Abstract: Disclosed is a compound represented by the following general formula (1), wherein, in the formula, M1 represents Sb or Bi; X1 and X2 each independently represent a sulfur atom or an oxygen atom; R1 represents a divalent organic group; Y1 represents a monovalent inorganic or organic group; a represents a number of 1 or 2; b represents a number of 0 or an integer of not less than 1; c represents an integer of not less than 1 and not more than d; d represents a valence of M1; when d?c is not less than 2, a plurality of Y1s each independently represent a monovalent inorganic or organic group and may be bonded to each other to form an M1-containing ring; and e represents a number of 0 or an integer of not less than 1.
Abstract: Hydrolytically and thermo-oxidatively stable sulfonated polyarylenes include the structural element —X—Ar(SO3M)n-Y—. The aromatic ring carrying the sulfonic acid group is substituted exclusively by electron-acceptor bridge groups X and Y and, if applicable, by other non-electron-donor substituents. Their synthesis and application are also included.
Type:
Grant
Filed:
March 7, 2006
Date of Patent:
January 8, 2013
Assignee:
Max-Planck-Gesellschaft zur Forderung der Wissenschaften e.V.
Inventors:
Michael Schuster, Klaus-Dieter Kreuer, Henrik Thalbitzer Andersen, Joachim Maier
Abstract: An optical material is provided that has a high transmittance, a high refractive index, a low Abbe constant, a high secondary dispersion property, and a low water absorption rate. The optical material includes a polymer of a mixture which contains: a sulfur-containing compound represented by the following general formula (1): a sulfur-containing compound represented by the following general formula (2): and an energy polymerization initiator, in which a content of the sulfur-containing compound represented by the chemical formula (2) is 10% by weight or more to 60% by weight or less, an Abbe constant (?d) of the polymer of the mixture satisfies 18<?d<23, and a secondary dispersion property (?g,F) thereof satisfies 0.68<?g,F<0.69.
Abstract: A polymer represented by the following Formula 1, and a membrane-electrode assembly and a fuel cell system including the polymer: In the above Formula 1, definitions of the substituents are the same as in described in the detailed description.
Type:
Grant
Filed:
May 8, 2009
Date of Patent:
January 1, 2013
Assignee:
Samsung SDI Co. Ltd.
Inventors:
Sung-Guk An, Sung-Yong Cho, Sang-Il Han, Kie Hyun Nam
Abstract: To provide a structure material having excellent mechanical characteristics and a functional material having excellent regularity, provided are a polymer alloy which is composed of at least two components of thermoplastic resins and of which the structure can be controlled finely and evenly dispersed and a production method of the polymer alloy. With respect to a polymer alloy composed of at least two or more components of thermoplastic resins, a precursor (A) of at least one thermoplastic resin among the thermoplastic resin components composing the polymer alloy is chemically reacted in the co-presence of the remaining thermoplastic resin component (B1) and/or a precursor (B2) of the thermoplastic resin component to induce spinodal decomposition, so that it is made possible to obtain a polymer alloy having excellent regularity and of which the structure is finely controllable and the structure is evenly dispersed.
Abstract: The present invention relates to a sulfonated poly(arylene ether) copolymer, a manufacturing method thereof and a polymer electrolyte membrane for fuel cell using the same.
Type:
Grant
Filed:
October 29, 2010
Date of Patent:
December 18, 2012
Assignee:
Hyundai Motor Company
Inventors:
Inchul Hwang, Ki Yun Cho, Dong Il Kim, Ju Ho Lee
Abstract: A method for producing a cyclic polyarylene sulfide, wherein a cyclic polyarylene sulfide is produced by heating a reaction mixture which is composed of at least a linear polyarylene sulfide (a), a sulfidizing agent (b), a dihalogenated aromatic compound (c) and an organic polar solvent (d). This method for producing a cyclic polyarylene sulfide is characterized in that not less than 1.25 liters of the organic polar solvent is used per 1 mole of the sulfur content in the reaction mixture. This method enables to efficiently produce a cyclic polyarylene sulfide, more specifically cyclic oligoarylene sulfide by an economical and simple process in short time.
Type:
Grant
Filed:
February 27, 2008
Date of Patent:
December 11, 2012
Assignee:
Toray Industries, Inc.
Inventors:
Shunsuke Horiuchi, Kohei Yamashita, Kayo Tsuchiya, Koji Yamauchi
Abstract: There is provided a method for producing a conductive polymer solution comprising: a freeze-drying step in which an aqueous conductive polymer solution containing a complex that includes a ?-conjugated conductive polymer and a polyanion is freeze dried to thereby obtain a solid complex; and a dispersion step in which an organic solvent having a water content of 4% by mass or less and an amine compound are mixed to the solid complex, followed by a dispersion treatment.
Abstract: The present invention provides an agent serving as oxidant and dopant in which it does not generate precipitates in a state of an alcohol solution for a certain period of time and the oxidizing power is not too strong. By using the same, the present invention provides a conductive polymer having a high conductivity and heat resistance. By using the same, the present invention provides a solid electrolytic capacitor reliable under a high temperature condition. The present invention provides an agent serving as oxidant and dopant for conductive polymer production, the agent serving as oxidant and dopant comprising: a ferric salt of acids comprising a benzene sulfonic acid derivative represented by formula (1) and sulfuric acid. “R” represents an alkyl or alkoxy group having a carbon number of 1 to 4. More than 90 mole % of the benzene sulfonic acid derivative have R at the para position with respect to the SO3H group. Sulfuric acid is contained at 0.05 to 1.5 mass % in the acids.
Abstract: The disclosed is a biodegradable copolymer, an amphiphilic diblock copolymer, composed of a hydrophilic segment and a hydrophobic segment. The hydrophilic segment is an endcapped PEG or derivatives thereof. The hydrophilic segment is a random polymer polymerized of lactone or cyclic C3-C6 molecule and lactic acid/glycolic acid. There is no coupling agent between the hydrophilic and hydrophobic segments, and the biodegradable copolymer is formed by one-pot ring-opening polymerization. The biodegradable copolymer can be dissolved in water to form a thermosensitive material having a phase transfer temperature of 25 to 50° C., thereby being applied to biological activity factor delivery, tissue engineering, cell culture and biological glue.
Type:
Grant
Filed:
November 23, 2010
Date of Patent:
November 13, 2012
Assignee:
Industrial Technology Research Institute
Abstract: Provided is a solid polymer electrolyte having increased heat resistance and high proton conductivity and a proton conductive membrane composed of the electrolyte. Also provided is a copolymer having a sulfonic acid group.
Abstract: A polymer semiconductor that includes a polythiophene having an Mn from about 1,000 to about 400,000 Daltons and derived from benzodithiophene monomer segments of Formula (1) and at least one divalent linkage providing compound selected from the group consisting of an aromatic or heteroaromatic electron acceptor compound X and an aromatic or heteroaromatic compound Y, wherein R1 and R2 are side chains independently selected from the group consisting of a hydrogen atom, a hydrocarbon group, a heteroatom and combinations thereof.
Type:
Grant
Filed:
January 19, 2010
Date of Patent:
November 6, 2012
Assignee:
Xerox Corporation
Inventors:
Anthony J. Wigglesworth, Yiliang Wu, Ping Liu, Nan-Xing Hu
Abstract: Provided are a polymerizable composition for giving a resin which has a high refractive index and low dispersion, and is especially excellent in impact resistance and tintability; and a resin and an optical component each obtained by curing the composition.
Abstract: A sulfonated copolymer including a crosslinking functional group and a fuel cell including a polymer composition of the same are provided. The sulfonated copolymer including a crosslinking functional group can remarkably reduce methanol crossover and maintain superior dimensional stability and ionic conductivity by reducing swelling.
Abstract: The present invention relates to a sulfonated poly(arylene ether) copolymer, a manufacturing method thereof and a polymer electrolyte membrane for fuel cell using the same.
Type:
Grant
Filed:
November 2, 2010
Date of Patent:
October 16, 2012
Assignee:
Hyundai Motor Company
Inventors:
Ju Ho Lee, Dong Ii Kim, Nak Hyun Kwon, Inchul Hwang
Abstract: Internal components of plasma reactors are composed of a toleratable, ceramic filled plasma-useful polymer such as a high temperature engineering thermoplastic, preferably a polyamideimide. The parts exhibit a low erosion rate upon exposure to plasma at low pressure.
Type:
Application
Filed:
April 11, 2011
Publication date:
October 11, 2012
Applicant:
QUADRANT EPP AG
Inventors:
Scott Howard Williams, Richard William Campbell, Stephan Glander
Abstract: The present invention is directed to a process for the cleavage of one or more starting polymers having thiocarbonylthio groups of the formula —S—(C?S)— into derived polymers having thiol end groups of the formula —SH. The process includes contacting the aforedescribed starting polymers, with a reagent having the formula Xa Yb, wherein Xa is a nucleophilic group and Yb is an extracting group that results in the starting polymer and a byproduct, which is then separated from the derived polymer by conventional separation processes. The derived polymer is free from any odor or color that is sometimes associated with the starting polymer and it can be used in making optical lenses, such as contact lenses.
Type:
Grant
Filed:
February 23, 2007
Date of Patent:
October 9, 2012
Assignee:
Commonwealth Scientific and Industrial Research Organisation
Inventors:
Graeme Moad, Ezio Rizzardo, San Hoa Thang
Abstract: A photovoltaic device with high photoelectric conversion efficiency includes an electron donating organic material for photovoltaic devices containing a conjugated polymer represented by formula (1): wherein R1 to R10 may be the same or different from each other and are each selected from the group consisting of hydrogen, an alkyl group, an alkoxy group and an aryl group; R11 and R12 may be the same or different from each other and are each selected from the group consisting of hydrogen, an alkyl group, an aryl group, a heteroaryl group and halogen; W, X, Y and Z may be the same or different from each other and are each selected from the group consisting of a single bond, an arylene group, a heteroarylene group, an ethenylene group, and an ethynylene group; m is 0 or 1; n is within a range of 1 to 1000.
Type:
Grant
Filed:
October 4, 2007
Date of Patent:
September 18, 2012
Assignee:
Toray Industries, Inc.
Inventors:
Daisuke Kitazawa, Jun Tsukamoto, Yukari Jo
Abstract: The invention relates to formulations comprising polythiophenes A) comprising at least one polythiophene containing recurring units of the general formula (I-a) and/or (I-b) and at least two further polymers, the use thereof and electroluminescent arrangements comprising hole-injecting layers comprising these formulations.
Type:
Grant
Filed:
January 19, 2007
Date of Patent:
August 28, 2012
Assignee:
Heraeus Precious Metals GmbH & Co. KG
Inventors:
Andreas Elschner, Knud Reuter, Peter Wilfried Loevenich
Abstract: This invention relates to a method of preparing poly(arylene sulfide) (PAS) from an iodo compound and a sulfur compound, and more particularly, to a method of preparing PAS, including adding a sulfur-containing polymerization terminator when PAS is produced using an iodo compound as an intermediate. Thereby, in final PAS, the residual iodine content may be maintained at the same level or decreased and other properties may be maintained at equal or superior levels, thanks to the use of the sulfur-containing polymerization terminator, which is much lower in price than conventional polymerization terminators.
Type:
Grant
Filed:
August 21, 2007
Date of Patent:
August 14, 2012
Assignee:
SK Chemicals Co., Ltd.
Inventors:
Young Rok Lee, Il Hoon Cha, Jun Sang Cho
Abstract: Disclosed herein are precursor polymers containing units of heteroaryls and units of Si, Sn, Ge, or Pb, methods of producing the precursor polymers, and applications utilizing these precursor polymers to prepare conductive polymers.
Abstract: A proton conducting hydrocarbon-based polymer has acid groups on side chains attached to the main chain, where the acid groups are between 7 and 12 atoms away from the main chain. Another polymer includes a semi-fluorinated aromatic hydrocarbon main chain and side chains that include at least one —CF2— group and an acid group. Another polymer includes an aromatic hydrocarbon main chain and side chains that include at least one —CH2-CF2— group and an acid group. Another aromatic polymer includes acid groups attached to both the main chain and the side chains where less than about 65 weight percent of the acid groups are attached to the side chains. Another aromatic polymer includes side chains attached to the main chain that include at least one aryl ring, and acid groups attached to both the main chain and to the aryl groups. Another polymer includes an aliphatic hydrocarbon main chain, side chains that include at least one deactivating aryl ring, and acid groups attached to the deactivating aryl rings.
Type:
Grant
Filed:
September 29, 2006
Date of Patent:
July 17, 2012
Assignee:
Battelle Memorial Institute
Inventors:
Ramanathan S. Lalgudi, Bhima R. Vijayendran, Jeffrey Cafmeyer, Jay R. Sayre
Abstract: A resin composition excellent in tintability and resin strength, a resin obtained by curing such a resin composition, and an optical component is provided. A polymerizable composition containing an isocyanate compound suitably used for transparent resin materials, at least one polythiol compound which may have one or more (poly)sulfide bonds in a molecule, and at least one polyhydroxy compound having two or more hydroxy groups in a molecule and/or at least one (poly)hydroxy(poly)mercapto compound having one or more hydroxy groups and one or more thiol groups is used.
Abstract: Disclosed are an oligomer and a phthalonitrile monomer having the formulas: M is a metal or H. The value n is an integer greater than or equal to 1 for the oligomer and greater than or equal to 0 for the phthalonitrile monomer. Ar1 and Ar2 are independently selected aromatic- or heterocyclic-containing groups. Ar1, Ar2, or both are heteroaromatic or heterocyclic groups containing a nitrogen, sulfur, or oxygen heteroatom. Also disclosed are thermosets and pyrolyzed materials made from the phthalonitrile monomer.
Type:
Grant
Filed:
November 12, 2009
Date of Patent:
July 17, 2012
Assignee:
The United States of America, as represented by the Secretary of the Navy
Abstract: Disclosed are water soluble polymeric reagents comprising the structure POLY-[Y—S—W]x, where POLY is a water soluble polymer; Y is a hydrocarbon-based spacer group, x is 1 to 25, and S—W is a thiol, protected thiol, or thiol-reactive derivative. Preferably, the water soluble polymer is a PEG polymer. Also disclosed are conjugates of such polymeric reagents with pharmaceutically relevant molecules, and methods of their formation and use.
Abstract: New thieno[3,4-b]pyrazine copolymers are prepared by reacting 5,7-functionalized thieno[3,4-b]pyrazines with substituted aromatics in the presence of solvents, bases and polymerization catalysts, the copolymers thus prepared being employed preferably in the production of photovoltaic cells.
Type:
Grant
Filed:
March 22, 2007
Date of Patent:
July 10, 2012
Assignees:
Thüringisches Institut für Textil-und Kunststoff-Forschung E.V., Friedrich Schiller Universität Jena
Inventors:
Steffi Sensfuss, Maher Al Ibrahim, Lars Blankenburg, Elisabeth Klemm, Raja Shahid Ashraf, Munazza Shahid
Abstract: A method for the synthesis of well-defined rod-coil block copolymers consisting of P3HT donor and C60 acceptor chromophores (P3HT-b-P(SxAy)-C60) in a molecular architecture is reported for use in bulk-heterojunction (BHJ) solar cells. In thin films of the resulting block copolymer, reproducible self-assembly into well-defined “nanofibrils” is observed. This is the first example of a block copolymer containing a C60 derivative that shows exclusively a nanofibrilar structure. A substantial improvement in device performance is achieved when the block copolymer is used as a “surfactant” for controlling the interface morphology of the P3HT:PCBM donor-acceptor phase domains within the composite.
Type:
Grant
Filed:
November 25, 2009
Date of Patent:
July 3, 2012
Assignee:
The Regents of the University of California
Abstract: Provided is a production process by which polyarylene sulfide can be obtained at a low temperature and in a short time, which production process is a process for producing polyarylene sulfide, comprising heating a cyclic polyarylene sulfide in the presence of a zero-valent transition metal compound. Examples of zero-valent transition metal compounds include complexes comprising, as metal species, nickel, palladium, platinum, silver, ruthenium, rhodium, copper, silver, and gold, and heating is preferably carried out in the presence of 0.001 to 20 mol % of the zero-valent transition metal compound based on sulfur atoms in the cyclic polyarylene sulfide.
Type:
Application
Filed:
July 28, 2010
Publication date:
June 28, 2012
Applicant:
TORAY INDUSTRIES, INC.
Inventors:
Shu Kaiho, Shunsuke Horiuchi, Koji Yamauchi
Abstract: A modified polyurethane including a lipid substituent from at least one urethane nitrogen and/or at least carbon atom of the modified polyurethane.
Type:
Grant
Filed:
June 20, 2008
Date of Patent:
June 5, 2012
Assignee:
The Children's Hospital of Philadelphia
Inventors:
Robert J. Levy, Ivan Alferiev, Stanley J. Stachelek
Abstract: A proton-conducting polymer composition which contains an aromatic hydrocarbon type of proton-conducting polymer in an amount of 1 to 30 mass %, wherein a component of said proton-conducting polymer having a molecular weight in the range of 2,000 to 230,000 in terms of polyethylene glycol accounts for 10 mass % or more of the total amount of said proton-conducting polymer; a method for preparing the proton-conducting polymer composition, a catalyst ink comprising the proton-conducting polymer composition and a fuel cell including the catalyst ink. The above proton-conducting polymer composition can well exploit the performance capability of a catalyst of a fuel cell, especially when it is allowed to be present with the electrode of a fuel cell.
Type:
Grant
Filed:
November 7, 2005
Date of Patent:
May 29, 2012
Assignee:
Toyo Boseki Kabushiki Kaisha
Inventors:
Masahiro Yamashita, Kota Kitamura, Yoshimitsu Sakaguchi
Abstract: Provided are hyperbranched poly(ether-ketone)-based nanocomposites with the following generic formula: wherein n is the degree of polymerization and R is carboxylic acid (COOH) and various functional groups that could be derived from COOH, such as benzothiazole, benzoxazole, benzimidazole, esters, and amines. Also provided are a process for preparing the above composite and a chain-end conversion methodology to tailor thermal and solubility properties.
Type:
Grant
Filed:
March 3, 2008
Date of Patent:
May 8, 2012
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: Nanocomposites comprising a sulfonated telechelic polycarbonate and an organically modified clay are disclosed. The polycarbonate nanocomposites have improved physical and mechanical properties.
Type:
Grant
Filed:
August 6, 2007
Date of Patent:
May 8, 2012
Assignee:
Sabic Innovative Plastics IP B.V.
Inventors:
Daniel J. Brunelle, Martino Colonna, Maurizio Fiorini, Corrado Berti, Enrico Binassi
Abstract: A membrane-electrode assembly for solid polymer electrolyte fuel cell that exhibits superior dimensional stability to high temperature of hot water generated on power generation, and that has both excellent power generation performance and durability in a low temperature environment is provided. According to the membrane-electrode assembly for solid polymer electrolyte fuel cell in which a polyarylene-based copolymer having a specific repeating constitutional unit is used as a proton conductive membrane, the membrane-electrode assembly for solid polymer electrolyte fuel cell that exhibits superior dimensional stability to high temperature of hot water generated on power generation, and that has both excellent power generation performance and durability in a low temperature environment can be provided.
Abstract: The invention relates to the field of polymer chemistry and relates to sulfonated polyarylene compounds such as can be used for example in ion exchange membranes in fuel cells, as well as a method for the production thereof and the use thereof. The object of the present invention is to disclose hydrolytically and thermally resistant sulfonated polyarylene compounds with a defined degree and position of sulfonation, from which membrane materials with an improved resistance to hydrolysis can be produced. The object is attained through sulfonated polyarylene compounds according to at least one of the general formulas (I)-(IV).
Abstract: An electronic device, such as a thin film transistor containing a semiconductor of the Formula: wherein R, R? and R? are, for example, independently hydrogen, a suitable hydrocarbon, a suitable hetero-containing group, a halogen, or mixtures thereof; and n represents the number of repeating units.
Type:
Grant
Filed:
October 19, 2010
Date of Patent:
April 10, 2012
Assignee:
Xerox Corporation
Inventors:
Beng S. Ong, Hualong Pan, Yuning Li, Yiliang Wu, Ping Liu
Abstract: A thin-film transistor comprises a semiconducting layer comprising a semiconducting material selected from Formula (I) or (II): wherein X, R1, R2, R3, R4, R5 a, b, and n are as described herein. Semiconducting compositions of Formula (I) or (II) are also described.
Type:
Grant
Filed:
November 19, 2008
Date of Patent:
April 10, 2012
Assignee:
Xerox Corporation
Inventors:
Yuning Li, Yiliang Wu, Ping Liu, Paul F. Smith
Abstract: In accordance with the present invention, there is provided a method of preparing higher generation 1?3 C-branched polyamide dendrons. The combination of commercially available acryloyl chloride with 1?3 C-branched amines, e.g., di-tert-butyl 4-[2-(tert-butoxycarbonyl)ethyl]-4-aminoheptanedioate, resulted in generally high yields of acryl amides, which upon treatment with other reagents, generated the desired higher generation dendrons. These second and third generation dendrons were fully characterized and compared to the samples prepared from a convergent synthesis.
Type:
Grant
Filed:
November 11, 2005
Date of Patent:
March 20, 2012
Assignee:
The University of Akron
Inventors:
George R. Newkome, Charles N. Moorefield, Kishore K. Kotta
Abstract: In a production process of a poly(arylene sulfide), a mixture containing an organic amide solvent, an alkali metal hydrosulfide and an alkali metal hydroxide in a proportion of 0.95 to 1.05 mol per mol of the alkali metal hydrosulfide is heated and dehydrated in a dehydration step. After the dehydration step, as needed, an alkali metal hydroxide and water are added to control the total number of moles of the alkali metal hydroxide, and the number of moles of water so as to amount to 1.00 to 1.09 per mol of a sulfur source including the alkali metal hydrosulfide existing in the system and to 0.5 to 2.0 per mol of the charged sulfur source, respectively. A polymerization step is conducted by a two-stage process.
Abstract: A biaxially oriented polyarylene sulfide film made of a polyarylene sulfide resin composition has a melt crystallization temperature of not lower than 160° C. and not higher than 220° C. The biaxially oriented polyarylene sulfide film contains 70 to 99 parts by weight of the polyarylene sulfide and 1 to 30 parts by weight of thermoplastic resin A; the thermoplastic resin A constitutes a dispersed phase having an average dispersion diameter of 50 nm to 500 nm. The biaxially oriented polyarylene sulfide film has a breaking stress at 200° C. in the machine direction and/or transverse direction of not less than 30 MPa and not more than 90 MPa and has an elongation at break at 200° C. in the machine direction and/or transverse direction of not less than 100% and not more than 250%.
Abstract: The present invention provides a polymer for use in detecting or quantifying an analyte Exposure of the polymer to the analyte is capable of causing a shift in the onset potential for conductivity or semiconductivity of the polymer. A sensor for an analyte comprising the polymer is also described.
Type:
Grant
Filed:
September 26, 2006
Date of Patent:
February 14, 2012
Assignee:
Agency for Science, Technology and Research
Inventors:
Jackie Y. Ying, Hsiao-Hua Yu, Emril Mohamed Ali, Eric Assen B Kantchev
Abstract: A polymer having a repeating unit represented by the following general formula (I) and a ferrocene-based reduction potential of ?1.5 to ?0.5 V as measured by a cyclic voltammetry method wherein Ar1 represents a divalent aromatic hydrocarbon group or a divalent heterocyclic group, and these groups may be substituted by a substituent.
Abstract: The present disclosure provides copolymers of 2-substituted-2-oxazolines possessing two or three reactive functional groups which are also chemically orthogonal. The copolymers described may be random copolymers, block copolymers or a mixture of random and block copolymer configurations. Furthermore, the present disclosure provides novel methods for synthesizing the above polymers and for conjugating to molecules such as targeting, diagnostic and therapeutic agents.
Type:
Grant
Filed:
January 12, 2009
Date of Patent:
February 7, 2012
Assignee:
Serina Therapeutics, Inc.
Inventors:
Kunsang Yoon, J. Milton Harris, Michael David Bentley
Abstract: Preformed compositions in shaped form comprising polymer blends, and the use of these preformed compositions in shaped form to seal apertures are disclosed. In certain embodiments, the preformed compositions are electrically conductive and are capable of shielding EMI/RFI radiation. The polymer blend includes a polysulfide component and a polythioether component.
Type:
Grant
Filed:
May 26, 2009
Date of Patent:
January 31, 2012
Assignee:
PRC DeSoto International, Inc.
Inventors:
Michael A. Cosman, Adrian K. Balladares
Abstract: Polyethersulfones having Tg greater than about 225° C. and a notched Izod value greater than about 1 ft-lb/in, as measured by ASTM D256, comprise from about 5 mol % to less than about 40 mol % structural units of formula 1; and from greater than about 60 mol % to about 95 mol % structural units of formula 2 wherein R1, R2, and R3 are independently at each occurrence a halogen atom, a nitro group, a cyano group, a C1-C12 aliphatic radical, C3-C12 cycloaliphatic radical, or a C3-C12 aromatic radical; n, m, q are independently at each occurrence integers from 0 to 4; and Q is a C3-C20 cycloaliphatic radical, or a C3-C20 aromatic radical.
Abstract: The present disclosure provides copolymers of 2-substituted-2-oxazolines possessing two or three reactive functional groups which are also chemically orthogonal. The copolymers described may be random copolymers, block copolymers or a mixture of random and block copolymer configurations. Furthermore, the present disclosure provides novel methods for synthesizing the above polymers and for conjugating to molecules such as targeting, diagnostic and therapeutic agents.
Type:
Grant
Filed:
May 25, 2010
Date of Patent:
January 24, 2012
Assignee:
Serina Therapeutics, Inc.
Inventors:
Kunsang Yoon, Michael David Bentley, J. Milton Harris, Zhihao Fang, Tacey Viegas
Abstract: An optical resin composition with superior impact resistance and a method for producing an optical lens from the composition are disclosed. In one embodiment, the optical resin composition for a plastic optical lens has superior impact resistance as well as light-weight, superior moldability, excellent dyeing ability, a high Abbe number and good transparency. The optical lens produced from the composition exhibits superior impact resistance even after multi-coating. The optical resin composition with superior impact resistance has a solid refractive index (nD) of about 1.53 to about 1.57, an Abbe number of about 35 to about 48, a liquid specific gravity of about 0.97 to about 1.25 and a solid specific gravity of about 1.10 to about 1.35, by which the composition comprises a mixture of isophorone diisocyanate and hexamethylene diisocyanate, pentaerythritol tetrakis(3-mercaptopropionate), a UV absorber, a release agent and a polymerization initiator.
Abstract: The present invention relates to a poly(arylene ether) copolymer having an ion exchange group, particularly a positive ion exchange group, a method for manufacturing the same, and use thereof. In the poly(arylene ether) copolymer having the ion exchange group according to the present invention, physical characteristics, ion exchanging ability, metal ion adsorption ability and a processability are excellent, and thus the copolymer can be molded in various shapes and can be extensively applied to various fields such as recovering of organic metal, air purification, catalysts, water treatment, medical fields and separating of proteins.
Type:
Grant
Filed:
December 6, 2010
Date of Patent:
December 27, 2011
Assignee:
Hyundai Motor Company
Inventors:
Inchul Hwang, Nak Hyun Kwon, Young Taek Kim, Dong Il Kim, Ju Ho Lee
Abstract: A poly(arylene sulfide) having properties that a melt viscosity is 1 to 3,000 Pa·s as measured under conditions of a temperature of 310° C. and a shear rate of 1,216 sec?1, a pH is 7.0 to 12.0 as measured in a mixed solvent of water/acetone (volume ratio=2/1), a crystallization temperature is at most 220° C. as measured in the course of lowing the temperature of the polymer at a rate of 10° C./min from a molten state, and a whiteness degree is at least 70 as measured in the form of a melt molded or formed product, and a production process thereof.
Abstract: The present invention relates to thioic acids according to formula (II) suitable as building block for polythioesters; Wherein X is O, N or S and whereby R1 is chosen from (—CH2—)2, —CH2—O—CH2— or (—CH2—)3, R2 is preferably chosen from a biodegradable oligomer or polymer chosen from poly(lactide) (PLLA), polyglycolide (PGA), co-oligomers or copolymers of PLA and PGA (PLGA), poly(anhydrides), poly(trimethylenecarbonates), poly(orthoesters), poly(dioxanones), poly(?-caprolactones) (PCL) or polyesteramides and n>1.
Type:
Application
Filed:
December 18, 2009
Publication date:
December 8, 2011
Applicant:
DSM IP ASSETS B.V.
Inventors:
Mark Johannes Boerakker, Aylvin Jorge Angelo Dias, Ronny Mathieu Versteegen