Polymerizing In The Presence Of A Specified Material Other Than A Reactant And Other Than Group Ia Or Group Iia Material As Sole Metal Atom Patents (Class 528/198)
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Patent number: 10544259Abstract: An aromatic polycarbonate, having an aromatic polycarbonate backbone, can comprise: less than or equal to 5 ppm of polymeric chlorine attached to the aromatic polycarbonate backbone; less than 0.5 ppm of dichloromethane, less than 5 ppm of monohydric phenols, and less than 0.5 ppm of aromatic compounds containing no chlorine based on the total weight of the aromatic polycarbonate, wherein the aromatic compounds are compounds other than the aromatic polycarbonate.Type: GrantFiled: August 31, 2016Date of Patent: January 28, 2020Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: James Franklin Hoover, Sasi Sethumadhavan Kannamkumarath, Peter Anthony DiMattia
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Patent number: 9410015Abstract: The invention relates to a method for producing a polycarbonate comprising at least the following steps: a) transesterification of one or more bisphenols with one or more diaryl carbonates in at least one transesterification reactor under continuous removal of the hydroxy aryl reaction product released, b) pre-polycondensation of the reaction product of the transesterification in at least one pre-polycondensation reactor under continuous removal of the hydroxy aryl reaction product released, c) polycondensation of the reaction product of the pre-polycondensation in at least one polycondensation reactor, wherein the aryl reaction product is removed during the transesterification reaction and the hydroxy aryl reaction product is removed during the pre-polycondensation reaction through a common column, wherein entrained diaryl carbonate is separated from the hydroxy aryl reaction product drawn off.Type: GrantFiled: June 13, 2013Date of Patent: August 9, 2016Assignee: EPC ENGINEERING CONSULTING GMBHInventor: Michael Streng
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Patent number: 9346949Abstract: In an embodiment, a reflector comprises a polycarbonate composition, the polycarbonate composition comprises: polycarbonate; 10 wt % to 20 wt % titanium dioxide, based upon a total weight of the polycarbonate composition; an optional flame retardant; and an optional UV stabilizer. A plaque formed from the polycarbonate composition has a reflectance of greater than or equal to 95%, as determined by reflectance measurements using a Gretag Macbeth Coloreye spectrophotometer (D65 light source, 10 degree observer, UV included) made at a wavelength of 680 nm. A molded article of the polycarbonate has transmission level greater than or equal to 90.0% at 2.5 mm thickness as measured by ASTM D1003-00 and a yellow index (YI) less than or equal to 1.5 as measured by ASTM D1925.Type: GrantFiled: February 12, 2013Date of Patent: May 24, 2016Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Amanda Marie Flores, Vandita Pai-Paranjape
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Patent number: 9315619Abstract: Embodiments of the disclosure provide a method for removing residual BPA from a residual BPA-containing substance and a method for making a container with residual BPA removed. The method may consist of preparing a stabilization reagent, wherein water is removed from the stabilization reagent. The method may also include preparing the residual BPA-containing substance. The method may also include reacting the residual BPA-containing substance in a melt condensation process with the stabilization reagent, wherein the stabilization reagent is non-toxic.Type: GrantFiled: January 29, 2013Date of Patent: April 19, 2016Assignee: International Business Machines CorporationInventors: Travis R. Hebig, Joseph Kuczynski, Robert E. Meyer, III, Steven R. Nickel
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Patent number: 9023973Abstract: Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.Type: GrantFiled: December 20, 2013Date of Patent: May 5, 2015Assignee: SABIC Global Technologies B.V.Inventors: Jean-Francois Morizur, Paul Dean Sybert, James Franklin Hoover, Derek Lake
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Patent number: 9018341Abstract: The present invention relates to a method of reducing type IV rubber allergy of synthetic rubber latex products caused by chemical residues remaining after manufacture of the synthetic rubber products by reducing levels of chemical residues found for said products, said method comprising the steps of: subjecting said products to a wash in a strong alkaline solution to remove the chemical residues remaining after manufacture of the rubber latex products, and a system for reducing type IV allergenicity of synthetic rubber products caused by chemical residues remaining after manufacture of the synthetic rubber latex products by reducing residual levels of chemical residues found for said products, and a product, such as a glove, manufactured from synthetic rubber latex processed in accordance with the method and/or using the system.Type: GrantFiled: May 24, 2012Date of Patent: April 28, 2015Assignee: Budev B.V.Inventors: Michiel Inno Paping, Karen-Marlies Schenck
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Patent number: 9018340Abstract: A copolycarbonate that is derived from a renewable resource, is excellent in heat resistance, flowability and transparency, and prevented from undergoing a dimensional change by water absorption and coloring during molding as well as a transparent molded article obtained therefrom. The copolycarbonate contains predetermined amounts of a unit (A) constituted of an ether diol residue represented by the formula (1), a unit (B) constituted of a bisphenol residue represented by the formula (2), and a unit (C) constituted of another diol residue, wherein the ratio of terminal groups falls within the ranges of the expressions (i) and (ii).Type: GrantFiled: April 13, 2012Date of Patent: April 28, 2015Assignee: Teijin LimitedInventors: Tsuyoshi Takeda, Tetsuya Motoyoshi, Hiroshi Okamoto
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Patent number: 9018338Abstract: A resin that has high heat resistance, high surface hardness and excellent moldability, and is obtained from a biomass resource, and a molded article thereof. The resin comprises a unit (A) and a unit (B) as the main recurring units, and the molar ratio of the unit (A) to the unit (B) being 5/95 to 95/5.Type: GrantFiled: September 29, 2011Date of Patent: April 28, 2015Assignee: Teijin LimitedInventor: Tetsuya Motoyoshi
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Patent number: 9012591Abstract: A copolymerized polycarbonate resin includes a repeat unit represented by Formula 1; a repeat unit represented by Formula 2; and a repeat unit represented by Formula 3, wherein the repeat unit represented by Formula 1 is different than the repeat unit represented by Formula 3, and wherein Formula 1, 2, and 3 are the same as defined in the specification. The copolymerized polycarbonate resin can have excellent properties in terms of chemical resistance, thermal resistance, and/or external appearance.Type: GrantFiled: December 17, 2013Date of Patent: April 21, 2015Assignee: Cheil Industries Inc.Inventors: Jun Ho Chi, Jong Chan Hur, O Sung Kwon, Woo Suk Chei
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Patent number: 9012593Abstract: Methods of preparing an aromatic liquid crystalline polyester resin and an aromatic liquid crystalline polyester resin compound are disclosed. A method of preparing an aromatic liquid crystalline polyester resin may include: acetylating a first monomer including an amino group by a reaction with a carboxylic acid anhydride; acetylating a second monomer including a hydroxyl group and not including an amino acid group with an additional carboxylic acid anhydride; and synthesizing an aromatic liquid crystalline polyester prepolymer by a condensation polymerization reaction of the acetylated first and second monomers with dicarboxylic acid. A method of preparing an aromatic liquid crystalline polyester resin compound may use the aromatic liquid crystalline polyester resin prepared according to the forgoing method.Type: GrantFiled: June 14, 2011Date of Patent: April 21, 2015Assignee: Shenzhen Wote Advanced Materials Co., Ltd.Inventors: Sun Hwa Chang, Sang Mi Kang, Dae Yeon Kim, Jin Kyu Lee
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Patent number: 9006378Abstract: A plastic article formed from a thermoplastic composition including a polycarbonate having repeating structural carbonate units according to the formula: in which at least 60 percent of the total number of R1 groups contain aromatic moieties and the balance thereof are aliphatic, alicyclic, or aromatic. The composition also includes an epoxy additive having at least two epoxy groups per molecule and a phenolic diphosphite derived from pentaerythritol. The thermoplastic composition exhibits a dE (2000 hrs.) value of less than 1.5 after 2000 hours of heat aging at 130° C., measured according ISO 11664-4:2008(E)/CIE S 014-4/E:2007 using CIE illuminant D65 and a 2.5 mm thick molded plaque of the thermoplastic composition.Type: GrantFiled: May 28, 2014Date of Patent: April 14, 2015Assignee: SABIC Global Technologies B.V.Inventors: Joshua Arie van den Bogerd, Johannes de Brouwer
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Patent number: 8981017Abstract: The present invention is a polycarbonate-polyorganosiloxane copolymer (A-1) comprising a polycarbonate block composed of a specific structural unit and a polyorganosiloxane block composed of a specific structural unit, wherein (1) the content of the polyorganosiloxane block portion is 1 to 30% by mass, (2) the average number of the repeating structural units represented by the general formula (II) is 70 to 1000, (3) the viscosity-average molecular weight of the copolymer is 13000 to 26000, and (4) the content of the phenol residue having an allyl group in the copolymer is 400 ppm by mass or less, the copolymer providing a molded article having excellent thermal stability and excellent color tone after even when the molding is carried out at high temperature; a process for production of the copolymer; and a polycarbonate resin using the polycarbonate-polyorganosiloxane copolymer.Type: GrantFiled: December 9, 2010Date of Patent: March 17, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventor: Yasuhiro Ishikawa
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Patent number: 8975361Abstract: The present invention relates to water and solvent-free polymers, in particular water and solvent-free synthetic rubber products like styrene butadiene rubber products and butadiene rubber products as well as a process for the production thereof. The invention further relates to a device suitable to accomplish said process.Type: GrantFiled: March 23, 2011Date of Patent: March 10, 2015Assignee: LANXESS Deutschland GmbHInventors: Wolfgang Krumbe, Rolf Feller, Paul Wagner, Hanns-Ingolf Paul, Martin Siebuerger, Heike Kloppenburg, Alicia Le-Sattler, John Lovegrove
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Patent number: 8969436Abstract: A method of producing a molded article by melting a granule at a temperature of 280 to 380° C. and molding it, wherein the granule satisfies the following conditions (I) and (II): (I) when 100 parts by weight of the granule is cleaned with 100 parts by weight of a 1N nitric acid aqueous solution, the amount of an Fe compound eluted into the 1N nitric acid aqueous solution cleaning fluid is 1 to 100 ppb in terms of the Fe atom based on the granule; and (II) the granule comprises (A) 100 parts by weight of a polycarbonate resin (component a) and (B) 0.00010 to 0.5 parts by weight of a specific phosphorous-based compound (component b).Type: GrantFiled: August 21, 2009Date of Patent: March 3, 2015Assignee: Teijin Chemicals, Ltd.Inventors: Manabu Norimatsu, Tomomitsu Onizawa, Seiichi Tanabe
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Patent number: 8962787Abstract: A method for producing polycarbonate by melt polymerization can comprise: (a) adding acetone, diaryl carbonate, and dihydroxy compound to the melt polymerization unit, wherein the acetone is added to the melt polymerization unit as a mixture with the diaryl carbonate and/or the dihydroxy compound; (b) adding a catalyst to the melt polymerization unit, optionally without separating out acetone prior to the addition of the catalyst; and (c) operating the melt polymerization unit under conditions so that the diaryl carbonate(s) and dihydroxy compound(s); dihydroxy compound reacts with the diaryl carbonate to produce polycarbonate with a desired specification, and a phenol by-product.Type: GrantFiled: December 17, 2012Date of Patent: February 24, 2015Assignee: Sabic Global Technologies B.V.Inventors: Ignacio Vic Fernandez, Fernan Mateos Salvador, Mykhaylo Lyakhovych, Sergio Ferrer Nadal
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Patent number: 8962788Abstract: A method for producing a polycarbonate comprising: reacting a diaryl carbonate with a dihydroxy compound to form a polycarbonate, wherein the polycarbonate comprises: less than or equal to 1000 ppb of molybdenum; less than or equal to 33 ppb of vanadium; less than or equal to 33 ppb of chromium; less than or equal to 375 ppb of niobium; less than or equal to 33 ppb of nickel; less than or equal to 10 ppb of zirconium; and less or equal to 10 ppb iron.Type: GrantFiled: March 13, 2014Date of Patent: February 24, 2015Assignee: Sabic Global Technologies B.V.Inventors: Ignacio Vic Fernandez, Mykhaylo Lyakhovych, Sergio Ferrer Nadal
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Patent number: 8937146Abstract: The polycarbonate resin of the present invention comprises a structural unit derived from a dihydroxy compound represented by a specific formula (1), a structural unit derived from a dihydroxy compound represented by a specific formula (2), and a structural unit derived from a dihydroxy compound represented by any one of specific formulae (3) to (6), wherein the content of structural units derived from dihydroxy compounds represented by the specific formulae (3) to (6) is within a specific range based on the total of structural units derived from dihydroxy compounds in the polycarbonate resin.Type: GrantFiled: November 12, 2013Date of Patent: January 20, 2015Assignees: Mitsubishi Chemical Corporation, Nitto Denko CorporationInventors: Masashi Yokogi, Shingo Namiki, Tomohiko Tanaka, Nao Murakami
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Patent number: 8933167Abstract: A polyamide comprising (a) a unit comprising adipic acid and hexamethylenediamine and (b) a unit comprising isophthalic acid and hexamethylenediamine, wherein a ratio of the isophthalic acid component to the total carboxylic acid component in the polyamide is 0.05?(x)?0.5 and a range of blocking ratio (Y) is ?0.3?(Y)?0.8. Also provided are compositions comprising 30 to 95% by mass of the above polyamide and 5 to 70% by mass of an inorganic filler.Type: GrantFiled: June 10, 2011Date of Patent: January 13, 2015Assignee: Asahi Kasei Chemicals CorporationInventors: Yukiyoshi Sasaki, Hiroshi Oyamada, Yasukazu Shikano
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Patent number: 8927678Abstract: A thermoplastic polyimide resin containing a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), a content ratio of the repeating structural unit of formula (2) with respect to the total of the repeating structural unit of formula (1) and the repeating structural unit of formula (2) being from 40 to 70% by mol: wherein R1 represents a divalent group having from 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; R2 represents a divalent chain aliphatic group having from 5 to 12 carbon atoms; and X1 and X2 each independently represent a tetravalent group having from 6 to 22 carbon atoms containing at least one aromatic ring.Type: GrantFiled: February 5, 2013Date of Patent: January 6, 2015Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yuuki Sato, Jun Mitadera
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Patent number: 8927680Abstract: A molded article produced by molding a coating solution that contains a polycarbonate resin represented by the following formula (1) has excellent transparency, good water repellency and oil repellency, a lower friction coefficient and excellent surface lubricity, having a capability of improving abrasion resistance. In the formula (1), Rf represents a perfluoroalkyl group having 5 or more carbon atoms and 11 or more fluorine atoms or a perfluoroalkyl group having a specific structure; and W represents a divalent group including therein a specific structural unit.Type: GrantFiled: August 16, 2012Date of Patent: January 6, 2015Assignee: Idemitsu Kosan Co., Ltd.Inventors: Hironobu Morishita, Kengo Hirata
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Patent number: 8921508Abstract: In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.Type: GrantFiled: September 27, 2013Date of Patent: December 30, 2014Assignee: Novomer, Inc.Inventors: Scott D. Allen, Geoffrey W. Coates, Anna E. Cherian, Chris A. Simoneau, Alexei A. Gridnev, Jay J. Farmer
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Patent number: 8907044Abstract: The polycarbonate resin of the present invention comprises a structural unit derived from a dihydroxy compound represented by a specific formula (1), a structural unit derived from a dihydroxy compound represented by a specific formula (2), and a structural unit derived from a dihydroxy compound represented by any one of specific formulae (3) to (6), wherein the content of structural units derived from dihydroxy compounds represented by the specific formulae (3) to (6) is within a specific range based on the total of structural units derived from dihydroxy compounds in the polycarbonate resin.Type: GrantFiled: November 12, 2013Date of Patent: December 9, 2014Assignees: Mitsubishi Chemical Corporation, Nitto Denko CorporationInventors: Masashi Yokogi, Shingo Namiki, Tomohiko Tanaka, Nao Murakami
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Patent number: 8865856Abstract: A polycarbonate of number average molecular weight from 500 to 10000, glass transition point from 30 to 80° C. and hydroxyl group value of 30 mg KOH/g or less. The use of the polycarbonate in a urethane modified resin used as an ingredient for the production of a toner or a developer. A urethane modified resin obtained by reacting a polymer mixture containing the polycarbonate and a polycondensed resin of glass transition point from 10 to 60° C. and hydroxyl group value from 20 to 100 mg KOH/g with a polyfunctional isocyanate compound wherein the ratio of polycarbonate to polycondensed resin is from 20:80 to 80:20 by weight and the molar ratio of isocyanate groups in the polyisocyanate compound to hydroxyl groups in the polymer mixture is from 0.4 to 1.2:1. A toner for electronic copying containing the urethane modified polycarbonate based resin. A developer containing the toner and optionally a carrier.Type: GrantFiled: July 6, 2010Date of Patent: October 21, 2014Assignee: BASF SEInventors: Yoshihisa Fujii, Hiroyasu Kanno, Torii Yoshinori, Ema Kenji
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Patent number: 8865857Abstract: A medical device includes a substrate having at least a portion thereof functionalized with at least one reactive member and a chemotactic agent functionalized with at least one complementary reactive member. The at least one reactive member and the at least one complementary reactive member are covalently bonded, adhering the chemotactic agent to the substrate.Type: GrantFiled: June 30, 2011Date of Patent: October 21, 2014Assignee: Sofradim ProductionInventors: Sébastien Ladet, Philippe Gravagna
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Patent number: 8865855Abstract: The problem to be solved by the present invention is to provide a polycarbonate copolymer containing a plant-derived raw material, which is excellent in the mechanical strength and heat-resistant and assured of small refractive index, large Abbe number, small birefringence and excellent transparency. The present invention provides a polycarbonate copolymer containing a constitutional unit derived from a dihydroxy compound represented by the following formula (1) and a constitutional unit derived from an alicyclic dihydroxy compound, wherein the Abbe number is 50 or more and the 5% thermal reduction temperature is 340° C. or more; and a method of producing this polycarbonate copolymer by reacting a dihydroxy compound represented by the following formula (1) and an alicyclic hydroxy compound with a carbonic acid diester in the presence of a polymerization catalyst.Type: GrantFiled: June 14, 2007Date of Patent: October 21, 2014Assignee: Mitsubishi Chemical CorporationInventors: Michiaki Fuji, Minako Akita, Tomohiko Tanaka
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Patent number: 8846858Abstract: The disclosure provides a method for alcoholysis of a polycarbonate-containing composition comprising a polycarbonate and a component comprising a phosphorus-containing flame retardant, an acrylonitrile-butadiene-styrene, or a combination of the phosphorus-containing flame retardant and acrylonitrile-butadiene-styrene. The method comprises contacting the composition with a solvent that forms a solution or a filterable suspension of the component but not the polycarbonate; separating the solution or the filterable suspension from the polycarbonate; and heating the polycarbonate in the presence of an alcohol and a catalyst at a temperature from 70° C. to 200° C., and a pressure from 5 mbar to 40 bar for a time sufficient to depolymerize the polycarbonate and produce a dihydroxy aromatic compound and a dialkyl carbonate.Type: GrantFiled: December 21, 2012Date of Patent: September 30, 2014Assignee: Saudi Basic Industries CorporationInventors: Philip Wesley Bell, Alexander Stanislaus, Venkata Ramanarayanan Ganapathy Bhotla, Rathinam Jothi Mahalingam
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Patent number: 8841405Abstract: A process, thermoset resin, and thermoplastic structures from renewable chemical feedstocks derived from the essential oils from herbs and other plants. The processes for making diphenol products including extracting isomers of 4-methoxyphenylpropene from plant sources, transforming isomers by olefin cross or self-cross olefin metathesis and at least one catalyst to produce dimeric structures having two equivalents of protected phenolic groups, and deprotecting methyl ethers to yield diphenolic products.Type: GrantFiled: May 2, 2013Date of Patent: September 23, 2014Assignee: The United States of America as Represented by the Secretary of the NavyInventor: Matthew C. Davis
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Patent number: 8841404Abstract: Polycarbonate compositions having flame retardant properties and improved impact resistance are disclosed, together with methods for preparing the same.Type: GrantFiled: May 18, 2011Date of Patent: September 23, 2014Assignee: SABIC Global Technologies B.V.Inventors: Haseena Aripuram Parakkal, Sriram Krishnamurthy, Wim Steendam, Gautam Chatterjee
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Patent number: 8816039Abstract: The present invention provides a copolycarbonate that has a low photoelastic constant and has fewer foamed cells and that is in particular suitable for use in optical fields. The present invention is a copolycarbonate containing 10 to 90 mol % of a unit (A) derived from spiroglycol and 90 to 10 mol % of a unit (B) derived from aromatic phenol and having terminals satisfying the following expressions (i) and (ii), 0.0001<(a)/(d)<0.1??(i) 0.02<(b)/(d)<0.8??(ii) wherein (a) is an amount of a terminal group derived from spiroglycol, (b) is an amount of a terminal group derived from aromatic phenol, and (d) is a total terminal group amount.Type: GrantFiled: November 10, 2011Date of Patent: August 26, 2014Assignee: Teijin LimitedInventors: Tetsuya Motoyoshi, Masatoshi Ando, Tsuyoshi Takeda
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Patent number: 8785591Abstract: The disclosure pertains to amphiphilic block copolymers comprising an aliphatic polycarbonate chain coupled to a hydrophilic polymer. Such amphiphilic polymers may have the formula A-L-B, where A- is a polycarbonate or polyethercarbonate chain having from about 3 to about 500 repeating units, L is a linker moiety and -B is a hydrophilic oligomer having from about 4 to about 200 repeating units. Provided copolymers are useful as surfactants capable of emulsifying aqueous solutions and supercritical carbon dioxide. Provided copolymers also have utility as additives for use in enhanced oil recovery methods.Type: GrantFiled: September 27, 2013Date of Patent: July 22, 2014Assignee: Novomer, Inc.Inventors: Scott D. Allen, Chris A. Simoneau, John M. Salladay, David M. Hatfield, John W. Stevens
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Patent number: 8748555Abstract: The present invention provides articles made from structurally precise poly(propylene carbonate) and blends thereof. Provided articles include articles manufactured from poly(propylene carbonate) wherein the PPC has a high head-to-tail ratio, low ether linkage content, narrow polydispersity and low cyclic carbonate content. Also provided are articles made from, incorporating or coated with structurally precise PPC.Type: GrantFiled: July 1, 2010Date of Patent: June 10, 2014Assignee: Novomer, Inc.Inventor: Scott D. Allen
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Patent number: 8742057Abstract: A polycarbonate resin composition (X), comprises: (A) a polycarbonate resin containing (a) a structural unit derived from a dihydroxy compound having a moiety represented by the following formula (1) in a part of a structure; and (B) an aromatic polycarbonate resin, wherein a reduced viscosity of the aromatic polycarbonate resin (B) is 0.55 dl/g or less, a proportion of the aromatic polycarbonate resin (B) in the polycarbonate resin composition (X) is 30 wt % or more, and a total light transmittance of the polycarbonate resin composition (X) is 90% or less: CH2—O??(1).Type: GrantFiled: August 19, 2013Date of Patent: June 3, 2014Assignee: Mitsubishi Chemical CorporationInventors: Masashi Yokogi, Haruo Sasaki
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Patent number: 8735535Abstract: A method for producing a polycarbonate resin comprises a step of performing polycondensation through a transesterification reaction in the presence of a transesterification catalyst by using a dihydroxy compound as a raw material compound and a carbonic acid diester, wherein the dihydroxy compound comprises at least an aliphatic dihydroxy compound having an etheric oxygen atom on a hydroxy group, the raw material compound comprises the specific amount of a nitrogen-containing compound, and the production method of a polycarbonate resin comprises a step of previously heating the aliphatic dihydroxy compound at the specific temperature, holding the compound in the melted state for the specific time, and then mixing the melt with a carbonic acid diester.Type: GrantFiled: September 30, 2013Date of Patent: May 27, 2014Assignee: Mitsubishi Chemical CorporationInventors: Shingo Namiki, Masanori Yamamoto
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Patent number: 8729215Abstract: Embodiments according to the present invention relate to sacrificial polymer compositions that include polycarbonate polymers having repeat units derived from stereospecific polycyclic 2,3-diol monomers. The sacrificial polymer compositions also include an acid generator that is selected from at least one photoacid generator and/or at least one thermal acid generator. In addition, embodiments according to the present invention relate to a method of forming a structure that includes a three-dimensional space interposed between a substrate and an overcoat layer, and a method of temporarily bonding first and second substrates together, which make use of the polycarbonate polymers.Type: GrantFiled: September 27, 2013Date of Patent: May 20, 2014Assignee: Promerus, LLCInventors: Andrew Bell, Robert A. Shick, Leah Langsdorf, Keitaro Seto, W. C. Peter Tsang
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Patent number: 8722813Abstract: A resin composition containing: an ester compound including a carboxylic acid ester obtained by using (1) a monohydric alcohol having an alkyl group having 1 to 4 carbon atoms; (2) a dicarboxylic acid having an alkylene group having 2 to 4 carbon atoms; and (3) a dihydric alcohol having an alkylene group having 2 to 6 carbon atoms, the ester compound having an acid value of 1.00 mgKOH/g or less, a hydroxyl value of 5.0 mgKOH/g or less, and a number-average molecular weight of from 300 to 700; and an aliphatic polyester. Since the resin composition of the present invention inhibits the generation of volatile compounds, the resin composition can be suitably used in various industrial applications, such as daily sundries, household electric appliance parts, and automobile parts.Type: GrantFiled: August 18, 2011Date of Patent: May 13, 2014Assignee: Kao CorporationInventors: Hiroki Sawada, Masahiro Mori
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Patent number: 8680226Abstract: The disclosure provides a method for recovering a dihydroxy aromatic compound and a dialkyl carbonate from a polycarbonate-containing composition comprising a polycarbonate and acrylonitrile-butadiene-styrene. The method comprises heating the composition in the presence of an alcohol and a transesterification catalyst at a temperature of 70° C. to 200° C. and a pressure of 50 mbar to 40 bar in a reactor for a time sufficient to depolymerize the polycarbonate producing a dihydroxy aromatic compound and a dialkyl carbonate; removing the dihydroxy aromatic compound and the dialkyl carbonate from the reactor, the acrylonitrile-butadiene-styrene remaining as a coating on the surfaces of the reactor; adding a solvent to the reactor; and heating the solvent to remove the acrylonitrile-butadiene-styrene from the surfaces of the reactor.Type: GrantFiled: December 21, 2012Date of Patent: March 25, 2014Assignee: Saudi Basic Industries CorporationInventors: Philip Wesley Bell, Alexander Stanislaus, Venkata Ramanarayanan Ganapathy Bhotla, Tukaram Gunale, Darshan Jayanna
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Patent number: 8680227Abstract: A method to produce a purified dihydroxy aromatic compound from a polycarbonate-containing composition is provided. The method includes depolymerizing the polycarbonate by alcoholysis using a titanium-based catalyst producing a dihydroxy aromatic compound and a dialkyl carbonate, recovering the dihydroxy aromatic compound as a crude dihydroxy aromatic compound; and contacting the recovered crude dihydroxyl aromatic compound with an acid in the presence of a solvent at an elevated temperature. Alternatively, the method comprises dissolving the recovered crude dihydroxyl aromatic compound in a solvent; contacting the dissolved crude dihydroxy aromatic compound with a base; and neutralizing the combination of the dissolved crude dihydroxy aromatic compound and the base with an acid.Type: GrantFiled: December 21, 2012Date of Patent: March 25, 2014Assignee: Saudi Basic Industries CorporationInventors: Philip Wesley Bell, Alexander Stanislaus, Venkata Ramanarayana Ganapathy Bhotla, Tukaram Gunale, Darshan Jayanna
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Patent number: 8674053Abstract: A method for highly polymerizing an aromatic polycarbonate resin, which enables the increase in molecular weight of the aromatic polycarbonate resin satisfactorily while keeping good quality of the resin. An aromatic polycarbonate is linked to an aliphatic diol compound having a boiling point of 240° C. or higher (preferably in an amount of 0.01 to 1.0 mole per mole of the total amount of the terminal of the aromatic polycarbonate) through a transesterification reaction in the presence of a transesterification catalyst under reduced pressure conditions (preferably at a reduced pressure ranging from 13 kPaA (100 torr) to 0.01 kPaA (0.01 torr)), thereby increasing the molecular weight of the resulting molecule. The weight average molecular weight (Mw) of the aromatic polycarbonate after the transesterification reaction can be increased preferably by 5,000 or more compared to that of the aromatic polycarbonate before the transesterification reaction.Type: GrantFiled: November 18, 2010Date of Patent: March 18, 2014Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yoshinori Isahaya, Shu Yoshida, Noriyuki Kato, Hiroki Furuhashi
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Patent number: 8669342Abstract: The invention provides a non-painting and high-gloss polycarbonate resin composition. Specifically, the invention provides a polycarbonate resin composition having a superior impact strength, heat-resistance, electric characteristics, weather resistance, and light resistance. In certain embodiments, the resin composition of the invention is obtained by mixing a butadiene-based impact modifier, such as acrylonitrile-butadiene-styrene (ABS) or methacrylate-butadiene-styrene and an acryl-based impact modifier in polycarbonate resin, followed by adding an ultraviolet (UV) absorbent to the mixture.Type: GrantFiled: December 12, 2012Date of Patent: March 11, 2014Assignees: Hyundai Motor Company, Kia Motors Corporation, LG Chem. Ltd.Inventors: Dae Sik Kim, Jung Gyun Noh, Kyeong Hoon Jang, Hyun Joon Choi, Yong Kim, Sung Tae Ahn, Min Han Kwak
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Patent number: 8664349Abstract: The present invention relates to polycarbonate compositions and copolycarbonate compositions having improved optical properties, and to their production and their use for the production of shaped parts, and to shaped parts which can thereby be obtained, the compositions containing a polycarbonate or copolycarbonate which comprises bisphenol-A and at least one pair of a phosphorus compound having the oxidation number +3 and a phosphorus compound having the oxidation number +5, and the phosphorus compound having the oxidation state +5 in a pair respectively corresponding to the oxidized form of the phosphorus compound having the oxidation state +3 and the amount of more highly oxidized compound contained being less than that of the compound with the lower oxidation number.Type: GrantFiled: September 17, 2010Date of Patent: March 4, 2014Assignee: Bayer MaterialScience AGInventors: Rolf Wehrmann, Helmut-Werner Heuer, Anke Boumans
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Patent number: 8648163Abstract: Disclosed are random copoly(phosphonate carbonate)s with the high molecular weight and narrow molecular weight distribution exhibiting a superior combination of properties compared to prior art.Type: GrantFiled: February 11, 2013Date of Patent: February 11, 2014Assignees: FRX Polymers, Inc., Bayer Material Science AGInventors: Dieter Freitag, Pin Go, Lawino Kagumba, Stephan Konrad, Helmut-Werner Heuer, Berit Krauter, Pieter Ooms, Michael Prein, Johann Rechner
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Patent number: 8604155Abstract: In one aspect, the present disclosure encompasses polymerization systems for the copolymerization of CO2 and epoxides comprising 1) a catalyst including a metal coordination compound having a permanent ligand set and at least one ligand that is a polymerization initiator, and 2) a chain transfer agent having two or more sites that can initiate polymerization. In a second aspect, the present disclosure encompasses methods for the synthesis of polycarbonate polyols using the inventive polymerization systems. In a third aspect, the present disclosure encompasses polycarbonate polyol compositions characterized in that the polymer chains have a high percentage of —OH end groups and a high percentage of carbonate linkages. The compositions are further characterized in that they contain polymer chains having an embedded polyfunctional moiety linked to a plurality of individual polycarbonate chains.Type: GrantFiled: August 14, 2012Date of Patent: December 10, 2013Assignee: Novomer, Inc.Inventors: Scott D. Allen, Geoffrey W. Coates, Anna E. Cherian, Chris A. Simoneau, Alexei A. Gridnev, Jay J. Farmer
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Patent number: 8580911Abstract: The disclosure pertains to amphiphilic block copolymers comprising an aliphatic polycarbonate chain coupled to a hydrophilic polymer. Such amphiphilic polymers may have the formula A-L-B, where A- is a polycarbonate or polyethercarbonate chain having from about 3 to about 500 repeating units, L is a linker moiety and —B is a hydrophilic oligomer having from about 4 to about 200 repeating units. Provided copolymers are useful as surfactants capable of emulsifying aqueous solutions and supercritical carbon dioxide. Provided copolymers also have utility as additives for use in enhanced oil recovery methods.Type: GrantFiled: October 30, 2009Date of Patent: November 12, 2013Assignee: Novomer, Inc.Inventors: Scott D. Allen, Chris A. Simoneau, John M. Salladay, David M. Hatfield, John W. Stevens
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Patent number: 8575297Abstract: Embodiments according to the present invention relate to sacrificial polymer compositions that include polycarbonate polymers having repeat units derived from stereospecific polycyclic 2,3-diol monomers. The sacrificial polymer compositions also include an acid generator that is selected from at least one photoacid generator and/or at least one thermal acid generator. In addition, embodiments according to the present invention relate to a method of forming a structure that includes a three-dimensional space interposed between a substrate and an overcoat layer, and a method of temporarily bonding first and second substrates together, which make use of the polycarbonate polymers.Type: GrantFiled: August 5, 2011Date of Patent: November 5, 2013Assignee: Promerus, LCCInventors: Andrew Bell, Robert A. Shick, Leah Langsdorf, Keitaro Seto, W. C. Peter Tsang
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Patent number: 8541537Abstract: This invention provides a branched polycarbonate resin obtained from a dihydric phenol compound, a branching agent, monohydric phenols and phosgene by an interfacial polymerization reaction method in the presence of an alkali aqueous solution and an organic solvent, the branched polycarbonate resin having features that: (i) the branching agent content (X) thereof is over 0.70 mol % but 1.50 mol % or less, (ii) the branching agent content (X) and the melt tension (Y) thereof at 280° C. satisfy the following expression (1), 3.8X?2.4?Y?3.8X+4.5 (1), and (iii) the entire N content in the branched polycarbonate resin is 0 to 7 ppm.Type: GrantFiled: October 5, 2010Date of Patent: September 24, 2013Assignee: Teijin Chemicals, Ltd.Inventors: Takayuki Ozaki, Hiroshi Okamoto, Hiroshi Shuto
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Patent number: 8530605Abstract: The invention provides a production process of a poly(arylene sulfide), comprising a polymerization step of subjecting at least one sulfur source selected from the group consisting of alkali metal sulfides and alkali metal hydrosulfides and a dihalo-aromatic compound to a polymerization reaction in an organic amide solvent; a reaction step of adding a hydroxyl group-containing organic compound containing no bonded halogen atom in a proportion of 0.001 to 20 mol per 100 mol of the charged sulfur source into the polymerization reaction system containing the organic amide solvent and a formed polymer after the polymerization step to cause the formed polymer to react with the hydroxyl group-containing organic compound; and a collecting step of collecting a polymer from the polymerization reaction system after the reaction step, and the poly(arylene sulfide).Type: GrantFiled: May 11, 2010Date of Patent: September 10, 2013Assignee: Kureha CorporationInventors: Akihiro Konno, Hiroshi Sakabe, Ken-ichi Takaki
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Patent number: 8530606Abstract: The invention relates to a process for preparing a diaryl carbonate from a dialkyl carbonate and an aryl alcohol using a series of reactive distillation columns.Type: GrantFiled: November 30, 2010Date of Patent: September 10, 2013Assignee: Shell Oil CompanyInventors: Timothy Michael Nisbet, Garo Garbis Vaporciyan, Cornelis Leonardus Maria Vrouwenvelder
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Publication number: 20130225763Abstract: Processes for preparing high purity polycarbonates having high light transmission, low yellowness, and color stability are disclosed herein. High purity starting ingredients are used to form a polycarbonate powder. The polycarbonate powder can be subsequently melt extruded at an optimum shear rate to minimize yellowness and the need to add colorant to overcome the yellowness. The lower amount of colorant increases the light transmission of the resulting polycarbonate resin.Type: ApplicationFiled: February 28, 2013Publication date: August 29, 2013Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventor: SABIC INNOVATIVE PLASTICS IP B.V.
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Patent number: 8519082Abstract: A polycarbonate copolymer includes a repeating unit represented by a formula (1) below and a molar copolymer composition represented by Ar2/(Ar1+Ar2) in a range of 25 mol % to 50 mol %. In the formula (1): Ar1 and Ar2 represent a divalent aromatic group; a chain end is terminated by a monovalent aromatic group or a monovalent fluorine-containing aliphatic group; and n represents an average repeating number of an Ar1 block and is a numeral of 1.0 to 3.0, provided that Ar1 and Ar2 are not the same.Type: GrantFiled: June 25, 2010Date of Patent: August 27, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takaaki Hikosaka, Hideyuki Miyamoto
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Patent number: 8492501Abstract: Polycarbonates are recovered from polymer blends by liquid chromatography. Polycarbonate recovered by the process can be reused in new applications. The invention can be extended to recycling of other polymers present in the blends.Type: GrantFiled: May 3, 2012Date of Patent: July 23, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Philip Bell, David Zoller