Polymer Derived From Alcohol Monomer Patents (Class 525/328.8)
  • Patent number: 7432330
    Abstract: The present invention is directed to hydrolytically stabilized maleimide-functionalized water soluble polymers and to methods for making and utilizing such polymers and their precursors.
    Type: Grant
    Filed: December 31, 2003
    Date of Patent: October 7, 2008
    Assignee: Nektar Therapeutics AL, Corporation
    Inventors: Antoni Kozlowski, Remy F. Gross, III, Samuel P. McManus
  • Patent number: 7432331
    Abstract: The present invention is directed to hydrolytically stabilized maleimide-functionalized water soluble polymers and to methods for making and utilizing such polymers and their precursors.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: October 7, 2008
    Assignee: Nektar Therapeutics AL, Corporation
    Inventors: Antoni Kozlowski, Remy F. Gross, III, Samuel P. McManus
  • Patent number: 7423092
    Abstract: The present invention relates to radiation-curable compositions useful as ink vehicles or inks, in particular UV-curable inks, such as UV-litho inks, comprising a (meth)acrylated styrene allyl alcohol copolymer obtained from the (meth)acrylation of a styrene allyl alcohol (SAA) copolymer with (meth)acrylic acid and/or one or more alkyl(meth)acrylates, and at least one alkoxylated acrylated monomer.
    Type: Grant
    Filed: August 26, 2004
    Date of Patent: September 9, 2008
    Assignee: Cytec Surface Specialties, SA
    Inventors: Isabelle Fallais, Luc Lindekens, Paul Gevaert
  • Patent number: 7413801
    Abstract: An aqueous composition that includes a) aqueous hydroxy functional, carboxy functional polymer including the reaction product of at least 5% by weight ?,?-ethylenically unsaturated hydroxy monomer, at least 30% by weight ethylenically unsaturated carboxylic acid monomer, from 0% by weight to less than 50% by weight ?,?-ethylenically unsaturated nonhydroxy functional, noncarboxy functional monomer, and chain transfer agent, and b) condensation accelerator, and articles that include a nonwoven web including glass fibers, and cured aqueous binder composition.
    Type: Grant
    Filed: April 20, 2006
    Date of Patent: August 19, 2008
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Wayne P. Miller, Stewart C. Anderson, Michael J. Dochniak
  • Publication number: 20080132648
    Abstract: The present invention provides a process for converting free hydroxyl groups of polyoxyalkylene glycols and/or polyoxyalkylene glycol monoethers by reacting at least one polyoxyalkylene glycol or at least one polyoxyalkylene glycol monoether with a base, and then alkylating or acylating it with a halohydrocarbon or acid halide in the presence of a reducing agent, the alkylation or acylation reaction being performed in the presence of atmospheric oxygen.
    Type: Application
    Filed: October 30, 2007
    Publication date: June 5, 2008
    Inventors: Alexander Snell, Erwin Holzhauser
  • Patent number: 7378471
    Abstract: The present invention is related to a polymer comprising terminal sulfonic acid groups, which has a high ionic conductivity and good structural stability, does not decompose even under low humidity conditions, and is inexpensive to produce. Furthermore, the present invention is related to a polymer electrolyte and a fuel cell using the same. The polymer of the present invention has a substituent comprising a terminal sulfonic acid group comprising Formula (1) at a side chain: where n may be a number in the range of about 1 to about 5.
    Type: Grant
    Filed: October 26, 2004
    Date of Patent: May 27, 2008
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Do-yun Kim, Min-ju Jeong, Myung-sup Jung, Bong-seok Moon
  • Patent number: 7358311
    Abstract: The instant invention relates to a process for crosslinking unsaturated polymer resins as e.g. unsaturated polyesters using hydroxyamine esters as radical source. Further aspects of the invention are a composition comprising unsaturated polymer resins as e.g. unsaturated polyester resins and a hydroxylamine ester and the use of hydroxylamine esters for crosslinking unsaturated polymers.
    Type: Grant
    Filed: September 17, 2002
    Date of Patent: April 15, 2008
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Michael Roth, Dirk Simon
  • Patent number: 7345126
    Abstract: The present invention provides a production method of a hydroxyl-containing polymer including: protecting a hydroxyl group of a hydroxyl-containing monomer with a protecting group to make the monomer a protected monomer with decreased hydrophilicity; adding the protected monomer alone or together with a hydrophobic monomer to a water-based medium containing a salt and a dispersion stabilizer; adding a polymerization initiator to the mixture to carry out suspension polymerization; and de-protecting the obtained polymer having the protecting group to recover the hydroxyl group.
    Type: Grant
    Filed: August 1, 2005
    Date of Patent: March 18, 2008
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yoshihiro Inaba, Takako Kobayashi, Hiroshi Yamamoto, Chisato Urano
  • Patent number: 7335705
    Abstract: Fluoropolymers are disclosed. The fluoropolymers include (i) units derived from a fluoromonomer composition comprising chlorotrifluoroethylene, and (ii) units derived from at least one donor monomer composition. In the disclosed fluoropolymers, units (i) and (ii) are distributed along the fluoropolymer chain in a substantially alternating fashion. Also disclosed are thermosetting compositions containing such fluoropolymers, substrates coated with such compositions, methods for making such compositions, and methods for coating substrates with such compositions.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: February 26, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, James B. O'Dwyer, Brian E. Woodworth
  • Patent number: 7332545
    Abstract: Fluoropolymers are disclosed. The fluoropolymers include (i) units derived from a fluoromonomer having the formula F2C?CXY, where X is CF3 and Y is either F or CF3, and (ii) units derived from at least one donor monomer. In the disclosed fluoropolymers, units (i) and (ii) are distributed along the fluoropolymer chain in a substantially alternating fashion. Also disclosed are thermosetting compositions containing such fluoropolymers, substrates coated with such compositions, methods for making such compositions, and methods for coating substrates with such compositions.
    Type: Grant
    Filed: September 30, 2005
    Date of Patent: February 19, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, James B. O'Dwyer, Brian E. Woodworth, Richard J. Winters
  • Patent number: 7285598
    Abstract: A polymer consisting mainly of structural units represented by the general formula (1), wherein the total molar amount of terminal aldehyde groups and acetal groups is 0.6 mol % or smaller based on the total molar amount of the structural units represented by the general formula (1). —[—(—CHR1—)n—CX1R2—CX2R3-]— (1) (In the formula, n is an integer of 2 to 10; X1 and X2 each represents —H, —OH, or a functional group capable of being converted into —OH, provided that at least one of X1 and X2 is hydroxy or a functional group capable of being converted into hydroxy; and R1, R2, and R3 each represents —H or C1-5 alkyl, aryl, aralkyl, or heteroaryl and the two or more R1's may be different).
    Type: Grant
    Filed: February 23, 2004
    Date of Patent: October 23, 2007
    Assignee: Kuraray Co., Ltd.
    Inventors: Kikuo Arimoto, Nobuhiro Moriguchi, Hiroyuki Ohgi, Yukiatsu Komiya
  • Patent number: 7282237
    Abstract: A method for hydrophilization and/or surface area enlargement of a porous base matrix comprising on its inner and/or outer surfaces a polymer (P?) carrying nucleophilic groups X?. The method is characterized in (a) ethoxylating a plurality of said X? thereby transforming them to groups comprising —(CH2CH2O)nH, or (b) (i) ethoxylating a polymer (P?) carrying nucleophilic groups X? thereby transforming P? to a polyhydroxy polymer (P??) carrying a plurality of —(CH2CH2O)nH groups, whereafter (ii) P?? is attached to the base matrix. n is an integer ?1. A support matrix which is obtainable by the method. The support matrix has a sufficient rigidity and swellability to permit liquid flow of a velocity >5 cm/h through the matrix when in form of particles packed to a bed or in form of a porous monolithic plug.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: October 16, 2007
    Assignee: GE Healthcare Bio-Sciences AB
    Inventors: Helene Derand, Rose Nasman, legal representative, Harry Nasman, legal representative, Jan Nasman, deceased
  • Patent number: 7279525
    Abstract: This invention relates to a curable composition comprising a solvent solution of a mixture comprising: (i) at least one hydroxy-functional acrylic-polymer; and (ii) at least one low molecular weight polyol reactive diluent; (iii) at least one polyisocyanate; (iv) a metal catalyst, such as a tin compound, for accelerating the isocyanate/hydroxyl reaction; and (v) propionic acid.
    Type: Grant
    Filed: August 9, 2005
    Date of Patent: October 9, 2007
    Assignee: The Sherwin-Williams Company
    Inventors: Thomas J. Staunton, Weilin Tang
  • Patent number: 7265186
    Abstract: The invention provides methods for making copolymers and multi-arm block copolymers useful as drug delivery vehicles. The multi-arm block copolymers comprise a central core molecule, such as a residue of a polyol, and at least three copolymer arms covalently attached to the central core molecule, each copolymer arm comprising an inner hydrophobic polymer segment covalently attached to the central core molecule and an outer hydrophilic polymer segment covalently attached to the hydrophobic polymer segment, wherein the central core molecule and the hydrophobic polymer segment define a hydrophobic core region. The solubility of hydrophobic biologically active agents can be improved by entrapment within the hydrophobic core region of the block copolymer. The invention further includes pharmaceutical compositions including such block copolymers, pharmaceutical compositions, and methods of using the block copolymers as drug delivery vehicles.
    Type: Grant
    Filed: November 8, 2004
    Date of Patent: September 4, 2007
    Assignee: Nektar Therapeutics AL, Corporation
    Inventor: Xuan Zhao
  • Patent number: 7226979
    Abstract: Novel copolymers, including block copolymers, which comprise: (a) a plurality of constitutional units that correspond to one or more olefin monomer species and (b) a plurality of constitutional units that correspond to one or more protected or unprotected hydroxystyrene monomer species.
    Type: Grant
    Filed: February 11, 2004
    Date of Patent: June 5, 2007
    Assignee: University of Massachusetts Lowell
    Inventors: Rudolf Faust, Laszlo Sipos
  • Patent number: 7217497
    Abstract: The present invention is directed to a thermally curable polymer composition, and a photolithographic substrate coated therewith, the composition comprising a hydroxyl-containing polymer, an amino cross-linking agent and a thermal acid generator. The thermally curable polymer composition may be dissolved in a solvent and used as an undercoat layer in deep UV lithography.
    Type: Grant
    Filed: June 8, 2004
    Date of Patent: May 15, 2007
    Assignee: Arch Specialty Chemicals, Inc.
    Inventors: Patrick Foster, Sydney George Slater, Thomas Steinhäusler, Andrew J. Blakeney, John Joseph Biafore
  • Patent number: 7186784
    Abstract: There are disclosed a phosphorus-containing carboxylic acid derivative which has a group containing phosphorus atom and has in its molecule, a group represented by the following formula (1): wherein R1, R2 and R3 are each hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms, and Y is oxygen atom or sulfur atom; a process for producing the derivative; and a flame retardant comprising the foregoing derivative as an effective ingredient. The present invention can provide the phosphorus-containing carboxylic acid derivative and a flame retardant which are each excellent in solubility in an organic solvent, compatibility with a variety of resins, stability and flame retardancy.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: March 6, 2007
    Assignee: NOF Corporation
    Inventors: Toshinobu Fujimura, Kazunori Waki, Koji Sato, Shiro Mibae
  • Patent number: 7183355
    Abstract: A curable, aqueous film-forming composition is provided, comprising: (a) a copolymer containing reactive functional groups and comprising at least 30 mol % of residues having alternating structural units: -[DM-AM]- wherein DM represents a residue from a donor monomer, and AM represents a residue from an acceptor monomer, at least 15 mol % of the copolymer comprising a donor monomer having the structure (I): wherein R1 is linear or branched C1 to C4 alkyl, R2 is selected from methyl, linear, cyclic or branched C1 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl; and (b) a curing agent having functional groups reactive with the reactive functional groups of (a). The invention is also directed to a multi-component composite coating composition including a base coat deposited from a pigmented film-forming composition and a transparent topcoat applied over the base coat. At least one-coat is the film-forming composition described above.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: February 27, 2007
    Assignee: PPG Industries, Ohio, Inc.
    Inventors: Roxalana L. Martin, Edward R. Coleridge, Mark A. Tucker, Mary E. Grolemund
  • Patent number: 7169847
    Abstract: A polymeric membrane suitable for use in electrophoresis formed from a pre-polymer having a plurality of crosslinkable moieties and the crosslinkable moieties being crosslinked with a polyfunctional crosslinking agent.
    Type: Grant
    Filed: February 27, 2002
    Date of Patent: January 30, 2007
    Assignee: Life Therapeutics, Inc.
    Inventors: David Henry Solomon, Marcus Julian Caulfield, Helen Katherine Purss
  • Patent number: 7141626
    Abstract: The present invention relates to novel catalysts for use with a fiberglass non-woven binder. The catalyst can be a Lewis acid, an organic acid salt, a free-radical generator, or a mixture thereof. The catalyst provides stronger bonding, increased crosslinking density, reduced curing times, and reduced curing temperatures. Fiberglass mats made with polymer binder compositions containing the catalyst exhibit both flexibility and elasticity, allowing the mats to be compressed for storage, yet return to original thickness once the compressive forces are removed. Formaldehyde-free wood composites, such as plywood and fiberboard, may also be produced with polymer binder compositions containing the catalyst.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: November 28, 2006
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Klein A. Rodrigues, Allen M. Carrier, Alvie L. Foster, Bick Hicks, James C. Long
  • Patent number: 7132476
    Abstract: A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: November 7, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 7132477
    Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material, and a monocarboxylic acid. Multi-component composite coatings, coated substrates, and related methods are also provided.
    Type: Grant
    Filed: August 27, 2004
    Date of Patent: November 7, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Kurt A. Humbert, Karen S. Rechenberg, Edward R. Coleridge, Charles M. Kania, Paul H. Lamers
  • Patent number: 7125931
    Abstract: A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: October 24, 2006
    Assignee: PPG industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 7122600
    Abstract: A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material. The crosslinking agent includes a copolymer having at least 30 mol % of alternating structural units of a residue from a donor monomer and a residue from one or more acrylic acceptor monomers. The thermosetting composition may coat a substrate by coalescing the composition to form a continuous film and curing the composition. The thermosetting composition may be included as part of a multi-component composite coating composition that includes an optional primer coat, a base coat deposited from a pigmented film-forming composition, and a transparent top coat applied over the base coat, where either the base coat, the transparent top coat, or both, are deposited from the thermosetting composition.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: October 17, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Karen S. Rechenberg, Simion Coca, Karen A. Barkac, James B. O'Dwyer, Linda J. Bowser
  • Patent number: 7101945
    Abstract: The invention relates to a phosphorus-containing polymer for coating dielectric materials, to processes for its preparation and to its use, as well as to an optical signal transducer having a coating of the polymer and to its use.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: September 5, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ingmar Dorn, Burkhard Köhler
  • Patent number: 7073277
    Abstract: The invention relates to the field of shoes in general, and more specifically to the application of microspheres in shoe material formulations to yield desired shoe properties. Even more specifically, the invention relates to a shoe component prepared from a closed cell foam incorporating microspheres to yield controlled cell size, cell size distribution and expansion characteristics. In another embodiment, the invention also relates to an inner sole for a shoe prepared from the reaction product of a polymer matrix component and a curing agent where the curing agent is incorporated in microspheres to yield a material conformable to the user's foot shape.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: July 11, 2006
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Robert Erb, Hyun Jin Kim, Marco Grott
  • Patent number: 7034083
    Abstract: An adhesive which comprises aqueous and nonaqueous polymers suitable for holding an lipophilic drug, etc., and has tackiness and cohesiveness which are sufficient for the plaster of a patch; and a patch employing the adhesive. The adhesive contains a polymer which comprises one or more kinds of acrylic or methacrylic monomer units, at least one kind of the monomer units having a hydroxy group, and which has been crosslinked with a boron compound.
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: April 25, 2006
    Assignee: Hisamitsu Pharmaceuticals Co., Inc.
    Inventors: Takashi Yasukochi, Toshiro Yamaguchi, Tetsuro Tateishi, Naruhito Higo
  • Patent number: 7015288
    Abstract: The present invention relates compositions containing acetoacetylated polyvinyl polymers obtained from polyvinyl polymers, such as polyvinyl butyrals. These coating compositions are especially suitable for use as wash primers in automotive OEM and refinish coating applications.
    Type: Grant
    Filed: March 4, 2005
    Date of Patent: March 21, 2006
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Lorenzo Fred Pelosi, Patricia Mary Ellen Sormani
  • Patent number: 7001958
    Abstract: The present invention relates to curable coating compositions containing acetoacetylated polyvinyl polymers obtained from polyvinyl polymers, such as polyvinyl butyrals. These coating compositions are especially suitable for use as wash primers in automotive OEM and refinish coating applications.
    Type: Grant
    Filed: March 14, 2005
    Date of Patent: February 21, 2006
    Assignee: E. I. duPont de Nemours and Company
    Inventors: Lorenzo Fred Pelosi, Patricia Mary Ellen Sormani
  • Patent number: 6995226
    Abstract: A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups or hydroxycarbonyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups or hydroxycarbonyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.
    Type: Grant
    Filed: June 5, 2002
    Date of Patent: February 7, 2006
    Assignee: Zeon Corporation
    Inventors: Kazunori Taguchi, Yasuo Tsunogae, Hitomi Takeuchi, Yasuhiro Wakisaka, Kei Sakamoto
  • Patent number: 6992137
    Abstract: A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: January 31, 2006
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 6989421
    Abstract: The present invention is directed to two component coating compositions that cure under ambient conditions and more particularly to those having low VOC (volatile organic content) that are suitable for use in automotive refinish and Original Equipment Manufacturing (OEM) applications. The coating composition includes crosslinkable and crosslinking components, wherein the crosslinkable component includes a low polydispersity, low molecular weight copolymer having on an average 2 to 25 crosslinkable functional groups, such as hydroxyl, acetoacetoxy, carboxyl, epoxy, primary amine and secondary amine. The copolymer is polymerized from a monomer mixture that includes one or more non-functional methacrylate monomers and one or more functional acrylate monomers provided with the functional groups. The crosslinking component includes polyisocyanate, polyamine, epoxy, polyacid, ketimine, melamine, or a combination thereof. The invention is also directed to coating produced from the coating composition.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: January 24, 2006
    Assignee: E. I. duPont deNemours and Company
    Inventor: Michael Charles Grady
  • Patent number: 6943219
    Abstract: The present invention provides a vinyl polymer with an epoxy group terminally introduced therein and an epoxy resin composition comprising (A) an epoxy resin and (B) a vinyl polymer which has a main chain produced by living radical polymerization and has a reactive functional group at a main chain terminus. A flexible epoxy resin composition can be obtained using these compounds. The invention further provides an epoxy resin composition having an epoxy group at a main chain terminus thereof.
    Type: Grant
    Filed: February 24, 2003
    Date of Patent: September 13, 2005
    Assignee: Kaneka Corporation
    Inventors: Kenichi Kitano, Yoshiki Nakagawa, Masayuki Fujita
  • Patent number: 6924339
    Abstract: Thermally cured undercoat for use in lithography of a thermally cured composition comprising a hydroxyl-containing polymer, an amino cross-linking agent and a thermal acid generator, wherein the hydroxyl containing polymer is a polymer comprising units m, n and o of the following formula: wherein R1 is H or methyl; R2 is a substituted or unsubstituted C6-C14 aryl acrylate or C6-C14 aryl methacrylate group wherein the substituted groups may be phenyl, C1-4 alkyl or C1-4 alkoxy; R3 is a hydroxyl functionalized C1-C8 alkyl acrylate, methacrylate or C6-C14 aryl group, R4 is a C1-C10 linear or branched alkylene; p is an integer of from 1 to 5 with the proviso that there are no more than thirty carbon atoms in the [—R4O—]p; R5 is a C1-C10 linear, branched or cyclic alkyl, substituted or unsubstituted C6-C14 aryl, or substituted or unsubstituted C7-C15 alicyclic hydrocarbon; and m is about 40 to 70, n is about 15 to 35 and o is about 15 to 25.
    Type: Grant
    Filed: May 14, 2003
    Date of Patent: August 2, 2005
    Assignee: Arch Specialty Chemicals, Inc.
    Inventors: Binod B. De, Sanjay Malik, Gregory Spaziano, John Joseph Biafore, Patrick Foster, Sidney George Slater, Thomas Steinhausler, Andrew J. Blakeney
  • Patent number: 6894123
    Abstract: The present invention relates to curable coating compositions containing acetoacetylated polyvinyl polymers obtained from polyvinyl polymers, such as polyvinyl butyrals. These coating compositions are especially suitable for use as wash primers in automotive OEM and refinish coating applications.
    Type: Grant
    Filed: February 9, 2004
    Date of Patent: May 17, 2005
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Lorenzo Fred Pelosi, Patricia Mary Ellen Sormani
  • Patent number: 6861503
    Abstract: The present invention is directed primarily to an interlinked crystalline solid polyethylene glycol composition (I-PEG) having a molecular weight of at least 20 kDa and a melting temperature of at least 40° C. and its use as an absorbable device having hydrolabile ester or carbonate interlinks that allow in vivo dissociation of the interlinked chain into excretable, low molecular weight PEG segments.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: March 1, 2005
    Assignee: Poly-Med, Inc.
    Inventor: Shalaby W. Shalaby
  • Patent number: 6838528
    Abstract: The invention provides multi-arm block copolymers useful as drug delivery vehicles comprising a central core molecule, such as a residue of a polyol, and at least three copolymer arms covalently attached to the central core molecule, each copolymer arm comprising an inner hydrophobic polymer segment covalently attached to the central core molecule and an outer hydrophilic polymer segment covalently attached to the hydrophobic polymer segment, wherein the central core molecule and the hydrophobic polymer segment define a hydrophobic core region. The solubility of hydrophobic biologically active agents can be improved by entrapment within the hydrophobic core region of the block copolymer. The invention further includes pharmaceutical compositions including such block copolymers, methods of making such copolymers and pharmaceutical compositions, and methods of using the block copolymers as drug delivery vehicles.
    Type: Grant
    Filed: March 8, 2004
    Date of Patent: January 4, 2005
    Assignee: Nektar Therapeutics AL, Corporation
    Inventor: Xuan Zhao
  • Publication number: 20040260031
    Abstract: A polymer comprising hydroxystyrene units and tert-alkoxycarbonylstyrene units is prepared by polymerizing an acetal group-blocked hydroxystyrene monomer and a tert-alkoxycarbonylstyrene monomer to form a preliminary polymer, and subjecting the preliminary polymer to selective deblocking reaction of acetal groups in the presence of an acid catalyst. The polymer thus produced has a narrower molecular weight distribution. A resist composition comprising the polymer as a base resin has advantages including a dissolution contrast of resist film, high resolution, exposure latitude, process flexibility, good pattern profile after exposure, and minimized line edge roughness.
    Type: Application
    Filed: June 17, 2004
    Publication date: December 23, 2004
    Inventors: Takanobu Takeda, Osamu Watanabe, Jun Hatakeyama, Wataru Kasaki
  • Patent number: 6825269
    Abstract: Process for the preparation of a derivative of a polymer having at least one functional group, characterized in that the process comprises the following step (i): (i) reaction of the polymer having at least one functional group, with at least one activating reagent or at least one derivative of an activating reagent in homogeneous phase.
    Type: Grant
    Filed: October 12, 2001
    Date of Patent: November 30, 2004
    Assignee: Dr. Gottschall Instruction Gesellschaft fuer Technische Chromatografie mbH
    Inventor: Klaus Gottschall
  • Publication number: 20040214959
    Abstract: A novel method for producing polyamide and/or polyester-amide copolymer is provided. The method of the present invention comprises the steps of: providing particles of the polyester, the polyester having pores extending from a surface of the particle to inside thereof; mixing the porous polyester with the diamine; and heating the mixture to the temperature not lower than a melting point of the diamine and not higher than a significant temperature of the polyester to cause reaction between the polyester and the diamine.
    Type: Application
    Filed: March 25, 2004
    Publication date: October 28, 2004
    Applicant: M&S Research and Development Co., Ltd.
    Inventor: Seiko Nakano
  • Patent number: 6803426
    Abstract: A composition that includes a fluorine-containing copolymer containing at least 30 mol % of residues having the following alternating structural unit: —[DM—AM]— where DM represents a residue from a donor monomer having the following structure (I): where R1 is linear or branched C1 to C4 alkyl; R2 is selected from methyl, linear, cyclic or branched C1 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl; and AM represents an acceptor monomer. The copolymer contains at least 5 wt. % fluorine. The composition may include co-reactive functional groups and may be a thermosetting composition, which can be used to coat a substrate. The thermosetting composition may be part of a multi-component composite coating composition that includes a base coat deposited from a pigmented film-forming composition and a substantially pigment free top coat applied over at least a portion of the base coat.
    Type: Grant
    Filed: February 4, 2003
    Date of Patent: October 12, 2004
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Edward R. Coleridge, Edward R. Millero, Jr., Robert T. Pogue, Truman F. Wilt, Carole A. Conley, Shawn A. DeSaw, Robert A. Montague
  • Patent number: 6794460
    Abstract: The present invention provides a production process for a transparent heat-resistant resin, and further, a transparent heat-resistant resin and uses therefor, wherein the production process involves high dealcoholation conversion and a low content of residual volatiles in the resultant resin, and therefore can prevent foam or silver streak from occurring in the molded product, and further, facilitates melt-molding such as injection molding, and is fit for industrial production, and involves good efficiency.
    Type: Grant
    Filed: November 15, 2002
    Date of Patent: September 21, 2004
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hideo Asano, Kazumi Fujioka
  • Patent number: 6794459
    Abstract: The present invention relates to cyclic polymers and their use in photolithographic applications. The cyclic polymers contain a pendant acid labile functional group and a functional group containing a protected hydroxyl moiety. The polymers are post modified by deprotecting the pendant hydroxyl moiety and reacting the deprotected hydroxyl containing moiety with a coreactant. The post-functionalized polymers find application in chemically amplified photoresist compositions.
    Type: Grant
    Filed: August 21, 2002
    Date of Patent: September 21, 2004
    Assignees: Sumitomo Bakelite Co., Ltd., International Business Machines Corp.
    Inventors: Saikumar Jayaraman, George Martin Benedikt, Larry Funderburk Rhodes, Richard Vicari, Robert David Allen, Richard Anthony DiPietro, Ratnam Sooriyakumaran, Thomas Wallow
  • Publication number: 20040176545
    Abstract: The present invention provides functionalized electrophiles, their analogous initiators, and processes for preparing these compounds. The present invention also relates to homotelechelic, heterotelechelic, and radial functional polydiene polymers, polyarylene polymers and polydiene/polyarylene copolymers, their optionally hydrogenated analogues, their optionally deprotected analogues, and processes for preparing these functionalized polymers.
    Type: Application
    Filed: March 16, 2004
    Publication date: September 9, 2004
    Inventors: James Anthony Schwindeman, Robert J. Letchford, Eric John Granger, Roderic P. Quirk
  • Patent number: 6784248
    Abstract: A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.
    Type: Grant
    Filed: February 15, 2002
    Date of Patent: August 31, 2004
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Simion Coca, Edward R. Coleridge, Gregory J. McCollum, James B. O'Dwyer, James E. Poole, Victoria A. Trettel
  • Patent number: 6783916
    Abstract: The present invention is directed to a thermally curable polymer composition, and a photolithographic substrate coated therewith, the composition comprising a hydroxyl-containing polymer, an amino cross-linking agent and a thermal acid generator. The thermally curable polymer composition may be dissolved in a solvent and used as an undercoat layer in deep UV lithography.
    Type: Grant
    Filed: July 9, 2001
    Date of Patent: August 31, 2004
    Assignee: Arch Specialty Chemicals, Inc.
    Inventors: Patrick Foster, Sydney George Slater, Thomas Steinhäusler, Andrew J. Blakeney, John Joseph Biafore
  • Publication number: 20040157991
    Abstract: The invention provides a method for preparing a 1-benzotriazolylcarbonate ester of a water-soluble and non-peptidic polymer by reacting a terminal hydroxyl group of a water-soluble and non-peptidic polymer with di(1-benzotriazolyl)carbonate in the presence of an amine base and an organic solvent. The polymer backbone can be poly(ethylene glycol). The 1-benzotriazolylcarbonate ester can then be reacted directly with a biologically active agent to form a biologically active polymer conjugate or reacted with an amino acid, such as lysine, to form an amino acid derivative.
    Type: Application
    Filed: December 2, 2003
    Publication date: August 12, 2004
    Inventor: Antoni Kozlowski
  • Publication number: 20040152843
    Abstract: A ring-opened metathesis copolymer and its hydrogenated product having a desired monomer unit ratio and a high molecular weight and having hydroxyl groups or hydroxycarbonyl groups can be obtained by conducting a ring-opening metathesis copolymerization of a norbornene-type monomer having hydroxyl groups or hydroxycarbonyl groups with an unsubstituted norbornene-type monomer having at least three rings in the presence of a catalyst predominantly comprised of an organic ruthenium compound having coordinated therewith a neutral electron-donating ligand, and, if desired, hydrogenating the resulting copolymer. The thus-obtained ring-opened metathesis copolymer and its hydrogenation product are characterized by having a low water absorption, good adhesion to metal and other materials, good compatibility with a curing agent and other compounds, and high heat resistance, and exhibiting reduced signal retardation and signal noise.
    Type: Application
    Filed: March 9, 2004
    Publication date: August 5, 2004
    Inventors: Kazunori Taguchi, Yasuo Tsunogae, Hitomi Takeuchi, Yasuhiro Wakisaka, Kei Sakamoto
  • Patent number: 6770709
    Abstract: The present invention provides a resin composition comprising: (1) a vinyl copolymer obtained from a starting material containing vinyl monomer (a) which comprises at least one carbonyl group or aldehyde group and vinyl monomer (b) which is different from vinyl monomer (a) and capable of copolymerization; (2) a hydrazide derivative represented by general formula (I):  (wherein R1 represents substituted or unsubstituted phenylene, substituted or unsubstituted cyclohexylene or alkylene; and R2 and R3, which may be the same or different, each represent a single bond or alkylene) or a hydrazide derivative in which the amino group(s) of the hydrazide derivative represented by general formula (I) are protected with a low molecular carbonyl compound; and (3) a polyamine compound represented by general formula (II):  (wherein R4 represents substituted or unsubstituted phenylene, substituted or unsubstituted cyclohexylene or alkylene; and R5 and R6, which may be the sam
    Type: Grant
    Filed: December 27, 2002
    Date of Patent: August 3, 2004
    Assignee: Kyowa Yuka Co., Ltd.
    Inventors: Yoshio Nakano, Shigeru Murata, Shohei Konishi, Iwao Hotta
  • Patent number: 6759483
    Abstract: A novel one-pot cost efficient process for the preparation of homo-, co- and terpolymers of p-hydroxystyrene or substituted p-hydroxystyrene and alkyl acrylates. The process involves polymerization of esters of p-hydroxystyrene (or its substituted analogs), alkyl acrylate monomers and/or one or more of ethylenically unsaturated monomers in an alcohol solvent in the presence of a free radical initiator. The reaction mixture containing the so formed polymer is subjected to transesterification conditions using a catalytic amount of catalyst to result in co- and/or terpolymers of p-hydroxystyrene without cleavage of the alkyl ester in the acrylate repeat unit, and then removing the catalyst from the system. Preferred embodiments include homopolymers of p-hydroxystyrene, copolymer of p-hydroxystyrene and tert-butyl acrylate and terpolymer of p-hydroxystyrene, tert-butyl acrylate and styrene. These polymers have a wide variety of applications including as photoresists in microelectronics industry.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: July 6, 2004
    Assignee: Chemfirst Electronic Materials L.P.
    Inventors: Michael T. Sheehan, James R. Sounik