Polycyclo, I.e., Fused Patents (Class 585/21)
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Patent number: 6593363Abstract: The present invention relates to diterpene derivatives prepared from the components which are extracted from Acanthopanax Koreanum and represented by Chemical Formula (1).Type: GrantFiled: September 15, 2000Date of Patent: July 15, 2003Assignees: Sae Han Pharm. Co., Ltd.Inventors: Young Ger Suh, Young Hoon Choi, Hye Kyung Lee, Young Ho Kim, Hyoung Sup Park
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Patent number: 6512152Abstract: The present invention is drawn to a tetracyclododecene composition having a regulated cyclopentadiene trimer content, whereby addition polymerization with the aid of a Ziegler catalyst can be carried out while preventing gelation caused by a cross-linking reaction. A tetracyclododecene composition regulated with respect to the content of a specific ingredient having a molecular weight of 188 is disclosed, whereby polymers having high glass transition temperatures can be obtained through various polymerizations. Further, the present invention is drawn to a method for producing tetracyclododecene in the presence of an aliphatic solvent having a boiling point close to that of norbornene, which solvent is effective in inhibiting the recovered norbornene from solidifying.Type: GrantFiled: February 28, 2000Date of Patent: January 28, 2003Assignee: Nippon Petrochemicals Company, LimitedInventors: Masaki Hashizume, Tomonobu Uchida, Fuyuki Aida, Takashi Suzuki, Yoshihisa Inomata, Yasuo Matsumura
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Publication number: 20030004090Abstract: The compound according to the formula set forth below 1Type: ApplicationFiled: May 17, 2001Publication date: January 2, 2003Inventors: Anthony T. Levorse, Anubahv P.S. Narula, Edward Mark Arruda, Charles E.J. Beck
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Publication number: 20020193648Abstract: Disclosed are processes for the recovery and purification of higher diamondoids from a hydrocarbonaceous feedstock. Specifically disclosed is a multi-step recovery process for obtaining diamondoid compositions enhanced in tetramantane components and higher diamondoid components. Also disclosed are compositions comprising at least about 10 weight percent of non-ionized tetramantane components and higher diamondoid components and at least about 0.5 weight percent of non-ionized pentamantane components and higher diamondoid components based on the total weight of diamondoid components present.Type: ApplicationFiled: December 12, 2001Publication date: December 19, 2002Inventors: Jeremy E. Dahl, Robert M. Carlson
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Patent number: 6482966Abstract: A process for producing a crosslink-cyclized cyclopentadiene, comprising the steps of reacting a cyclopentenone with an alkali metal hydride to thereby reduce the cyclopentenone (reduction step A) into a cyclopentenol; and reacting the cyclopentenol with a dehydrating agent to thereby dehydrate the cyclopentenol (dehydration step B) into a crosslink-cyclized cyclopentadiene of the general formula (III): wherein each of R1 and R2 independently represents a hydrogen atom or a linear or branched saturated alkyl group having 1 to 6 carbon atoms, n is an integer of 3 to 10, and the broken line in the 5-membered ring denotes that the 5-membered ring has two double bonds.Type: GrantFiled: January 31, 2001Date of Patent: November 19, 2002Assignee: Honshu Chemical Industry Co., Ltd.Inventor: Keiichi Yokoyama
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Patent number: 6323315Abstract: The present invention provides compounds of the formula where R1-R5 are each, independently, a hydrogen atom or a normal or branched C1-C6-alkyl group; A is a methionyl, phenylalanyl or phenylglycyl residue; n is 0 or 1; R6 is a hydrogen atom; and R7 is a carbocylic group, an aromatic group, a C1-C4-alkyl group, a pyridylalkyl group or a heterocyclic group. In another embodiment, R6 is benzyl or —C(O)OR8, where R8 is a C1-C6-alkyl group, and R7 is a heteroaromatic group, such as a 2-thiazolyl group.Type: GrantFiled: March 31, 2000Date of Patent: November 27, 2001Assignees: BASF Aktiengesellschaft, Arizona Board of RegentsInventors: George R. Pettit, Jayaram K. Srirangam, Michael D. Williams, Kieran P. M. Durkin, Teresa Barlozzari, Andreas Kling, Bernd Janssen, Andreas Haupt
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Patent number: 6320088Abstract: Traction drive fluids comprise a saturated polycyclic hydrocarbon compound obtained by hydrogenating a trimeric compound of a cyclopentadiene-based condensed hydrocarbon compound resulting from the Diels-Alder reaction of cyclopentadiene and then isomerizing the resulting compound so as to have a pour point of −10° C. or below. The traction drive fluids can be used not only in driving force transmitting mechanisms but also in hydraulic pressure controlling mechanism and friction properties controlling mechanisms of wet clutches.Type: GrantFiled: February 27, 2001Date of Patent: November 20, 2001Assignee: Nippon Mitsubishi Oil CorporationInventors: Mitsuo Matsuno, Shinichi Shirahama, Tetsuo Okawa
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Publication number: 20010012902Abstract: A process for producing a crosslink-cyclized cyclopentadiene, comprising the steps of reacting a cyclopentenone with an alkali metal hydride to thereby reduce the cyclopentenone (reduction step A) into a cyclopentenol; and reacting the cyclopentenol with a dehydrating agent to thereby dehydrate the cyclopentenol (dehydration step B) into a crosslink-cyclized cyclopentadiene of the general formula (III): 1Type: ApplicationFiled: January 31, 2001Publication date: August 9, 2001Inventor: Keiichi Yokoyama
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Patent number: 6242393Abstract: A traction drive fluid comprises a tractant selected from the specific types of hydrocarbons, carboxylates and carbonate, optionally an effective amount of a base oil selected from a mineral oil and a synthetic oil and additives selected from a viscosity index improver, a ashless dispersant, a phosphorus-containing additive, a friction adjusting agent, a metallic detergent, an oxidation inhibitor, a polar additive, a corrosion inhibitor, a rubber swelling agent, a antifoamer and a colorant.Type: GrantFiled: April 8, 1999Date of Patent: June 5, 2001Assignee: Nippon Mitsubishi Oil CorporationInventors: Noboru Ishida, Junya Kohno, Shinichi Shirahama, Tetsuo Okawa
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Patent number: 6191330Abstract: Disclosed is a traction drive fluid which comprises (A) one or more than two compounds selected from the group consisting of saturated polycyclic hydrocarbon compounds represented by the formulae: wherein R1 and R2 are each independently hydrogen or a methyl group, provided that the case where both R1 and R2 are a methyl group at the same time is excluded, and R3 and R4 are each independently hydrogen or a methyl group; wherein R5 and R6 are each independently hydrogen or a methyl group, provided that the case where both R5 and R6 are a methyl group at the same time is excluded, R7 and R8 are each independently hydrogen or a methyl group; and wherein R9, R10 and R11 are each independently hydrogen or a methyl group.Type: GrantFiled: September 16, 1999Date of Patent: February 20, 2001Assignees: Nippon Mitsubishi Oil Corporation, San-Petrochemical Co., Ltd.Inventors: Mitsuo Matsuno, Shinichi Shirahama, Tetsuo Okawa, Takashi Kiyota
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Patent number: 6139484Abstract: Bridged cyclopentadienyl derivatives having general formula (I)A--X--B (I)wherein:1) A is a monofunctional hydrocarbyl radical having general formula (II) ##STR1## 2) --X-- is the bridge between A and B and consists of a bifunctional radical selected from an alkylene group, a silanylene group, an alkyl substituted silaalkylene group, a siloxasilanylene group;3) B is a monofunctional hydrocarbyl radical selected from:e) any of the A radicals defined above,f) a cyclopentadienyl radical.Type: GrantFiled: October 10, 1996Date of Patent: October 31, 2000Assignee: Enichem S.p.A.Inventors: Paolo Biagini, Gabriele Lugli, Roberto Santi, Giampiero Borsotti, Viviano Banzi
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Patent number: 5939595Abstract: A process for preparing diarylethanes of the general formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each hydrogen or C.sub.1 -C.sub.8 -alkyl, by reacting aromatic compounds of the general formula II ##STR2## where R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 have the abovementioned meanings, with styrenes of the general formula III ##STR3## where R.sup.1 has the abovementioned meanings, at from -20 to 300.degree. C. under from 1 to 100 bar in the presence of heterogeneous catalysts, wherein beta-zeolites or mordenites are used as heterogeneous catalysts.Type: GrantFiled: April 26, 1996Date of Patent: August 17, 1999Assignee: BASF AktiengesellschaftInventors: Eugen Gehrer, Klemens Massonne, Hermann Gausepohl, Martin Fischer, Christopher William Rieker, Lorenz Siggel
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Patent number: 5900517Abstract: Cyclopentadienyl derivatives are described having general formula (I) ##STR1## where R, R.sub.1, R.sub.2, R.sub.4, equivalent to or different from one another, are selected from: --H, alkyl radicals having a number of carbon atoms from 1 to 5, cycloalkyl radicals having a number of carbon atoms from 5 to 8, aryl and alkylaryl radicals having a number of carbon atoms from 6 to 8, aralkyl radicals having a number of carbon atoms from 7 to 9; n is an integer from 2 to 18; with the proviso that the number of R different from H does not exceed 2; with the exclusion of the compound having n=3, R.dbd.R.sub.1 .dbd.R.sub.2 .dbd.R.sub.4 .dbd.H. The invention a-so describes the process for the preparation of the above-mentioned cyclopentadienyl derivatives.Type: GrantFiled: August 12, 1996Date of Patent: May 4, 1999Assignee: Enichem S.p.A.Inventors: Paolo Biagini, Roberto Santi, Giampiero Borsotti, Gabriele Lugli, Viviano Banzi
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Patent number: 5866733Abstract: Diarylethanes of the formula I ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.8 -alkyl, are prepared by reacting benzene with a styrene of the formula III ##STR2## where R.sup.1 has the abovementioned meanings, by a process in which the reaction is carried out batchwise or continuously in the liquid or supercritical phase at from 150.degree. to 350.degree. C. and from 5 to 200 bar in the presence of a strongly acidic large-pore zeolite.Type: GrantFiled: July 12, 1996Date of Patent: February 2, 1999Assignee: BASF AktiengesellschaftInventors: Eugen Gehrer, Klemens Massonne, Wolfgang Harder
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Patent number: 5847247Abstract: The specification discloses terpene-based solvent compositions which comprise diterpenes as a major component and a minor amount of monoterpenes. The mixtures exhibit solvent properties similar to monoterpenes but have flash points high enough to be classified as combustible rather than flammable materials.Type: GrantFiled: March 18, 1996Date of Patent: December 8, 1998Assignee: Arizona Chemical CompanyInventors: Alexander J. Conte, Bobby G. Johnson, Raymond H. Jones, Claude F. Phillips, Jr.
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Patent number: 5807477Abstract: A process for treating a light cracked naphtha to be used as an etherification or alkylation feedstock in which the mercaptans and diolefins reacted in a single pass fixed bed reactor and are removed in a distillation column reactor which hydrogenate the unreacted diolefins. The mercaptans are reacted with the diolefins to form sulfides which are higher boiling than that portion of the naphtha which is used as feed to the etherification or alkylation unit. The higher boiling sulfides are removed as bottoms along with any C.sub.6 and heavier materials. Any diolefins not converted to sulfides are selectively hydrogenated to mono-olefins for use in the etherification process. Certain C.sub.5 olefins, for example pentene-1 and 3-methyl butene-1 are isomerized during the process to more beneficial isomers.Type: GrantFiled: September 23, 1996Date of Patent: September 15, 1998Assignee: Catalytic Distillation TechnologiesInventors: Dennis Hearn, Gary R. Gildert
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Patent number: 5723709Abstract: Terpene dimer compositions are provided which dry into a hard, tack free film upon exposure to air. The compositions include a terpene dimer having the molecular formula C.sub.20 H.sub.32 and contain at least one double bond. The terpene dimer is derived from a naturally occurring monoterpene, or mixtures thereof, having the molecular formula C.sub.10 H.sub.16. In an another embodiment the compositions, in addition to the terpene dimer, include isomers of the monoterpenes. The compositions are substantially free of higher terpene oligomers having molecular formulas greater than C.sub.20 H.sub.32. Processes for making the terpene dimer compositions are also provided. Advantageous utilization of these compositions is as a diluent, solvent or component in coating, adhesive, alkyd or ink formulations, as an environmentally safe non-toxic material.Type: GrantFiled: July 9, 1996Date of Patent: March 3, 1998Assignee: Arizona Chemical CompanyInventors: Claude Frank Phillips, Jr., James William Booth
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Patent number: 5662830Abstract: A novel liquid crystal material having a carbon chain containing a conjugated diene as a terminal substituent of the molecule and exhibiting superior characteristics is provided, which is a diene derivative expressed by the formula (I) ##STR1## wherein R and R' each independently represent 1-5C alkyl; A and B each independently represent 1,4-cyclohexylene or 1,4-phenylene; n is 0 or 1; m is an integer of 0 to 2; X and X' each independently represent H atom or F atom when A is 1,4-phenylene or represent H atom when A is 1,4-cyclohexylene; Y is alkyl, halogen or CN, alkoxy, methyl group substituted by 1-3 halogen atoms or trihaloalkoxy when A is 1,4-phenylene, or represent alkyl, alkoxy, methyl group substituted by 1-3 halogen atoms or trihaloalkoxy when A is 1,4-cyclohexylene; and R and R' are not simultaneously alkyl chain of 4 or more carbon atoms.Type: GrantFiled: July 11, 1996Date of Patent: September 2, 1997Assignee: Chisso CorporationInventors: Atsuko Fujita, Shuichi Matsui, Yuichi Onji, Makoto Ushioda, Yasuyuki Goto
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Patent number: 5455265Abstract: Process of treatment of mammals, including humans to treat diseases or conditions of the type which are normally treated with retinoid-like compounds is disclosed, with pharmaceutical compositions containing an active compound which is a selective agonist of the RXR retinoid receptor sites in preference to the RAR retinoid receptor sites. A compound is defined to be a selective agonist of the RXR receptor site if the compound is at least approximately ten times more effective as an agonist in the RXR receptor sites than in the RAR receptor sites.Type: GrantFiled: February 11, 1993Date of Patent: October 3, 1995Assignee: Allergan, Inc.Inventor: Roshantha A. S. Chandraratna
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Patent number: 5446222Abstract: The invention provides a two-step process for converting cyclopentadiene dimer to a high density fuel mixture comprising the steps of:(a) reacting said cyclopentadiene dimer in the presence of a solid catalyst comprising a porous crystalline material having a Constraint Index of from about 0.1 to about 12 under oligomerization/isomerization conditions to convert at least a portion of said cyclopentadiene dimer to a normally liquid intermediate product containing cyclopentadiene trimer, cyclopentadiene tetramer, and the isomerized and oligomerized products derived from the reaction of at least three cyclopentadiene monomer units;(b) hydrogenating said normally liquid intermediate product of step (a) in the presence of a hydrogenation catalyst to form a normally liquid high energy density fuel.Type: GrantFiled: June 17, 1994Date of Patent: August 29, 1995Assignee: Mobil Oil CorporationInventors: James R. Boulton, Ross A. Kremer
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Patent number: 5422027Abstract: A process for improving the traction coefficient between at least two relatively rotatable elements having tractive surfaces in a torque transmitting relationship which comprises introducing between the tractive surfaces of the elements a traction drive fluid comprising, as the active component, a hydrocarbon compound having a bicylo octane skeleton.Type: GrantFiled: November 1, 1993Date of Patent: June 6, 1995Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuaki Abe, Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 5399647Abstract: New copolymers are disclosed which are copolymers of 1-(1'-cyanoethenyl)adamantane or 2-norbornene-2-carbonitrile monomer with an acrylate or methacrylate monomer. Resist compositions are also disclosed which comprise one of the disclosed new copolymers and an acid generator. The resist compositions advantageously form thinner resist films on substrates and, on the exposure to light having a short wavelength, such as KrF and ArF excimer laser light, provide finer resist pattern required in the production of advanced, highly integrated semiconductor devices. Novel 1-(1'-cyanoethenyl)adamantane is also disclosed.Type: GrantFiled: July 15, 1994Date of Patent: March 21, 1995Assignee: Fujitsu LimitedInventor: Koji Nozaki
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Patent number: 5384059Abstract: Mixtures consisting essentially of cyclohexylbiphenyls, dicyclohexylbenzenes, phenylbicyclohexyls and tercyclohexyls are outstandingly suitable as heat transfer media. The mixtures can be prepared from biphenyl and cyclohexanol in the presence of bleaching earths and subsequent hydrogenation.Type: GrantFiled: August 20, 1993Date of Patent: January 24, 1995Assignee: Bayer AktiengesellschaftInventors: Alfons Klein, Rudolf Kron, Helmut Fiege, Klaus-Christian Paetz
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Patent number: 5344582Abstract: A traction fluid lubricant is disclosed which contains a naphthenic ingredient having a weight average molecular weight of 200-300 and obtained by hydrogenating oligomers of cyclopentadiene having a ratio of the number of norbornenic double bond to that of cyclopentenic double bond of smaller than 0.9 but not smaller than 0.1. The naphthenic ingredient is suitably used in conjunction with an auxiliary ingredient selected from a polybutene having a viscosity of 5-60 cSt at 40.degree. C. and a bicyclohexyl compound.Type: GrantFiled: July 29, 1992Date of Patent: September 6, 1994Assignee: Tonen CorporationInventors: Noboru Umemoto, Takeshi Nomura, Toshiaki Kuribayashi, Takehisa Sato, Hirotaka Tomizawa
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Patent number: 5306851Abstract: The invention provides a composition comprising at least about 10 different diamondoid compounds selected from the group consisting of methyl-substituted and ethyl-substituted adamantane, diamantane, and triamantane, wherein each of said selected diamondoid compounds comprises no more than about 10 weight percent of said composition. The composition is useful as high quality lubricating fluid and exhibits the unusual combination of high Viscosity Index and very low pour point.Type: GrantFiled: November 23, 1992Date of Patent: April 26, 1994Assignee: Mobil Oil CorporationInventors: Margaret M. Wu, Dong-Ming Shen, Catherine S. H. Chen
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Patent number: 5283384Abstract: A traction drive fluid composition comprising a hydrocarbon having a bicyclo octane skeleton, such as a bicyclo(3,2,1) octane skeleton, a bicyclo(2,2,2)octane skeleton or a bicyclo(3,3,0)octane skeleton. The traction drive fluid has a low viscosity and has a high traction coefficient over a wide temperature range.Type: GrantFiled: March 2, 1992Date of Patent: February 1, 1994Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuaki Abe, Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 5262501Abstract: Mixtures essentially comprising compounds of formula I or II ##STR1## wherein X is a hydrogen atom or vinyl, A is a divalent aromatic radical which is unsubstituted or substituted by one or more C.sub.1 -C.sub.20 alkyl groups, halogen atoms or halogen-substituted C.sub.1 -C.sub.20 alkyl groups, R.sub.1, R.sub.1 ', R.sub.2, R.sub.2 ', R.sub.3 and R.sub.3 ' are each a hydrogen atom, or R.sub.1 and R.sub.1 ', R.sub.2 and R.sub.2 ' and R.sub.3 and R.sub.3 ' are each together ethylene, R.sub.4 is C.sub.1 -C.sub.6 alkyl, phenylalkyl containing 1 to 6 carbon atoms in the alkyl moiety or is trialkylsilyl containing 1 to 6 carbon atoms in each alkyl moiety, m is 0, 1 or 2, n is 0 or an average number from 1 to 200, p is an average number from 1 to 100 and q is 0 or an average number from 1 to 100, can be cured by heating and are suitable for making laminates, especially for fabricating copper-clad circuit boards.Type: GrantFiled: May 12, 1992Date of Patent: November 16, 1993Assignee: Ciga-Geigy CorporationInventors: Sheik Abdul-Cader Zahir, Cecile Pasquier, Wolfgang Scharf, Maurice Dupre
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Patent number: 5107041Abstract: The invention provides a novel compound 1,1-dicyclohexyl cycloalkane derivative represented by the general formula ##STR1## in which R.sup.1 and R.sup.2 are each a hydrogen atom or lower alkyl group, R.sup.3 to R.sup.6 are each a hydrogen atom, lower alkyl group or alkylene group forming a ring structure together with either one of the others and the carbon atom in the cycloalkane ring, and m and n are each zero or a positive integer not exceeding 6 with the proviso that m+n is 4-6, such as 1,1-dicyclohexyl cyclohexane. The compound has a relatively low viscosity and high traction coefficient even at elevated temperatures so that it is useful as a constituent of a traction-drive fluid usable in a compact and light-weight traction-drive apparatus. The compound can be synthesized by subjecting a corresponding 1,1-di(hydroxyphenyl) cycloalkane compound to a hydrogenation reaction and dehydration reaction in combination in the simultaneous presence of a hydrogenation catalyst and a dehydration catalyst.Type: GrantFiled: September 13, 1989Date of Patent: April 21, 1992Assignee: Idemitsu Kosan Co., Ltd.Inventors: Kazuaki Abe, Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 5064642Abstract: A composition for external application comprising a tricyclic saturated hydrocarbon represented by formula (I) is disclosed. ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and independently represents a hydrogen atom or a methyl group and R.sup.3 represents an alkyl group having 2-3 carbon atoms. The compositions for external application of the present invention exhibit an excellent moisture-retention effect and impart moistened feel without sliminess and irritation to the skin. They are thus useful as skin cosmetics, hair cosmetics, medical compositions for external application, and the like.Type: GrantFiled: September 13, 1990Date of Patent: November 12, 1991Assignee: Kao CorporationInventors: Yoko Kikuchi, Yukihiro Ohashi, Yuji Suzuki, Toshiyuki Suzuki
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Patent number: 5053568Abstract: The present invention provides a lubricant additive and lubricant composition comprising the copolymer of 1-vinyladamantane and 1-alkene having from about 4 to about 16 carbon atoms, said copolymer having a Viscosity Index of at least 80 and a kinematic viscosity of at least 6 cS at 212.degree. F. The invention further provides a catalytic method for the preparation of such a copolymer useful as a lubricant stock. In a preferred embodiment of the composition, the 1-alkene is 1-decene. Suitable polymerization catalysts include both acid and coordination catalysts. Useful coordination catalysts include Group VIA metals on an inert support, for example, chromium oxide supported on silica, or Ziegler-Natta catalysts such as TiCl.sub.4 and aluminum alkyl, while useful acid catalysts include BF.sub.3 and AlCl.sub.3, and their appropriate co-catalysts.Type: GrantFiled: November 15, 1990Date of Patent: October 1, 1991Assignee: Mobil Oil Corp.Inventor: Catherine S. H. Chen
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Patent number: 5043497Abstract: A lubricating oil is disclosed, which mainly is composed of a naphthenic hydrocarbon having 19 carbon atoms comprising two cyclohexane rings which have methyl-substitution at the 1, 2 and 4 positions thereof, the two cyclohexane rings being linked by a methylene group.Type: GrantFiled: September 26, 1989Date of Patent: August 27, 1991Assignee: Mitsubishi Oil Co., Ltd.Inventors: Masayoshi Muraki, Hajime Yoshida, Koji Tsuchimoto
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Patent number: 5017734Abstract: 1,3-Diethynyl-5,7-dimethyladamantane; 1,3,5-triethynyladamantane; 3,3'-diethynyl-1,1'-biadamantane; 1-ethynyldiamantane; 1,4-diethynyldiamantane; 1,6-diethynyldiamantane and 4,9-diethynyldiamantane as new compositions of matter, and a method of forming them in which adamantane; 1,3-dimethyladamatane; 1-hydroxy-3,5-dimethyladamantane; 1,1'-biadamantane and diamantane are each brominated to form a bromo derivative thereof; the bromo derivative is reacted with vinyl bromide in the presence of a Friedel-Crafts catalyst to convert it to its corresponding 2,2-dibromoethyl derivative and the 2,2-dibromoethyl derivative is subjected to dehydrohalogenation to convert it to its final ethynyl form. The 1,3-diethynyl-5,7-dimethyladamantane; 1,3,5-triethynyladamantane; 3,3'-diethynyl-1,1'-biadamantane; 1,4-diethynyldiamantane; 1,6-diethynyldiamantane and 4,9-diethynyldiamantane can be heat cured to form homopolymers having useful commercial properties.Type: GrantFiled: December 11, 1989Date of Patent: May 21, 1991Inventors: Kurt Baum, Thomas G. Archibald, Aslam A. Malik
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Patent number: 4943302Abstract: A fuel composition with a high energy content, for direct-ignition internal combustion engines contains a gasoline from petroleum and an amount of up to 90% by volume, as referred to the same fuel composition, of hydrocarbon "cubane" or of its alkyl-derivatives, to be defined by means of the formula: ##STR1## wherein R' and R" represent, independently from each other, a hydrogen atom or an alkyl radical containing from 1 to 3 carbon atoms.Type: GrantFiled: October 11, 1989Date of Patent: July 24, 1990Assignees: Enichem Synthesis S.p.A., AGIP Petroli S.p.A.Inventors: Philip Eaton, Nereo Nodari, Carlo Neri, Luigi Cassar, Fabio Monti, Fausto Alberici
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Patent number: 4918158Abstract: 1,3-Diethynyladamantane and a method of forming same by brominating adamantane to yield 1,3-dibromoadamantane, subjecting vinyl bromide to Friedel-Crafts alkylation with the 1,3-dibromoadamantane to form 1,3-bis(2,2-dibromoethyl)adamantane and subjecting the 1,3-bis(2,2-dibromoethyl)adamantane to dehydrohalogenation to yield the 1,3-diethynyladamantane. 1,3-Diethynyladamantane can be polymerized to produce strong, thermally stable resins suitable for advanced aerospace structural applications, as matrices for carbon-carbon systems and as electrical insulators. It can also be copolymerized with 1-ethynyladamantane to yield similarly useful resins.Type: GrantFiled: July 21, 1986Date of Patent: April 17, 1990Assignee: Fluorochem Inc.Inventors: Kurt Baum, Thomas G. Archibald
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Patent number: 4804795Abstract: The present invention provided a high-density fuel oil comprising an isomerized product prepared by isomerizing an alicyclic saturated hydrocarbon represented by the following formula in the presence of an acid catalyst: ##STR1## wherein each of m and n is 0 or 1, and each of R.sup.1 to R.sup.3 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, but the number of the total carbons of R.sup.1 to R.sup.3 is within the range of 1 to 3.Type: GrantFiled: February 2, 1988Date of Patent: February 14, 1989Assignee: Nippon Oil Co., Ltd.Inventors: Hitoshi Yuasa, Mitsuo Matsuno, Hirosuke Imai
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Patent number: 4755317Abstract: The working fluid for traction drive use has a particularly high traction coefficient at high temperatures and the principal ingredient thereof is a decahydronaphthalene compound substituted, on either one or both of the decahydronaphthalene rings, with two or three substituent groups which may be cyclohexyl groups, cyclohexyl alkyl groups, e.g. cyclohexyl methyl, cyclohexyl ethyl, 1-methyl-1-cyclohexyl ethyl and 1-methyl-1-(methylcyclohexyl) ethyl groups, or a combination thereof. The working fluid can be a mixture of a base oil of various types and the above mentioned decahydronaphthalene compound in an amount of 5 to 250 parts by weight per 100 parts by weight of the base oil.Type: GrantFiled: March 18, 1987Date of Patent: July 5, 1988Assignee: Idemitsu Kosan Company LimitedInventors: Tomiyasu Minokami, Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 4707295Abstract: Bicyclooctane derivatives of the formula IR.sup.1 --A.sup.1 --A.sup.2 --R.sup.2 IwhereinR.sup.1 and R.sup.2 independently of one another are each an alkyl group which has 1-12 C atoms and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by O atoms and/or CO groups and/or --O13 CO groups and/or --CO--O groups and/or --CH.dbd.CH-- groups, one of the radicals R.sup.1 and R.sup.2 being also --A.sup.3 --R.sup.3,A.sup.1 is a 1,4-cyclohexylene group which is unsubstituted or substituted in the 1-position and/or 2-position and/or 3-position and/or 4-position by alkyl which has in each case 1-5 C atoms and is unsubstituted or substituted or fluorinated, and in which it is also possible for one or two non-adjacent CH.sub.2 groups to be replaced by one or two different groupings from the group --O--, --CO--, --CH.dbd.CH--, --S--, --SO-- or --SO.sub.2 --, or is substituted by F, Cl, Br, CN and/or CHO,A.sup.2 is a 1,4-bicyclo[2.2.2] octylene group,--A.sup.3 --R.sup.3 is --Cy--R.sup.Type: GrantFiled: March 24, 1986Date of Patent: November 17, 1987Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Ludwig Pohl, Bernhard Scheuble, Andreas Wachtler, Reinhard Hittich, Peter Fuss
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Patent number: 4684754Abstract: The working fluid for traction drive comprises (A) a compound having, in a molecule, two decahydronaphthalene rings bonded either directly to each other or to the same or different carbon atoms in an alkane molecule or a compound having, in a molecule, one decahydronaphthalene ring and one cyclohexane ring bonded either directly to each other or to the same carbon atom in an alkane molecule and (B) a compound having two cyclohexane rings bonded either to the terminal carbon atoms of a C.sub.2-3 alkane molecule or to the carbon atoms of cyclopentane. The working fluid has a high traction coefficient with stability over a wide range of temperature, especially, in low temperatures.Type: GrantFiled: November 14, 1986Date of Patent: August 4, 1987Assignee: Idemitsu Kosan Company LimitedInventors: Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 4675459Abstract: A traction drive fluid comprising as a base stock at least one hydrocarbon selected from the group consisting of compounds of the following general formulae (I) to (V) ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3, independently from each other, represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9 and R.sup.10, independently from each other, represent a hydrogen atom or a methyl group.Type: GrantFiled: July 1, 1986Date of Patent: June 23, 1987Assignee: Nippon Oil Company, Ltd.Inventors: Hitoshi Yuasa, Mitsuo Matsuno
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Patent number: 4627933Abstract: Compounds of the formulaR.sup.1 --Q.sup.1 --(CH.sub.2).sub.m --(COO).sub.n --(CH.sub.2).sub.p --Q.sup.2 --R.sup.2whereinR.sup.1 and R.sup.2 are each independently alkyl or alkoxy each of 1-12 C atoms, F, Cl, Br, CN or --Q.sup.3 --R.sup.3, or one of R.sup.1 and R.sup.2 can also be H;Q.sup.1, Q.sup.2 and Q.sup.3 are each independently 1,4-phenylene, 1,4-cyclohexylene, 1,4-bicyclo(2,2,2)-octylene or 1,3-dioxane-2,5-diyl, each of which is unsubstituted or substituted by 1-4 fluorine, chlorine or bromine atoms;R.sup.3 is alkyl or alkoxy each of 1-8 C atoms, H, F, Cl, Br or CN;m is 1, 2, 3, 4, 5 or 6; n is 0 or 1; and p is 0, 1, 2, 3, 4 or 5; the sum of (m+p) being 2, 4 or 6 and the sum of (m+n+p) being at least 3;but with the proviso that Q.sup.3 is unsubstituted 1,4-phenylene or 1,4-phenylene substituted by a fluorine, chlorine or bromine atom, only when n=1 or (m+p)=6 or at least one of R.sup.1 or R.sup.3 is F, Cl or Br or none of R.sup.1 to R.sup.3 is CN or two of the radicals R.sup.1 to R.sup.Type: GrantFiled: July 7, 1983Date of Patent: December 9, 1986Assignees: Merck Patent Gesellschaft mit beschrankter Haftung, The Secretary of State for Defense in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern IrelandInventors: Rudolf Eidenschink, Joachim Krause, Beatrice M. Andrews, George W. Gray, Neil Carr
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Patent number: 4609481Abstract: A traction drive fluid composition comprising the principal component of at least one component represented by the general formula (I): ##STR1## wherein R.sup.1 to R.sup.5 are each a hydrogen or an alkyl group containing from 1 to 4 carbon atoms, and 1, m and n are each 1 to 3, said compound (I) comprising a mixture of 70% or less of the cis-form and 30% or more of the trans-form.Type: GrantFiled: May 21, 1985Date of Patent: September 2, 1986Assignee: Idemitsu Kosan Company LimitedInventors: Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 4604492Abstract: The invention provides a novel class of compounds dicyclohexylcyclopentanes or, in particular, 1,3-dicyclohexyl-1-methyl cyclopentane which is synthesized by the hydrogenation of 1-methyl-1,3-diphenyl cyclopentane which in turn is obtained by the dimerization reaction of .alpha.-methylstyrene in the presence of metallic sodium as the catalyst. The compound is useful as a fluid for traction drive.Type: GrantFiled: October 8, 1985Date of Patent: August 5, 1986Assignee: Idemitsu Kosan Company LimitedInventors: Nobuaki Shimizu, Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 4604490Abstract: The present invention is connected with a high-density liquid fuel for rockets and jet engines which mainly comprises a compound represented by the general formula ##STR1## wherein each of m and n is 0 or 1, and each of R.sup.1 to R.sup.3 is a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, but a sum of R.sup.1 to R.sup.3 is an integer of 1 to 3.Type: GrantFiled: June 19, 1985Date of Patent: August 5, 1986Assignee: Nippon Oil Company Ltd.Inventors: Hitoshi Yuasa, Mitsuo Matsuno, Hirosuke Imai
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Patent number: 4604493Abstract: The invention provides a novel compound 1-cyclohexyl-1,4-dimethyl decahydronaphthalene which is useful as fluids for traction drive. The compound can be synthesized by the hydrogenation of 1,4-dimethyl-4-phenyl-1,2,3,4-tetrahydronaphthalene and analytical results for the identification of the compound are given.Type: GrantFiled: October 8, 1985Date of Patent: August 5, 1986Assignee: Idemitsu Kosan Company LimitedInventors: Nobuaki Shimizu, Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 4570024Abstract: An aromatic hydrocarbon in which at least one hydrogen atom on the ring is substituted by a group selected from the class consisting of unsubstituted or lower alkyl-substituted tricyclo[5.2.1.0.sup.2,6 ]dec-3-yl, tricyclo[5.2.1.0.sup.2,6 ]dec-4-yl, tetracyclo[6.2.1.1.sup.3,6.0.sup.2,7 ]dodec-4-yl and tetracyclo[6.2.1.1.sup.3,6.0.sup.2,7 ]dodec-5-yl groups, or its hydrogenation product.The compound is prepared by reacting an aromatic hydrocarbon having at least one hydrogen atom on the ring with a compound selected from the group consisting of unsubstituted or lower alkyl-substituted tricyclo[5.2.1.0.sup.2,6 ]dec-3-ene and tetracyclo[6.2.1.1.sup.3,6.0.sup.2,7 ]dodec-4-ene in the presence of a Friedel-Crafts catalyst, or hydrogenating the thus-obtained compound in the presence of a hydrogenation catalyst.The compound is useful as an additive for adhesives.Type: GrantFiled: May 7, 1985Date of Patent: February 11, 1986Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kinya Mizui, Masami Takeda, Yoshimi Ozaki, Ryosuke Tomita
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Patent number: 4556503Abstract: A traction drive fluid is described, containing as the base stock a compound represented by the general formula (I): ##STR1## wherein all the symbols are as defined in the appended claims. This traction drive fluid has a high traction coefficient, has a good thermal stability, is of low viscosity, is of low volatility and further is reduced in temperature dependency of viscosity. Thus it is suitable for use in continuously variable transmission of cars or industrial machines.Type: GrantFiled: September 4, 1984Date of Patent: December 3, 1985Assignee: Idemitsu Kosan Company LimitedInventors: Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 4544497Abstract: Liquid crystal compositions are described which comprise a mixture of compounds and which includes at least one additive compound characterized in that the composition includes one or more additive compounds of Formula I as follows: ##STR1## wherein R.sub.1 represents an alkyl group, R.sub.2 represents an alkyl or alkoxy group or hydrogen and ##STR2## represents a 1,4-disubstituted bicyclo(2,2,2)octane ring. The preparation and properties of novel compounds of Formula I are also described. These liquid crystal compositions are useful in display devices such as digital calculators and word displays.Type: GrantFiled: January 25, 1984Date of Patent: October 1, 1985Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern IrelandInventors: Hilal M. Abdullah, Jennifer Constant, George W. Gray, Damien G. McDonnell, Kenneth J. Toyne
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Patent number: 4525290Abstract: A process for improving traction coefficient of traction drive fluid at high temperatures by using a compound represented by the general formulae (I), (II) or (III) as a base stock of traction drive fluid, ##STR1## (All the symbols are as defined in the appended claims). This process is helpful for reducing the change of traction coefficients over a wide range of from low temperature to high temperature.Type: GrantFiled: June 29, 1984Date of Patent: June 25, 1985Assignee: Idemitsu Kosan Company LimitedInventors: Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 4521324Abstract: A fluid for traction drive is described, containing a liquid material as a base stock wherein the liquid material is prepared by bringing naphthalene or tetralin into contact with a Friedel-Crafts catalyst and then hydrogenating the resulting compounds. This traction drive fluid exhibits a superior traction coefficient from low temperature to elevated temperature and further has a low viscosity. Thus the fluid contributes to the production of small-sized drive mechanisms and can be widely used in various machines.Type: GrantFiled: October 7, 1983Date of Patent: June 4, 1985Assignee: Idemitsu Kosan Company LimitedInventors: Toshiyuki Tsubouchi, Hitoshi Hata
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Patent number: 4434073Abstract: Perhydrophenanthrene derivatives of formula I ##STR1## wherein R.sub.1 is alkyl of 1-10 C atoms and R.sub.2 is alkyl, alkoxy or alkanoyloxy each of 1-10 C atoms, H, Br, Cl or CN, have an extremely low optical anisotropy and are particularly suitable as components of liquid-crystalline dielectrics.Type: GrantFiled: December 8, 1982Date of Patent: February 28, 1984Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Wolfgang Sucrow, Hans-R/u/ diger Murawski, Hermann Minas, Horst Stegemeyer