Abstract: An absorption heat pump achieves improved efficiency by lowering the low cycle temperature of the circulation fluid. This is accomplished by adding a crystallization-inhibiting compound to the circulation fluid which substantially depresses the temperature at which the absorbent salt in the fluid begins to crystallize.

Abstract: An apparatus having a refrigeration cycle using a flammable refrigerant, comprises an oil-free compressor, a condenser, an expansion device and an evaporator, wherein an amount of lubricant in the oil-free compressor is equal to or smaller than 3 cc. With this structure, the charging amount of the flammable refrigerant into the refrigeration cycle can be reduced, and the safety of the apparatus having a refrigeration cycle can be enhanced.

Abstract: There is disclosed an novel refrigeration apparatus and a method of refrigeration. The novel refrigeration apparatus comprises a desorber/evaporator, a scroll compressor operatively connected to said desorber/evaporator, a resorber/condenser operatively connected to said compressor, an expansion device operatively connected to said resorber/condenser and to said desorber/evaporator and a circulating refrigerant comprising carbon dioxide and a liquid co-fluid in which the carbon dioxide is differentially soluble. The refrigeration method comprises compressing carbon dioxide gas and a liquid co-fluid in a scroll compressor to an increased pressure, such that carbon dioxide at least partially dissolves in the liquid co-fluid, and reducing the pressure on the liquid co-fluid containing the dissolved carbon dioxide so that dissolved carbon dioxide comes out of solution with the liquid co-fluid, and recirculating the gaseous carbon dioxide and liquid co-fluid to the scroll compressor.

Abstract: An air conditioner comprises a refrigeration cycle consisting of a compressor, a heat exchanger, a throttling device, a dryer provided with an adsorbent, a connection piping and a refrigerant. The refrigerant contains a hydrofluorocarbon refrigerant, the adsorbent contains a plurality of bulk particles, and the dryer includes a container, wherein the adsorbent is located within the container, having a pressing means for holding the adsorbent by pressing it. The load of the pressing means is within a range of about 0.5 kg/cm.sup.2 to about 3 kg/cm.sup.2. The container is of a cylindrical shape having a sectional area of "A", the refrigerant is at a circulation rate of "B", and the value of B/A is within a range of about 100 g/min cm.sup.2 to about 400 g/min cm.sup.2.

Abstract: An object of the present invention is to provide a method for forming an initial anticorrosive film in an absorption chiller-heater, by selecting optimal conditions of absorbent solution, steel material surface and film-forming operation for forming a good initial anticorrosive film. In the process for forming an initial anticorrosion film in an absorption chiller-heater having steel parts and containing an absorbent solution comprising lithium bromide as its main component and containing a lithium molybdate corrosion inhibitor according to the present invention, the main characteristics are that at least part of the steel parts of the absorption chiller-heater contacting with an absorbent solution at a temperature of higher than 100.degree. C. include a bare metal surface having an arithmetic mean surface roughness of not more than 1.0 .mu.

Abstract: An absorption refrigerator is minimized in the size and the weight. A sensible heat exchanger 14 and a cooling fan 19 for cooling the sensible heat exchanger 14 are mounted front and rear opposite to each other to form a cooling unit. At one side of the fan 19, a regenerator 3 and a rectifier 6 are aligned vertically one over the other. At the other side of the fan 19, an evaporator 1 and an absorber 2 of a rectangular configuration are provided side by side. A condenser 9 is laid above the cooling unit. The cooling unit, the evaporator 1, the absorber 2, the condenser 9, the regenerator 3, the rectifier 6, and a set of pumps P1 to P4 all are installed in a main housing 20 of substantially a rectangular parallelopiped shape having a depth reduced axially of the cooling fan 19.

Abstract: Anticorrosion solutions useful for refrigeration processes are disclosed. Heteropoly complex anions of transitional metal elements can be added to alkali metal halide absorption refrigeration solutions to minimize corrosion of the refrigeration system.

Abstract: Anticorrosion solutions and processes useful for refrigeration processes are disclosed. Heteropoly complex anions of transitional metal elements can be added to an absorption refrigeration solutions which includes at least one alkali metal halide or similar compounds, or mixtures thereof, in combination with transition metal compounds or compounds of the metallic elements of Groups IIIa to VIa of the Periodic Table of Elements to minimize corrosion of the refrigeration system.

Abstract: A performance enhancing additive is introduced into a vapor compression system used in cooling and the like. The additive is selected from a class of compounds, e.g. tetraglyme, and added in a predetermined concentration measured relative to the mass of the system's lubricant. The additive can be soluble or non-soluble in the lubricant used in the system's single-phase compressor. It can be added anywhere in the system to provide lower thermodynamic load on the system compressor.

Abstract: After a running stop command is released, a pump P2 for transferring a solution from the absorber 2 to a regenerator 3 is kept running. The transfer of the solution permits separation of the solution from a refrigerant during non-operation of the refrigerator. The solution saved in the regenerator 3 remains at as a high concentration of the absorbent as that before the end of the operation while the refrigerant is saved in an evaporator 1. This enables the refrigerator to restart its normal operation corresponding to an operation start command.

Abstract: A modified Generator-Absorber-Heat Exchanger (GAX) absorption cycle system and method of operation are provided wherein, in addition to a primary refrigerant circulated through a first refrigerant circuit, a secondary refrigerant is circulated through a second refrigerant circuit to improve the coefficient of performance (COP) of the cycle.

Abstract: An auxiliary heating and air conditioning system has an output for selectively delivering warm air and cool air to the passenger area of a motor vehicle. The auxiliary system includes a thermo-electric cooler, which is a solid state device having a hot side and a cold side. Heat exchangers are disposed in connection with the hot side and cold side of the thermo-electric cooler to facilitate the transfer of thermal energy away from each side of the thermo-electric cooler. Two fans are disposed in fluid communication with the first and second heat exchangers to transfer air across the exchangers and to the output for selectively heating and cooling the passenger area of the motor vehicle. Interposed between the first and second heat exchangers and the output, are first and second arrays of energy storage panels. Preferably, these panels contain phase change material which is charged during the operation of the motor vehicle to change phase and therefore store thermal energy.

Abstract: A thermochemical system and process for producing heat and/or cold by solid-gas chemical reaction is disclosed. The system and process utilizes a reactant formed of a compressed support and at least two salts which are distributed throughout the compressed support, the salts being active towards a gas. The salts of the reactant are selected for the system and process so that in the system and process one salt will react with the gas in the reactor while the other salts in the reactant remain substantially unreacted to produce heat or cold at a first temperature or power level and, thereafter, one of the other salts of the reactant reacts with the gas to produce heat or cold at a second temperature or power level which is different from the first temperature or power level.

Abstract: An absorbent for use in absorption refrigeration systems, air conditioning systems, heat pumps or dehumidifiers comprising a solution of potassium formate. The absorbent is relatively non-toxic and relatively non-corrosive towards metals. The absorbent is generally water-based but may also comprise ammonia or methanol. Additives such as corrosion inhibitors or other absorbent salts may be included.

Abstract: The invention relates especially to a refrigerating device comprising a pressure-resistant container (1) furnished with an adsorbent material (2), which device furthermore comprises an adjustably set valve (7) whose passage communicates, on the one hand, with the inside of the container and, on the other hand, with the outside, and means (5, 6) for bringing said container temporarily into communication with a pressurized source (10, 11) of gas which can be adsorbed by said adsorbent material.Use in refrigerated clothing or portable refrigerators.

Abstract: The rate of water vapor sorption of an absorption cycle cooling and/or heating system using an aqueous alkali metal halide or hydroxide solution as the working fluid is increased by adding to the fluid an effective additive amount of at least 2 parts per million of a primary, secondary or tertiary aliphatic, cycloaliphatic, heterocyclic or aromatic amine to the fluid capable of increasing the rate of water vapor absorption.

Abstract: A performance enhancing additive is introduced into a vapor compression system used in cooling and the like. The additive is selected from a class of compounds, e.g. tetraglyme, and added in a predetermined concentration measured relative to the mass of the system's lubricant. The additive can be soluble or non-soluble in the lubricant used in the system's single-phase compressor. It can be added anywhere in the system to provide lower thermodynamic load on the system compressor.

Abstract: A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.

Abstract: A refrigerant/absorbent composition is disclosed which comprises an aqueous solution of at least one absorbent salt, present in an amount sufficient to provide utility of said composition as an absorbent, and at least one germanium compound, present in an amount sufficient to inhibit corrosion. Also, a method of inhibiting corrosion by adding a germanium compound to a refrigerant/absorbent composition is disclosed. Further, an absorption heat transferring machine having a working fluid which comprises an absorber salt, a germanium compound and water is disclosed.

Abstract: In order to depress a crystallization temperature of an absorbent composition for an absorption refrigeration system without depressing vapor absorption ability, cesium chloride is added to an alkaline solution containing lithium bromide as a main component, in an amount of 0.01 to 15% by weight, based on the weight of an aqueous 64% lithium bromide solution.

Abstract: A fuzzy logic controller for a cryogenic system in which, for example, a cold tip cooling an infrared detector uses a Stirling cycle cooler-compressor with the helium coolant maintained at typically 78.degree. K. This temperature is maintained by a fuzzy logic controller which has as its inputs the temperature differential between the desired temperature and actual cold tip temperature, rate of change of such temperature, and especially for startup the difference between a maximum voltage which can be applied to the Stirling type cooler-compressor and the actual control voltage which is applied. Appropriate membership functions for all of the inputs are provided of the triangular type. And appropriate rules related to the operation of a Stirling cycle cooler provide for fuzzy outputs which with an output membership function are defuzzified to provide a control output signal which controls the final cooling power of the cooler-compressor.

Abstract: Absorption heat pump system and process for heating, refrigeration, air conditioning and heat transforming, employing an aqueous buffer solution of a lithium salt therein; an aqueous buffer solution of a lithium salt perfectly neutral in pH useful as a coolant, achieving a very high C.O.P. at a temperature lift much higher than usual, without danger of crystallization, even at high generator temperature (up to 330.degree. C.) and evaporator temperature as low as minus 10.degree. C., while in most cases the absorber and condenser can be economically cooled by (ambient) air.

Abstract: An apparatus capable of providing rapid cooling and/or freezing comprises a cabinet or container having a cooling chamber, one or more reactors each containing a complex compound formed by adsorbing a polar gas on a metal salt, in which the polar gas is alternately adsorbed and desorbed on the complex compound, and in which the complex compound is formed by restricting the volumetric expansion and controlling the density during adsorption of the polar gas on the metal salt, whereby the complex compound is capable of adsorbing said polar gas at a rate of greater than 15 moles per mole hour of the complex compound in about 20 minutes or less, a condenser for condensing the polar gas, an evaporator thermally exposed to the cooling chamber for providing cooling therein, and conduits and one or more valves for directing said polar gas from the one or more reactors to the condenser, from the condenser to the evaporator and from the evaporator to the one or more reactors.

Abstract: An apparatus capable of providing rapid cooling and/or freezing comprises a cabinet or container having a cooling chamber, one or more reactors each containing a complex compound formed by adsorbing a polar gas on a metal salt, in which the polar gas is alternately adsorbed and desorbed on the complex compound, and in which the complex compound is formed by restricting the volumetric expansion and controlling the density during adsorption of the polar gas on the metal salt, whereby the complex compound is capable of adsorbing said polar gas at a rate of greater than 15 moles per mole hour of the complex compound in about 20 minutes or less, a condenser for condensing the polar gas, an evaporator thermally exposed to the cooling chamber for providing cooling therein, and conduits and one or more valves for directing said polar gas from the one or more reactors to the condenser, from the condenser to the evaporator and from the evaporator to the one or more reactors.

Abstract: A refrigerant/absorbent composition is disclosed which comprises an aqueous solution of at least one lithium halide, at least one zinc halide, and a corrosion inhibiting amount of thiocyanate ion. Also, a method of inhibiting corrosion of the metallic parts of an absorption heat transfer machine by adding a thiocyanate compound to a refrigerant/absorbent composition is disclosed. Further disclosed is a triple-effect absorption heat transfer machine having a working fluid in contact with metallic parts, said working fluid comprising a corrosion inhibiting amount of at least one thiocyanate salt.

Abstract: A refrigerator and/or freezer incorporates one or more reactors containing a complex compound of a metal salt and a polar gas adsorbed thereon in which the volumetric expansion of the complex compound is restricted during adsorption, and which reactors comprise one or reaction chambers having a maximum means mass diffusion path length of less than about 15 mm, and/or a maximum thermal diffusion path length of less than 1.5 mm.

Abstract: The rate of water vapor sorption of an absorption cycle cooling and/or heating system using an aqueous alkali metal halide or hydroxide solution as the working fluid is increased by adding to the fluid an effective additive amount of at least 2 parts per million of a primary, secondary or tertiary aliphatic, cycloaliphatic, heterocyclic or aromatic amine to the fluid capable of increasing the rate of water vapor absorption.

Abstract: A corrosion inhibiting working fluid for absorption refrigeration systems and a method of manufacturing such a fluid. The fluid is an aqueous solution of a halogen salt of lithium or ammonia to which are added water soluble compounds containing molybdates, borates and, in a preferred embodiment, silicates. Preferred concentrations of the resultant molybdenum, boron and silicon ions are disclosed. A water soluble compound containing a hydroxide is also added to produce an alkaline normality. In a preferred method of manufacture, the additive compounds are added to the working fluid as aqueous solutions.

Abstract: An improved absorption cycle apparatus and system using aqueous solutions of metal salts selected from the group consisting of alkali metal hydroxides, nitrites, and alkaline earth and transition metal hydroxides, halides, thiocyanates, and mixtures thereof between about 14% and about 30%, by weight, of said metal salt, of an organic compound selected from the group consisting of alcohols, glycerol, glycols, polyglycols, alkaline glycol ethers, aliphatic amines and alkanol amines.

Abstract: The invention relates especially to a process for the production of cold, comprising at least one stage of adsorption of carbon dioxide by an adsorbent solid substance and at least one stage of desorption of the carbon dioxide adsorbed in the said adsorbent substance, in which the said adsorbent substance comprises activated carbon fibers or an active charcoal and has a specific surface of at least 700 m.sup.2 /g and an external specific surface of at least 0.005 m.sup.2 /g.

Abstract: The disclosure is directed to an apparatus and method to increase the coefficient of performance (COP) of hydride heat pump systems to compete with the performance of conventional vapor compression and absorption refrigeration systems. The disclosure is particularly directed to hydrides with van't Hoff curves that cross, whereby the regeneration of the refrigerant hydride occurs at a temperature above the crossing, thereby allowing for a major fraction of the energy required for the regeneration to be supplied by the heat of absorption of the refrigerant. Additionally, the COP can be increased by selection of hydrides, and the kinetics of the system can be improved by the use of heat pipes and phase change materials.

Abstract: In a sorption reaction system comprising one or more first reactors in which a refrigerant is alternately adsorbed and desorbed, and one or more second reactors in which a refrigerant is alternately desorbed and adsorbed, respectively, and having a cooling loop for directing heat transfer fluid to and from said reactors, a method of cooling an adsorbing reactor comprises directing liquid phase heat transfer fluid having a phase change from liquid to gas at a temperature at or below the temperature of adsorption to an adsorbing reactor in heat exchange exposure to the adsorbent utilizing vaporized heat transfer fluid for driving the liquid heat transfer fluid in the cooling loop. The refrigerant may be used as the heat transfer fluid. The invention includes apparatus for carrying out the method.

Abstract: The rate of water vapor sorption of an absorption cycle cooling and/or heating system using an aqueous alkali metal hydroxide solution as the working fluid is increased by adding at least 2 parts per million of a primary, secondary or tertiary aliphatic, cycloaliphatic or aromatic amine to the fluid.

Abstract: Apparatus for cooling components or subassemblies of equipment at one or more locations comprises a first reactor located at a remote location from said equipment, and a second reactor located in heat exchange communication with a component or subassembly of said equipment, each of said first or second reactors containing a different complex compound of a polar refrigerant and a metal salt, wherein the equilibrium temperature of the complex compound in said first reactor differs from the equilibrium temperature of the complex compound in said second reactor by between about 10.degree. C. and about 150.degree. C. at the same operating pressure, heating means for heating a complex compound in said first reactor, and conduit means for directing polar refrigerant between said reactors.

Abstract: The basic apparatus of the invention is a triple effect absorption cycle apparatus, comprising first, second and third generators each containing an aqueous absorption fluid and operating at successively higher temperatures; first, second and third condensers operating at successively higher temperatures, and operatively communicating with the generators; first heat exchange means cooperating between the third and second generators, and between the second condenser and first generator, for directing energy therebetween; one, two or three absorbers and one, two or three fluid loops for directing aqueous absorption fluid between absorbers and second heat exchange means for exchanging energy between aqueous absorption fluid flows in said loops; and one, two or three evaporators operatively communicating with the absorbers.

Abstract: An absorption system for heating, refrigerating and conditioning air for use in vehicles is disclosed. The refrigerant-absorbent mixture, presenting a coefficient of performance of around 0.9, is heated by the waste heat of exhaust gases from the vehicle which has a fuel-driven internal combustion engine. The absorption system is based on the principle of evaporation at relatively low pressure and temperature followed by absorption of refrigerant vapor by the absorbent and then evaporation of the refrigerant from the absorbent when heated by an external heat source.

Abstract: Reaction rates in chemisorption reactions involving solid reactants and gaseous ligands are improved by maintaining optimized solid density throughout the reaction. Methods and apparatus which restrict volumetric solid expansion, compression of the solid reactant, and mixture with inert solid porous or particulate materials are disclosed.

Abstract: A refrigerator includes a cylinder containing a bed of adsorbent material and a gas, e.g. carbon dioxide. A piston compresses the gas which is adsorbed by the adsorbent material and the heat of adsorption is dissipated by fins to atmosphere. The piston, when retracted, decompresses the gas which desorbs from the adsorbent material. Repeated compression and decompression of the gas causes a cold zone to be created within the material which is thermally linked to a location to be refrigerated.

Abstract: An improved apparatus for staging solid-vapor complex compounds comprises heat exchange means for transferring heat from super-heated refrigerant vapor from a desorbing reactor to cooled refrigerant vapor directed to an adsorbing reactor. In another embodiment a liquid subcooler is used to cool liquid refrigerant passing from a condenser to an evaporator with cold refrigerant gas directed to an adsorbing reactor from the evaporator.

Abstract: The basic apparatus of the invention is a triple effect absorption cycle apparatus, comprising first, second and third generators each containing an aqueous absorption fluid and operating at successively higher temperatures; first, second and third condensers operating at successively higher temperatures, and operatively communicating with the generators; first heat exchange means cooperating between the third condenser and second generator, and between the second condenser and first generator, for directing energy therebetween; one, two or three absorbers and one, two or three fluid loops for directing aqueous absorption fluid between absorbers and second heat exchange means for exchanging energy between aqueous absorption fluid flows in said loops; and one, two or three evaporators operatively communicating with the absorbers.

Abstract: An improved apparatus for staging solid-vapor complex compounds comprises heat exchange means for transferring heat from super-heated refrigerant vapor from a desorbing reactor to cooled refrigerant vapor directed to an adsorbing reactor. In another embodiment a liquid subcooler is used to cool liquid refrigerant passing from a condenser to an evaporator with cold refrigerant gas directed to an adsorbing reactor from the evaporator.

Abstract: An apparatus comprises a plurality of two or more reaction chambers, each having a different compound therein comprising a solid reactant adsorbent and a gaseous reactant adsorbed thereon, each of said compounds having a different gaseous refrigerant vapor pressure, substantially independent of the concentration of the gaseous reactant, and having an ascending order of gaseous reactant vapor pressure wherein the adsorption temperature of a lower vapor pressure compound at adsorption temperature of a lower vapor pressure compound at adsorption pressure is at least 8.degree..degree.C.

Abstract: The regeneration temperature of a chemical heat pump of closed system utilizing reversible reaction between calcium oxide and water is lowered by using an aqueous solution of a salt in an absorber-condensor provided separately from a reactor filled with calcium hydroxide.

Abstract: An absorbent-refrigerant solution containing a promoter which enhances the vapor absorbent properties of the absorbent-refrigerant. The promoter comprises titanium trifluoride and titanium tetrafluoride.

Abstract: An improved absorption cycle apparatus and system using aqueous solutions of metal salts selected from the group consisting of alkali metal hydroxides, nitrites, and alkaline earth and transition metal hydroxides, halides, thiocyanates, and mixtures thereof between about 14% and about 30%, by weight, of said metal salt, of an organic compound selected from the group consisting of alcohols, glycerol, glycols, polyglycols, alkaline glycol ethers, aliphatic amines and alkanol amines.

Abstract: The invention disclosed herein relates to an apparatus for being detachably connected to a chemical or refrigeration system for selectively receiving and dispensing a gaseous refrigerant or chemical from and to that system, respectively, including a vessel having a chamber capable of maintaining a pressurized gas therein, gas inlet means for directing the gas to and from the chamber, and connection means for connecting the gas inlet to a refrigeration or chemical system; a plurality of heat exchange conduits exposed in the chamber for directing heat exchange fluid therethrough and fluid inlet and outlet means communicating exteriorly of the vessel for directing the fluid to and from the conduits, respectively; and a solid adsorbent capable of alternately adsorbing and desorbing the gaseous refrigerant or chemical and positioned in thermal communication with each of the heat exchange conduits.

Abstract: An improved heat exchange system incorporates the cooling created by using a metal salt/ammonia ligand complex compound which is alternately heated and cooled to alternately desorb and adsorb, respectively, the ammonia creating useful cooling or refrigeration in the temperature range of between -65.degree. C. to 15.degree. C.

Abstract: A system for storing chemical energy comprises first and second vessels, the first containing a liquid solution of an alkali or alkaline earth metal hydroxide, halide, or thiocyanate, or ammonium halide or thiocynate at an initial concentration of between about 30% to abotu 80%, by weight, the second vessel containing liquid, a space about the liquid in each vessel and a conduit communicating between the spaces having a valve for selectively allowing liquid vapor to pass between the spaces, means for heating the solution to a temperature above about 80.degree. F., means for cooling the liquid to a temperature below about 55.degree. F., and heat exchange means for transferring heat from the heated solution and for transferring heat to the cooled liquid. Water is the preferred liquid although ammonia, lower alcohols, and polyols such as glycerol, glycols, polyglycols, glycol ethers, lower aliphatic amines and alkanol amines, and mixtures thereof, may be used.

Abstract: The basic apparatus of the invention is a triple effect absorption cycle apparatus, comprising first, second and third generators each containing an aqueous absorption fluid and operating at successively higher temperatures; first, second and third condensers operating at successively higher temperatures, and operatively communicating with the generators; first heat exchange means cooperating between the third and second generators, and between the second condenser and first generator, for directing energy therebetween; one, two or three absorbers and one, two or three fluid loops for directing aqueous absorption fluid between absorbers and second heat exchange means for exchanging energy between aqueous absorption fluid flows in said loops; and one, two or three evaporators operatively communicating with the absorbers.

Abstract: The basic apparatus of the invention is a triple effect absorption cycle apparatus, comprising first, second and third generators each containing an aqueous absorption fluid and operating at successively higher temperatures; first, second and third condensers operating at successively higher temperatures, and operatively communicating with the generators; first heat exchange means cooperating between the third condenser and second generator, and between the second condenser and first generator, for directing energy therebetween; one, two or three absorbers and one, two or three fluid loops for directing aqueous absorption fluid between absorbers and second heat exchange means for exchanging energy between aqueous absorption fluid flows in said loops; and one, two or three evaporators operatively communicating with the absorbers.