Chemical Treating Agent Contains A Sulfur Atom Patents (Class 525/343)
  • Patent number: 7262244
    Abstract: The present invention relates to polymer composites comprising at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) below 30 at least one filler and optionally at least one cross-linking agent, a process for preparing said polymer composite wherein at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) below 30, at least one filler and optionally at least one cross-linking agent are mixed and a process for the manufacture of a shaped article comprising the step of injection molding a polymer composite comprising at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) below 30, at least one filler and at least one cross-linking agent.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: August 28, 2007
    Assignee: Lanxess Inc.
    Inventor: Frederic Guerin
  • Patent number: 7241843
    Abstract: A rubber composition for a tread optimizing a vulcanization speed in a vulcanization step and, further, improving heat aging resistance is provided. A rubber composition for a tread comprising 20 to 90 parts by weight of silica, 0.5 to 2 parts by weight of (A) a guanidine vulcanization accelerator, 0.1 to 0.5 part by weight of (B) a thiuram vulcanization accelerator, and 0.5 to 2 parts by weight of (C) a sulfenamide vulcanization accelerator represented by the general formula (1): (wherein R is a linear alkyl group or a branched alkyl group having 1 to 18 carbons), based on 100 parts by weight of a rubber component.
    Type: Grant
    Filed: June 5, 2006
    Date of Patent: July 10, 2007
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Tatsuya Miyazaki
  • Patent number: 7241831
    Abstract: The present invention includes compositions suitable for air barriers such as innerliners where adhesion to tire carcass materials (e.g., SBR) and flexibility are desirable, as well as low air permeability. The invention includes a tire innerliner made by combining a filler; a sulfur cure system; optionally at least one secondary rubber; and at least one halogenated terpolymer of C4 to C8 isoolefin derived units, C4 to C14 multiolefin derived units, and p-alkylstyrene derived units. Examples of suitable fillers include modified carbon black, carbon black, silica, exfoliated clays, and combinations thereof. The present invention also includes a method of producing an elastomeric terpolymer composition comprising combining in a diluent C4 to C8 isoolefin monomers, C4 to C14 multiolefin monomers, and p-alkylstyrene monomers in the presence of a Lewis acid and at least one initiator to produce the terpolymer.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: July 10, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Walter Harvey Waddell, David Yen-Lung Chung
  • Patent number: 7241844
    Abstract: A method for making isotactic polymer using a cross-linking agent entails introducing the cross-linking agent to a polymer and an accelerator. The cross-linking agent includes a peroxide and a sulfur. The peroxide has an activity ranging from about 40% to about 100%. The ratio of the accelerator to sulfur or peroxide ranges from 1:4 to 1:10 depending on the activity of the peroxide. The method further entails shearing the polymer in a high shear rate mixer and initiating cross-linking with the peroxide, wherein the accelerator partially inhibits the cross-linking of the peroxide. The method ends by forming macro radicals during the cross-linking; and forming macromolecular chains of polymer with sulfur bridges without the need for high torque. The accelerator ensures that the cross-linking and the formation of sulfur bridges occur simultaneously.
    Type: Grant
    Filed: July 29, 2005
    Date of Patent: July 10, 2007
    Inventor: Said Bouhelal
  • Patent number: 7235601
    Abstract: The present invention relates to polymer composites containing at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50–30 at least one filler and optionally at least one cross-linking agent, a process for preparing said polymer composite wherein at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50–30, at least one filler and optionally at least one cross-linking agent are mixed and a process for the manufacture of a shaped article including the step of injection molding a polymer composite containing at least one, optionally hydrogenated, nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) in the range of from 50-30, at least one filler and at least one cross-linking agent.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: June 26, 2007
    Assignee: Lanxess Inc.
    Inventors: Frederic Guerin, Ezio Campomizzi, Lorenzo Ferrari, Janet Gamlin, Richard Pazur, Carl Walter von Hellens
  • Patent number: 7235599
    Abstract: There is provided a racing tire improving grip performance, processability and rubber strength at a high temperature in highly good balance and a rubber composition capable of producing a tread having thereof. A rubber composition comprising 70 to 150 parts by weight of carbon black with a nitrogen adsorption specific area of 100 to 300 m2/g based on 100 parts by weight of a rubber component comprising a solution polymerization styrene-butadiene rubber satisfying the formula below: (Vinyl content)?100?2×(styrene content), 30 to 170 parts by weight of a softener and 1 to 30 parts by weight of a compound satisfying the general formula (1): —(R—Sx)n—??(1) (wherein R is —(CH2—CH2—O)m—CH2—CH2— , x is an integer of 3 to 6, n is an integer of 10 to 400 and m represents an integer of 2 to 5.).
    Type: Grant
    Filed: January 20, 2006
    Date of Patent: June 26, 2007
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Tetsuya Kunisawa, Toshiro Matsuo
  • Patent number: 7169848
    Abstract: The present invention is a novel block copolymer containing a controlled distribution copolymer block of a conjugated diene and a mono alkenyl arene, where the controlled distribution copolymer block has terminal regions that are rich in conjugated diene units and a center region that is rich in mono alkenyl arene units. Also disclosed is a method for manufacture of the block copolymer.
    Type: Grant
    Filed: February 6, 2003
    Date of Patent: January 30, 2007
    Assignee: Kraton Polymers U.S. LLC
    Inventors: Robert C. Bening, Dale L. Handlin, Jr., Larry L. Sterna, Carl L. Willis
  • Patent number: 7160955
    Abstract: Polymers grafted with a compound of formula I, formula (I) wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation [R1—SOmnR—SOp—R2.
    Type: Grant
    Filed: March 26, 2002
    Date of Patent: January 9, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Hans-Rudolf Meier, Gerrit Knobloch, Pierre Rota-Graziosi, Samuel Evans, Paul Dubs, Michèle Gerster
  • Patent number: 7138462
    Abstract: A functionalized polymer for binding a dissolved molecule in an aqueous solution is presented. The polymer has a backbone polymer to which one or more functional groups are covalently linked. The backbone polymer can be such polymers as polyethylenimine, polyvinylamine, polyallylamine, and polypropylamine. These polymers are generally water-soluble, but can be insoluble when cross-linked.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: November 21, 2006
    Assignee: Los Alamos National Security, LLC
    Inventors: Barbara F. Smith, Thomas W. Robison
  • Patent number: 7132482
    Abstract: The invention relates to a method for vulcanizing caoutchouc or latex by adding a mixture M which contains a component a) from a1) 20 to 96% by weight of sulfur, a2) 4 to 80% by weight of a complexing agent, and optionally other additives b) to caoutchouc or latex and then vulcanizing the mixture. The inventive method is characterized in that the average particle size of the primary particles of component a) ranges from 0.05 to 20 ?m.
    Type: Grant
    Filed: June 30, 2003
    Date of Patent: November 7, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Joern Tidow, Herbert Scholz, Fritz Nimtz, Michael Stang, Thomas Danner, Adolf Parg, Rolf Foerster, Karl-Heinrich Schneider, Hans-Josef Sterzel, Bernhard Albert
  • Patent number: 7041744
    Abstract: The present invention relates to a method for cross-linking a polymer article which comprises a cross-linkable polymer with hydrolyzable silane groups and a crystallinity level of at least 30%. The cross-linking is performed in the presence of a silanol condensation catalyst comprising a compound of formula (I): ArSO3H or a precursor thereof, Ar being a hydrocarbyl substituted aromatic group comprising at least 14 carbon atoms.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: May 9, 2006
    Assignee: Borealis Technology Oy
    Inventors: Magnus Palmlöf, Carl-Gustaf Ek, Gunhild Rohne
  • Patent number: 7026409
    Abstract: The present invention provides a solid acid catalyst that is excellent from the point of toxicity, environment and others, wherein reaction can be progressed effectively with Bronsted acid or Lewis acid catalyst. For example, the benzoylation reaction of alcohol can also be progressed easily, and further, the catalyst can be recovered and recycled easily. The para position of arylbis(perfluoroalkylsulfonyl)methane represented by the general formula [1] (wherein R1 shows a substituted or unsubstituted aryl group, Rf1 and Rf2 are independent to each other and show a perfluoroalkyl group), a pentafluorophenylbis(perfluoroalkylsulfonyl)methane, for example, is supported on a polystyrene resin, and a polystyrene-supported arylbis(perfluoroalkylsulfonyl)methane represented by the general formula [3] (wherein R3 shows a substituted or unsubstituted arylene group, Rf1 and Rf2 are the same as described above) is obtained.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: April 11, 2006
    Assignee: Japan Science and Technology Agency
    Inventors: Kazuaki Ishihara, Hisashi Yamamoto
  • Patent number: 7001966
    Abstract: The present invention relates to a process for preparing an isobutene polymer using a cyclopentene derivative as initiator and to the isobutene polymer obtainable by means of the process and to particular functionalization products thereof.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: February 21, 2006
    Assignee: BASF Aktiengesellschaft
    Inventors: Gabriele Lang, Arno Lange, Hans Peter Rath, Helmut Mach
  • Patent number: 6992147
    Abstract: A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) where A is a substituent that will undergo an addition reaction with a pseudo-living polymer, R1 is a divalent organic group, R2 is a monovalent organic group, and each R4, which may be the same or different, is a monovalent organic group or a substituent defined by —OR5 where R5 is a monovalent organic group, with the proviso that A, R1, R2, R4, and R5 are substituents that will not protonate a pseudo-living polymer. Also, the functionalized polymer and a vulcanizable composition containing the polymer.
    Type: Grant
    Filed: November 10, 2000
    Date of Patent: January 31, 2006
    Assignee: Bridgestone Corporation
    Inventors: Yoichi Ozawa, H. Jerrold Miller, Koji Masaki, Tatsuo Fujimaki, Takuo Sone, Iwakazu Hattori, Koichi Morita
  • Patent number: 6987149
    Abstract: This invention concerns the crosslinking of isotactic polypropylene, which has always been considered a non-crosslinkable polymer. Isotactic polypropylene crosslinking not only generates new uses but also the prospects of both economic and environmentally friendly mixing and recovery operations with other polymers. The crosslinking and interpenetrating polymer network (IPN) (as is the case with polypropylene/polyethylene mixture) provides both interesting properties and significant economic and environmentally friendly interest. The principle of the crosslinking mechanism is to create macro radicals and cause them to act immediately on sulphur before the reaction of peroxide termination. The mixing process used is extrusion; however, all other processes of transformation used for thermoplastics would be useful for subsequent industrial use.
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: January 17, 2006
    Inventor: Said Bouhelal
  • Patent number: 6916888
    Abstract: A rubber composition comprising a vulcanizable rubber, a reinforcing filler, a softening agent, and other reagents for rubber to which is added in a specific amount of a sulfur compound having the formula (I): —(SxR1)n—??(I) wherein R1 represents an organic group, x is a number of 3 to 5 on average, and n is an integer of 1 to 100, or a specific sulfur compound (1) and sulfur (2), and optionally a thiazole base, sulfenamide base, thiuram base, and/or diothio acid base vulcanization accelerator (3).
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: July 12, 2005
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Fumito Yatsuyanagi, Kazunori Ishikawa, Shuichi Fukutani
  • Patent number: 6914099
    Abstract: Superabsorbent polymers having reduced levels of residual monomer are produced using a peroxodisulfate salt.
    Type: Grant
    Filed: December 18, 2001
    Date of Patent: July 5, 2005
    Assignee: Dow Global Technologies Inc.
    Inventor: Young-Sam Kim
  • Patent number: 6903155
    Abstract: The present invention relates to tires suitable for bearing heavy loads, and to the use of a rubber composition to form the treads of such tires which delays the appearance of irregular wear on the treads of such tires during travel. The invention applies to tires for motor vehicles, such as heavy vehicles, construction vehicles or aircraft. The rubber composition comprises: an elastomeric matrix comprising majoritarily at least one diene elastomer having at one or more of its chain ends a functional group which is active for coupling to a reinforcing white filler, a reinforcing filler comprising at least 50% by weight a reinforcing white filler, and a reinforcing white filler/functionalized diene elastomer bonding agent. The present invention relates to tires suitable for bearing heavy loads, and to the use of the rubber composition to delay the appearance of irregular wear on the treads of such tires during travel.
    Type: Grant
    Filed: February 7, 2001
    Date of Patent: June 7, 2005
    Assignee: Michelin Recherche et Technique S.A.
    Inventor: Thomas Hodge
  • Patent number: 6900263
    Abstract: The present invention relates to tires suitable for bearing heavy loads, and to the use of a rubber composition to form the treads of such tires which delays the appearance of irregular wear on the treads of such tires during travel. The invention applies to tires for motor vehicles, such as heavy vehicles, construction vehicles or aircraft. The rubber composition comprises: an elastomeric matrix comprising majoritarily at least one diene elastomer having at one or more of its chain ends a functional group which is active for coupling to a reinforcing white filler, a reinforcing filler comprising at least 50% by weight a reinforcing white filler, and a reinforcing white filler/functionalized diene elastomer bonding agent. The present invention relates to tires suitable for bearing heavy loads, and to the use of the rubber composition to delay the appearance of irregular wear on the treads of such tires during travel.
    Type: Grant
    Filed: July 21, 2002
    Date of Patent: May 31, 2005
    Assignee: Michelin Recherche et Technique S.A.
    Inventor: Thomas Hodge
  • Patent number: 6894093
    Abstract: The present invention describes plastic materials and food additives that are free or substantially free from endocrine disruptive chemicals. The plastic materials may be used in products which are exposed to individuals in which endocrine disruptive activity is particularly disadvantageous, such as baby bottles, baby toys, food containers, medical containers, animal cages and medical products. The food additives may be used in food products that are ingested by individuals in which endocrine disruptive activity is particularly disadvantageous, such as newborns or the physically infirm. The present invention also describes a series of assays which, when performed in combination, provide a novel method for determining the presence of endocrine disruptive activity.
    Type: Grant
    Filed: May 10, 2002
    Date of Patent: May 17, 2005
    Inventor: George D. Bittner
  • Patent number: 6858679
    Abstract: Compositions including one or more anionic polymerization initiators and one or more additives for improving functionalizing efficiency of living polymer anions are disclosed. The present invention also provides compositions including one or more electrophiles and one or more additives for improving functionalizing efficiency of living polymer anions. Novel electrophiles and processes for improving polymer anion functionalization efficiencies are also disclosed.
    Type: Grant
    Filed: February 7, 2003
    Date of Patent: February 22, 2005
    Assignee: FMC Corporation
    Inventors: Roderic Paul Quirk, Young Joon Lee, James Anthony Schwindeman, Robert James Letchford
  • Patent number: 6844399
    Abstract: Sulfonated substantially random interpolymers made from monomer components comprise from 1 to 65 mole percent of (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinylidene monomer, or (c) a combination of at least one vinyl or vinylidene aromatic monomer and at lest one hindered aliphatic or cycloaliphatic vinylidene monomer, and from 35 to 99 mole percent of at least one aliphatic ?-olefin having from 2 to 20 carbon atoms; and optionally, from 0 to 20 mole percent of a diene containing from 4 to 20 carbon atoms; wherein the sulfonated interpolymer contains at least one mer (or moiety) of a group represented by the formula —SO3?M where M is hydrogen or a group 1, 7 or 12 metal in ionic form or combination thereof. Blends of these polymers with polyamides and polyolefins are made.
    Type: Grant
    Filed: October 7, 2002
    Date of Patent: January 18, 2005
    Assignee: Dow Global Technologies, Inc.
    Inventors: Yunwa W. Cheung, Stephen F. Hahn, James C. Stevens, Francis J. Timmers, Gregory F. Schmidt, Thoi H. Ho, Robert H. Terbrueggen
  • Publication number: 20040242795
    Abstract: The present invention includes compositions suitable for air barriers such as innerliners where adhesion to tire carcass materials (e.g., SBR) and flexibility are desirable, as well as low air permeability. The invention includes a tire innerliner made by combining a filler; a sulfur cure system; optionally at least one secondary rubber; and at least one halogenated terpolymer of C4 to C8 isoolefin derived units, C4 to C14 multiolefin drived units, and p-alkylstyrene derived units. Examples of suitable fillers include modified carbon black, carbon black, silica, exfoliated clays, and combinations thereof. The present invention also includes a method of producing an elastomeric terpolymer composition comprising combining in a diluent C4 to C8 isoolefin monomers, C4 to C14 multiolefin monomers, and p-alkylstyrene monomers in the presence of a Lewis acid and at least one initiator to produce the terpolymer.
    Type: Application
    Filed: May 10, 2004
    Publication date: December 2, 2004
    Inventors: Walter Harvey Waddell, David Yen-Lung Chung
  • Publication number: 20040242731
    Abstract: The present invention includes compositions suitable for tire treads or sidewalls and other articles where abrasion resistance and flexibility are desirable. The invention includes a tire tread or sidewall made by combining a filler; a sulfur cure system; optionally at least one secondary rubber; and at least one halogenated terpolymer of C4 to C8 isoolefin derived units, C4 to C14 multiolefin derived units, and p-alkylstyrene derived units. Examples of suitable fillers include carbon black, silica, and combinations thereof. The present invention also includes a method of producing an elastomeric terpolymer composition comprising combining in a diluent C4 to C8 isoolefin monomers, C4 to C14 multiolefin monomers, and p-alkylstyrene monomers in the presence of a Lewis acid and at least one initiator to produce the terpolymer.
    Type: Application
    Filed: May 10, 2004
    Publication date: December 2, 2004
    Inventors: Walter Harvey Waddell, David Yen-Lung Chung
  • Publication number: 20040230011
    Abstract: A polymer composition for a conductive roller composed of a rubber component whose main component is an epichlorohidrin rubber containing ethylene oxide at not less than 55 mol % nor more than 95 mol %. Thioureas are added to 100 g of the rubber component as a crosslinking agent at a rate not less than 0.014 mol nor more than 0.080 mol. In a compression set test of a vulcanized rubber described in JIS K6262, a compression set measured at 70° C. for 22-24 hours is less than 15%; and in a volume resistivity value test described in JIS K6911, a volume resistivity value measured at an applied voltage of 1000V is less than 107.5[&OHgr;·cm].
    Type: Application
    Filed: June 22, 2004
    Publication date: November 18, 2004
    Applicant: Sumitomo Rubber Industries, Ltd.
    Inventors: Takayuki Hattori, Tetsuo Mizoguchi, Shunichi Yabushita, Kenichi Uesaka
  • Patent number: 6806307
    Abstract: The invention provides chain-coupled polymeric sulfide compounds for use as the elastomeric component in vulcanizable elastomeric compositions comprising silica, carbon black or mixtures thereof. In particular, the invention provides anionically polymerized polymers having polymer chain living ends that are functionalized with sulfide groups and coupled together by a metal or nonmetal atom. The chain-coupled polymeric sulfide compounds have an initial high viscosity for ease of handling prior to compounding, a stable viscosity during storage, and a decreased compound viscosity for better filler dispersion and improved mixing efficiency. The invention further provides a pneumatic tire having at least one component produced from the vulcanizable elastomeric composition of the invention. A tire tread produced from vulcanized elastomers exhibiting these improved properties will exhibit reduced hysteresis resulting in an increase in rebound and improved rolling resistance and wet traction.
    Type: Grant
    Filed: October 11, 2001
    Date of Patent: October 19, 2004
    Assignee: Bridgestone Corporation
    Inventors: Terrence E. Hogan, William L. Hergenrother
  • Patent number: 6784256
    Abstract: A controlled free-radical polymerization process for forming end-functionalized polymers is disclosed, particularly by degenerative iodine transfer. The end-functionalized polymers are characterized by a polydispersity less than 2.5 and a predetermined molecular weight. The end-functionalized polymers are useful as reactive intermediates in condensation polymerization, chain polymerization and heterogeneous polymerization reactions.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: August 31, 2004
    Assignee: Noveon IP Holdings Corp.
    Inventors: Jinsong Lee, Paul Peter Nicholas, Naser Pourahmady, Rutger D. Puts
  • Patent number: 6780925
    Abstract: The invention relates to the preparation of a silica reinforced rubber composition where alkoxysilane and/or sulfur cure reactions within the elastomer host are controlled by the use of a selected amino acid, or amino acid-containing protein based, activator. The invention also relates to such composite and to a tire having at least one component of such composite.
    Type: Grant
    Filed: December 11, 2002
    Date of Patent: August 24, 2004
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thierry Florent Edme Materne, Francois Kayser, Michael Paul Mallamaci, Harlan Roy Wilk
  • Publication number: 20040116612
    Abstract: Compositions of specialty fluoroelastomers containing copolymerized units of tetrafluoroethylene, propylene, optionally vinylidene fluoride, and a cure site monomer selected from the group consisting of i) trifluoroethylene, ii) 3,3,3-trifluoropropene-1, iii) 1,2,3,3,3-pentafluoropropylene, iv) 1,1,3,3,3-pentafluoropropylene, and v) 2,3,3,3-tetrafluoropropene are readily curable with polyhydroxy curing systems. The resulting cured articles have a combination of excellent resistance to alkaline fluids, superior tensile properties and compression set resistance.
    Type: Application
    Filed: November 24, 2003
    Publication date: June 17, 2004
    Inventors: John Gordon Bauerle, Walter Werner Schmiegel
  • Publication number: 20040116617
    Abstract: The present invention provides a solid acid catalyst that is excellent from the point of toxicity, environment and others, wherein reaction can be progressed effectively with Bronsted acid or Lewis acid catalyst. For example, the benzoylation reaction of alcohol can also be progressed easily, and further, the catalyst can be recovered and recycled easily. The para position of arylbis(perfluoroalkylsulfonyl)methane represented by the general formula [1] (wherein R1 shows a substituted or unsubstituted aryl group, Rf1 and Rf2 are independent to each other and show a perfluoroalkyl group), a pentafluorophenylbis(perfluoroalkylsulfonyl)methane, for example, is supported on a polystyrene resin, and a polystyrene-supported arylbis(perfluoroalkylsulfonyl)methane represented by the general formula [3] (wherein R3 shows a substituted or unsubstituted arylene group, Rf1 and Rf2 are the same as described above) is obtained.
    Type: Application
    Filed: September 10, 2003
    Publication date: June 17, 2004
    Inventors: Kazuaki Ishihara, Hisashi Yamamoto
  • Patent number: 6703450
    Abstract: Compositions of specialty fluoroelastomers containing copolymerized units of tetrafluoroethylene, propylene, optionally vinylidene fluoride, and a cure site monomer selected from the group consisting of i) trifluoroethylene, ii) 3,3,3-trifluoropropene-1, iii) 1,2,3,3,3-pentafluoropropylene, iv) 1,1,3,3,3-pentafluoropropylene, and v) 2,3,3,3-tetrafluoropropene are readily curable with polyhydroxy curing systems. The resulting cured articles have a combination of excellent resistance to alkaline fluids, superior tensile properties and compression set resistance.
    Type: Grant
    Filed: May 2, 2002
    Date of Patent: March 9, 2004
    Assignee: DuPont Dow Elastomer, L.L.C.
    Inventors: John Gordon Bauerle, Walter Werner Schmiegel
  • Publication number: 20030204026
    Abstract: A rubber composition comprising a vulcanizable rubber, a reinforcing filler, a softening agent, and other reagents for rubber to which is added in a specific amount of a sulfur compound having the formula (I):
    Type: Application
    Filed: December 23, 2002
    Publication date: October 30, 2003
    Applicant: The Yokohama Rubber Co., Ltd.
    Inventors: Fumito Yatsuyanagi, Kazunori Ishikawa, Shuichi Fukutani
  • Patent number: 6639022
    Abstract: A process for the preparation of superabsorbent polymers by alkaline hydrolysis of polyacrylonitrile emulsions is disclosed. In an embodiment of the invention the process comprise preparing a PAN emulsion, subjecting the emulsion to alkaline hydrolysis, neutralizing the hydrolysate followed by drying, granulation and modifying the surface of the granular polymer by crosslinking. The process is characterized in that the isolation of the superabsorbent polymer entails neither alcohols nor organic solvents.
    Type: Grant
    Filed: April 16, 2001
    Date of Patent: October 28, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gisbert Michels, Thomas Gross
  • Patent number: 6639023
    Abstract: This invention is directed to a fluorophenyl resin compound, to methods of its preparation; and to its use in the solid phase synthesis of amides, peptides, hydroxamic acids, amines, urethanes, carbonates carbamates, sulfonamides and &agr;-substituted carbonyl compounds.
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: October 28, 2003
    Assignee: Aventis Pharmaceuticals Inc.
    Inventors: Joseph M. Salvino, Robert D. Groneberg, John E. Airey, Gregory B. Poli, Gerard M. McGeehan, Richard F. Labaudiniere, François-Frédéric Clerc, Daniel Noël André Bezard
  • Publication number: 20030195302
    Abstract: A rubber composition comprising a vulcanizable rubber, a reinforcing filler, a softening agent, and other reagents for rubber to which is added in a specific amount of a sulfur compound having the formula (I):
    Type: Application
    Filed: December 23, 2002
    Publication date: October 16, 2003
    Applicant: The Yokohama Rubber Co., Ltd
    Inventors: Fumito Yatsuyanagi, Kazunori Ishikawa, Shuichi Fukutani
  • Publication number: 20030153693
    Abstract: Compositions including one or more anionic polymerization initiators and one or more additives for improving functionalizing efficiency of living polymer anions are disclosed. The present invention also provides compositions including one or more electrophiles and one or more additives for improving functionalizing efficiency of living polymer anions. Novel electrophiles and processes for improving polymer anion functionalization efficiencies are also disclosed.
    Type: Application
    Filed: February 7, 2003
    Publication date: August 14, 2003
    Inventors: Roderic Paul Quirk, Young Joon Lee, James Anthony Schwindeman, Robert James Letchford
  • Patent number: 6602961
    Abstract: A fluorine-containing elastomer composition comprising a terpolymer of tetrafluoroethylene, perfluoro(lower alkyl vinyl ether) and perfluoro(&ohgr;-cyanoalkyl vinyl ether) and a bisaminophenyl compound represented by the following general formula as a curing agent: wherein A is an alkylidene group having 1 to 6 carbon atoms, a perfluoroalkylidene group having 1 to 10 carbon atoms, a SO2 group, an O group, a CO group, or a carbon-carbon bond capable of directly coupling two benzene rings; and X and Y each are a hydroxyl group or an amino group can give a rubbery vulcanization product with a good processability and good physical properties by a commercially available cross-linking agent free from any safety problem.
    Type: Grant
    Filed: July 11, 1995
    Date of Patent: August 5, 2003
    Inventors: Satoru Saito, Haruyoshi Tatsu, Hiroaki Murata
  • Publication number: 20030138846
    Abstract: Embodiments of the present invention generally relate to carrying out organic chemistry on solid supports comprising derivatised functionalities, methods for synthesizing said supports, methods for synthesizing compounds comprising amine groups or N-containing heterocycles using said solid supports, intermediate compounds linked to said supports and uses thereof.
    Type: Application
    Filed: September 17, 2002
    Publication date: July 24, 2003
    Inventors: David Gani, Friedrich Erich Karl Kroll, Michael John Plater, John Richard Morphy, David Rees
  • Patent number: 6590042
    Abstract: A process for reclaiming sulfur-cured, vulcanized rubber by combining finely ground scrap vulcanized rubber within a specialized, twin-screw extruder capable of providing strong shearing and just-on-time mixing; adding a reclaiming agent to the extruder; and masticating the rubber scrap and reclaiming agent within the extruder until the rubber scrap is devulcanized. The present invention also discloses a unique composition of reclaiming agent, which preferably includes the following compounds: accelerators TBBS, ZMBT, MBT, and TMTM; activators zinc oxide and stearic acid; and zinc salts of fatty acids and sulfur. The reclaimed rubber is suitable for use in producing high-grade, rubber products without adding a binder, or for combining with fresh rubber compounds to produce high-specification rubber products.
    Type: Grant
    Filed: October 3, 2001
    Date of Patent: July 8, 2003
    Inventor: Ying Tang
  • Patent number: 6590017
    Abstract: The invention provides an amide compound as a processing aid to improve the dispersion of silica reinforcing filler in a rubber composition, while reducing or eliminating the use of expensive bifunctional silica coupling agents. The invention further provides a vulcanizable elastomeric composition and vulcanized elastomeric products, especially pneumatic tires that exhibit decreased rolling resistance, hysteresis, and improved snow, ice, and wet traction.
    Type: Grant
    Filed: May 15, 2000
    Date of Patent: July 8, 2003
    Assignee: Bridgestone Corporation
    Inventors: William L. Hergenrother, Chenchy Jeffrey Lin
  • Patent number: 6579949
    Abstract: A vulcanized elastomeric composition of matter comprises the reaction product of a sulfur-containing reagent with an anionic living polymer, the reagent being selected from the group consisting of R3—Si—S—R′—X, where R can all be the same or different and is selected from the group consisting of alkyls having from 1 to 8 carbon atoms, cycloalkyls having from 3 to 11 carbon atoms, or an arylene having from 6 to 14 carbon atoms, and X is a halogen, to form a R3—Si—S—R′ ended polymer; a filler; processing oil; and a cure package containing a deprotecting agent and at least one sulfur cure accelerator.
    Type: Grant
    Filed: October 30, 2001
    Date of Patent: June 17, 2003
    Assignee: Bridgestone Corporation
    Inventors: William L. Hergenrother, Christine M. Rademacher, James D. Ulmer
  • Publication number: 20030092810
    Abstract: Water-continuous emulsion of silylated elastomeric polymers are disclosed having a solids content of greater than 75%, an average particle size less than 5 &mgr;m, and having sufficient stability to produce a stable lower solids emulsion upon dilution with water comprising; a silylated elastomeric polymer, surfactant, water, optional plasticizer, and optional low molecular weight acid.
    Type: Application
    Filed: July 13, 2001
    Publication date: May 15, 2003
    Inventors: Michael Gene Altes, Lee Bowen Jensen, Shaow Burn Lin, Anil Kumar Saxena, Todd Matthew Starke, Toshio Suzuki
  • Publication number: 20030078345
    Abstract: A process for manufacturing a cation-selective ion exchange membrane which comprises contacting one or both sides of a membrane comprising a polymer having side chains which contain acid groups with a solution which comprises one or more soluble salts of one or more onium ions and a salt which will prevent swelling of the membrane, for a period of time sufficient to allow the desired extent of substitution of the cations which are associated with the acid groups by onium ions.
    Type: Application
    Filed: October 16, 2002
    Publication date: April 24, 2003
    Inventor: Patrick John Morrisey
  • Patent number: 6548604
    Abstract: A nitrile group-containing highly saturated copolymer rubber comprising (a) 10-40 wt. % of &agr;,&bgr;-ethylenically unsaturated nitrile monomer units, (b) 10-60 wt. % of &agr;,&bgr;-ethylenically unsaturated carboxylic acid ester monomer units, (c) 0.01-21 wt. % of conjugated diene monomer units, and (d) 14-69.99 wt. % of saturated conjugated diene monomer units, wherein the sum of monomer units (c) plus (d) is 20-70 wt. %, the ratio of monomer units (d)/[monomer units (c) plus (d)] is at least 70 wt. %, and the difference between the extrapolated glass transition-initiating temperature (Tig) and the extrapolated glass transition-ending temperature (Teg), as measured by DSC is not higher than 10° C. The copolymer rubber gives a crosslinked product having good cold resistance, oil resistance and dynamic properties.
    Type: Grant
    Filed: April 15, 2002
    Date of Patent: April 15, 2003
    Assignee: Zeon Corporation
    Inventors: Hiroyuki Kotsuji, Akira Tsukada
  • Patent number: 6545103
    Abstract: Compositions including one or more anionic polymerization initiators and one or more additives for improving functionalizing efficiency of living polymer anions are disclosed. The present invention also provides compositions including one or more electrophiles and one or more additives for improving functionalizing efficiency of living polymer anions. Novel electrophiles and processes for improving polymer anion functionalization efficiencies are also disclosed.
    Type: Grant
    Filed: July 2, 2001
    Date of Patent: April 8, 2003
    Assignee: FMC Corporation
    Inventors: Roderic Paul Quirk, Young Joon Lee, James Anthony Schwindeman, Robert James Letchford
  • Patent number: 6536492
    Abstract: The present invention provides for a coupling system (white filler/diene elastomer) for a rubber composition based on diene elastomer reinforced with a white filler, formed by the association of a polysulphurized alkoxysilane, a zinc dithiophosphate and a guanidine derivative. The invention also provides a rubber composition usable for the manufacture of tires, comprising, as base constituents, one or more diene elastomer(s), a reinforcing white filler, a polysulphurized alkoxysilane coupling agent with which are associated a zinc dithiophosphate and a guanidine derivative. Also provided is a process for preparing such a rubber composition, and a tire or semi-finished product, in particular a tread for a tire, comprising a rubber composition according to the invention.
    Type: Grant
    Filed: January 22, 2001
    Date of Patent: March 25, 2003
    Assignee: Michelin Recherche et Technique S.A.
    Inventor: Didier Vasseur
  • Patent number: 6538072
    Abstract: A method of preparing a multivalent array that includes: polymerizing at least one monomer comprising at least one polymerizable group and at least one latent reactive group in the presence of a metal carbene catalyst to form a polymer template comprising at least one latent reactive group; and combining the polymer template with at least one functionalizing reagent comprising at least one reactive group under conditions effective to react the latent reactive group of the polymer template with the reactive group of the functionalizing reagent to form a multivalent array.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: March 25, 2003
    Assignee: Wisconsin Alumni Research Foundation
    Inventors: Laura L. Kiessling, Laura E. Strong
  • Patent number: 6528592
    Abstract: This invention relates to a conjugated diene-based rubber composition reinforced with particulate silica-based reinforcement together with 2-hydroxyethyl methacrylate (a non-silane coupling agent) or a combination of 2-hydroxyethyl methacrylate and bis(3-trialkoxysilylalkyl) polysulfide having an average of from 2 to 2.6, or from 3.5 to 4, sulfur atoms in its polysulfidic bridge to aid in the reinforcement of the rubber composition with a particulate silica-based material and an article of manufacture, including a tire, having at least one component comprised of such rubber composition.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: March 4, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Lawson Gibson Wideman, Kevin James Pyle, Richard Robinson Smith, Paul Harry Sandstrom
  • Patent number: 6518367
    Abstract: A rubber composition comprising a vulcanizable rubber, a reinforcing filler, a softening agent, and other reagents for rubber to which is added in a specific amount of a sulfur compound having the formula (I): —(SxR1)n—  (I) wherein R1 represents an organic group, x is a number of 3 to 5 on average, and n is an integer of 1 to 100, or a specific sulfur compound (1) and sulfur (2), and optionally a thiazole base, sulfenamide base, thiuram base, and/or diothio acid base vulcanization accelerator (3).
    Type: Grant
    Filed: February 15, 2000
    Date of Patent: February 11, 2003
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Fumito Yatsuyanagi, Kazunori Ishikawa, Shuichi Fukutani
  • Patent number: 6512051
    Abstract: An elastomer composition including an elastomer having a functional group, and a compound having a functional group, in which corresponding functional groups form a cross-link by at least one of an ionic bond, a hydrogen bond, and Diels-Alder reaction with temperatures, i.e., by heating, while the cross-link is cleaved at around room temperature, forming and cleaving of the cross-link being reversible.
    Type: Grant
    Filed: January 21, 1999
    Date of Patent: January 28, 2003
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Keisuke Chino, Masahiro Ikawa, Makoto Ashiura