Two Azo Groups Attached Indirectly To Each Other By Nonionic Bonding Patents (Class 534/797)
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Patent number: 7446184Abstract: A compound of Formula (1) and salts thereof: wherein: Q is an optionally substituted aryl ring; Y is CO2H, SO3H or PO3H2; R and X are substituents; m is 0 to 3; n is 0 to 6; and q is 0 to 6. Also compositions comprising these compounds, ink-jet inks, an ink jet process and an ink-jet cartridge.Type: GrantFiled: December 6, 2004Date of Patent: November 4, 2008Assignee: Fujifilm Imaging Colorants LimitedInventors: Clive Edwin Foster, David Schofield, Julie Ann Downey, Neil Burnham, Philip John Double, Roy Bradbury
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Dyes Comprising [(4-[2-Amino-3,6-Disulpho-8-Hydroxynaphth-1-Ylazo]Anilino)- 1,3,5-Triazinyl] Moities
Publication number: 20080233289Abstract: A dyestuff according to formula (1) or a salt thereof wherein the substituents have the definitions as defined in claim 1. The dyestuffs are useful for dyeing or printing nitrogen-containing or hydroxy-group-containing organic substrates and for the production of (ink-jet) printing inks.Type: ApplicationFiled: September 23, 2004Publication date: September 25, 2008Inventor: Markus Gisler -
Publication number: 20070155960Abstract: The present invention discloses a yellow dye compound having a structure of the following formula (I): wherein M is H, Li, NH4 or Na. The dye compound of the present invention is particularly applied to yellow dye compound for paper-printing ink jet ink and can be made into yellow ink jet ink with greenish yellow, wide color gamut, and excellent solubility.Type: ApplicationFiled: June 15, 2006Publication date: July 5, 2007Applicant: Everlight USA, Inc.Inventors: Wen-Chin Lin, Tzu-Kwei Sun, Jen-Fang Lin
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Patent number: 7163576Abstract: A compound of Formula (1): wherein: A1 and A2 are each independently optionally substituted phenyl or naphthyl; each Q independently is optionally substituted phenylene; each R1 independently is H or optionally substituted alkyl; R2 is H or optionally substituted alkyl; and R3 is alkyl carrying a sulpho group; provided that the compound of Formula (1) carries at least one carboxylic acid group; and provided the compound of Formula (1) is not of Formula (2): wherein: m is 1 or 2; n is 1 or 2; and x is 2 to 4. Also claimed are compositions and inks.Type: GrantFiled: July 14, 2003Date of Patent: January 16, 2007Assignee: Fujifilm Imaging Colorants LimitedInventors: Helen Ava Oshaughnessy, Maria Soteri Hadjisoteriou
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Patent number: 7150783Abstract: A composition comprising a liquid medium and a compound of Formula (1) or a salt thereof: wherein: m is 1 or 2; n is 1 or 2; and x is 2 to 4. Also claimed are compounds and printing processes.Type: GrantFiled: July 14, 2003Date of Patent: December 19, 2006Assignee: Fujifilm Imaging Colorants LimitedInventors: Helen Ava Oshaughnessy, Maria Soteri Hadjisoteriou
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Patent number: 7078497Abstract: The dyes of formula (1) according to claim 1 and the copper complexes of dyes of formula (2) according to claim 9 or the mixtures of mono-copper complex with the bis-copper complex are excellently suitable for dyeing paper with good light-fastness properties.Type: GrantFiled: December 19, 2001Date of Patent: July 18, 2006Assignee: Ciba Specialty Chemicals CorporationInventors: Adolf Käser, Holger Lautenbach
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Patent number: 6867286Abstract: Provided are novel yellow azo dyes which are useful in ink compositions, especially ink jet compositions. The dyes and ink compositions of the present invention exhibit a good balance of optical density, print reliability, water fastness and light fashion and exhibit improved water solubility, thus rendering the ink compositions to be especially suitable for printheads having small nozzle openings.Type: GrantFiled: March 11, 2004Date of Patent: March 15, 2005Assignee: Lexmark International, Inc.Inventors: Ann P. Holloway, James Frederic Feeman
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Patent number: 6844428Abstract: The invention relates to the use of disazo compounds according to formula (I) wherein all substituents are as defined in claim 1 salts thereof and mixtures of these compounds for dyeing or printing organic substrates, to novel compounds, to the process for the production of these compounds and to substrates dyed or printed by these compounds.Type: GrantFiled: December 3, 2001Date of Patent: January 18, 2005Assignee: Clariant Finance (BVI) LimitedInventors: Ludwig Hasemann, Friedrich Lehr
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Patent number: 6784287Abstract: Organic dye molecular materials prepared by coupling existing organic chromophore molecules to benzene or carbazole derivatives and nonlinear optical polymeric compounds having polyimide repeating units coupled with the organic dye molecular material are provided. The organic dye molecular material coupled to a polymer main chain in the preparation of the nonlinear optical polymeric compound has one of the following formula: where X1 is carbon, oxygen, sulfur, nitrogen, ester (CO2), or amide (CONR1), where R1 is an alky or phenyl group having 1 to 6 carbon atoms, D is an organic chromophore molecule, and n is an integer from 1 to 10.Type: GrantFiled: February 27, 2002Date of Patent: August 31, 2004Assignee: Electronics and Telecommunications Research InstituteInventors: Jung Yun Do, Myung Hyun Lee, Seung Koo Park, Jung Jin Ju, Suntak Park
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Patent number: 6758890Abstract: Aqueous ink for ink jet recording comprising a coloring matter and an aqueous medium, in which at least one of dyes represented by the formula (A) or a salt thereof is contained as the coloring matter wherein R1 and R3, independently from each other, represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted alkoxy group, an amino group, a hydroxyl group or a halogen atom, R2 and R4, independently from each other, represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted aryl group or an aralkyl group, A represents an optionally substituted phenyl group or naphthyl group, X represents a divalent bonding group free from a saturated carbon ring, and m and n, independently from each other, represent an integer of 1 to 4.Type: GrantFiled: March 15, 2002Date of Patent: July 6, 2004Assignee: Mitsui Chemicals, Inc.Inventors: Yoriaki Matsuzaki, Kenichi Fujii, Osamu Kohgo, Hiroshi Naruse, Tsutami Misawa
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Patent number: 6736888Abstract: A compound comprising a disazo chromophore and an optionally substituted heterocyclic group linked together through a —SO2—NH— group, inks comprising these compounds, ink jet printer cartridges containing these inks and their use in ink jet printing.Type: GrantFiled: March 18, 2002Date of Patent: May 18, 2004Assignee: Avecia LimitedInventor: Mark Robert James
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Patent number: 6730780Abstract: An oil-soluble dye prepared by subjecting a water-soluble dye having at least one group selected from the group consisting of sulfonate group and carboxyl group in its molecule to amidation: a water-based ink comprising the oil-soluble dye: and a process for preparing an oil-soluble dye, comprising halogenating a water-soluble dye having at least one group selected from the group consisting of sulfonate group and carboxyl group in its molecule, and thereafter subjecting the resulting halogenated water-soluble dye to amidation. The Oil-soluble dye of the present invention can be suitably and favorably used for inks for inkjet recording, inks for ball-points pens, inks for markers, toners, paints such as lacquers, inks for felt pens, and the like.Type: GrantFiled: October 19, 2001Date of Patent: May 4, 2004Assignee: Kao CorporationInventors: Shigemi Wakabayashi, Takehiro Tsutsumi, Kenji Kaida, Makoto Sakakibara
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Patent number: 6695899Abstract: A compound of Formula (1) and salts thereof: wherein: A is a substituted phenyl group carrying a group of the formula —NR3R4 and an ortho carboxy group; n is 0 or 1; L1 and L2 are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or L1 and L2 together with the N atom to which they are attached form an optionally substituted 5- or 6-membered ring; R1 and R2 are each independently optionally substituted alkyl or optionally substituted alkoxy; and R3 and R4 are each independently H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl, or R3 and R4 together with the N atom to which they are attached form an optionally substituted 5- or 6-membered ring; or R3 is H, optionally substituted alkyl, optionally substituted cycloalkyl or optionally substituted aryl; and R4 is an acyl group.Type: GrantFiled: March 26, 2002Date of Patent: February 24, 2004Assignee: Avecia LimitedInventor: Prahalad Manibhai Mistry
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Publication number: 20030136301Abstract: A composition comprising a dye of Formula (I) and a dye of Formula (II) or salts thereof, and use of the composition in ink jet printing.Type: ApplicationFiled: September 4, 2002Publication date: July 24, 2003Inventors: Andrew Paul Shawcross, Mark Holbrook, Paul Nicholas Ewing
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Publication number: 20030079648Abstract: Aqueous ink for ink jet recording comprising a coloring matter and an aqueous medium as main components, in which at least one of dyes represented by the formula (A) or their salts is contained as the coloring matter.Type: ApplicationFiled: March 15, 2002Publication date: May 1, 2003Inventors: Yoriaki Matsuzaki, Kenichi Fujii, Osamu Kohgo, Hiroshi Naruse, Tsutami Misawa
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Patent number: 6482255Abstract: Compounds of the Formula (1) and salts thereof: wherein B1, B2, Q, R1, R2, A, Z1 and Z2 are defined in the description. Also claimed are compositions containing two or more compounds of the Formula (1), inks containing the compounds and compositions, an ink jet printing process using the inks, a substrate printed with the inks, and an ink jet printer cartridge containing an ink containing a compound of the Formula (1).Type: GrantFiled: June 26, 2000Date of Patent: November 19, 2002Assignee: Avecia LimitedInventors: Aidan Joseph Lavery, Colin Dick Robertson, Janette Watkinson, Kathryn Carr, Paul Wight
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Patent number: 6451988Abstract: Novel naphthol derivatives, and various azo compounds and metal complexes prepared by using the derivatives are provided. The instant invention provides naphthol derivatives represented by general formula (1); wherein at least one of Y1 and Y2 is a group represented by formula (2); wherein X1 is —O—, —S— or —NH—; and Z is an optionally substituted aromatic group or heterocyclic group having conjugated double bonds, and salts thereof; mono-, bis-, and trisazo compounds prepared from the derivatives; and metal complexes containing the derivatives as the ligand.Type: GrantFiled: January 16, 2002Date of Patent: September 17, 2002Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo KenkyujoInventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori
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Patent number: 6395885Abstract: The use of lithium as a cation for an anionic dye to enhance the light-fastness of the dye. Also claimed are the lithium salts of certain anionic dyes as defined in the description; mixed lithium/sodium salts of an anionic dye wherein the molar ratio of lithium to sodium is from 1:4 to 99:1 and at least 20 mole % of the total counter ions in the dye are lithium cations; inks containing the dyes; a method of ink jet printing using the inks; a substrate printed with the inks; an ink jet printer cartridge containing the ink and a ink jet printer containing the ink jet printer cartridge.Type: GrantFiled: December 5, 2000Date of Patent: May 28, 2002Assignee: Avecia LimitedInventors: Aidan Joseph Lavery, Janette Watkinson, John Parker Meyers
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Patent number: 6365719Abstract: Compounds of formula (I) with the meanings of D, R1, R2, X and Y as given in claim 1 can be used as paper dyes or direct dyes or for the preparation of ink-jet inks.Type: GrantFiled: March 27, 2000Date of Patent: April 2, 2002Assignee: Clariant Finance (BVI) LimitedInventor: Friedrich Lehr
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Publication number: 20010044527Abstract: The invention is related to compounds according to the formula (I) 1Type: ApplicationFiled: March 14, 2001Publication date: November 22, 2001Applicant: CLARIANT FINANCE (BVI) LIMITEDInventor: Markus Gisler
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Patent number: 6290763Abstract: Azo dyes of Formula (1) have utility as dyes for ink-jet printing, where Formula (1) represents: which comprises any suitable form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: n represents from 1 to 5 inclusive; R1, R1B, R4 and R4B each independently comprises at least one of the following substituents, optionally substituted: H, C1-8alkyl; C1-8,alkoxy; —NHCOH, C1-8alkylcarbonylamino; and —NHCONR5R6 where R5 and R6 each independently comprises at least one of the following substituents: H, C1-8alkyl and aryl; and R2 and R3 each independently comprises at least one of the following substituents, optionally substituted: H; C1-8alkoxy; -NHC1-8alkyleneOH, —SC1-8-alkyleneSO3H; -NHC1-8alkyleneN(C1-8alkyl)2; where X comprises one of the following: —NHC1-8alkylene; —NHphenylSO2NHC1-8alkylene; and a direct link,Type: GrantFiled: March 18, 1999Date of Patent: September 18, 2001Assignee: Zeneca LimitedInventors: Christine Millard, Peter Gregory, Roy Bradbury
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Patent number: 6277185Abstract: Azo dyes of Formula (1) have utility as dyes for ink-jet printing where Formula (1) represents: which comprises any suitable form of the compound: such as salt; stereoisomer, zwitterion, polymorph, complex, isotopic form, combinations thereof in the same species and mixtures thereof; where: p represents from 1 to 7 inclusive; the napthyl moiety may be optionally substituted; R1 comprises at least one of the following substituents, optionally substituted: H, C1-4-alkyl, NHCOC1-4 alkyl, C1-4 alkoxy, NHCOaryl, NHSO2C1-4 alkyl, NHSO2aryl, NHCONR3R4 where R3 and R4 each independently comprises H, C1-4alkyl or aryl; R2 comprises H, C1-4 alkyl or C1-4 alkoxy; L1 and L2 each independently comprises at least one of the following substituents, optionally substituted: —NH2, —NHC1-4 alkyleneOH, —SC1-4alkylene —SO3H, —NHC1-4alkyleneN(C1-4alkyl)2, —N(C1-4alkyleneOH)2, —NHC1-4alkyleneSO3H, —NHC1-4alkylene(CO2H)n where n is 1, 2 or 3, —SC1-4alkylType: GrantFiled: May 26, 1999Date of Patent: August 21, 2001Assignee: Zeneca LimitedInventors: Anthony Alanzo Watson, Kathryn Carr
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Patent number: 6140477Abstract: A polyazo compound capable of effectively absorbing near-infrared rays, which can be produced from readily available raw materials is provided, which comprises at least one --OH group or at least one group derived from --OH group at p-position of the azo group in the molecule of the polyazo compound. This compound can be produced by diazotizing a substituted or nonsubstituted aromatic monocyclic or polycyclic compound or heterocyclic compound, each having a diazotizable primary amino group, and successively coupling the resulting diazo component with an azo component having a diazotizable primary amino group, the last azo component being such that --OH group or a group derived from --OH group be present at p-position to the azo group resulting from the azo component.Type: GrantFiled: March 23, 1999Date of Patent: October 31, 2000Assignee: Hakkol Chemical Co., Ltd.Inventors: Shigekazu Matsumoto, Takao Yanagisawa, Shigehiro Matsumoto, Kunio Shimabukuro
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Patent number: 6130320Abstract: Disazo dyes of formula (I) where one of the two symbols X.sup.1 and X.sup.2 means hydroxy and the other amino and R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are as defined in the specification. The invention also relates to sulphonamides as their intermediate products and to the use of the dyes for the dyeing of natural and synthetic substrates.Type: GrantFiled: July 22, 1998Date of Patent: October 10, 2000Assignee: BASF AktiengesellschaftInventors: Gunther Lamm, Helmut Reichelt, Gerhard Wagenblast
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Patent number: 6127531Abstract: A dyestuff according to formula (I) ##STR1## or a salt thereof wherein the substituents have the definitions as defined in claim 1.The dyestuffs are useful for dyeing or printing nitrogen-containing or hydroxy-group-containing organic substrates and for the production of printing inks.Type: GrantFiled: May 26, 1999Date of Patent: October 3, 2000Assignee: Clariant Finance (BVI) LimitedInventor: Rainer Nusser
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Patent number: 6068687Abstract: Azo dyes of formula (4) ##STR1## wherein A, R.sub.4, M and m are as defined in the specification, are excellent dyes for dyeing and printing of cellulose containing materials and especially for the preparation of inks for ink jet printing.Type: GrantFiled: November 19, 1998Date of Patent: May 30, 2000Assignee: Ilford Imaging Switzerland GmbHInventors: Kurt Baettig, Gerald Jan
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Patent number: 6008331Abstract: A compound of the formula (1) ##STR1## or a salt thereof wherein J is a group of the formula (1a) ##STR2## and A, Y, T, T.sup.1, R, R.sup.1, R.sup.4, R.sup.5 and R.sup.6 are as defined in the specification are useful as black colorants for ink jet printing inks.Type: GrantFiled: April 21, 1999Date of Patent: December 28, 1999Assignee: Zeneca LimitedInventors: Peter Gregory, Ronald Wynford Kenyon, Paul Wight
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Patent number: 6005085Abstract: The present invention provides novel condensed azo compounds using bisamide compounds of 2-hydroxynaphthalene-3,6-dicarboxylic acid, amide, or ester as the couplers, which have excellent properties such as excellent water resistance, chemical resistance, solvent resistance, and heat resistance.Type: GrantFiled: November 18, 1998Date of Patent: December 21, 1999Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo KenkyujoInventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori, Katsunori Tanikawa
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Patent number: 5969114Abstract: A compound of Formula (1) or a salt thereof: wherein:J is --OR.sup.4 or --NR.sup.4 R.sup.5 ;R.sup.4 is H or optionally substituted alkyl, aryl or acyl; andR.sup.4 and R.sup.5 taken together with the N atom to which they are attached form a 5- or 6-membered carbocyclic group optionally containing a ring oxygen atom;A is optionally substituted phenylene or optionally substituted naphthylene;Y is a substituted or unsubstituted naphthylene or phenylene ring;R.sup.1 is H or optionally substituted alkyl, alkylcarbonyl, alkylsulphonyl, alkoxycarbonyl, alkoxysulphonyl, arylcarbonyl or arylsulphonyl;T and T.sup.1 each independently is H or SO.sub.3 H; andR is, for example, H or optionally substituted alkyl or aryl. The compounds are used as black colorants for ink jet printing inks.Type: GrantFiled: November 3, 1998Date of Patent: October 19, 1999Assignee: Zeneca LimitedInventors: Paul Wight, Peter Gregory, Ronald Wynford Kenyon
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Patent number: 5965715Abstract: The invention provides novel bisazo compounds which is obtained by coupling two molecules of a 2-hydroxynaphthalene-3,6-dicarboxylic acid derivative and a compound having two diazo groups in its molecule, as well as a process for producing the same. The present compounds are superior in resistance to water, chemical agents, solvents, heat and the like.Type: GrantFiled: June 22, 1998Date of Patent: October 12, 1999Assignee: Kabushiki Kaisha Ueno Seiyaku Oyo KenkyujoInventors: Ryuzo Ueno, Masaya Kitayama, Kenji Minami, Hiroyuki Wakamori
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Patent number: 5925746Abstract: Azo dyes of the formula (1) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are each hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,R.sub.5, R.sub.6, R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen or sulfo,D.sub.1 and D.sub.2 independently of one another are each a radical of the benzene or naphthalene series, andY.sub.1 and Y.sub.2 independently of one another are each halogen, substituted or unsubstituted amino, morpholino or piperidin-1-yl or are piperazin-1-yl which is unsubstituted or substituted on the nitrogen,with the proviso that D.sub.1 and D.sub.2 are not both sulfophenyl if Y.sub.1 and Y.sub.2 are chlorine and R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are hydrogen, are dyes for various substrates, especially cellulosic fibre materials.Type: GrantFiled: June 17, 1998Date of Patent: July 20, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Urs Lauk, Patric Nowack
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Patent number: 5882391Abstract: A bisazo dye of Formula (1) and salts thereof: ##STR1## in which R is H or ##STR2## R.sub.1 and R.sub.2 each independently is H, optionally substituted C.sub.1-4 -alkyl or optionally substituted aryl;R.sub.3 and R.sub.5 together with the carbon atoms to which they are attached form a 5- or 6-membered carbocyclic ring which is optionally substituted by SO.sub.3 H;R.sub.4 is H;R.sub.6 is COOH;n is 1, 2 or 3; andp is 1, 2, 3 or 4.The dyes are useful for ink jet printing.Type: GrantFiled: October 9, 1997Date of Patent: March 16, 1999Assignee: Zeneca LimitedInventors: Peter Gregory, Prahalad Manibhai Mistry, Roy Bradbury, Paul Wight
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Patent number: 5882392Abstract: A dye of Formula (1) and salts thereof: ##STR1## in which R is H, --NHC.sub.1-4 -alkylN(C.sub.1-4 -alkyl).sub.2 or ##STR2## R.sub.1 and R.sub.2 each independently is H, optionally substituted C.sub.1-4 -alkyl or optionally substituted aryl;R.sub.3 is C.sub.1-4 -alkyl;R.sub.4 is C.sub.1-4 -alkyl or OC.sub.1-4 -alkyl;R.sub.5 is H;R.sub.6 is COOH; andn is 1, 2 or 3.The dyes are useful for preparing ink jet printer inks.Type: GrantFiled: October 9, 1997Date of Patent: March 16, 1999Assignee: Zeneca LimitedInventors: Peter Gregory, Prahalad Manibhai Mistry, Roy Bradbury, Paul Wight
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Patent number: 5869627Abstract: A composition of a water-soluble bis-azo dye of the Formula (1) and an oxidising agent. ##STR1## wherein A is optionally substituted phenyl or optionally substituted naphthyl;B is optionally substituted phenylene or optionally substituted naphthylene;R.sup.1 is H or sulpho;R.sup.2 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted acyl;R.sup.3 is H, optionally substituted aryl, optionally substituted alkyl or a group, -D-E,D is optionally substituted C.sub.2-6 -alkylene; andE is a group of the Formula (1a): ##STR2## R.sup.4 & R.sup.5 each independently is H or optionally substituted alkyl; andR.sup.6 is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted acyl.Type: GrantFiled: January 8, 1998Date of Patent: February 9, 1999Assignee: Zeneca LimitedInventors: Peter Gregory, Ronald Wynford Kenyon, Paul Wight
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Patent number: 5844101Abstract: The novel dyestuffs of the formula (I) ##STR1## in which the substituents R and X have the meaning given in the description, are outstandingly suitable for dyeing cellulosic materials in blue color shades which are particularly fast to light.Type: GrantFiled: September 17, 1997Date of Patent: December 1, 1998Assignee: Bayer AktiengesellschaftInventor: Klaus Kunde
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Patent number: 5834602Abstract: Disazo dyes of the formula ##STR1## where the ring A may be benzofused,X is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, halogen, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl or hydroxysulfonyl,R.sup.2 is hydrogen, C.sub.1 -C.sub.4 -alkyl, halogen, carboxyl or C.sub.1 -C.sub.4 -alkoxycarbonyl, or R.sup.1 and R.sup.2 together are a radical of the formula L--NZ--CO, where L is methylene or carbonyl and Z is substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl, andR.sup.3 is hydrogen, C.sub.1 -C.sub.4 -alkyl, hydroxyl, C.sub.1 -C.sub.4 -alkoxy, phenoxy, C.sub.1 -C.sub.4 -alkanoyloxy or benzoyloxy,are useful for dyeing natural or synthetic substrates.Type: GrantFiled: January 26, 1998Date of Patent: November 10, 1998Assignee: BASF AktiengesellschaftInventors: Gunther Lamm, Helmut Reichelt
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Patent number: 5827332Abstract: Azo dyes of the formula ##STR1## where the ring A may be benzofused,n is 0 or 1, and R.sup.1 -R.sup.8 are as defined,as pH-dependent markers for hydrocarbons, hydrocarbons containing the above-mentioned azo dyes, and a method for detecting these azo dyes in hydrocarbons.Type: GrantFiled: June 6, 1996Date of Patent: October 27, 1998Assignee: BASF AktiengesellschaftInventors: Georg Zeidler, Gerhard Scholz, Claudia Krah, Karin Heidrun Beck, Udo Mayer
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Patent number: 5795971Abstract: The novel aminomethylnaphthalenecarboxylic acid dyestuffs of the formula (I) ##STR1## in which the substituents and indices have the meaning given in the description, are outstandingly suitable for dyeing cellulosic materials, in particular paper.Type: GrantFiled: September 2, 1997Date of Patent: August 18, 1998Assignee: Bayer AktiengesellschaftInventor: Klaus Kunde
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Patent number: 5786459Abstract: Compounds of the formula (I) ##STR1## have been found which are suitable for dyeing and printing hydroxyl- and/or amido-containing substrates, in particular for printing paper by the ink-jet method.Type: GrantFiled: July 5, 1996Date of Patent: July 28, 1998Assignee: Bayer AktiengesellschaftInventors: Frank-Michael Stohr, Peter Wild
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Patent number: 5773593Abstract: A bisazo compound of the Formula (1) and salts thereof: ##STR1## wherein Ar.sup.1, Ar.sup.2, each J, each X, L, R.sup.1 and R.sup.2 are as defined in the description, provided that L comprises the residue ##STR2## and/or L.sup.1 is--NH--A--NR.sup.9 R.sup.10wherein L.sup.1, A, R.sup.9 and R.sup.10 are as defined in the description, the compounds of Formula (1) being free from fiber-reactive groups and any carboxyl substituents present in the compounds being attached in the form of one or more residue of the following formulae: ##STR3## Also disclosed are ink compositions comprising the above compound; a process for printing substrates with the ink compositions using an ink-jet printer; paper, project slides and textile materials printed with the ink compositions; and a process for coloration of textile materials with the ink compositions.Type: GrantFiled: December 18, 1996Date of Patent: June 30, 1998Assignee: Zeneca LimitedInventors: Peter Gregory, Ronald Wynford Kenyon, Paul Wight
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Patent number: 5762653Abstract: Dye mixtures which comprise at least one dye of the formula ##STR1## and at least one dye of the formula ##STR2## in which Y.sub.1 is a radical of the formula ##STR3## and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, X.sub.1, X.sub.2, X.sub.3, L, W.sub.1, B.sub.1, A.sub.1, and A.sub.3 are as defined in claim 1.The dye mixtures according to the invention are particularly suitable for dyeing or printing natural or synthetic polyamide fibre materials.Type: GrantFiled: March 3, 1997Date of Patent: June 9, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Jean-Marie Adam, Jean-Pierre Bacher
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Patent number: 5756692Abstract: A bisazo compound of the Formula (1) and salts thereof: ##STR1## wherein the variables are as defined in the specification, the compounds of Formula (1) being free from fibre-reactive groups and any carboxyl substituents present in the compounds being attached in the form of one or more residue of the following formulae: ##STR2## Also claimed are ink compositions comprising the above compound; a precess for printing substrates with the ink compositions using an ink-jet printer; paper, project slides and textile materials printed with the ink compositions; and a process for coloration of textile materials with the ink compositions.Type: GrantFiled: December 18, 1996Date of Patent: May 26, 1998Assignee: Zeneca LimitedInventors: Peter Gregory, Ronald Wynford Kenyon, Paul Wight
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Patent number: 5756693Abstract: A compound of the Formula (1) and salts thereof: ##STR1## wherein: A is optionally substituted phenyl or optionally substituted naphthyl;R.sup.1 is NR.sup.4 R.sup.5 ;R.sup.2 is H, halo, --COOH, --SO.sub.2 0H, optionally substituted alkyl, optionally substituted alkoxy, or optionally substituted alkylthio;R.sup.3, R.sup.4 & R.sup.5 are each independently H or optionally substituted alkyl;T is H or sulpho; andB is H, optionally substituted alkyl or optionally substituted phenyl;provided that the compound does not contain a piperazinyl group.The compound is suitable for use as a black colorant in ink jet printing inks especially for printing on plain paper.Type: GrantFiled: January 30, 1997Date of Patent: May 26, 1998Assignee: Zeneca LimitedInventors: Ronald Wynford Kenyon, Peter Gregory
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Patent number: 5750661Abstract: Dyes of the formula ##STR1## where the ring A may be benzofused and R.sup.1 -R.sup.6 have the meaning defined in the specification, with the proviso that at least one quaternizable or quaternary group is present in the molecule; use of said dyes for dyeing or printing polymeric material, and novel amides of J-acid.Type: GrantFiled: August 30, 1996Date of Patent: May 12, 1998Assignee: BASF AktiengesellschaftInventors: Ulrike Schloesser, Udo Mayer
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Patent number: 5747345Abstract: Diaza-18-crown-6 compounds of the formula I: ##STR1## wherein X is a phenol, naphthol or quinolinol moiety selected from those of the formulae: ##STR2## R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are independently selected from hydrogen, halo, cyano, nitro, (C.sub.1 -C.sub.6) alkyl, (C.sub.2 -C.sub.8) acyl, acetamido, mercapto, alkyl or arylsulfonyl, trifluoromethyl, aryl, and substituted aryl wherein the aryl moiety is selected from phenyl and naphthyl and the aryl substituent is selected from halo, cyano, nitro, (C.sub.1 -C.sub.6) alkyl, (C.sub.2 -C.sub.8) acyl, phenyl, acetamido, mercapto, alkyl or arylsulfonyl and trifluoromethyl; provided that when R.sub.1, R.sub.2, R.sub.3 and R.sub.5 are hydrogen and X is phenol, R.sub.4 is not nitro; and provided that when X is phenol and R.sub.5 is hydrogen, R.sub.1 (or R.sub.2) and R.sub.4 are not both nitro.Type: GrantFiled: August 15, 1996Date of Patent: May 5, 1998Assignee: Johnson & Johnson Clinical Diagnostics, Inc.Inventors: Wayne Woodrow Weber, II, Calvin Roman Messing, Margaret Elizabeth Logan
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Patent number: 5698682Abstract: The present invention provides a polarizing film having high heat resistance and a high degree of polarization and excellent optical properties by dyeing a polymer film with a novel azo compound represented by the following formula (1) or (2): ##STR1##Type: GrantFiled: February 18, 1997Date of Patent: December 16, 1997Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Yoriaki Matsuzaki, Ryu Oi, Rihoko Imai, Keisuke Takuma, Hisato Itoh
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Patent number: 5684139Abstract: Dyestuffs of the formula (I) ##STR1## wherein R.sup.1 and R.sup.4 independently of one another represent an acyl radical,R.sup.2 and R.sup.3 independently of one another represent hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl,X represents a bridge member which is not fibre-reactive andn and m independently of one another represent 1 or 2,are outstandingly suitable for dyeing and printing substrates containing hydroxyl and/or amide groups, in particular for printing paper by the ink-jet method.Type: GrantFiled: July 5, 1996Date of Patent: November 4, 1997Assignee: Bayer AktiengesellschaftInventors: Peter Wild, Karin Hassenruck, Frank-Michael Stohr
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Patent number: 5674986Abstract: There are described heat-developable photosensitive image-recording materials which include a compound having at least one cyclic 1,3-sulfur-oxygen moiety. The compound is stable in the photographic processing composition but capable of undergoing cleavage in the presence of an imagewise distribution of silver ions and/or soluble silver complex made available as a function of development to liberate a reagent in an imagewise distribution corresponding to that of the silver ion and/or the soluble silver complex. The reagent includes a photographically useful group such as a complete dye or dye intermediate.Type: GrantFiled: May 13, 1996Date of Patent: October 7, 1997Assignee: Polaroid CorporationInventors: Peter Viski, David P. Waller
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Patent number: 5667571Abstract: According to the present invention, there was provided a non-pollutive ink composition using alcohol or glycol ether as a solvent. The ink composition has excellent stability against an environmental change such as a temperature change, a humidity change, etc., and storage stability in comparison with a conventional salt-formed type dye. Further, the written ink has excellent water resistance and light resistance. It can be used as various quick-drying black dye ink compositions such as writing ink, (industrial) ink-jet printing ink, stamp ink, etc.Type: GrantFiled: February 29, 1996Date of Patent: September 16, 1997Assignee: Orient Chemical Industries, Ltd.Inventors: Takashi Ono, Tatsuya Yagyu, Yoshihiro Sawatari
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Patent number: 5631352Abstract: Dye mixtures which comprise at least one anionic acid dye of the formula ##STR1## together with at least one anionic acid dye of the formula ##STR2## in which the substituents are as defined in claim 1, and the novel dyes of the formulae (1) and (2) are direct dyes for cellulosic fibre materials in particular. They have a high heat stability and are particularly suitable for one-bath, one-stage dyeing of polyester/cotton blend fabrics with a disperse dye for the polyester fibres under the dyeing conditions for polyester fibres.Type: GrantFiled: June 2, 1995Date of Patent: May 20, 1997Assignee: Ciba-Geigy CorporationInventor: Urs Lauk