Abstract: Feedstock comprising C.sub.2.sup.+ olefins, C.sub.2 -C.sub.7 paraffins or a mixture thereof is converted to product comprising C.sub.5.sup.+ hydrocarbon compounds over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.
Abstract: A process is provided for converting feedstock comprising C.sub.2.sup.+ olefins, C.sub.2 -C.sub.7 paraffins or mixtures thereof to product comprising C.sub.5.sup.+ hydrocarbons over a catalyst comprising zeolite ZSM-58.
Abstract: A process is provided for converting feedstock comprising C.sub.2.sup.+ olefins, C.sub.2 -C.sub.7 paraffins or a mixture thereof to conversion product comprising C.sub.5.sup.+ hydrocarbon compounds over a catalyst composition prepared by compositing a high-silica zeolite having a Constraint Index of from 1 to 12 with binder, followed by treating the composite under conditions effective for increasing the catalytic activity of the composition.
Abstract: The invention is directed to improve the profitability of existing catalytic cracking operations. Specifically, in thermofor catalytic cracking, liquified petroleum gases (LPG) are injected to the internal seal leg of the reactor for converting LPG to more valuable products and to prevent products and feed from surging out of the reaactor vessel.
Abstract: A process is provided for converting feedstock comprising paraffins, olefins or mixtures thereof to product comprising C.sub.5 + hydrocarbons over a catalyst comprising a high silica crystalline zeolite which has been treated by steps of calcining the crystalline material, contacting the calcined material with solid aluminum fluoride, and converting the aluminum fluoride contacted material to hydrogen form.
Abstract: Y Zeolites are prepared with rare earth cations and Group VIII metal cations exchanged thereinto, such zeolites being especially useful in hydrocracking catalysts. The zeolites of the invention are prepared by exchanging a sodium Y zeolite with cations of one or more rare earth elements followed by a calcination, an ammonium ion exchange, and a Group VIII metal cation exchange. The resultant zeolite is not only highly active for catalytically promoting hydrocracking reactions but is also, after use in hydrocracking environments resulting in coke deposition, essentially completely regenerable by combustion of the coke.
Abstract: A process for the conversion of a hydrocarbon charge stock which comprises contacting said charge stock at hydrocarbon conversion conditions with a catalytic composite comprising a combination of a carrier material, a Group VIB metal component and Group VIII metal component wherein said Group VIB metal component and said Group VIII metal component are incorporated in said catalytic composite by means of a non-aqueous organic solution of a Group VIB metal compound and a Group VIII metal compound, wherein said non-aqueous organic solution comprises dimethylformamide, formamide, diethylformamide, ethylformamide, methylformamide, pyridine, aniline or toluene and wherein said catalytic composite is calcined in a non-oxidizing atmosphere.
Abstract: A method of preparing aromatics processing catalysts which comprises incorporating a noble metal with a member or members of a useful class of zeolites, with such incorporation occurring after zeolite crystallization, but prior to final catalyst particle formation, i.e. extrusion into particles. Said useful class of zeolites is characterized by a silica to alumina mole ratio of at least 12 and a Constraint Index in the approximate range of 1 to 12.
Abstract: An improved process for alkylation of isoparaffins with olefins to yield a product which includes a high proportion of highly branched alkylates for blending into gasolines. The improved process comprises contacting the isoparaffins and olefins with a composite catalyst comprising a large pore zeolite and a Lewis acid.
Abstract: An improved process for alkylation of isoparaffins with olefins to yield a product which includes a high proportion of highly branched alkylates for blending into gasolines. The improved process comprises contacting the isoparaffins and olefins with a catalyst comprising ZSM-20, preferably a HZSM-20 zeolite or a rare-earth cation exchanged ZSM-20 zeolite.
Abstract: Hydrocarbon, suitable for use as propellant, is contacted with a solid effective to remove odor-forming impurity therefrom. Hydrocarbons include isobutene-containing stream also containing minor proportions of unsaturated hydrocarbon, e.g. ethylene, propylene, isobutylene, and 2-butenes. Solids include an acid montmorillonite clay, aluminum chloride, AlCl.sub.3 .multidot.HCl, AlCl.sub.3 .multidot.RCl, at least one metal of Groups I, II, and III of the periodic table, and supported H.sub.3 PO.sub.4.
Type:
Grant
Filed:
May 22, 1979
Date of Patent:
September 28, 1982
Assignee:
Phillips Petroleum Company
Inventors:
Robert E. Reusser, Elizabeth A. Claytor, Brenton E. Jones
Abstract: Processes are provided for conducting selective acid catalyzed reactions involving olefins. Said catalytic reactions comprise isomerization, alkylation, addition, oligomerization, polymerization, aromatization, cracking and hydrocracking. The useful catalysts of this invention are the acidic forms of a novel class of zeolites characterized by a silica to alumina mole ratio of at least 12 and a constraint index in the approximate range of greater than about 2 to about 12. By utilization of such zeolites, smaller olefins are preferentially reacted when in mixed streams with larger olefins. Further of the such smaller olefins, linear olefins are preferentially reacted when in mixed streams with non-linear olefins and lesser branched olefins are preferentially reacted when in mixed streams with more highly branched olefins.
Abstract: A hydrocarbon conversion catalyst composition, useful for paraffin-olefin alkylation, can comprise a three dimensional crystalline zeolite molecular sieve having a pore size large enough to adsorb 2,2,3-trimethylpentane and having a composition expressed in terms of mole ratios of oxides asa(I.sub.2 O):b(IIO):c(III.sub.2/3 O):d(IV.sub.1/2 O)Al.sub.2 O.sub.3 :eSiO.sub.2wherein I represents a monovalent metal cation; II represents a divalent metal cation; III represents a trivalent metal cation; IV represents a tetravalent cation; a has a value of from zero to 0.15; b has a value of from zero to 0.75; c and d each have values of from zero to 1; e has a value of from 2 to 20; with the proviso that when e has a value of from 2 to 3, the value of ((b+c)=0.75 to 1 and d=0; and with the proviso that when e has a value of > 3 to 4, the value of (b+c+d)=0.6 to 1.0; and with the further proviso that when e has a value of > 4 to 20, the value of (b+c+d)=0.25 to 1.0.
Type:
Grant
Filed:
March 4, 1975
Date of Patent:
November 10, 1981
Assignee:
Sun Oil Company of Pennsylvania
Inventors:
Francis W. Kirsch, David S. Barmby, John D. Potts
Abstract: A process for the simultaneous production of high octane motor fuel and isobutane. The process is effected with a physical mixture of compatible reforming catalyst and hydrocracking catalyst.