Abstract: The present invention provides an aqueous dispersion comprising a polyamide-based rubber-like elastomer emulsified and dispersed therein, wherein 0.8 to 10 parts by weight of a copolymer of ethylene with an ethylenically unsaturated carboxylic acid, relative to 100 parts by weight of the polyamide-based rubber-like elastomer is contained. The aqueous dispersion of the present invention is a novel aqueous dispersion of polyamide-based rubber-like elastomer that is excellent in storage stability at low temperatures, and that can provide processed products excellent in flexibility and heat resistance when used as a coating material.

Abstract: The present invention relates to odor-inhibiting compositions comprising water-absorbing polymer particles and metal peroxides, and to the production thereof.

Abstract: A particulate water absorbing agent of the present invention is a water absorbing agent containing a water absorbing resin as a main component, the particulate water absorbing agent containing a polyvalent metal cation and satisfying: (1) the polyvalent metal cation is contained in an amount between 0.001 wt % and 5 wt % relative to the amount of the water absorbing agent; (2) an absorbency without pressure (CRC) is not less than 28 (g/g) and an absorbency against pressure (AAP 4.83 kPa) is not less than 10 (g/g); (3) the absorbency against pressure and the absorbency without pressure satisfy 77?AAP (4.83 kPa)+1.8×CRC?100; and (4) a moisture content of the water absorbing agent is between 5 wt % and 20 wt %. This provides a water absorbing agent which has blocking resistance after moisture absorption, is excellent in stability to shock and suppresses Re-Wet when used in a diaper.

Abstract: A technique for forming fibers (e.g., nanofibers, microfibers, etc.) from an aqueous spinning solution is provided. Through careful control over the nature and relative concentration of the components in the solution, fibers can be formed that remain relatively water resistant. To help accomplish these unique features, a pH-sensitive polymer is employed in the spinning solution that is generally soluble in water at a certain pH value, yet generally insoluble in water at a different pH value. This property allows for selective adjustment of the pH both before and after spinning to control the water-solubility of the polymer as desired.

Abstract: There are provided a sealing composition for a hard disk drive (HDD) motor and a HDD motor fabricated using the same. The sealing composition includes: 45 to 65 parts by weight of urethane methacrylate; 35 to 50 parts by weight of methacrylate; and 2 to 4 parts by weight of acrylic acid. A sealing composition having a new composition is used as a sealing material of a flexible printed circuit (FPC) adhering part of the HDD motor, whereby a haze phenomenon due to air leak and outgas at the FPC adhering part may be improved and reliability of a HDD motor may be enhanced due to a reduction in generation of the outgas of the adhering part.

Abstract: The invention provides a novel method for producing a water-absorbent resin comprising: subjecting at least one water-soluble ethylenic unsaturated monomer to reversed-phase suspension polymerization in a petroleum hydrocarbon dispersion medium, the reversed-phase suspension polymerization being conducted using a 0.00005 to 0.00016 mole of water-soluble azo initiator for radical polymerization per mole of the water-soluble ethylenic unsaturated monomer in the presence of 0.000015 to 0.00015 mole of hypophosphorous compound per mole of the water-soluble ethylenic unsaturated monomer. According to the method, the environmental impact can be lessened by reducing the amount of petroleum hydrocarbon dispersion medium released to the outside of the system, and the method makes it possible to obtain a water-absorbent resin having a high water-retention capacity and water-absorption capacity under a load, and a small content of water soluble component at the same time.

Abstract: This disclosure provides a business method and system for generating sugars and recycling a non-biomass component from a waste stream. In some embodiments, a waste stream comprising cellulose and a non-biomass component is saccharified to produce glucose, followed by recovery of the glucose and non-biomass component, which may be recycled to another site associated with production of a cellulose-containing product that contains the non-biomass component. In certain scenarios, the waste stream is generated at a first location, cellulose pretreatment (if desired) and hydrolysis are conducted at a second location, and the non-biomass component is recycled to the first location or a third location. The non-biomass component may include metals, metal oxides, salts, organic compounds, inorganic compounds, oligomers, or polymers, for example.

Abstract: Disclosed herein is a preparation method of homopolymer nanoparticles without using a surfactant. The homopolymer nanoparticles prepared thereby are expected to be widely used not only as a template of a semiconductor metal oxide, a drug delivery system (DDS), an electron transport layer (ETL), and a seed having vertical structural shape, but also in a high precision field such as replacement of an organic device polystyrene bead film.

Abstract: The purpose of the present invention is to provide a method for producing a water absorbent resin having improved physical properties, particularly, improved saline flow conductivity (SFC) and less amount of fine powder.

Abstract: This invention relates to a method for preparing a star-shaped polycarboxylate superplasticizer by the first esterification step with polyol and (meth)acrylic acid as main reactants and the second polymerization step. In the first step, the star-shaped polymerizable active ends were synthesized by esterification between polyol and (meth)acrylic acid in the presence of catalyst. In the second step, the final star-shaped polycarboxylate superplasticizer was prepared by radical polymerization among the product obtained in first step, unsaturated polyoxyethylene ethers, molecular weight regulator and unsaturated carboxylic acid in the presence of initiator. The production process of this invention exhibits some characteristics including simple, easily controllable, high polymerization degree, low cost and pollution free. The star-shaped molecular structure of polycarboxylate superplasticizer can be achieved through synthesizing active “core” by esterification and “arm” by radical polymerization.

Abstract: A quaternized copolymer obtainable by: (A) copolymerization of straight-chain, branched or cyclic, ethylenically unsaturated C2 to C100 hydrocarbons, which may bear oxygen- or nitrogen-functional substituents which cannot be reacted with amines to give amides or imides or with alcohols to give esters, with ethylenically unsaturated C3- to C12-mono- or dicarboxylic acids or acid derivatives, which can be reacted with amines to give amides or imides or with alcohols to give esters, to give a copolymer with a number-average molecular weight of 500 to 20 000; (B) partial or full amidation or imidation or esterification of the carboxylic acid functions by reacting them with oligoamines having 2 to 6 nitrogen atoms or alcoholamines, each of which comprises primary or secondary nitrogen atom or a hydroxyl group and a quaternizable tertiary nitrogen atom; (C) partial or full quaternization of the tertiary nitrogen atom with a quaternizing agent.

Abstract: The present invention provides a thermoplastic acrylic resin of a copolymer comprising 10 to 70% by weight of a repeating unit derived from the particular methacrylate monomer, 5 to 40% by weight of a repeating unit derived from the particular vinyl aromatic monomer, and 20 to 50% by weight of a repeating unit of the particular cyclic acid anhydride, characterized in that a molar ratio (B/A) is within the range of more than 1 to not more than 10, wherein (A) is a content of the repeating unit of the vinyl aromatic monomer and (B) is a content of the repeating unit of the cyclic acid anhydride, and the total amount of remaining monomers to 100 parts by weight of the copolymer is not more than 0.5 part by weight.

Abstract: In one aspect, a process for the preparation of a superabsorbent polymer is described herein. In some embodiments, the process comprises (I) preparing acrylic acid, wherein the process comprises (a1) provision of a fluid F1 having a composition comprising from about 5 to about 20 wt. % of hydroxypropionic acid, salts thereof, or mixtures thereof; from about 0.1 to about 5 wt. % of inorganic salts; from about 0.1 to about 30 wt. % of organic compounds which differ from hydroxypropionic acid; from 0 to about 50 wt. % of solids; and from about 20 to about 90 wt. % of water; (a2) dehydration of said hydroxypropionic acid to give a fluid F2 containing acrylic acid; and (a3) purification of said fluid F2 to give a purified acrylic acid phase comprising acrylic acid having a purity of at least 70 wt. %; and (II) polymerizing the acrylic acid of (I) to form a superabsorbent polymer.

Abstract: A class of molecularly imprinted polymers that specifically recognizes and binds to TSNAs are useful, for example, in analysis and separation of TSNAs from biological fluids. Such polymers are also useful in methods of treating and manufacturing tobacco products and materials.

Abstract: A method for producing a water-absorbent resin by performing a reversed-phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a petroleum hydrocarbon dispersion medium, comprising the following steps of: (A) performing a primary dispersion in the absence of surfactants by adding an aqueous solution of a water-soluble ethylenically unsaturated monomer containing a hydrophilic polymeric dispersion agent to a petroleum hydrocarbon dispersion medium in which a hydrophobic polymeric dispersion agent was heat-dispersed or heat-dissolved, under stirring; (B) further performing a secondary dispersion by adding a surfactant to a dispersion liquid obtained after the primary dispersion; and (C) performing the reversed-phase suspension polymerization by using a radical polymerization initiator; and the water-absorbent resin obtained by the method.

Abstract: This invention provides methods for controlled single electron transfer living radical polymerization (SET-LRP) of monomers with increased conversion, high molecular weights and low polydispersity by allowing the polymerization to proceed at low temperatures via a tubular reactor either made of copper or containing copper metal surface.

Abstract: The invention relates to absorptive, crosslinked polymers which are based on partly neutralized, monoethylenically unsaturated monomers carrying acid groups wherein the absorptive crosslinked polymer may be coated with a thermoplastic polymer, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which has a high gel bed permeability and high centrifuge retention capacity.

Abstract: The present invention is to provide a drying method by which both cost reduction and superior physical properties can be attained in a step which comprises subjecting a water-containing gel-like crosslinked polymer obtained by polymerizing an aqueous monomer solution to fine granulation during or after the polymerization, and drying the resultant particulate water-containing gel-like crosslinked polymer with a through-circulation band dryer. The method has a feature in that the drying conditions over a period from a time of introducing the particulate water-containing gel-like crosslinked polymer into a drying zone of the through-circulation band dryer to a time of reaching a solid content concentration thereof to 80% by weight, satisfy that (1) a difference of temperature between a temperature of hot air blown to a particulate hydrogel layer and a temperature measured after the hot air passes through the particulate hydrogel layer is 20 to 70° C.

Abstract: A method for the preparation of a fluoropolymer by means of emulsion polymerization of a reaction mixture in an aqueous medium is disclosed wherein the reaction mixture includes a fluoromonomer having the structure of wherein R1, R2, and R3 are each independently hydrogen atoms, alkyl groups, substituted alkyl groups, or halogens, wherein at least one of R1, R2, and R3 is a fluorine atom, and wherein R is each independently a substituent on the styrenic ring, n is an integer from 0 to 5 representing the number of the substituents on the styrenic ring; b) an emulsion stabilizer combination comprising: i) an anionic surfactant; and, ii) a cationic surfactant or a non-ionic surfactant; and, c) a free-radical initiator.

Abstract: Ethylene-based interpolymers, e.g., ethylene-acrylic acid copolymers, are made by a process comprising the steps of: A. Injecting a first feed comprising a chain transfer agent system (CTA system) and ethylene into a first autoclave reactor zone to produce a first zone reaction product, the CTA system of the first reactor zone having a transfer activity Z1; and B. (1) Transferring at least part of the first zone reaction product to a second reactor zone selected from a second autoclave reactor zone or a tubular reactor zone, and (2) at least one of transferring or freshly injecting a feed comprising a CTA system into the second reactor zone to produce a second zone reaction product, the CTA system of the second reactor zone having a transfer activity of Z2; and with the proviso that the ratio of Z1:Z2 is greater than 1. The comonomer comprises at least one carboxylic acid group or an anhydride group.

Abstract: A process for producing a water-absorbing polymer comprises: (i) mixing (?1) 0.1-99.99% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof, or ethylenically unsaturated monomers including a protonated or quaternized nitrogen, or mixtures thereof, (?2) 0-70% by weight of ethylenically unsaturated monomers copolymerizable with (?1), (?3) 0.001-10% by weight of one or more crosslinkers, (?4) 0-30% by weight of water-soluble polymers, and (?5) 0-20% by weight of one or more assistants, where the sum of the weights (?1) to (?5) is 100%; (ii) free-radical polymerization with crosslinking to form an untreated hydrogel polymer; (iii) coarse comminution of the untreated hydrogel polymer to give pieces having a diameter from 0.1 mm to 5.0 cm; (iv) cooling and grinding the untreated hydrogel polymer; (v) drying the untreated hydrogel polymer after grinding at a temperature from 85° C. to 260° C.; (vi) postcrosslinking the hydrogel polymer and (vii) drying the water-absorbing polymer.

Abstract: A process for producing a water absorbent resin is provided with which it is possible to efficiently and inexpensively obtain a surface-crosslinked water-absorbing resin having excellent material properties, while ensuring high productivity. In continuous production scaled up to a large scale (in particular, 1 t/hr or more), the physical properties are improved and stabilized (for example, a reduction in standard deviation of the physical properties) by a surface crosslinking treatment to further improve absorption against pressure (AAP) and saline flow conductivity (SFC).

Abstract: A method for producing a water-absorbent resin having a further reduced odor as compared with a water-absorbent resin obtained by a conventional method as well as a water-absorbent resin produced by the same method, by maintaining the addition rate V from the pouring nozzle for the aqueous solution of the water-soluble ethylenically unsaturated monomer in a polymerization reaction tank not more than 0.30 [min?1], in the first stage polymerization step which is within the step of the conventional method upon performing multi-stages such as two or more stages of reversed-phase suspension polymerizations in a method for producing a water-absorbent resin, and thereby by being able to reduce the amount of the petroleum hydrocarbon dispersion medium remaining in the above water-absorbent resin.

Abstract: A process for producing acrolein, comprising: a glycerin dehydration step of conducting dehydration reaction of glycerin to obtain an acrolein-containing gas; a partial-condensation step of cooling the acrolein-containing gas to condense a part of acrolein, water and a high-boiling substance contained in the acrolein-containing gas, thereby obtaining a purified gas and a condensate; and a separation step of separating the purified gas from the condensate; wherein a polymerization inhibitor is added to the acrolein-containing gas or the condensate in the partial-condensation step.

Abstract: The invention relates to a bituminous composition containing at least one bitumen and at least one polyolefin capable of forming a supramolecular assembly comprising one or more associative group(s). The invention also relates to the use of such bituminous composition for the preparation of asphalt mixtures useful for the coating of rolling surfaces, for the preparation of water-proofing coatings, and for the preparation of adhesive formulations.

Abstract: The present invention provides a chromatography medium comprising one or more electrospun polymer nanofibres which form a stationary phase comprising a plurality of pores through which a mobile phase can permeate and use of the same in chromatography, such as the isolation of recombinant proteins, monoclonal antibodies, viral vaccines and plasmid DNA. The invention further provides for the use of the chromatographic medium in a simulated moving bed system.

Abstract: The invention relates to a process for preparing pressure-sensitive adhesives (PSAs) which have high molar masses in combination with a narrow molar mass distribution, and also to PSAs, especially polyacrylate-based PSAs, prepared accordingly. It has been found that, surprisingly, polymers with high molar masses and a narrow molar mass distribution, more particularly polyacrylates with high molar masses and a narrow molar mass distribution, can be prepared outstandingly in particular by means of RAFT processes in the presence of a diradical initiator which undergoes thermal cyclization to form a diradical, these polymers being suitable for use as high-shear-strength PSAs.

Abstract: The object of the present invention is to provide a silicone-based copolymer which has excellent long-term antifouling property even in a dry-wet alternate portion of a ship and the like or a portion thereof near the surface of water, is excellent also in mechanical strength and recoatability and exhibits high antifouling performance even if an antifouling agent is not added, and an antifouling coating composition containing the copolymer.

Abstract: A binder resin for a nonaqueous secondary battery electrode of the invention satisfies Is?30 (Is indicates a sum of scattering intensities observed in a particle size range of from 1 to 100 nm) when a solution is formed by dissolving the binder resin in water at a concentration of 5% by mass and particle size distribution is measured by a dynamic light scattering method at 25° C. The binder resin contains a polymer (B) having a structural unit represented by the following Formula (11) and a specific structural unit. The binder resin also contains a polymer (?) having a specific structural unit and a structural unit represented by the following Formula (22), and/or a mixture of a polymer (?1) having a specific structural unit and a polymer (?2) having a structural unit represented by the following Formula (22).

Abstract: Provided herein is a non-naturally occurring microbial organism having a methanol metabolic pathway that can enhance the availability of reducing equivalents in the presence of methanol. Such reducing equivalents can be used to increase the product yield of organic compounds produced by the microbial organism, such as 3-hydroxyisobutyrate or MAA. Also provided herein are methods for using such an organism to produce 3-hydroxyisobutyrate or MAA.

Abstract: The present invention provides a method for producing a water-absorbent resin by a reversed-phase suspension polymerization method, wherein an odor originating from a raw material component, in particular, a petroleum hydrocarbon dispersion medium, was reduced, and a water-absorbent resin obtained by the method. More specifically, the present invention provides a method for producing a water-absorbent resin comprising performing a reversed-phase suspension polymerization of a water-soluble ethylenically unsaturated monomer in a petroleum hydrocarbon dispersion medium by using a surfactant, wherein an aqueous solution of the water-soluble ethylenically unsaturated monomer is dispersed in the dispersion medium at a specific pouring rate to reduce an odor, and a water-absorbent resin obtained by the method, are provided.

Abstract: A cement dispersant that includes a copolymer resulting from a reaction of components (A) to (C), where: (A) is an ester compound obtained by adding 0 to 10 moles of C2-4 alkylene oxide to 1 mole of at least one compound of Formula (1) RO-(AO)n-H (where R is a C1-12 alkyl group, A is a C2-4 alkylene group, and n is an integer of 0 to 7) and subjecting the resulting adduct to a reaction with an ?,?-unsaturated carboxylic acid, in which the compound of Formula (1) contains not more than 5% by mass of the constituent compounds having n of 3 or less relative to the total mass of the compound of Formula (1); (B) is an ?,?-unsaturated carboxylic acid or a salt thereof; and (C) is another copolymerizable monomer, where appropriate, or a salt thereof.

Abstract: A composition including an actinic radiation or thermally curable polyorganosiloxane ionomer having one or more reactive groups, for example, vinyl, acrylate, epoxy groups.

Abstract: A process for continuously producing water-absorbing polymer particles, wherein the monomer stems from at least two different sources and the monomer from one source differs from the monomer from at least one other source in the content of at least one secondary component.

Abstract: The present invention relates to a production method for efficiently obtaining an acrylic acid-based polymer having a narrow molecular mass distribution and a low molecular mass, without using a large amount of chain transfer agent. A method for continuously producing an acrylic acid-based polymer obtained by continuously polymerizing a monomer having acrylic acid as an essential component, characterized in that a liquid feed pump applies a mechanical load of 0.5 to 2.5 kJ/L to the liquid discharged from the outlet of a reactor. An acrylic acid-based polymer having fewer high-molecular-mass components, excellent dispersion and other properties, and a low molecular mass is thereby obtained.

Abstract: A process for continuously producing water-absorbing polymer particles, wherein the acrylic acid used to produce the polymer particles has a low purity.

Abstract: A process for transporting a liquid monomer phase which has been withdrawn from a storage vessel and comprises methacrylic monomers to an extent of ?90% by weight, in a tank truck or in a tanker ship, in which the liquid monomer phase is subjected to a separating operation on the route from the storage vessel into the tank of a tank truck or of a tanker ship in order to separate polymer of the monomer present in dissolved form in the liquid monomer phase.

Abstract: A polymer having the formula (XIV) as a dispersing agent for powder-form substances, typically selected from the group consisting of clays, porcelain slip, silicate flour, chalk, carbon black, rock flour, pigments, talc, plastic powders and mineral binders, and methods for improving the flow properties of powder-form substances and mixtures including powder-form substances and polymers having the formula (XIV).

Abstract: Process for the preparation of aqueous formulations, wherein (A) at least one ethylenically unsaturated carboxylic acid, (B) at least one heterocyclic comonomer having at least one permanent cationic charge per molecule and (C-P1) at least one ethylenically unsaturated dicarboxylic acid or its anhydride are subjected to free radical copolymerization with one another in an aqueous medium and, shortly before the end or after the end of the copolymerization, further ethylenically unsaturated dicarboxylic acid (C-P2) or its anhydride is added.

Abstract: A copolymer composition is provided including a block copolymer having a poly(styrene) block and a poly(silyl acrylate) block; wherein the block copolymer exhibits a number average molecular weight, MN, of 1 to 1,000 kg/mol; and, wherein the block copolymer exhibits a polydispersity, PD, of 1 to 2. Also provided are substrates treated with the copolymer composition.

Abstract: The invention relates to a novel support material for the fused deposition modelling process for producing three-dimensional objects. The invention relates more particularly to a 3D printing process involving support materials which are easier to remove than in the prior art. The support materials according to the invention are styrene-maleic anhydride copolymers for example.

Abstract: A copolymer composition is provided including a block copolymer having a poly(acrylate) block and a poly(silyl acrylate) block; wherein the block copolymer exhibits a number average molecular weight, MN, of 1 to 1,000 kg/mol; and, wherein the block copolymer exhibits a polydispersity, PD, of 1 to 2. Also provided are substrates treated with the copolymer composition.

Abstract: A block copolymer formulation is provided including a block copolymer blend including a first poly(acrylate)-b-poly(silyl acrylate) block copolymer; and, a second poly(acrylate)-b-poly(silyl acrylate) block copolymer. Also provided are substrates treated with the block copolymer formulation.

Abstract: There is provided a pressure sensitive adhesive composition and a pressure sensitive adhesive. A pressure sensitive adhesive composition example of the present application can provide a pressure sensitive adhesive having, for example, a high shear resistance together with an excellent peeling property or tacking property with respect to an attachment target surface.

Abstract: The present invention relates to ionic silicone hydrogel polymers displaying improved thermal stability. More specifically, the present invention relates to a polymer formed from reactive components comprising at least one silicone component and at least one ionic component comprising at least one anionic group. The polymers of the present invention display good thermal stability and desirable protein uptake.

Abstract: A production method for a water-absorbent resin, comprising a polymerization step for obtaining hydrogel by subjecting a monomer aqueous solution to a polymerization reaction, and a drying step for drying the hydrogel, wherein drying in the drying step is performed using a continuous through-flow belt-type drying machine, the solid content of the hydrogel supplied to the drying step is 35% by weight or more, and thickness variation rate (1) represented by the following EXPRESSION 1 of the hydrogel loaded onto through-flow belt in the continuous through-flow belt, is 1.05 to 5: [MATH. 1] Thickness variation rate (1)=(Maximum thickness of hydrogel in a width direction of the through-flow belt)/(Average thickness of hydrogel in a width direction of the through-flow belt).

Abstract: The present invention provides a carboxyl group-containing polymer composition that exhibits excellent anti-soil redeposition ability in fabric washing. The carboxyl group-containing polymer composition contains a carboxyl group-containing polymer, which includes specific ratios of a structure unit (a) derived from an acrylic acid-based monomer (A) and a structure unit (b) derived from a sulfonic acid group-containing monomer (B) and has a specific weight average molecular weight, and a specific amount of an adduct of a hydrogen sulfite to the acrylic acid-based monomer (A).

Abstract: A lithography method for forming nanoparticles includes patterning sacrificial material on a multilayer substrate. In some cases, the pattern is transferred to or into a removable layer of the multilayer substrate, and functional material is disposed on the removable layer of the multilayer substrate and solidified. At least a portion of the functional material is then removed to expose protrusions of the removable layer, and pillars of the functional material are released from the removable layer to yield nanoparticles. In other cases, the multilayer substrate includes the functional material, and the pattern is transferred to or into a removable layer of the multilayer substrate. The sacrificial layer is removed, and pillars of the functional material are released from the removable layer to yield nanoparticles.

Abstract: A production method for a water-absorbent resin, comprising a polymerization step for obtaining hydrogel by subjecting a monomer aqueous solution to a polymerization reaction, and a drying step for drying the hydrogel, wherein drying in the drying step is performed using a continuous through-flow belt-type drying machine, the pore opening rate of the through-flow belt in the continuous through-flow belt-type drying machine is 20 to 50%, the solid content of the hydrogel supplied to the drying step is 35% by weight or more, and the area occupancy rate of the hydrogel is 85 to 100% relative to the through-flow belt.

Abstract: The invention relates to a neutralization process in which at least one ethylenically unsaturated carboxylic acid is preneutralized at least partly with a base, wherein the preneutralized solution is divided into at least two part-solutions and at least one part-solution is aftertreated so as to form part-solutions with different degree of neutralization and/or solids content, and also to an apparatus for carrying out the process.