Abstract: An improvement in the alkylation of olefins with isoalkanes in the presence of sulfuric acid wherein the sulfuric acid is removed from the product by a mechanical coalescer means prior to fractionation. No water wash or caustic treatment is required. Any sulfonates or sulfonic esters are removed by hydrodesulfurization or decomposition catalyst in a separate reactor or in either the deisobutanizer (DIB) or debutanizer (DB) column.

Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises (1) at least one solid acid component, (2) at least one metal-based component comprised of two or more elements from Groups 4–15 of the Periodic Table of the Elements and at least one of oxygen and sulfur, wherein the elements from Groups 4–15 and the at least one of oxygen and sulfur are chemically bound both within and between the groups and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.

Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises: (1) at least one solid acid component, (2) at least one metal-based component comprised of (i) at least one of oxygen and sulfur (ii) one or more elements from Groups 5–15 of the Periodic Table of the Elements; and (iii) one or more elements from at least one of (a) Groups 1–2 and (b) Group 4; of the Periodic Table of the Elements; and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.

Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed. The catalyst comprises (1) at least one solid acid component, (2) at least one metal-based component comprised of one or more elements from Groups 1 and 2; one or more elements from Group 3; one or more elements from Groups 4–15 of the Periodic Table of the Elements; and at least one of oxygen and sulfur and (3) at least one of at least one support, at least one filler and at least one binder. The process is such that the yield of hydrogen is less than the yield of hydrogen when contacting the hydrocarbons with the solid acid component alone.

Abstract: A catalyst system and process for combined cracking and selective hydrogen combustion of hydrocarbons are disclosed.

Abstract: A process for the removal of organic sulfur compounds, primarily oxygenated organic compounds, such as sulfates and sulfonic esters from a hydrocarbon liquid is disclosed which comprises contacting the hydrocarbon liquid with a coalescer comprising a mesh material which has been wetted by sulfuric acid. The hydrocarbon liquid may be the product from a sulfuric acid catalyzed alkylation process and contain sufficient sulfuric acid to remove the sulfates and sulfonic esters. Sulfuric acid may be added to the coalescer vessel counter current to the hydrocarbon liquid to improve the efficiency of the contacting and removal.

Abstract: Multifunctional liquid phase carriers (LPCs) and methods of using LPCs for the preparation of biopolymers are provided. The LPCs are highly symmetrical compounds that possess more than two points of attachment for biopolymer synthesis. The LPCs have the formula Sp(X1)n, where Sp is a highly symmetrical moiety such that all X1 groups are equivalent. X1 is a functional group that is suitable for biopolymer synthesis, including OH, SH, NH2, COOH and the like. Biopolymers that may be produced using the methods provided include oligonucleotides, peptides, protein nucleic acids (PNAs) and oligosaccharides. Analogs of the biopolymers may also be prepared using the methods.

Abstract: Disclosed is a process for removing DME from a stream containing C4 olefins. The process includes providing a first stream comprising C4 olefins, C5+ hydrocarbons, DME, and methanol. The first stream is separated into a second stream comprising the C4 olefins and the DME and a third stream comprising the C5+ hydrocarbons and the methanol. The second stream is directed to a DME absorption unit, wherein the second stream contacts water under conditions effective to separate the C4 olefins from the DME. Also disclosed is a process including contacting the first stream with water in a methanol removal unit under conditions effective to separate remove the methanol therefrom; distilling the methanol-depleted stream to remove C5+ hydrocarbon components, and contacting the stream with water in a DME removal unit under conditions effective to form an overhead stream comprising the C4 olefins and a bottoms stream comprising the DME.

Abstract: Multifunctional liquid phase carriers (LPCs) and methods of using LPCs for the preparation of biopolymers are provided. The LPCs are highly symmetrical compounds that possess more than two points of attachment for biopolymer synthesis. The LPCs have the formula Sp(X1)n, where Sp is a highly symmetrical moiety such that all X1 groups are equivalent. X1 is a functional group that is suitable for biopolymer synthesis, including OH, SH, NH2, COOH and the like. Biopolymers that may be produced using the methods provided include oligonucleotides, peptides, protein nucleic acids (PNAs) and oligosaccharides. Analogs of the biopolymers may also be prepared using the methods.

Abstract: Process for obtaining a hydrocarbon fraction that can be used as a feedstock of an etherification unit and that contains a small amount of diene compounds, nitrogen-containing compounds and sulfur-containing compounds, starting from an initial hydrocarbon feedstock that comprises a mixture of olefins, dienes, and nitrites as well as sulfur-containing compounds, whereby said process comprises at least the following successive stages: a) a selective hydrogenation of said initial hydrocarbon feedstock in the presence of a catalyst of group VIII of the periodic table, b) a fractionation by distillation of the effluents that are obtained from stage a) under conditions that make it possible to obtain at least two fractions including said hydrocarbon fraction and that comprises a small amount of diene compounds, nitrogen-containing compounds and sulfur-containing compounds, and a heavy fraction that contains heavy hydrocarbons and the majority of the nitrogen-containing compounds and sulfur-containing compounds

Abstract: Disclosed are processes for the recovery and purification of higher diamondoids from a hydrocarbonaceous feedstock. Specifically disclosed is a multi-step recovery process for obtaining diamondoid compositions enhanced in tetramantane components and other higher diamondoid components. Also disclosed are compositions comprising at least about 10 weight percent of non-ionized tetramantane components and other higher diamondoid components and at least about 0.5 weight percent of non-ionized pentamantane components and other higher diamondoid components based on the total weight of diamondoid components present.

Abstract: Disclosed are processes for the recovery and purification of higher diamondoids from a hydrocarbonaceous feedstock. Specifically disclosed is a multi-step recovery process for obtaining diamondoid compositions enhanced in tetramantane components and higher diamondoid components. Also disclosed are compositions comprising at least about 10 weight percent of non-ionized tetramantane components and higher diamondoid components and at least about 0.5 weight percent of non-ionized pentamantane components and higher diamondoid components based on the total weight of diamondoid components present.

Abstract: Disclosed are compositions comprising one or more pentamantanes. Specifically disclosed are compositions comprising 10 to 100 weight percent of one or more pentamantanes. Also disclosed are novel processes for the separation and isolation of pentamantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more pentamantane components.

Abstract: A method of separating and purifying conjugated dienes includes a step of obtaining a first bottom product by taking out a hydrocarbon mixture including conjugated diene under an environment in the presence of a polymerization inhibitor including at least one of nitrite and di-lower aklylhydroxylamine in a first extractive distillation column; a step of obtaining a second bottom product and a distillation portion by distilling the first bottom product in a first diffusion column; a step of obtaining a third bottom product by taking out the distillation portion under an environment in the presence of the polymerization inhibitor in a second extractive distillation column; a step of obtaining a fourth bottom product by distilling the third bottom product in a second diffusion column; a step of recovering the second bottom product and fourth bottom product and supplying to the first extractive distillation column and/or second extractive distillation column; a step of measuring concentration of a polymerization

Abstract: Disclosed are compositions comprising one or more octamantanes. Specifically disclosed are compositions comprising 25 to 100 weight percent of one or more octamantanes. Also disclosed are novel processes for the separation and isolation of octamantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more octamantane components.

Abstract: Disclosed are compositions comprising one or more heptamantanes. Specifically disclosed are compositions comprising 25 to 100 weight percent of one or more heptamantanes. Also disclosed are novel processes for the separation and isolation of heptamantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more heptamantane components.

Abstract: Disclosed are compositions comprising one or more tetramantanes. Specifically disclosed are compositions comprising 10 to 100 weight percent of one or more tetramantanes. Also disclosed are novel processes for the separation and isolation of tetramantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more tetramantane components.

Abstract: Disclosed are compositions comprising one or more tetramantanes. Specifically disclosed are compositions comprising 10 to 100 weight percent of one or more tetramantanes. Also disclosed are novel processes for the separation and isolation of tetramantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more tetramantane components.

Abstract: Disclosed are compositions comprising one or more hexamantanes. Specifically disclosed are compositions comprising 25 to 100 weight percent of one or more hexamantanes. Also disclosed are novel processes for the separation and isolation of hexamantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more hexamantane components.

Abstract: Disclosed are compositions comprising one or more nonamantanes. Specifically disclosed are compositions comprising 25 to 100 weight percent of one or more nonamantanes. Also disclosed are novel processes for the separation and isolation of nonamantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more nonamantane components.

Abstract: In a method and an apparatus for cleaning tar-bearing waste water (17), a mixture of water and hydrocarbons, e.g. comprising polyaromatic hydrocarbons and phenols, the mixture is separated into a low-boiling-point part and a high-boiling-point part, bringing the low-boiling-point part on vapour form in a boiler (1), and the low-boiling-point part is cracked in vapour form at a high temperature in a reactor (2), providing light combustible gases, which can be utilised in e.g. gas engines, gas turbines or the like. Furthermore, the high-boiling-point part may be used for energy supply to the process or other processes or as an alternative be cracked for providing light combustible gases.

Abstract: The method comprises separation of contacting products into liquid and gaseous products, complete burning of gaseous products in the presence of the catalyst of complete oxidation of light hydrocarbons and addition of carbon dioxide and water vapor mixture formed during burning to the raw paraffin hydrocarbons. The mixture of paraffin hydrocarbons C2÷C5 is used as a raw material in this method. Before feeding the said mixture of hydrocarbons the catalyst is subjected to treatment by paraffin hydrocarbons C3÷C4 mixed with mercaptan so that the amount of mercaptan passed through the catalyst is 0.01-0.1 mass % of the catalyst weight.

Abstract: A process for partial oxidation of a hydrocarbon gas or liquid, involving the steps of partial oxidation and removal of soot by forming a slurry having water and carbon from the gaseous oxidation product, and separating part of the water from the slurry to obtain a soot composition having less water, wherein the separation is performed by means of a decanter centrifuge.

Abstract: The invention relates to a method for producing naphthalene from coke oven crude gas. The coke oven crude gas is directly cooled by means of sprinkling water thereon, and the naphthalene is obtained by subsequent refrigerating and treatment. The invention is characterised in that after direct cooling, the coke oven crude gas is then guided through an electrofiler to be subsequently cooled in such a manner that the naphthalene contained in the coke oven crude gas is separated from the gaseous phase and is obtained in the form of pure naphthalene without any additional treatment.

Abstract: Hydroprocessing such as hydrocracking is advantageously employed in processes for the recovery and purification of higher diamondoids from petroleum feedstocks. Hydrocracking and other hydroprocesses degrade nondiamondoid contaminants.

Abstract: A process for the separation of diisobutylene from tertiary butyl alcohol utilizing pressure swing azeotropic distillation to achieve the desired separation. The pressure swing azeotropic distillation takes advantage of the fact that different azeotropes are formed at different pressures. Isobutylene in C4 streams is oligomerized in the presence of tertiary butyl alcohol to produce the diisobutylene. Tertiary butyl alcohol is present in the dimerization because it improves the selectivity to the dimer (diisobutylene) by suppressing further reaction to the trimer or higher. The diisobutylene is separated from the tertiary butyl alcohol utilizing two distillation columns. The first distillation is operated at a higher pressure than the second such that the minimum boiling azeotropes of tertiary butyl alcohol and diisobutylene have different concentrations of tertiary butyl alcohol. Diisobutylene is removed as bottoms from the first distillation column and unreacted C4's are removed as overheads at 60-130 psig .

Abstract: The present invention is a heat-integrated process for obtaining an ethylene and propylene enriched stream from an oxygenate to olefin reactor. The process comprises providing an effluent stream from an oxygenate to olefins reactor. The effluent stream comprises ethylene, propylene and one or more byproducts selected from the group consisting of propane, methyl acetylene, propadiene, dimethyl ether, acetaldyhyde and butylene. The process further includes quenching the effluent stream with the quench medium to provide an olefin stream. The olefin stream is separated into a heavy fraction and a remaining fraction. The remaining fraction is directed to a distillation column which separates the remaining fraction into a first fraction comprising a majority of both ethylene and a propylene and a second fraction comprising at least a majority of one or more heavier fraction. The bottoms of the distillation column is reboiled by the quench medium.

Abstract: The present invention includes methods for improving the operational parameters in primary fractionators which are experiencing diminished operation efficiencies due to deposits of polymerized hydrocarbon species. The invention comprises the step of adding a foam reducing amount of a foam reducing composition at the primary fractionator. A reduction in foaming is achieved whereby the operational efficiency of the process is improved based upon operation parameters including, but not limited to, liquid-gas contact ratio, product top temperature, pressure differentials, gasoline end point or combinations thereof.

Abstract: Taught is a process for purifying a benzoquinoid ansamycin antibiotic such as geldanamycin through the use of a fluid comprising supercritical carbon dioxide. In certain embodiments the fluid also includes an aliphatic alcohol such as methanol or ethanol.

Abstract: A gas/liquid(s) separation system is constituted by three different sections: a primary separator (1) for flows with a G/L in the range 0.1 to 10; a secondary separator (2) for flows with a G/L in the range 10 to 50; a system (3) which limits the formation of a liquid vortex; where G/L is the ratio of the gas to liquid mass flow rates. The separation system is suitable for the separation of gas and liquid from a hydrocarbon conversion process, e.g. a hydrotreatment process.

Abstract: A process for the dimerization of isobutene wherein tertiary butyl alcohol is used to enhance the selectivity of the catalyst to the dimer is disclosed wherein the tertiary butyl alcohol is removed from the diisobutene product by water wash. The water/TBA stream is then subjected to reextraction to remove the TBA for recycle to the dimerization reactor. The dimerization is preferably carried out in a reactor wherein the pressure is controlled to maintain the reaction mixture at is boiling point. Additional dimerization is carried out in a distillation column reactor that acts as a debutanizer to separate the unreacted isobutene form the product and the tertiary butyl alcohol.

Abstract: Process for the continuous drying of a hydrocarbon stream at a temperature being effective in drying the stream with an ionic liquid drying agent comprising a salt of sulphuric acid being in liquid or melted form at the drying temperature.

Abstract: A processing method and system for separating methane-rich and ethane-rich components from an LNG stream. The LNG stream is preheated against a distillation column overhead vapor stream and against an overhead vapor product prior to entering the column. The overhead vapor product is methane-rich. The LNG stream may further be preheated against the column bottoms and another heating medium. The method may also include compressing the methane-rich product, condensing it against the LNG stream, and pumping it. The system may also comprise third and fourth heat exchangers configured to preheat the LNG stream with the bottoms product and the heating medium. Further, the system may provide for compressing the overhead vapor product prior to the its exchanging heat with the LNG stream and a pump for pumping condensed overhead vapor product. Additionally, the system generates all of the required reflux by cross exchanging the column overhead with the incoming LNG stream.

Abstract: An integrated process for producing LNG and GTL products is provided comprising cooling natural gas in at least one cooling step so as to provide a cooled natural gas stream; processing the cooled natural gas stream in at least two expansion/separation cycles, each expansion/separation cycle comprising the Substeps of (a) isentropically or isenthalpically expanding at least a portion of the cooled natural gas steam for producing a natural gas vapor component and a LNG component, (b) separating at least a portion of the natural gas vapor component from the LNG component, and (c) repeating substeps (a) through (b) wherein at least a portion of the LNG component from the previous expansion/separation cycle is directed to each successive Substep (a) and wherein the final LNG product is the LNG component after the final separating step and is substantially liquid at substantially atmospheric pressure; and converting at least a portion of one or more of the expansion/separation cycle natural gas vapor components in

Abstract: This invention is directed to a method of removing dimethyl ether from an olefin stream. The method includes distilling the olefin stream so that the dimethyl ether is separated out of the olefin stream with propane. The olefin stream can then be further distilled to provide a polymer grade ethylene stream and a polymer grade propylene stream, with each stream containing not greater than about 10 wppm dimethyl ether.

Abstract: Disclosed is a method for recovering olefin in an oxygenate to olefin production process. The method includes reacting a stream containing olefin with water in the presence of a hydrating catalyst to produce an alcohol containing stream. The alcohol containing stream can be used as an oxygenate feed in the oxygenate to olefin production process.

Abstract: A purification method is disclosed for a predetermined water-insoluble extractant present in a liquid phase composition that additionally contains one or more additional extractants, synthesis reaction starting materials, and reaction byproducts dissolved as solutes in an organic diluent. An ion-containing compound is admixed with the composition to form an extractant/ion complex in the organic diluent phase that has an affinity for a new phase that is greater than the affinity for the first-named phase. The predetermined extractant/ion complex is separated from the diluent by using the new phase affinity, and the extractant/ion complex is preferably although not necessarily recovered. The extractant/ion complex is separated into extractant and ion. The extractant is recovered. Exemplary extractants include polyethers, crown ethers, crown thioethers, calixarenes, polyamines, cryptands, porphyrins and the like.

Abstract: A process is provided to produce a dilute ethylene stream and a dilute propylene stream to be used as feedstocks for producing olefin-based derivatives. Specifically, the dilute ethylene stream is used as a feedstock to produce ethylbenzene, and the dilute propylene stream is used as a feedstock to produce cumene, acrylic acid, propylene oxide and other propylene based derivatives.

Abstract: This invention describes materials and methods usable for the purification of polyelectrolytes, such as nucleic acids and proteins. The materials of the invention are separation media that possess pH-dependent groups with pKa value in the range of about 5 to about 7. Separation of the nucleic acids or proteins from a separation medium is effected at a neutral or higher pH.

Abstract: Fractional distillation performed to recover butane used as a desorbent component for adsorptive separation is integrated with the other fractionation of the raffinate stream of a C5-C6 paraffin adsorptive separation zone. A single fractionation column is employed to recover the desorbent butane, a highly branched paraffin product stream and a mono-branched paraffin rich recycle stream, thus reducing the cost of the process.

Abstract: Process for pretreating a natural gas under pressure containing hydrocarbons, acid compounds such as hydrogen sulfide and carbon dioxide, and water. The natural gas is cooled to condense part of the water. The partially dehydrated natural gas is then contacted with a liquid stream consisting of a majority of hydrogen in two successive contact zones so as to obtain a natural gas containing substantially no water any more. Finally, this dehydrated natural gas is cooled to condense and separate the acid compounds, this cooling stage being carried out by means of a heat exchanger, an expander or a venturi neck.

Abstract: A process for treating waste water streams containing at least hydrocarbons and salts to yield a clean water product, a concentrated brine product and a hydrocarbon-rich product, which process includes the steps of: (a) feeding the waste water feed into a first distillation column at a stage in the range of from 0.05 to 0.15 from the top, wherein n represents the total number of theoretical stages of the first distillation column and has a value in the range of from 20 to 40; (b) drawing off a vapor stream at a stage in the range of from 0.55 to 0.

Abstract: Disclosed are processes for the recovery and purification of higher diamondoids from a hydrocarbonaceous feedstock. Specifically disclosed is a multi-step recovery process for obtaining diamondoid compositions enhanced in tetramantane components and other higher diamondoid components. Also disclosed are compositions comprising at least about 10 weight percent of non-ionized tetramantane components and other higher diamondoid components and at least about 0.5 weight percent of non-ionized pentamantane components and other higher diamondoid components based on the total weight of diamondoid components present.

Abstract: Mass transfer process, in which, in at least two contact stages, and at least two liquid or gaseous phases are brought into contact with one another, at least one component being transferred between the phases and the phases moving countercurrently. The flow through at least one of the contact stages is batchwise for one phase and continuous for another phase. The phases flow through contact stages which are formed by trays in a column, which trays are opened periodically so that the phase which flows through the column in a batchwise manner flows to the next tray.

Abstract: The invention relates to a process for the recovery as a feedstock of an alpha-olefin from a mixture containing mainly hydrocarbon compounds, such as is obtained by Fischer-Tropsch-synthesis after an at least crude separation of components boiling higher and/or lower than the alpha-olefin, wherein tertiary olefins of the mixture, after superstoichiometrical addition of a low alcohol, are subjected to catalytic etherification and a stream derived by etherification is fed jointly with the alpha-olefin and the ethers produced and other high boiling reaction products to a distillative separation of components boiling higher than the olefin.

Abstract: Cyclopentane and/or cyclopentene and, if desired, isopentane can be obtained by distillative separation from a pre-benzene fraction or a C5 fraction which has in each case being partially hydrogenated to remove acetylene compounds and diolefins, wherein a) in a first fractional distillation, low boilers are removed as first top product and, either b1) the first bottom product is fed to a second fractional distillation and there cyclopentene is taken off as second top product and cyclopentane and higher-boiling hydrocarbons are taken off as second bottom product and this second bottom product is separated into cyclopentene and higher boilers in a third fractional distillation, or b2) the first bottom product is subjected to a catalytic hydrogenation and subsequently, in a fractional distillation, separated into cyclopentane as top product and higher boilers as bottom product, or b3) the first bottom product is subjected to a fractional distillation to separate off the relatively high boilers as bottom prod

Abstract: Disclosed are compositions comprising one or more octamantanes. Specifically disclosed are compositions comprising 25 to 100 weight percent of one or more octamantanes. Also disclosed are novel processes for the separation and isolation of octamantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more octamantane components.

Abstract: Disclosed are compositions comprising one or more hexamantanes. Specifically disclosed are compositions comprising 25 to 100 weight percent of one or more hexamantanes. Also disclosed are novel processes for the separation and isolation of hexamantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more hexamantane components.

Abstract: Disclosed are compositions comprising one or more heptamantanes. Specifically disclosed are compositions comprising 25 to 100 weight percent of one or more heptamantanes. Also disclosed are novel processes for the separation and isolation of heptamantane components into recoverable fractions from a feedstock containing at least a higher diamondoid component which contains one or more heptamantane components.

Abstract: An improved process for the production and purification of unsaturated monomers employing nitroxyl-containing inhibitors wherein process streams containing the inhibitor are recycled is disclosed, wherein the improvement comprises recycling said streams at a reboiler temperature no higher than about 110° C.