Ethylenically Unsaturated Carboxylic Acid Or Ethylenically Unsaturated Derivative Patents (Class 528/303)
  • Patent number: 7160961
    Abstract: The invention relates to cast resins containing A) at least one solid unsaturated polyester and B) at least one oligomer and/or polymer cross-linking agent that can be copolymerised therewith, said cross-linking agent having at least one terminal and/or lateral propenyl-, isoprenyl- and/or (meth)acrylester group in relation to the oligomer- and/or polymer main chain. The invention also relates to the use of cast resins as casting beans and impregnants and as coating agents. The invention further relates to a method for melt impregnating or melt coating components, absorbent mattes or grounded or ungrounded substrates with the cast resins.
    Type: Grant
    Filed: July 31, 2000
    Date of Patent: January 9, 2007
    Assignee: Altana Electrical Insulation GmbH
    Inventors: Rainer Blum, Manfred Eichhorst, Gunther Hegemann, Klaus-Wilhelm Lienert
  • Patent number: 7144975
    Abstract: The invention relates to unsaturated, amorphous polyesters based on certain dicidol isomers and on saturated and/or unsaturated dicarboxylic acids.
    Type: Grant
    Filed: February 15, 2003
    Date of Patent: December 5, 2006
    Assignee: Degussa AG
    Inventors: Patrick Gloeckner, Alessandro Cerri, Werner Andrejewski, Giselher Franzmann, Peter Denkinger
  • Patent number: 7138480
    Abstract: This invention relates to a process for the preparation of a 3-hydroxycarboxylic acid from a 3-hydroxynitrile. More specifically, 3-hydroxyvaleronitrile is converted to 3-hydroxyvaleric acid in high yield at up to 100% conversion, using as an enzyme catalyst 1) nitrile hydratase activity and amidase activity or 2) nitrilase activity of a microbial cell. 3-Hydroxyvaleric acid is used as a substitute for ?-caprolactone in the preparation of highly branched copolyester.
    Type: Grant
    Filed: March 3, 2003
    Date of Patent: November 21, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Michael G. Bramucci, Robert Dicosimo, Robert Fallon, John E. Gavagan, Frank Herkes, Lech Wilczek
  • Patent number: 6916547
    Abstract: Novel multifunctional unsaturated polyester polyols, UV-curable top coat formulations including these polyols, and a one-step process for preparing these polyols, are disclosed. Surface coverings and surface covering components including these top coat formulations are also disclosed. The polyols are generally formed by the ring opening polymerization of a lactone with a compound of the formula (R1)aR(OH)b, where a+b>2. R1 is a double bond-containing moiety such as allyl, vinyl, vinylidene, vinyl ether, acrylate, and the like. R is generally an alkyl, aryl, aralkyl, alkaryl, ether or ester group, including substituted versions thereof. R can be a polymer, including polymers with a plurality of functional groups. Examples of lactone groups which can be used include caprolactone, lactide and glycolide.
    Type: Grant
    Filed: February 1, 2002
    Date of Patent: July 12, 2005
    Assignee: AWI Licensing Company
    Inventors: Dong Tian, Jeff S. Ross
  • Patent number: 6881785
    Abstract: An aqueous dispersion based on an amorphous unsaturated polyester resin obtained by polycondensing a mixture of Dicidol isomers and one or more saturated and/or unsaturated dicarboxylic acids.
    Type: Grant
    Filed: December 22, 2003
    Date of Patent: April 19, 2005
    Assignee: Degussa AG
    Inventors: Patrick Glöckner, Martina Ortelt, Werner Andrejewski, Alessandro Cerri, Lutz Mindach, Stephan Kohlstruk
  • Patent number: 6881818
    Abstract: Allyletherester monomers to be used as an intermediate product for the production of graft copolymers and/or their salts for use as cement dispersants are prepared by an esterification reaction of ?-allyl-?-hydroxy-polyoxyalkylene refined so as to have peroxide value less than 5.0 meq/kg and aliphatic monocaboxylic acid under a specified condition in the absence of solvent and in the presence of an antioxidant.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: April 19, 2005
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Mitsuo Kinoshita, Shinji Tamaki
  • Patent number: 6861495
    Abstract: This invention relates to rapid drying lacquers that are particularly useful for automotive OEM refinish applications. The lacquer includes a novel highly branched copolyester polyol. This invention is also directed to a process for producing coatings from the rapid drying lacquers. These lacquers are especially useful in providing for chip and humidity resistant coatings having improved adhesion.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: March 1, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert John Barsotti, Carl Brent Douglas, Renee Jeanne Kelly, Lech Wilczek
  • Patent number: 6858314
    Abstract: A brominated unsaturated polyester resin containing a hydroxyl value of about 35 or less and a hydroxyl acid molar ratio of about 2:1 to about 1:4. The brominated unsaturated polyester resin is prepared from a polyfunctional carboxylic acid, a monocarboxylic acid, and a polyfunctional glycol or alcohol that contains bromine under polyester esterification reaction conditions. The brominated unsaturated polyester resin can be incorporated into a resin composition that also contains vinyl monomer. The invention is also directed to a method of making a brominated unsaturated polyester resin, and to castings, coatings, and laminate panels containing cured brominated unsaturated polyester resin compositions of the invention.
    Type: Grant
    Filed: October 22, 2002
    Date of Patent: February 22, 2005
    Assignee: Ashland, Inc.
    Inventor: Danny George Hartinger
  • Patent number: 6838515
    Abstract: The invention relates to a process for the preparation of esters of (meth)acrylic acid by (trans)esterifying (meth)acrylic acid or its ester derivatives with monohydric or polyhydric alcohols in the presence of an acidic (trans)esterification catalyst, wherein said process after the formation of the esters of (meth)acrylic acid further comprises reacting remaining acid groups with one or more component(s), wherein at least one component forms with at least said catalyst an ester compound not having a ?-hydroxy group or forms an amid compound. The component that reacts with the acidic (trans)esterification catalyst preferably is selected from the group consisting of an oxetane component or derivative, an ortho-ester component, an alcohol component or any mixture thereof.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: January 4, 2005
    Assignee: DSM IP Assets B.V.
    Inventors: Franciscus J.M. Derks, Michael A.C. Van Dijck
  • Patent number: 6828411
    Abstract: A one-step polymerization process, leading directly to highly branched polyesters with unsaturated, either acrylate or sorbate end groups is described, which is based on the Diels-Alder reaction of polyfunctional sorbic esters with acrylates in defined ratios. A preferred embodiment of the invention is the Diels-Alder polymerization in aqueous emulsion.
    Type: Grant
    Filed: February 21, 2003
    Date of Patent: December 7, 2004
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Rainer Bruno Frings, Gerwald F. Grahe, Ou Shibata
  • Patent number: 6808788
    Abstract: The strength of wood composites, including hybrid composites comprising wood members bonded to reinforced polyester members, is improved by modifying the polyester components with a polyisocyanate. Wood composites adhesively bonded with polyester resins modified according to this invention are particularly desirable for use in applications where exterior exposure is contemplated.
    Type: Grant
    Filed: May 17, 2002
    Date of Patent: October 26, 2004
    Assignee: The University of Maine
    Inventor: Ben R. Bogner
  • Patent number: 6740193
    Abstract: In accordance with the present invention, there are provided gem-diesters and epoxidized derivatives thereof. When cured, thermosets comprising invention gem-diesters and epoxidized derivatives thereof have thermally and/or chemically labile gem-diester groups interspersed throughout the crosslinked network. Thus, thermosets based on invention gem-diesters and epoxidized derivatives thereof can be easily reworked thermally or chemically by treatment with dilute acidic or basic solutions. Further provided by the present invention are adhesive compositions comprising invention gem-diesters and epoxidized derivatives thereof.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: May 25, 2004
    Assignee: Henkel Corporation
    Inventors: John G. Woods, Jianzhao Wang, Jean M. J. Fréchet
  • Patent number: 6699945
    Abstract: A formaldehyde free co-binder solution formed by using a polyol to crosslink polycarboxylic acid and a polyacid monomer is provided. In forming the co-binder solution, the polyacid monomer and the polyol are mixed in any conventional device with heat and agitation for a period of time sufficient for the chemicals to react and form a reaction product. The resultant product is then admixed with polycarboxylic acid to form a co-binder solution. In a preferred embodiment, the polyacid is maleic anhydride and the polyol is triethanolamine.
    Type: Grant
    Filed: December 3, 2002
    Date of Patent: March 2, 2004
    Assignee: Owens Corning Fiberglas Technology, Inc.
    Inventors: Liang Chen, Kathleen M. Bullock, William E. Downey, Michael T. Pellegrin, Yadollah Delaviz, Kevin Guigley, Harry B. Cline
  • Publication number: 20040019158
    Abstract: A high performance UPR (unsaturated polyester resin) is disclosed. The UPR comprises recurring units of phthalic anhydride, 2-methyl-1,3-propanediol, and maleic anhydride. It has a fumarate/maleate ratio 85/15 or greater. It has a bi- or multi-modal molecular weight distribution. A high molecular weight portion of the UPR has a peak molecular weight (Mp) 50,000 or greater. It has a weight average molecular weight (Mw) 15,000 or greater. An ortho UPR of the invention performs as well as or better than traditional iso UPR.
    Type: Application
    Filed: July 29, 2002
    Publication date: January 29, 2004
    Inventors: Lau S. Yang, Paul Malcolm Puckett
  • Patent number: 6660398
    Abstract: The invention concerns powder thermosetting coating compositions comprising (a) an amorphous polyester containing carboxyl groups, rich in isophthalic acid and neopentylglycol, optionally branched with a polycarboxylic acid or a polyol containing at least three functional groups; (b) a semicrystalline polyester containing carboxyl groups prepared from one or several saturated aliphatic dicarboxylic acids with linear chain, and from a saturated aliphatic diol with linear or cyclic chain optionally branched with a polycarboxylic acid or with a polyol containing at least three functional groups, and having a melting point (Tm) of at least 40° C. and an acid value of 5 to 50 mg of KOH/g, and (c) a cross-linking agent. Said compositions are useful for preparing powder paints and varnishes providing excellent quality coatings whereof the brilliance, measured at an angle of 60°, according to the ASTM D 523 standard is always less than 50%, that is half-gloss or matt coatings.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: December 9, 2003
    Assignee: UCB, S.A.
    Inventors: Luc Moens, Kris Buysens, Daniel Maetens
  • Patent number: 6660810
    Abstract: The present invention relates to a non crosslinked block polymer. It also relates to a process for the preparation thereof and to the use thereof particularly in pharmaceutical compositions. The block polymer according to the invention contains sequences of polyethylene glycol linked to sequences of polyester and/or polycarbonate. The polyester sequences are selected in particular from polyfumarate, polymaleate and polysuccinate sequences.
    Type: Grant
    Filed: December 20, 2000
    Date of Patent: December 9, 2003
    Assignee: Debio Recherche Pharmaceutique SA
    Inventors: Paolo Ferruti, Piero Orsolini
  • Patent number: 6653435
    Abstract: A nonlinear crystalline polyester obtained by polycondensing monomers containing trivalent or higher polyvalent monomers selected from the group consisting of trihydric or higher polyhydric alcohols and tricarboxylic or higher polycarboxylic acid compounds in an amount of from 0.1 to 20 mol % of all monomers used for polycondensation.
    Type: Grant
    Filed: September 28, 2000
    Date of Patent: November 25, 2003
    Assignee: Kao Corporation
    Inventors: Katsutoshi Aoki, Takashi Yamaguchi
  • Patent number: 6639046
    Abstract: The present invention relates to a composition comprising: a compound comprising two or more olefinically unsaturated groups comprising at least on electron-withdrawing functionality linked to a carbon atom of the unsaturated bond; a compound comprising at least two mercapto-functional groups; and a catalyst comprising at least one, optionally blocked, NH-group. The invention further relates to a method for the application of the composition and to the use of the composition as a coating composition or an adhesive.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: October 28, 2003
    Assignee: Akzo Nobel N.V.
    Inventor: Joseph Theodorus Maria Van Dijk
  • Publication number: 20030175222
    Abstract: The present invention provides biodegradable polyesters based on lower hydroxy acids and hydroxy fatty acids. The resulting polyesters are useful as cosmetic vehicles for sunscreens, skin lotions and by themselves are also useful as milder skin exfoliants.
    Type: Application
    Filed: March 17, 2003
    Publication date: September 18, 2003
    Applicant: ETHOX CHEMICALS LLC
    Inventors: Paul David Weipert, Bharat B. Desai
  • Patent number: 6617395
    Abstract: A low tack, low VOC gel coat is disclosed comprising a unsaturated polyester resin derived from maleic anhydride and up to about 30% of an organic solvent. The resin is characterized by: a viscosity of less than or equal to about 1750 cp at 70% NVM in styrene; a glass transition temperature greater than or equal to about 11° C.; and a weight average molecular weight less than or equal to about 6,050. A process for making such a gel coat is also disclosed.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: September 9, 2003
    Assignee: Cook Composites & Polymers Co.
    Inventors: Ming Yang Zhao, L. Scott Crump, Chih-Pin Hsu, Erwoan Pezron
  • Patent number: 6521716
    Abstract: A coating, adhesive or sealant composition curable by Michael reaction comprises (A) a Michael acceptor which is a compound or polymer containing at least two activated olefinic double bonds and (B) a Michael donor which is a compound or polymer containing at least two nucleophilic groups. The double bonds of the Michael acceptor (A) are activated by two adjacent electron-withdrawing groups. Alternatively or additionally, the Michael donor (B) contains &bgr;-ketoamide, enamine carboxylate, enamine amide, pyrazolone, isoxazolone, hydantoin, rhodanine, thio-substituted unsaturated ester, thio-substituted lactone or phosphonite or phosphinite ester groups. More rapid ambient temperature curing is achieved.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: February 18, 2003
    Assignee: Akzo Nobel N.V.
    Inventor: Jonathan Stuart Leake
  • Publication number: 20020103329
    Abstract: The invention relates to a powder paint binder-composition comprising a polymer that contains endomethylene tetrahydrophthalic acid units and a crosslinker.
    Type: Application
    Filed: November 30, 2001
    Publication date: August 1, 2002
    Applicant: DSM N.V.
    Inventors: Fokeltje A. Koldijk, Eimbert G. Belder, Coenraad M. Gehrels, Tosko A. Misev
  • Patent number: 6423816
    Abstract: The present invention relates to polyester polyols having a hydroxyl number of 60 to 400, which are esterification products of a) an alcohol component containing one or more aliphatic or cycloaliphatic alcohols having at least 3 hydroxyl groups and 3 to 8 carbon atoms with b) a carboxylic acid component containing itaconic acid, maleic acid, their anhydrides and/or fumaric acid, provided that at least 10 mole % of either component a) or component b) is an aliphatic or cycloaliphatic, saturated or unsaturated monoalcohol or monocarboxylic acid having 1 to 18 carbon atoms. The present invention also relates to two-component polyurethane coating compositions containing these polyester polyols and lacquer polyisocyanates as the binder and to their use for coating substrates, in particular automotive substrates.
    Type: Grant
    Filed: January 4, 1996
    Date of Patent: July 23, 2002
    Assignee: Bayer Aktiengesellscahft
    Inventors: Christian Wamprecht, Michael Sonntag
  • Patent number: 6384181
    Abstract: A method of producing a polyamide resin by reacting with at least one diamine compounds at least one linear polyester resin consisting of at least one dicarboxylic acid component and at least one diol component and having an intrinsic viscosity of not less than 0.2 dl/g, so that the at least one diol component of the linear polyester resin is substituted by the diamine compound, resulting in the polyamide resin as a reaction product, wherein the improvement comprises: at least one of a carboxylic acid-activator and an inorganic salt being present in a reaction system of the linear polyester resin and the diamine compound.
    Type: Grant
    Filed: June 28, 2000
    Date of Patent: May 7, 2002
    Assignee: M & S Research and Development Co., Ltd.
    Inventor: Seiko Nakano
  • Patent number: 6361700
    Abstract: A polyester is provided which facilitates the separation of blood into light and heavy phases via centrifugation in a blood collection vessel. The polyester is useful as a component of a partitioning composition formulated to have appropriate specific gravity to be positioned intermediate the light and heavy blood phases during centrifugation. The polyester composition can be prepared with relative ease compared to prior art polyesters useful in blood partitioning compositions. The polyesters of this invention comprise a dicarboxylic acid member, a polymeric fatty acid, a diol member and a moiety having at least one polymerizable carbon-carbon double bond and at least one functional group capable of reacting with the ends of the polyester chain. The polyesters have a lower viscosity when synthesized and are later cured to increase their viscosity to the desired level.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: March 26, 2002
    Assignee: Cognis Corporation
    Inventors: Jeffrey A. Gates, Michael S. Sharp
  • Patent number: 6337137
    Abstract: The invention relates to a powder paint composition comprising a polymer that contains endomethylene tetrahydrophthalic acid units and a crosslinker. The polymer is obtained by preparing an unsaturated polymer in a first step, which then reacts with cyclopentadiene at a temperature between 160 ° C and 220 ° C in a second step. The polymer preferably contains more than 10 wt.% endomethylene tetrahydrophthalic acid units and is preferably an unsaturated polymer.
    Type: Grant
    Filed: October 14, 1999
    Date of Patent: January 8, 2002
    Assignee: DSM N.V.
    Inventors: Fokeltje A. Koldijk, Eimbert G. Belder, Coenraad M. Gehrels, Tosko A. Misev
  • Patent number: 6326435
    Abstract: The polyester resin composition of the present invention comprises (A) a thermoplastic polyester resin, (B) an olefinic polymer modified with at least one member selected from the group consisting of an unsaturated carboxylic acid and its derivative, and (C) an aliphatic ester having a molecular weight of 400 to 1,000. The polyester resin of the present invention may comprises: (D) a flame retardant, (E) an inorganic flame retardant auxiliary, and others. The thermoplastic polyester resin composition is useful for the fabrication of sliding members (particularly, gears). Polyester resin compositions with improved dimensional accuracy and sliding properties and shaped articles formed therefrom can be obtained from the resin composition of the present invention.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: December 4, 2001
    Assignee: Polyplastics Co., Ltd.
    Inventors: Katsunori Takayama, Kazuhito Kobayashi
  • Publication number: 20010009956
    Abstract: A polyester is provided which facilitates the separation of blood into light and heavy phases via centrifugation in a blood collection vessel. The polyester is useful as a component of a partitioning composition formulated to have appropriate specific gravity to be positioned intermediate the light and heavy blood phases during centrifugation. The polyester composition can be prepared with relative ease compared to prior art polyesters useful in blood partitioning compositions. The polyesters of this invention comprise a dicarboxylic acid member, a polymeric fatty acid, a diol member and a moiety having at least one polymerizable carbon-carbon double bond and at least one functional group capable of reacting with the ends of the polyester chain. The polyesters have a lower viscosity when synthesized and are later cured to increase their viscosity to the desired level.
    Type: Application
    Filed: February 20, 2001
    Publication date: July 26, 2001
    Inventors: Jeffrey A. Gates, Michael S. Sharp
  • Patent number: 6248844
    Abstract: A polyester is provided which facilitates the separation of blood into light and heavy phases via centrifugation in a blood collection vessel. The polyester is useful as a component of a partitioning composition formulated to have appropriate specific gravity to be positioned intermediate the light and heavy blood phases during centrifugation. The polyester composition can be prepared with relative ease compared to prior art polyesters useful in blood partitioning compositions. The polyesters of this invention comprise a dicarboxylic acid member, a polymeric fatty acid, a diol member and a moiety having at least one polymerizable carbon—carbon double bond and at least one functional group capable of reacting with the ends of the polyester chain. The polyesters have a lower viscosity when synthesized and are later cured to increase their viscosity to the desired level.
    Type: Grant
    Filed: June 4, 1999
    Date of Patent: June 19, 2001
    Assignee: Henkel Corporation
    Inventors: Jeffrey A. Gates, Michael S. Sharp
  • Patent number: 6239200
    Abstract: A composition suitable for use as a starting material for preparing a high molecular weight polyester through melt polymerization and solid state polymerization is disclosed. The composition comprises (a) a dicarboxylic acid or diester; (b) a glycol; (c) 0.1-5 mol %, relative to said component (a), of a multifunctional acid and/or a multifunctional alcohol; and (d) 0.05-5 wt %, based on the weight of the polyester, of a hindered phenolic aromatic phosphate. A process for preparing a high molecular weight polyester utilizing the above composition is also disclosed.
    Type: Grant
    Filed: March 14, 2000
    Date of Patent: May 29, 2001
    Assignee: Industrial Technology Research Institute
    Inventors: Hsin-Ching Kao, Lee-Hua Chen, Chi-Lang Wu, Jinn-Jong Wong, Szu-Yuan Chan, Sheng-Te Yang
  • Patent number: 6214898
    Abstract: New modified polyester resin/organic peroxide systems for powder coatings which are applicable to temperature sensitive and metallic substrates include (a) a polyester resin which is a hydroxylated or carbonxylated polyester with unsaturation in its chain, and (b) an organic peroxide with a minimum curing temperature of between 140° and 190° C.; the relative proportions of resin and organic peroxides being 55-60% by weight of resin based on the final composition and 0.5-3.0 by weight of organic peroxide based on the final formulation. These systems find their main application in the manufacture of powder coatings for the coating of temperature sensitive substrates like plastics and metallic substrates, especially aluminum substrates, using the systems currently existing in industry.
    Type: Grant
    Filed: October 2, 1998
    Date of Patent: April 10, 2001
    Assignee: Herberts Gesellschaft mit beschränkter Haftung
    Inventor: José Luis Diloy Barrio
  • Patent number: 6171700
    Abstract: A curable composite material composition comprising (A) a polymerizable unsaturated compound, (B) a fiber reinforcing material and/or fiber, and (C) a polymerization initiator comprising an organic boron compound represented by the general formula (1) wherein R1, R2, R3 and R4 each independently represent an alkyl, aryl, allyl, aralkyl, alkenyl, alkynyl, silyl or heterocyclic group, a halogen atom, or a substituted alkyl, substituted aryl, substituted allyl, substituted aralkyl, substituted alkenyl, substituted alkynyl or substituted silyl group, and Z+ represents a cation, and an acidic compound, as well as a curing process for the curable composite material composition which includes irradiating and/or heating the curable composite material composition.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: January 9, 2001
    Assignees: Showa Denko Kabushiki Kaisha, Showa Highpolymer., Ltd.
    Inventors: Shuichi Sugita, Hirotoshi Kamata, Tomio Yamamoto, Kazuo Ohtani, Hidetake Sendai
  • Patent number: 6162891
    Abstract: The present invention relates to polyester polyols having hydroxyl numbers of 175 to 520 which are the reaction products ofa) 50 to 60 mole % of a polyol component containing(i) 0 to 39 mole % of one or more dihydric aliphatic or cycloaliphatic alcohols having at least 2 carbon atoms other than neopentyl glycol,(ii) 20 to 59 mole % of neopentyl glycol and(iii) 41 to 80 mole % of one or more at least trihydric aliphatic alcohols containing at least 3 carbon atoms andb) 40 to 50 mole % of a dicarboxylic acid component containing(iv) 0 to 60 mole % of one or more aliphatic or cycloaliphatic, saturated or unsaturated dicarboxylic acids or their anhydrides having at least 2 carbon atoms other than fumaric acid, itaconic acid and maleic acid or their anhydrides and(v) 40 to 100 mole % of one or more of fumaric acid, itaconic acid, maleic acid or their anhydrides,wherein the percentages set forth in a) and b) each add up to 100.
    Type: Grant
    Filed: December 9, 1994
    Date of Patent: December 19, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Michael Sonntag, Jurgen Meixner
  • Patent number: 6162840
    Abstract: The invention concerns the use of monomer-free saturated or unsaturated polyester resins or mixtures of saturated and unsaturated polyester resins containing structural units of general formulae (I) and/or (II), in which n=1-10, as impregnation, sealing and coating compounds for electrical engineering and electronic components and for carrier substances for flat insulating materials.
    Type: Grant
    Filed: July 6, 1998
    Date of Patent: December 19, 2000
    Assignee: Dr. Beck + CO.AG
    Inventors: Rainer Blum, Thomas Loerzer, Gunther Hegemann, Manfred Eichhorst
  • Patent number: 6150458
    Abstract: The present invention relates to a process for preparing (meth)acrylic acid esters by1) reacting hydroxyl group-containing polyethers, polyesters or polyester ethers with (meth)acrylic acid in the presence of an acid esterification catalyst and a solvent to form (meth)acrylic acid esters, and2) reacting the acid esterification catalyst acid and unreacted (meth)acrylic acid with a compound containing two or more epoxide groups in the presence of the solvent used in step 1).
    Type: Grant
    Filed: July 21, 1999
    Date of Patent: November 21, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jan Weikard, Wolfgang Fischer
  • Patent number: 6143801
    Abstract: A method of forming an esterification product Comprises providing (1) a material selected from the group consisting of ester monomers, ester oligomers, ester polymers, and mixtures thereof, and (2) a catalyst selected from the group consisting of: ##STR1## and mixtures thereof. wherein D is selected from the group consisting of carbon and silicon; Q is selected from the group consisting of O, S, and NR; M is selected from the group consisting of sodium, lithium, potassium, rubidium, and cesium; R, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R', R", and R'" are each independently selected from the group consisting of H, O, halogen, Si, N, S, P, C.sub.1 to C.sub.20 linear or branched alkyl, C.sub.3 to C.sub.10 cycloalkyl, and aromatic; and reacting the material in the presence of the catalyst to form an esterification product.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: November 7, 2000
    Assignee: The University of North Carolina at Chapel Hill
    Inventors: Michel R. Gagne', Michael R. Korn
  • Patent number: 6127080
    Abstract: A process for the preparation of an unsaturated polyester which comprises (i) reacting an organic diol with a cyclic akylene carbonate in the presence of a first catalyst to thereby form a polyalkoxy diol, and (ii) optionally adding thereto a further amount of cyclic alkylene carbonate in the presence of a second catalyst, and (iii) subsequently polycondensing the resulting mixture with a dicarboxylic acid.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: October 3, 2000
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Daniel A. Foucher, J. Stephen Kittelberger, Dongming Li, Marko D. Saban, Alan E. J. Toth, Robert D. Bayley
  • Patent number: 6114458
    Abstract: A branched radial block copolymer including the reaction product of a dendritic macromolecular initiator, and one or more chain extending monomers.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: September 5, 2000
    Assignee: International Business Machines Corporation
    Inventors: Craig Jon Hawker, James Lupton Hedrick, Olof Mikael Trollsas
  • Patent number: 6110264
    Abstract: A phase change ink carrier composition comprising at least one anhydride/alcohol inclusive reaction product.
    Type: Grant
    Filed: June 25, 1998
    Date of Patent: August 29, 2000
    Assignee: Xerox Corporation
    Inventors: Jeffrey H. Banning, Clifford R. King, Donald R. Titterington
  • Patent number: 6093792
    Abstract: This invention relates to high molecular weight bioresorbable copolymers constructed to be useful for specific applications in the biomedical arts. Also provided is a new cyclic carbonate monomer, and copolymers containing the new monomers.
    Type: Grant
    Filed: September 16, 1998
    Date of Patent: July 25, 2000
    Assignee: University of Massachusetts
    Inventors: Richard A. Gross, Xianhai Chen, Stephen P. McCarthy
  • Patent number: 6063827
    Abstract: A process for the preparation of an unsaturated polyester which comprises (i) reacting an organic diol with a cyclic akylene carbonate in the presence of a first catalyst to thereby form a polyalkoxy diol, and (ii) optionally adding thereto a further amount of cyclic alkylene carbonate in the presence of a second catalyst, and (iii) subsequently polycondensing the resulting mixture with a dicarboxylic acid.
    Type: Grant
    Filed: July 22, 1998
    Date of Patent: May 16, 2000
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Daniel A. Foucher, J. Stephen Kittelberger, Dongming Li, Marko D. Saban, Alan E. J. Toth, Robert D. Bayley
  • Patent number: 6034204
    Abstract: Condensation products of basic amino acids with copolymerizable compounds which are obtainable by condensing(a) a basic amino acid selected from the group consisting of lysine, arginine, ornithine, tryptophane and mixtures thereof,(b) a copolymerizable compound selected from the group consisting of saturated monobasic carboxylic acids, unsaturated mono-basic carboxylic acids, polybasic carboxylic acids, carboxylic acid anhydrides, diketenes, monohydroxycarboxylic acids, polyhydroxycarboxylic acids and mixtures thereof, and optionally(c) at least one compound selected from the group consisting of amines, lactams, non-proteinogenic acids, alcohols, alkoxylated alcohols, alkoxylated amines, amino sugars, carbohydrates and sugar carboxylic acidsin a molar ratio of (a):(b) of from 100:1 to 1:1 at a temperature of at least 120.degree. C., and a process for the production of said condensation products by condensing compounds (a) and (b) and optionally (c) at a temperature of from 120.degree. to 300.degree. C.
    Type: Grant
    Filed: August 7, 1998
    Date of Patent: March 7, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernhard Mohr, Dieter Boeckh, Ralf Norenberg, Sherri Randall, Rajan Panandiker, Eugene Paul Gosselink, LeeAnn Luipold
  • Patent number: 6015551
    Abstract: The disclosure relates to a copolymer obtainable by radically initiated polymerization of the following: A) 70-99.9 wt. % an olefinically unsaturated C.sub.3 -C.sub.5 monocarboxylic acid, an olefinically unsaturated C.sub.4 -C.sub.8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids; with B) 0.1-30 wt. % one or more multiply olefinically unsaturated carboxylic acid derivatives of formula (I)Z--Y--(CHR.sup.3 --CH.sub.2 --X).sub.n --R.sup.4 (I)in which Z is a vinyl or allyl group or structure (a), ##STR1## R.sup.1, R.sup.2 are hydrogen or methyl, R.sup.3 is hydrogen, methyl or ethyl, R.sup.4 is a singly or multiply olefinically unsaturated alkenyl or cycloalkenyl group or a singly or doubly olefinically unsaturated arylalkylene group, X is oxygen or NH, Y is oxygen, NH or N-alkyl, n is a number between 0 and 50; and C) 0-29.9 wt. % other copolymerizable monomers. The proposed copolymer can be used as a thickener or dispergent for aqueous systems.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: January 18, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Hans-Ulrich Wekel, Axel Sanner, Karin Sperling
  • Patent number: 6001910
    Abstract: A remoistenable hot melt adhesive composition comprising (i) 25 to 80% by weight of a sulfonated polyester;(ii) 3 to 40% by weight of an anionic or cationic plasticizer;(iii) 0 to 40% by weight of a polar tackifier;(iv) 0 to 3% by weight of an antioxidant; and(v) 10 to 35% by weight of a polar wax; and(vi) optionally 0 to 30% nonionic plasticizer, wherein the total of (i)-(vi) to equal 100% by weight.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: December 14, 1999
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Mitchell J. Blumenthal, Charles W. Paul, Matthew L. Sharak
  • Patent number: 6001891
    Abstract: A biodegradable aliphatic polyester elastomer which has rubber-like elasticity, hardness of 80 or less in accordance with ASTM D 676-58T, and elastic modulus from 1.times.10.sup.5 Pa to 1.times.10.sup.8 Pa at 25.degree. C., and decomposes with ease in the natural environment, under composting conditions or under hydrolysis conditions. The biodegradable aliphatic elastomer can be obtained by crosslinking aliphatic polyester containing aliphatic unsaturated polybasic acid as a polymer constituting ingredient and having a weight average molecular weight of 15,000 or more.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: December 14, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Chojiro Higuchi, Masatoshi Takagi, Takeshi Kashima, Masanobu Ajioka, Yuji Terado
  • Patent number: 5998568
    Abstract: A method for making a polyester resin comprises reacting a first polyfunctional alcohol or polyfunctional thiol and a carbonate in the presence of a catalyst to form an alkoxylated intermediate. The catalyst comprises: (1) a metal, a salt of a metal, or mixtures thereof and (2) a quaternary ammonium salt, a tertiary amine, an imidazole, or mixtures thereof. The alkoxylated intermediate is then reacted with a polyfunctional organic acid or anhydride thereof to form the polyester resin.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: December 7, 1999
    Assignee: Reichhold, Inc.
    Inventors: Hildeberto Nava, Karin F. Nelson-Baron
  • Patent number: 5981787
    Abstract: Novel peroxyoxalate compositions of Structure A, ##STR1## and use of the novel monoperoxyoxalates of Structure A as initiators for polymerizing ethylenically unsaturated monomers and for curing of unsaturated polyester resins are disclosed.
    Type: Grant
    Filed: October 10, 1997
    Date of Patent: November 9, 1999
    Assignee: Elf Atochem North America, Inc.
    Inventors: Jose Sanchez, Daryl L. Stein
  • Patent number: 5976706
    Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: November 2, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Albert Ilya Yezrielev, Konstantinos R. Rigopoulos, Richard William Ryan, Karen K. Kuo, George Andrew Knudsen
  • Patent number: 5959067
    Abstract: The current invention relates to an alkyd resin particularly useful in high-solids coating compositions. The alkyd resin comprises the reaction product of an unsaturated fatty acid, a polyol, and the adduct of an .alpha.,.beta.-unsaturated dicarboxylic acid to an unsaturated fatty acid wherein the resin containsa) about 5 to about 40 weight % of the adduct of an .alpha.,.beta.-unsaturated dicarboxylic acid to an unsaturated fatty acid,b) about 50 to about 90 weight % of an unsaturated fatty acid which is not part of an adduct,c) about 8 to about 18 weight % of a polyol free from carboxylic groups,d) about 1 to about 30 weight % of an at least two hydroxyl groups-containing monocarboxylic acid,e) optionally, up to about 10 weight % of a dicarboxylic and/or a tricarboxylic acid, andf) optionally, up to 15 weight % of one or more monomers other than the monomers (a) through (e).Also disclosed is their use in coating compositions, particularly high-solids coating compositions having a VOC of less than 170.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: September 28, 1999
    Assignee: Akzo Nobel N.V.
    Inventors: Petrus Josephus Bakker, Dick Boekee
  • Patent number: 5932344
    Abstract: A cement retarder which comprises a saturated or unsaturated polyester obtained by a reaction of a polycarboxylic acid component comprising a polycarboxylic acid having 2 to 6 carbon atoms in the main chain or its derivative, and a polyol component containing a polyhydric alcohol having 2 to 4 carbon atoms or its condensate, wherein:(a) the saturated polyester has a weight average molecular weight of about 300 to about 50,000; or(b) the unsaturated polyester has a weight average molecular weight of about 500 to about 25,000; or(c) the polyhydric alcohol used to obtain the saturated or unsaturated polyester is a condensate of a C.sub.2-4 alkylene glycol; or(d) the saturated polyester is a polyester obtained by the use of a condensate of a C.sub.2-4 alkylene glycol and has a weight average molecular weight of about 300 to about 50,000; or(e) the unsaturated polyester is a polyester obtained by the use of a condensate of a C.sub.
    Type: Grant
    Filed: October 7, 1996
    Date of Patent: August 3, 1999
    Assignee: Daicel-Huels Ltd.
    Inventors: Yoshiyuki Ikemoto, Toru Ikuta