Having -c(=x)-, Wherein X Is Chalcogen Bonded Directly To The Diazole Ring Patents (Class 548/369.4)
  • Patent number: 7456133
    Abstract: The invention relates to novel aryl ketones of the formula (I) in which A1, A2, Q, R1, R2, X, Y and Z are as defined in the description, their use as herbicides and processes and intermediates for their preparation.
    Type: Grant
    Filed: July 10, 2006
    Date of Patent: November 25, 2008
    Assignee: Bayer CropScience AG
    Inventors: Stefan Herrmann, Dorothee Hoischen, Kristian Kather, Klaus-Helmut Muller, Otto Schallner, Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen
  • Patent number: 7442799
    Abstract: A method is disclosed for preparing a 2-substituted-5-oxo-3-pyrazolidinecarboxylate compound of Formula I. The method comprises contacting a succinic acid derivative of the formula R1OC(O)C(H)(X)C(R2a)(R2b)C(O)Y (i.e. Formula II)wherein X and Y are leaving groups and L, R1, R2a and R2b are as defined in the disclosure, with a substituted hydrazine of the formula LNHNH2 (i.e. Formula III) in the presence of a suitable acid scavenger and solvent. Also disclosed is the preparation of compounds of Formula IV wherein X1, R6, R7, R8a, R8b, R9, and n are as defined in the disclosure. Also disclosed is a composition comprising on a weight basis about 20 to 99% of the compound of Formula II wherein R1, R2a, R2b, R3, R4 and R5 are as defined in the disclosure; X is Cl, Br or I; and Y is F, Cl, Br or I; provided that when R2a and R2b are each H, and X and Y are each Cl then R1 is other than benzyl and when R2a and R2b are each phenyl, and X and Y are each Cl, then R1 is other than methyl or ethyl.
    Type: Grant
    Filed: March 25, 2004
    Date of Patent: October 28, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Gary David Annis
  • Publication number: 20080254990
    Abstract: What is described are 4-(3-aminobenzoyl)-1,3-dimethylpyrazoles of the general formula (I) and their use as herbicides. In this general formula (I), R1 and R2 are radicals such as hydrogen and organic radicals, such as alkyl, alkenyl and alkynyl. Y is hydrogen or a protective group, such as tosyl.
    Type: Application
    Filed: April 10, 2008
    Publication date: October 16, 2008
    Applicant: Bayer CropScience AG
    Inventors: Ines Heinemann, Andreas van Almsick, Lothar Willms, Monika Schmitt, Jan Dittgen, Martin Hills, Heinz Kehne, Christopher Rosinger, Dieter Feucht
  • Publication number: 20080254991
    Abstract: 4-(3-Aminobenzoyl)-1-ethylpyrazoles and their use as herbicides What is described are 4-(3-aminobenzoyl)-1-ethylpyrazoles of the general formula (I) and their use as herbicides. In this general formula (I), R1 and R2are radicals such as hydrogen and organic radicals, such as alkyl, alkenyl and alkynyl. Y is hydrogen or a protective group, such as tosyl.
    Type: Application
    Filed: April 10, 2008
    Publication date: October 16, 2008
    Applicant: Bayer CropScience AG
    Inventors: Ines Heinemann, Andreas van Almsick, Lothar Willms, Monika Schmitt, Jan Dittgen, Martin Hills, Heinz Kehne, Christopher Rosinger, Dieter Feucht
  • Publication number: 20080254992
    Abstract: What is described are 4-(3-aminobenzoyl)pyrazoles of the general formula (I) and their use as herbicides. In this formula (I), R1 and R2 are radicals such as hydrogen and organic radicals, such as alkyl, alkenyl and alkynyl. Y is hydrogen or a protective group, such as tosyl.
    Type: Application
    Filed: April 10, 2008
    Publication date: October 16, 2008
    Applicant: Bayer CropScience AG
    Inventors: Ines Heinemann, Andreas van Almsick, Lothar Willms, Monika Schmitt, Jan Dittgen, Martin Hills, Heinz Kehne, Christopher Rosinger, Dieter Feucht
  • Publication number: 20080214642
    Abstract: N-benzoyl-5-hydroxy-5-phenylpyrazolines of the formula I in which the substituents are as defined below: L1, L2 are hydrogen, halogen, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl; L3, L4, L5 are alkyl or one of the groups mentioned under L1 and L2; X is oxygen or sulfur; R1 is halogen, nitro, cyano, NR?2, alkyl, haloalkyl, alkoxy, alkenyl, haloalkyl, alkynyl, haloalkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, phenyl, 5- or 6-membered heterocyclyl or hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; R? independently of one another are hydrogen or alkyl; m is 1, 2, 3, 4 or 5; R2 is hydrogen or alkyl; R3 is hydrogen, nitro, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl, haloalkynyl or NR?2, where R4 is hydrogen, halogen, nitro, cyano, NR?2, alkyl, haloalkyl, COOR? or 5- or 6-membered heterocyclyl or hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; where the variables mentioned above ma
    Type: Application
    Filed: May 24, 2006
    Publication date: September 4, 2008
    Inventors: Markus Gewehr, Jochen Dietz, Thomas Grote, Andreas Gypser, Matthias Niedenbruck
  • Publication number: 20080182886
    Abstract: Novel 5-hydroxypyrazolines of the formula I in which the substituents are as defined below: B is phenyl, naphthyl or 5- or 6-membered hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; A is C?O, C?S or SO2; W is CX1X2; X1, X2 are hydrogen, fluorine, chlorine or bromine; R1 is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, phenyl, 5- or 6-membered heterocyclyl or hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; R2 is hydrogen or alkyl; R3 is hydrogen, nitro, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl, haloalkynyl or NR?2, where R? independently of one another are hydrogen or alkyl; R4 is hydrogen, halogen, nitro, cyano, NR?2, alkyl, haloalkyl, COOR? or 5- or 6-membered hetaryl or heterocyclyl; where the variables mentioned above may be substituted according to the description; processes for their preparation, their use for controlli
    Type: Application
    Filed: May 24, 2006
    Publication date: July 31, 2008
    Applicant: BASF Aktiengesellschaft
    Inventors: Markus Gewehr, Jochen Dietz, Thomas Grote, Andreas Gypser, Matthias Niedenbruck
  • Publication number: 20080167468
    Abstract: The present invention relates to a diastereomeric mixture of Silacycle Compounds and methods for using the diastereomeric mixture of Silacycle Compounds for stereoselective synthesis.
    Type: Application
    Filed: June 6, 2007
    Publication date: July 10, 2008
    Applicant: THE TRUSTEES OF COLUMBIA UNIVERSITY IN THE CITY OF NEW YORK
    Inventors: James Lincoln Leighton, Richard Berger, Seiji Shirakawa, Gregory T. Notte
  • Patent number: 7396939
    Abstract: What is described are 3-cyclopropyl-4-(3-amino-2-methylbenzoyl)pyrazoles of the formula (I) and their use as herbicides. In this formula (I), R1, R2, R3, R4 and R5 are various radicals.
    Type: Grant
    Filed: December 8, 2005
    Date of Patent: July 8, 2008
    Assignee: Bayer CropScience GmbH
    Inventors: Monika Schmitt, Lothar Willms, Ines Heinemann, Andreas Van Almsick, Thomas Auler, Martin Hills, Heinz Kehne, Dieter Feucht
  • Publication number: 20080064682
    Abstract: A compound represented by formula (I): (wherein Ar1 represents a phenyl group which may have 1 to 3 substituents, or a non-substituted 5- or 6-membered aromatic heterocyclic group; Ar2 represents (i) a non-substituted phenyl group, (ii) a phenyl group which has been substituted by a lower alkyl group having 1 to 3 groups or atoms selected from among a carbamoyl group, an amino group, a hydroxyl group, a lower alkoxy group, and a halogen atom, or (iii) a 5- or 6-membered nitrogen-containing aromatic heterocyclic group which has been substituted by 1 to 3 groups or atoms selected from among a lower alkyl group, a lower alkynyl group, a lower alkanoyl group, a carbamoyl group, a cyano group, an amino group, a hydroxyl group, a lower alkoxy group, and a halogen atom; and X represents a group represented by formula (II): (wherein the ring structure represents a 4- to 7-membered heterocyclic group which may have, in addition to the nitrogen atom shown in formula (II), one heteroatom selected from among nitr
    Type: Application
    Filed: July 1, 2005
    Publication date: March 13, 2008
    Applicant: DAIICHI PHARMACEUTICAL CO., LTD.
    Inventors: Naoaki Kanaya, Takashi Ishiyama, Ryo Muto, Toshiyuki Watanabe, Yuichi Ochiai
  • Patent number: 7153813
    Abstract: The invention relates to novel substituted aryl ketones of the formula (I) in which Z, X, R and n are as defined in the disclosure, to processes for their preparation and to their use as crop treatment agents, and to intermediates for preparing compounds of the formula (I).
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: December 26, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen, Monika Schmitt
  • Patent number: 7112554
    Abstract: The invention relates to novel aryl ketones of the formula (I) in which A1, A2, Q, R1, R2, X, Y and Z are as defined in the description, their use as herbicides and processes and intermediates for their preparation.
    Type: Grant
    Filed: April 29, 2002
    Date of Patent: September 26, 2006
    Assignee: Bayer Cropscience AG
    Inventors: Stefan Herrmann, Dorothee Hoischen, Kristian Kather, Klaus-Helmut Müller, Otto Schallner, Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht
  • Patent number: 6872691
    Abstract: What is described are herbicidal compositions comprising herbicidal compounds of the formula I and a compound which acts as safener. In the formula I, the symbols R1 to R4 denote hydrogen, halogen, alkyl and haloalkyl.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: March 29, 2005
    Assignee: Bayer CropScience GmbH
    Inventors: Monika H. Schmitt, Lothar Willms, Frank Ziemer, Christopher Rosinger, Hermann Bieringer, Philipp Huff, Erwin Hacker
  • Patent number: 6828276
    Abstract: There are described benzoylcyclohexanediones of the formula I, their preparation, and their use as herbicides and plant growth regulators. In this formula (I), C1, C2, C3 are cyclic radicals, X1 is a hetero atom, X2 is a chain of carbon atoms, L is a chain-like element, R1, R2, R3, R4, R5 are various radicals, and Y and Z are monoatomic bridge elements.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: December 7, 2004
    Assignee: Aventis CropScience GmbH
    Inventors: Thomas Seitz, Andreas van Almsick, Lothar Willms, Hermann Bieringer, Thomas Auler, Hubert Menne
  • Publication number: 20040110640
    Abstract: The invention relates to benzoylpyrazoles of the general formula (I), 1
    Type: Application
    Filed: November 14, 2003
    Publication date: June 10, 2004
    Inventors: Hans-Georg Schwarz, Klaus-Helmut Mller, Stefan Herrmann, Dorothee Hoischen, Kristian Kather, Stefan Lehr, Otto Schallner, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen
  • Patent number: 6686318
    Abstract: The invention relates to new substituted aromatic amino compounds of the general formula (I) in which R1, R2, R3, R4 and Z have the meanings given in the description, to a process for their preparation, and to their use as herbicides.
    Type: Grant
    Filed: April 22, 2003
    Date of Patent: February 3, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Roland Andree, Mark Wilhelm Drewes, Kurt Findeisen, Joachim Kluth, Karl-Heinz Linker, Klaus-Helmut Müller, Otto Schallner, Markus Dollinger
  • Patent number: 6605658
    Abstract: Stabilizing mixtures for organic polymers comprising: a) at least one compound belonging to the group of pyrazolones; b) at least one compound belonging to the group of organic phosphites or phosphonites; c) at least one compound belonging to the group of sterically hindered phenols; and d) at least one compound belonging to the group of sterically hindered amines. The above mixtures are useful in the stabilization to degradation caused by oxygen, heat and/or light, of organic polymers.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: August 12, 2003
    Assignee: Great Lakes Chemical (Europe) GmbH
    Inventors: Fabio Broussard, Daniele Girelli, Maria Lucia Wis, Carlo Neri, Vincenzo Malatesta
  • Publication number: 20030144530
    Abstract: A “one-pot” process is described herein for the production of pyrazole compounds of general formula (II) 1
    Type: Application
    Filed: January 17, 2003
    Publication date: July 31, 2003
    Inventors: Harris Laurence James, Levett Philip Charles
  • Patent number: 6566307
    Abstract: Pyrazoles of the formula I where: R1 is hydrogen, nitro, halogen, cyano, thiocyanato or an aliphatic radical; R2 is a substituted sulfur, nitrogen or phosphorus atom; R3 is hydrogen, halogen or an aliphatic radical; R4, R5 are hydrogen, nitro, halogen, cyano, thiocyanato, or an aliphatic radical; R6 is hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R7, R8, R9 are hydrogen, C1-C6-alkyl, but at most one of the radicals R7, R8 and R9 is hydrogen; and their tautomers and agriculturally useful salts are described. Moreover, the invention relates to processes for preparing compounds of the formula I, to compositions comprising them and to the use of the compounds of the formula I and of the compositions comprising them for controlling harmful plants.
    Type: Grant
    Filed: January 3, 2002
    Date of Patent: May 20, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Neidlein, Norbert Götz, Ernst Baumann, Wolfgang von Deyn, Steffen Kudis, Roland Götz, Klaus Langemann, Guido Mayer, Ulf Misslitz, Matthias Witschel, Martina Otten, Karl-Otto Westphalen, Helmut Walter
  • Patent number: 6475957
    Abstract: Cycloalkyl-substituted benzoylpyrazoles of the formula I where the variables have, for example, the following meanings: R1 is hydrogen, nitro, halogen, cyano, thiocyanato, or an unsubstituted or substituted aliphatic radical; R2 is an unsubstituted or substituted aliphatic radical, halogen, nitro, or substituted sulfonyl or amino groups, R3 is hydrogen, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkynyl; R4, R5 are hydrogen, nitro, halogen, cyano, thiocyanato, an unsubstituted or substituted aliphatic radical or substituted sulfonyl or amino groups; R6 is hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R7 is a cyclic ring system having 3-14 ring atoms; R16 is hydroxyl or a substituted hydroxyl group; and their tautomers or agriculturally useful salts are described.
    Type: Grant
    Filed: December 27, 2001
    Date of Patent: November 5, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Neidlein, Norbert Götz, Ernst Baumann, Wolfgang von Deyn, Steffen Kudis, Roland Götz, Klaus Langemann, Guido Mayer, Ulf Misslitz, Matthias Witschel, Martina Otten, Karl-Otto Westphalen, Helmut Walter
  • Publication number: 20020103245
    Abstract: The present invention relates to certain pyrazole derivatives of Formula (I): 1
    Type: Application
    Filed: July 19, 2001
    Publication date: August 1, 2002
    Inventors: David Michael Goldstein, Sharada Shenvi Labadie, David Mark Rotstein, Eric Brian Sjogren, Francisco Xavier Talamas
  • Patent number: 6420317
    Abstract: Benzoylpyrazoles of the formula (I) and their use as herbicides are described. In the formula (I), R1, R2, R3, R4 and R5 are various radicals and n is from 0 to 2.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: July 16, 2002
    Assignee: Aventis CropScience GmbH
    Inventors: Monika Schmitt, Andreas van Almsick, Rainer Preuss, Lothar Willms, Thomas Auler, Hermann Bieringer, Felix Thürwächter
  • Publication number: 20020058816
    Abstract: Pyrazole carboxamide derivatives of the formula: 1
    Type: Application
    Filed: July 3, 2001
    Publication date: May 16, 2002
    Inventors: Cheryl P. Kordik, Timothy W. Lovenberg, Allen B. Reitz
  • Publication number: 20020016468
    Abstract: The invention relates to 1-arylpyrazole-3-thiocarboxamide derivatives of formula (I): 1
    Type: Application
    Filed: June 24, 1999
    Publication date: February 7, 2002
    Applicant: Rhone-Poulenc Agrochimie
    Inventors: DAVID TREADWAY MANNING, MICHAEL PILATO, TAI-TEH WU, DAVID WILLIAM HAWKINS
  • Patent number: 6322775
    Abstract: The present invention relates to novel cosmetic compositions, in particular for coloring the skin and/or the hair, comprising, in a cosmetically acceptable support, at least one 4,5-pyrazolinedione. The invention also relates to novel 4,5-pyrazolinediones, to processes for their preparation and to their uses in the cosmetics field.
    Type: Grant
    Filed: January 6, 1999
    Date of Patent: November 27, 2001
    Assignee: L'Oreal S.A.
    Inventors: Gérard Malle, Laurent Vidal
  • Patent number: H1942
    Abstract: Novel herbicidal compounds, compositions containing them, and methods for their preparation and use in controlling weeds are disclosed. The novel herbicidal compounds are 3-(pyrazolylphenyl)propanoic acids and derivatives having the formula: wherein X is H or halogen; Y is halogen, trihaloalkyl or cyano; Z and R are halogen; R1 is carboxyl or agriculturally acceptable salt thereof, cyano, alkoxycarbonyl, alkylthiocarbonyl, alkoxyalkoxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, or alkylsulfonylaminocarbonyl; and R2 is hydrogen or lower alkyl.
    Type: Grant
    Filed: September 1, 1998
    Date of Patent: February 6, 2001
    Assignee: FMC Corporation
    Inventors: George Theodoridis, Scott D. Crawford, Lester L. Maravetz