Rehfuss, Walter H Ohrbom, Gregory G. Menovcik
  • Patent number: 5637645
    Abstract: The invention relates to a caoutchouc mixture for the manufacture of rubber products with low-temperature application capability, resistance to oil, low crystallization tendency, and high dynamic stressability, on the basis of natural caoutchouc, in particular viscosity-stabilized natural caoutchouc, and the usual mixture ingredients. The essence of said invention lies in that the caoutchouc mixture additionally contains 5 to 30% by weight 1,4-polybutadiene with a high cis-proportion, and 5 to 30% by weight epoxidized natural caoutchouc. An additional mixture variation is introduced.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: June 10, 1997
    Assignee: Phoenix Aktiengesellschaft
    Inventors: Manfred Klerk, Gerhard Merkmann, Karl-Heinz Krause
  • Patent number: 5625003
    Abstract: The present invention provides a golf ball having excellent hit feeling and control property as well as excellent flying performance and cut resistance, which comprises a core and a cover for covering the core, wherein a heated mixture of an ionomer resin and a polymer containing a glycidyl group is used as a main component of a base resin for the cover.
    Type: Grant
    Filed: February 16, 1993
    Date of Patent: April 29, 1997
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Akira Kato, Kuniyasu Horiuchi, Akihiko Hamada
  • Patent number: 5623018
    Abstract: Disclosed is a thermoplastic resin composition comprising (A) an amorphous resin and further comprising, per 100 parts by weight of the amorphous resin,0.01 to 20 parts by weight of (B) an epoxy group-containing ethylene copolymer, and0.01 to 20 parts by weight of at least one member selected from the group consisting of (C) a polyfunctional compound and (D) a carboxylic acid metal salt, wherein the polyfunctional compound contains, per molecule, at least two identical or different functional groups selected from the group consisting of carboxyl group, amino group, carboxylic acid anhydride group and a unit represented by the formula (1) ##STR1## wherein X and Y are identical and each represents oxygen atom or sulfur atom, or one of X and Y is an oxygen atom and the other is a sulfur atom, or wherein the polyfunctional compound contains, per molecule, at least one unit represented by the formula (2) ##STR2## wherein Z represents oxygen atom or sulfur atom.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 22, 1997
    Assignees: Sumitomo Chemical Company, Ltd., Sumika A&L Inc.
    Inventors: Tadayuki Ohmae, Noboru Yamaguchi, Kenzo Chikanari, Kiyoshi Ogura
  • Patent number: 5618884
    Abstract: Anhydride-functional polymerizable monomers having the structure: ##STR1## and polymers and reactive compositions prepared from these monomers are disclosed. The reactive compositions are especially useful in primer and clearcoat/basecoat applications.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: April 8, 1997
    Assignee: The Sherwin-Williams Company
    Inventors: Rubing Cai, Thomas W. Yokoyama
  • Patent number: 5578677
    Abstract: A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: November 26, 1996
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5574111
    Abstract: Crystalline propylene (co)polymers modified by grafting with a vinylpolybutadiene having 1,2-structure content of at least 10%.Said (co)polymers are reacted with a liquid vinylpolybutadiene in the presence of a non-peroxidic radical initiator at a temperature in the range 200.degree. to 350.degree. C., the liquid vinylpolybutadiene having a 1.2-structure content of at least 10% and being generally used in amounts within the range 0,5 to 20% by weight.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: November 12, 1996
    Assignee: Centro Sviluppo Settori Impiego S.r.l.
    Inventors: Corrado Brichta, Francesco Mascia, Amodio Di Somma, Gabriele Torregiani, Antonio Addeo
  • Patent number: 5569710
    Abstract: Polymer blends of at least one polar polymer are prepared by admixture with a poly(vinyl alcohol) and a (meth)acrylate copolymer also containing vinyl amide and/or unsaturated acid units. The ternary compositions have attractive processing and performance properties.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: October 29, 1996
    Assignee: Rohm and Haas Company
    Inventors: Edward E. LaFleur, William J. Work, Robert M. Amici, Newman M. Bortnick, Norman L. Holy
  • Patent number: 5565524
    Abstract: The present invention provides a golf ball which is superior in hit feeling, control properties, flying performances and cut resistance. As the base resin of the cover of the golf ball, a heated mixture composed of (A) an ionomer resin or a mixture thereof, (B) a terpolymer resin of .alpha.-olefin, unsaturated carboxylate and unsaturated carboxylic acid and (C) a glycidyl group-containing .alpha.-olefinic copolymer resin is used.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: October 15, 1996
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Akihiko Hamada, Yoshikazu Yabuki, Yoshinori Sano
  • Patent number: 5565538
    Abstract: Flame retardant additive for plastics, compositions containing the additive, and methods for preparing the additives and compositions. The additives include a halostyrene-glycidyl (meth)acrylate copolymer. The compositions include a thermoplastic substrate requiring flame retardancy and copolymers of a halostyrene and glycidyl (meth)acrylate.
    Type: Grant
    Filed: September 21, 1994
    Date of Patent: October 15, 1996
    Assignee: Great Lakes Chemical Corporation
    Inventors: Gurudas Zingde, Nicolai A. Favstritsky, Ray W. Atwell
  • Patent number: 5559192
    Abstract: An air curing polymer composition is disclosed which contains acetoacetate functional polymer and an autoxidizable material. The composition cures on exposure to oxygen. One pack stable ambient curing compositions and a method of stabilizing acetoacetate functional groups to prevent hydrolysis are also disclosed.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 24, 1996
    Assignee: Rohm and Haas Company
    Inventors: Daniel A. Bors, Alvin C. Lavoie, William D. Emmons
  • Patent number: 5559188
    Abstract: In a golf ball comprising a cover around a core, the cover is formed of a resin blend of 10-60 parts by weight of a thermoplastic elastomer having a crystalline polyethylene block and 90-40 parts by weight of an ionomer resin. The ball is well controllable, highly repulsive, and resistant to scuffing upon iron shots and offers pleasant hitting feel.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: September 24, 1996
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Yasushi Ichikawa, Hideo Watanabe
  • Patent number: 5549932
    Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: August 27, 1996
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5548029
    Abstract: Graft copolymers which are isoolefin/para-alkylstyrene copolymer represented by the formula ##STR1## in which R and R' can be hydrogen, alkyl, and the primary and secondary alkyl halides, "a" ranges from about 14 to about 70,000, "b" ranges from 0 to about 70,000, "c" ranges from 0 to about 70,000, "d" ranges from about 1 to about 70,000, X is a halogen, and Nu is a nucleophilic residue provided by a polymeric nucleophile.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: August 20, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Kenneth W. Powers, Hsien-Chang Wang, T-C. Chung, Anthony J. Dias, Joseph A. Olkusz
  • Patent number: 5543467
    Abstract: A golf ball having excellent hit feeling, control properties and flying performance. The golf ball has a core and a cover covering the core, and the base material of the cover comprises a heated mixture of an ionomer resin, a maleic anhydride-modified olefinic copolymer and a glycidyl group-containing olefinic copolymer.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: August 6, 1996
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Akihiko Hamada, Yoshikazu Yubuki, Akira Kato
  • Patent number: 5543462
    Abstract: The present invention relates to an impact resistant polystyrene composition which comprises an (A) styrenic polymer having syndiotactic configuration and a (B) rubbery elastomer modified by a modifier having a polar group, or to an impact resistant polystyrene composition which comprises the aforesaid composition and a (C) rubbery elastomer and/or a (D) poly(phenylene ether).The polystyrene compositions according to the present invention are excellent in heat resistance, modulus of elasticity, impact resistance and extensibility and thus are expected to find effective use for molding electric and electronic materials, industrial construction materials, automobile part, domestic electrical appliances, industrial materials such as various machine parts, etc.
    Type: Grant
    Filed: November 2, 1994
    Date of Patent: August 6, 1996
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akihiko Okada, Nobuyuki Sato
  • Patent number: 5541262
    Abstract: Crystalline propylene (co)polymers modified by grafting with a vinylpolybutadiene having 1,2-structure content of at least l0%.The (co)polymers are reacted with a liquid vinylpolybutadiene in the presence of a non-peroxidic radical initiator at a temperature in the range 200.degree. to 350.degree. C., the liquid vinylpolybutadiene having a 1,2-structure content of at least 10% and being generally used in amounts within the range 0.5 to 20% by weight.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 30, 1996
    Assignee: Centro Sviluppo Settori Impiego S.r.l.
    Inventors: Corrado Brichta, Francesco Mascia, Amodio Di Somma, Gabriele Torregiani, Antonio Addeo
  • Patent number: 5525673
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: June 11, 1996
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5508347
    Abstract: Disclosed is a thermoplastic resin composition comprising (A) an amorphous resin and further comprising, per 100 parts by weight of the amorphous resin,0.01 to 20 parts by weight of (B) an epoxy group containing ethylene copolymer, and0.01 to 20 parts by weight of at least one member selected from the group consisting of (C) a polyfunctional compound and (D) a carboxylic acid metal salt, wherein the polyfunctional compound contains, per molecule, at least two identical or different functional groups selected from the group consisting of carboxyl group, amino group, carboxylic acid anhydride group and a unit represented by the formula (1) ##STR1## wherein X and Y are identical and each represents oxygen atom or sulfur atom, or one of X and Y is an oxygen atom and the other is a sulfur atom, or wherein the polyfunctional compound contains, per molecule, at least one unit represented by the formula (2) ##STR2## wherein Z represents oxygen atom or sulfur atom.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: April 16, 1996
    Assignees: Sumitomo Chemical Company, Limited, Sumitomo Dow Limited
    Inventors: Tadayuki Ohmae, Noboru Yamaguchi, Kenzo Chikanari, Kiyoshi Ogura
  • Patent number: 5508352
    Abstract: The present invention provides, a curable resin composition and a process for forming a cured film therefrom wherein the cured film has not only excellent acid resistance but also good weather resistance, good mar resistance and sealer cracking resistance because of its high extensibility, The curable resin composition comprises (a) 20 to 80% by weight of a polymer having carboxyl and carboxylate groups; and (b) 20 to 80% by weight of a polymer having hydroxyl and epoxy groups.
    Type: Grant
    Filed: February 9, 1995
    Date of Patent: April 16, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Shigeyuki Sasaki, Takeshi Takagi, Yoshitaka Okude
  • Patent number: 5502111
    Abstract: Heat distortion temperature of polyvinyl chloride compositions can be significantly increased above the heat distortion temperature of uncompounded polyvinyl chloride while good appearance of extruded material is preserved by preblending an imidized acrylic resin having a glass transition temperature above 130.degree. C. with a third polymer melt-processable throughout the temperature range of 150.degree.-300.degree. C. under conditions where a two-phase blend is formed, wherein the third polymer forms the continuous phase and the imidized acrylic resin forms the dispersed phase and then melt-blending the two-phase blend with polyvinyl chloride at a temperature of 150.degree.-220.degree. C. to form a composition in which the imidized acrylic resin forms a substantially homogeneous blend with polyvinyl chloride.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: March 26, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Gia Huynh-Ba
  • Patent number: 5494970
    Abstract: A coating composition for a clearcoat in a multilayer coating system for metallic substrates is described, comprising:A) a resin with epoxy and hydroxy functionality;B) a resin with anhydride functionality;C) an aminoplast resin; andD) additives selected from the group consisting of solvents, catalysts, flow agents, hindered amine light stabilizers, ultraviolet absorbers.
    Type: Grant
    Filed: August 6, 1991
    Date of Patent: February 27, 1996
    Assignee: BASF Corporation
    Inventor: Paul Serdiuk
  • Patent number: 5470912
    Abstract: Polymeric powder coating compositions featuring improved physical properties including improved impact strength, improved adhesivity and other properties is provided by a polymeric powder coating composition which comprises: (a) polymeric powder coating resin, (b) at least one low molecular weight ethylene copolymer having a degree of saponification of at least 25%, (c) a further constituent selected from the group consisting of catalyzing agents, flow control agents, coloring agents, fillers, processing aids, wherein the weight ratio of (b) to (a) is preferably in the range of 0.01%-20% to 99.99%-80%. The powder coating composition may be applied to articles using conventional techniques. Processes for producing the polymeric powder coating compostiions, and articles comprising the same are also disclosed.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: November 28, 1995
    Assignee: AlliedSignal Inc.
    Inventor: Doanld F. Loar
  • Patent number: 5446101
    Abstract: A composite vinylidene chloride copolymer composition excellent in processability which comprises a vinylidene chloride copolymer A having a molecular weight of not less than 50,000 and not more than 300,000 and a vinylidene chloride copolymer B having a molecular weight of not less than 5,000 and not more than the smaller one of either 0.8 times the weight average molecular weight of the vinylidene chloride copolymer A or 80,000, and a monolayer film which comprises the composite vinylidene chloride copolymer composition and is excellent in various properties including barrier property, non-extractability by oily foods and high frequency sealability, and is suitable as a barrier packaging material and wrapping film used for ham, sausage and other like foods.
    Type: Grant
    Filed: October 18, 1994
    Date of Patent: August 29, 1995
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Noboru Anazawa, Yoshitaka Shimoda
  • Patent number: 5444122
    Abstract: An unsaturated acid-functional monomer having the structure: ##STR1## wherein R.sup.1 is hydrogen or methyl and Z is a direct bond or is a divalent radical having 1 to about 20 carbon atoms.
    Type: Grant
    Filed: February 17, 1995
    Date of Patent: August 22, 1995
    Assignee: The Sherwin-Williams Company
    Inventor: Rodney M. Harris
  • Patent number: 5436397
    Abstract: There are disclosed a polystyrene composition which comprises 100 parts by weight of a resin component comprising 0 to 99% by weight of SPS (a) and 100 to 1% by weight of a modified SPS (b) and 1 to 100 parts by weight of a rubbery elastomer which can react with the functional group of the component (b) as the component (c) and optionally, 1 to 350 parts by weight of an inorganic filler (e); and a polystyrene composition which comprises 100 parts by weight of a resin component comprising 0 to 99% by weight of the component (a) and 100 to 1% by weight of the component (b), 1 to 10 parts by weight of the component (c) and 1 to 100 parts by weight of a rubbery elastomer (d) and optionally, 1 to 350 parts by weight of an inorgaic filler (e). The above compositions are greatly improved in impact resistance, elongation and retention of physical properties during recycling without detriment to heat resistance and modulus of elasticity.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: July 25, 1995
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Akihiko Okada
  • Patent number: 5424365
    Abstract: An ambient curing coating composition made from at least two packages wherein one package contains a copolymer having acetoacetoxy groups and glycidyl groups plus an aluminum catalyst and the other package contains a copolymer having carboxylic acid groups plus a strong organic base catalyst.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: June 13, 1995
    Assignee: McWhorter Technologies, Inc.
    Inventors: Jim D. Elmore, Donald E. Babcock, William J. DeGooyer
  • Patent number: 5419929
    Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: May 30, 1995
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5420201
    Abstract: A thermoplastic resin composition exhibiting excellent processability and producing remarkable advantages in that it gives far better physical properties than that expected from each polymer which constitutes the thermoplastic resin composition. The composition can be easily processed into molded articles, films and sheets and can give products which have well-balanced properties among stiffness, heat resistance, impact resistance, scratch resistance, coatability, oil-resistance, chemical resistance, water resistance, etc. and which are excellent in appearance, uniformity and smoothness.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: May 30, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroomi Abe, Takeshi Fujii, Masashi Yamamoto, Shinji Date
  • Patent number: 5408001
    Abstract: Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: April 18, 1995
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5387646
    Abstract: The invention provides:1) a fluorine-containing resin composition including:a) a fluorine-containing resin having (i) a hydrolyzable group attached directly to a silicon atom and/or a silanol group and (ii) an epoxy group in the molecule, orb) a mixture of a component (I) having a hydrolyzable group attached directly to a silicon atom and/or a silanol group and a component (II) having an epoxy group, such that at least one of the components (I) and (II) is a fluorine-containing resin;2) a curable composition including the resin composition and a metal chelate compound; and3) a coating composition including this resin composition or this curable composition.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: February 7, 1995
    Assignee: Kansai Paint Company, Limited
    Inventors: Akimasa Nakahata, Nobushige Numa, Masahiro Yamane, Osamu Isozaki, Noboru Nakai
  • Patent number: 5384367
    Abstract: A curable composition useful as a clear coat in composite color plus clear coatings contains an epoxy group-containing acrylic copolymer having carbamate, urea or urethane pendant groups and a polyacid curing agent which is a carboxylic acid group-containing oligomer or polymer.
    Type: Grant
    Filed: April 19, 1993
    Date of Patent: January 24, 1995
    Assignee: PPG Industries, Inc.
    Inventors: Shanti Swarup, Brij N. Sharma, B. Keith Johnston
  • Patent number: 5374679
    Abstract: A sizing agent for paper, which comprises 100 parts by weight of a polyvinyl alcohol (component A) and from 1 to 20 parts by weight of a compound (component B provided with the following requisites (1) to (4):(1) the backbone chain is a random copolymer of ethylene oxide and propylene oxide, (2) in the backbone chain, the proportion of oxyethylene units is from 20 to 40% by weight, and the proportion of oxypropylene units is from 60 to 80% by weight, (3) of the two terminals, one terminal is a hydroxyl group, and the other terminal is a C.sub.1-10 alkoxyl group or a hydroxyl group, and (4) the weight average molecular weight is from 600 to 1,200.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: December 20, 1994
    Assignees: Denki Kagaku Kogyo Kabushiki Kaisha, Nippon Paper Industries Co., Ltd.
    Inventors: Yoshihumi Nosaka, Osamu Ishiguro
  • Patent number: 5369178
    Abstract: A resin composition for thermosetting coating, which comprises(a.sub.1) an acrylic copolymer having a particular acid value and/or (a.sub.2) an acrylic copolymer having a particular acid value and a particular hydroxyl value,(b) an acrylic copolymer having a particular epoxy equivalent,(c) a monobasic acid having a dissociation constant (pKa) of 3 or less, and, as necessary,(d) an amino resin and(e) a quaternary phosphoium salt,and wherein the equivalent ratio of the acid groups of (a.sub.1) and/or (a.sub.2) and the epoxy groups of (b) is 1:0.5 to 0.5:1 and the amounts of (c), (d) and (e) are 0.01-5 parts by weight, 1-25 parts by weight and 0.01-3 parts by weight, respectively, per 100 parts by weight of the total of (a.sub.1) and/or (a.sub.2) and (b).The resin composition, when used as a clear coating for automobiles, is superior in film appearance, acid resistance, solvent resistance water resistance, weatherability, storage stability and low temperature curing.
    Type: Grant
    Filed: July 1, 1992
    Date of Patent: November 29, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Eiichiro Miyazaki, Taisaku Kano
  • Patent number: 5367027
    Abstract: The present invention provides a curable resin composition which provides cured film having not only excellent acid resistance but also good weather resistance and good mar resistance. The curable resin composition comprises (a) a hydroxyl and carboxyl group containing polymer, (b) a carboxyl and carboxylate group containing polymer, and (c) a hydroxyl and epoxy group containing polymer.
    Type: Grant
    Filed: July 22, 1993
    Date of Patent: November 22, 1994
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Akira Fushimi, Tsuneyoshi Hisai, Kazuhiko Takeoka, Yoshitaka Okude
  • Patent number: 5352727
    Abstract: There are disclosed a polystyrene composition which comprises 100 parts by weight of a resin component comprising 0 to 99% by weight of syndiotactic polystyrene (SPS) (a) and 100 to 1% by weight of a modified syndiotactic polystrene (SPS) (b) and 1 to 100 parts by weight of a rubbery elastomer which can react with the functional group of the component (b) as the component (c) and optionally, 1 to 350 parts by weight of an inorganic filler (e); and a polystyrene composition which comprises 100 parts by weight of a resin component comprising 0 to 99% by weight of the component (a) and 100 to 1% by weight of the component (b), 1 to 10 parts by weight of the component (c) and 1 to 100 parts by weight of a rubbery elastomer (d) and optionally, 1 to 350 parts by weight of an organic filler (e). The above compositions are greatly improved in impact resistance, elongation and retention of physical properties during recycling without detriment to heat resistance and modulus of elasticity.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: October 4, 1994
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventor: Akihiko Okada
  • Patent number: 5352740
    Abstract: Thermosetting composition is excellent in storage stability, useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics.The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.
    Type: Grant
    Filed: April 4, 1991
    Date of Patent: October 4, 1994
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5344858
    Abstract: A composition useful as an aqueous anionic electrodepositable coating comprises a film-former of from about 67-95% by weight of a phosphated polyepoxide resin, from about 5-33% by weight of a carboxyl group-containing vinyl addition resin, and up to about 40% by weight of the film-former of a crosslinking agent.
    Type: Grant
    Filed: May 28, 1993
    Date of Patent: September 6, 1994
    Assignee: PPG Industries, Inc.
    Inventors: Terence J. Hart, Ellor J. Van Buskirk, Thomas R. Hockswender
  • Patent number: 5332780
    Abstract: Thermoplastic resin compositions having the following component A-1 or A-2, component B and component C:(A-1): a polymer component having a functional group capable of reacting with an amino group, or(A-2): a composition of component (A-1) and a resin that is non-reactive with an amino group and is different from the resin used in the following component B(B) a thermoplastic resin component that is non-reactive with an amino group under the conditions required to mold the entire resin composition; and(C) a graft copolymer obtained by a graft reaction of a thermoplastic polymer, with a compound (I), or a copolymer having the repeating unit (II) and the repeating unit of an ethylenic unsaturated monomer, ##STR1## wherein R.sup.1 -R.sup.4, the same or different represent a hydrogen atom, an alkyl group, a cycloalkyl group, an aryl group or an aralkyl group.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: July 26, 1994
    Assignee: Dai-Ichi Kogyo Seiyaku Co., Ltd.
    Inventors: Naoki Kitazawa, Manabu Kikuta, Hiroshi Hotta, Yutaka Nakayama, Hideyuki Sumi
  • Patent number: 5331052
    Abstract: Curable composition based on branched acrylates with COOH groups and/or branched acrylates with epoxide groups, and aminoplast resins.The present invention relates to a curable composition consisting ofA) a polymer with at least 2 COOH groups,B) a polymer with at least 2 epoxide groups andC) an aminoplast resin.At least one of components A) or B) is based on a branched soluble acrylate copolymer, more than 3 to 30% by weight, based on the total weight of the monomers, of a monomer with at least two polymerizable, olefinically unsaturated double bonds being used in the preparation of these branched acrylate copolymers and the proportions of the individual components relative to one another being chosen so that a molar ratio of 3:1 to 1:3 prevails between the carboxyl groups of component A) and the epoxide groups of component B) and a weight ratio of 65:35% by weight to 98:2% by weight prevails between the epoxy resin component and the aminoplast resin component.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: July 19, 1994
    Assignee: BASF Lacke + Farben AG
    Inventor: Werner A. Jung
  • Patent number: 5322894
    Abstract: A thermoplastic resin composition of the present invention contains at least one modified polypropylene resin or resin composition and an epoxy group-containing copolymer, which thermoplastic resin composition is suitably usable where a high-level balance among the properties is required, since said composition has easy processability into molded articles, films and sheets and can give products having well balanced properties among stiffness, heat resistance, impact resistance, scratch resistance, coatability, oil resistance, chemical resistance, water resistance, etc. and having excellent appearance, uniformity and smoothness.
    Type: Grant
    Filed: January 29, 1991
    Date of Patent: June 21, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Takeshi Fujii, Masashi Yamamoto
  • Patent number: 5310795
    Abstract: Novel addition polymers and copolymers derived from carbamate-functionalized vinyl monomers, and optionally one or more conventional vinyl monomers such as acrylonitrile and/or styrene, are disclosed. When the addition polymers or copolymers are melt processed with an elastomer containing moieties reactive with amines, novel addition polymer-rubber copolymers are formed which are useful as compatibilizers and impact modifiers in plastic blends, such as AES.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: May 10, 1994
    Assignee: General Electric Company
    Inventors: William P. England, Gregory J. Stoddard, James J. Scobbo, Jr.
  • Patent number: 5306771
    Abstract: High rubber graft thermoplastic compositions are prepared by melt blending an EPDM or an EP rubber and a copolymer derived from a vinyl cyanide compound and a vinyl aromatic compound. Both the copolymer and the rubber are independently either epoxy or carboxy functionalized.
    Type: Grant
    Filed: January 22, 1993
    Date of Patent: April 26, 1994
    Assignee: General Electric Company
    Inventors: Michael P. Laughner, Marinus E. J. Dekkers, James J. Scobbo, Jr., Robert J. Halley, Ronald L. Jalbert
  • Patent number: 5292825
    Abstract: A vulcanizable epoxy group-containing elastomer composition is disclosed, comprising (A) an epoxy group-containing elastomer, (B) an organic compound containing at least two ##STR1## bonds, wherein X and Y, which may be the same or different, each represents an oxygen atom or a sulfur atom, per molecule or an organic compound containing at least two carboxyl groups per molecule, and (C) a phosphine compound represented by formula: ##STR2## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl group having from 1 to 4 carbon atoms; and R represents a hydrogen atom or an alkoxy group having from 1 to 4 carbon atoms. The composition has excellent compression set, particularly in a high temperature atmosphere, as well as excellent mechanical characteristics.
    Type: Grant
    Filed: September 7, 1990
    Date of Patent: March 8, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Keisaku Yamamoto, Hideaki Yamada, Masahiro Fukuyama