Utilizing Particular Refrigerant And/or Sorbent Materials Patents (Class 62/112)
  • Patent number: 4428854
    Abstract: An absorption refrigerant composition for use in absorption refrigeration systems comprising 1,1,1,2-tetrafluoroethane and an organic solvent capable of dissolving the ethane.
    Type: Grant
    Filed: November 15, 1982
    Date of Patent: January 31, 1984
    Assignee: Daikin Kogyo Co., Ltd.
    Inventors: Naonori Enjo, Hideki Aomi
  • Patent number: 4413480
    Abstract: A high efficiency space conditioning process and apparatus for heating and cooling utilizing an absorption cycle in the nature of absorption heat pumps for heating and cooling. The invention provides a process and apparatus having a higher Coefficient of Performance than conventional absorption heat pumps by utilization of a substantially saturated salt solution cycle between the absorber and generator wherein salt is crystallized to the solid phase in the generator and the heat of crystallization is utilized for refrigerant vaporization occurring simultaneously.
    Type: Grant
    Filed: April 5, 1982
    Date of Patent: November 8, 1983
    Assignee: Institute of Gas Technology
    Inventors: Robert A. Macriss, Thomas S. Zawacki
  • Patent number: 4410028
    Abstract: Process for storing heat and for upgrading its temperature, in which a working substance is expelled from an absorbing substance by means of heat of a predetermined intermediate temperature range, the vapor of the working substanced generated during the expulsion step being condensed at a comparatively low temperature and the condensed working substance being evaporated in the intermediate temperature range and being absorbed in the absorbing substance under an increased pressure and at a relatively high temperature while generating heat of absorption, in which a zeolite is used as the absorbing substances and water is used as the working substance.
    Type: Grant
    Filed: June 10, 1981
    Date of Patent: October 18, 1983
    Assignee: Georg Alefeld
    Inventors: Georg Alefeld, Peter Maier-Laxhuber, Markus Rothmeyer
  • Patent number: 4386501
    Abstract: A thermochemical heat pump/energy storage system using a liquid ammoniated salt, that is, a salt complexed or reacted with ammonia, is described. The system, which can be used for heating or cooling an enclosure either in a batch operation or continuously, provides energy storage for both heating and cooling functions. The energy is stored predominantly as chemical energy which has substantially no limit on the period during which it may be stored. A pumpable liquid ammoniated absorbent formed by chemically combining about equimolar amounts of ammonia with ammonium chloride ("low ammoniate"), can be further ammoniated to form a "high ammoniate" containing about 3 moles of ammonia. The high ammoniate is desorbed at a heat source temperature below 100.degree. C. available from a geothermal well or the like, and preferably at a heat source temperature below 80.degree. C.
    Type: Grant
    Filed: July 29, 1981
    Date of Patent: June 7, 1983
    Assignee: Martin Marietta Corporation
    Inventor: Frederick A. Jaeger
  • Patent number: 4373347
    Abstract: A hybrid double absorption air cooling system employing a liquid desiccant solution and capable of operating at low heat source temperature between 55.degree. C. and 80.degree. C. is provided. In one embodiment the system which utilizes low-grade thermal energy, includes an open absorber employing a liquid desiccant solution for absorbing moisture from air passing therethrough, a cooling coil adapted for cooling air passing through the open absorber, and a vapor-absorption refrigeration system which employs the liquid desiccant solution as an evaporable refrigerant and is adapted for cooling and circulating a working fluid, such as water, through the cooling coil and for circulating the desiccant solution through the open absorber. In an alternate embodiment, an open evaporator is adapted for providing cooling water to the open absorber.
    Type: Grant
    Filed: April 2, 1981
    Date of Patent: February 15, 1983
    Assignee: Board of Regents, University of Texas System
    Inventors: John R. Howell, C. S. Patrick Peng
  • Patent number: 4321799
    Abstract: Heat is transferred from a first body to a second body and thereby provides power by carrying a thermodynamic fluid comprising a dispersion of a particulate solid in a gas around a thermodynamic cycle or cycles involving the expansion and contraction of the said thermodynamic fluid. Reverse cycles are used to provide refrigeration.
    Type: Grant
    Filed: March 28, 1980
    Date of Patent: March 30, 1982
    Assignee: Georgia Tech Research Institute
    Inventors: Robert A. Pierotti, Thomas R. Rybolt
  • Patent number: 4315411
    Abstract: The present invention relates to a chiller of the type using water as refrigerant and aqueous lithium bromide or the like as absorbant, wherein 2-ethyl n-hexanol or a similar compound is used as additive to said solution to improve heat transfer in the absorber, comprising a separator for separating a large part of the additive from said solution, said separator being located between the exit of the lithium bromide solution from the absorber and between the heat exchanger in the conduit leading to the generator. According to one embodiment, the separator operates on gravity separation. According to one embodiment, the separator comprises a vessel large enough for substantially slowing down the velocity of flow of the solution, provided with inlet means at its lower part, outlet means at its upper part for a small part of the solution substantially enriched respective said additive, and an outlet at its lower part for the bulk of the solution, depleted of part of the additive.
    Type: Grant
    Filed: May 15, 1980
    Date of Patent: February 16, 1982
    Assignee: Tadiran Israel Electronics Industries Ltd.
    Inventors: Isaih Vardi, Yigal Kimchi, Jonathan Ben-Dror
  • Patent number: 4311024
    Abstract: A hermetically circulating, absorption type refrigerator based on a closed circulation system comprised of a successive communication of a regenerator, a condenser, an evaporator, an absorber and a heat exchanger, parts or the whole of said constituent members in contact with an absorbing solution being comprised of a copper material selected from copper and copper alloy, and refrigeration being produced by repetitions of concentration, refrigerant dilution and heat exchange of an aqueous lithium bromide solution sealed in the circulation system is characterized in that the absorbing solution is an aqueous lithium bromide solution containing (a) a nitrate and (b) at least one triazole compound selected from benzotriazole and tolyltriazole, and has a particularly distinguished corrosion resistance.
    Type: Grant
    Filed: December 17, 1979
    Date of Patent: January 19, 1982
    Assignee: Hitachi, Ltd.
    Inventors: Masahiko Itoh, Heihatiro Midorikawa, Akira Minato
  • Patent number: 4285209
    Abstract: The absorption heat pump installation operates with water as a working medium. The installation is equipped with an energy accumulator which acts as a direct evaportor and is operated through the choice of a suitable hydroscopic absorption medium at the triple point of water (6.1 mbar, 0.degree. C.) as an ice accumulator. Water of a room heating system and/or a utility water heater serves as a coolant in the absorber and condenser of the installation. Outside air is preferably used as a low temperature heat source in which case the useful time for heat pump operation is extended without the danger of freezing of an outside-air heat exchanger at temperatures of the ambient air below 0.degree. C.
    Type: Grant
    Filed: September 10, 1979
    Date of Patent: August 25, 1981
    Assignee: Sulzer Brothers Limited
    Inventors: Johannes Luthi, George Ziegler
  • Patent number: 4283918
    Abstract: An absorption refrigerator in which the refrigerant is miscible in the absorbent at the relatively low absorbing temperature and is at least partly immiscible at elevated temperatures, allowing separation of refrigerant and absorbant in the liquid phase.
    Type: Grant
    Filed: July 20, 1979
    Date of Patent: August 18, 1981
    Assignee: Intertechnology/Solar Corporation
    Inventor: Gurmukh D. Mehta
  • Patent number: 4272268
    Abstract: A chemical heat pump system is disclosed for use in heating and cooling structures such as residences or commercial buildings. The system is particularly adapted to utilizing solar energy, but also increases the efficiency of other forms of thermal energy when solar energy is not available. When solar energy is not available for relatively short periods of time, the heat storage capacity of the chemical heat pump is utilized to heat the structure, as during nighttime hours. The design also permits home heating from solar energy when the sun is shining. The entire system may be conveniently rooftop located. In order to facilitate installation on existing structures, the absorber and vaporizer portions of the system may each be designed as flat, thin wall, thin pan vessels which materially increase the surface area available for heat transfer.
    Type: Grant
    Filed: October 17, 1977
    Date of Patent: June 9, 1981
    Inventor: Leonard Greiner
  • Patent number: 4251382
    Abstract: 1-chloro-2,2,2-trifluoroethane (refrigerant 133a) is dissolved in a furan-derivative absorbent, and especially an ether of tetrahydrofurfuryl alcohol, to form an absorption refrigerant pair composition. It exhibits a good combination of performance, capacity, stability, low toxicity and convenient operating pressures. These compositions are useful in methods of absorption refrigeration, cooling and heating and especially in an absorption heat pump.
    Type: Grant
    Filed: July 26, 1979
    Date of Patent: February 17, 1981
    Assignee: Allied Chemical Corporation
    Inventor: Chien C. Li
  • Patent number: 4172043
    Abstract: The invention comprises absorption pair compositions consisting essentially of selected one and two carbon fluorocarbon solutes dissolved in selected furan ring absorbents. These absorption pair compositions are useful in methods of absorption refrigeration, cooling and heating and particularly in an absorption heat pump.
    Type: Grant
    Filed: July 22, 1977
    Date of Patent: October 23, 1979
    Assignee: Allied Chemical Corporation
    Inventor: Chien C. Li
  • Patent number: 4152901
    Abstract: A method and apparatus for transferring energy in an absorption system according to the heat pump principle to improve the cycle efficiency thereof, in which the selected working medium is vaporized in an evaporator by heat exchange with heat source of ambient pressure and passed into a sorption station where it is brought into contact with an absorbent solution with consequent release of heat of absorption and heat of condensation. The mixture of absorbent solution and absorbed working medium is passed from the sorption station into a pressurized separating station, where the absorbent is separated from the working medium by diffusing the mixture under pressure through a semi-permeable membrane defining a zone of relatively high pressure and a zone of relatively low pressure higher than the ambient pressure, the concentrated absorbent solution being collected in the high pressure zone and the solution of working medium being received in the low pressure zone by virtue of the resultant reverse osmotic flow.
    Type: Grant
    Filed: December 21, 1976
    Date of Patent: May 8, 1979
    Assignee: Aktiebolaget Carl Munters
    Inventor: Carl G. Munters
  • Patent number: 4151721
    Abstract: Primarily this system includes an air inducting, circulating, and exhausting section and a pair of solar responsive fluid treating sections, one of the latter being provided to cool the air and the other to heat the air. Both solar responsive fluid treating sections, however, function in concert for cooling and heating.The air inducting, circulating and exhausting section has duct portions through which air is drawn from the atmosphere by a fan and either used as admitted or heated or cooled, then directed into the enclosure being served, all or part of the air being recirculated, the part not recirculated being discharged to the atmosphere. The duct portions contain air heating and air and other solution cooling devices as well as fans and guide or flow controlling vanes. One solar responsive fluid treating section has an absorptive chemical solution reservoir, a solution cooler, a solar heated solution concentrator, heat and vapor exchangers, pumps, valves, and connecting lines.
    Type: Grant
    Filed: September 9, 1977
    Date of Patent: May 1, 1979
    Inventor: Emerson L. Kumm
  • Patent number: 4138855
    Abstract: Heat is transferred from a cold heat source to a hot heat sink by an absorption type heat pump wherein the working fluid and the absorbent liquid are capable of forming a solution having a lower critical solution temperature t.sub.c. The working fluid at a low pressure extracts heat from the cold source and is reabsorbed in the absorbent liquid to form a solution which, at a higher pressure, is heated above t.sub.c to separate the working fluid from the solution. The heat requirement for this separation is less than that for distillation in prior heat pumps.
    Type: Grant
    Filed: June 20, 1977
    Date of Patent: February 13, 1979
    Assignee: Exxon Research & Engineering Co.
    Inventors: Christian C. Jahan, Jacques Bouvin
  • Patent number: 4102388
    Abstract: Heat energy, preferably from a low grade energy source, is concentrated and transferred to another medium by a multi-zone steam absorption procedure.
    Type: Grant
    Filed: September 26, 1977
    Date of Patent: July 25, 1978
    Assignee: Shell Oil Company
    Inventor: George C. Blytas
  • Patent number: 4094355
    Abstract: Process for recovery of heat characterized by the concentration of heat from a heat source and transfer of the heat to raise the temperature of a heat receiving medium above that of the heat source.
    Type: Grant
    Filed: September 23, 1976
    Date of Patent: June 13, 1978
    Assignee: Shell Oil Company
    Inventor: George C. Blytas
  • Patent number: 4072027
    Abstract: A stabilized heat exchange medium is disclosed including a fluorocarbon, an absorbant and a tribasic phosphite stabilizer. The preferred absorbants are assymetrical furan derivatives containing at least 1 oxygen with a single bond to an adjacent carbon, and is most preferably an alkyl tetrahydrofurfuryl ether. The fluorocarbon contains 1 or 2 carbons, 1 or 2 hydrogens and the remainder chlorine and fluorine. The tribasic phosphites are of the formula (R.sub.1 'O)(R.sub.2 'O)(R.sub.3 'O)P, wherein R.sub.1 ', R.sub.2 ' and R.sub.3 ' are each independently alkyl, alkenyl, phenyl, alkylene phenyl, alkylene alkylphenyl or alkylphenyl.
    Type: Grant
    Filed: January 19, 1977
    Date of Patent: February 7, 1978
    Assignee: Allied Chemical Corporation
    Inventors: Morris B. Berenbaum, Francis E. Evans, Richard E. Eibeck, Martin A. Robinson
  • Patent number: 4042524
    Abstract: The invention comprises a novel compound having the chemical name 2-(t-butoxymethyl) tetrahydrofuran and a novel absorption pair comprising 2-(t-butoxymethyl) tetrahydrofuran as the solvent and a lower alkyl fluorocarbon as the solute. The invention further comprises a method of absorption heating and method of absorption refrigeration using the novel absorption pair and absorption heating and an absorption cooling apparatus using the novel absorption pair.
    Type: Grant
    Filed: April 10, 1975
    Date of Patent: August 16, 1977
    Assignee: Allied Chemical Corporation
    Inventors: Henry R. Nychka, Richard E. Eibeck, Chien C. Li
  • Patent number: 4034569
    Abstract: A system for the effective utilization of low-grade heat sources such as solar energy, with a system including a molecular sieve material such as zeolite and a gaseous fluid adapted to be absorbed by the material which is in a closed container and circuit which includes a condenser and a gas expansion cooler member. When the container is heated, a gas is given off from the molecular sieve material, cooled in a condenser, and thereafter expaned for cooling purposes. In one embodiment, the cooled gas is received in a further container having absorbent material and subsequently, upon cooling of the first container, the gaseous fluid may be returned thereto via again a condenser and gas expansion cooler member to provide further cooling. In another embodiment, the molecular sieve material is formed by sintering same to form a pressure resistant divider across the container.
    Type: Grant
    Filed: November 4, 1974
    Date of Patent: July 12, 1977
    Inventor: Dimiter I. Tchernev
  • Patent number: 4019992
    Abstract: Working fluid compositions for absorption refrigeration systems comprising alcohol, lithium bromide, zinc bromide and a synergistic mixture of arsenic trioxide and the sodium salt of ethylenediaminetetraacetic acid which are markedly inhibited in corrosion of ferrous metals, and a method for inhibiting the corrosion of ferrous metals by alcohol-lithium bromide-zinc bromide mixture by adding a synergistic combination of arsenic trioxide and ethylenediaminetetraacetic acid.
    Type: Grant
    Filed: November 3, 1975
    Date of Patent: April 26, 1977
    Assignee: Borg-Warner Corporation
    Inventor: Robert Harold Krueger
  • Patent number: 4018694
    Abstract: Solutions containing lower aliphatic alcohols, the halides of lithium, calcium, strontium and barium and water are used as absorbent-refrigerant compositions in absorption refrigeration systems.
    Type: Grant
    Filed: October 2, 1975
    Date of Patent: April 19, 1977
    Assignee: Arkla Industries Inc.
    Inventor: Philip P. Anderson
  • Patent number: 4005584
    Abstract: The invention comprises absorption pair compositions consisting essentially of selected lower alkyl fluorocarbon solutes dissolved in selected furan ring containing absorbents. The invention further comprises a method of absorption heating utilizing such compositions and absorption heating apparatus incorporating such compositions. The invention also comprises a novel furan compound, namely, n-butyl tetrahydrofurfuryl ether.
    Type: Grant
    Filed: April 10, 1975
    Date of Patent: February 1, 1977
    Assignee: Allied Chemical Corporation
    Inventor: Chien C. Li
  • Patent number: 3977204
    Abstract: An alcohol circuit for use in an absorption refrigeration system for circulating alcohol through the system along an independent path of travel which prevents the alcohol from stagnating within the evaporator section of the system. Further means are provided to precondition the alcohol prior to its introduction into the absorber section to enhance the effective use of this additive within this section.
    Type: Grant
    Filed: November 14, 1975
    Date of Patent: August 31, 1976
    Assignee: Carrier Corporation
    Inventor: Joseph R. Bourne
  • Patent number: 3968045
    Abstract: Carbon dioxide gas is bled into an absorption refrigeration system to reduce the alkaline normality of an aqueous lithium bromide solution. The carbon dioxide reacts with lithium hydroxide contained in the solution to form a carbonate thereby reducing the alkaline normality of the solution.
    Type: Grant
    Filed: February 28, 1975
    Date of Patent: July 6, 1976
    Assignee: Carrier Corporation
    Inventor: Howard W. Sibley
  • Patent number: 3949566
    Abstract: A purge arrangement for absorption refrigeration systems using a solution of lithium bromide as an absorbent and water as a refrigerant, and a heat transfer additive, such as octyl alcohol being added to and mixing with the lithium bromide solution. The purge arrangement includes means for automatically removing noncondensible gases or vapor from the system, said means including a vacuum pump connected to a receiver to draw noncondensible gases therefrom; automatic electrical control means for said vacuum pump; and an additive overflow conduit to prevent additive collecting in the storage receiver and to assure additive return flow into the solution conduit.
    Type: Grant
    Filed: August 1, 1974
    Date of Patent: April 13, 1976
    Assignee: Borg-Warner Corporation
    Inventor: Neil E. Hopkins