Stretched Product Patents (Class 526/348.1)
  • Patent number: 8202937
    Abstract: The present invention is to provide an optical film which exhibits low hygroscopicity, high transparency, high heat resistance and markedly lowered brittleness, and particularly to provide an optical film which is appropriately employed as a polarizing plate protective film for large liquid crystal display devices and outdoor liquid crystal display devices. The above optical film is characterized in that acrylic resin (A) and cellulose ester resin (B) are incorporated at a weight ratio of 95:5-30:70, weight average molecular weight Mw of aforesaid acrylic resin (A) is at least 80,000, total substitution degree (T) of the acyl group of aforesaid cellulose ester resin (B) is 2.0-3.0, the substitution degree of the acyl group having 3-7 carbon atoms is 1.2-3.0, and weight average molecular weight Mw of aforesaid cellulose ester resin (B) is at least 75,000. It is characterized that the total substitution degree of the acyl group other than carbon atoms of 3-7 of the cellulose ester resin (B) is at most 1.3.
    Type: Grant
    Filed: March 30, 2010
    Date of Patent: June 19, 2012
    Assignee: Konica Minolta Opto, Inc.
    Inventors: Takashi Takebe, Masataka Takimoto, Nobuo Kubo
  • Patent number: 8188207
    Abstract: Process for producing high strength polyethylene films or tapes comprising the steps of: providing a quantity of disentangled polyethylene, applying a pressure of at least 20 bar to the quantity of disentangled polyethylene and a temperature between the ?-relaxation temperature and the melting temperature of the disentangled polyethylene Tm PE resulting in a block of disentangled polyethylene, skiving a film or tape off the block of disentangled polyethylene and, drawing said film or tape in a single or multi stage drawing step at a total draw ratio of at least 1:20.
    Type: Grant
    Filed: April 21, 2009
    Date of Patent: May 29, 2012
    Assignee: Novameer B.V.
    Inventors: Jan Adolph Dam Backer, Bart Clemens Kranz, Benjamin Slager
  • Patent number: 8168112
    Abstract: Blown films and processes of forming the same are described herein. The processes generally include providing a bimodal ethylene based polymer, blending the bimodal ethylene based polymer with at least about 30 ppm peroxide to form modified polyethylene and forming the modified polyethylene into a blown film.
    Type: Grant
    Filed: December 20, 2008
    Date of Patent: May 1, 2012
    Assignee: Fina Technology, Inc.
    Inventors: Cyril Chevillard, Jay Nguyen
  • Patent number: 8101687
    Abstract: The present invention relates to a polyethylene resin having a multimodal molecular weight distribution, said resin being further characterized in that it has a density in the range of from about 0.925 g/ccm to about 0.950 g/ccm, a melt index (I2) In the range of from about 0.05 g/10 min to about 5 g/10 min, and in that it comprises at least one high molecular weight (HMW) ethylene interpolymer and at least a low molecular weight (LMW) ethylene polymer, and a composition comprising such resin. Also provided is a shaped article comprising said resin or composition, in particular a pipe.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: January 24, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Detlef Schramm, Wolfgang Quack, Julien Damen, Pak-Meng Cham
  • Publication number: 20110301309
    Abstract: [Object] To provide a propylene homopolymer suitable for capacitor films having high withstand voltage and a stretched film formed by stretching the propylene homopolymer. [Solution] A propylene homopolymer of the present invention for capacitors satisfies the following requirements (i) to (v) and (ix): (i) the MFR is 1 to 10 g/10 minutes; (ii) the meso pentad fraction (mmm) measured by 13C-NMR is 0.940 to 0.995; (iii) the integrted amount of elution at 90° C. by CFC using o-dichlorobenzene is 0.5% by weight or less; (iv) the melting point measured using DSC is 152° C. or more; (v) the chlorine content is 2 ppm by weight or less; and (ix) in an elution temperature-elution volume curve measured by cross-fractionation chromatography (CFC) using o-dichlorobenzene, the maximum peak has a peak top temperature in the range of 105° C. to 130° C. and half width of 7.0° C. or less.
    Type: Application
    Filed: January 26, 2010
    Publication date: December 8, 2011
    Inventors: Satoshi Tamura, Keita Itakura, Satoshi Hashizume
  • Patent number: 8067518
    Abstract: Ethylene alpha-olefin copolymers formed by contacting at least one supported metallocene catalyst, ethylene, and an alpha-olefin in a gas phase reactor are disclosed. In some embodiments, the polymer may have: a density of between 0.890 and 0.970 g/cc; a melt index of between 0.7 and 200 dg/min; a melt index ratio of less than 30; an ESCR value of greater than 1000 hours; and a 1% secant modulus of greater than 75,000 psi. In other embodiments, the polymer may have: a density of between 0.930 g/cc and 0.970 g/cc; a melt index of between 10 dg/min and 200 dg/min; a melt index ratio of between 10 and 25; a part weight of greater than 3 g and a part length of greater than 38 cm in a spiral flow test, and; a zero shear viscosity of less than 150 Pa·s. Processes to produce these polymers are also disclosed.
    Type: Grant
    Filed: June 7, 2007
    Date of Patent: November 29, 2011
    Assignee: Univation Technologies, LLC
    Inventors: Christopher R. Davey, James M. Farley, Rainer Kolb, Mark P. Ossowski
  • Patent number: 8058379
    Abstract: The present invention provides a 4-methyl-1-pentene polymer having excellent balance between heat resistance and rigidity, a process for producing the polymer, and a film and a LED mold formed from the polymer. The 4-methyl-1-pentene polymer comprises 50 to 100% by mass of a constituting unit derived from 4-methyl-1-pentene and 0 to 50% by mass of a constituting unit derived from at least one of olefins having 2 to 20 carbon atoms excluding 4-methyl-1-pentene, wherein the 4-methyl-1-pentene polymer is obtainable by continuously feeding a monomer forming the 4-methyl-1-pentene polymer and an organic solvent to a polymerization reactor and continuously extracting a polymerization reaction mixture containing the resulting 4-methyl-1-pentene polymer from the polymerization reactor.
    Type: Grant
    Filed: July 7, 2008
    Date of Patent: November 15, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kazuaki Yasuda, Tooru Tanaka
  • Patent number: 8021759
    Abstract: The present invention is directed to a heat-shrinkable, thermoplastic film or bag which contains at least one homogeneous ethylene alpha-olefin copolymer having a density of at least 0.90 g/cc. Oriented films made in accordance with the present invention exhibit improved optics and improved impact resistance. A homogeneous ethylene alpha-olefin may be present in a monolayer film either alone or in a blend or may be included in one or more layers of a multilayer film in accordance with the present invention.
    Type: Grant
    Filed: December 22, 1997
    Date of Patent: September 20, 2011
    Assignee: Cryovac Inc.
    Inventors: Kelly R. Ahlgren, Robert Babrowicz, Solomon Bekele, Blaine C. Childress, Marvin R. Havens, Vincent W. Herran, Ronald D. Moffitt, Gautam P. Shah, George D. Wofford
  • Patent number: 8022160
    Abstract: The invention relates to a process for making a monofilament-like product from a precursor containing at least one strand of fibers made from ultra-high molar mass polyethylene, comprising a) exposing the precursor to a temperature within the melting point range of the polyethylene for a time sufficient to at least partly fuse adjacent fibers and b) simultaneously stretching the precursor, wherein the precursor is mechanically compressed during fusing. The monofilament-like product thus made has a smoother surface appearance, and improved abrasion resistance, for example a reduced tendency to pilling during use as fishing line, than known similar products; making it very suitable for use as fishing line and the like. The invention further relates to a monofilament-like product obtainable by said process, and to semi-finished and end-use products comprising said monofilament-like product.
    Type: Grant
    Filed: October 14, 2005
    Date of Patent: September 20, 2011
    Assignee: DSM IP Assets B.V.
    Inventors: Christiaan H P. Dirks, Joseph A. P. M. Simmelink
  • Patent number: 8022171
    Abstract: The invention relates to a process for making a monofilament-like product from a precursor containing a multitude of continuous polyolefin filaments, comprising exposing the precursor to a temperature within the melting point range of the polyolefin for a time sufficient to at least partly fuse adjacent fibers and simultaneously stretching the precursor at a draw ratio of at least 2.8. With the process according to the invention a monofilament-like product can be made that shows improved tensile properties; making it very suitable for application as e.g. fishing line.
    Type: Grant
    Filed: October 14, 2005
    Date of Patent: September 20, 2011
    Assignee: DSM IP Assets B.V.
    Inventors: Francois Jean Valentine Goossens, Johannes Eliazbeth Adrianus Kriele, Joseph Arnold Paul Maria Simmelink, Christiaan Henri Peter Dirks
  • Patent number: 8008403
    Abstract: A polyethylene which comprises ethylene homopolymers and/or copolymers of ethylene with 1-alkenes and has a molar mass distribution width Mw/Mn of from 5 to 30, a density of from 0.92 to 0.955 g/cm3, a weight average molar mass Mw of from 50000 g/mol to 500 000 g/mol and has from 0.01 to 20 branches/1000 carbon atoms and a z-average molar mass Mz of less than 1 million g/mol, a process for its preparation, catalysts suitable for its preparation and also films in which this polyethylene is present.
    Type: Grant
    Filed: April 25, 2005
    Date of Patent: August 30, 2011
    Assignee: Basell Polyolefine GmbH
    Inventors: Jennifer Kipke, Shahram Mihan, Rainer Karer, Dieter Lilge
  • Patent number: 7951873
    Abstract: This invention relates to blends of linear low density polyethylene copolymers with other linear low density polyethylenes or very low density, low density, medium density, high density, and differentiated polyethylenes. The invention also includes articles produced from the linear low density polyethylene and polyethylene blends described.
    Type: Grant
    Filed: April 18, 2007
    Date of Patent: May 31, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Steven Arthur Best, Paul Masten German, Jerry Michael Johnson, Alan M. Malakoff, Stefan Bertil Ohlsson
  • Patent number: 7935884
    Abstract: An encapsulant layer for a photovoltaic module enabling recovering and recycling or reusing of reutilizeable resources such as a transparent front face substrate and photovoltaic cell and the like among constituents of a photovoltaic module, and a method for manufacturing a regenerated photovoltaic cell and a regenerated transparent front face substrate. The photovoltaic module is formed by laminating: a transparent front face substrate; a photovoltaic cell carrying a wiring electrode and a takeoff electrode, and an encapsulant layer is placed on at least one surface; and a rear face protecting sheet. The encapsulant layer is a separable layer formed mainly of a thermoplastic resin, and an output maintenance factor of photoelectronic power of the photovoltaic module using the encapsulant layer is in a range of 80% to 100%.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: May 3, 2011
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Kasumi Oi, Takaki Miyachi, Isao Inoue, Koujiro Ohkawa, Hiroki Nakagawa
  • Patent number: 7935755
    Abstract: A method for forming a heat sealable coating on a substrate, wherein the substrate is formed from at least one oriented polymer is shown. The method includes depositing an aqueous polymer dispersion on the substrate, wherein the aqueous polymer dispersion includes (A) at least one thermoplastic resin; (B) at least one dispersing agent; and (C) water; wherein the dispersion has a pH of less than 12, and drying the dispersion to form a first layer.
    Type: Grant
    Filed: June 15, 2010
    Date of Patent: May 3, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Brad M. Moncla, Sarah T. Eckersley, Ralph G. Czerepinksi, Charles F. Diehl, Matthew J. Kalinowski, Dale C. Schmidt
  • Patent number: 7932341
    Abstract: An object of the present invention is to provide a polypropylene polymer film superior in convenience in handling that does not generate troubles such as wrinkling, elongation or breakage during processing at a high temperature of 80° C. to 120° C., independently of the conveying method used in the drying step, and an adhesive film having the polypropylene polymer film as its carrier. Provided are a polypropylene polymer film, characterized by having a tensile modulus of 300 MPa to 1,000 MPa under an atmosphere at 23° C. and 60 MPa to 120 MPa under an atmosphere at 120° C. and an adhesive film containing it as the carrier.
    Type: Grant
    Filed: November 24, 2005
    Date of Patent: April 26, 2011
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Michihiro Shimane, Osamu Yamamoto, Yasushi Ooyama
  • Patent number: 7923121
    Abstract: A photo-crosslinkable polyolefin composition comprises a polyolefin, a source of functionality receptive to crosslinking by UV radiation, a cationic photoinitiator and optionally includes a free-radical photoinitiator, a crosslinking accelerator or sensitizer, and other additives such as compatibilizers, inorganic fillers, nanofillers, glass, polymeric and ceramic microspheres, glass fibers, flame retardants, antioxidants, stabilizers, processing aids, foaming agents and pigments. A method for manufacturing a UV-crosslinked polyolefin article comprises forming an article by extruding, molding or otherwise forming the UV-crosslinkable polyolefin composition and subjecting the article to UV radiation on-line with the extrusion, molding or other forming operation.
    Type: Grant
    Filed: May 14, 2010
    Date of Patent: April 12, 2011
    Assignee: ShawCor Ltd.
    Inventors: Peter Jackson, Eileen Wan
  • Patent number: 7897710
    Abstract: Film formed from a polyethylene resin composition which obeys a dynamic rheological relationship at 190° C. between melt storage modulus G?, measured in Pa and at a dynamic frequency where the loss modulus G?=3000 Pa, and dynamic complex viscosity ?*100, measured in Pa·s at 100 rad/s, such that (a) G?(G?=3000)>?0.86?*100+z where z=3800, and at the same time (b) G?(G?=3000)>0.875?*100?y where y=650, and having an impact strength (DDT) of at least 250 g, measured on 15 ?m thick film (blown under conditions with BUR=5:1 and Neck Height=8×D) conditioned for 48 hours at 20°-25° C., according to ASTM D1709.
    Type: Grant
    Filed: August 12, 2005
    Date of Patent: March 1, 2011
    Assignee: Ineos Manufacturing Belgium NV
    Inventors: John Amos, Choon Kooi Chai, Luc Marie Ghislain Dheur
  • Patent number: 7893180
    Abstract: A novel process for the polymerization of olefins is provided. The process involves contacting at least one olefin with a Ziegler-Natta type catalyst in the presence of a specified compound that results in the production of polymeric products having a narrower molecular weight distribution. Also provide is a process for narrowing the molecular weight distribution of a polyolefin comprising contacting an olefin, a Ziegler-Natta catalyst and a compound specified herein. Further provided are novel polyethylenes, and films and articles produced therefrom.
    Type: Grant
    Filed: August 20, 2007
    Date of Patent: February 22, 2011
    Assignee: Westlake Longview Corp.
    Inventors: Randal Ray Ford, Richard Kingsley Stuart, Jr.
  • Patent number: 7893159
    Abstract: The present invention includes a composition comprising a propylene-alpha olefin copolymer having at least seventy weight percent units derived from propylene, and from ten to twenty five weight percent units derived from ethylene or a C4-C10 alpha olefin, the propylene-alpha olefin copolymer exhibiting a heat of fusion of less than 37 Joules/gram and a melt flow rate of from 0.1 to 100 gram/10 minutes; and a styrenic block copolymer, wherein the weight ratio of the propylene-alpha olefin copolymer to the styrenic block copolymer is from 3:7 to 7:3. The composition exhibits tensile modulus of less than 20 MPa, tensile strength of at least 5 MPa, and elongation at break of at least 900% with low relative immediate set.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: February 22, 2011
    Assignee: Dow Global Technologies Inc.
    Inventor: Andy C. Chang
  • Patent number: 7893167
    Abstract: The object of the present invention is to provide a sealing film having excellent productivity, and improved light resistance and heat resistance, and a solar cell provided with the sealing film. A sealing film for a solar cell comprising ethylene-vinyl acetate copolymer and an organic peroxide, wherein the organic peroxide comprises an organic peroxide A having a 10 hour half-life in the range of 110 to 130° C. in and an organic peroxide B having a 10 hour half-life in the range of 80 to 100° C.; and a solar cell having the sealing film.
    Type: Grant
    Filed: April 5, 2007
    Date of Patent: February 22, 2011
    Assignee: Bridgestone Corporation
    Inventors: Hisataka Kataoka, Ichiro Aoki
  • Patent number: 7893181
    Abstract: A polymer, and a process of producing the polymer, that comprises at least one olefin and has a density of 0.955 g/cc to 0.959 g/cc and a secant modulus 140,000 psi to 220,000 psi. A film that comprises the polymer, that has a thickness of 0.5 mil to 10 mil, a drop dart impact of 10 g to 200 g, a tear strength of 10 to 1200 g and a secant modulus of 140,000 psi to 220,000 psi.
    Type: Grant
    Filed: July 6, 2007
    Date of Patent: February 22, 2011
    Assignee: Fina Technology, Inc.
    Inventors: Gerhard Guenther, Curtis D. Clark
  • Patent number: 7871557
    Abstract: The object is to provide a method for producing a film excellent in a quality of odorless or free from deteriorating taste of food contained in a package of the extruded molded article by using an ethylene-?-olefin copolymer excellent in extrusion molding processability. This object is achieved by a method for producing an extruded molded article comprising a step of extruding a copolymer of ethylene and ?-olefin of from 3 to 20 carbon atoms having an activation energy for melt flow of not less than 50 kJ/mol under one of the following conditions: (a) a temperature of melted resin at die gap of T-die is not more than 200° C., (b) a temperature of melted resin at die gap of tubular tie is not more than 170° C.
    Type: Grant
    Filed: September 23, 2004
    Date of Patent: January 18, 2011
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Yuki Iseki, Kenzo Chikanari, Yasuro Suzuki
  • Patent number: 7872085
    Abstract: The present invention relates to a biaxially oriented polypropylene film containing: a polypropylene resin as a main component thereof, having a weight average molecular weight of 100,000 or more and 500,000 or less, the weight average molecular weight being determined by gel permeation chromatography, wherein at least one surface of the biaxially oriented polypropylene film has a protrusion volume of 2.0×104 ?m3 or more and 3.0×104 ?m3 or less, the protrusion volume being determined in an area of 560 ?m×745 ?m using a super-depth surface profile measurement microscope by determining an average plane of the surface based on distances between plural points on the surface and an irradiation source of the super-depth surface profile measurement microscope and measuring a volume of protrusions projecting from the average plane.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: January 18, 2011
    Assignee: Oji Paper Co., Ltd.
    Inventors: Yoshinori Matsuo, Tadakazu Ishiwata, Fumio Jinno
  • Patent number: 7867581
    Abstract: A retardation film, formed by stretching a film including a norbornene-based, ring-opening polymer containing a structural unit (A) represented by a formula (1), has high transparency, excellent wavelength dispersion characteristics in a single layer, is capable of providing specific retardation to broadband light, is extremely adhesive to other materials, is capable of attaining optical characteristics that are unique among negative birefringence characteristics, and is capable of providing a reverse dispersion of birefringence wavelength dispersion characteristics. The present invention also provides a liquid crystal display device using the foregoing film.
    Type: Grant
    Filed: February 24, 2009
    Date of Patent: January 11, 2011
    Assignee: Nippon Oil Corporation
    Inventors: Shinichi Komatsu, Toshikatsu Shoko, Tadahiro Kaminade
  • Patent number: 7851575
    Abstract: A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: December 14, 2010
    Assignee: Promerus LLC
    Inventors: Ramakrishna Ravikiran, Xiaoming Wu, Larry F. Rhodes, Robert A. Shick, Hiroko Nakano, Hirotaka Nonaka, Huabin Wang, Robert John Duff, Saikumar Jayaraman, John-Henry Lipian
  • Patent number: 7851644
    Abstract: A new class of heterocyclic metallocenes, a catalytic system containing them and a process for polymerizing addition polymerizable monomers using the catalytic system are disclosed; the heterocyclic metallocenes correspond to the formula (I): YjR?iZjjMeQkPl wherein Y is a coordinating group containing a six ? electron central radical directly coordinating Me, to which are associated one or more radicals containing at least one non-carbon atom selected from B, N, O, Al, Si, P, S, Ga, Ge, As, Se, In, Sn, Sb and Te; R? is a divalent bridge between the Y and Z groups; Z is a coordinating group, optionally being equal to Y; Me is a transition metal; Q is halogen or hydrocarbon substituents; P is a counterion; i is 0 or 1; j is 1-3; jj is 0-2; k is 1-3; and l is 0-2.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: December 14, 2010
    Assignee: Basell Polyolefine GmbH
    Inventors: John A. Ewen, Michael J. Elder, Robert L. Jones, Jr., Yuri A. Dubitsky
  • Publication number: 20100243498
    Abstract: Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a metallocene random propylene-based copolymer.
    Type: Application
    Filed: March 26, 2009
    Publication date: September 30, 2010
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: Luyi Sun, Mark Leland
  • Publication number: 20100216963
    Abstract: A process for producing a cycloolefin resin film which comprises: a step in which a cycloolefin resin is melt-extruded at an extrusion temperature of 230-260° C. and a melt viscosity of 500-3,000 Pa·s into a film through a die; a step in which the melt-extruded film is cast; a step in which the cast film is wound up; and a step in which the film which has been wound is unwound and then stretched in the machine and/or transverse direction to cause retardation. The process is characterized by including the step of molecular orientation before the film winding step.
    Type: Application
    Filed: September 16, 2008
    Publication date: August 26, 2010
    Applicant: FUJIFILM CORPORATION
    Inventor: Tadashi Ueda
  • Patent number: 7772346
    Abstract: Propylene polymers having a content of isotactic pentads (mmmm) higher than 97%, molecular weight distribution, expressed by the formula (a) ratio, equal to or higher than 6 and a value of formula (b) ratio equal to or lower than 5.5. The said polymers are prepared in the presence of a particular combination of Ziegler-Natta solid catalyst components and highly stereoregulating electron-donor compounds. Laminated articles, in particular bi-axially oriented films and sheets, can be prepared with the said polymers.
    Type: Grant
    Filed: August 1, 2006
    Date of Patent: August 10, 2010
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Els Meesters, Jean News, Alessandro Guidicini
  • Patent number: 7763676
    Abstract: A method for forming a heat sealable coating on a substrate, wherein the substrate is formed from at least one oriented polymer is shown. The method includes depositing an aqueous polymer dispersion on the substrate, wherein the aqueous polymer dispersion includes (A) at least one thermoplastic resin; (B) at least one dispersing agent; and (C) water; wherein the dispersion has a pH of less than 12, and drying the dispersion to form a first layer.
    Type: Grant
    Filed: February 28, 2005
    Date of Patent: July 27, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Brad Maurice Moncla, Sarah T. Eckersley, Ralph G. Czerepinski, Charles F. Diehl, Matthew James Kalinowski, Dale C. Schmidt
  • Patent number: 7759445
    Abstract: For the (co) polymerization of ethylene with other 1-olefins, a Ziegler catalyst which comprises the product from the reaction of a magnesium alkoxide suspended or dispersed as ge in an inert solvent with a tetravalent transition metal compound and is subjected to a thermal after-treatment for a period of not more than 180 minutes is prepared. The catalyst gives a high yield of a polymer powder which has a broad molar mass distribution and is best suited to the production of films, hollow bodies and pipes.
    Type: Grant
    Filed: February 15, 2006
    Date of Patent: July 20, 2010
    Assignee: Basell Polyolefine GmbH
    Inventors: Friedhelm Gundert, Maria Schmitt (nee Fusto), Martin Schneider
  • Patent number: 7744969
    Abstract: The present invention provides a method for producing a retardation film of a polypropylene resin, the method comprising subjecting a film of a polypropylene resin to longitudinal stretching and transverse stretching which are performed sequentially, wherein the transverse stretching comprises the following steps, and a polypropylene resin retardation film which is obtained by such a method and has both a high axial retardation and a uniform retardation: a step of preheating the film at a preheating temperature which is equal to or higher than the melting point of the polypropylene resin; a step of stretching the preheated film in the transverse direction at a stretching temperature which is lower than the preheating temperature; and a step of heat setting the film stretched in the transverse direction.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: June 29, 2010
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kyoko Hino, Toshihiko Suzuki, Hiroaki Takahata
  • Publication number: 20100151755
    Abstract: The invention relates to a method for the production of high-strength ribbons having a high modulus of elasticity made of a highly molecular polyolefin, wherein the polyolefins, particularly polypropylene and polyethylene, are extruded through a slotted nozzle, are then subjected to a temperature of 85° to 135° C. for a duration of at least one second, the films are then cut into individual ribbons, if necessary, and stretched at temperatures between 90° and 165° C. in one or more steps, are rolled up or further processed directly into textiles or technical flexible sheet materials. The ribbons can be laminated into multi-layer flexible sheet materials by using adhesives or adhesion promoters, the flexible sheet materials being particularly suitable as protection from ballistic projectiles. In this case particularly in the form of plate-shaped or flexible compound bodies.
    Type: Application
    Filed: April 11, 2008
    Publication date: June 17, 2010
    Inventors: Hans-Joachim Bruning, Andreas Fischer, Jan Adolph Dam Backer, Mark James Bonner, Ian McMillan Ward
  • Patent number: 7736561
    Abstract: A process for preparing ultra-high molecular weight polyethylene (UHMWPE) multi-filament yarns having improved tensile properties and the yarns and articles thereby produced.
    Type: Grant
    Filed: October 21, 2009
    Date of Patent: June 15, 2010
    Assignee: Honeywell International Inc.
    Inventors: Thomas Y-T. Tam, Qiang Zhou, John A. Young, Charles R. Arnett, Conor Twomey
  • Publication number: 20100143643
    Abstract: The invention relates to a process for making high-performance polyethylene multi-filament yarn comprising the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DRfluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DRsolid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DRfluid=DRsp*DRag of at least 150, wherein DRsp is the draw ratio in the spinholes and DRag is the draw ratio in the air-gap, with DRsp being greater than 1 and DRag at least 1.
    Type: Application
    Filed: October 8, 2009
    Publication date: June 10, 2010
    Applicant: DSM IP ASSETS B.V.
    Inventors: Joseph Arnold Paul Maria Simmelink, Jacobus Johannes Mencke, Martinus Johannes Nicolaas Jacobs, Roeloef Marissen
  • Patent number: 7718744
    Abstract: Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.
    Type: Grant
    Filed: December 3, 2003
    Date of Patent: May 18, 2010
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Cheol Yoon, Sung-Ho Chun, Won-Kook Kim, Tae-Sun Lim, Heon Kim, Jung-Min Lee
  • Patent number: 7718747
    Abstract: A fiber and a process for obtaining same from a high-modulus polyethylene, extrudable in state-of-the-art equipment and in the absence of previous solubilization in any kind of organic solvent is described, the process comprising providing such a polyethylene, introducing it in a state-of-the-art extruder, extruding it according to a temperature pattern, obtaining an extrudate that is directed to a cooling bath to have its temperature reduced, then directing the extrudate to a first stretcher where it is stretched or drawn into a fiber of improved tenacity, at a first velocity v1, then heating the fiber at nearly 90° C. and then directing said fiber to a second stretcher to be drawn at a final velocity v2, wherein v1<v2, at a draw ratio of 2/1 until 65/1. The tenacity of the polyethylene fiber obtained by the said process attains at least 4 gf/den, which makes it useful to naval and offshore applications.
    Type: Grant
    Filed: January 7, 2008
    Date of Patent: May 18, 2010
    Assignee: Petroleo Brasileiro S.A.-Petrobras
    Inventors: Dellyo Ricardo dos Santos Alvares, Roberto Barcala Haag
  • Patent number: 7709572
    Abstract: The present invention is to provide an optical film which exhibits low hygroscopicity, high transparency, high heat resistance and markedly lowered brittleness, and particularly to provide an optical film which is appropriately employed as a polarizing plate protective film for large liquid crystal display devices and outdoor liquid crystal display devices. The above optical film is characterized in that acrylic resin (A) and cellulose ester resin (B) are incorporated at a weight ratio of 95:5-30:70, weight average molecular weight Mw of aforesaid acrylic resin (A) is at least 80,000, total substitution degree (T) of the acyl group of aforesaid cellulose ester resin (B) is 2.0-3.0, the substitution degree of the acyl group having 3-7 carbon atoms is 1.2-3.0, and weight average molecular weight Mw of aforesaid cellulose ester resin (B) is at least 75,000. It is characterized that the total substitution degree of the acyl group other than carbon atoms of 3-7 of the cellulose ester resin (B) is at most 1.3.
    Type: Grant
    Filed: October 3, 2008
    Date of Patent: May 4, 2010
    Assignee: Konica Minolta Opto, Inc.
    Inventors: Takashi Takebe, Masataka Takimoto, Nobuo Kubo
  • Publication number: 20100093965
    Abstract: The inventive heat-shrinkable polyolefin film is high in shrinkability in the longitudinal direction that is its main shrinkage direction and excellent in finish properties after shrinkage, perforated line openability, and thermal blocking resistance. The heat-shrinkable polyolefin film is characterized by particular values with respect to hot-water heat shrinkage ratio in the longitudinal and width directions, right angle tear strength in the width direction, and heat-resistant peel strength.
    Type: Application
    Filed: December 19, 2007
    Publication date: April 15, 2010
    Applicant: TOYO BOSEKI KABUSHIKI KAISHA
    Inventors: Shigetomo Yamamoto, Yukinobu Mukoyama, Kyoko Inagaki, Kenji Kawai, Masatoshi Hashimoto, Katsuhiko Nose
  • Patent number: 7691958
    Abstract: A polypropylene for an electric material has a melt flow rate of 0.1 to 30 g/10 min., a mesopentad fraction calculated from a 13C-NMR spectrum of 0.90 to 0.99, and a firing residue of 50 ppm by weight or less based on the polypropylene, a titanium content and an iron content which are detected from the firing residue, of 1 ppm by weight or less and 0.1 ppm or less, respectively, based on the polypropylene, and the chlorine content of 5 ppm by weight or less based on the polypropylene. The above polypropylene exhibits excellent electric insulation and has a roughened surface when it is formed into a film, and thus the polypropylene can be suitably used for a capacitor film without using an additive such as a ? crystal nucleating agent. The polypropylene is also useful as a material of a film for coating an electric wire and a material for an instrument for conveying an electronic material.
    Type: Grant
    Filed: November 25, 2004
    Date of Patent: April 6, 2010
    Assignee: Prime Polymer Co., Ltd.
    Inventors: Akihiro Inukai, Jyun Birukawa, Shuji Matsumura
  • Patent number: 7683141
    Abstract: The present invention relates in a first embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the sealing initiation temperature SIT of the film is Tm?30° C. or less, preferably Tm?33° C. or less, in a second embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the film is having a relative reduction of the static friction value (inside-inside) from one to four days of 35% or more, preferably 40% or more, in a third embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol % wherein the distribution of the comonomer in the random copolymer determined according to TREF method is multimodal, preferably bimodal, in a fourth embodiment to a polymer film comprising a propylene random copolymer with a total comonomer content of 4.5 to 12 mol %, wherein the copolymer is having an elution interval of 50° C.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: March 23, 2010
    Assignee: Borealis Technology Oy
    Inventors: Pirjo Jaaskelainen, Markus Gahleitner, Manfred Kirchberger, Paivi Pitkanen
  • Publication number: 20100063213
    Abstract: Semicrystalline polyolefins with narrow molecular weight distributions characterized by a low polydispersity index (PDI) and selected from the families of homopolymers, statistical copolymers, block copolymers, and graft copolymers, can be blended with a low molecular weight fluid diluent to create gel fiber and film compositions. These gel compositions, when subjected to mechanical or thermomechanical processing, either before or after removal of the diluent, result in fiber or film compositions that combine high tensile strength with other desirable physical properties, such as high rigidity, large extension at break, and/or high recoverable elasticity. These desirable combinations of properties are superior to those obtained from gel-processed semicrystalline polyolefins that are substantially similar in composition and molecular weight, but that have large PDIs.
    Type: Application
    Filed: September 4, 2009
    Publication date: March 11, 2010
    Inventors: Glenn H. Fredrickson, Edward Kramer, Geoffrey W. Coates
  • Patent number: 7658875
    Abstract: A polymer film having a thickness of 10 microns or less and improved barrier characteristics to both water vapor and oxygen is formed from a biaxially-oriented polypropylene film of isotactic polypropylene. The polypropylene is prepared by the polymerization of propylene in the presence of an isospecific metallocene catalyst. The film has a permeability to water vapor of less than about 2.5 g/m2 day/25 ?m and a permeability to oxygen of less than about 2200 cc/m2 day/25 ?m. The film also has a haze properties of less than about 1%. The polypropylene contains 0.1 to 1% 2,1 insertions and has an isotacticity of at least 96% meso pentads. The isotactic polypropylene thus produced is then extruded into a sheet that is biaxially-oriented by stressing the sheet in the transverse and longitudinal directions to a draw ratio of at least about 6:1 in the transverse direction, and at least about 4:1 in the longitudinal direction.
    Type: Grant
    Filed: November 25, 2008
    Date of Patent: February 9, 2010
    Assignee: Fina Technology, Inc.
    Inventor: Scott D. Cooper
  • Patent number: 7655742
    Abstract: There is provided a method of forming a thin film of vinylidene fluoride homopolymer having crystal form I which is applicable to various substrates in relatively easy way (coating conditions, application method, etc.), a process for preparing a vinylidene fluoride homopolymer having crystal form I efficiently at high purity, and novel vinylidene fluoride homopolymers which can give a thin film being excellent in ferroelectricity.
    Type: Grant
    Filed: September 22, 2005
    Date of Patent: February 2, 2010
    Assignee: Daikin Industries, Ltd.
    Inventors: Takayuki Araki, Tetsuhiro Kodani
  • Publication number: 20090315226
    Abstract: Injection stretch blow molded (ISBM) articles and methods of forming the same are described herein. The ISBM articles generally include a propylene-based impact copolymer.
    Type: Application
    Filed: June 19, 2008
    Publication date: December 24, 2009
    Applicant: Fina Technology, Inc.
    Inventor: Luyi Sun
  • Publication number: 20090312514
    Abstract: The present invention relates to a retardation film having a zero wavelength dispersibility and a uniform retardation, and an optical laminated film having a positive wavelength dispersibility. Here, in the retardation film, a homo polypropylene resin has an isotactic index more than 85 percents and having, and a value subtracting an average in-plain retardation value of the retardation film from the in-plain retardation value at the retardation film is in a range of ±5 nm. In the optical laminated film, another retardation film having a negative wavelength dispersibility is laminated on the above retardation film having a zero wavelength dispersibility.
    Type: Application
    Filed: June 12, 2009
    Publication date: December 17, 2009
    Applicant: HWASEUNG Industries Co. Ltd
    Inventors: Ho Young Lee, Ju Han Kim, Young Joong Kim, Byung Woo Kim, Ki Sung Ju
  • Patent number: 7632907
    Abstract: A polyethylene film comprising a polymer composition having the characteristics of a total energy dart drop, measured in accordance with ASTM D4272, of greater than a bout 0.45 ft.lbf, a dart drop impact strength, measured in accordance with ASTM D1709 Method A, of greater than about 135 g, and a moisture vapor transmission rate, measured in accordance with ASTM F1249 at 100° F. and 90% relative. humidity, of less than about 0.85 g-mil/100 square inch/24 hr, wherein said ASTM tests are performed on a test specimen having a 0.8 mil thickness.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: December 15, 2009
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Ashish M. Sukhadia, Joel L. Martin, Qing Yang, Kumudini C. Jayaratne, J. Todd Lanier
  • Patent number: 7615602
    Abstract: The invention relates to a process for producing a polypropylene film having a small dynamic coefficient of friction (CoF) and to a film obtained by this process. The invention further relates to the use of a polypropylene composition in a film forming process in order to reduce the required amount of slip agent for achieving a certain CoF and, alternatively, to the use of a polypropylene composition in a film forming process in order to reduce the required storage time for achieving a certain CoF.
    Type: Grant
    Filed: May 13, 2005
    Date of Patent: November 10, 2009
    Assignee: Borealis Technology Oy
    Inventors: Johannes Wolfschwenger, Manfred Kirchberger, Peter Niedersuess, Holger Poehler, Peter Denifl, Timo Leinonen
  • Patent number: 7601409
    Abstract: Stretch films are disclosed, the films having at least one layer formed of or including a polyethylene copolymer and having a natural draw ratio of at least 250%, a tensile stress at the natural draw ratio of at least 22 MPa, and a tensile stress at second yield of at least 12 MPa. In some embodiments, the polyethylene copolymer can have a CDBI of at least 70%, a melt index I2.16 of from 0.1 to 15 g/10 min., a density of from 0.910 to 0.940 g/cm3, a melt index ratio I21.6/I2.16 of from 30 to 80, and an Mw/Mn ratio of from 2.5 to 5.5. The stretch films are particularly useful in bundling and packaging applications.
    Type: Grant
    Filed: August 22, 2003
    Date of Patent: October 13, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Stefan Bertil Ohlsson
  • Patent number: 7595371
    Abstract: An ethylene-?-olefin copolymer comprising repeating units derived from ethylene and repeating units derived from an ?-olefin having 3 to 20 carbon atoms and having a melt flow rate (MFR) of from 0.01 to 100 g/10 min, a density (d) of from 890 to 970 kg/m3, a flow activation energy (Ea) of 50 kJ/mol or more, a molecular weight distribution (Mw/Mn) of 3 or more measured by gel permeation chromatography, and a hexane extraction rate (C) of 2.8% or less.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: September 29, 2009
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasutoyo Kawashima, Katsuhiro Yamada, Yoshinobu Nozue