Mixture Contains Two Or More Solid Block Or Block-type Copolymers Patents (Class 525/89)
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Publication number: 20140070131Abstract: A composition for a refrigerator gasket is provided. The composition includes, as a polymer base, a blend of an olefin/?-olefin (OAO) copolymer having a melting point of at least 100° C. and a styrene block copolymer (SBC). The polymer base has a melt index (190° C., 5 kg) of 0.01 to 15 g/10 min.Type: ApplicationFiled: September 12, 2013Publication date: March 13, 2014Applicant: FINE CHEMICAL CO., LTD.Inventor: Sung Yull LEE
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Patent number: 8653189Abstract: The present invention relates to oil-extended styrenic block copolymer compositions that include a thermoplastic polymer, such as polystyrene, and a styrenic block copolymer, especially a linear styrene-butadiene-styrene triblock copolymer, with a styrene content less than 23 percent by weight, based upon total composition weight. The compositions yield very thin polymeric films with satisfactory physical properties.Type: GrantFiled: February 18, 2008Date of Patent: February 18, 2014Assignee: TSRC (USA) Investment CorporationInventor: Andre J. Uzee
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Patent number: 8637131Abstract: Articles useful in the food packaging, food service, and healthcare industries are formed from a composition prepared by melt blending specific amounts of a poly(phenylene ether), a radial block copolymer of an alkenyl aromatic monomer and a conjugated diene, a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer, a hydrogenated terpene resin, and benzoin. The composition provides optical clarity, heat resistance, and impact resistance to the articles.Type: GrantFiled: March 7, 2013Date of Patent: January 28, 2014Assignee: Sabic Innovative Plastics IP B.V.Inventors: Kim G. Balfour, Kristopher Rexius
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Patent number: 8618221Abstract: Methods of directed self-assembly of multi-block (i.e., triblock and higher-order) copolymers on patterned substrates and related compositions are provided. According to various embodiments, the methods involve depositing copolymer materials on substrates configured to drive the assembly of micro-phase separated films that exhibit the same morphology as that copolymer materials in the bulk. In certain embodiments, binary patterns are used to drive the triblock copolymer films. The binary two-dimensional surface patterns are transformed into three-component and three-dimensional structures throughout the thickness of the overlying copolymer films.Type: GrantFiled: October 12, 2006Date of Patent: December 31, 2013Assignee: Wisconsin Alumni Research FoundationInventors: Paul Franklin Nealey, Frank S. Bates, Juan J. de Pablo
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Patent number: 8598271Abstract: An object of the present invention is to provide a block copolymer composition containing an aromatic vinyl-conjugated diene-aromatic vinyl block copolymer, which is capable of achieving a high-level balance between a high elastic modulus and a small permanent set, and is capable of producing a highly isotropic molded product having uniform mechanical properties even when a molding method which is likely to cause molecular orientation, such as extrusion molding, is applied.Type: GrantFiled: December 25, 2009Date of Patent: December 3, 2013Assignee: Zeon CorporationInventors: Ryouji Oda, Takeshi Ooishi
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Patent number: 8598266Abstract: The present technology relates to compositions comprising a copolymer comprising a poly(C2-4 alkylene oxide) and a cationic polyacrylamide, and a plurality of nanoparticles of titanium dioxide, zinc oxide or a mixture thereof. The compositions may serve as flocculating agents to remove neutral and negatively charged nanoparticle pollutants from gasses, including air, and liquids such as water.Type: GrantFiled: March 25, 2011Date of Patent: December 3, 2013Assignee: Empire Technology Development LLCInventor: Yanjie Xu
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Patent number: 8580884Abstract: A novel block copolymer composition including a hydrogenated block copolymer that has at least one block A and at least one block B, and wherein (a) prior to hydrogenation each A block is a mono alkenyl arene homopolymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene, (b) subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced, (c) each A block having a number average molecular weight between about 3,000 and about 60,000 and each B block having a number average molecular weight between about 30,000 and about 300,000, (d) each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and one or more regions not adjacent to the A blocks that are rich in mono alkenyl arene units, (e) the total amount of mono alkenyl arene in the hydrogenated block copolymer is about 5 percent wType: GrantFiled: November 11, 2010Date of Patent: November 12, 2013Assignee: Kraton Polymers U.S. LLCInventor: Ruidong Ding
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Patent number: 8578852Abstract: Disclosed is a block copolymer composition for flexographic printing plates, which is capable of providing a flexographic printing plate that has much more excellent wear resistance than conventional flexographic printing plates, while maintaining sufficient rubber elasticity. The block copolymer composition for flexographic printing plates comprises a block copolymer A and a block copolymer B, each of which is an aromatic vinyl-conjugated diene-aromatic vinyl block copolymer having a specific structure, wherein a content of the aromatic vinyl monomer unit in the block copolymer A is 41% or more.Type: GrantFiled: February 24, 2010Date of Patent: November 12, 2013Assignee: Zeon CorporationInventors: Tetsuaki Matsubara, Ryouji Oda
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Publication number: 20130296492Abstract: The invention relates to a functionalized diene elastomer composed a) of a specific block copolymer functionalized, at the chain end or in the middle of the chain, by a tin functional group, b) of a specific block copolymer star-branched by tin and c) of a content of less than 15% by weight, with respect to the total weight of the functionalized diene elastomer, of a specific non-tin-functional block copolymer.Type: ApplicationFiled: November 23, 2011Publication date: November 7, 2013Applicants: Michelin Recherche et Technique S.A., COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELINInventors: Mathilde Abad, Margarita Dorato, Jean-Michel Favrot, Nathalie Simon, Jean Marc Marechal, Stéphanie De Landtsheer
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Publication number: 20130296491Abstract: The invention provides a class of wedge-type block copolymers having a plurality of chemically different blocks, at least a portion of which incorporates a wedge group-containing block providing useful properties. For example, use of one or more wedge group-containing blocks in some block copolymers of the invention significantly inhibits chain entanglement and, thus, the present block copolymers materials provide a class of polymer materials capable of efficient molecular self-assembly to generate a range of structures, such as periodic nanostructures and microstructures. Materials of the present invention include copolymers having one or more wedge group-containing blocks, and optionally for some applications copolymers also incorporating one or more polymer side group-containing blocks. The present invention also provides useful methods of making and using wedge-type block copolymers.Type: ApplicationFiled: March 13, 2013Publication date: November 7, 2013Inventors: Yan XIA, Benjamin R. SVEINBJORNSSON, Robert H. GRUBBS, Raymond WEITEKAMP, Garrett M. MIYAKE, Victoria PIUNOVA, Christopher Scot DAEFFLER
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Patent number: 8575269Abstract: A mixture which contains a) a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from ?70° to 0° C., c) a polystyrene C, and its use for the production of packaging for electronics components.Type: GrantFiled: September 3, 2008Date of Patent: November 5, 2013Assignee: Styrolution GmbHInventors: Konrad Knoll, Jürgen Koch, Piyada Charoensirisomboon, Daniel Wagner
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Patent number: 8563646Abstract: An adhesive composition having good balance in tackiness properties such as tack strength and retentivity, low melt viscosity, high processability, and high stability in melt viscosity under high temperature heating is provided. An adhesive composition containing two hydrogenated block copolymers and a predetermined tackifier is provided, the two hydrogenated block copolymers each having a different structure obtained by controlling the degree of hydrogenation of a block copolymer of a conjugated diene compound and a vinyl aromatic hydrocarbon in a particular range.Type: GrantFiled: April 10, 2009Date of Patent: October 22, 2013Assignees: Asahi Kasei Chemicals Corporation, Japan Elastomer Co., Ltd.Inventors: Shigeo Nakajima, Yukinori Nakamichi
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Patent number: 8552114Abstract: The present invention provides a block copolymer composition and method of making the same having the structures (A2-B)n-X-(A1) or (A2-B2)n-X-(B1A1), where A1 and A2 are each a polymer block of a monoalkenyl arene and B, B1, and B2 are each a polymer block of one or more conjugated dienes or a hydrogenated diene polymer, n is an integer from 2 to 30 and X is the residue of a coupling agent.Type: GrantFiled: November 30, 2012Date of Patent: October 8, 2013Assignee: Kraton Polymers U.S. LLCInventors: Dale Lee Handlin, Jr., Peter Pasman, Glenn H. Fredrickson, Carl L. Willis, Robert C. Bening
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Patent number: 8546488Abstract: Cleavable, disulfide-coupled block copolymers as can be used in the preparation of nanoporous thin films, micellar configurations and related structures.Type: GrantFiled: May 25, 2012Date of Patent: October 1, 2013Assignee: University of MassachusettsInventors: Sankaran Thayumanavan, Akamol Klaikherd, Suhrit Ghosh
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Publication number: 20130237648Abstract: A poly(phenylene ether)-poly(hydroxy ether) block copolymer is used to compatibilize blends of polar polymers and non-polar polymers. The resulting compatibilized blends exhibit physical property improvements relative to blends without a compatibilizer and blends with a poly(hydroxy ether).Type: ApplicationFiled: March 8, 2012Publication date: September 12, 2013Inventor: Edward Norman Peters
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Publication number: 20130237655Abstract: Compositions comprising (A) propylene-alpha-olefin copolymer, (B) olefin block copolymer, and (C) DPO-BSA molecular melt (MM) are useful in the preparation of the top skin layer of artificial leather multi-layer structures.Type: ApplicationFiled: November 24, 2010Publication date: September 12, 2013Inventors: Yong Chen, Hong Yang, David Hong Fei Guo, Kim L. Walton
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Patent number: 8513356Abstract: A diblock copolymer blend containing a unique combination of an ordered poly(styrene)-b-poly(methyl methacrylate) diblock copolymer and a disordered poly(styrene)-b-poly(methyl methacrylate) diblock copolymer is provided. Also provided are substrates treated with the diblock copolymer blend.Type: GrantFiled: February 10, 2012Date of Patent: August 20, 2013Assignee: Dow Global Technologies LLCInventors: Rahul Sharma, Valeriy V. Ginzburg, Phillip D. Hustad, Jeffrey D. Weinhold
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Publication number: 20130210945Abstract: The invention relates to a cross-linked elastomer composition including: an ethylene/alpha-olefin multiblock copolymer comprising polymerized ethylene and alpha-olefin units, an elastomer including a block copolymer having at least two, identical or different, aromatic blocks which are separated by at least one elastomer block, and a cross-linkable polymer, for example, a diene elastomer. The invention also relates to a product including the composition, and to the use of such a product as a seal.Type: ApplicationFiled: June 20, 2011Publication date: August 15, 2013Inventors: Fabrice Picot, Démosthène Sakkas, Aline Grudet
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Publication number: 20130203909Abstract: The present disclosure relates to thermoplastic polycarbonate blends compositions having, among other characteristics, improved electroplate adhesion properties. In particular, the disclosure relates to such polycarbonate compositions comprising a polycarbonate component, a primary ABS impact modifier, and a secondary impact modifier chemically different from the primary impact modifier. Also included herein are methods for preparing and/or using the same, as well as articles formed from such compositions/blends.Type: ApplicationFiled: February 3, 2012Publication date: August 8, 2013Inventors: Amit S. Kulkarni, Thomas Dulmage, Jeffrey Eshenaur
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Patent number: 8501869Abstract: Provided is a hot-melt adhesive composition which can be easily applied at a relatively low temperature, has a long open time, and also has high holding power. A hot-melt adhesive composition comprising a block copolymer composition which includes a block copolymer A and a block copolymer B, and a tackifying resin, wherein a weight ratio (A/B) of the block copolymer A and the block copolymer B is 25/75 to 90/10, and an aromatic vinyl monomer unit content of the block copolymer A is 41% or greater.Type: GrantFiled: December 25, 2009Date of Patent: August 6, 2013Assignee: Zeon CorporationInventors: Ryouji Oda, Sadaharu Hashimoto, Ayako Furuko
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Patent number: 8492481Abstract: The present invention relates to a block polymeric material. Typically the block polymer comprises units capable of having an average cationic charge density of about 15 or less, preferably 5 or less, more preferably from about 0.05 to about 5, even more preferably from about 0.05 to about 2.77, even more preferably from about 0.1 to about 2.75, most preferably from about 0.75 to about 2.25 units per 100 daltons molecular weight at a pH of from about 4 to about 12. The polymeric material is a suds enhancer and a suds volume extender for personal care products such as soaps and shampoos. The compositions have increased effectiveness for preventing re-deposition of grease during hand and body washing. The polymers are also effective as a soil release agent in fabric cleaning compositions.Type: GrantFiled: March 25, 2011Date of Patent: July 23, 2013Assignee: Rhodia Inc.Inventors: Dominic Wai-Kwing Yeung, Vance Bergeron, Jean-Francois Bodet, Mark R. Sivik, Bernard W. Kluesener, William M. Scheper
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Patent number: 8492479Abstract: A process for preparing a functionalized or unfunctionalized diene block copolymer comprising at least one polyether block of number-average molecular weight approximately from 150 to 5000 g/mol linked to at least one block constituted of a diene elastomer via at least one silicon atom. The process allows a high degree of grafting of the polyether to the polymer chains. Also disclosed is a reinforced rubber composition, especially intended for the manufacture of tires, comprising such a diene block copolymer which is intended to interact with the reinforcing filler. Such a rubber composition has improved hysteresis properties in the vulcanized state, while retaining satisfactory processing properties in the non-vulcanized state.Type: GrantFiled: June 19, 2008Date of Patent: July 23, 2013Assignees: Michelin Recherche et Technique S.A., Compagnie Generale des Etablissements MichelinInventors: Pierre Robert, Nicolas Seeboth, Jean-Michel Favrot, Philippe Chaboche
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Patent number: 8492480Abstract: A block copolymer composition comprising an aromatic vinyl-conjugated diene-aromatic vinyl block copolymer having a high-level balance between a high elastic modulus and a small elongation set is provided. The block copolymer composition comprises a block copolymer A represented by formula (A) and a block copolymer B represented by formula (B), where the weight ratio of the block copolymer A to the block copolymer B, A/B, is from 36/64 to 85/15 and the ratio of the aromatic vinyl monomer units relative to all polymer components in the block copolymer composition is 27-70 wt %. Ar1a-Da-Ar2a (A). Ar1b-Db-Ar2b (B).Type: GrantFiled: March 30, 2009Date of Patent: July 23, 2013Assignee: Zeon CorporationInventors: Takeshi Ooishi, Ryouji Oda
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Patent number: 8481644Abstract: Compositions comprising a coupled interpolymer such as polybutadiene which may be suitable for HIPS and ABS have been discovered. The coupled interpolymer composition comprises an interpolymer comprising one or more monomeric units derived from a diene wherein the coupled interpolymer composition is characterized by: (A) a halide content of less than about 30 ppm based on the total weight of the coupled interpolymer; (B) a molecular weight distribution of from about 1.6 to about 2.4; and (C) a vinyl content of from about 5 to about 15 weight percent based on the total weight of the coupled interpolymer.Type: GrantFiled: June 2, 2009Date of Patent: July 9, 2013Assignee: Styron Europe GmbHInventors: Evemarie Hamann, Vera Steinert, Norbert Jantsch
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Patent number: 8469143Abstract: An insert for sealing and acoustic damping of a longitudinal cavity having an interior surface, comprising: a) one or more carrier plates made of a polymeric material (A) which does not deform when heated to a temperature not higher than 180° C. and which comprises a main polymer (A1) which gives mechanical strength to the carrier plate, and—at least one vibration-damping polymer (A2), and b) a thermally expandable material (B). The vibration-damping polymer (A2) is preferably selected from the group comprising: thermoplastic polyurethanes, styrene/butadiene block copolymers, hydrogenated styrene/butadiene block copolymers, styrene/isoprene block copolymers, hydrogenated styrene/isoprene block copolymers, styrene/isoprene/styrene tri-block copolymers, and hydrogenated styrene/isoprene/styrene tri-block copolymers.Type: GrantFiled: June 16, 2011Date of Patent: June 25, 2013Inventors: Fabrice Prunarety, Jean-Luc Wojtowicki, Josef Hudina
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Patent number: 8470929Abstract: Provided is a composition for a stretchable film, which achieves a high-level balance between a high elastic modulus and a small permanent set, and can be formed into a stretchable film with satisfactory formability. A composition for a stretchable film comprises a block copolymer composition containing a block copolymer A represented by the following general formula (A) and a block copolymer B represented by the following general formula (B), and a tackifier resin: Ar1a-Da-Ar2a ??(A) (Arb-Db)n-X ??(B), in the general formulas (A) and (B), Ar1a and Arb each represent an aromatic vinyl polymer block having a weight average molecular weight of 6,000 to 20,000; Ar2a represents an aromatic vinyl polymer block having a weight average molecular weight of 40,000 to 400,000; Da and Db each represent a conjugated diene polymer block having a vinyl bond content of 1 mol % to 20 mol %; X represents a single bond or a residue of a coupling agent; and n represents an integer of 2 or greater.Type: GrantFiled: March 29, 2010Date of Patent: June 25, 2013Assignee: Zeon CorporationInventors: Takeshi Ooishi, Takurou Sakurai
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Patent number: 8465844Abstract: Hot melt adhesive compositions containing radial polystyrene-polyisoprene/polybutadiene block copolymer and use as elastic attachment adhesive in the manufacture of disposable absorbent elastic articles.Type: GrantFiled: February 13, 2004Date of Patent: June 18, 2013Assignee: Henkel AG & Co. KGaAInventors: Qiwei He, Michael G. Harwell
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Patent number: 8461246Abstract: The present invention provides a mixture of conjugated diene-vinyl aromatic hydrocarbon copolymers and an adhesive having the same. The mixture of conjugated diene-vinyl aromatic hydrocarbon copolymers comprises 10 to 45 wt. % of a conjugated diene-vinyl aromatic hydrocarbon di-block copolymer, 10 to 45 wt. % of a conjugated diene-vinyl aromatic hydrocarbon tapered di-block copolymer and 10 to 80 wt. % of a conjugated diene-vinyl aromatic multi-block copolymer.Type: GrantFiled: April 28, 2010Date of Patent: June 11, 2013Assignee: TSRC CorporationInventors: Kung-Hsi Chan, Tsung Hsin Chen, Tai Wen Chiu
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Publication number: 20130120509Abstract: An elastic member for inkjet includes a resin composition including at least a (b)-(a)-(b) type isobutylene-based triblock copolymer including an isobutylene-based polymer block (a) and a styrene-based polymer block (b), and a styrene-based polymer.Type: ApplicationFiled: July 15, 2011Publication date: May 16, 2013Applicant: CANON KABUSHIKI KAISHAInventors: Takashi Fukushima, Toshihiko Ujita, Akihiko Shimomura, Kyosuke Nagaoka
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Patent number: 8419890Abstract: The invention relates to composition for an acrylic structural adhesive containing a mixture of block copolymers containing styrene and an elastomer.Type: GrantFiled: December 24, 2007Date of Patent: April 16, 2013Assignee: JacretInventors: Arnaud Curet, Régis David
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Publication number: 20130090420Abstract: The invention provides a thermoplastic polymer composition which is excellent in flexibility, mechanical properties, moldability, and coloring resistance and which provides excellent adhesion to polar resin, a resin containing an inorganic filler (particularly, glass fiber), ceramic material, glass, or metal, and an article formed from the thermoplastic polymer composition. Specifically, the invention provides a thermoplastic polymer composition containing 100 parts by mass of a hydrogenated block copolymer mixture (a); 0.1 to 100 parts by mass of a polyvinyl acetal (b); and 0.Type: ApplicationFiled: March 30, 2011Publication date: April 11, 2013Applicant: KURARAY CO LTDInventors: Shigenao Kuwahara, Asako Minamide
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Patent number: 8415429Abstract: We disclose a monovinylarene-conjugated diene block copolymer containing a plurality of monovinylarene-conjugated diene mixed blocks, wherein each mixed block contains conjugated diene units and monovinylarene units in a weight ratio of about 0.05 to about 0.33. We also disclose a composition containing (a) from about 50 parts by weight to about 95 parts by weight of the monovinylarene-conjugated diene block copolymer and (b) from about 5 parts by weight to about 50 parts by weight of polystyrene; wherein the monovinylarene-conjugated diene block copolymer and the polystyrene total 100 parts by weight.Type: GrantFiled: December 11, 2006Date of Patent: April 9, 2013Assignee: Chervron Phillips Chemical Company LPInventors: John Mark Brown, Michael A. Smith, Nathan E. Stacy, Carleton E. Stouffer, John D. Wilkey
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Patent number: 8415438Abstract: Disclosed is a new method and compositions from the method consisting of block copolycarbonate/phosphonates that exhibit an excellent combination of flame resistance, hydrolytic stability, high Tg, low melt viscosity, low color and high toughness. Also disclosed are polymer mixtures or blends comprised of these block copolycarbonate/phosphonate compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, adhesives and fiber-reinforced articles, or any combination thereof.Type: GrantFiled: October 26, 2010Date of Patent: April 9, 2013Assignee: FRX Polymers, Inc.Inventor: Dieter Freitag
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Patent number: 8410215Abstract: A thermoplastic resin composition contains (i) a polylactic acid, (ii) a polyolefin, and (iii) a compatibilizer (functional group-containing polymer that includes a functional group selected from functional groups X including a carboxyl group, an acid anhydride group, an epoxy group, a (meth)acryloyl group, an amino group, an alkoxysilyl group, a hydroxyl group, an isocyanate group, and an oxazoline group). The thermoplastic resin composition contains (iii-1) a functional group-containing hydrogenated diene polymer and (iii-2) a functional group-containing olefin polymer as the component (iii).Type: GrantFiled: August 23, 2007Date of Patent: April 2, 2013Assignee: JSR CorporationInventors: Takuya Sano, Toshiyuki Hayakawa, Takeo Nakamura, Teruo Aoyama, Akihiko Okubo, Satoshi Kura
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Publication number: 20130079468Abstract: There is provided a pressure-sensitive adhesive composition for optical films, which is excellent in heat resistance, weathering resistance and bleed resistance, which has an excellent balance of pressure-sensitive adhesion properties, such as adhesive strength, cohesive force and tack, the tack of which can be controlled, which is excellent in initial reworkability when it is used for applying an optical film to an adherend or applying a protective film to an optical film, and which further exhibits excellent adhesive durability by virtue of rise of adhesive strength when such a film as above in the applied state is kept over a long period of time after application or especially when the film in the applied state is exposed to high temperatures or moist heat.Type: ApplicationFiled: June 3, 2011Publication date: March 28, 2013Applicant: KURARAY CO., LTD.Inventors: Hideaki Kanemura, Yoshihiro Morishita, Shinya Oshita, Masahiko Kawasaki
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Patent number: 8399555Abstract: To provide an aqueous coating composition which has a high storage stability and which is capable of forming a coating film excellent in gloss, adhesion and water resistance; a process for its production; and a process for forming a coating film by using the aqueous coating composition. An aqueous coating composition comprising a fluoro-olefin copolymer, a pigment, a copolymer (1) (an A-B type block copolymer which is a copolymer having no fluorine atoms or ionic groups and which comprises hydrophilic blocks (A) having repeating units (a) having a polyoxyethylene chain in the side chain, and hydrophobic blocks (B) having repeating units (b) having a hydrocarbon chain in the side chain) and an aqueous medium.Type: GrantFiled: April 7, 2011Date of Patent: March 19, 2013Assignee: Asahi Glass Company, LimitedInventors: Isao Kimura, Naoko Sumi
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Patent number: 8394892Abstract: The present invention provides a thermoplastic elastomer composition comprising: 100 parts by weight of component (A), 10 to 100 parts by weight of component (B), 50 to 200 parts by weight of component (C), and 5 to 30 parts by weight of component (D). Component (A) is a propylene polymer having a melting point of 155° C. or more. Component (B) is a crystalline propylene-ethylene copolymer. Component (C) is an ethylene-?-olefin rubber having Mooney Viscosity of 30 to 100(ML1+4, 125° C.). Component (D) is a hydrogenated product of block copolymer comprising blocks of aromatic vinyl compound units and blocks of conjugated diene compound units.Type: GrantFiled: September 14, 2009Date of Patent: March 12, 2013Assignee: Sumitomo Chemical Company, Ltd.Inventors: Nadeem Akhtar Bokhari, Kousuke Ohtani, Yasuhito Ijichi
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Patent number: 8357754Abstract: A process for producing a microporous polymeric object to improve the degree of freedom for its various properties, compared to conventional processes, includes: mixing a block copolymer made of three or more kinds of segments with a polymer, wherein one or more of the segments are made of monomer units having a first functional group forming ionic and/or hydrogen bond, the segments constitute a co-continuous structure having mutually-independent and continuous regions due to a phase separation based on incompatibility between the segments, and the polymer has, at other than polymer chain terminals, a second functional group forming such bond with the first functional group, thereby allowing the segments to associate with the polymer at many points; forming a co-continuous structure including a region composed of the polymer and the segments due to the phase separation; and removing the polymer from the region by weakening the bond between the functional groups.Type: GrantFiled: May 8, 2012Date of Patent: January 22, 2013Assignee: Nitto Denko CorporationInventors: Takahisa Konishi, Takuji Shintani, Yushu Matsushita, Atsushi Takano, Takeshi Asari
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Publication number: 20120329939Abstract: A poly(arylene ether)-poly(hydroxy ether) block copolymer includes at least one poly(hydroxy ether) block and at least one poly(arylene ether) block, and the mole ratio of poly(hydroxy ether) blocks to poly(arylene ether) blocks is 0.95:1 to about 1.00:1. The poly(arylene ether)-poly(hydroxy ether) block copolymer can be prepared by reacting a telechelic poly(arylene ether) having terminal hydroxyl groups with a telechelic poly(hydroxy ether) epoxy resin having terminal epoxy groups, wherein the mole ratio of the telechelic poly(hydroxy ether) to the telechelic poly(arylene ether) is 0.95:1 to 1.00:1. The poly(arylene ether)-poly(hydroxy ether) block copolymer can be shaped into an article by extrusion, thermoforming, or molding, and is a compatibilizing agent for non-polar and polar polymers.Type: ApplicationFiled: June 27, 2011Publication date: December 27, 2012Inventor: Edward Norman Peters
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Patent number: 8338535Abstract: The present invention relates to an epoxy resin composition comprising the following [A], [A?], [B], and [C]: [A] a bisphenol-type epoxy resin having a glass transition temperature or melting point of 50° C. or higher; [A?] an epoxy resin which is in a liquid state at 25° C.; [B] an epoxy resin curing agent; and [C] at least one block copolymer selected from the group consisting of S-B-M, B-M, and M-B-M, wherein the blocks are linked to each other by a covalent bond or by an intermediate molecule bound to one of the blocks via one covalent bond formation and to the other block via another covalent bond formation; the block M is a methyl methacrylate homopolymer or a copolymer comprising at least 50% by weight of methyl methacrylate; the block B is incompatible with the block M and has a glass transition temperature of 20° C.Type: GrantFiled: June 25, 2007Date of Patent: December 25, 2012Assignee: Toray Industries, Inc.Inventors: Hiroaki Sakata, Nobuyuki Tomioka, Shiro Honda
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Patent number: 8338534Abstract: A process for producing a microporous polymeric object to improve the degree of freedom for its various properties, compared to conventional processes, includes: mixing a block copolymer made of three or more kinds of segments with a polymer, wherein one or more of the segments are made of monomer units having a first functional group forming ionic and/or hydrogen bond, the segments constitute a co-continuous structure having mutually-independent and continuous regions due to a phase separation based on incompatibility between the segments, and the polymer has, at other than polymer chain terminals, a second functional group forming such bond with the first functional group, thereby allowing the segments to associate with the polymer at many points; forming a co-continuous structure including a region composed of the polymer and the segments due to the phase separation; and removing the polymer from the region by weakening the bond between the functional groups.Type: GrantFiled: January 7, 2008Date of Patent: December 25, 2012Assignee: Nitto Denko CorporationInventors: Takahisa Konishi, Takuji Shintani, Yushu Matsushita, Atsushi Takano, Takeshi Asari
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Patent number: 8328979Abstract: The invention relates to a composition for an acrylic structural adhesive containing a mixture of block copolymers, of elastomer and of elastomeric polymer particles.Type: GrantFiled: April 4, 2008Date of Patent: December 11, 2012Assignee: JacretInventors: Arnaud Curet, Régis David
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Publication number: 20120309901Abstract: A liquid crystal block copolymer comprising at least one liquid crystal polymer block comprising a polymer of diethylene glycol bis(4-hydroxybenzoate) and diphenyl 2,6-naphthalene dicarboxylate and at least one non-liquid crystal polymer block.Type: ApplicationFiled: April 19, 2012Publication date: December 6, 2012Applicant: BOSTON SCIENTIFIC SCIMED, INC.Inventors: John J. Chen, Daniel J. Horn, Zhikuan Lu, Dong Zhang, Jiaokai Jing, Frank W. Harris
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Patent number: 8299177Abstract: The present invention provides for a composition that includes a hydrogenated styrenic block copolymer that has at least one block A and at least one block B, and about 10 to about 90 percent by weight of an styrene-isobutylene-styrene block copolymer. Each A is an monoalkenyl arene and each B block is a controlled distribution copolymer of at least one mono alkenyl arene and at least one conjugated diene, having the general formula A-EB/A-A and (A-EB/A)nX. Each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and one or more regions not adjacent to the A blocks that are rich in mono alkenyl arene units. Oil-free compositions that result in the combination of low gaseous permeability, low thermal conductivity, strong vibration and sound attenuation, and optionally high levels of light transmission with relatively low haze values while maintaining melt flow rates suitable for easy processability are preferred.Type: GrantFiled: January 19, 2011Date of Patent: October 30, 2012Assignee: Kranton Polymers U.S. LLCInventors: Kathryn J. Wright, Sharman K. McGilbert
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Patent number: 8288473Abstract: A disk-like nanoparticle includes a core layer that comprises a cross-linked multi-vinyl substituted aromatic hydrocarbon and a shell layer that comprises tri-block copolymer chains, each having a first, a second, and a third block. The first and third blocks of the tri-block copolymer chains comprise vinyl aromatic monomer units and are crosslinked with the core. The second block comprises conjugated diene monomer units and comprises a top and bottom axial surface of the disk-like nanoparticle. In the case of a nanoparticle having A-B-C tri-block copolymer chains, the third block comprises a top and bottom axial surface of the disk-like nanoparticle.Type: GrantFiled: October 17, 2008Date of Patent: October 16, 2012Assignee: Bridgestone CorporationInventors: Xiaorong Wang, Victor J. Foltz, Yuan-Yong Yan, Pat Sadhukhan
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Publication number: 20120245290Abstract: This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)?C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.Type: ApplicationFiled: March 25, 2011Publication date: September 27, 2012Inventors: John R. Hagadorn, Charles J. Ruff, Renuka N. Ganesh, Patrick Brant
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Patent number: 8273821Abstract: The present invention relates to an adhesive composition comprising a mixture of multi-block copolymers, in particular, an adhesive composition comprising a block copolymer represented by Formula 1, a hydrocarbon adhesive resin and a plasticizer. The adhesive composition according to the present invention can be easily processed due to its low melting point and shows improved adhesive properties such as loop tack, 180° peel strength and holding power.Type: GrantFiled: November 27, 2009Date of Patent: September 25, 2012Assignee: Korea Kumho Petrochemical Co., Ltd.Inventors: Jae Yun Kim, Ok Kil Mun, Eun Kyung Noh
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Patent number: 8268928Abstract: [Object] Provided are a sheet-like molded article having excellent surface smoothness, moldability, flexibility, and a high transmittance of short-wavelength light, and a thermoplastic polymer composition used to produce the sheet-like molded article.Type: GrantFiled: November 5, 2009Date of Patent: September 18, 2012Assignee: Kuraray CC., Ltd.Inventors: Hiroshi Oshima, Toyoaki Kurihara
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Patent number: 8263696Abstract: A HMPSA is provided that preferably includes at least a) from 30 to 50% of a mixture of triblock and diblock styrenic copolymers having an overall styrene content comprised between 14 and 40%, b) from 40 to 55% of a tackifying resin with a softening temperature comprised between 70 and 150° C. obtainable by hydrogenating, polymerizing or copolymerizing mixtures of aliphatic unsaturated hydrocarbons having about 5, 9 or 10 carbon atoms; c) from 4 to 20% of a hydrocarbon oil with an aromatic content less than 15%; d) from 1 to 6% of a filler selected among calcium carbonate or a low molecular weight homopolymer or copolymer of polyethylene. A laminated system is also provided that includes at least an adhesive layer utilizing the HMPSA and paper facestock. Also included are PSA labels obtainable from the laminated system with a reduced tendency to discolor after storage.Type: GrantFiled: December 29, 2008Date of Patent: September 11, 2012Assignee: Bostik, S.A.Inventors: David Goubard, Robert John Haeger
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Patent number: 8258236Abstract: The present invention relates to tubular forming material made of a composition comprising block copolymers each made of a vinyl aromatic hydrocarbon and a conjugated diene, which has a uniaxial elongation viscosity at 88° C. at a strain rate of 0.5 sec?1 satisfying the following formula between 1.0 sec and 2.8 sec after initiation of elongation, 0.25<(LOG ?2.8?LOG ?1.0)/(2.8?1.0)<0.4 wherein ?1.0 and ?2.8 represent uniaxial elongation viscosities (Pa·sec) at elongation times of 1.0 sec and 2.8 sec, respectively, when measured by a Meissner model elongation viscometer. The composition contains three block copolymers at a specified blend ratio.Type: GrantFiled: December 21, 2007Date of Patent: September 4, 2012Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Tadashi Sawasato, Eiji Sato, Hideki Toya, Hitoshi Nakazawa