Plural Ring Hetero Atoms In The Hetero Ring Patents (Class 549/30)
  • Patent number: 4230720
    Abstract: Compounds of the formula ##STR1## wherein R is alkyl having 1-4 carbon atoms;R.sup.1 is alkyl having 1-4 carbon atoms, or alkoxy having 1-4 carbon atoms;R.sup.2 is hydrogen or alkyl having 1-4 carbon atoms;X is oxygen or sulfur;X.sup.1 is oxygen or sulfur and n is 0, 1 or 2 which are useful as insecticides and acaricides.
    Type: Grant
    Filed: July 30, 1979
    Date of Patent: October 28, 1980
    Assignee: Stauffer Chemical Company
    Inventor: Francis H. Walker
  • Patent number: 4225612
    Abstract: New cyclopropane compounds have the formula ##STR1## wherein Y and Z each independently is oxygen or sulfur and X is chlorine, bromine or OR in which R is hydrogen, a salt-forming cation, an alkyl group or residues of certain other alcohols. The compounds are pesticides or intermediates therefore.
    Type: Grant
    Filed: September 17, 1979
    Date of Patent: September 30, 1980
    Assignee: Shell Oil Company
    Inventor: James E. Powell
  • Patent number: 4220561
    Abstract: 1,3-Oxathiane and 1,3-oxathiolane derivatives, some which are new, are disclosed as being useful as perfuming and flavoring agents for the preparation of perfumes and perfumed articles and for the manufacture of artificial flavors, flavored foodstuffs, animal feeds, beverages, pharmaceutical preparations and tobacco products.
    Type: Grant
    Filed: June 10, 1977
    Date of Patent: September 2, 1980
    Assignee: Firmenich SA
    Inventors: Max Winter, deceased, by Pierre Mottu, executor
  • Patent number: 4212883
    Abstract: Sulfonic acid-N'-methylamide-N'-sulfenyl-N-methyl-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1-4 carbon atoms in each alkyl group, phenyl substituted in the o- or m-position by halogen or by alkyl with 1-4 carbon atoms, or phenyl substituted in the o-, m- or p-position by NO.sub.2, CF.sub.3 or CN, andR.sup.2 is phenyl, naphthyl, benzodioxolanyl or indanyl; phenyl, naphthyl, benzodioxolanyl or indanyl substituted by trihalogenomethyl, halogen, nitro, cyano, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto or dialkylamino wherein each hydrocarbon portion has 1-4 carbon atoms; cycloalkyl of 5-7 carbon atoms, or ##STR2## in which R .sup.3 and R.sup.4 each independently is cyano or alkyl, alkoxy, alkylthio or alkoxycarbonyl with 1-4 carbon atoms in each alkyl group, or R.sup.3 and R.sup.4 together form a ring, or, provided that R.sup.1 is a NO.sub.2 -substituted phenyl, R.sup.3 and R.sup.
    Type: Grant
    Filed: April 24, 1978
    Date of Patent: July 15, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Peter Siegel, Engelbert Kuhle, Ingeborg Hammann, Bernhard Homeyer, Wolfgang Behrenz
  • Patent number: 4212887
    Abstract: N-Methyl-N-(sulphonic acid amide-N'-sulphenyl)-carbamic acid esters of the formula ##STR1## in which R.sup.1 is dialkylamino with 1 to 4 carbon atoms in each alkyl radical, phenyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trihalogenomethyl substituent,R.sup.2 is alkyl with 2 to 8 carbon atoms, cycloalkyl, phenyl or cycloalkyl or phenyl carrying at least one halogen, alkyl with 1 to 4 carbon atoms, nitro or trifluoromethyl substituent, andR.sup.3 is phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl; phenyl, naphthyl, benzodioxolanyl, dihydrobenzofuranyl or indanyl substituted at least once by trihalogenomethyl, halogen, nitro, cyano, cycloalkyl, formamidino, dioxanyl or dioxolanyl, or by alkyl, alkenyl, alkynyl, alkoxy, alkenoxy, alkynoxy, alkylmercapto, alkenylmercapto, alkynylmercapto or dialkylamino, each with up to 4 carbon atoms per aliphatic moiety, or an oxime radical of the formula ##STR2## R.sup.4 and R.sup.
    Type: Grant
    Filed: October 2, 1978
    Date of Patent: July 15, 1980
    Assignee: Bayer Aktiengesellschaft
    Inventors: Alfons Hartmann, Engelbert Kuhle, Ingeborg Hammann, Wolfgang Behrenz, Bernhard Homeyer
  • Patent number: 4189435
    Abstract: 5,6-Dihydro-2-methyl-1,4-oxathiin derivatives are prepared by chlorinolysis of an appropriate 1,3-oxathiolane derivative to generate alkene-sulfenic acid, followed by cyclization and loss of hydrogen chloride to form said product.
    Type: Grant
    Filed: September 12, 1978
    Date of Patent: February 19, 1980
    Inventor: Wha S. Lee
  • Patent number: 4182716
    Abstract: This method of making 5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide is based on the use of an oxathiolane, namely, 2-methyl-N-phenyl-1,3-oxathiolane-2-acetamide, which may be formed by condensing 2-mercaptoethanol with acetoacetanilide under acidic conditions in a solvent medium (aromatic hydrocarbon, chlorinated hydrocarbon or alkyl ester of an aliphatic acid). The said oxathiolane, with or without purification, is reacted with hydrogen peroxide in water or in a water-organic solvent mixture under basic conditions in the presence of a catalytic amount of a metal compound such as sodium tungstate to form 2-methyl-N-phenyl-1,3-oxathiolane-2-acetamide 3-oxide.
    Type: Grant
    Filed: November 8, 1978
    Date of Patent: January 8, 1980
    Assignee: Uniroyal, Ltd.
    Inventors: Andrew A. Znotins, Arthur D. Brewer
  • Patent number: 4169894
    Abstract: Unsymmetrical N-substituted bis-carbamoyloxy disulfide compounds exhibit outstanding nematocidal, miticidal and insecticidal activity, coupled with substantially reduced mammalian toxicity and phytotoxicity as compared to known pesticidal compounds having a comparable spectrum of activity against insect, arachnid and nematode pests.
    Type: Grant
    Filed: March 28, 1977
    Date of Patent: October 2, 1979
    Assignee: Union Carbide Corporation
    Inventor: Themistocles D. J. D'Silva
  • Patent number: 4166864
    Abstract: Unsymmetrical bis-arylcarbamate disulfide compounds exhibit outstanding miticidal and insecticidal activity, coupled with substantially reduced mammalian toxicity and phytotoxicity as compared to known pesticidal compounds having a comparable spectrum of activity against insect and mite pests.
    Type: Grant
    Filed: March 28, 1977
    Date of Patent: September 4, 1979
    Assignee: Union Carbide Corporation
    Inventor: Themistocles D. J. D'Silva