The Chalcogen, X, Is Part Of A -c(=x)x- Group Or A -x-x- Group, Wherein The X's Are The Same Or Diverse Chalcogens (e.g., -coo-hch-oxirane, Etc.) Patents (Class 549/557)
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Patent number: 5218074Abstract: The invention provides epoxy resins having the following structure: ##STR1## The cross-linked epoxy resins have non-linear optical properties. The group "Z" constitutes a nonlinear optical chromophone having stilbene, azo, azomethine or propargyl moieties as linking units.Type: GrantFiled: September 17, 1991Date of Patent: June 8, 1993Assignees: Siemens Aktiengesellschaft, Siemens AktiengesellschaftInventors: Jens Nordmann, Heinz Hacker
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Patent number: 5187298Abstract: Novel laser-optical recording elements which can be repeatedly erased and recorded on contain recording layers (a) which exhibit enantiotropic, ferroelectric smectic liquid crystalline (S.sub.C*) behavior, so that they can be switched back and forth between two thermodynamically stable, optically distinguishable ferroelectric smectic liquid crystlaline S.sub.C* order states on exposure to a laser beam of sufficient luminous power, by applying an external electric field. The recording layers (a) themselves consist mainly or exclusively of novel polymers P having chiral mesogenic side groups.Type: GrantFiled: May 18, 1990Date of Patent: February 16, 1993Assignee: BASF AktiengesellschaftInventors: Kark-Heinz Etzbach, Gerhard Wagenblast, Wolfgang Brox, Axel Paul, Volker Bach
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Patent number: 5182394Abstract: The liquid crystalline compounds of the structure ##STR1## where Ar represents phenylene (e.g., bonded in their para positions) and B represents a cyclohydrocarbylene bridging group such as cyclohexylene or phenylene, are disclosed.Type: GrantFiled: January 14, 1992Date of Patent: January 26, 1993Assignee: Akzo N.V.Inventor: Ki-Soo Kim
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Patent number: 5138078Abstract: A compound of the formula (I) ##STR1## wherein R is hydrogen, methyl of C.sub.2 -C.sub.5 alkyl and R.sup.1 is O-phenylene, a saturated or unsaturated 1,2-cyclohexylene group; a 2,3-bicyclo[2.2.2]-hept-5-enyl group of the formula (II) ##STR2## or a saturated or unsaturated aliphatic group of about 2 to about 20 carbon atoms; said O-phenylene is optionally substituted in the ring by one or two alkyl groups of from 1 to 4 carbon atoms; said 1,2-cyclohexylene and bicyclo groups are optionally substituted by one or two alkyl groups of from 1 to 4 carbon atoms and/or by one to six chlorine or bromine atoms; and said aliphatic group is optionally substituted by one or more chlorine or bromine atoms. This compound can be used as a coating compound when mixed with curing agents.Type: GrantFiled: December 10, 1990Date of Patent: August 11, 1992Assignee: Ciba-Geigy CorporationInventor: Vincent Brytus
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Patent number: 5004817Abstract: Compounds having the formula (I): ##STR1## wherein: M is an alkali or alkaline-earth metal or a C.sub.1 -C.sub.18 alkyl group;X is a group selected from --CH.sub.2 --, --CO--, --CH.sub.2 --CO--, --CH(CH.sub.3)--CO--,p is 0 or 1;Ar is a simple or condensed aromatic ring or Ar represents two or more aromatic nuclei bonded either by a simple bond or by an --O--, --S--, --SO.sub.2 --, --SO--, --CO--, --CS--, or --NH-- group;y is H or CH.sub.3 ;m is 1 when Y=--CH.sub.3, or an integer from 1 to 5 (including both values) when Y=H; n is a number ranging from 1 to 500 (including both values); andZ is H; a C.sub.1 -C.sub.18 alkyl; benzyl; glycidyl; acetyl; allyl; --CO--NH--R or --CO--NH--R.sub.1 --NCO group.Type: GrantFiled: February 27, 1989Date of Patent: April 2, 1991Assignee: Montefibre, S.p.A.Inventors: Catia Bastioli, Salvatore Garlisi, Dario Fornara, Vittorio Bellotti
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Patent number: 4999048Abstract: A method for reducing pesticide drift caused by crystallization of a pesticide from a pesticide spraying formulation. Crystallization of a pesticide from a pesticide spraying formulation is suppressed by incorporating an expoxidized vegetable oil into the formulation. The method increases pesticidal efficacy of a pesticide applied in the form of a pesticide spraying formulation. A pesticide spraying formulation is provided which comprises a pesticide, a diluent and an epoxidized vegetable oil.Type: GrantFiled: September 21, 1989Date of Patent: March 12, 1991Assignee: Canbra Foods Ltd.Inventor: Donald Freepons
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Patent number: 4931584Abstract: The invention relates to novel monoesters and diesters of 9,10-endoethano-9,10-dihydroanthracene-11,11-dicarboxylic acid.These novel monoesters and diesters correspond to the following structural chemical formula (II): ##STR1## in which R.sup.1 and R.sup.2 are identical or different and can represent H, an alkali metal or alkaline earth metal atom, a linear or branched alkyl group having from 1 to 6 carbon atoms, an alicyclic group having from 3 to 6 carbon atoms, an alkenyl group having from 2 to 6 carbon atoms, defined in their cis or trans variety, or an alkynyl group having from 2 to 6 carbon atoms, the said groups optionally being substituted by one or more functional groups such as ether, epoxide, halogeno, cyano, ester, aldehyde, ketone, aryl etc., where R.sup.1 and R.sup.2 cannot be H or ethyl simultaneously. These addition products constitute valuable intermediates for the preparation of methylidenemalonates in high yields and with a high purity.Type: GrantFiled: March 1, 1988Date of Patent: June 5, 1990Assignee: Laboratoires UPSAInventors: Nicole Bru-Magniez, Christian De Cock, Jacques Poupaert, Jean-Luc De Keyser, Pierre Dumont
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Patent number: 4885375Abstract: Optically active 3-(4-methoxyphenyl)glycidic acid alkyl esters of high enantiomeric purity can be prepared through optical resolution of a racemic or optically enriched sample of a 3-(4-methoxyphenyl) glycidic acid. The alkali metal salt of the acid, generated in situ by hydrolysis of the corresponding alkyl ester with an alkali metal hydroxide is contacted with a suitable resolving agent such as an optically pure amine to form the corresponding diastereomeric salts. The desired diastereomeric salt is separated from the mixture and transformed to an alkali metal salt, which optionally without isolation is converted into the desired alkyl ester of high enantiomeric purity.Type: GrantFiled: May 18, 1988Date of Patent: December 5, 1989Assignee: Marion Laboratories, Inc.Inventors: Hans Wynberg, Wolter ten Hoeve
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Patent number: 4835295Abstract: Chiral, nonracemic compounds of the general formula: ##STR1## wherein n=1 or 2, Y is a hydrogen, fluorine, chlorine or bromine atom, R' is an alkyl or alkoxy group having three to fifteen carbons, and R is an alkyl group having three to fifteen carbons, which are useful as ferroelectric liquid crystal components having high polarization are described. Also described are compounds of the same general formula in which X is OH, which are useful as synthetic intermediates in the preparation of the FLC components of the present invention.Type: GrantFiled: September 21, 1987Date of Patent: May 30, 1989Assignee: The University of Colorado Foundation, Inc.Inventors: David M. Walba, Homaune A. Razavi
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Patent number: 4820852Abstract: The subject of the invention is an improved process for the industrial scale preparation of the compounds of the formula ##STR1## and salts thereof by acylating the hexitols of the formula (II) with an anhydride of the formula (II) at a temperature of 0.degree.-30.degree. C. in the presence of an organic base and a catalyst of the formula (IV) in a dipolar-aprotic or aprotic solvent.Type: GrantFiled: March 31, 1988Date of Patent: April 11, 1989Assignee: Chinoin Gyogyszer es Vegyeszeti Termekek GyaraInventors: Tibor Szabo, Ildiko Vidra nee Sandor, Gyula Dalmadi, Judit Kaczmarek nee Sebestyen, Janos ri
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Patent number: 4764581Abstract: The invention relates to new, liquid-crystalline diglycidyle compounds of optionally ring-substituted 4-hydroxyphenyl 4-hydroxybenzoates, a synthesis of p-epoxypropoxy-phenyl p-epoxy-propoxybenzoate, furthermore epoxy resin mixtures containing the new diglycidyle compounds, and the use of the new diglycidyl compounds and the epoxy resin mixtures thereof in curable mixtures.Type: GrantFiled: June 22, 1987Date of Patent: August 16, 1988Assignee: Bayer AktiengesellschaftInventors: Hanns P. Muller, Roland Gipp, Heinrich Heine
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Patent number: 4758262Abstract: This invention relates to herbicidally active propylene oxide derivatives, agriculturally suitable compositions thereof, and a method of using them as herbicides or plant growth regulants.Type: GrantFiled: December 13, 1985Date of Patent: July 19, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Rafael Shapiro
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Patent number: 4755262Abstract: This invention relates to a method for the purification of glycidyl acrylate or glycidyl methacrylate. Specifically, the invention effects the purification by using a residual catalyst-inactivating additive and consequently produces highly purified glycidyl acrylate or glycidyl methacrylate containing substantially no epichlorohydrin and having a low chlorine content.Type: GrantFiled: October 26, 1987Date of Patent: July 5, 1988Assignee: Osaka Yuki Kagaku Kogyo Kabushiki KaishaInventors: Mitsumasa Matsunaga, Yukio Tanaka, Akio Tani, Shigeaki Matsumoto
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Patent number: 4705874Abstract: Ferroelectric (chiral) smectic liquid crystal compounds having an achiral core and chiral tail units derived from (2,3)-epoxyalkyloxiranemethanols possess a high ferroelectric polarization density. These newly made compounds exhibit high speed, multistate electro-optic switching properties which make them ideally suited to certain electro-optic display device applications.Type: GrantFiled: October 31, 1986Date of Patent: November 10, 1987Assignee: University Patents, Inc.Inventors: David M. Walba, Rohini Vohra
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Patent number: 4703110Abstract: The application discloses certain benzoic acid compounds, the same being more adequately described as benzoic acid derivatives having a para substituent which is a substituted phenyl radical attached to the benzoic acid in the para position by any one of a variety of linking groups, representative compounds being p-(3,4-diisopropylphenylcarbamoyl) benzoic acid and p-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylcarbamoyl)benzoic acid, pharmaceutical compositions thereof, method of treating therewith, method of diagnosis therewith, and method for the preparation thereof. The compounds and compositions are useful for diagnosis of leukemia types, the treatment of dermatological disorders, and as differentiation-inducing agents for neoplastic cells.Type: GrantFiled: July 8, 1985Date of Patent: October 27, 1987Assignee: Koichi ShudoInventor: Koichi Shudo
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Patent number: 4667044Abstract: Aromatic mono or polycarboxylic acid glycidyl esters are obtained in good yields and high purity by transesterification of the corresponding aromatic carboxylic acid alkyl esters with glycidol in the presence of weakly toxic catalysts, namely the alkali, ammonium, and alkaline earth metal salts of pseudohalogen hydride acids with readily polarizable anions.Type: GrantFiled: May 28, 1982Date of Patent: May 19, 1987Assignee: Degussa AktiengesellschaftInventors: Friedbert Nees, Peter Werle, Gunther Reissmann, Wolfgang Merk
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Patent number: 4652584Abstract: Phenoxypropanol derivatives having a 2-acetylenic moiety on the phenyl group thereof of the following formula (I): ##STR1## and their use as anti-hypertensives, e.g. in man. Also part of the invention are pharmaceutical compositions and intermediates used in the synthesis.Type: GrantFiled: July 13, 1984Date of Patent: March 24, 1987Assignee: McNeilab, Inc.Inventor: John R. Carson
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Patent number: 4638073Abstract: Ferroelectric (chiral) smectic liquid crystal compounds having an achiral core and chiral tail units derived from (2,3)-epoxyalkyloxiranemethanols possess a high ferroelectric polarization density. These newly made compounds exhibit high speed, multistate electro-optic switching properties which make then ideally suited to certain electro-optic display device applications.Type: GrantFiled: October 1, 1985Date of Patent: January 20, 1987Inventors: David M. Walba, Rohini Vohra
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Patent number: 4559407Abstract: There is described a novel process for the manufacture of hydroquinone derivatives of the formula ##STR1## wherein R represents an ether protecting group, and their conversion into d-.alpha.-tocopherol starting from compounds of the formula ##STR2## wherein R has the above significance.Type: GrantFiled: October 11, 1983Date of Patent: December 17, 1985Assignee: Hoffmann-La Roche Inc.Inventors: Richard Barner, Josef Hubscher
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Patent number: 4540802Abstract: An epoxy resin of the general formula: ##STR1## wherein X.sub.1 and X.sub.2 are --OH or ##STR2## and X.sub.3 is --OH, ##STR3## or a group of the general formula: ##STR4## in which X.sub.4, X.sub.5 and X.sub.6 are --OH or ##STR5## provided that at least one of X.sub.1 to X.sub.6 is ##STR6## The epoxy resin is prepared by reacting gallic acid or tannic acid with an epihalohydrin in the presence of a phase transfer catalyst and reacting the obtained reaction mixture with an aqueous alkali solution.Type: GrantFiled: May 3, 1983Date of Patent: September 10, 1985Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Haruo Tomita, Kazuya Yonezawa
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Patent number: 4419522Abstract: The invention relates to new hexitols having the general formula (I) and (II), ##STR1## wherein the hexitol skeleton is dulcitol, mannitol or iditol,X represents halogen, preferably bromine,R is a saturated or unsaturated C.sub.4-10 alkylcarbonyl group which also contains a free carboxy group, andR.sup.1 is hydrogen, a saturated or unsaturated C.sub.4-10 alkylcarbonyl group which also contains a free carboxy group, a saturated or unsaturated C.sub.2-10 alkylcarbonyl group, a saturated or unsaturated C.sub.4-10 alkylcarbonyl group which also contains an alkoxycarbonyl group, or a saturated or unsaturated C.sub.8-10 aralkylcarbonyl group,and salts of these compounds. The new compounds according to the invention have tumor-inhibiting affects.The above compounds are prepared according to the invention so that(a) a compound of the general formula (IX), whereinthe hexitol skeleton is dulcitol, mannitol or iditol,Q is a saturated or unsaturated C.sub.Type: GrantFiled: October 26, 1981Date of Patent: December 6, 1983Assignee: Chinoin Gyogyszer Vegyeszeti Termekek Gyara Rt.Inventors: Ilona Elekes, Laszlo Institoris, Kalman Medzihradsz, Laszlo tvos, Hedvig Medzihradszky-Schweiger, Katalin De Gleria, Janos Sugar, Somfai Relle, Sandor Eckhardt, Ivan Hidy, Sandor Kerpel-Fronius
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Patent number: 4374945Abstract: Certain substituted thioglycolates and thiopropionates were found useful as secondary stabilizers for polymers, particularly polyvinyl chloride, when used in conjunction with metal octanoates, such as zinc octanoate, as the primary stabilizer. The specific thioglycolates and thiopropionates are those formed by thio adducts to the double bond of a monomer, such as the product of reacting isooctyl thioglycolate with glycidyl acrylate, to provide isooctyl S-2(glycidyloxycarbonyl)ethyl thioglycolate, as an example.Type: GrantFiled: March 11, 1981Date of Patent: February 22, 1983Assignee: Witco Chemical CorporationInventors: Koei-Liang Liauw, Michael H. Fisch
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Patent number: 4346042Abstract: Processes for preparing (S) or (R) epihalohydrin and an (S) substituted glycerol intermediate are disclosed.Type: GrantFiled: May 5, 1980Date of Patent: August 24, 1982Assignee: Merck & Co., Inc.Inventors: John J. Baldwin, David E. McClure