Terpenic, Wherein The Number Of Carbons Is A Multiple Of Five (e.g., Linalool, Farnesol, Etc.) Patents (Class 568/875)
  • Patent number: 4125735
    Abstract: A process for the synthesis of perfume products, Vitamin E and intermediates described herein involving a coupling reaction. For instance, a process for the synthesis of dehydrophytol and Vitamin E comprising forming a C.sub.15 acetylene from hexahydropseudoionone and then coupling said acetylene with 1-acetoxy-4-chloro-3-methylbut-2-ene to form a C.sub.20 acetoxy-enyne. The latter is readily subjected to partial hydrogenation and saponification in that order to form a dehydrophytol, a useful intermediate for the synthesis of Vitamin E and other products.
    Type: Grant
    Filed: October 16, 1975
    Date of Patent: November 14, 1978
    Assignee: SCM Corporation
    Inventors: Ralph E. Close, William Oroshnik
  • Patent number: 4107219
    Abstract: A chain terpene alcohol having the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and respectively represent hydrogen atom or a lower alkyl group is produced by oxidizing a chain unsaturated amine having the formula ##STR2## wherein R.sup.3 represents an alkyl group and heating the product for a thermal rearrangement to form a chain unsaturated hydroxylamine having the formula ##STR3## and then reducing the chain unsaturated hydroxylamine with hydrogen in the presence of a catalyst selected from the group consisting of iron family elements, copper family elements, oxides thereof and copper chromite.
    Type: Grant
    Filed: May 11, 1977
    Date of Patent: August 15, 1978
    Assignee: Nissan Chemical Industries Ltd.
    Inventors: Atsuo Murata, Shuji Tsuchiya, Hideo Suzuki, Hisao Ikeda
  • Patent number: 4105700
    Abstract: A process for obtaining a stereospecific nerolidol at the .DELTA..sup.6 -position thereof by rectifying a mixture of .DELTA..sup.6 -cis-nerolidol and .DELTA..sup.6 -trans-nerolidol in rectification column having from 10 to 100 theoretical plates with a reflux ratio of from 2 to 200 at a temperature below 230.degree. C. under reduced pressure to separate each stereospecific nerolidol from said mixture.
    Type: Grant
    Filed: March 17, 1977
    Date of Patent: August 8, 1978
    Assignee: Kuraray Company, Ltd.
    Inventors: Yoshiji Fujita, Yoshiaki Omura, Takashi Nishida, Kazuo Itoi
  • Patent number: 4104202
    Abstract: The invention relates to the preparation of perfume compositions. More specifically the invention relates to the use of new 1,5-alkadien-4-ols and esters derived therefrom as components of such compositions.
    Type: Grant
    Filed: March 11, 1977
    Date of Patent: August 1, 1978
    Assignee: Naarden International N.V.
    Inventor: Hans J. Wille
  • Patent number: 4100180
    Abstract: A solid catalyst for preparation of unsaturated alcohols by selective hydrogenation of the aldehyde group of unsaturated aldehydes, said catalyst comprising platinum oxide and deposited on its surface in an atmosphere of hydrogen, an iron compound and a zinc compound, and an improved process for preparing unsaturated alcohols by catalytic hydrogenation of unsaturated aldehydes with hydrogen in the presence of the aforesaid catalyst.
    Type: Grant
    Filed: December 23, 1975
    Date of Patent: July 11, 1978
    Assignee: Teijin, Limited
    Inventors: Yataro Ichikawa, Nobuo Suzuki, Toru Sawaki