Sulfur-containing Heterocyclic Compound Patents (Class 525/348)
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Publication number: 20020123573Abstract: Polymers coupled by reaction with coupling agents according to the practice of the invention advantageously have at least one of these desirable properties and preferably have desirable combinations of these properties. The present invention includes a process of preparing a coupled polymer comprising heating an admixture containing (1) at least one elastomer comprising ethylene and at least one comonomer which is selected from alpha olefins having at least 3 carbon atoms, dienes and combinations thereof and (2) a coupling amount at least one poly(sulfonyl azide) to at least the decomposition temperature of the poly(sulfonyl azide) for a period sufficient for decomposition of at least about 80 weight percent of the poly(sulfonyl azide) and sufficient to result in a coupled polymer having a gel content of less than about 2 weight percent.Type: ApplicationFiled: October 29, 2001Publication date: September 5, 2002Inventors: Wendy D. Hoenig, Teresa Karjala, Che-I Kao, Clark H. Cummins, Michael J. Mullins, H. Craig Silvis, Thoi H. Ho
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Patent number: 6346577Abstract: The heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an &agr;-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B). This heat-resistant rubber composition can provide a vulcanized rubber molded product showing not only excellent mechanical properties and electrical properties and but also prominently high thermal aging resistance.Type: GrantFiled: February 28, 2000Date of Patent: February 12, 2002Assignee: Mitsui Chemicals INCInventors: Takashi Hakuta, Tetsuo Tojo, Masaaki Kawasaki, Mikio Hosoya
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Patent number: 6291586Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a polyurethane or polyurea polymer and an amide functional ultraviolet light absorbing compound, wherein the polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polymeric matrix and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.Type: GrantFiled: October 31, 1997Date of Patent: September 18, 2001Assignee: 3M Innovative Properties CompanyInventors: James E. Lasch, David B. Olson, David M. Burns
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Publication number: 20010007885Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a polyurethane or polyurea polymer and an amide functional ultraviolet light absorbing compound, wherein the polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polymeric matrix and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.Type: ApplicationFiled: October 31, 1997Publication date: July 12, 2001Inventors: JAMES E. LASCH, DAVID B. OLSON, DAVID M. BURNS
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Patent number: 6239231Abstract: A chemical amplifying type positive resist composition, excellent in adhesion to a substrate and good in resist performances and suitable for exposure using a KrF excimer laser, ArF excimer laser, or the like, which comprises a resin having a polymerization unit of 2-alkyl-2-adamantyl (meth)acrylate and a polymerization unit of a monomer selected from 3-hydroxy-1-adamantyl (meth)acrylate and (meth)acrylonitrile, and an acid generator is provided.Type: GrantFiled: August 26, 1999Date of Patent: May 29, 2001Assignee: Sumitomo Chemical, Company LimitedInventors: Hiroaki Fujishima, Yasunori Uetani, Karou Araki
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Patent number: 6114469Abstract: Rubber compositions which contain a complex of zinc hexasulfide with an amine, together with a vulcanization accelerator exhibit favorable vulcanization behavior, and their vulcanizates show improved properties.Type: GrantFiled: August 17, 1998Date of Patent: September 5, 2000Assignee: Flexsys America L.P.Inventors: Thomas Bigley Rauchfuss, Otto William Maender, Frederick Ignatz-Hoover
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Patent number: 6069209Abstract: Chelating resins for use in selectively binding heavy metals, having the structure ##STR1## where Ps represents a poly(divinylbenzene), and R represents an organic radical containing at least one N and/or S atoms but not a C--OH group, that is bound to the S atom. The preparation of these chelating resins is also disclosed.Type: GrantFiled: May 16, 1997Date of Patent: May 30, 2000Inventors: Graham Darling, Lise Hubbard
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Patent number: 5981662Abstract: The present invention relates to rubber compounds containing polymeric bis-succinimide polysulfides of the formula: ##STR1## wherein R is selected from the group consisting of phenylene and xylylene; R.sup.1 is selected from the group consisting hydrogen and alkyls having from 1 to 18 carbon atoms; x is an integer of from 2 to 8 and y is an integer of from 2 to 10.Type: GrantFiled: September 16, 1997Date of Patent: November 9, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Richard Michael D'Sidocky, Lawson Gibson Wideman
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Patent number: 5891956Abstract: Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.Type: GrantFiled: May 30, 1995Date of Patent: April 6, 1999Assignee: The Regents of the University of California, Office of Technology TransferInventors: Barbara F. Smith, Thomas W. Robison, Joel W. Gohdes
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Patent number: 5834575Abstract: As a heteroaromatic compound made functional so as to be used in nonlinear optical materials, the present invention provides a heteroaromatic compound represented by the following Formula (1), (2), (3) or (4), a polymer obtained from any of these, a nonlinear optical element comprised of the polymer, an optical device having such an element, and a process for producing them. ##STR1## wherein Ar.sup.1, Ar.sup.2 and Ar.sup.3 each independently represent an aromatic group or an aromatic group having a substituent, R.sup.1, R.sup.2 and R.sup.3 each independently represent a hydrogen atom or a monovalent organic group, X represents a monovalent organic group, Y represents a hydrogen atom or a monovalent functional group, and n represents an integer of 2 to 10.Type: GrantFiled: November 13, 1996Date of Patent: November 10, 1998Assignee: Hitachi Chemical Company, Ltd.Inventors: Yutaka Honda, Iwao Fukuchi, Masato Taya, Kwan-Yue Alex Jen
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Patent number: 5821308Abstract: There is provided a method of introducing functionality into a copolymer of an isoolefin and an alkylstyrene at the alkylbenzyl carbon atom comprising the steps of: forming a solution of said copolymer in a hydrocarbon solvent; adding to said polymer solution an alkali metal Cs, K, Na alkoxide and an alkyl lithium compound to form a superbase with the polymer solution; and adding an electrophile to said base polymer solution also provided are the metalated copolymers and the functionalized derivative therefrom.Type: GrantFiled: June 5, 1997Date of Patent: October 13, 1998Assignees: Exxon Chemical Patents Inc, Cornell Research FoundationInventors: Jean M. J. Frechet, Shah A. Haque, Joachim Hans Georg Steinke, Hsien-Chang Wang
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Patent number: 5783642Abstract: Coating compositions containing new classes of 1,3,5-triazine compounds as crosslinkers are disclosed, which compounds are of the general formula ##STR1## wherein each of Y, Z, and optionally X are independently selected from a group of the formula (II), (III) and/or (IV) ##STR2## and wherein A, D, Q, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are as defined herein.Type: GrantFiled: July 3, 1997Date of Patent: July 21, 1998Assignee: Cytec Industries Inc.Inventors: Subban Ramesh, Laurence Lyman Williams, Ram Baboo Gupta, Lon-Tang Wilson Lin
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Patent number: 5759967Abstract: The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene/alpha-olefin/diene interpolymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted interpolymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such s amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.Type: GrantFiled: June 16, 1997Date of Patent: June 2, 1998Assignee: Exxon Chemical Patents IncInventors: Won R. Song, Albert Rossi, Howard W. Turner, Howard C. Welborn, deceased, Robert D. Lundberg, Antonio Gutierrez, Robert A. Kleist
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Patent number: 5747601Abstract: Vulcanization accelerators constituted by compounds belonging to the class of dihydropyridines having the general formula (I): ##STR1## and their use in natural or synthetic rubbers.Type: GrantFiled: February 20, 1997Date of Patent: May 5, 1998Assignee: Great Lakes Chemical Italia S.r.l.Inventors: Fabio Broussard, Mauro Adovasio, Jose Roncalli
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Patent number: 5733983Abstract: A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-.alpha.-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an .alpha.-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B).Type: GrantFiled: December 10, 1996Date of Patent: March 31, 1998Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Hakuta, Tetsuo Tojo, Masaaki Kawasaki, Mikio Hosoya
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Patent number: 5710211Abstract: According to the present invention, there are provided a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (A) having an epoxy group with a compound (B) having a thiol or thioester group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction; and a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (C) having a thiol or thioester group with a compound (D) having an epoxy group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction. According to the present invention, it is possible to efficiently introduce into PVA various functional groups having excellent reactivity, crosslinkability, ionic interactivity, water-solubility, interfacial physical properties, low-temperature flexibility, etc., under relatively mild reaction conditions.Type: GrantFiled: July 19, 1996Date of Patent: January 20, 1998Assignee: Kuraray Co., Ltd.Inventors: Toshiaki Sato, Naoki Fujiwara, Atsushi Jikihara
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Patent number: 5656696Abstract: A resin composition for injection molding that has excellent transparency, and also has excellent strength and sufficient flexibility. The composition contains 50 to 99% by weight of component A, which is a copolymer of ethylene and .alpha.-olefin having a carbon number of not less than 4, and 1 to 50% by weight of component B, which is an olefin-containing polymer. The component A has: (a) a melt flow rate (MFR) of 10 to 120 g/10 min.; (b) a density (D) of not more than 0.915 g/cm.sup.3 ; and (c) at least one peak of elution volume indicated by an elution curve obtained by temperature rising elution fractionation (TREF), wherein the peak corresponds to a temperature of not more than 85.degree. C., and the elution curve may also indicate substantial elution volume at temperatures other than the temperature to which the peak corresponds.Type: GrantFiled: February 23, 1994Date of Patent: August 12, 1997Assignee: Mitsubishi Chemical CorporationInventors: Koji Yamamoto, Keiko Shichijo, Norikazu Komiya
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Patent number: 5624764Abstract: A composite material comprising a rubber composition and a metal material, wherein the rubber composition contains, per 100 parts by weight of rubber, a cobalt salt of an organic acid in an amount up to 0.5 parts by weight, 3 to 6 parts by weight of sulfur, and N-oxydiethylene-2-benzothiazolylsulfenamide or N-tert-butyl-2-benzothiazolylsulfenamide as a vulcanization accelerator, and the metal material is provided with a plating of a ternary alloy consisting of copper, zinc, and nickel.Type: GrantFiled: June 5, 1995Date of Patent: April 29, 1997Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kiyoshige Muraoka, Mamoru Uchida, Takafumi Taguchi
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Patent number: 5616655Abstract: A method is disclosed for processing a rubber composition comprising thermomechanically mixing at a rubber temperature in a range of 140.degree. C. to 190.degree. C. for a mixing time of 1 to 20 minutes(i) 100 parts by weight of at least one sulfur vulcanizable elastomer selected from conjugated diene homopolymers and copolymers, natural rubber and copolymers of at least one conjugated diene and aromatic vinyl compound;(ii) 10 to 250 phr of particulate precipitated silica;(iii) 0.01 to 1.0 parts by weight per weight of said silica of an organosilicon compound; and(iv) 0.05 to 10 phr of sodium thiosulfate pentahydrate.Addition of the sodium thiosulfate pentahydrate to sulfur vulcanizable rubber, silica and sulfur containing organosilicon compound decreases the mixing/processing time without sacrificing end product properties.Type: GrantFiled: September 11, 1995Date of Patent: April 1, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Richard M. D'Sidocky, David J. Zanzig, Shingo Futamura
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Patent number: 5569719Abstract: A vulcanizable rubber composition including a partially hydrogenated unsaturated nitrile-conjugated diene copolymer having an iodine value of smaller than 25, a sulfur vulcanizer and a tellurium dithiocarbamate compound as a vulcanization promotor. This rubber composition provides a vulcanizate having reduced heat build-up, reduced compression set and high mechanical strength.Type: GrantFiled: December 19, 1994Date of Patent: October 29, 1996Assignee: Nippon Zeon Co., Ltd.Inventors: Sachio Hayashi, Isamu Miyauchi, Motofumi Oyama
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Patent number: 5565496Abstract: A process for producing a deionizing resin, which comprises reacting an organic compound having at least one reactive hydroxy group and at least one active chelating site with an organic polymer matrix having at least one reactive --OH or --NH.sub.2 group, at a pH greater than 10.0 and thereby producing a polymer complex, washing the polymer complex with water followed by washing with a mineral acid solution and then again washing with water and thereby reducing the level of sodium, iron and chromium ions in the polymer complex to less than 500 ppb each.Type: GrantFiled: November 22, 1993Date of Patent: October 15, 1996Assignee: Hoechst Celanese CorporationInventors: M. Dalil Rahman, Philomen Z. deCroos
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Patent number: 5549932Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: March 9, 1995Date of Patent: August 27, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5464905Abstract: An ethylene/.alpha.-olefin copolymer composition containing a first and second ethylene/.alpha.-olefin copolymer is disclosed. The first ethylene/.alpha.-olefin copolymer is prepared in the prsence of a polymerization catalyst containing an organoaluminum oxy compound and at least two kinds of metallocene compounds (b) and the second ethylene/.alpha.-olefin copolymer, which differs from the first in at least one physical property, is prepared in the presence of a polymerization catalyst containing an organoaluminum oxy compound and a metallocene compound (b'). The ethylene/.alpha.-olefin copolymer composition has excellent moldability and heat stability properties and forms films having high transparency and mechanical strength.Type: GrantFiled: November 18, 1993Date of Patent: November 7, 1995Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Toshiyuki Tsutsui, Ken Yoshitsugu, Mamoru Takahashi, Akira Todo, Seiji Ohta, Hajime Inagaki
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Patent number: 5374689Abstract: Thiols, or thiolate salts, disulfides and sulfenamides of certain pyrazines are effective accelerators in the sulfur vulcanization of rubber. These compounds, based on 2-pyrazine, show improved rates of vulcanization compared with known sulfenamide accelerators.Type: GrantFiled: May 4, 1993Date of Patent: December 20, 1994Assignee: Monsanto CompanyInventors: Charles J. Rostek, Jr., Horng-Jau Lin, David J. Sikora
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Patent number: 5331058Abstract: Process for anionically polymerising a conjugated 1,3-diene monomer consists of contacting the monomer in an inert hydrocarbon solvent with a monofunctional silyl ether initiator of general formula R.sup.1 R.sup.2 R.sup.3 Si--O--A--Li where R.sup.1 to R.sup.3 are independently selected from monovalent organic substituent groups and A is a short chain hydrocarbon bridging group, to yield a polydiene having a molecular weight of typically 1,000-10,000, a high 1.4 content of typically 90% and a low polydispensity of typically 1.15. The reactive ends of the living polymer chains may be terminated with a reactive group such as hydroxyl by treating the polymer with ethylene oxide. Subsequent removal of the polymer's relatively unreactive silyl end groups by reaction with tetra-n-butylammonium fluoride produces a difunctional, chain-extendable, hydroxy-terminated polydiene useful as a rubbery binder prepolymer.Type: GrantFiled: August 17, 1992Date of Patent: July 19, 1994Assignee: The Secretary of State for Defence in her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern IrelandInventors: Neil Shepherd, Malcolm J. Stewart
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Patent number: 5312873Abstract: Water insoluble polymers are treated to place on their exposed surfaces the pendant alkyl imidocarbonyl (amide) groups to impart a high degree of hydrophilicity to that surface. Nitrile-containing polymers or copolymers in the form of insoluble films, filters or membranes are treated to convert a substantial fraction of the surface nitrile groups into the corresponding amide by the use of hydrogen peroxide or concentrated acids. The surface is rendered hydrophilic and resistant to fouling to the extent that even proteins are not denatured thereupon. The surface may also be converted to substituted amides by subsequent reactions to impart to it other functionalities or to serve as the basis for coupling reactions. Other polymers capable of surface treatment to produce pendant amidocarbonyl groups include ones containing pendant esters which on cleavage of the oxygen-carbon bond give pendant alcohol groups.Type: GrantFiled: June 6, 1991Date of Patent: May 17, 1994Assignee: Harry P. GregorInventors: Harry P. Gregor, Alexander Burshteyn, Leonard T. Hodgins, John Kassotis, Edgar Samuelson
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Patent number: 5310818Abstract: A vulcanizable rubber composition containing (i) (A) a chlorine-containing rubber and (B) a triazinethiol.amine salt or (ii) (a) a chlorine-containing rubber, (b) a triazinethiol as a vulcanization agent, and (c), as a vulcanization agent, (c-1) an aromatic carboxylic acid amine salt, (c-2) an aliphatic carboxylic acid amine salt, and (c-3) a phenolamine salt.Type: GrantFiled: November 24, 1992Date of Patent: May 10, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Tetsuo Tojo, Keiji Okada, Takashi Nakahara, Yoshiharu Kikuchi
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Patent number: 5272218Abstract: Disclosed are polymers which contain NLO dye moieties based upon a barbituric acid group, a thiobarbituric acid group or a 1,3-bis(dicyanomethylene)indan-2-ylidene group. These polymers, after poling, are useful in NLO elements in devices employing nonlinear optics. Also disclosed are various intermediates used in making such polymers.Type: GrantFiled: August 21, 1992Date of Patent: December 21, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Lap-Tak A. Cheng, Wilson Tam
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Patent number: 5270398Abstract: A curable acrylic rubber composition which is comprised of (A) an acrylic polymer and, as a curing agent, a combination of (B) a polymer of a dibutylaminotriazine thiol with (C) 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10 -oxide or a reaction product thereof with a carbonyl compound. This rubber composition is not scorched at room temperature, but is cured at a high rate of reaction at a rubber curing temperature.Type: GrantFiled: May 26, 1992Date of Patent: December 14, 1993Assignee: Nippon Zeon Co., Ltd.Inventors: Kunio Mori, Kiyoshi Hosoya
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Patent number: 5266651Abstract: Polymer reagents containing reactive functional groups are crosslinked by reacting them with compounds (crosslinking agents) which contain complimentary functional groups and have large nonlinear polarizability. The resulting polymer reagents, after poling, are useful for nonlinear optic applications. Also disclosed are the mixture which react to form the crosslinked polymer and novel crosslinking agents.Type: GrantFiled: May 3, 1991Date of Patent: November 30, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Robert P. Foss, Wilson Tam, Fredrick C. Zumsteg, Jr.
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Patent number: 5262490Abstract: A fluoroelastomer composition is disclosed comprising an elastomeric polymer and a combination of a sulfonium compound and an ammonium or phosphonium compound. Shaped articles comprising the composition are also disclosed.Type: GrantFiled: August 24, 1992Date of Patent: November 16, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert E. Kolb, Werner M. Grootaert
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Patent number: 5260411Abstract: A method for the preparation of a polyimide containing reversible crosslinks comprising the step of curing a monomer having the formula ##STR1## wherein R and R' may be the same or different and each is H or lower alkyl having 1-5 carbon atoms under conditions conducive to the formation of a polyimide and thereby forming a polyimide having the formula ##STR2## R and R' are as defined above and n is an integer from 10 to 100. The polyimide may be converted to a soluble polymer by cleaving the disulfide bond in the presence of a solvent and a reducing agent. The reduced polymer may be reformed into the polymer in an oxidation step or into a modified polyimide in other reaction steps. Copolymerization processes are also disclosed.Type: GrantFiled: April 20, 1988Date of Patent: November 9, 1993Assignee: Polytechnic UniversityInventors: Giuliana C. Tesoro, Vinod R. Sastri
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Patent number: 5248736Abstract: There are provided a process for producing a diene polymer having markedly improved tensil strength and wear resistance and further having improved heat build-up, refound resilience, processability and wet skid resistance, as well as a rubber composition containing said diene polymer and having improved tensil strength, wear resistance, etc. Said diene polymer is produced by polymerizing a conjugated diene monomer or a mixture of the conjugated diene monomer and an aromatic vinyl monomer in a hydrocarbon solvent using a composite initiator containing an alkaline earth metal, and reacting active ends of the obtained active diene polymer with (a) a compound represented by the formula M.dbd.C.dbd.M (wherein M denotes an oxygen atom or a sulfur atom) or (b) N-substituted aminoketone, N-substituted thioaminoketone, N-substituted aminoaldehyde, N-substituted thioaminoaldehyde or a compound having an atomic group in a molecule represented by the formula --C(.dbd.M)--N< in a molecule.Type: GrantFiled: March 13, 1992Date of Patent: September 28, 1993Assignee: Nippon Zeon Co., Ltd.Inventors: Fumitoshi Suzuki, Yoshihiro Chino
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Patent number: 5232990Abstract: Derivatives of melamine are disclosed having a carboxylic acid substituent on an amine nitrogen appended to the triazine ring. The compounds can be used to cross-link polymers having epoxy groups thereon.Type: GrantFiled: November 25, 1991Date of Patent: August 3, 1993Assignee: BASF CorporationInventor: John W. Rehfuss
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Patent number: 5221331Abstract: An aquatic antifouling composition characterized by containing as effective antifouling component a metal salt of hexamethylenedithiocarbamic acid represented by the formula below: ##STR1## (where M is a divalent or trivalent metal; n is 2 or 3.Type: GrantFiled: November 27, 1991Date of Patent: June 22, 1993Assignee: Rohm and Haas CompanyInventors: Hirotake Ikari, Teruyoshi Takahashi, Hiroshi Kanbara
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Patent number: 5219904Abstract: A cross-linkable, fluorine-containing elastomer composition comprising a fluorine-containing elastomer containing at least one of iodine and bromine in the molecule, an organic peroxide having a peroxy group --O--O--C(CH.sub.3).sub.2 R, where R is a lower alkyl group, in the molecule and an activation energy of not more than 34.0 Kcal/mole and another organic peroxide having the same peroxy group as defined above in the molecule and an activation energy of less than 34.0 Kcal/mole as cross-linking agents for the elastomer has less generation of CH.sub.3 I or CH.sub.3 Br at the decomposition of the organic peroxides without any substantial decrease in the compression set of the vulcanization products.Type: GrantFiled: May 19, 1992Date of Patent: June 15, 1993Assignee: Nippon Mektron LimitedInventor: Masatoshi Abe
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Patent number: 5126409Abstract: Polyglutarimides exhibit improved optical properties, as well as lowered content of non-aqueous volatiles, when the molten polyglutarimide is mixed with water, methanol, ethanol, or mixtures thereof, and the water, methanol, ethanol, or mixtures thereof is removed prior to isolation and processing of the polyglutarimide.Type: GrantFiled: January 8, 1991Date of Patent: June 30, 1992Assignee: Rohm and Haas CompanyInventors: Robert E. Jerman, William T. Freed, Leslie A. Cohen, Lucinda F. Buhse, Glenn W. Miller
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Patent number: 5078905Abstract: A vulcanization composition for elastomers, the composition comprising, by weight: 0.5 parts to 3 parts mercaptobenzothiazole, 0.5 parts to 3 parts tetramethylthiuram disulfide, 3 parts to 5 parts zinc oxide, 1 part to 3 parts stearic acid, 1 part to 4 parts anti-oxidant, and 1 part to 5 parts vulcanization agent constituted by 0% to 100% sublimated sulfur, 0% to 75% sulfur donor selected from thiurams and dithiomorpholines, and 0% to 50% sulfenamide, with the weight ratio of sulfenamide to sulfur donor lying in the range 1/3 to 1. The invention is applicable to vulcanizing a three-sequence copolymer of styrene-butadiene-styrene mixed with bitumen.Type: GrantFiled: May 16, 1989Date of Patent: January 7, 1992Assignee: Societe Anonyme d'Application des Derives de l'AsphalteInventors: Cu C. Trinh, Denis Million
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Patent number: 5079305Abstract: Heterocyclic thiol sulfenimide compounds are useful as an accelerator in the curing of natural and/or synthetic rubbers. The compound can be represented by the formula ##STR1## wherein each of A.sup.1 and R.sup.2, independently, is at least one heterocyclic ring containing one or more nitrogen atoms therein, or at least one heterocyclic ring containing one or more nitrogen atoms therein and (1) one or more hydrocarbyl substituents, or (2) one or more electron withdrawing groups, or (3) one or more electron releasing groups, wherein A.sup.Type: GrantFiled: September 5, 1989Date of Patent: January 7, 1992Assignee: Monsanto CompanyInventor: Charles J. Rostek, Jr.
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Patent number: 5075385Abstract: A vulcanizable elastomer composition is prepared by blending 100 parts by weight of a copolymer containing(A) 50-85% by mole of ethylene unit,(B) 10-45% by mole of an alkyl acrylate unit having the formula (I), ##STR1## wherein R.sub.1 is an alkyl having 1-8 carbon atoms, (C) 2-35% by mole of an alkoxyalkyl acrylate unit having the formula (II), ##STR2## wherein R.sub.2 is hydrogen or methyl, R.sub.3 is an alkylene having 1-4 carbon atoms, and R.sup.4 is an alkyl or alkoxyalkyl, each having 1-4 carbon atoms, and(D) up to 5% by mole of a glycidyl ester unit having the formula (III), ##STR3## wherein R.sup.5 is hydrogen or methyl, and 0.1-10 parts by weight of at least one vulcanizing agent.The vulcanizable composition can give vulcanizates of well-balanced properties having an improved low-temperature resistance and retaining excellent oil resistance.Type: GrantFiled: December 4, 1990Date of Patent: December 24, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Nobuyuki Yoshida, Hisao Tanaka, Masahiro Fukuyama
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Patent number: 5036142Abstract: The invention provides a method for making optionally active polymers having a carbon-to-carbon backbone chain and pendant "transducer" groups having an azo linkage which involves azo-coupling, in homogeneous solution, a carbon-to-carbon backbone polymer having pendant groups terminating in an aromatic group with an aromatic diazonium salt, and recovering the resultant reaction product.Type: GrantFiled: December 26, 1989Date of Patent: July 30, 1991Assignee: Allied-Signal Inc.Inventor: Chengjiu Wu
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Patent number: 4985507Abstract: A vulcanizable elastomer composition is prepared by blending100 parts by weight of a copolymer containing(A) 50-85% by mole of ethylene unit,(B) 10-45% by mole of an alkyl acrylate unit having the formula (I), ##STR1## wherein R.sub.1 is an alkyl having 1-8 carbon atoms, (C) 2-35% by mole of an alkoxyalkyl acrylate unit having the formula (II), ##STR2## wherein R.sub.2 is hydrogen or methyl, R.sub.3 is an alkylene having 1-4 carbon atoms, and R.sub.4 is an alkyl or alkoxyalkyl, each having 1-4 carbon atoms, and(D) up to 5% by mole of a glycidyl ester unit having the formula (III), ##STR3## wherein R.sup.5 is hydrogen or methyl, and 0.1-10 parts by weight of at least one vulcanizing agent.The vulcanizable composition can give vulcanizates of well-balanced properties having an improved low-temperature resistance and retaining excellent oil resistance.Type: GrantFiled: May 15, 1989Date of Patent: January 15, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Nobuyuki Yoshida, Hisao Tanaka, Masahiro Fukuyama
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Patent number: 4981917Abstract: Polymer bound antioxidants are provided in which the antioxidant stabilizer groups are chemically bound to polymers or copolymers by an acylaminoimide or diacylhydrazide function. The polymer bound antioxidants are prepared by reacting hydrazido substituted antioxidants with some or all of the anhydride groups of anhydride containing polymers or copolymers. The concentration of the stabilizers bound to the polymer may be readily varied depending upon the particular end-use of said polymer. Polymer with high concentrations of bound antioxidants can be used as masterbatches to stabilize other polymer systems.Type: GrantFiled: June 22, 1989Date of Patent: January 1, 1991Assignee: Atochem North America, Inc.Inventors: Ronald E. MacLeay, Terry N. Myers
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Patent number: 4956419Abstract: This invention provides fluorine-containing polymers having a plurality of thioorgano groups. These polymers are prepared by reacting a fluoropolymer precursor with one or more, organic, thiolate compounds thereby modifying the fluoropolymer precursor by grafting onto its backbone the thioorgano groups. Said thioorgano groups may contain functional moieties that modify the cure properties, bulk properties or compatibility of the thioorgano fluoropolymer precursor. This invention also provides shaped or formed cured articles, coatings and solutions comprising the thioorgano fluoropolymers, and blends thereof with other compatible polymers.Type: GrantFiled: November 20, 1989Date of Patent: September 11, 1990Assignee: Minnesota Mining and Manufacturing CompanyInventors: Robert E. Kolb, Paul F. Tuckner, Richard A. Guenthner
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Patent number: 4948843Abstract: Dye-containing polymers wherein the dyes are organic in nature are incorporated into glasses produced by a sol-gel technique. The glasses may be inorganic or organic-modified metal oxide heteropolycondensates. The dye-containing polymers are covalently bonded to the glass through a linking group. The products of this invention can be used to make optically clear colored films which can be employed in the imaging, optical, solar heat energy and related arts.Type: GrantFiled: May 30, 1989Date of Patent: August 14, 1990Assignee: Eastman Kodak CompanyInventors: Michael R. Roberts, Bradley K. Coltrain, Sharon M. Melpolder
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Patent number: 4946593Abstract: A rubber composition for use with potable water is disclosed. The composition is based on butyl rubber. The accelerator system is carbamate-free and the composition preferably includes coal-derived carbon black. Improvements in processing are also disclosed.Type: GrantFiled: August 29, 1989Date of Patent: August 7, 1990Assignee: Acushnet CompanyInventor: Edward P. Pinigis
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Patent number: 4910266Abstract: Chlorothio-sulfonamide modified rubbery terpolymers, such as chlorothio-sulfonamide modified EPDM rubbers, have utility in a variety of applications. For example, such modified rubbers can be utilized in the sidewalls of pneumatic tires. Such modified rubbers are prepared by reacting a terpolymer of ethylene, an .alpha.-olefin containing from 3 to 6 carbon atoms, and a non-conjugated diene containing from 6 to 12 carbon atoms with a N-chlorothio-sulfonamide. The present invention is based upon the unexpected finding that the rate of this reaction can be greatly accelerated by conducting it in the presence of a saturated aliphatic carboxylic acid containing from 6 to 30 carbon atoms, such as stearic acid. The present invention accordingly disclosed in a method of preparing a N-chlorothio-sulfonamide modified terpolymer by reacting a terpolymer of ethylene, an .alpha.Type: GrantFiled: April 10, 1989Date of Patent: March 20, 1990Assignee: The Goodyear Tire & Rubber CompanyInventor: Roger J. Hopper
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Patent number: 4910267Abstract: An anti-degrading rubber article to be used in contact with a mineral oil containing an oil modifier, at least that surface of said rubber article which is to come into contact with said mineral oil being composed substantially of a vulcanization product, obtained by using a sulfur vulcanization system, of a copolymer rubber having polymer chains consisting of(1) 10 to 60% by weight of units derived from an unsaturated nitride,(2) 2 to 30% by weight of units derived from a conjugated diene, and(3) 88 to 10% by weight of units derived from a copolymerizable ethylenically unsaturated monomer other than the unsaturated nitride and/or units resulting from the hydrogenation of units derived from a conjugated diene.Type: GrantFiled: February 10, 1988Date of Patent: March 20, 1990Assignee: Nippon Zeon Co., Ltd.Inventors: Motofumi Oyama, Yoichiro Kubo, Toshiharu Honda
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Patent number: RE37527Abstract: A heat-resistant rubber composition of the invention is a vulcanizable composition comprising a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) and an organic peroxide (B). This heat-resistant composition has high crosslinking efficiency given by the organic peroxide and high modulus, and can provide a vulcanized rubber molded product of excellent resistance to environmental deterioration such as thermal aging resistance. The other heat-resistant rubber composition of the invention is a vulcanizable composition comprising 100 parts by weight of a specific ethylene-&agr;-olefin-nonconjugated polyene copolymer rubber (A) composed of ethylene, an &agr;-olefin or 3 to 20 carbon atoms and a nonconjugated polyene which is a vinyl end group-containing norbornene compound, 0.2 to 5 parts by weight of an amine type anti-aging agent (C) and/or a hindered phenol type anti-aging agent (D), 1 to 10 parts by weight of a sulfur type anti-aging agent (E) and an organic peroxide (B).Type: GrantFiled: March 29, 2000Date of Patent: January 22, 2002Assignee: Mitsu ChemicalsInventors: Takashi Hakuta, Tetsuo Tojo, Masaaki Kawasaki, Mikio Hosoya
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Patent number: RE34514Abstract: A composition comprising (a) at least one oxidized polycationic polyheteroaromatic compound and (b) at least one polyanion of a film-forming thermoplastic polymer containing sulfated alcohol groups ##STR1## in repeating structural units. The composition has high electrical conductivity and good mechanical properties, especially after drawing at temperatures below the melt/decomposition temperature. The material may be used as electrodes, electrically conductive filaments or components for electromagnetic screening.Type: GrantFiled: April 27, 1992Date of Patent: January 18, 1994Assignee: Ciba-Geigy CorporationInventors: Wolfgang Wernet, Jean Stoffer