Abstract: The present invention aims to provide a method for stably producing highly pure acrylic acid and/or an ester thereof for a long time, in which a blockage in an evaporator or reactor and lowering of the catalytic activity are suppressed. The present invention also aims to provide a method for producing a hydrophilic resin with excellent performance and high safety using acrylic acid and/or an ester thereof containing fewer impurities as a raw material.

Abstract: A process for producing copolymers of (meth)acrylates:(meth)acrylic acid amine complexes useful for hard surfaces having increased performance for stain resistance, oil and water repellency properties.

Abstract: Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid.

Abstract: Bio-based glacial acrylic acid, produced from hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof and having impurities of hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof, is polymerized to poly(acrylic acid) or superabsorbent polymer using the same processes as petroleum-derived glacial acrylic acid.

Abstract: The present invention relates to an aqueous polymer dispersion whose dispersed addition polymer P comprises, copolymerized in free-radically polymerized form, at least one polar monomer having a water solubility of greater than 50 g/liter (measured at 20° C.), and obtainable by free-radically initiated aqueous emulsion polymerization, the polar monomer being metered to the reaction mixture during the polymerization process at a variable, i.e., nonconstant rate, for example in the sense of a rate gradient. The present invention further relates to processes for preparing these aqueous polymer dispersions, to their use as binders and/or in coatings, and also to coatings comprising the polymer dispersion of the invention.

Abstract: Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is ?1 or ?2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.

Abstract: The present invention relates to a method for producing water-absorbing polymer particles by radiation-inducing polymerization on a continuously revolving belt, electromagnetic radiation having a wavelength of greater than 400 nm being shielded.

Abstract: A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution in a surrounding gas phase in a reaction chamber, wherein the monomer solution is metered into the reaction chamber via at least one bore, and the diameter is from 210 to 290 ?m per bore and the metering rate is from 0.9 to 5 kg/h per bore.

Abstract: In one aspect, a process for the preparation of a superabsorbent polymer is described herein. In some embodiments, the process comprises (I) preparing acrylic acid, wherein the process comprises (a1) provision of a fluid F1 having a composition comprising from about 5 to about 20 wt. % of hydroxypropionic acid, salts thereof, or mixtures thereof; from about 0.1 to about 5 wt. % of inorganic salts; from about 0.1 to about 30 wt. % of organic compounds which differ from hydroxypropionic acid; from 0 to about 50 wt. % of solids; and from about 20 to about 90 wt. % of water; (a2) dehydration of said hydroxypropionic acid to give a fluid F2 containing acrylic acid; and (a3) purification of said fluid F2 to give a purified acrylic acid phase comprising acrylic acid having a purity of at least 70 wt. %; and (II) polymerizing the acrylic acid of (I) to form a superabsorbent polymer.

Abstract: A process for the preparation of a copolymer in a semicontinuous mode of operation in a polymerization apparatus containing a polymerization reactor connected to a metering device, in each case acid monomer being initially introduced into the metering device and polyether macromonomer and water into the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, the metering of the acid monomer into the polymerization reactor being effected in such a way that first a polymerization pH is established in the aqueous medium and then, until the conversion of 70 mol % of the polyether macromonomer initially introduced into the polymerization reactor, acid monomer is passed into the polymerization reactor in an amount per unit time such that the pH in the aqueous medium deviates by not more than ±0.3 from the initially established polymerization pH.

Abstract: A process for producing water-absorbing polymer particles, wherein an aqueous polymer gel is dried in a forced-air belt drier on a circulating conveyor belt and the surface of the conveyor belt has a multitude of elevations or depressions which are suitable for restricting the mobility of the aqueous polymer gel in transverse direction.

Abstract: A process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus, comprising a polymerization reactor connected to a metering device, acid monomer being initially taken in the metering device and polyether macromonomer, acid monomer and water in the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, the metering of the acid monomer being effected with the proviso that at least 70 mol % of the acid monomer metered in altogether are metered in the course of 5 to 19 minutes at a metering rate that is constant or varies to a limited extent.

Abstract: A process for removing metallic impurities from a product mass flow comprising water-absorbing polymer particles, wherein the product mass flow has a temperature of 35 to 90° C.

Abstract: A process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus including a polymerization reactor connected to a metering device, acid monomer being initially taken in the metering device and polyether macromonomer and water in the polymerization reactor, acid monomer being metered from the metering device via an acid monomer metering line into the polymerization reactor, a portion of the copolymer-containing aqueous medium being passed continuously during the free radical polymerization from the polymerization reactor via a reaction mixture line which is connected via a mixing device to the acid monomer metering line, the discharged copolymer-containing aqueous medium being mixed with the acid monomer in the mixing device during the metering of the acid monomer and being recycled to the polymerization reactor after the mixing via the acid monomer metering line.

Abstract: The present invention provided a polymer and a method for preparing the polymer, wherein the polymer was a terpolymer having a molecular weight of more than 1000, and copolymerized by acrolein, acrylic acid, and low alkene-alkyl dibasic acid or low-alkene-alkyl polybasic acid.

Abstract: Provided are buffered adhesive compositions comprising a high molecular weight polymeric buffer and products such as wound dressings and ostomy skin barriers incorporating the compositions.

Abstract: The present invention provides a production process by which a water-absorbent resin of excellent quality can be obtained at a low cost by reasonable steps in aqueous solution polymerization. The process for producing a water-absorbent resin comprises the step of polymerizing an aqueous solution of water-absorbent resin-forming monomers including acrylic acid and/or its sodium salt as major components, wherein: (1) the aqueous solution has a monomer component concentration of not less than 45 weight %; (2) the polymerization is carried out while water is evaporated so that the ratio (concentration ratio) between a solid component concentration in a hydropolymer as formed by the polymerization and a solid component concentration in the aqueous monomer solution will not be less than 1.10; and (3) the solid component concentration in the hydropolymer as formed by the polymerization is not more than 80 weight %.

Abstract: Provided are low-viscosity aqueous compositions comprising compounds of Formula (III) and (IV). These compositions are prepared by jointly ethoxylating a mixture of the compounds of the Formula (I) and (II) to give an intermediate which represents a mixture of compounds of Formulas (I*) and (II*). The intermediate is then converted by sulfation or phosphation and subsequent neutralization, into an aqueous composition comprising the compounds of Formula (III) and (IV). The aqueous compositions are notable for having, at 20° C., a Brookfield viscosity of 3000 mPas or less (measured at 20° C. with spindle 2 and 20 rpm), and are suitable as emulsifiers for emulsion polymerization.

Abstract: A copolymer defines interconnected pores and comprises polymerized monomers. The monomers comprise a first monomer more hydrophilic than 2-hydroxyethyl methacrylate (HEMA), and a second monomer as hydrophilic as, or less hydrophilic than, HEMA. In a method of forming a polymer, a bicontinuous microemulsion comprising water, a surfactant, and a combination of monomers copolymerizable for forming a porous copolymer is provided. The combination of monomers comprises the first and second monomers. The monomers in the bicontinuous microemulsion are polymerized to form the porous copolymer. The first monomer may comprise N-vinylpyrrolidone (NVP) or methacrylic acid (MAA). The second monomer may comprise HEMA or methyl methacrylate (MMA).

Abstract: The present invention provides a method for producing a water-absorbing resin powder. The method includes a polymerization step, a drying step, a pulverization step, a classification step, and a surface cross-linking step. It further includes an additional step, performed before the surface cross-linking step, in which at least part of the classified polymer is supplied again to the same or a different pulverization step. The circulation pulverization ratio in the pulverization step is higher than 1.50.

Abstract: A production method of a water-absorbent resin includes the steps of: obtaining a hydrogel by supplying monomer liquid to a reaction device so that the monomer liquid is polymerized; and detaching the hydrogel from the reaction device, wherein the reaction device's surface in contact with the monomer liquid at a position where polymerization occurs is made of a fluororesin having a melt viscosity of less than 1×108 poise at 380° C. On this account, it is possible to obtain a water-absorbent resin having less amounts of an extractable content with high productivity and it is possible to carry out continuous production for an extended period of time.

Abstract: A positive type photosensitive resin composition for forming patterned resin film is provided. The patterned resin film has high transparency, low dielectric constant, high solvent resistance, high water resistance, high acid resistance, high alkali resistance, high heat resistance, and excellent adhesive properties with the substrate, which is obtained by developing with an alkali solution. The positive type photosensitive resin composition contains copolymer of compound of formula (I) and 1,2-quinonediazido compound, or further mixes with other alkali-soluble polymers, in formula (I), R1 is hydrogen or alkyl group having 1-5 carbon atoms in which any hydrogen may be replaced by fluorine; and R2, R3 and R4 are independently hydroxyl group, alkyl group having 1-5 carbon atoms, alkoxyl group having 1-5 carbon atoms or —O(Si(ClH2l+1)2O)mSi(CpH2p+1)3, 1 is an integer of 1-5, m is 0 or an integer of 1-10, n is an integer of 1-5, and p is an integer of 1-5.

Abstract: The invention provides a catalyst for producing acrylic acid at high yield for a long time, in a method for producing acrylic acid by catalytic gas phase oxidation of propane and/or acrolein in the presence of molecular oxygen or a molecular oxygen-containing gas. This catalyst comprises a complex oxide containing molybdenum, vanadium and X component (here the X component is at least one element selected from antimony, niobium and tin) as the essential components, and is characterized in that its main peak as measured by X-ray diffractiometry using K? ray of Cu, d=4.00±0.1 angstrom, and in that the particle size of the X component in the catalyst does not exceed 20 ?m.

Abstract: The present invention relates to a process for preparing a water absorbent resin, particularly to a process for preparing a water absorbent resin which can resolve the uneven size of the fine pulverized gel-type resin and long pulverizing time those are the problems of prior process for preparing the water absorbent resin, by carrying out the pulverizing process of the gel-type resin divided into the coarse pulverizing process which is carried out with the internal cross-linking polymerization, and the fine pulverizing process. According to the preparation process, it is possible to mass-produce the water absorbent resin showing excellent absorption under pressure and low extractable content.

Abstract: The invention relates to a liquid radiation curable resin capable of curing into a solid upon irradiation comprising: (A) from about 0 to about 12 wt % of a cycloaliphatic epoxide having a linking ester group; (B) from about 30 to about 65 wt % of one or more epoxy functional components other than A; (C) from about 10 to about 30 wt % of one or more oxetanes; (D) from, about 1 to about 10 wt % of one or more polyols; (E) from about 2 to about 20 wt % of one or more radically curable (meth)acrylate components; (F) from about 2 to about 12 wt % of one or more impact modifiers; (G) from about 0.1 to about 8 wt % of one or more free radical photoinitiators; and (H) from about 0.1 to about 8 wt % of one or more cationic photoinitiators; wherein the liquid radiation curable resin has a viscosity at 30° C. of from about 600 cps to about 1300 cps.

Abstract: A homogeneously surface cross-linked water absorbent resin and a method for the production thereof are provided. The water absorbent material is formed of a surface cross-linked water absorbent resin resulting from granular irregularly pulverized shaped surface cross-linking the product of partial neutralization or whole neutralization of a water absorbent resin having acrylic acid or a metal salt thereof as a main component, which water absorbent material shows a metal atom concentration on the surface of the water absorbent material in the range of 0-10% within 0 second of polishing and 2-35% at 10 seconds value of polishing as determined by subjecting the water absorbent material to Ar ion discharge polishing under a voltage of 500 ?. The surface cross-linked water absorbent resin to be used herein can be produced by surface cross-linking a water absorbent resin having a specific particle diameter with a surface cross-linking agent having a water concentration in a specific range.

Abstract: The present invention provides: resins which can be used for various applications such as radical curable resin compositions, colorant-dispersed compositions, and photosensitive resin compositions; resin compositions; and means for producing the resins. Specifically, the present invention provides an ?-allyloxymethylacrylic copolymer having in its main chain a structural unit represented by formula (1): wherein R is a hydrogen atom or a C1-C30 organic group.

Abstract: A process for producing water-absorbing polymer particles, wherein at least one aliphatic aldehyde or reaction product thereof with an aliphatic alcohol, an aliphatic amine, ammonia, a hypophosphite or a phosphite is added.

Abstract: A process for producing water-absorbing polymer particles with a low centrifuge retention capacity by polymerizing in a continuous kneading reactor under an inert gas volume flow of at most 10 m3/h per m3 of reactor volume.

Abstract: The present invention provides a method for producing a silicone hydrogel having a high water content. The method comprises the following steps: (a) polymerizing a monomer mixture to form the silicone hydrogel, wherein the monomer mixture comprises at least one silicon-containing monomer and at least one ionic monomer; and (b) placing the silicone hydrogel in an alkaline solution for at least 20 minutes, wherein the alkaline solution has a pH not less than 7.5 and the ionic monomer is present in an amount not less than 0.7 wt % based on the total dry weight of the silicone hydrogel.

Abstract: The present invention relates to polymer coated metal powders, such as metal powders used in the formation of solder alloys and pastes. The metal powders are coated with curable compositions of cyanoacrylates. The present invention relates to polymer coated metal powders, such as metal powders used in the formation of solder alloys and pastes. The metal powders are coated with curable compositions of cyanoacrylates, and once cured the coating on the metal powder is a cyanoacrylate polymer.

Abstract: Objects of the present invention are: to provide a water-absorbent resin which exhibits excellent balances between water absorption performances; and further to provide a process by which a water-absorbent resin having excellent absorption properties can be produced even if no hydrophilic organic solvent is used, or even if its amount is extremely reduced, when carrying out the surface-crosslinking treatment; and further to provide a water-absorbent resin optimum to absorbent articles such as diapers.

Abstract: As a characteristic that had not been known conventionally at all, “permeability potential under pressure (PPUP)” of a particulate water absorbing agent is regulated, and further, “range of particle size distribution” and “coloring” are concomitantly regulated. The present invention is directed to a particulate water absorbing agent having the following (a) to (c): (a) permeability potential under pressure (PPUP) being 50 to 100%; (b) yellowness index (YI) being 0 to 10, and rate of change of yellowness index (?YI) being 100 to 150% following a coloring acceleration test for 14 days at 70±1° C. and the relative humidity of 95±1%; and (c) particles of smaller than 150 ?m specified by standard sieve classification accounting for 0 to 5% by weight, weight average particle diameter (D50) being 200 to 550 ?m, and logarithmic standard deviation (??) of particle size distribution being 0.20 to 0.40.

Abstract: The invention relates to a method for producing anionic water-in-water polymer dispersions containing at least one finely dispersed, water-soluble and/or water-swellable polymer A and a continuous aqueous phase. This phase has a partial quantity of at least one polymeric dispersing agent B in which monomers dispersed in this aqueous phase are subjected to a radical polymerization, and after the polymerization is completed, the reaction mixture is subsequently diluted with the remaining amount of dispersing agent B. The invention also relates to the polymer dispersions obtained according to the method and to their use, particularly in the paper industry.

Abstract: The invention relates to the use of protective-colloid-stabilized vinyl ester/ethylene copolymers in the form of polymer powder as low-profile-additives (LPAs).

Abstract: The present invention relates to ionic silicone hydrogel polymers displaying improved thermal stability. More specifically, the present invention relates to a polymer formed from reactive components comprising at least one silicone component and at least one ionic component comprising at least one anionic group. The polymers of the present invention display good thermal stability and desirable protein uptake.

Abstract: The present invention relates to synthetic polymers having high molecular weights and low polydispersities and methods of synthesis. In one embodiment of the present invention, a polymer includes a polyacrylate polymer obtained from a polymerization reaction in which the polyacrylate polymer has a molecular weight of at least about 500,000 and a polydispersity index of about 1.25 or less.

Abstract: A polyvinyl alcohol polymer capable of, in producing hydrolyzable cellulose using a cellulosic biomass as a basic material, readily disrupting the cellulosic biomass at a molecular level by imparting a suitable flow resistance to a solution containing the cellulosic biomass, or the like, thereby resulting in efficient production of hydrolyzable cellulose to be enabled; and a method for producing hydrolyzable cellulose using the polyvinyl alcohol polymer. Provided is a polyvinyl alcohol polymer for use in producing hydrolyzable cellulose using a cellulosic biomass as a basic material, the polyvinyl alcohol polymer having: an average degree of polymerization of no less than 200 and no greater than 5,000; a degree of saponification of no less than 70 mol % and no greater than 99.9 mol %; and a molecular weight distribution of no less than 2.2.

Abstract: The invention relates to absorptive, crosslinked polymers which are based on partly neutralized, monoethylenically unsaturated monomers carrying acid groups, and have improved properties, in particular in respect of their capacity for transportation of liquids in the swollen state, and which has a high gel bed permeability and high centrifuge retention capacity.

Abstract: An aqueous slurry of finely divided fillers which are at least partly coated with anionic latices, wherein the slurry is obtainable by treating an aqueous slurry of finely divided fillers with an aqueous dispersion comprising at least one anionic latex and at least one degraded starch, preparation of the aqueous slurries and their use as an additive to the paper stock in the production of filler-containing paper, filler-containing cardboard or filler-containing board by draining the paper stock.

Abstract: Processes for producing high pressure polyethylene and processes for increasing the crosslinkability of high pressure polyethylene are disclosed. The processes comprise controlling particular reaction parameters that have been found to promote crosslinkability in the resulting high pressure polyethylene. High pressure polyethylenes having improved crosslinkability are also disclosed.

Abstract: The present invention relates to a process for producing water-absorbing polymer fibers, especially micro-or nanofibers, by electrospinning process and to fibers obtainable by this process.

Abstract: An additive composition for imparting caustic removability to a hot melt adhesive comprises a low molecular weight ?,? ethylenically unsaturated anhydride-containing or acid-containing polymer. The polymer is selected from the group consisting of a low molecular weight carboxylic anhydride homo-polymer or the at least partial ester thereof, a low molecular weight carboxylic anhydride copolymer or the at least partial ester thereof, a low molecular weight carboxylic anhydride polyolefin, a low molecular weight carboxylic anhydride vinyl aromatic copolymer, and a low molecular weight carboxylic anhydride grafted copolymer, or the combination or mixtures thereof. A caustic removable hot melt adhesive composition comprises a hot melt adhesive additive and a conventional hot melt adhesive resin. A caustic removable adhesive label comprises a substrate and a caustic removable hot melt adhesive composition which includes an additive composition.

Abstract: A process for producing water-absorbing polymer particles, wherein heated water-absorbing polymer particles are remoisturized and cooled in a high-speed mixer.

Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, which comprises thermal postcrosslinking in the presence of steam.

Abstract: The invention relates to producing a superabsorbent polymer comprising (I) producing a (meth)acrylic acid comprising the steps of (a) synthesizing a crude (meth)acrylic acid phase; (b) distillatively working-up the crude (meth)acrylic acid phase to obtain a (meth)acrylic acid phase and a dimer phase comprising (meth)acrylic acid dimers and/or (meth)acrylic acid oligomers; (c) splitting at least a part of the (meth)acrylic acid dimers or of the (meth)acrylic acid oligomers or both from the dimer phase to obtain a (meth)acrylic acid-comprising a low boiling phase and a high boiling phase comprising less (meth)acrylic acid than the low boiling phase; (d) separating at least a part of the (meth)acrylic acid from the low boiling phase by forming crystals to obtain a pure (meth)acrylic acid, and a residue; (II) polymerizing a monomer phase comprising the pure (meth)acrylic acid to obtain a polymer phase; and (III) working-up the polymer phase to obtain the polymer.

Abstract: The invention relates to crosslinked polymerizates which are capable of absorbing, which are based on partially neutralized, monoethylenically unsaturated monomers that carry acidic groups, which exhibit improved properties, in particular, with regard to their ability to transport liquids when in a swollen state, and which have been subsequently crosslinked on the surface thereof with a combination consisting of an organic crosslinker compound, with the exception of polyols, and of a cation provided in the form of a salt in an aqueous solution.

Abstract: A method for forming polymer carbon nanotube composites, the method comprising: contacting carbon nanotubes with ozone to functionalize the sidewalls of the carbon nanotubes with at least one oxygen moiety; and reacting the functionalized carbon nanotubes with at least one monomer or at least one polymer or copolymer to attach polymer chains to the sidewalls of the carbon nanotubes.

Abstract: A solar cell module comprising a solar cell layer and a sheet comprising at least one layer of a sodium ionomer composition, wherein the sodium ionomer composition consists essentially of a sodium ionomer that is an ionic, neutralized derivative of a precursor ?-olefin carboxylic acid copolymer, wherein about 10% to about 35% of the total content of the carboxylic acid groups present in the precursor ?-olefin carboxylic acid copolymer have been neutralized with sodium ions, and wherein the precursor ?-olefin carboxylic acid copolymer comprises (i) copolymerized units of an ?-olefin having 2 to 10 carbons and (ii) about 20 to about 25 wt %, based on the total weight of the ?-olefin carboxylic acid copolymer, of copolymerized units of an ?,?-ethylenically unsaturated carboxylic acid having 3 to 8.

Abstract: A method for producing a water-absorbent resin having a further reduced odor as compared with a water-absorbent resin obtained by a conventional method as well as a water-absorbent resin produced by the same method, by maintaining the addition rate V from the pouring nozzle for the aqueous solution of the water-soluble ethylenically unsaturated monomer in a polymerization reaction tank not more than 0.30 [min?1], in the first stage polymerization step which is within the step of the conventional method upon performing multi-stages such as two or more stages of reversed-phase suspension polymerizations in a method for producing a water-absorbent resin, and thereby by being able to reduce the amount of the petroleum hydrocarbon dispersion medium remaining in the above water-absorbent resin.