Polymer Patents (Class 585/10)
  • Patent number: 5387730
    Abstract: There is disclosed a linear block copolymer comprising at least one triblock I-B-I, wherein I is a block of at least one polymerized conjugated diene of at least five (5) carbon atoms, such as isoprene, and B is a block of a polymer of at least one conjugated diene, different from that used to polymerize the block I, of at least four (4) carbon atoms, such as butadiene. The B block is selectively hydrogenated, while each of the I blocks is unhydrogenated and therefore retains a sufficient amount of its original unsaturation to vulcanize the copolymer. There is also disclosed an alternative linear block copolymer containing at least one triblock of the first polymer block made from a minor proportion of at least one aryl-substituted olefin, such as styrene, and a major proportion of at least one conjugated diene used to polymerize the block I, the second middle polymer block of at least one diene used to polymerize the block B, and the third polymer block which is the same as the first polymer block.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: February 7, 1995
    Assignee: Mobil Oil Corporation
    Inventors: Thomas S. Coolbaugh, Frederick C. Loveless, Demetreos N. Matthews, Leslie R. Rudnick
  • Patent number: 5366658
    Abstract: The invention relates to the use of polymethylalkanes having terminal methyl groups and methylene and ethylidene groups of the formula I ##STR1## in which the total number of C atoms n+2 m+2 is 20 to 100 and the ratio of the methyl and methylene groups to the ethylidene groups is 3 to 20:1 and the ethylidene groups are always separated by at least one methylene group, as biodegradable base oils for lubricants and functional fluids. Suitable polymethylalkanes are obtained by oligomerization of .alpha.,.omega.-diolefins, for example in particular according to P 41 19 332.6, or by pyrolysis of ethene/propane copolymers and subsequent hydrogenation in each case. The polymethylalkanes can be combined with conventional additives and other degradable or non-degradable base oils.
    Type: Grant
    Filed: January 10, 1994
    Date of Patent: November 22, 1994
    Assignee: Huls Aktiengesellschaft
    Inventors: Dirk Hoppe, Horst Pennewiss, Frank Kraushaar, Michael Stehr, Roland Streck, Jaroslaw Monkiewicz, Hans G. Wey
  • Patent number: 5348673
    Abstract: Composition of matter useful as multifunctional viscosity index improver for lubricating oil comprising reaction product of: (i) (a) molecular weight degraded ethylene-alpha-olefin copolymer obtained by degrading copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.z /M.sub.w of less than 1.8, and said degraded copolymer grafted with (b) ethylenically monounsaturated carboxylic acid material having 1 to 2 carboxylic acid groups or anhydride group to form grafted ethylene copolymer; (ii) about C.sub.50 to about C.sub.
    Type: Grant
    Filed: December 8, 1993
    Date of Patent: September 20, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, Mark J. Struglinski
  • Patent number: 5344582
    Abstract: A traction fluid lubricant is disclosed which contains a naphthenic ingredient having a weight average molecular weight of 200-300 and obtained by hydrogenating oligomers of cyclopentadiene having a ratio of the number of norbornenic double bond to that of cyclopentenic double bond of smaller than 0.9 but not smaller than 0.1. The naphthenic ingredient is suitably used in conjunction with an auxiliary ingredient selected from a polybutene having a viscosity of 5-60 cSt at 40.degree. C. and a bicyclohexyl compound.
    Type: Grant
    Filed: July 29, 1992
    Date of Patent: September 6, 1994
    Assignee: Tonen Corporation
    Inventors: Noboru Umemoto, Takeshi Nomura, Toshiaki Kuribayashi, Takehisa Sato, Hirotaka Tomizawa
  • Patent number: 5329055
    Abstract: There is disclosed a method of suppressing misting or spatting from an oil-containing functional fluid, such as a chain saw lubricant, by blending with the functional fluid a mist suppressing effective amount of a copolymer of a C.sub.3 or C.sub.4 alpha-monoolefin and at least one other alpha-monoolefin having from 5 to about 20 carbon atoms, said copolymer having a viscosity average molecular weight of from about 500,000 to about 10 million.
    Type: Grant
    Filed: May 14, 1993
    Date of Patent: July 12, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Harold E. Bachman, Chung K. Shih
  • Patent number: 5321107
    Abstract: In accordance with the present invention, there are provided an olefin polymerization catalyst formed from:[A] a compound of a transition metal belonging to Group IV B of the periodic table,[B] an aluminoxane, and[C] water,an olefin polymerization catalyst formed from [D] an organoaluminum compound in addition to the above-mentioned [A], [B] and [D] components, and processes for the polymerization of olefins using the above-mentioned olefin polymerization catalysts, respectively.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: June 14, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Toshiyuki Tsutsui, Kazunori Okawa, Akinori Toyota
  • Patent number: 5315053
    Abstract: A lubricating oil composition comprising a normally liquid alpha-olefin oligomer consisting essentially of repeating units having the structural formula: ##STR1## wherein x represents an integer from 3 to 11, inclusive; andy represents the number of repeating units in the oligomer such that the weight average molecular weight is from about 5,000 to about 20,000;said oligomer having from about 70 to 100 percent head-to-tail alignment of the repeating units of the oligomer. Preferably the weight average molecular weight of the oligomer is from 5,000 to about 10,000; and said oligomer is further characterized as having a dispersity of less than about 5.5, and a Z average molecular weight of less than about 24,000.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: May 24, 1994
    Assignee: Chevron Research Company
    Inventors: David L. Beach, Paul G. Bercik, Neal E. Morganson
  • Patent number: 5290461
    Abstract: Composition of matter useful as multifunctional viscosity index improver for lubricating oil comprising reaction product of:(i) (a) degraded ethylene-alpha-olefin copolymer obtained by degrading copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.z /M.sub.w of less than 1.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: March 1, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, Mark J. Struglinski
  • Patent number: 5284595
    Abstract: The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight terminally substituted with amine compounds, which are also useful additives to oleaginous compositions, e.g., as fuel and lubricating oil dispersants.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: February 8, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Alan M. Schilowitz, Antonio Gutierrez, Won R. Song
  • Patent number: 5276227
    Abstract: Liquid hydrocarbon lubricant viscosity index improver compositions are disclosed having high shear stability. The compositions comprise the homopolymer or copolymer product of the oligomerization of C.sub.3 to C.sub.5 alpha-olefin or mixtures thereof, with or without ethylene as co-monomer. The process is carried out under oligomerization conditions in contact with a reduced valence state Group VIB metal catalyst on porous support. The viscosity index improver of the invention has a regio-irregularity of at least 20%, weight average molecular weight between 6,000 and 30,000 and molecular weight distribution between 2 and 5.
    Type: Grant
    Filed: February 3, 1992
    Date of Patent: January 4, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Margaret M. Wu, Alice S. Chu
  • Patent number: 5264642
    Abstract: A process is disclosed to produce liquid oligomers of olefins, such as l-decene, with controlled molecular weight and with branch ratios below 0.19 and having higher viscosity indices than oligomers with higher branch ratios. These oligomers with low branch ratios and controlled molecular weight can be used as basestocks for many lubricants or greases with an improved viscosity-temperature relationship, oxidative stability, volatility, etc. They can also be used to improve viscosities and viscosity indices of lower quality oils. The olefins can, for example, be oligomerized in the presence of hydrogen over a supported and reduced metal oxide catalyst from Group VIB of the Periodic Table to give oligomers of controlled viscosity suitable for lubricant application.
    Type: Grant
    Filed: June 19, 1992
    Date of Patent: November 23, 1993
    Assignee: Mobil Oil Corp.
    Inventor: Margaret M. Wu
  • Patent number: 5227551
    Abstract: There is disclosed a method of suppressing misting or spatting from an oil-containing functional fluid, such as a chain saw lubricant, by blending with the functional fluid a mist suppressing effective amount of a copolymer of a C.sub.3 or C.sub.4 alpha-monoolefin and at least one other alpha-monoolefin having from 5 to about 20 carbon atoms, said copolymer having a viscosity average molecular weight of from about 500,000 to about 10 million.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: July 13, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Harold E. Bachman, Chung K. Shih
  • Patent number: 5225092
    Abstract: The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 20,000 number average molecular weight terminally substituted with amine compounds, which are also useful additives to oleaginous compositions, e.g., as fuel and lubricating oil dispersants.
    Type: Grant
    Filed: February 1, 1990
    Date of Patent: July 6, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Alan M. Schilowitz, Antonio Gutierrez, Won R. Song
  • Patent number: 5217636
    Abstract: The invention is an improvement in wide viscosity range multigrade lubricants of the type having a mineral oil base into which is added a viscosity index improver and a wear enhancer package and, more specifically, in the viscosity index improver which is used. The viscosity index improver mixture of contains (a) 85 to 99.5% by weight, preferably 91%-95% by weight, of low molecular weight ethylene-propylene copolymers; and (b) 0.5 to 15% by weight, preferably 5% to 9% by weight, of an esterified alkenyl-vinyl polymer pour point depressant to make 100% total amount of (a) and (b). Normally, this mixture will be contained in the base lubricant in an amount of about 1% to 95% by weight, preferably 1% to 25% by weight or 1 to 20% by weight and, most preferably, either 1-5% or 3-10% depending on the desired viscosity properties. To ensure the effect of the compounds in the final mixture, the pour point depressant component (b) should be present in the multigrade lubricant in an amount of at least about 0.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: June 8, 1993
    Assignee: Albright & Wilson Americas Inc.
    Inventor: James L. Paboucek
  • Patent number: 5210346
    Abstract: A synthetic oil composition comprises a major portion by weight of synthetic base oil having a kinetic viscosity of from about 1.5 to 2.5 cSt at 100.degree. C. and a minor portion by weight of one or more property enhancing additives for said base oil, said base oil comprising a major portion by weight of dimer of 1-decene, said dimer having a kinetic viscosity of less than about 250 cSt at -40.degree. C., a kinetic viscosity of less than about 1,000 cSt at -54.degree. C. and a pour point of less than about -65.degree. C.
    Type: Grant
    Filed: February 6, 1992
    Date of Patent: May 11, 1993
    Assignee: Ethyl Corporation
    Inventor: Thomas J. Dileo
  • Patent number: 5208403
    Abstract: Lubricant compositions comprise blends or mixtures of low viscosity, 3-8 cS e.g. about 5 cS(100.degree. C.), HVI lube basestock with higher viscosity, 15 cS+e.g. 30+ cS(100.degree. C.) HVI PAO lube basestock produced from slack wax by thermal cracking to alpha olefins followed by Lewis acid catalyzed oligomerization of the alpha olefin mixture to lube base stock. Blending these components in appropriate proportions produces lube basestock having viscosities in the range of 8-15 cS (100.degree. C.) from which material suitable for the formulation of 10W-30 automobile engine lube can be produced. The blends are notable for exhibiting high VI values greater than that of either component of the blend.
    Type: Grant
    Filed: April 28, 1992
    Date of Patent: May 4, 1993
    Assignee: Mobil Oil Corporation
    Inventors: J. Scott Buchanan, Margaret M. Wu
  • Patent number: 5194168
    Abstract: Lubricant compositions of high lubrication and light coloration characteristics are made up essentially of a selected mineral or synthetic oil and a selected polybutadiene. The polymeric component contains greater than 20% by mol of vinyl bonds in terms of its monomeric unit and has crosslinked more than 10% of the vinyl bond content.
    Type: Grant
    Filed: January 28, 1991
    Date of Patent: March 16, 1993
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Nobuo Aoki, Shinichiro Suzuki
  • Patent number: 5190682
    Abstract: This invention provides lubricant mixtures for use as base fluid in open-gear grease comprising 10% to 90% w of a liquid polybutene having a viscosity at 38.degree. C. in the range of 1,000 to 20,000 mm.sup.2 /s and a viscosity at 100.degree. C. in the range of 40 to 500 mm.sup.2 /s, and 10% to 90% of a liquid polyalphaolefin having a viscosity at 38.degree. C. in the range of 10 to 75 mm.sup.2 /s and a viscosity at 100.degree. C. in the range of 2 to 15 mm.sup.2 /s, and open-gear grease compositions containing a major proportion of such lubricant mixtures.
    Type: Grant
    Filed: March 26, 1992
    Date of Patent: March 2, 1993
    Assignee: Shell Oil Company
    Inventor: John W. Harris
  • Patent number: 5188724
    Abstract: A pour point depressant for lubricating oils comprises an olefin copolymer which contains alkyl side chains having carbon atoms, wherein the average side chain length in the copolymer is 10.5 to 12.0.
    Type: Grant
    Filed: February 6, 1991
    Date of Patent: February 23, 1993
    Assignee: Pennzoil Products Company
    Inventors: William J. Heilman, Bruce E. Wilburn
  • Patent number: 5180863
    Abstract: A process is disclosed for the preparation of low viscosity lubricant range hydrocarbons having high viscosity index which comprises: contacting olefinic dimer, or mixtures thereof, with a Group 6 metal oxide disproportionation catalyst on a solid support under disproportionation reaction conditions. The dimer comprises the product of the oligomerization of C.sub.6 -C.sub.20 alpha-olefins in contact with reduced chromium oxide catalyst on silica support. The disproportionation catalyst preparation includes treatment by oxidation at a temperature of 200.degree. C. to 900.degree. C. in the presence of an oxidizing gas and then treatment with a reducing agent at a temperature and a time sufficient to reduce said catalyst. The disproportionation reaction effluent is separated and lubricant range hydrocarbons recovered. The preferred disproportionation catalyst for the process is reduced tungsten oxide on silica support.
    Type: Grant
    Filed: June 17, 1991
    Date of Patent: January 19, 1993
    Assignee: Mobil Oil Corporation
    Inventor: Thomas R. Forbus
  • Patent number: 5180864
    Abstract: An improved process is disclosed for preparing synthetic lubricant base stocks. Synthetic lubricant base stocks are prepared in good yield by oligomerizing linear olefins using certain acidic calcium montmorillonite clay catalysts which have aluminum nitrate deposited thereon.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: January 19, 1993
    Assignee: Texaco Chemical Company
    Inventors: John R. Sanderson, John F. Knifton
  • Patent number: 5180865
    Abstract: Fully synthetic lubricating base oil compositions are formulated from blends of 50-97 wt % of synthetic hydrocarbons and 3-50 wt % isobutylene oligomers. The lubricating base oil compositions have constant viscosity indexes which are higher than those of the components used to form the compositions. The synthetic hydrocarbon and isobutylene oligomers are combinable in various amounts with conventional additives to form multi-grade engine lubricants, which are shear stable.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: January 19, 1993
    Assignee: Pennzoil Products Company
    Inventors: William J. Heilman, Clifford G. Venier
  • Patent number: 5177276
    Abstract: An alpha-olefin oligomer consisting essentially of repeating units having the structural formula: ##STR1## wherein x represents an integer from 3 to 11, inclusive; andy represents the number of repeating units in the oligomer such that the weight average molecular weight is from about 5,000 to about 20,000;said oligomer having from about 70 to 100 percent head-to-tail alignment of the repeating units of the oligomer. Preferably the weight average molecular weight of the oligomer is from 5,000 to about 10,000; and said oligomer is further characterized as having a dispersity of less than about 5.5, and a Z average molecular weight of less than about 24,000.
    Type: Grant
    Filed: November 4, 1988
    Date of Patent: January 5, 1993
    Assignee: Chevron Research Company
    Inventors: David L. Beach, Paul G. Bercik, Neal E. Morganson
  • Patent number: 5171918
    Abstract: Heat transfer, lubricating, functional and/or insulating fluid compositions for use in apparatus such as electrical transformers contain up to 25 weight percent of one or more oil additives and a 1-octene and/or 1-decene dimer and/or a 1-octene and 1-decene co-dimer oil having improved low temperature properties which oil contains less than about 2.5 weight percent of, respectively, the 7-methylpentadecene, 9-methylnonadecene and, 7- and 9-methylheptadecene isomers. The dimers can be hydrogenated to provide the saturated counterparts of the isomers.
    Type: Grant
    Filed: May 28, 1991
    Date of Patent: December 15, 1992
    Assignee: Ethyl Corporation
    Inventors: Ronald L. Shubkin, Kevin J. Theriot
  • Patent number: 5171904
    Abstract: Synthetic lubricant base stocks having a low pour point are disclosed. These synthetic lubricant base stocks comprise a mixture of (1) oligomers prepared from a linear olefin having from 10 to 24 carbon atoms; and (2) alkylated decalin having an alkyl group containing from 10 to 24 carbon atoms. These synthetic lubricant base stocks may be prepared by hydrogenating the co-reaction products of a linear olefin having from 10 to 24 carbon atoms and naphthalene.
    Type: Grant
    Filed: May 31, 1990
    Date of Patent: December 15, 1992
    Assignee: Texaco Chemical Company
    Inventors: John R. Sanderson, Edward T. Marquis
  • Patent number: 5171905
    Abstract: A 1-octene and/or 1-decene dimer and/or 1-octene/1-decene co-dimer product composition having improved low temperature properties contains less than about 2.5 weight percent of, respectively, the 7-methylpentadecene, 9-methylnonadecene isomers, or 7- and 9-methylheptadecene isomers.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: December 15, 1992
    Assignee: Ethyl Corporation
    Inventors: Kevin J. Theriot, Ronald L. Shubkin
  • Patent number: 5171908
    Abstract: The invention is directed to method of making a thermally and oxidatively stable lubricating oil having a high viscosity index and a low pour point by the thermal polymerization of 1-olefins containing 8 to 10 carbon atoms, the preferred 1-olefins are 1-decanes. The polymerization is conducted at temperatures ranging from 280.degree. C. to 350.degree. C. and low pressures, of less than about 280 psig, in a reactor which is free of catalytic material. Thereafter, the polyalphaolefin is hydrotreated over a nickel catalyst, preferably nickel on Kieselguhr. In an improved process the polyalphaolefin is separated from a low molecular weight product by distillation. The low molecular product contains unreacted 1-olefins which are recycled to the thermal polymerization zone to produce more of the lubricant base stock.
    Type: Grant
    Filed: November 18, 1991
    Date of Patent: December 15, 1992
    Assignee: Mobil Oil Corporation
    Inventor: Leslie R. Rudnick
  • Patent number: 5169914
    Abstract: A method for producing polymers with narrow molecular weight distribution which involves combining (1) an initiator component of the formula ##STR1## in which R.sub.1, R.sub.2, and R.sub.3 are alkyl, aryl, or aralkyl groups, and can be the same or different, and X is an acetate, etherate, a hydroxyl group, or a halogen, and i is a positive whole number, (2) a Lewis acid of the formula MX.sub.n in which M is titanium, aluminum, boron, or tin, X is a halogen, and n is a positive whole number, (3) an electron donor component having an electron donor number of from at least about 25 to no more than about 50, (4) a solvent for the preceding and (5) a hydrocarbon monomer component.
    Type: Grant
    Filed: April 1, 1992
    Date of Patent: December 8, 1992
    Assignee: Edison Polymer Innovation Corporation
    Inventors: Gabor Kaszas, Judit E. Puskas, Joseph P. Kennedy
  • Patent number: 5157177
    Abstract: A novel composition is disclosed that is particularly useful as a lubricant viscosity index improver. The composition comprises branched C.sub.30 -C.sub.10000 hydrocarbons that have a branch ratio of less than 0.19 and viscosity at 100.degree. C. between 725 cS and 15,000 cS. The novel compositions comprise the product of the oligomerization of C.sub.6 to C.sub.20 alpha-olefin feedstock, or mixtures thereof, under oligomerization conditions at a temperature between -20.degree. C. and +90.degree. C. in contact with a reduced valence state Group VIB metal catalyst on porous support. The compositions have viscosities at 100.degree. C. between 725 cS and 15,000 cS. Using the foregoing compositions in admixture with mineral oil and synthetic lubricants provides novel lubricant blends that show an elevated viscosity index. The mixtures also show an increased stability to shear stress at high temperature with all blends notable by exhibiting Newtonian flow.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: October 20, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Bruce P. Pelrine, Margaret M. Wu
  • Patent number: 5151204
    Abstract: The present invention is directed to a lubricating oil composition exhibiting improved viscosity index comprising lubricating oil and a viscosity improving effective amount of ethylene alpha-olefin polymer comprising monomer units derived from ethylene and at least one alpha-olefin represented by the formula H.sup.2 C=CHR.sup.1 wherein R.sup.1 is an alkyl group of from 1 to 18 carbon atoms, and wherein said polymer has a number average molecular weight of from above 20,000 to about 500,000, and an average of at least about 30% of the polymer chains contain terminal ethylidene unsaturation.
    Type: Grant
    Filed: February 1, 1990
    Date of Patent: September 29, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Mark J. Struglinski
  • Patent number: 5146021
    Abstract: A novel composition is disclosed that is particularly useful as a lubricant viscosity index improver. The composition comprises branched C.sub.30 -C.sub.10000 hydrocarbons that have a branch ratio of less than 0.19 and viscosity at 100.degree. C. between 725 cS and 15,000 cS. The novel compositions comprise the product of the oligomerization of C.sub.6 to C.sub.20 alpha-olefin feedstock, or mixtures thereof, under oligomerization conditions at a temperature between -20.degree. C. and +90.degree. C. in contact with a reduced valence state Group VIB metal catalyst on porous support. The compositions have viscosities at 100.degree. C. between 725 cS and 15,000 cS. Using the foregoing compositions in admixture with mineral oil and synthetic lubricants provides novel lubricant blends that show an elevated viscosity index. The mixtures also show an increased stability to shear stress at high temperture with all blends notable by exhibiting Newtonian flow.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: September 8, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Andrew Jackson, Margaret M. Wu, Alice S. Chu, Bruce P. Pelrine
  • Patent number: 5146022
    Abstract: A process is disclosed for the production of synthetic lubricants having high viscosity index and thermal stability by oligomerizing a mixture of C.sub.5 -C.sub.18 or C.sub.6 -C.sub.16 alpha-olefins produced from the thermal cracking of slack wax or recycled slack wax. The oligomerization is carried out with Lewis acid catalyst. Promoted aluminum chloride is a preferred catalyst.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: September 8, 1992
    Assignee: Mobil Oil Corporation
    Inventors: J. Scott Buchanan, Margaret M. Wu
  • Patent number: 5146023
    Abstract: A process is disclosed for preparing synthetic lubricant base stocks having improved properties. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefins using certain acidic calcium montmorillonite clay catalysts. When a mixture of alpha and internal-olefins having up to 50 wt. % internal-olefin is used, and the oligomers prepared therefrom are hydrogenated, a synthetic lubricant base stock having a higher viscosity index and a lower pour point is prepared.
    Type: Grant
    Filed: April 30, 1990
    Date of Patent: September 8, 1992
    Assignee: Texaco Chemical Company
    Inventors: John R. Sanderson, Edward T. Marquis
  • Patent number: 5136118
    Abstract: A process is disclosed for the production of synthetic hydrocarbon lubricants having high viscosity index by oligomerizing a mixture of alpha-olefins comprising the reaction product from the thermal cracking of refined wax. The oligomerization is carried out with Lewis acid catalyst or reduced chromium oxide on porous support.
    Type: Grant
    Filed: August 23, 1990
    Date of Patent: August 4, 1992
    Assignee: Mobil Oil Corporation
    Inventors: J. Scott Buchanan, Margaret M. Wu
  • Patent number: 5126065
    Abstract: A process for improving the coefficient of traction at high temperatures in a traction drive, and a tranction drive fluid for use therein. This traction drive fluid comprises the hydrogenated product of a dimer, a trimer or a tetramer of norbornanes and/or norbornenes, and exhibits excellent traction performance over a wide temperature range from low temperature to high temperature.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: June 30, 1992
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Toshiyuki Tsubouchi, Kazuaki Abe, Hitoshi Hata
  • Patent number: 5118433
    Abstract: Composition of matter useful as multifunctional viscosity index improver for lubricating oil comprising reaction product of:(i)(a) degraded ethylene-alpha-olein copolymer obtained by degrading copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.z /M.sub.w of less than 1.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: June 2, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, Mark J. Struglinski
  • Patent number: 5113030
    Abstract: Novel synthetic lubricants having high viscosity index are made from lower olefins. These materials have a viscosity above about 2 cS at 100.degree. C. and viscosity index above about 130 and are characterized by internal methyl groups attached to side chain tertiary carbon atoms.Hydrocarbon lubricant can be based on propene feedstock with the resulting oligomer containing less than 2.5 methyl groups per 12 carbon atoms.
    Type: Grant
    Filed: August 22, 1990
    Date of Patent: May 12, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Catherine S. H. Chen, Margaret M. Wu
  • Patent number: 5105038
    Abstract: Synthetic lubricant blends exhibiting superior lubricant properties such as high viscosity index, including mixtures of oligomeric products of shape selective catalysis with other lubricants, such as high viscosity index poly-alpha-(.alpha.-)olefins lubricant basestock, conventional poly(.alpha.-olefin) and/or other liquid lubricant basestock material.Preferred lubricant mixtures comprise hydrogenated components:a) a low viscosity C.sub.20 -C.sub.60 lubricant range liquid comprising substantially linear hydrocarbon moietoes prepared by shape selective catalysis of lower olefin with medium pore acid zeolite catalyst to provide substantially linear liquid olefinic intermediates or C.sub.20.sup.+ lubricants, said lubricant range liquid having a kinematic viscosity of about 2-10 cS at 100.degree. C.; andb) at least one poly(.alpha.-olefin) having viscosity greater than 20 cS and viscosity index improvement properties.
    Type: Grant
    Filed: December 7, 1990
    Date of Patent: April 14, 1992
    Assignee: Mobil Oil Corporation
    Inventors: Catherine S. H. Chen, Margaret M. Wu
  • Patent number: 5093539
    Abstract: The invention relates to polymers and oligomers characterized in that they have been prepared from .alpha.-olefin monomers or mixtures thereof and the distances between the methyl branching paints are controllable by the selection of the .alpha.-olefins and to a process for preparing said novel polymers and oligomers.
    Type: Grant
    Filed: November 29, 1988
    Date of Patent: March 3, 1992
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Gerhard Fink, Volker Mohring
  • Patent number: 5068048
    Abstract: Oligomers produced from lower olefins by acidic zeolite catalyzed oligomerization can be converted to useful lubricant additives or lubricants by epoxidation of olefinic bonds in the oligomers, whereby oligomers containing oxirane ring structures are produced. The epoxided products so produced exhibit high viscosity index and low pour points. The discovery is particularly applicable to the epoxidation of oligomers produced from lower olefins such as propylene by oligomerization using ZSM-5 catalyst which has been surface deactivated.
    Type: Grant
    Filed: February 7, 1990
    Date of Patent: November 26, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Catherine S. H. Chen, Paul G. Rodewald
  • Patent number: 5068476
    Abstract: Liquid olefin oligomers are produced by the oligomerization of C.sub.2 -C.sub.5 alpha olefin alone or with ethylene as a co-monomer. The oligomers having high viscosity index and a structure which is characterized by a regio-irregularity of at least 20 percent, usually from 20 to 40 percent. The olefins are oligomerized with a reduced valence state chromium oxide catalyst on a silica support, usually at a temperature from 90.degree. to 250.degree. C., although lower temperatures can also be used with ethylene as a con-monomer. The liquid oligomerization products can be produced in wide range of viscosities including the direct production of low viscosity lubricants having high viscosity index.
    Type: Grant
    Filed: January 29, 1991
    Date of Patent: November 26, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Margaret M. Wu, Suzzy C. Ho
  • Patent number: 5030791
    Abstract: A process is disclosed for preparing synthetic lubricant base stocks having improved properties. Synthetic lubricant base stocks may be prepared in good yield by oligomerizing linear olefins using certain acidic calcium montmorillonite clay catalysts. When a mixture of 1,3-di-isopropenyl benzene and long-chain alpha-olefin is used, in which up to about 20 wt. % of the mixture comprises 1,3-di-isopropenyl benzene, and the co-oligomers prepared therefrom are hydrogenated, a synthetic lubricant base stock having a lower pour point and a higher viscosity is prepared.
    Type: Grant
    Filed: May 21, 1990
    Date of Patent: July 9, 1991
    Assignee: Texaco Chemical Company
    Inventors: John R. Sanderson, Edward T. Marquis
  • Patent number: 5026933
    Abstract: A process for producing substantially linear hydrocarbons by oligomerizing a lower olefin at elevated temperature and pressure which comprises contacting the lower olefin under oligomerization/polymerization conditions with siliceous acidic ZSM-23 zeolite having Bronsted acid activity; wherein the zeolite has acidic pore activity and wherein the zeolite surface is rendered substantially inactive for acidic reactions. The zeolite surface can be neutralized by a bulky pyridine compound having an effective cross-section larger than the zeolite pore. The preferred deactivating agent is 2,4,6-collidine, which may be applied to the zeolite as a pretreatment or added with olefin feed in a continuous process. The olefin oligomers may be used as alkylating agents to prepare biodegradable alkylbenzenes and alkylphenylsulfonates. A preferred catalyst for this alkylation reaction is dealuminized mordenite.
    Type: Grant
    Filed: July 18, 1989
    Date of Patent: June 25, 1991
    Assignee: Mobil Oil Corporation
    Inventors: David A. Blain, Nancy M. Page, Lewis B. Young
  • Patent number: 5019537
    Abstract: A forming aid to be mixed in a ceramic material for forming the ceramic material into a formed ceramic body of a desired shape, including at least one of a thermoplastic resin and a wax, and a mineral oil in an amount of 30-95% by volume with respect to an entire volume of the aid. Also disclosed is a process of producing a ceramic article from the formed ceramic body containing the aid.
    Type: Grant
    Filed: April 21, 1988
    Date of Patent: May 28, 1991
    Assignee: NGK Insulators, Ltd.
    Inventors: Kiminari Kato, Masahiro Shirai
  • Patent number: 5017279
    Abstract: A multistep process is disclosed for the manufacture of synthetic lubricants from the C.sub.8 to C.sub.24 linear olefin components of below liquid fuel value petroleum distillate fractions derived via the high temperature thermal cracking of petroleum residua. Such feeds contain major amounts of 1-n-olefins, n-paraffins and greater than 0.1% concentration of sulfur mostly in the form aromatic, thiophene type sulfur compounds.In the first step of the present process such feeds are enriched in the straight chain aliphatic hydrocarbon components by one or more separation processes, preferably via urea adduction or by crystallization. In the second step, the olefin components are oligomerized to sulfur containing C.sub.30 to C.sub.60 polyolefins, preferably in the presence of BF.sub.3 complex catalysts. In the third step, the polyolefins are hydrogenated to novel isoparaffin lubricants in the presence of sulfur resistant catalysts, preferably transition metal sulfides.
    Type: Grant
    Filed: February 13, 1990
    Date of Patent: May 21, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Alexis A. Oswald, Frank J. Chen, Ramon L. Espino, Kuo L. Peng
  • Patent number: 5012020
    Abstract: A novel composition is disclosed that is particularly useful as a lubricant viscosity index improver. The composition comprises branched branched C.sub.30 -C.sub.10000 hydrocarbons that have a branch ratio of less than 0.19 and viscosity at 100.degree. C. between 725 CS and 15,000 cS. The novel compositions comprise the product of the oligomerization of C.sub.6 to C.sub.20 alpha-olefin feedstock, or mixtures thereof, under oligomerization conditions at a temperature between -20.degree. C. and +90.degree. C. in contact with a reduced valence state Group VIB metal catalyst on porous support. The compositions have viscosities at 100.degree. C. between 725 cS and 15,000 cS. Using the foregoing compositions in admixture with mineral oil and synthetic lubricants provides novel lubricant blends that show an elevated viscosity index. The mixtures also show an increased stability to shear stress at high temperature with all blends notable by exhibiting Newtonian flow.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: April 30, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Andrew Jackson, Margaret M. Wu
  • Patent number: 4999409
    Abstract: 1,4-Addition polymers or copolymers of diolefins useful as a functional or active polymer is provided which comprises, in combination, the following recurring units (A) and (B): ##STR1## wherein n=4 to 6 and A/B mole ratio=0 to 98/100 to 2.
    Type: Grant
    Filed: September 29, 1988
    Date of Patent: March 12, 1991
    Assignee: Toa Nenryo Kogyo Kabushiki Kaisha
    Inventors: Yoshiharu Doi, Kazuo Soga, Satoshi Ueki
  • Patent number: 4996384
    Abstract: A process for producing oligomers from alpha-olefins, such as 1-decene, in which the olefins are oligomerized over a supported, reduced metal oxide catalyst from Group VIB of the Periodic Table to give oligomers with a branch ratio of less than 0.19. The catalyst, preferably a chromium/silica catalyst the catalyst can be regenerated to allow repeated recycling of the catalyst without a loss in yield of the oligomer product. The regeneration process comprises: (i) purging or stripping the deactivated catalyst with inert gas at elevated temperature to strip unreacted olefin and oligomer product from the catalyst; (ii) contacting the deactivated and purged catalyst with a stream of oxidizing gas while heating to elevated temperature to oxidize the metal component of the catalyst and remove carbonaceous deposits from the catalyst; (iii) cooling the oxidized catalyst and contacting it with a stream of reducing gas to reduce the metal component of the oxidized catalyst to a lower valence state.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: February 26, 1991
    Assignee: Mobil Oil Corporation
    Inventors: Bruce P. Pelrine, Margaret M. Wu
  • Patent number: 4992183
    Abstract: Non-polymer thickened multigrade engine oils based on synthetic basestocks are provided. The SAE 5W-30, SAE 10W-30 and SAE 15W-40 engine oils are derived from hydrogenated decene-1 oligomer mixtures wherein the oligomers range from C.sub.30 up to C.sub.70+ and are present in specified proportions. Synthetic esters may be combined with the polyalphaolefin oligomer mixture. The synthetic basestocks are formulated with appropriate performance additives to obtain engine oils which meet the desired API Service Requirements for gasoline and/or diesel engine usage. In addition to specified oligomer distributions, the polyalphaolefins have specified viscosities, molecular weights and branching.
    Type: Grant
    Filed: August 15, 1989
    Date of Patent: February 12, 1991
    Assignee: Ethyl Corporation
    Inventors: Bruce J. Beimesch, James E. Davis
  • Patent number: H1407
    Abstract: Synthetic lubricant base stocks having improved properties are disclosed. The base stocks may be obtained by a two-step process, comprising the steps of (1) co-reacting vinylcyclohexene and long-chain linear olefin with a free-radical initiator; and (2) further reacting the mixture resulting from step (1) in the presence of an acidic montmorillonite clay.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: January 3, 1995
    Assignee: Texaco Chemical Company
    Inventors: John R. Sanderson, Wheeler C. Crawford