Solid Polymer Derived From An Aromatic Hydrocarbon Reactant Patents (Class 525/241)
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Patent number: 7947751Abstract: Resin beads having an average particle size of from 0.001 mm to 10 mm and containing a continuous phase and a particulate dispersed phase are described. The continuous phase includes elastomeric polymers; the dispersed phase includes homopolymers and/or copolymers containing repeat units resulting from the polymerization of one or more aryl polymerizable monomers. The unexpanded polymer resin beads can be prepared by dispersing an organic phase containing elastomeric polymers and one or more monomers, into droplets and polymerizing the monomers in the organic droplets in a low shear flow pattern. The beads can be impregnated with blowing agents, expanded and can be used to make molded articles. Resin beads having a continuous phase comprising a nitrile rubber, and a dispersed phase comprising one or more homopolymers and/or copolymers containing repeat units resulting form the polymerization of one or more aryl polymerizable show prolonged retention of blowing agents in unexpanded form.Type: GrantFiled: November 13, 2009Date of Patent: May 24, 2011Assignee: NOVA Chemicals Inc.Inventors: Grazyna Petela, Michel F. J. Berghmans, Karel Cornelis Bleijenberg, Paul E. Arch
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Patent number: 7947782Abstract: The present invention concerns a vulcanizable composition, vulcanized products produced from it, and their use in particular in the production of golf balls or roll coverings.Type: GrantFiled: May 15, 2006Date of Patent: May 24, 2011Assignees: Rhein Chemie Rheinau GmbH, LANXESS Deutschland GmbH, LANXESS Inc.Inventors: Judy E. Hannay, Thomas Früh, Werner Obrecht
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Polymer mixture consisting of an impact-resistance modified poly (meth) acrylate and a fluoropolymer
Patent number: 7947781Abstract: The invention relates to a molded body consisting of plastic with a material thickness of at least 150 $g(m)m at any point. Said body contains a polymer mixture of an impact-resistance modified poly(meth)acrylate plastic, a polymethyl methacrylate matrix, elastomer particles contained in said matrix and a fluoropolymer. According to the invention, the fraction of the fluoropolymer in the mixture is between 30 and 95 wt. % and the polymer mixture of the impact-resistance modified poly(meth)acrylate plastic and the fluoropolymer is present in an outer layer with a continuous material thickness of at least 10 $g(m)m. The invention is characterized in that the impact-resistance modified poly(meth)acrylate plastic consists of between 20 and 70 wt. % poly(meth)acrylate matrix and between 30 and 80 wt. % elastomer particles.Type: GrantFiled: May 17, 2005Date of Patent: May 24, 2011Assignee: Evonik Rohm GmbHInventors: Thomas Arndt, Uwe Numrich, Norbert Deusch, Christoph Krohmer -
Patent number: 7939594Abstract: The invention provides a composition that contains at least one specific non-crosslinkable organic medium at least one microgel and at least one thickening agent, a process for the preparation thereof and uses of the compositions.Type: GrantFiled: March 13, 2006Date of Patent: May 10, 2011Assignees: Rhein Chemie Rheinau GmbH, LANXESS Deutschland GmbHInventors: Werner Obrecht, Torsten Ziser, Thomas Früh, Patrick Galda, Achim Fessenbecker
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Patent number: 7935401Abstract: A shrink film comprises a skin layer and a base layer. The skin layer may comprise polystyrene or modified polyester. The base layer may comprise alpha-olefin/cyclic-olefin copolymer or alpha-olefin/vinyl aromatic copolymer. The film has a free shrink at 100° C. of at least about 10%. The film is useful for shrink sleeve applications.Type: GrantFiled: October 27, 2005Date of Patent: May 3, 2011Assignee: Cryovac, Inc.Inventors: Slawomir Opuszko, Hubert J. Cook, Vincent W. Herran, Larry B. McAllister
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Patent number: 7935761Abstract: The present invention relates to a process for preparing a thermoplastic vulcanizate (TPV) comprising: contacting a thermoplastic polymer, a cross-linkable elastomer, at least one curative, and at least one cure activator in a solvent to form Composition A. The solvent is then removed, and thereafter the cross-linkable elastomer is at least partially cured. The average particle size of the cross-linkable elastomer is 10 microns or less after the solvent is removed.Type: GrantFiled: April 18, 2007Date of Patent: May 3, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, Peter W. Manders, Pradeep Shirodkar, Palanisamy Arjunan
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Patent number: 7923509Abstract: A composition for delivery of a therapeutic agent is provided. The composition comprises: (a) a biocompatible block copolymer comprising one or more elastomeric blocks and one or more thermoplastic blocks and (b) a therapeutic agent, wherein the block copolymer is loaded with the therapeutic agent. The block copolymer is preferably of the formula X-(AB)n, where A is an elastomeric block, B is a thermoplastic block, n is a positive whole number and X is a seed molecule. The elastomeric blocks are preferably polyolefin blocks, and the thermoplastic blocks are preferably selected from vinyl aromatic blocks and methacrylate blocks. According to another aspect of the invention, a medical device is provided, at least a portion of which is insertable or implantable into the body of a patient. The medical device comprises (a) the above biocompatible block copolymer and (b) a therapeutic agent, wherein the block copolymer is loaded with the therapeutic agent.Type: GrantFiled: October 13, 2009Date of Patent: April 12, 2011Assignee: Boston Scientific Scimed, Inc.Inventors: Leonard Pinchuk, Sepideh Hashemi, Marlene C. Schwarz, Kalpana Kamath, Ni Ding
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Patent number: 7915346Abstract: The invention relates to an impact modified acrylic sheet composition having a bimodal distribution of impact modifier particle sizes. The composition provides an optimal balance of impact performance and appearance after melt processing.Type: GrantFiled: September 28, 2006Date of Patent: March 29, 2011Assignee: Arkema FranceInventors: Harold R. Banyay, Brian Edgecombe
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Patent number: 7915345Abstract: This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.Type: GrantFiled: April 18, 2007Date of Patent: March 29, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, James R. Ayers, David J. Lohse, Peter W. Manders, Palanisamy Arjunan
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Patent number: 7906589Abstract: Interpolymer resin particles comprised of 20% to 60% by weight of uncross-linked polyolefin e.g. polyethylene, polypropylene, and from 40% to 80% by weight based on the weight of the particles of a vinyl aromatic monomer, e.g. styrene, that is polymerized in a suspension process to form an interpenetrating network of polyolefin with polymerized vinyl aromatic monomer particles and having a gel content of 0 to 1.5% by weight based on the weight of the particles for improved processability in end-use applications and improved ESCR properties. The interpolymer resin particles have a VICAT softening temperature from about 90° C. to about 115° C., and a melt index from 0.2 to 35.0 g/10 minutes (Condition G). The particles can be mixed with a blowing agent to form extruded foam articles, such as foam board, and can be used in extrusion, injection molding, rotomolding, and thermoforming processes to form a layer, e.g.Type: GrantFiled: July 9, 2008Date of Patent: March 15, 2011Assignee: NOVA Chemicals Inc.Inventor: Steven M. Krupinski
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Publication number: 20110060103Abstract: Embodiments of the invention provide a class of mesophase separated butene/?-olefin block interpolymers with controlled block sequences. The butene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block butene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (TREF'), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the butene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: ApplicationFiled: January 30, 2009Publication date: March 10, 2011Applicant: Dow Global Technologies Inc.Inventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts
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Publication number: 20110060086Abstract: A copolymer is formed from an isoolefin having from 4 to 7 carbon atoms and an alkylstyrene. The copolymer has a substantially homogeneous compositional distribution. The copolymer has from about 8 to about 12 wt % of alkylstyrene and at least 85 wt % of isoolefin. The copolymer is preferably halogenated with about 1.1 to about 1.5 wt % of a halogen. The copolymer may in elastomeric nanocomposites. To obtain a good dispersion of the nanoclay in a formulated compound, at least one cure accelerator is selected from the group consisting of mercaptobenzothiazole disulfide, mercaptobenzothiazole, cyclohexyl benzothiazole disulfide, dibutyl thiourea, tetramethylthiuram disulfide, 4-4-dithiodimropholine, zinc dimethyldithiocarbamate, and zinc dibutylphosphorodithiate.Type: ApplicationFiled: August 23, 2010Publication date: March 10, 2011Inventors: Michael Brendan Rodgers, Weiqing Weng, John Patrick Soisson, Robert Norman Webb, Sunny Jacob
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Patent number: 7902298Abstract: High-temperature-curing reactive compositions based on natural and/or synthetic elastomers containing olefinic double bonds, and on vulcanizing agents, are described, which contain at least one liquid polyene having a molecular weight between 400 and 80,000 and at least one liquid polybutadiene having a narrow molecular weight distribution and a microstructure of 10 to 20% vinyl-1,2 double bonds, 50 to 60% trans-1,4 double bonds, and 25 to 35% cis-1,4 double bonds in the molecule. These compositions furthermore contain a vulcanizing system of sulfur and accelerators and/or, if applicable, quinone oximes. These compositions are suitable for use as a single-component adhesive, sealant, or coating compound in automobile manufacture, with high tensile shear strength and high impact peel strength even, in particular, at low temperatures.Type: GrantFiled: July 31, 2008Date of Patent: March 8, 2011Assignee: Henkel AG & Co. KGaAInventors: Rainer Kohlstrung, Klaus Rappmann
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Patent number: 7902288Abstract: A method of making a sealant material, such as a grease material, which includes providing a diblock copolymer, where the diblock copolymer includes a plurality of styrene zones and a plurality of rubber zones, and where the styrene zones have a glass transition temperature, and combining the diblock copolymer with mineral oil at a processing temperature less than about the glass transition temperature of the styrene zones. Also disclosed are such sealant and gel materials.Type: GrantFiled: May 31, 2005Date of Patent: March 8, 2011Assignee: 3M Innovative Properties CompanyInventor: William V. Dower
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Publication number: 20110054121Abstract: Embodiments of the invention provide a class of butene/?-olefin block interpolymers. The butene/?-olefin inter-polymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.3. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block butene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the butene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: ApplicationFiled: January 30, 2009Publication date: March 3, 2011Inventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Philip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Metin, Patricia L. Robert
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Patent number: 7893159Abstract: The present invention includes a composition comprising a propylene-alpha olefin copolymer having at least seventy weight percent units derived from propylene, and from ten to twenty five weight percent units derived from ethylene or a C4-C10 alpha olefin, the propylene-alpha olefin copolymer exhibiting a heat of fusion of less than 37 Joules/gram and a melt flow rate of from 0.1 to 100 gram/10 minutes; and a styrenic block copolymer, wherein the weight ratio of the propylene-alpha olefin copolymer to the styrenic block copolymer is from 3:7 to 7:3. The composition exhibits tensile modulus of less than 20 MPa, tensile strength of at least 5 MPa, and elongation at break of at least 900% with low relative immediate set.Type: GrantFiled: December 22, 2006Date of Patent: February 22, 2011Assignee: Dow Global Technologies Inc.Inventor: Andy C. Chang
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Patent number: 7884150Abstract: Flame retardant polymeric blend compositions including a synergistic combination of flame retardants, including a halogenated flame retardant and a nanoparticulate, such as an organically modified clay or a natural nanoclay. The compositions are thermoplastic elastomers, include a polyolefin and a styrenic block copolymer, and exhibit high char formation upon burning as well as desirable vertical burn characteristics. In a preferred embodiment, the flame retardants include at least a halogenated flame retardant and a metal oxide.Type: GrantFiled: August 17, 2007Date of Patent: February 8, 2011Assignee: Teknor Apex CompanyInventors: Biing-Lin Lee, Darnell C. Worley, II
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Publication number: 20110024011Abstract: This invention discloses a tire which is comprised of a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, wherein said tread is adapted to be ground-contacting, and wherein said tread is comprised of (1) a filler, (2) a cured rubbery polymer, and (3) core-shell particles which are comprised of (a) a crosslinked elastomeric core consisting essentially of repeat units that are derived from at least one conjugated diolefin monomer and from 15 weight percent to 30 weight percent at least one crosslinking monomer, wherein the crosslinked elastomeric core is a polymeric composition having a glass transition temperature which is within the range of ?20° C. to 20° C., and (b) a polymeric shell which is derived from at least one vinyl aromatic monomer, wherein the polymeric shell has a glass transition temperature which is within the range of 50° C.Type: ApplicationFiled: October 13, 2010Publication date: February 3, 2011Applicant: THE GOODYEAR TIRE & RUBBER COMPANYInventors: Eric Sean Castner, Lei Zheng, Feng Anne Xie, Ping Zhang
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Patent number: 7875678Abstract: Compositions, processes, and methods are provided relating to styrenic polymers, including high impact polystyrene (HIPS), also referred to as rubber-modified polystyrene. In one aspect, a process is provided for making high impact polystyrenes, comprising the steps of combining a monovinylarene component, a monovinylarene-conjugated diene block copolymer, and a conjugated diene polymer. In another aspect, the feed components form an emulsion having a continuous phase and a dispersed phase. The continuous phase comprises at least a portion of the monovinylarene component and at least a portion of the conjugated diene polymer. The dispersed phase is suspended within the continuous phase, and comprises globules having at least a portion of the monovinylarene-conjugated diene block copolymer, a remaining portion of the monovinylarene component, and a remaining portion of the conjugated diene polymer.Type: GrantFiled: April 11, 2006Date of Patent: January 25, 2011Assignee: Chevron Phillips Cheimcal Company, LPInventors: Michael J. Hanner, Chen-Youn Sue, Clifford C. Pettey, Carleton Stouffer, Paul M. Hunt, Ken E. Bowen
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Patent number: 7868093Abstract: Process for removal of residual styrene monomers from polystyrene and from blends comprising water-insoluble, crosslinked polyvinylpyrrolidone, via treatment with water, which comprises carrying out the treatment on a particulate solid blend.Type: GrantFiled: March 14, 2006Date of Patent: January 11, 2011Assignee: BASF SEInventors: Klemens Mathauer, Marianna Pierobon, Tobias Petsch, Karl-Otto Heilmann, Michael Kerber, Robert Bayer
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Publication number: 20110003104Abstract: A dielectric weldable material includes a blend of at least two components including an inert polymer and an elastomeric polar polymer. A method of forming a bond includes providing a substrate having a first end and a second end, wherein the substrate includes a blend of at least two components including an inert polymer and an elastomeric polar polymer. The method further includes bonding the first end and second end of the substrate with high frequency electromagnetic energy.Type: ApplicationFiled: July 2, 2010Publication date: January 6, 2011Applicant: SAINT-GOBAIN PERFORMANCE PLASTICS CORPORATIONInventors: Sridhar Krishnamurthi Siddhamalli, Mark W. Simon, Michael E. Cahill
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Patent number: 7863385Abstract: A vinyl•cis-polybutadiene rubber is provided containing 1,2-polybutadiene and a polymer substance of a melting point lower than that of the 1,2-polybutadiene and with at least one unsaturated double bond per repeating unit, where the 1,2-polybutadiene and the polymer substance are dispersed at physically and/or chemically adsorbed states in the cis-polybutadiene rubber as the matrix component of the vinyl•cis-polybutadiene rubber, and a method for producing the same, to provide a vulcanized product exerting a small die swell ratio and excellent extrusion processability and operability, as well as very great characteristics demanded for the side tread of tire and the like.Type: GrantFiled: March 1, 2010Date of Patent: January 4, 2011Assignee: Ube Industries, Ltd.Inventors: Yoshio Asakura, Yasuyoshi Okabe
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Patent number: 7863383Abstract: The invention relates to a polyolefin-based heat sealable and peelable seal. The peelable seals comprise from 5 to 98 percent by weight of a propylene based plastomer or elastomer and from 2 to 95 percent by weight of a second polymer selected from the group consisting of polyethylene, polybutylene, and styrenic polymer and mixtures thereof. The invention also relates to tamper evident peelable seals. The invention also relates to methods of making and using the heat sealable, peelable seal.Type: GrantFiled: September 8, 2006Date of Patent: January 4, 2011Assignee: Dow Global Technologies Inc.Inventors: Julie W. Gibbons, Alveda J. Williams, Rajen M. Patel, Jeffrey J. Wooster, Enrique Torres, Miguel A. Prieto Goubert, Olga Bertran
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Publication number: 20100331474Abstract: A method of modifying the rheology of a thermoplastic resin that includes the steps of providing a thermoplastic resin and blending interpolymer resin particles with the thermoplastic resin. The interpolymer resin contains a styrenic polymer intercalated within a polyolefin, such that the thermoplastic resin is present as a continuous phase and the interpolymer resin is present as a dispersed phase. The method provides a rheology modified thermoplastic resin with improved physical characteristics.Type: ApplicationFiled: March 17, 2010Publication date: December 30, 2010Applicant: NOVA CHEMICALS INC.Inventor: Eric Vignola
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Patent number: 7851558Abstract: A thermally stable brominated butadiene copolymer, such as brominated styrene/butadiene block copolymer, brominated random styrene/butadiene copolymer or brominated styrene/butadiene graft copolymer, preparation of the brominated butadiene copolymers, use of the brominated butadiene copolymers as a flame retardant additive and polymeric compositions, both foamed and non-foamed, that incorporate a flame-retarding amount of brominated butadiene copolymer.Type: GrantFiled: October 23, 2006Date of Patent: December 14, 2010Assignee: Dow Global Technologies Inc.Inventors: Bruce A. King, William G. Stobby, Daniel J. Murray, Anteneh Z. Worku, Inken Beulich, Sheila M. Tinetti, Stephen F. Hahn, Ray E. Drumright
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Patent number: 7851556Abstract: A thermoplastic vulcanizate comprising a dynamically-cured rubber, where the rubber is selected from the group consisting of ethylene-propylene-non-conjugated diene rubber, propylene-based rubbery copolymers with units derived from non-conjugated diene monomers, and butyl rubber, where dynamic vulcanization is effected with a phenolic resin or a silicon-containing curative, and where the rubber is dynamically cured to an extent where greater than 94% by weight of the rubber is insoluble in cyclohexane at 23° C., and from about 25 to about 250 parts by weight of a thermoplastic polymer phase per 100 parts by weight rubber, where from about 75% to about 100% by weight of said thermoplastic polymer phase includes a butene-1-based polymer.Type: GrantFiled: January 12, 2007Date of Patent: December 14, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Tonson Abraham, Norman G. Barber
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Patent number: 7851553Abstract: The present invention relates to a composition comprising at least two incompatible thermoplastic polymers and at least one compatibilizer, to a method of preparing this composition, and to the use of said composition for the manufacture of thermoplastic articles or semi-finished products having, in particular, improved mechanical properties. A composition according to the invention is such that said polymeric compatibilizer includes at least two groups of polar and apolar units compatible with the respectively polymers, and it is characterized in that it comprises the product of a hot compounding reaction, in the presence of a crosslinking system, of said compatibilizer in the crosslinkable state with said thermoplastic polymers, in such a way that only said compatibilizer is crosslinked in said composition.Type: GrantFiled: August 3, 2006Date of Patent: December 14, 2010Assignee: HutchinsonInventors: Nicolas Garois, Philippe Sonntag, Logan Bouchereau
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Patent number: 7847024Abstract: Compositions including a thermoplastic elastomer or thermoplastic vulcanizate derived from a styrenic block copolymer having a reactive or crosslinkable hard block including aromatic vinyl repeat units and also preferably a crosslinkable soft block, and a non-olefin thermoplastic polymer or copolymer and preferably a compatibilizer such as the reaction product of a non-olefin thermoplastic polymer and a functionalized polymer such as a maleic anhydride functionalized styrenic block copolymer that is compatible with the styrenic block copolymer having a reactive or crosslinkable hard block, and optionally a linking compound. The vulcanizates are prepared by crosslinking the styrenic block copolymer in the presence of the non-olefin thermoplastic polymer and a suitable crosslinking agent, and optionally the compatibilizer, preferably utilizing dynamic vulcanization.Type: GrantFiled: February 23, 2007Date of Patent: December 7, 2010Assignee: Teknor Apex CompanyInventors: Darnell C. Worley, II, Elliot ByungHwa Lee, Raman Patel, Jushik Yun
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Patent number: 7834095Abstract: Disclosed are blends of polystyrene and at least one of syndiotactic polypropylene, ethylene propylene copolymers, and styrene-butadiene-styrene triblock copolymers. These blends are prepared using solution polymerization and have unique morphologies and desirable physical properties. The blends can also be prepared with graft-promoting or crosslinking agents and rubbers to prepare modified high impact polystyrene.Type: GrantFiled: December 11, 2008Date of Patent: November 16, 2010Assignee: Fina Technology, Inc.Inventor: Jose Sosa
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Publication number: 20100273951Abstract: An anti-blocking agent master batch is provided, obtained by compounding 100 parts by mass of a polyolefin-based resin with 1 to 40 parts by mass of polymer fine particles, the polymer fine particles obtained by: causing two or more fluids including a liquid medium, a monomer or monomers, and a polymerization initiator to continuously and successively pass through a plurality of net bodies which are disposed at given intervals in a cylindrical passage and each have a surface crossing a direction of the passage to obtain an emulsion including liquid droplets containing the monomer or monomers and the polymerization initiator, the liquid droplets being dispersed in the liquid medium; and heating this emulsion to polymerize the monomer or monomers. Also provided is a manufacturing method thereof.Type: ApplicationFiled: October 1, 2008Publication date: October 28, 2010Inventors: Toshikatsu Shoko, Shozo Hayashi, Hideko Hayashi, Yasuo Togami, Akira Takagi
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Patent number: 7820771Abstract: Rubber composition based on at least one diene elastomer, a polymeric filler as reinforcing filler and a coupling agent for bonding between the polymeric filler and the elastomer. The polymeric filler includes nanoparticles of a polyvinylaromatic (PVAr) carrying a functional group denoted by Z of formula a ?Si—X, X representing a hydroxyl or hydrolyzable group. The PVAr is especially a copolymer of styrene, ethylvinylbenzene, divinylbenzene and trimethoxysilylpropylacrylate or trimethoxysilylpropylmethacrylate, being in the form of nanobeads, the diameter of which is between 10 and 100 nm. Also described is a method of obtaining such a composition, and use of such a rubber composition for the manufacture of rubber articles, in particular tires or rubber semi-finished products intended for these tires, as well as a masterbatch including at least one diene elastomer and such a polymeric filler, and a method of obtaining such a masterbatch.Type: GrantFiled: December 30, 2005Date of Patent: October 26, 2010Assignee: Michelin Recherche et Technique S. A.Inventors: Arnaud Lapra, Sylvie Gandon-Pain, Franck Varagniat
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Publication number: 20100267884Abstract: The present invention relates to arborescent polymers and to a process for making same. In one embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with a polymer or copolymer having a low glass transition temperature (Tg), and to a process for making such arborescent polymers. In another embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with less than about 5 weight percent end blocks derived from a polymer or copolymer having a high glass transition temperature (Tg), and to a process for making such arborescent polymers.Type: ApplicationFiled: November 20, 2009Publication date: October 21, 2010Applicant: LANXESS, INC.Inventors: Gabor Kaszas, Kevin Kulbaba
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Publication number: 20100256305Abstract: The invention relates to block polymers, for example, arborescent copolymer compounds, and to methods of making and purifying such compounds. In one embodiment, the invention relates to arborescent polymer compounds that contain one or more styrene polymeric blocks in combination with one or more isobutylene polymeric blocks. In another embodiment, the invention relates to methods for purifying arborescent polymer compounds that contain at least one styrene polymeric block in combination with at least one isobutylene polymeric block.Type: ApplicationFiled: October 29, 2009Publication date: October 7, 2010Applicant: LANXESS, INC.Inventor: Gabor Kaszas
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Publication number: 20100240834Abstract: A method of improving the stress crack resistance of an impact modified styrenic polymer comprising (a) combining about 95 to about 99.5 wt. % of an impact modified styrenic polymer with about 0.5 to about 5 wt. % of a polymer solution comprising about 25 to about 75 wt. % polyisobutylene and about 25 to about 75 wt. % of a polyolefin comprising one or more C2 to C12 alpha olefins.Type: ApplicationFiled: February 23, 2010Publication date: September 23, 2010Applicant: INEOS NOVA LLCInventors: Thomas Cochran, Jeffrey P. Viola
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Publication number: 20100234801Abstract: Disclosed is a resin composition for balloons, which is excellent in gas permeation resistance and hydrolysis resistance (acid resistance), while having an excellent balance among flexibility, mechanical strength and elastic recoverability. Also disclosed is a balloon made of such a resin composition for balloons. Specifically disclosed is a resin composition for balloons, which is characterized by containing an isobutylene block copolymer (A) having a polymer block (a) mainly composed of isobutylene and a polymer block (b) mainly composed of an aromatic vinyl monomer. This resin composition for balloons is also characterized in that the polymer block (b) is 10-40% by weight of the weight of the isobutylene block copolymer (A).Type: ApplicationFiled: October 27, 2008Publication date: September 16, 2010Applicant: Kaneka CorporationInventors: Kazumasa Ohara, Hidekazu Miyauchi
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Patent number: 7795351Abstract: Adhesive composition for bonding and filling large assemblies, including a mixture of about 5 percent to about 75 percent by weight of a thermoplastic polymer, about 0.5 percent to about 35 percent by weight of a polyester resin or vinyl ester resin, and about 20 percent to about 80 percent by weight of an alkyl acrylate or methacrylate monomer.Type: GrantFiled: December 28, 2006Date of Patent: September 14, 2010Assignee: IPS CorporationInventors: Samuel B. Osae, Paul C. Briggs
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Patent number: 7790808Abstract: Disclosed is a method for producing a thermoplastic resin composition, the method including a first step of melt-kneading 100 parts by weight component (A) and from 15 to 200 parts by weight of component (B) to form a melt-kneaded material, and a second step of melt-kneading from 35 to 2300 parts by weight of additional component (B) with the melt-kneaded material formed in the first step, wherein component (A) is an elastomer having a melt viscosity, as measured at a temperature of 230° C. and a shear rate of 121 sec?1, of 1500 Pa·s or more and the component (B) is a polyolefin resin.Type: GrantFiled: November 14, 2005Date of Patent: September 7, 2010Assignee: Sumitomo Chemical Company, LimitedInventors: Satoru Moritomi, Takashi Sanada
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Patent number: 7781529Abstract: The invention relates to polymeric resin blends containing polyelectrolyte resins blended into a polymer or copolymer matrix. Specifically, the polyelectrolyte resins are (co)polymers without hydrolyzable groups. The matrix polymer is a tough, and highly chemical-resistant (co)polymer, preferably a fluoropolymer. The polymeric resin blend is useful for forming films, and especially films useful for MEAs for use in fuel cells.Type: GrantFiled: June 18, 2008Date of Patent: August 24, 2010Assignee: Arkema Inc.Inventors: James T. Goldbach, David A. Mountz
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Patent number: 7781530Abstract: Polymeric compositions and methods of making and using such compositions are provided. The compositions incorporate a first component that is an isobutylene-based polymer and a second component having propylene-derived units and polyene derived units. The polymeric compositions have desirable processability characteristics, particularly for injection molding applications.Type: GrantFiled: January 13, 2006Date of Patent: August 24, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Hsien-Chang Wang, Wai Keung Wong, Srivatsan Srinivas Iyer, Pascal Van Hoeck
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Patent number: 7776968Abstract: The invention provides a thermoplastic elastomer composition comprising: (a) 100 parts by weight of a hydrogenated block copolymer; (b) 0.01 to 3 parts by weight of an organic peroxide; and (c) 1 to 80 parts by weight of a carboxylated liquid polybutadiene. Also disclosed is a thermoplastic resin composition comprising the thermoplastic elastomer composition.Type: GrantFiled: February 3, 2005Date of Patent: August 17, 2010Assignee: Riken Technos Corp.Inventors: Michihisa Tasaka, Satoshi Takahashi
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Publication number: 20100203785Abstract: A composition having a sulfonated block copolymer which is solid and non-dispersible in water having at least two polymer end blocks A, at least one polymer interior block B, and at least one polymer block D. Each A block is a segment of one or more polymerized para-substituted styrene monomers, each B block contains segments of one or more vinyl aromatic monomers selected from polymerized (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) 1,1-diphenylethylene, (vi) 1,2-diphenylethylene and (vii) mixtures thereof, and each D block having a glass transition temperature of less than 20° C. and a number average molecular weight of between 1,000 and 50,000 Adhesives, coatings and membranes are formed from the composition. Various articles are formed with the composition including films, fibers, fabrics, laminates, and absorbent cores.Type: ApplicationFiled: April 20, 2010Publication date: August 12, 2010Applicant: KRATON POLYMERS U.S. LLCInventors: Carl Lesley Willis, Dale Lee Handlin, JR., Scott Russell Trenor, Brian Douglas Mather
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Patent number: 7772323Abstract: The present invention relates to conjugated copolymers comprising blocks which are linked by random or partly random sections. The materials of the invention display an improved efficiency, a reduced operating voltage and a longer life.Type: GrantFiled: August 12, 2004Date of Patent: August 10, 2010Assignee: Merck Patent GmbHInventors: Heinrich Becker, Esther Breuning, Aurélie Falcou, Amir Parham
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Patent number: 7767311Abstract: Disclosed are adhesive compositions comprising nonfunctionalized base resins and functionalized ethylene copolymers such as ethylene/maleic anhydride (E/MAH) or ethylene/ethyl hydrogen maleate (E/MAME) copolymer, which are synthesized directly in a high pressure autoclave. These adhesive compositions can be applied as self-supporting films or can be co-extruded or extrusion coated onto a substrate. Also disclosed are multilayer structures, films, pipe coatings and building panels comprising these compositions.Type: GrantFiled: July 28, 2005Date of Patent: August 3, 2010Assignee: E.I. du Pont de Nemours and CompanyInventor: Richard T. Chou
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Patent number: 7762295Abstract: A rubber composition for a tire and a tire made therefrom which possesses excellent grip performance and abrasion resistance, said rubber composition containing a diene rubber and an aromatic vinyl polymer having a glass transition temperature at most 10° C., the amount of the aromatic vinyl polymer being preferably 5 to 150 parts by weight based on 100 parts by weight of the diene rubber.Type: GrantFiled: September 25, 2006Date of Patent: July 27, 2010Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kazuyuki Nishioka, Katsumi Terakawa
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Publication number: 20100184919Abstract: The present invention concerns a monovinylaromatic polymer composition comprising a bio-sourced polymer dispersed phase and optionally a rubber dispersed phase wherein said bio-courced polymer dispersed phase is predominantly made of particles having a size of less than 10 ?m. The present invention also relates to a process (hereunder referred as the first process) to make said monovinylaromatic polymer composition, said process comprising admixing: a monovinylaromatic monomer, at least one bio-sourced polymer, optionally a rubber, at conditions effective to polymerize at least a part of the monovinylaromatic monomer and generate a compatibilizer of the bio-sourced polymer and monovinylaromatic polymer.Type: ApplicationFiled: March 19, 2008Publication date: July 22, 2010Applicant: TOTAL PETROCHEMICALS FRANCEInventor: Michel Duc
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Patent number: 7759427Abstract: An elastomeric compound comprises 20-80 parts per hundred cross-linkable materials of liquid elastomer. The liquid elastomer has a complex dynamic viscosity less than 5 McP (5,000 N*s/m2) at a temperature between 20° C. and the maximum flow temperature TF, and the elastomeric compound the elastomeric material has a complex dynamic viscosity of less than 5 McP (5,000 N*s/m2) for at least 2 minutes at a maximum flow temperature TF.Type: GrantFiled: February 16, 2010Date of Patent: July 20, 2010Assignee: Veyance Technologies, Inc.Inventors: Douglas Bruce Wood, Thomas George Burrowes
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Patent number: 7754325Abstract: Disclosed is a rubber-modified styrene-based resin comprising a styrene-based polymer forming a matrix and rubber-like polymer particles dispersed in the matrix like islands, each of the rubber-like polymer particles having a cross sectional structure where the styrene-based polymer particles are contained like islands-sea, wherein the rubber-modified styrene-based resin is constituted of 1-10 wt % of the rubber-like polymer and 99-90 wt % of the styrene-based polymer; the particle-diameter of the rubber-like polymer particle falls within a range of 1.0 to 5.0 ?m; and a value of (styrene-based polymer weight/rubber-like polymer weight) in a methylethylketone-insoluble matter of the rubber-modified styrene-based resin falls within a range of 0.5 to 1.5.Type: GrantFiled: January 30, 2007Date of Patent: July 13, 2010Assignee: PS Japan CorporationInventors: Mitsutoshi Toyama, Shinichi Nakayama
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Publication number: 20100170636Abstract: A description is given of a semi-interpenetrating network having a first phase of a linear noncrosslinked isobutene polymer and a second phase of a crosslinked polymer, wherein the crosslinked polymer is obtained by crosslinking molecular enlargement reaction in the presence of the isobutene polymer. The crosslinked polymer is preferably obtained by free-radical polymerization of ethylenically unsaturated monomers comprising at least one polyethylenically unsaturated monomer. The networks are suitable as molding compounds having gas and moisture barrier effect or as adhesives.Type: ApplicationFiled: June 19, 2008Publication date: July 8, 2010Applicant: BASF SEInventors: Phillip Hanefeld, Nicole Hildebrandt, Klaus Muehlbach, Helmut Mach, Hans-Michael Walter, Dominique Teyssie, Odile Fichet, Cedric Vancaeyzeele, Benjamin Davion
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Publication number: 20100168281Abstract: Disclosed herein are a spalling-preventing composite material composed of fiber and powder, which have different diameters and melting points so as to be capable of realizing the effect of preventing spalling of high-strength concrete and the effect of improving the fluidity of concrete, and a high-strength refractory concrete comprising the spalling-preventing material. The composite material for preventing spalling of high-strength concrete is composed of powder and fiber at 1:1-3, wherein the powder is a polymer powder having a diameter of 0.10-0.5 mm and a melting point of 110-150° C., and the fiber is a conjugate fiber including a first fiber having a diameter of 0.05-0.10 mm, a length of 5-25 mm and a melting point of 150-190° C., and a second fiber having a diameter of 0.01-0.05 mm, a length of 5-25 mm and a melting point of 190-250° C., the first fiber being a polypropylene fiber, and the second fiber being a nylon fiber or a polyvinyl alcohol fiber.Type: ApplicationFiled: December 24, 2009Publication date: July 1, 2010Inventors: Joo Ho Lee, Soon Jeon Park, Jeong Jin Kim, Kwang Ki Kim, Hyung Jae Moon, Yin Seong Hwang, Yong Jeong, Jin Man Choi, Jae Kyung Shin, Se Hoon Kim, Chang Hyoo Choi, Hui Chan Kim
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Patent number: 7745538Abstract: Polymer composite including a compatibilizer and having selective permeability to chemical permeants due to interaction differences between the compatibilizer and the chemical permeants, includes 50-99 wt % of an amorphous thermoplastic resin selected from the group polyethylenepropylendienterpolymer, poly(1-(trimethylsilyl)-1-propyne), amorphous nylon, polystyrene and polycarbonate; 0.9-50 wt % of a semi-crystalline polymer selected from the group polyamide (nylons), polyethylene terephthalate, polybutylene terephthalate, polyethylene, polypropylene, polyetheretherketone, polyvinylidene fluoride, polytetrafluoroethylene, polyphenylene sulfide, and thermotropic or lyotropic liquid crystal polymer, and dispersed in the amorphous thermoplastic resin to provide a dispersed phase having an interface with the amorphous thermoplastic resin; and 0.Type: GrantFiled: February 16, 2005Date of Patent: June 29, 2010Inventor: Yongsok Seo