Abstract: In the process of producing N-(alkadienyl)amines by the amination of conjugated dienes in a hydroxylic solvent medium in the presence of a catalyst comprising a palladium compound co-catalyzed with a phosphonite ligand, the improvement in which the phosphonite ligand is polymerized with polyvinyl alcohol whereby the catalyst can be readily separated from the liquid rection products.
Abstract: N-(alkadienyl)amines are produced at a rapid rate and in high yield by the reaction of conjugated dienes with ammonia and amines in a hydroxylic solvent using a catalyst system comprising a palladium compound co-catalyzed with a phosphonite ligand.
Abstract: Novel 7-amino-benzocycloheptenes of the formula ##STR1## wherein X is selected from the group consisting of hydrogen, chlorine, bromine and iodine in the 2- or 4-position when a halogen, Y and Z are hydrogen or together form a double bond, R is selected from the group consisting of hydrogen, alkyl of 1 to 5 carbon atoms and phenyl optionally substituted with fluorine, chlorine, methyl or methoxy, R.sub.1 is selected from the group consisting of hydrogen, alkyl of 1 to 5 carbon atoms and alkenyl of 2 to 5 carbon atoms and R.sub.2 is selected from the group consisting of alkyl of 1 to 5 carbon atoms and alkenyl of 2 to 5 carbon atoms and R.sub.1 and R.sub.
Type:
Grant
Filed:
July 26, 1976
Date of Patent:
May 23, 1978
Assignee:
Roussel Uclaf
Inventors:
Lucien Nedelec, Andre Pierdet, Claude Dumont, Marie-Helene Kannengiesser
Abstract: A new process for the manufacture of N-substituted tetrahydro-1,4-oxazines, also called morpholines, by conversion of N-substituted bis-(2-hydroxyalkyl)-amines in the presence of catalysts.
Type:
Grant
Filed:
July 22, 1976
Date of Patent:
January 10, 1978
Assignee:
BASF Aktiengesellschaft
Inventors:
Norbert Goetz, Bernd Zeeh, Martin Decker, Leopold Hupfer, Herbert Toussaint
Abstract: A method of recovering primary or secondary amines from aqueous, organic or aquo-organic solutions of said amines by subjecting these solutions to distillation or rectification in the presence of carbonic acid.
Type:
Grant
Filed:
February 25, 1974
Date of Patent:
December 6, 1977
Inventors:
Lazar Isaevich Blyakhman, Sergei Lvovich Davydov, Valentina Fedorovna Kashina
Abstract: This application discloses arylethynylphenylcyclopropylamines and processes for their preparation. These amines exhibit monoamine oxidase (MAO) inhibiting activity.