Having -c(=x)-, Wherein X Is Chalcogen Bonded Directly To The Diazole Ring Patents (Class 548/369.4)
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Patent number: 7456133Abstract: The invention relates to novel aryl ketones of the formula (I) in which A1, A2, Q, R1, R2, X, Y and Z are as defined in the description, their use as herbicides and processes and intermediates for their preparation.Type: GrantFiled: July 10, 2006Date of Patent: November 25, 2008Assignee: Bayer CropScience AGInventors: Stefan Herrmann, Dorothee Hoischen, Kristian Kather, Klaus-Helmut Muller, Otto Schallner, Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen
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Patent number: 7442799Abstract: A method is disclosed for preparing a 2-substituted-5-oxo-3-pyrazolidinecarboxylate compound of Formula I. The method comprises contacting a succinic acid derivative of the formula R1OC(O)C(H)(X)C(R2a)(R2b)C(O)Y (i.e. Formula II)wherein X and Y are leaving groups and L, R1, R2a and R2b are as defined in the disclosure, with a substituted hydrazine of the formula LNHNH2 (i.e. Formula III) in the presence of a suitable acid scavenger and solvent. Also disclosed is the preparation of compounds of Formula IV wherein X1, R6, R7, R8a, R8b, R9, and n are as defined in the disclosure. Also disclosed is a composition comprising on a weight basis about 20 to 99% of the compound of Formula II wherein R1, R2a, R2b, R3, R4 and R5 are as defined in the disclosure; X is Cl, Br or I; and Y is F, Cl, Br or I; provided that when R2a and R2b are each H, and X and Y are each Cl then R1 is other than benzyl and when R2a and R2b are each phenyl, and X and Y are each Cl, then R1 is other than methyl or ethyl.Type: GrantFiled: March 25, 2004Date of Patent: October 28, 2008Assignee: E.I. du Pont de Nemours and CompanyInventor: Gary David Annis
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Publication number: 20080254990Abstract: What is described are 4-(3-aminobenzoyl)-1,3-dimethylpyrazoles of the general formula (I) and their use as herbicides. In this general formula (I), R1 and R2 are radicals such as hydrogen and organic radicals, such as alkyl, alkenyl and alkynyl. Y is hydrogen or a protective group, such as tosyl.Type: ApplicationFiled: April 10, 2008Publication date: October 16, 2008Applicant: Bayer CropScience AGInventors: Ines Heinemann, Andreas van Almsick, Lothar Willms, Monika Schmitt, Jan Dittgen, Martin Hills, Heinz Kehne, Christopher Rosinger, Dieter Feucht
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Publication number: 20080254991Abstract: 4-(3-Aminobenzoyl)-1-ethylpyrazoles and their use as herbicides What is described are 4-(3-aminobenzoyl)-1-ethylpyrazoles of the general formula (I) and their use as herbicides. In this general formula (I), R1 and R2are radicals such as hydrogen and organic radicals, such as alkyl, alkenyl and alkynyl. Y is hydrogen or a protective group, such as tosyl.Type: ApplicationFiled: April 10, 2008Publication date: October 16, 2008Applicant: Bayer CropScience AGInventors: Ines Heinemann, Andreas van Almsick, Lothar Willms, Monika Schmitt, Jan Dittgen, Martin Hills, Heinz Kehne, Christopher Rosinger, Dieter Feucht
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Publication number: 20080254992Abstract: What is described are 4-(3-aminobenzoyl)pyrazoles of the general formula (I) and their use as herbicides. In this formula (I), R1 and R2 are radicals such as hydrogen and organic radicals, such as alkyl, alkenyl and alkynyl. Y is hydrogen or a protective group, such as tosyl.Type: ApplicationFiled: April 10, 2008Publication date: October 16, 2008Applicant: Bayer CropScience AGInventors: Ines Heinemann, Andreas van Almsick, Lothar Willms, Monika Schmitt, Jan Dittgen, Martin Hills, Heinz Kehne, Christopher Rosinger, Dieter Feucht
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Publication number: 20080214642Abstract: N-benzoyl-5-hydroxy-5-phenylpyrazolines of the formula I in which the substituents are as defined below: L1, L2 are hydrogen, halogen, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl; L3, L4, L5 are alkyl or one of the groups mentioned under L1 and L2; X is oxygen or sulfur; R1 is halogen, nitro, cyano, NR?2, alkyl, haloalkyl, alkoxy, alkenyl, haloalkyl, alkynyl, haloalkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, phenyl, 5- or 6-membered heterocyclyl or hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; R? independently of one another are hydrogen or alkyl; m is 1, 2, 3, 4 or 5; R2 is hydrogen or alkyl; R3 is hydrogen, nitro, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl, haloalkynyl or NR?2, where R4 is hydrogen, halogen, nitro, cyano, NR?2, alkyl, haloalkyl, COOR? or 5- or 6-membered heterocyclyl or hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; where the variables mentioned above maType: ApplicationFiled: May 24, 2006Publication date: September 4, 2008Inventors: Markus Gewehr, Jochen Dietz, Thomas Grote, Andreas Gypser, Matthias Niedenbruck
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Publication number: 20080182886Abstract: Novel 5-hydroxypyrazolines of the formula I in which the substituents are as defined below: B is phenyl, naphthyl or 5- or 6-membered hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; A is C?O, C?S or SO2; W is CX1X2; X1, X2 are hydrogen, fluorine, chlorine or bromine; R1 is alkyl, haloalkyl, alkenyl, haloalkenyl, alkynyl or haloalkynyl, cycloalkyl, cycloalkenyl, cycloalkynyl, phenyl, 5- or 6-membered heterocyclyl or hetaryl which contains one to four heteroatoms from the group consisting of O, N and S; R2 is hydrogen or alkyl; R3 is hydrogen, nitro, cyano, alkyl, haloalkyl, alkoxy, haloalkoxy, alkenyl, haloalkenyl, alkynyl, haloalkynyl or NR?2, where R? independently of one another are hydrogen or alkyl; R4 is hydrogen, halogen, nitro, cyano, NR?2, alkyl, haloalkyl, COOR? or 5- or 6-membered hetaryl or heterocyclyl; where the variables mentioned above may be substituted according to the description; processes for their preparation, their use for controlliType: ApplicationFiled: May 24, 2006Publication date: July 31, 2008Applicant: BASF AktiengesellschaftInventors: Markus Gewehr, Jochen Dietz, Thomas Grote, Andreas Gypser, Matthias Niedenbruck
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Publication number: 20080167468Abstract: The present invention relates to a diastereomeric mixture of Silacycle Compounds and methods for using the diastereomeric mixture of Silacycle Compounds for stereoselective synthesis.Type: ApplicationFiled: June 6, 2007Publication date: July 10, 2008Applicant: THE TRUSTEES OF COLUMBIA UNIVERSITY IN THE CITY OF NEW YORKInventors: James Lincoln Leighton, Richard Berger, Seiji Shirakawa, Gregory T. Notte
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Patent number: 7396939Abstract: What is described are 3-cyclopropyl-4-(3-amino-2-methylbenzoyl)pyrazoles of the formula (I) and their use as herbicides. In this formula (I), R1, R2, R3, R4 and R5 are various radicals.Type: GrantFiled: December 8, 2005Date of Patent: July 8, 2008Assignee: Bayer CropScience GmbHInventors: Monika Schmitt, Lothar Willms, Ines Heinemann, Andreas Van Almsick, Thomas Auler, Martin Hills, Heinz Kehne, Dieter Feucht
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Publication number: 20080064682Abstract: A compound represented by formula (I): (wherein Ar1 represents a phenyl group which may have 1 to 3 substituents, or a non-substituted 5- or 6-membered aromatic heterocyclic group; Ar2 represents (i) a non-substituted phenyl group, (ii) a phenyl group which has been substituted by a lower alkyl group having 1 to 3 groups or atoms selected from among a carbamoyl group, an amino group, a hydroxyl group, a lower alkoxy group, and a halogen atom, or (iii) a 5- or 6-membered nitrogen-containing aromatic heterocyclic group which has been substituted by 1 to 3 groups or atoms selected from among a lower alkyl group, a lower alkynyl group, a lower alkanoyl group, a carbamoyl group, a cyano group, an amino group, a hydroxyl group, a lower alkoxy group, and a halogen atom; and X represents a group represented by formula (II): (wherein the ring structure represents a 4- to 7-membered heterocyclic group which may have, in addition to the nitrogen atom shown in formula (II), one heteroatom selected from among nitrType: ApplicationFiled: July 1, 2005Publication date: March 13, 2008Applicant: DAIICHI PHARMACEUTICAL CO., LTD.Inventors: Naoaki Kanaya, Takashi Ishiyama, Ryo Muto, Toshiyuki Watanabe, Yuichi Ochiai
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Patent number: 7153813Abstract: The invention relates to novel substituted aryl ketones of the formula (I) in which Z, X, R and n are as defined in the disclosure, to processes for their preparation and to their use as crop treatment agents, and to intermediates for preparing compounds of the formula (I).Type: GrantFiled: February 12, 2003Date of Patent: December 26, 2006Assignee: Bayer AktiengesellschaftInventors: Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen, Monika Schmitt
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Patent number: 7112554Abstract: The invention relates to novel aryl ketones of the formula (I) in which A1, A2, Q, R1, R2, X, Y and Z are as defined in the description, their use as herbicides and processes and intermediates for their preparation.Type: GrantFiled: April 29, 2002Date of Patent: September 26, 2006Assignee: Bayer Cropscience AGInventors: Stefan Herrmann, Dorothee Hoischen, Kristian Kather, Klaus-Helmut Müller, Otto Schallner, Hans-Georg Schwarz, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht
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Patent number: 6872691Abstract: What is described are herbicidal compositions comprising herbicidal compounds of the formula I and a compound which acts as safener. In the formula I, the symbols R1 to R4 denote hydrogen, halogen, alkyl and haloalkyl.Type: GrantFiled: November 20, 2002Date of Patent: March 29, 2005Assignee: Bayer CropScience GmbHInventors: Monika H. Schmitt, Lothar Willms, Frank Ziemer, Christopher Rosinger, Hermann Bieringer, Philipp Huff, Erwin Hacker
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Patent number: 6828276Abstract: There are described benzoylcyclohexanediones of the formula I, their preparation, and their use as herbicides and plant growth regulators. In this formula (I), C1, C2, C3 are cyclic radicals, X1 is a hetero atom, X2 is a chain of carbon atoms, L is a chain-like element, R1, R2, R3, R4, R5 are various radicals, and Y and Z are monoatomic bridge elements.Type: GrantFiled: August 30, 2001Date of Patent: December 7, 2004Assignee: Aventis CropScience GmbHInventors: Thomas Seitz, Andreas van Almsick, Lothar Willms, Hermann Bieringer, Thomas Auler, Hubert Menne
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Publication number: 20040110640Abstract: The invention relates to benzoylpyrazoles of the general formula (I), 1Type: ApplicationFiled: November 14, 2003Publication date: June 10, 2004Inventors: Hans-Georg Schwarz, Klaus-Helmut Mller, Stefan Herrmann, Dorothee Hoischen, Kristian Kather, Stefan Lehr, Otto Schallner, Mark Wilhelm Drewes, Peter Dahmen, Dieter Feucht, Rolf Pontzen
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Patent number: 6686318Abstract: The invention relates to new substituted aromatic amino compounds of the general formula (I) in which R1, R2, R3, R4 and Z have the meanings given in the description, to a process for their preparation, and to their use as herbicides.Type: GrantFiled: April 22, 2003Date of Patent: February 3, 2004Assignee: Bayer AktiengesellschaftInventors: Roland Andree, Mark Wilhelm Drewes, Kurt Findeisen, Joachim Kluth, Karl-Heinz Linker, Klaus-Helmut Müller, Otto Schallner, Markus Dollinger
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Patent number: 6605658Abstract: Stabilizing mixtures for organic polymers comprising: a) at least one compound belonging to the group of pyrazolones; b) at least one compound belonging to the group of organic phosphites or phosphonites; c) at least one compound belonging to the group of sterically hindered phenols; and d) at least one compound belonging to the group of sterically hindered amines. The above mixtures are useful in the stabilization to degradation caused by oxygen, heat and/or light, of organic polymers.Type: GrantFiled: November 22, 2000Date of Patent: August 12, 2003Assignee: Great Lakes Chemical (Europe) GmbHInventors: Fabio Broussard, Daniele Girelli, Maria Lucia Wis, Carlo Neri, Vincenzo Malatesta
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Publication number: 20030144530Abstract: A “one-pot” process is described herein for the production of pyrazole compounds of general formula (II) 1Type: ApplicationFiled: January 17, 2003Publication date: July 31, 2003Inventors: Harris Laurence James, Levett Philip Charles
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Patent number: 6566307Abstract: Pyrazoles of the formula I where: R1 is hydrogen, nitro, halogen, cyano, thiocyanato or an aliphatic radical; R2 is a substituted sulfur, nitrogen or phosphorus atom; R3 is hydrogen, halogen or an aliphatic radical; R4, R5 are hydrogen, nitro, halogen, cyano, thiocyanato, or an aliphatic radical; R6 is hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R7, R8, R9 are hydrogen, C1-C6-alkyl, but at most one of the radicals R7, R8 and R9 is hydrogen; and their tautomers and agriculturally useful salts are described. Moreover, the invention relates to processes for preparing compounds of the formula I, to compositions comprising them and to the use of the compounds of the formula I and of the compositions comprising them for controlling harmful plants.Type: GrantFiled: January 3, 2002Date of Patent: May 20, 2003Assignee: BASF AktiengesellschaftInventors: Ulf Neidlein, Norbert Götz, Ernst Baumann, Wolfgang von Deyn, Steffen Kudis, Roland Götz, Klaus Langemann, Guido Mayer, Ulf Misslitz, Matthias Witschel, Martina Otten, Karl-Otto Westphalen, Helmut Walter
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Patent number: 6475957Abstract: Cycloalkyl-substituted benzoylpyrazoles of the formula I where the variables have, for example, the following meanings: R1 is hydrogen, nitro, halogen, cyano, thiocyanato, or an unsubstituted or substituted aliphatic radical; R2 is an unsubstituted or substituted aliphatic radical, halogen, nitro, or substituted sulfonyl or amino groups, R3 is hydrogen, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C2-C6-alkenyl or C2-C6-alkynyl; R4, R5 are hydrogen, nitro, halogen, cyano, thiocyanato, an unsubstituted or substituted aliphatic radical or substituted sulfonyl or amino groups; R6 is hydrogen, halogen, C1-C6-alkyl, C1-C6-alkoxy, C3-C8-cycloalkyl; R7 is a cyclic ring system having 3-14 ring atoms; R16 is hydroxyl or a substituted hydroxyl group; and their tautomers or agriculturally useful salts are described.Type: GrantFiled: December 27, 2001Date of Patent: November 5, 2002Assignee: BASF AktiengesellschaftInventors: Ulf Neidlein, Norbert Götz, Ernst Baumann, Wolfgang von Deyn, Steffen Kudis, Roland Götz, Klaus Langemann, Guido Mayer, Ulf Misslitz, Matthias Witschel, Martina Otten, Karl-Otto Westphalen, Helmut Walter
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Publication number: 20020103245Abstract: The present invention relates to certain pyrazole derivatives of Formula (I): 1Type: ApplicationFiled: July 19, 2001Publication date: August 1, 2002Inventors: David Michael Goldstein, Sharada Shenvi Labadie, David Mark Rotstein, Eric Brian Sjogren, Francisco Xavier Talamas
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Patent number: 6420317Abstract: Benzoylpyrazoles of the formula (I) and their use as herbicides are described. In the formula (I), R1, R2, R3, R4 and R5 are various radicals and n is from 0 to 2.Type: GrantFiled: March 29, 2001Date of Patent: July 16, 2002Assignee: Aventis CropScience GmbHInventors: Monika Schmitt, Andreas van Almsick, Rainer Preuss, Lothar Willms, Thomas Auler, Hermann Bieringer, Felix Thürwächter
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Publication number: 20020058816Abstract: Pyrazole carboxamide derivatives of the formula: 1Type: ApplicationFiled: July 3, 2001Publication date: May 16, 2002Inventors: Cheryl P. Kordik, Timothy W. Lovenberg, Allen B. Reitz
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Publication number: 20020016468Abstract: The invention relates to 1-arylpyrazole-3-thiocarboxamide derivatives of formula (I): 1Type: ApplicationFiled: June 24, 1999Publication date: February 7, 2002Applicant: Rhone-Poulenc AgrochimieInventors: DAVID TREADWAY MANNING, MICHAEL PILATO, TAI-TEH WU, DAVID WILLIAM HAWKINS
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Patent number: 6322775Abstract: The present invention relates to novel cosmetic compositions, in particular for coloring the skin and/or the hair, comprising, in a cosmetically acceptable support, at least one 4,5-pyrazolinedione. The invention also relates to novel 4,5-pyrazolinediones, to processes for their preparation and to their uses in the cosmetics field.Type: GrantFiled: January 6, 1999Date of Patent: November 27, 2001Assignee: L'Oreal S.A.Inventors: Gérard Malle, Laurent Vidal
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Patent number: H1942Abstract: Novel herbicidal compounds, compositions containing them, and methods for their preparation and use in controlling weeds are disclosed. The novel herbicidal compounds are 3-(pyrazolylphenyl)propanoic acids and derivatives having the formula: wherein X is H or halogen; Y is halogen, trihaloalkyl or cyano; Z and R are halogen; R1 is carboxyl or agriculturally acceptable salt thereof, cyano, alkoxycarbonyl, alkylthiocarbonyl, alkoxyalkoxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, or alkylsulfonylaminocarbonyl; and R2 is hydrogen or lower alkyl.Type: GrantFiled: September 1, 1998Date of Patent: February 6, 2001Assignee: FMC CorporationInventors: George Theodoridis, Scott D. Crawford, Lester L. Maravetz