Abstract: An solvent-based pressure sensitive adhesive (PSA) having improved shear adhesion is composed of an acrylic-based PSA resin, an ethylenically unsaturated polyester, an ultraviolet radiation (UV) photosensitizer, and fugative organic solvent for the acrylic-based PSA resin. The PSA is cured by evaporation of the fugative organic solvent coupled with heat and UV irradiation or UV irradiation alone. Such PSA has improved shear adhesion by dint of the addition of the ethylenically-unsaturated polyester and an ultraviolet radiation (UV) photosensitizer. A method for adhering two substrates using the PSA includes applying the PSA to one or both of substrates. The solvent in the PSA is evaporated from the applied PSA. Finally, the polyester component of the applied PSA is cured by exposure of the applied PSA to ultraviolet (UV) radiation.
Type:
Grant
Filed:
August 7, 2000
Date of Patent:
January 29, 2002
Assignee:
Ashland Chemical, Inc.
Inventors:
Daniel Joseph Riley, Raymond Scott Harvey, Harvey Joseph Richards, Peter Albert Yurcick
Abstract: A composition comprising aqueous fluid absorbent polymer particles which have been heat-treated at temperatures greater than 170° C. for more than 10 minutes, wherein the composition has been remoisturized, after the heat-treatment, with an aqueous additive solution, in the absence of an organic solvent or water-insoluble, non-swellable powder, and comprises 1 to 10 percent by weight, based on the total weight of the composition, water and wherein the composition is characterized by the ability to absorb at least 20 grams of a 0.9 weight percent aqueous saline solution under a pressure of 0.3 psi (21,000 dynes/cm2), that is, a 60 minute 0.3 psi (21,000 dynes/cm2) AUL greater than 20 grams/gram. A process for preparing such a composition.
Type:
Grant
Filed:
January 10, 2000
Date of Patent:
November 27, 2001
Assignee:
The Dow Chemical Company
Inventors:
Herbert A. Gartner, Thomas L. Staples, Michael A. Fialkowski
Abstract: A polymeric amphipathic stabilizer is formed of hydrophobic monomer units and hydrophilic monomer units which comprise carboxylic free acid or acid salt units and glycidyl or anhydride units. The glycidyl or anhydride units react onto reactive groups on polymer particles when dispersed in non-aqueous liquid and provide improved stability when the particles are subsequently dispersed in liquid electrolyte.
Type:
Application
Filed:
July 31, 2001
Publication date:
November 22, 2001
Inventors:
Kenneth Charles Symes, Kishor Kumar Mistry, Mads Lykke, Ole Simonson
Abstract: Film-forming, functionalized polymers having 1,2-dicarboxylic acid monoester groups have at least two polymer units, one of which is acid-labile and hydrolysis-stable and the other is thermally stable. These polymers are used in particular in photoresists.
Abstract: The hydrogels are based on polymerized monomers or on graft polymers and each have a Pressure Absorbency Index <100 and a vertical absorption of not less than 12 g/g under a pressure of 1922.8 Pa.
Type:
Grant
Filed:
February 5, 1999
Date of Patent:
October 2, 2001
Assignee:
BASF Aktiengesellschaft
Inventors:
RĂ¼diger Funk, Norbert Herfert, Mariola Wanior, Patricia D. Brown, Fritz Engelhardt, Guy T. Woodrum
Abstract: The present invention is an acrylic polymer particle which is consistently and substantially spherical in shape and which has a mean diameter that can be predetermined from about 30 microns in diameter to about 5 microns or less. Polyacrylonitrile is synthesized in an aqueous dispersion polymerization with a ionic monomer or “surfmer” to attain a narrow particle size distribution with a mean diameter as low as approximately 3±1.5 microns which is characteristic of an emulsion polymerization. The polymer comprises the ionic monomer and, optionally, a neutral comonomer. The mean particle size is dependent on the concentration of the ionic monomer present, the particular ionic monomer or monomers selected, and the counterion associated with the ionic monomers, the persulfate initiator, and the bisulfite activator. The counterions, often sodium ions, can be removed from the polymer particles by ion exchange with quaternary ammonium compounds.
Abstract: An aqueous dispersion of a copolymer formed by the emulsion polymerization of a monomer mixture including from 0.1 to 20% by weight of one or more terminally unsaturated carboxylic acid oligomers; from 80 to 99.9% by weight of at least two monomers selected from esters and amides of (meth)acrylic acid, vinyl esters of carboxylic acids, vinyl aromatic compounds, ethylenically unsaturated nitrites, vinyl halides, and non-aromatic hydrocarbons; and 0 to 10% by weight of other copolymerisable monomers is provided. The aqueous copolymer dispersion is polymerized in the presence of anionic surfactant and at an acid pH. Also provided is a method of preparing the aqueous copolymer dispersion. Aqueous copolymer dispersions including the terminally unsaturated carboxylic acid oligomers have low viscosities over a broad pH range and are useful in coating compositions, as binders for nonwovens, textiles, paper coatings, and as adhesives.
Type:
Grant
Filed:
July 16, 1999
Date of Patent:
June 19, 2001
Assignee:
Rohm and Haas Company
Inventors:
Robert David Solomon, Gary David Greenblatt
Abstract: The invention relates to build-up agents which comprise a condensation product among an aldehyde, a phenol compound and an aromatic carboxylic acid, hydroxy-substituted on the aromatic nucleus. The products are particularly effective in reducing or suppressing the build-up formation in the polymerization of vinyl chloride or vinyl acetate, other copolymerizable substances being optionally present. Further objects of the invention are compositions containing the above agents, their use as build-up agents, methods for their preparation and the products obtained therefrom, the polymerization processes carried out in reactors whose inner walls are coated with these agents and polymers obtained from these process.
Type:
Grant
Filed:
June 3, 1999
Date of Patent:
May 15, 2001
Assignee:
3V Inc.
Inventors:
Giuseppe Raspanti, Matteo Zanotti Russo
Abstract: The present invention provides a novel class of polymer antiscalants which are polymers comprising a 1,2-dihydroxy-3-butene monomer unit and at least one monomer unit derived from the groups consisting of maleic acid, acrylic acid, acrylamide, methacrylic acid, itaconic acid, vinyl sulfonic acid, styrene sulfonic acid, N-tertbutylacrylamide, butoxymethylacrylamide, N,N-dimethylacrylamide, sodium acrylamidomethyl propane sulfonic acid, and salts thereof, with the proviso that said polymers do not contain the monomer unit —(CH2—CH═CH—CH2—O)—.
Type:
Grant
Filed:
November 9, 1999
Date of Patent:
May 15, 2001
Assignee:
Nalco Chemical Company
Inventors:
Prasad Yogendra Duggirala, John David Morris, Peter Edward Reed, Steven John Severtson
Abstract: Solvent-free, fine white powders of a copolymer of maleic anhydride and a C1-C4 alkyl vinyl ether substantially free of poly(alkyl vinyl ether) homopolymer.
Abstract: Copolymers based on unsaturated dicarboxylic acid derivatives, oxyalkylene glycol alkenyl ethers, unsaturated dicarboximides and/or -amides and vinyl monomers are described, as also their use as additives for hydraulic binders, especially cement. The copolymers also have an excellent plasticizing effect—even if they are added in large quantities—when used in concrete mixtures with an extremely low water content, and they do not retard the setting process.
Type:
Grant
Filed:
July 30, 1998
Date of Patent:
April 3, 2001
Assignee:
SWK Bauchemie GmbH
Inventors:
Gerhard Albrecht, Hubert Leitner, Josef Weichmann, Alfred Kern
Abstract: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated dicarboxylic acid monomer, and an ethylenically unsaturated monocarboxylic acid monomer. The total amount of said ethylenically unsaturated acid monomers is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.
Type:
Grant
Filed:
September 13, 1996
Date of Patent:
March 6, 2001
Assignee:
Henkel Corporation
Inventors:
Stephen A. Fischer, Michael S. Wiggins, Bruce Matta, Eric Nowicki
Abstract: In one embodiment, the present invention relates to metal oxide sols comprising a liquid and a polycondensation product of about 2 to about 5,000 monomers of a partially hydrolyzed chelated metal oxide precursor. In another embodiment, the present invention relates to a process for making a metal oxide sol comprising contacting a metal oxide precursor with a multifunctional compound in a liquid to provide a chelated metal oxide precursor; contacting the chelated metal oxide precursor with a hydrolyzing agent to provide partially hydrolyzed chelated metal oxide precursor monomers; and permitting the partially hydrolyzed chelated metal oxide precursor monomers to polycondense thereby forming a metal oxide sol.
Type:
Grant
Filed:
February 13, 1998
Date of Patent:
January 2, 2001
Assignee:
Reliance Electric Technologies, LLC
Inventors:
Hong-Son Ryang, Young Jin Chung, Joseph T. Snyder, II, An-Min Jason Sung