Acyclic Carbon Bonded Directly To The Isocyanate Group Patents (Class 560/355)
  • Patent number: 5210286
    Abstract: Herein disclosed are an .alpha.-(aminocyclohexyl)alkylamine represented by the following general formula (II): ##STR1##wherein R represents hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms, provided that the amino group bonded to the cyclohexyl group may be in either of the 2-, 3- and 4-positions and a method for preparing it; an .alpha.-(isocyanatocyclohexyl)alkylisocyanate of Formula (II) wherein the amino groups are replaced with isocyanato groups and a method for preparing it; polyisocyanato-isocyanurate represented by the following general formula (IV): ##STR2##wherein R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: May 11, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Ryuji Haseyama, Masatoshi Takagi, Kouzou Hayashi, Katsuyoshi Sasagawa, Kazuyuki Kuroda, Taisaku Kano, Kiyoshi Shikai
  • Patent number: 5162575
    Abstract: The present invention relates to a process for producing isocyanates which comprises reacting an N-halogenated amide with an organic base in an essentially water-free modified Hofmann reaction using a soluble silver salt promoter in the presence of an organic solvent. Also disclosed is a process for producing a carbamate which comprises reacting an N-halogenated amide with an organic base in an essentially water-free modified Hofmann reaction using a soluble silver salt promoter in the presence of an alcohol solvent.
    Type: Grant
    Filed: April 1, 1991
    Date of Patent: November 10, 1992
    Assignee: Olin Corporation
    Inventor: Ming Shen
  • Patent number: 5149805
    Abstract: Monoblocked diisocyanates which contain little free and diblocked diisocyanate are obtained by a process which involves adding 1 mole of a blocking agent to a diisocyanate which is present in excess and subsequently removing the excess diisocyanate by thin film evaporation. The compounds produced are useful for the production of cataphoresis resins.
    Type: Grant
    Filed: September 13, 1988
    Date of Patent: September 22, 1992
    Assignee: Huels Aktiengesellschaft
    Inventors: Rainer Gras, Elmar Wolf, Josef Disteldorf, Werner Huebel, Horst Schnurbusch
  • Patent number: 5047097
    Abstract: A diisocyanate crosslinking agent having a minimum chain length of methylene groups from 25 to 45 which has a coiling-uncoiling ability in a cured solid propellant composition (under stress and relaxing of stress) as a result of the chain length and configuration imparts superior structural strength to the solid propellant composition. A preferred species is 1,37-heptatriacontane diisocyanate, OCN--(CH.sub.2).sub.37 --NCO, which is employed as an effective crosslinking agent in hydroxyl-terminated polybutadiene propellants.
    Type: Grant
    Filed: March 13, 1980
    Date of Patent: September 10, 1991
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: David C. Sayles
  • Patent number: 5021602
    Abstract: Novel compounds have at least one perfluorocyclobutane ring and at least two functional groups suitable for forming condensation polymers. Preferably the compounds have a structures represented by Formula II: ##STR1## wherein R and R' independently represent optionally inertly substituted groups; X and X' represent any molecular structures which link R and R' with the perfluorocyclobutane ring; n and n' are the number of G and G' groups, respectively; and G and G' independently represent any reactive functional groups or any groups convertible into reactive functional groups. The compound are preferably prepared by a process of thermally dimerizing trifluorovinyl compound to form a compounds of Formula IG.sub.n --R--X--CF.dbd.CF.sub.2wherein G represents G or G' in Formula II; X represents X or X' of Formual II; and n represents n or n' of Formula II, to form a compound having a perfluorocyclobutane group.
    Type: Grant
    Filed: June 9, 1989
    Date of Patent: June 4, 1991
    Assignee: The Dow Chemical Company
    Inventors: Katherine S. Clement, David A. Babb, Bobby R. Ezzell
  • Patent number: 5008447
    Abstract: This invention relates to a process for preparing polyurethanes having liquid crystal properties comprising reacting, in proportions corresponding to an NCO/OH equivalent ratio of from about 0.9:1 to 1.1:1, an organic polyhydroxyl compound with an organic diisocyanate having at least two phenylene groups and at least one carboxylic ester group. The organic diisocyanate comprises an aliphatic diisocyanate wherein at least one of the carboxylic ester groups connects an aliphatic group to a phenylene group or an aromatic diisocyanate wherein at least one of the carboxylic acid groups connects two phenylene groups.This invention further relates to preferred diisocyanates used in the process according to this invention.
    Type: Grant
    Filed: November 7, 1989
    Date of Patent: April 16, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Mormann, Barbara Brahm, Martin Brahm
  • Patent number: 4975514
    Abstract: A polyisocyanate composition containing an amide-modified product, obtained by modifying a polyisocyanate compound with a polybasic carboxylic acid in an equivalent ratio of carboxyl groups/isocyanate groups being at most 0.9.
    Type: Grant
    Filed: May 8, 1989
    Date of Patent: December 4, 1990
    Assignee: Asahi Glass Company, Ltd.
    Inventors: Hiroyuki Watanabe, Hiroshi Washita, Kazuhiko Kuga
  • Patent number: 4946854
    Abstract: Novel compounds of formula I ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3, R.sup.7, R.sup.8 and R.sup.9, independently of the others, is H or halogen,R.sup.4 is H, R.sup.10 CO-- or R.sup.11 NHCO-- wherein R.sup.10 is a C.sub.1 -C.sub.4 alkyl group which is unsubstituted or substituted by one to three identical or different substituents selected from the group consisting of halogen, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 - acyloxy and --COOG, wherein G is H, an alkali metal cation or an alkaline earth metal cation, and R.sup.11 is an unsubstituted or halo-substituted C.sub.1 -C.sub.4 alkyl or phenyl group,each of R.sup.5 and R.sup.6, independently of the other, is H, halogen, alkyl or haloalkyl andX is O, S(O)n or NH wherein n is 0, 1 or 2, the preparation of the novel compounds and their use against parasites in and on productive livestock and against insect pests, and novel starting materials and their preparation.
    Type: Grant
    Filed: December 5, 1988
    Date of Patent: August 7, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Maienfisch, Jean-Claude Gehret, Bruno Frei
  • Patent number: 4906674
    Abstract: A polyisocyanate composition, suitable for use in the production of elastomers by the RIM process, or foams, said composition being the product of reacting an imino-functional or enamine-containing compound having a molecular weight of at least 1000 with a stoichiometric excess of an organic polyisocyanate.
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: March 6, 1990
    Assignee: ICI Americas Inc/Imperial Chemical Industries PLC
    Inventors: Edward F. Cassidy, Herbert R. Gillis, Malcolm Hannaby, Jan W. Leenslag, Alain Parfondry
  • Patent number: 4855490
    Abstract: The present invention relates to a polyisocyanate adduct mixture which at a 100% solids concentration has an isocyanate content of about 4 to 19 weight percent and is liquid at room temperature. The adduct mixture is prepared from a biuret-containing polyisocyanate and a monohydroxy alcohol which contains 11 to 36 carbon atoms. The adduct mixture possesses good storage stability in common polyisocyanate solvents and good compatibility with apolar solvents. The present invention also relates to the use of the liquid polyisocyante adduct mixture in the process of curing alkyd or acrylic resins and to compositions containing the adduct mixture and alkyd or acrylic resins.
    Type: Grant
    Filed: October 25, 1988
    Date of Patent: August 8, 1989
    Assignee: Mobay Corporation
    Inventors: Peter Markusch, George A. Hudson, deceased
  • Patent number: 4840953
    Abstract: 9-(Substituted thio)-4H-pyrido[1,2-a]pyrimidin-4-one derivatives of the formula: ##STR1## wherein n is 0 or 1, R is --COR.sup.1, --CONR.sup.4 R.sup.5 or --CH.sub.2 R.sup.6, R.sup.1 is C.sub.1 -C.sub.5 alkyl, C.sub.3 -C.sub.7 cycloalkyl, allythio, styryl, phenoxymethyl, thienylmethyl, C.sub.6 -C.sub.10 aryl optionally substituted, benzyl optionally substituted or 5- or 6-membered heterocyclic group optionally substituted, R.sup.2 and R.sup.3 each is hydrogen, C.sub.1 -C.sub.5 alkyl, carboxy, C.sub.2 -C.sub.5 alkoxycarbonyl or benzyloxycarbonyl optionally substituted, R.sup.4 and R.sup.5 each is hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.3 -C.sub.7 cycloalkyl or phenyl optionally substituted, and R.sup.8 is pyridyl or phenyl optionally substituted) being useful as antiulcer agents are provided through several routes.
    Type: Grant
    Filed: June 15, 1988
    Date of Patent: June 20, 1989
    Assignee: Shionogi & Co., Ltd.
    Inventors: Shigeru Matsutani, Yukio Mizushima, Masami Doteuchi, Yasunobu Ishihara
  • Patent number: 4829099
    Abstract: Metabolically-acceptable, surgical adhesives are prepared from polyisocyanates having the structral formula: ##STR1## wherein R is a polyvalent aliphatic radical of about 1 to 10 carbon atoms or a polyvalent aromatic radical of 6 to about 24 carbon atoms;A is C, S or P;Z is O or S;Y is 1 when A is C or P, and 2 when A is S;n is 1 or 2;p is at least 1;q is 0 or 1, with the proviso that when A is carbon or sulfur, q is 0;r is 0 or 1, with the proviso that when A is carbon or sulfur, r is 0;X is a residue of an organic compound having active hydrogen-containing groups; andX' is a residue of an organic compound having at least 1 active hydrogen-containing group.
    Type: Grant
    Filed: July 17, 1987
    Date of Patent: May 9, 1989
    Assignee: Bioresearch, Inc.
    Inventors: William D. Fuller, Robert K. Blair, Murray Goodman
  • Patent number: 4736055
    Abstract: Oxime sulfonates of formula I ##STR1## wherein Y is a polymerizable unsaturated group or epoxide group or an --OH, --NHR.sup.5, --COOH, COOR.sup.6, --COCl, --CH.sub.2 Hal, --SO.sub.2 Cl or --NCO group, Z is an (x+y)-valent connecting member, R.sup.1 and R.sup.2 are monovalent organic radicals, m is 0 or 1, x is 1 or 2 and y is 1 or 2, can be converted into polymers which can be thermally or photochemically dissociated to form free sulfonic acid groups. Said polymers can therefore be used as photoresists which can be developed with aqueous alkalis.
    Type: Grant
    Filed: April 11, 1986
    Date of Patent: April 5, 1988
    Assignee: Ciba-Geigy Corporation
    Inventors: Kurt Dietliker, Werner Rutsch, Godwin Berner, Max Hunziker, Christopher G. Demmer
  • Patent number: 4633010
    Abstract: 1,3,5-Tris(1-isocyanatomethylethyl)benzene is disclosed as a component in coating formulations and the like.
    Type: Grant
    Filed: December 27, 1982
    Date of Patent: December 30, 1986
    Assignee: American Cyanamid Company
    Inventors: Balwant Singh, Peter S. Forgione
  • Patent number: 4574059
    Abstract: Decane-1,10-diisocyanates corresponding to the formula ##STR1## wherein R.sub.1 is an alkyl or cycloalkyl radical, and R.sub.
    Type: Grant
    Filed: February 27, 1985
    Date of Patent: March 4, 1986
    Assignee: ATOCHEM
    Inventors: Jacques Kervennal, Pierre Durual