The Chalcogen, X, Is Part Of A -c(=x)x- Group Or A -x-x- Group, Wherein The X's Are The Same Or Diverse Chalcogens (e.g., -coo-hch-oxirane, Etc.) Patents (Class 549/557)
  • Patent number: 5218074
    Abstract: The invention provides epoxy resins having the following structure: ##STR1## The cross-linked epoxy resins have non-linear optical properties. The group "Z" constitutes a nonlinear optical chromophone having stilbene, azo, azomethine or propargyl moieties as linking units.
    Type: Grant
    Filed: September 17, 1991
    Date of Patent: June 8, 1993
    Assignees: Siemens Aktiengesellschaft, Siemens Aktiengesellschaft
    Inventors: Jens Nordmann, Heinz Hacker
  • Patent number: 5187298
    Abstract: Novel laser-optical recording elements which can be repeatedly erased and recorded on contain recording layers (a) which exhibit enantiotropic, ferroelectric smectic liquid crystalline (S.sub.C*) behavior, so that they can be switched back and forth between two thermodynamically stable, optically distinguishable ferroelectric smectic liquid crystlaline S.sub.C* order states on exposure to a laser beam of sufficient luminous power, by applying an external electric field. The recording layers (a) themselves consist mainly or exclusively of novel polymers P having chiral mesogenic side groups.
    Type: Grant
    Filed: May 18, 1990
    Date of Patent: February 16, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Kark-Heinz Etzbach, Gerhard Wagenblast, Wolfgang Brox, Axel Paul, Volker Bach
  • Patent number: 5182394
    Abstract: The liquid crystalline compounds of the structure ##STR1## where Ar represents phenylene (e.g., bonded in their para positions) and B represents a cyclohydrocarbylene bridging group such as cyclohexylene or phenylene, are disclosed.
    Type: Grant
    Filed: January 14, 1992
    Date of Patent: January 26, 1993
    Assignee: Akzo N.V.
    Inventor: Ki-Soo Kim
  • Patent number: 5138078
    Abstract: A compound of the formula (I) ##STR1## wherein R is hydrogen, methyl of C.sub.2 -C.sub.5 alkyl and R.sup.1 is O-phenylene, a saturated or unsaturated 1,2-cyclohexylene group; a 2,3-bicyclo[2.2.2]-hept-5-enyl group of the formula (II) ##STR2## or a saturated or unsaturated aliphatic group of about 2 to about 20 carbon atoms; said O-phenylene is optionally substituted in the ring by one or two alkyl groups of from 1 to 4 carbon atoms; said 1,2-cyclohexylene and bicyclo groups are optionally substituted by one or two alkyl groups of from 1 to 4 carbon atoms and/or by one to six chlorine or bromine atoms; and said aliphatic group is optionally substituted by one or more chlorine or bromine atoms. This compound can be used as a coating compound when mixed with curing agents.
    Type: Grant
    Filed: December 10, 1990
    Date of Patent: August 11, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Vincent Brytus
  • Patent number: 5004817
    Abstract: Compounds having the formula (I): ##STR1## wherein: M is an alkali or alkaline-earth metal or a C.sub.1 -C.sub.18 alkyl group;X is a group selected from --CH.sub.2 --, --CO--, --CH.sub.2 --CO--, --CH(CH.sub.3)--CO--,p is 0 or 1;Ar is a simple or condensed aromatic ring or Ar represents two or more aromatic nuclei bonded either by a simple bond or by an --O--, --S--, --SO.sub.2 --, --SO--, --CO--, --CS--, or --NH-- group;y is H or CH.sub.3 ;m is 1 when Y=--CH.sub.3, or an integer from 1 to 5 (including both values) when Y=H; n is a number ranging from 1 to 500 (including both values); andZ is H; a C.sub.1 -C.sub.18 alkyl; benzyl; glycidyl; acetyl; allyl; --CO--NH--R or --CO--NH--R.sub.1 --NCO group.
    Type: Grant
    Filed: February 27, 1989
    Date of Patent: April 2, 1991
    Assignee: Montefibre, S.p.A.
    Inventors: Catia Bastioli, Salvatore Garlisi, Dario Fornara, Vittorio Bellotti
  • Patent number: 4999048
    Abstract: A method for reducing pesticide drift caused by crystallization of a pesticide from a pesticide spraying formulation. Crystallization of a pesticide from a pesticide spraying formulation is suppressed by incorporating an expoxidized vegetable oil into the formulation. The method increases pesticidal efficacy of a pesticide applied in the form of a pesticide spraying formulation. A pesticide spraying formulation is provided which comprises a pesticide, a diluent and an epoxidized vegetable oil.
    Type: Grant
    Filed: September 21, 1989
    Date of Patent: March 12, 1991
    Assignee: Canbra Foods Ltd.
    Inventor: Donald Freepons
  • Patent number: 4931584
    Abstract: The invention relates to novel monoesters and diesters of 9,10-endoethano-9,10-dihydroanthracene-11,11-dicarboxylic acid.These novel monoesters and diesters correspond to the following structural chemical formula (II): ##STR1## in which R.sup.1 and R.sup.2 are identical or different and can represent H, an alkali metal or alkaline earth metal atom, a linear or branched alkyl group having from 1 to 6 carbon atoms, an alicyclic group having from 3 to 6 carbon atoms, an alkenyl group having from 2 to 6 carbon atoms, defined in their cis or trans variety, or an alkynyl group having from 2 to 6 carbon atoms, the said groups optionally being substituted by one or more functional groups such as ether, epoxide, halogeno, cyano, ester, aldehyde, ketone, aryl etc., where R.sup.1 and R.sup.2 cannot be H or ethyl simultaneously. These addition products constitute valuable intermediates for the preparation of methylidenemalonates in high yields and with a high purity.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: June 5, 1990
    Assignee: Laboratoires UPSA
    Inventors: Nicole Bru-Magniez, Christian De Cock, Jacques Poupaert, Jean-Luc De Keyser, Pierre Dumont
  • Patent number: 4885375
    Abstract: Optically active 3-(4-methoxyphenyl)glycidic acid alkyl esters of high enantiomeric purity can be prepared through optical resolution of a racemic or optically enriched sample of a 3-(4-methoxyphenyl) glycidic acid. The alkali metal salt of the acid, generated in situ by hydrolysis of the corresponding alkyl ester with an alkali metal hydroxide is contacted with a suitable resolving agent such as an optically pure amine to form the corresponding diastereomeric salts. The desired diastereomeric salt is separated from the mixture and transformed to an alkali metal salt, which optionally without isolation is converted into the desired alkyl ester of high enantiomeric purity.
    Type: Grant
    Filed: May 18, 1988
    Date of Patent: December 5, 1989
    Assignee: Marion Laboratories, Inc.
    Inventors: Hans Wynberg, Wolter ten Hoeve
  • Patent number: 4835295
    Abstract: Chiral, nonracemic compounds of the general formula: ##STR1## wherein n=1 or 2, Y is a hydrogen, fluorine, chlorine or bromine atom, R' is an alkyl or alkoxy group having three to fifteen carbons, and R is an alkyl group having three to fifteen carbons, which are useful as ferroelectric liquid crystal components having high polarization are described. Also described are compounds of the same general formula in which X is OH, which are useful as synthetic intermediates in the preparation of the FLC components of the present invention.
    Type: Grant
    Filed: September 21, 1987
    Date of Patent: May 30, 1989
    Assignee: The University of Colorado Foundation, Inc.
    Inventors: David M. Walba, Homaune A. Razavi
  • Patent number: 4820852
    Abstract: The subject of the invention is an improved process for the industrial scale preparation of the compounds of the formula ##STR1## and salts thereof by acylating the hexitols of the formula (II) with an anhydride of the formula (II) at a temperature of 0.degree.-30.degree. C. in the presence of an organic base and a catalyst of the formula (IV) in a dipolar-aprotic or aprotic solvent.
    Type: Grant
    Filed: March 31, 1988
    Date of Patent: April 11, 1989
    Assignee: Chinoin Gyogyszer es Vegyeszeti Termekek Gyara
    Inventors: Tibor Szabo, Ildiko Vidra nee Sandor, Gyula Dalmadi, Judit Kaczmarek nee Sebestyen, Janos ri
  • Patent number: 4764581
    Abstract: The invention relates to new, liquid-crystalline diglycidyle compounds of optionally ring-substituted 4-hydroxyphenyl 4-hydroxybenzoates, a synthesis of p-epoxypropoxy-phenyl p-epoxy-propoxybenzoate, furthermore epoxy resin mixtures containing the new diglycidyle compounds, and the use of the new diglycidyl compounds and the epoxy resin mixtures thereof in curable mixtures.
    Type: Grant
    Filed: June 22, 1987
    Date of Patent: August 16, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hanns P. Muller, Roland Gipp, Heinrich Heine
  • Patent number: 4758262
    Abstract: This invention relates to herbicidally active propylene oxide derivatives, agriculturally suitable compositions thereof, and a method of using them as herbicides or plant growth regulants.
    Type: Grant
    Filed: December 13, 1985
    Date of Patent: July 19, 1988
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Rafael Shapiro
  • Patent number: 4755262
    Abstract: This invention relates to a method for the purification of glycidyl acrylate or glycidyl methacrylate. Specifically, the invention effects the purification by using a residual catalyst-inactivating additive and consequently produces highly purified glycidyl acrylate or glycidyl methacrylate containing substantially no epichlorohydrin and having a low chlorine content.
    Type: Grant
    Filed: October 26, 1987
    Date of Patent: July 5, 1988
    Assignee: Osaka Yuki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Mitsumasa Matsunaga, Yukio Tanaka, Akio Tani, Shigeaki Matsumoto
  • Patent number: 4705874
    Abstract: Ferroelectric (chiral) smectic liquid crystal compounds having an achiral core and chiral tail units derived from (2,3)-epoxyalkyloxiranemethanols possess a high ferroelectric polarization density. These newly made compounds exhibit high speed, multistate electro-optic switching properties which make them ideally suited to certain electro-optic display device applications.
    Type: Grant
    Filed: October 31, 1986
    Date of Patent: November 10, 1987
    Assignee: University Patents, Inc.
    Inventors: David M. Walba, Rohini Vohra
  • Patent number: 4703110
    Abstract: The application discloses certain benzoic acid compounds, the same being more adequately described as benzoic acid derivatives having a para substituent which is a substituted phenyl radical attached to the benzoic acid in the para position by any one of a variety of linking groups, representative compounds being p-(3,4-diisopropylphenylcarbamoyl) benzoic acid and p-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthylcarbamoyl)benzoic acid, pharmaceutical compositions thereof, method of treating therewith, method of diagnosis therewith, and method for the preparation thereof. The compounds and compositions are useful for diagnosis of leukemia types, the treatment of dermatological disorders, and as differentiation-inducing agents for neoplastic cells.
    Type: Grant
    Filed: July 8, 1985
    Date of Patent: October 27, 1987
    Assignee: Koichi Shudo
    Inventor: Koichi Shudo
  • Patent number: 4667044
    Abstract: Aromatic mono or polycarboxylic acid glycidyl esters are obtained in good yields and high purity by transesterification of the corresponding aromatic carboxylic acid alkyl esters with glycidol in the presence of weakly toxic catalysts, namely the alkali, ammonium, and alkaline earth metal salts of pseudohalogen hydride acids with readily polarizable anions.
    Type: Grant
    Filed: May 28, 1982
    Date of Patent: May 19, 1987
    Assignee: Degussa Aktiengesellschaft
    Inventors: Friedbert Nees, Peter Werle, Gunther Reissmann, Wolfgang Merk
  • Patent number: 4652584
    Abstract: Phenoxypropanol derivatives having a 2-acetylenic moiety on the phenyl group thereof of the following formula (I): ##STR1## and their use as anti-hypertensives, e.g. in man. Also part of the invention are pharmaceutical compositions and intermediates used in the synthesis.
    Type: Grant
    Filed: July 13, 1984
    Date of Patent: March 24, 1987
    Assignee: McNeilab, Inc.
    Inventor: John R. Carson
  • Patent number: 4638073
    Abstract: Ferroelectric (chiral) smectic liquid crystal compounds having an achiral core and chiral tail units derived from (2,3)-epoxyalkyloxiranemethanols possess a high ferroelectric polarization density. These newly made compounds exhibit high speed, multistate electro-optic switching properties which make then ideally suited to certain electro-optic display device applications.
    Type: Grant
    Filed: October 1, 1985
    Date of Patent: January 20, 1987
    Inventors: David M. Walba, Rohini Vohra
  • Patent number: 4559407
    Abstract: There is described a novel process for the manufacture of hydroquinone derivatives of the formula ##STR1## wherein R represents an ether protecting group, and their conversion into d-.alpha.-tocopherol starting from compounds of the formula ##STR2## wherein R has the above significance.
    Type: Grant
    Filed: October 11, 1983
    Date of Patent: December 17, 1985
    Assignee: Hoffmann-La Roche Inc.
    Inventors: Richard Barner, Josef Hubscher
  • Patent number: 4540802
    Abstract: An epoxy resin of the general formula: ##STR1## wherein X.sub.1 and X.sub.2 are --OH or ##STR2## and X.sub.3 is --OH, ##STR3## or a group of the general formula: ##STR4## in which X.sub.4, X.sub.5 and X.sub.6 are --OH or ##STR5## provided that at least one of X.sub.1 to X.sub.6 is ##STR6## The epoxy resin is prepared by reacting gallic acid or tannic acid with an epihalohydrin in the presence of a phase transfer catalyst and reacting the obtained reaction mixture with an aqueous alkali solution.
    Type: Grant
    Filed: May 3, 1983
    Date of Patent: September 10, 1985
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Haruo Tomita, Kazuya Yonezawa
  • Patent number: 4419522
    Abstract: The invention relates to new hexitols having the general formula (I) and (II), ##STR1## wherein the hexitol skeleton is dulcitol, mannitol or iditol,X represents halogen, preferably bromine,R is a saturated or unsaturated C.sub.4-10 alkylcarbonyl group which also contains a free carboxy group, andR.sup.1 is hydrogen, a saturated or unsaturated C.sub.4-10 alkylcarbonyl group which also contains a free carboxy group, a saturated or unsaturated C.sub.2-10 alkylcarbonyl group, a saturated or unsaturated C.sub.4-10 alkylcarbonyl group which also contains an alkoxycarbonyl group, or a saturated or unsaturated C.sub.8-10 aralkylcarbonyl group,and salts of these compounds. The new compounds according to the invention have tumor-inhibiting affects.The above compounds are prepared according to the invention so that(a) a compound of the general formula (IX), whereinthe hexitol skeleton is dulcitol, mannitol or iditol,Q is a saturated or unsaturated C.sub.
    Type: Grant
    Filed: October 26, 1981
    Date of Patent: December 6, 1983
    Assignee: Chinoin Gyogyszer Vegyeszeti Termekek Gyara Rt.
    Inventors: Ilona Elekes, Laszlo Institoris, Kalman Medzihradsz, Laszlo tvos, Hedvig Medzihradszky-Schweiger, Katalin De Gleria, Janos Sugar, Somfai Relle, Sandor Eckhardt, Ivan Hidy, Sandor Kerpel-Fronius
  • Patent number: 4374945
    Abstract: Certain substituted thioglycolates and thiopropionates were found useful as secondary stabilizers for polymers, particularly polyvinyl chloride, when used in conjunction with metal octanoates, such as zinc octanoate, as the primary stabilizer. The specific thioglycolates and thiopropionates are those formed by thio adducts to the double bond of a monomer, such as the product of reacting isooctyl thioglycolate with glycidyl acrylate, to provide isooctyl S-2(glycidyloxycarbonyl)ethyl thioglycolate, as an example.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: February 22, 1983
    Assignee: Witco Chemical Corporation
    Inventors: Koei-Liang Liauw, Michael H. Fisch
  • Patent number: 4346042
    Abstract: Processes for preparing (S) or (R) epihalohydrin and an (S) substituted glycerol intermediate are disclosed.
    Type: Grant
    Filed: May 5, 1980
    Date of Patent: August 24, 1982
    Assignee: Merck & Co., Inc.
    Inventors: John J. Baldwin, David E. McClure